#------------------------------------------------------------------------------
#$Date: 2021-05-03 11:10:53 +0300 (Mon, 03 May 2021) $
#$Revision: 264764 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/07/16/4071636.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4071636
loop_
_publ_author_name
'Buchalski, Piotr'
'Grabowska, Ilona'
'Karaskiewicz, Anna'
'Suwińska, Kinga'
'Jerzykiewicz, Lucjan'
_publ_section_title
;
 Novel 9-Nickelafluorenyl Sandwich Complexes of Nickel(II) and Cobalt(II)
;
_journal_issue                   13
_journal_name_full               Organometallics
_journal_page_first              3316
_journal_paper_doi               10.1021/om8002834
_journal_volume                  27
_journal_year                    2008
_chemical_formula_moiety         'C36 H30 Co Ni2'
_chemical_formula_sum            'C36 H30 Co Ni2'
_chemical_formula_weight         638.95
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                96.93(1)
_cell_angle_beta                 98.93(1)
_cell_angle_gamma                114.74(1)
_cell_formula_units_Z            2
_cell_length_a                   9.256(5)
_cell_length_b                   9.305(5)
_cell_length_c                   17.278(5)
_cell_measurement_reflns_used    8432
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      26
_cell_measurement_theta_min      2
_cell_volume                     1306.3(11)
_computing_cell_refinement
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.13 beta (release 14.11.2003 CrysAlis171 VC++)
;
_computing_data_collection
;
CrysAlis CCD, Oxford Diffraction Ltd.,
Version 1.171.13 beta (release 14.11.2003 CrysAlis171 VC++)
;
_computing_data_reduction
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.13 beta (release 14.11.2003 CrysAlis171 VC++)
(compiled Nov 14 2003,14:35:41)
;
_computing_molecular_graphics    'SHELXTL-NT V5.1, Bruker AXS 1999'
_computing_publication_material  'SHELXTL-NT V5.1, Bruker AXS 1999'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'Kuma KM4CCD kappa-axis diffractometer'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0471
_diffrn_reflns_av_sigmaI/netI    0.0698
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            17504
_diffrn_reflns_theta_full        28.05
_diffrn_reflns_theta_max         28.05
_diffrn_reflns_theta_min         2.97
_exptl_absorpt_coefficient_mu    2.080
_exptl_absorpt_correction_T_max  0.8752
_exptl_absorpt_correction_T_min  0.6541
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.13 beta (release 14.11.2003 CrysAlis171 VC++)
Analytical numeric absorption correction using a multifaceted crystal
model based on expressions derived by R.C. Clark & J.S. Reid.
;
_exptl_crystal_colour            BLACK
_exptl_crystal_density_diffrn    1.624
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       PLATE
_exptl_crystal_F_000             658
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.03
_refine_diff_density_max         0.669
_refine_diff_density_min         -0.501
_refine_diff_density_rms         0.096
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     355
_refine_ls_number_reflns         6292
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.0717
_refine_ls_R_factor_gt           0.0409
_refine_ls_shift/su_max          0.029
_refine_ls_shift/su_mean         0.003
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0418P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0844
_refine_ls_wR_factor_ref         0.0909
_reflns_number_gt                4451
_reflns_number_total             6292
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om8002834-file002.cif
_cod_data_source_block           compound_(3)
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

2021-05-03
Z value and formula fixed to values more according to usual
chemical conventions.                 miguel
;
_cod_original_formula_sum            'C72 H60 Co2 Ni4'
_cod_original_formula_weight         1277.90
_cod_original_formula_moiety         '2(C36 H30 Co Ni2)'
_cod_original_formula_units_Z            1
_cod_database_code               4071636
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ni1 Ni 0.30700(5) 0.49823(5) 0.39172(2) 0.01403(11) Uani 1 1 d .
Ni2 Ni 0.23579(5) 0.47870(5) -0.04976(2) 0.01540(11) Uani 1 1 d .
Co1 Co 0.5000 0.5000 0.5000 0.01245(14) Uani 1 2 d S
Co2 Co 0.5000 0.5000 0.0000 0.01362(14) Uani 1 2 d S
C11 C 0.5767(4) 0.4415(4) 0.37251(18) 0.0152(7) Uani 1 1 d .
C12 C 0.4095(4) 0.3582(4) 0.37509(18) 0.0153(7) Uani 1 1 d .
C13 C 0.3351(4) 0.1872(4) 0.35541(18) 0.0190(7) Uani 1 1 d .
H13A H 0.2244 0.1275 0.3579 0.023 Uiso 1 1 calc R
C14 C 0.4230(4) 0.1059(4) 0.33246(19) 0.0229(8) Uani 1 1 d .
H14A H 0.3712 -0.0089 0.3186 0.028 Uiso 1 1 calc R
C15 C 0.5863(4) 0.1907(4) 0.32951(19) 0.0231(8) Uani 1 1 d .
H15A H 0.6447 0.1336 0.3135 0.028 Uiso 1 1 calc R
C16 C 0.6632(4) 0.3575(4) 0.34975(19) 0.0206(7) Uani 1 1 d .
H16A H 0.7747 0.4151 0.3482 0.025 Uiso 1 1 calc R
C17 C 0.6424(4) 0.6186(4) 0.39554(18) 0.0171(7) Uani 1 1 d .
C18 C 0.5265(4) 0.6681(4) 0.41758(18) 0.0170(7) Uani 1 1 d .
C19 C 0.5785(4) 0.8366(4) 0.44325(19) 0.0208(7) Uani 1 1 d .
H19A H 0.5049 0.8740 0.4599 0.025 Uiso 1 1 calc R
C20 C 0.7368(4) 0.9467(4) 0.4440(2) 0.0257(8) Uani 1 1 d .
H20A H 0.7701 1.0591 0.4610 0.031 Uiso 1 1 calc R
C21 C 0.8474(4) 0.8950(4) 0.4204(2) 0.0264(8) Uani 1 1 d .
H21A H 0.9540 0.9723 0.4198 0.032 Uiso 1 1 calc R
C22 C 0.8029(4) 0.7325(4) 0.39796(19) 0.0212(7) Uani 1 1 d .
H22A H 0.8800 0.6973 0.3842 0.025 Uiso 1 1 calc R
C31 C 0.0623(4) 0.3607(4) 0.3221(2) 0.0222(8) Uani 1 1 d .
C32 C 0.1246(4) 0.5155(4) 0.3047(2) 0.0228(8) Uani 1 1 d .
H32A H 0.1359 0.5414 0.2508 0.027 Uiso 1 1 calc R
C33 C 0.1739(4) 0.6294(4) 0.3778(2) 0.0239(8) Uani 1 1 d .
H33A H 0.2213 0.7495 0.3835 0.029 Uiso 1 1 calc R
C34 C 0.1319(4) 0.5448(4) 0.4399(2) 0.0254(8) Uani 1 1 d .
H34A H 0.1448 0.5939 0.4969 0.030 Uiso 1 1 calc R
C35 C 0.0647(4) 0.3786(4) 0.4064(2) 0.0229(8) Uani 1 1 d .
H35A H 0.0232 0.2886 0.4357 0.027 Uiso 1 1 calc R
C36 C -0.0109(5) 0.2039(4) 0.2630(2) 0.0334(9) Uani 1 1 d .
H36A H -0.1267 0.1724 0.2413 0.050 Uiso 1 1 calc R
H36B H -0.0006 0.1203 0.2895 0.050 Uiso 1 1 calc R
H36C H 0.0464 0.2163 0.2192 0.050 Uiso 1 1 calc R
C41 C 0.3200(4) 0.3619(4) 0.08489(19) 0.0169(7) Uani 1 1 d .
C42 C 0.2567(4) 0.3116(4) 0.00061(19) 0.0176(7) Uani 1 1 d .
C43 C 0.2022(4) 0.1475(4) -0.0333(2) 0.0225(7) Uani 1 1 d .
H43A H 0.1625 0.1105 -0.0896 0.027 Uiso 1 1 calc R
C44 C 0.2057(4) 0.0395(4) 0.0144(2) 0.0278(8) Uani 1 1 d .
H44A H 0.1658 -0.0714 -0.0096 0.033 Uiso 1 1 calc R
C45 C 0.2670(4) 0.0905(4) 0.0973(2) 0.0275(8) Uani 1 1 d .
H45A H 0.2692 0.0148 0.1292 0.033 Uiso 1 1 calc R
C46 C 0.3239(4) 0.2503(4) 0.1323(2) 0.0240(8) Uani 1 1 d .
H46A H 0.3659 0.2855 0.1886 0.029 Uiso 1 1 calc R
C47 C 0.3814(4) 0.5375(4) 0.11363(19) 0.0170(7) Uani 1 1 d .
C48 C 0.3655(4) 0.6194(4) 0.05135(19) 0.0164(7) Uani 1 1 d .
C49 C 0.4279(4) 0.7896(4) 0.07263(19) 0.0188(7) Uani 1 1 d .
H49A H 0.4211 0.8490 0.0323 0.023 Uiso 1 1 calc R
C50 C 0.4988(4) 0.8705(4) 0.1518(2) 0.0223(7) Uani 1 1 d .
H50A H 0.5399 0.9847 0.1650 0.027 Uiso 1 1 calc R
C51 C 0.5105(4) 0.7864(4) 0.21220(19) 0.0235(8) Uani 1 1 d .
H51A H 0.5580 0.8435 0.2662 0.028 Uiso 1 1 calc R
C52 C 0.4535(4) 0.6212(4) 0.19400(19) 0.0230(8) Uani 1 1 d .
H52A H 0.4626 0.5640 0.2350 0.028 Uiso 1 1 calc R
C61 C 0.0886(4) 0.3633(4) -0.16831(19) 0.0194(7) Uani 1 1 d .
C62 C -0.0053(4) 0.4021(4) -0.11842(19) 0.0203(7) Uani 1 1 d .
H62A H -0.1082 0.3231 -0.1067 0.024 Uiso 1 1 calc R
C63 C 0.0699(4) 0.5698(4) -0.09009(19) 0.0201(7) Uani 1 1 d .
H63A H 0.0292 0.6317 -0.0555 0.024 Uiso 1 1 calc R
C64 C 0.2141(4) 0.6378(4) -0.1217(2) 0.0227(8) Uani 1 1 d .
H64A H 0.2904 0.7554 -0.1132 0.027 Uiso 1 1 calc R
C65 C 0.2212(4) 0.5100(4) -0.17211(19) 0.0211(7) Uani 1 1 d .
H65A H 0.3059 0.5209 -0.2036 0.025 Uiso 1 1 calc R
C66 C 0.0426(5) 0.2002(4) -0.2168(2) 0.0269(8) Uani 1 1 d .
H66A H -0.0267 0.1851 -0.2691 0.040 Uiso 1 1 calc R
H66B H -0.0175 0.1167 -0.1887 0.040 Uiso 1 1 calc R
H66C H 0.1416 0.1916 -0.2244 0.040 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C18 Ni1 C12 84.26(14) . .
C18 Ni1 C33 101.03(14) . .
C12 Ni1 C33 165.13(13) . .
C18 Ni1 C34 117.50(14) . .
C12 Ni1 C34 148.26(14) . .
C33 Ni1 C34 39.57(14) . .
C18 Ni1 C35 154.97(14) . .
C12 Ni1 C35 114.13(14) . .
C33 Ni1 C35 65.68(14) . .
C34 Ni1 C35 38.92(14) . .
C18 Ni1 C31 155.69(14) . .
C12 Ni1 C31 104.34(13) . .
C33 Ni1 C31 65.49(14) . .
C34 Ni1 C31 65.87(13) . .
C35 Ni1 C31 39.59(13) . .
C18 Ni1 C32 118.91(13) . .
C12 Ni1 C32 126.19(13) . .
C33 Ni1 C32 39.23(13) . .
C34 Ni1 C32 65.59(14) . .
C35 Ni1 C32 65.01(13) . .
C31 Ni1 C32 38.11(13) . .
C18 Ni1 Co1 60.75(10) . .
C12 Ni1 Co1 61.17(9) . .
C33 Ni1 Co1 133.50(10) . .
C34 Ni1 Co1 107.54(10) . .
C35 Ni1 Co1 111.87(10) . .
C31 Ni1 Co1 143.26(10) . .
C32 Ni1 Co1 172.52(9) . .
C48 Ni2 C42 84.33(14) . .
C48 Ni2 C64 103.46(14) . .
C42 Ni2 C64 170.55(13) . .
C48 Ni2 C63 105.10(13) . .
C42 Ni2 C63 143.44(13) . .
C64 Ni2 C63 40.11(13) . .
C48 Ni2 C62 135.93(13) . .
C42 Ni2 C62 112.27(13) . .
C64 Ni2 C62 65.83(13) . .
C63 Ni2 C62 38.52(13) . .
C48 Ni2 C61 168.75(13) . .
C42 Ni2 C61 106.88(13) . .
C64 Ni2 C61 65.49(13) . .
C63 Ni2 C61 65.35(12) . .
C62 Ni2 C61 39.16(12) . .
C48 Ni2 C65 133.26(13) . .
C42 Ni2 C65 131.67(13) . .
C64 Ni2 C65 38.88(13) . .
C63 Ni2 C65 65.59(13) . .
C62 Ni2 C65 65.11(13) . .
C61 Ni2 C65 38.59(12) . .
C48 Ni2 Co2 60.41(9) . .
C42 Ni2 Co2 60.39(9) . .
C64 Ni2 Co2 118.64(10) . .
C63 Ni2 Co2 154.31(9) . .
C62 Ni2 Co2 163.28(9) . .
C61 Ni2 Co2 125.73(9) . .
C65 Ni2 Co2 107.40(9) . .
C18 Co1 C18 180.000(1) 2_666 .
C18 Co1 C12 71.34(12) 2_666 2_666
C18 Co1 C12 108.66(12) . 2_666
C18 Co1 C12 108.66(12) 2_666 .
C18 Co1 C12 71.34(12) . .
C12 Co1 C12 180.000(1) 2_666 .
C18 Co1 Ni1 49.46(9) 2_666 2_666
C18 Co1 Ni1 130.54(9) . 2_666
C12 Co1 Ni1 49.47(8) 2_666 2_666
C12 Co1 Ni1 130.53(8) . 2_666
C18 Co1 Ni1 130.54(9) 2_666 .
C18 Co1 Ni1 49.46(9) . .
C12 Co1 Ni1 130.53(8) 2_666 .
C12 Co1 Ni1 49.47(8) . .
Ni1 Co1 Ni1 180.0 2_666 .
C18 Co1 C11 61.49(11) 2_666 2_666
C18 Co1 C11 118.51(11) . 2_666
C12 Co1 C11 34.63(11) 2_666 2_666
C12 Co1 C11 145.37(11) . 2_666
Ni1 Co1 C11 70.90(8) 2_666 2_666
Ni1 Co1 C11 109.10(8) . 2_666
C18 Co1 C11 118.51(11) 2_666 .
C18 Co1 C11 61.49(11) . .
C12 Co1 C11 145.37(11) 2_666 .
C12 Co1 C11 34.63(11) . .
Ni1 Co1 C11 109.10(8) 2_666 .
Ni1 Co1 C11 70.90(8) . .
C11 Co1 C11 180.00(6) 2_666 .
C18 Co1 C17 34.40(11) 2_666 2_666
C18 Co1 C17 145.60(11) . 2_666
C12 Co1 C17 61.30(11) 2_666 2_666
C12 Co1 C17 118.70(11) . 2_666
Ni1 Co1 C17 70.57(8) 2_666 2_666
Ni1 Co1 C17 109.43(8) . 2_666
C11 Co1 C17 34.44(10) 2_666 2_666
C11 Co1 C17 145.56(10) . 2_666
C18 Co1 C17 145.60(11) 2_666 .
C18 Co1 C17 34.40(11) . .
C12 Co1 C17 118.70(11) 2_666 .
C12 Co1 C17 61.30(11) . .
Ni1 Co1 C17 109.43(8) 2_666 .
Ni1 Co1 C17 70.57(8) . .
C11 Co1 C17 145.56(10) 2_666 .
C11 Co1 C17 34.44(10) . .
C17 Co1 C17 180.000(1) 2_666 .
C48 Co2 C48 180.00(15) . 2_665
C48 Co2 C42 108.01(12) . 2_665
C48 Co2 C42 71.99(12) 2_665 2_665
C48 Co2 C42 71.99(12) . .
C48 Co2 C42 108.01(12) 2_665 .
C42 Co2 C42 180.0 2_665 .
C48 Co2 Ni2 130.58(9) . 2_665
C48 Co2 Ni2 49.42(9) 2_665 2_665
C42 Co2 Ni2 49.74(9) 2_665 2_665
C42 Co2 Ni2 130.26(9) . 2_665
C48 Co2 Ni2 49.42(9) . .
C48 Co2 Ni2 130.58(9) 2_665 .
C42 Co2 Ni2 130.26(9) 2_665 .
C42 Co2 Ni2 49.74(9) . .
Ni2 Co2 Ni2 180.0 2_665 .
C48 Co2 C41 62.27(11) . .
C48 Co2 C41 117.73(11) 2_665 .
C42 Co2 C41 144.89(11) 2_665 .
C42 Co2 C41 35.11(11) . .
Ni2 Co2 C41 108.52(8) 2_665 .
Ni2 Co2 C41 71.48(8) . .
C48 Co2 C41 117.73(11) . 2_665
C48 Co2 C41 62.27(11) 2_665 2_665
C42 Co2 C41 35.11(11) 2_665 2_665
C42 Co2 C41 144.89(11) . 2_665
Ni2 Co2 C41 71.48(8) 2_665 2_665
Ni2 Co2 C41 108.52(8) . 2_665
C41 Co2 C41 180.00(16) . 2_665
C48 Co2 C47 145.08(11) . 2_665
C48 Co2 C47 34.92(11) 2_665 2_665
C42 Co2 C47 62.32(11) 2_665 2_665
C42 Co2 C47 117.68(11) . 2_665
Ni2 Co2 C47 71.23(8) 2_665 2_665
Ni2 Co2 C47 108.77(8) . 2_665
C41 Co2 C47 144.94(11) . 2_665
C41 Co2 C47 35.06(10) 2_665 2_665
C48 Co2 C47 34.92(11) . .
C48 Co2 C47 145.08(11) 2_665 .
C42 Co2 C47 117.68(11) 2_665 .
C42 Co2 C47 62.32(11) . .
Ni2 Co2 C47 108.77(8) 2_665 .
Ni2 Co2 C47 71.23(8) . .
C41 Co2 C47 35.06(11) . .
C41 Co2 C47 144.94(11) 2_665 .
C47 Co2 C47 180.00(16) 2_665 .
C16 C11 C12 121.2(3) . .
C16 C11 C17 125.9(3) . .
C12 C11 C17 112.9(3) . .
C16 C11 Co1 132.8(2) . .
C12 C11 Co1 62.44(16) . .
C17 C11 Co1 73.08(17) . .
C13 C12 C11 117.5(3) . .
C13 C12 Ni1 128.2(2) . .
C11 C12 Ni1 113.7(2) . .
C13 C12 Co1 123.4(2) . .
C11 C12 Co1 82.92(18) . .
Ni1 C12 Co1 69.36(10) . .
C14 C13 C12 120.4(3) . .
C13 C14 C15 120.9(3) . .
C16 C15 C14 120.1(3) . .
C15 C16 C11 119.9(3) . .
C22 C17 C18 121.2(3) . .
C22 C17 C11 125.9(3) . .
C18 C17 C11 113.0(3) . .
C22 C17 Co1 133.4(2) . .
C18 C17 Co1 61.59(17) . .
C11 C17 Co1 72.48(17) . .
C17 C18 C19 117.7(3) . .
C17 C18 Ni1 114.0(2) . .
C19 C18 Ni1 127.5(3) . .
C17 C18 Co1 84.01(19) . .
C19 C18 Co1 123.7(2) . .
Ni1 C18 Co1 69.79(10) . .
C20 C19 C18 120.1(3) . .
C19 C20 C21 121.1(3) . .
C22 C21 C20 120.3(3) . .
C21 C22 C17 119.6(3) . .
C32 C31 C35 107.7(3) . .
C32 C31 C36 126.4(3) . .
C35 C31 C36 125.6(3) . .
C32 C31 Ni1 71.50(19) . .
C35 C31 Ni1 69.47(19) . .
C36 C31 Ni1 129.5(2) . .
C31 C32 C33 107.8(3) . .
C31 C32 Ni1 70.39(18) . .
C33 C32 Ni1 67.41(18) . .
C34 C33 C32 108.8(3) . .
C34 C33 Ni1 71.4(2) . .
C32 C33 Ni1 73.35(18) . .
C35 C34 C33 107.4(3) . .
C35 C34 Ni1 71.09(19) . .
C33 C34 Ni1 69.08(19) . .
C34 C35 C31 108.1(3) . .
C34 C35 Ni1 70.0(2) . .
C31 C35 Ni1 70.94(19) . .
C46 C41 C42 121.0(3) . .
C46 C41 C47 126.0(3) . .
C42 C41 C47 113.0(3) . .
C46 C41 Co2 131.6(2) . .
C42 C41 Co2 62.94(17) . .
C47 C41 Co2 72.52(17) . .
C43 C42 C41 117.4(3) . .
C43 C42 Ni2 128.7(3) . .
C41 C42 Ni2 113.5(2) . .
C43 C42 Co2 122.7(2) . .
C41 C42 Co2 81.95(19) . .
Ni2 C42 Co2 69.87(11) . .
C44 C43 C42 120.7(3) . .
C43 C44 C45 121.2(3) . .
C46 C45 C44 119.7(3) . .
C45 C46 C41 119.9(3) . .
C52 C47 C48 121.6(3) . .
C52 C47 C41 125.3(3) . .
C48 C47 C41 113.1(3) . .
C52 C47 Co2 132.0(2) . .
C48 C47 Co2 62.78(17) . .
C41 C47 Co2 72.42(17) . .
C47 C48 C49 117.2(3) . .
C47 C48 Ni2 114.1(2) . .
C49 C48 Ni2 128.2(2) . .
C47 C48 Co2 82.30(18) . .
C49 C48 Co2 123.0(2) . .
Ni2 C48 Co2 70.17(10) . .
C50 C49 C48 120.7(3) . .
C49 C50 C51 121.0(3) . .
C52 C51 C50 120.3(3) . .
C51 C52 C47 119.3(3) . .
C65 C61 C62 108.1(3) . .
C65 C61 C66 125.7(3) . .
C62 C61 C66 125.8(3) . .
C65 C61 Ni2 71.43(19) . .
C62 C61 Ni2 70.01(18) . .
C66 C61 Ni2 130.5(2) . .
C63 C62 C61 108.4(3) . .
C63 C62 Ni2 70.04(18) . .
C61 C62 Ni2 70.83(19) . .
C62 C63 C64 107.8(3) . .
C62 C63 Ni2 71.44(18) . .
C64 C63 Ni2 69.31(19) . .
C65 C64 C63 108.0(3) . .
C65 C64 Ni2 73.03(19) . .
C63 C64 Ni2 70.57(19) . .
C64 C65 C61 107.7(3) . .
C64 C65 Ni2 68.09(19) . .
C61 C65 Ni2 69.98(19) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ni1 C18 1.920(3) .
Ni1 C12 1.926(3) .
Ni1 C33 2.075(3) .
Ni1 C34 2.104(3) .
Ni1 C35 2.119(4) .
Ni1 C31 2.138(3) .
Ni1 C32 2.153(3) .
Ni1 Co1 2.3711(8) .
Ni2 C48 1.921(3) .
Ni2 C42 1.933(3) .
Ni2 C64 2.095(3) .
Ni2 C63 2.112(3) .
Ni2 C62 2.130(3) .
Ni2 C61 2.141(3) .
Ni2 C65 2.160(3) .
Ni2 Co2 2.3789(13) .
Co1 C18 2.205(3) 2_666
Co1 C18 2.205(3) .
Co1 C12 2.220(3) 2_666
Co1 C12 2.220(3) .
Co1 Ni1 2.3711(8) 2_666
Co1 C11 2.485(3) 2_666
Co1 C11 2.485(3) .
Co1 C17 2.493(3) 2_666
Co1 C17 2.493(3) .
Co2 C48 2.199(3) .
Co2 C48 2.199(3) 2_665
Co2 C42 2.203(3) 2_665
Co2 C42 2.203(3) .
Co2 Ni2 2.3789(13) 2_665
Co2 C41 2.449(3) .
Co2 C41 2.449(3) 2_665
Co2 C47 2.451(3) 2_665
Co2 C47 2.451(3) .
C11 C16 1.397(4) .
C11 C12 1.423(4) .
C11 C17 1.473(4) .
C12 C13 1.415(4) .
C13 C14 1.391(4) .
C14 C15 1.395(5) .
C15 C16 1.380(5) .
C17 C22 1.409(4) .
C17 C18 1.416(4) .
C18 C19 1.421(4) .
C19 C20 1.389(5) .
C20 C21 1.393(5) .
C21 C22 1.376(5) .
C31 C32 1.401(5) .
C31 C35 1.442(5) .
C31 C36 1.493(5) .
C32 C33 1.421(5) .
C33 C34 1.415(5) .
C34 C35 1.407(5) .
C41 C46 1.407(4) .
C41 C42 1.423(4) .
C41 C47 1.476(4) .
C42 C43 1.406(4) .
C43 C44 1.381(5) .
C44 C45 1.399(5) .
C45 C46 1.373(5) .
C47 C52 1.413(4) .
C47 C48 1.415(4) .
C48 C49 1.416(4) .
C49 C50 1.388(4) .
C50 C51 1.395(5) .
C51 C52 1.377(5) .
C61 C65 1.421(5) .
C61 C62 1.431(5) .
C61 C66 1.492(5) .
C62 C63 1.399(5) .
C63 C64 1.443(5) .
C64 C65 1.417(5) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C18 Ni1 Co1 C18 180.0 . 2_666
C12 Ni1 Co1 C18 -79.79(15) . 2_666
C33 Ni1 Co1 C18 103.24(18) . 2_666
C34 Ni1 Co1 C18 67.79(15) . 2_666
C35 Ni1 Co1 C18 26.59(15) . 2_666
C31 Ni1 Co1 C18 -5.14(18) . 2_666
C32 Ni1 Co1 C18 90.5(7) . 2_666
C12 Ni1 Co1 C18 100.21(15) . .
C33 Ni1 Co1 C18 -76.76(18) . .
C34 Ni1 Co1 C18 -112.21(15) . .
C35 Ni1 Co1 C18 -153.41(15) . .
C31 Ni1 Co1 C18 174.86(18) . .
C32 Ni1 Co1 C18 -89.5(7) . .
C18 Ni1 Co1 C12 79.79(16) . 2_666
C12 Ni1 Co1 C12 180.000(2) . 2_666
C33 Ni1 Co1 C12 3.02(17) . 2_666
C34 Ni1 Co1 C12 -32.42(15) . 2_666
C35 Ni1 Co1 C12 -73.62(15) . 2_666
C31 Ni1 Co1 C12 -105.36(19) . 2_666
C32 Ni1 Co1 C12 -9.7(7) . 2_666
C18 Ni1 Co1 C12 -100.21(16) . .
C33 Ni1 Co1 C12 -176.98(17) . .
C34 Ni1 Co1 C12 147.58(15) . .
C35 Ni1 Co1 C12 106.38(15) . .
C31 Ni1 Co1 C12 74.64(19) . .
C32 Ni1 Co1 C12 170.3(7) . .
C18 Ni1 Co1 Ni1 -85(100) . 2_666
C12 Ni1 Co1 Ni1 15(100) . 2_666
C33 Ni1 Co1 Ni1 -162(100) . 2_666
C34 Ni1 Co1 Ni1 163(100) . 2_666
C35 Ni1 Co1 Ni1 121(100) . 2_666
C31 Ni1 Co1 Ni1 90(100) . 2_666
C32 Ni1 Co1 Ni1 -175(100) . 2_666
C18 Ni1 Co1 C11 111.63(14) . 2_666
C12 Ni1 Co1 C11 -148.16(13) . 2_666
C33 Ni1 Co1 C11 34.86(16) . 2_666
C34 Ni1 Co1 C11 -0.59(13) . 2_666
C35 Ni1 Co1 C11 -41.78(13) . 2_666
C31 Ni1 Co1 C11 -73.52(17) . 2_666
C32 Ni1 Co1 C11 22.1(7) . 2_666
C18 Ni1 Co1 C11 -68.37(14) . .
C12 Ni1 Co1 C11 31.84(13) . .
C33 Ni1 Co1 C11 -145.14(16) . .
C34 Ni1 Co1 C11 179.41(13) . .
C35 Ni1 Co1 C11 138.22(13) . .
C31 Ni1 Co1 C11 106.48(17) . .
C32 Ni1 Co1 C11 -157.9(7) . .
C18 Ni1 Co1 C17 148.17(13) . 2_666
C12 Ni1 Co1 C17 -111.61(13) . 2_666
C33 Ni1 Co1 C17 71.41(16) . 2_666
C34 Ni1 Co1 C17 35.96(13) . 2_666
C35 Ni1 Co1 C17 -5.24(13) . 2_666
C31 Ni1 Co1 C17 -36.97(17) . 2_666
C32 Ni1 Co1 C17 58.7(7) . 2_666
C18 Ni1 Co1 C17 -31.83(13) . .
C12 Ni1 Co1 C17 68.39(13) . .
C33 Ni1 Co1 C17 -108.59(16) . .
C34 Ni1 Co1 C17 -144.04(13) . .
C35 Ni1 Co1 C17 174.76(13) . .
C31 Ni1 Co1 C17 143.03(17) . .
C32 Ni1 Co1 C17 -121.3(7) . .
C42 Ni2 Co2 C48 -101.07(16) . .
C64 Ni2 Co2 C48 89.70(16) . .
C63 Ni2 Co2 C48 60.7(2) . .
C62 Ni2 Co2 C48 -169.0(3) . .
C61 Ni2 Co2 C48 168.79(15) . .
C65 Ni2 Co2 C48 130.38(15) . .
C48 Ni2 Co2 C48 180.0 . 2_665
C42 Ni2 Co2 C48 78.93(16) . 2_665
C64 Ni2 Co2 C48 -90.30(16) . 2_665
C63 Ni2 Co2 C48 -119.3(2) . 2_665
C62 Ni2 Co2 C48 11.0(3) . 2_665
C61 Ni2 Co2 C48 -11.21(15) . 2_665
C65 Ni2 Co2 C48 -49.62(15) . 2_665
C48 Ni2 Co2 C42 -78.93(16) . 2_665
C42 Ni2 Co2 C42 180.0 . 2_665
C64 Ni2 Co2 C42 10.77(15) . 2_665
C63 Ni2 Co2 C42 -18.2(2) . 2_665
C62 Ni2 Co2 C42 112.1(3) . 2_665
C61 Ni2 Co2 C42 89.85(16) . 2_665
C65 Ni2 Co2 C42 51.44(15) . 2_665
C48 Ni2 Co2 C42 101.07(16) . .
C64 Ni2 Co2 C42 -169.23(15) . .
C63 Ni2 Co2 C42 161.8(2) . .
C62 Ni2 Co2 C42 -67.9(3) . .
C61 Ni2 Co2 C42 -90.15(16) . .
C65 Ni2 Co2 C42 -128.56(15) . .
C48 Ni2 Co2 Ni2 -162(100) . 2_665
C42 Ni2 Co2 Ni2 97(100) . 2_665
C64 Ni2 Co2 Ni2 -72(100) . 2_665
C63 Ni2 Co2 Ni2 -101(100) . 2_665
C62 Ni2 Co2 Ni2 29(100) . 2_665
C61 Ni2 Co2 Ni2 7(100) . 2_665
C65 Ni2 Co2 Ni2 -31(100) . 2_665
C48 Ni2 Co2 C41 68.94(14) . .
C42 Ni2 Co2 C41 -32.12(13) . .
C64 Ni2 Co2 C41 158.64(13) . .
C63 Ni2 Co2 C41 129.7(2) . .
C62 Ni2 Co2 C41 -100.0(3) . .
C61 Ni2 Co2 C41 -122.27(14) . .
C65 Ni2 Co2 C41 -160.68(12) . .
C48 Ni2 Co2 C41 -111.06(14) . 2_665
C42 Ni2 Co2 C41 147.88(13) . 2_665
C64 Ni2 Co2 C41 -21.36(13) . 2_665
C63 Ni2 Co2 C41 -50.3(2) . 2_665
C62 Ni2 Co2 C41 80.0(3) . 2_665
C61 Ni2 Co2 C41 57.73(14) . 2_665
C65 Ni2 Co2 C41 19.32(12) . 2_665
C48 Ni2 Co2 C47 -148.13(13) . 2_665
C42 Ni2 Co2 C47 110.80(14) . 2_665
C64 Ni2 Co2 C47 -58.43(14) . 2_665
C63 Ni2 Co2 C47 -87.4(2) . 2_665
C62 Ni2 Co2 C47 42.9(3) . 2_665
C61 Ni2 Co2 C47 20.66(14) . 2_665
C65 Ni2 Co2 C47 -17.75(13) . 2_665
C48 Ni2 Co2 C47 31.87(13) . .
C42 Ni2 Co2 C47 -69.19(14) . .
C64 Ni2 Co2 C47 121.57(14) . .
C63 Ni2 Co2 C47 92.6(2) . .
C62 Ni2 Co2 C47 -137.1(3) . .
C61 Ni2 Co2 C47 -159.34(14) . .
C65 Ni2 Co2 C47 162.25(13) . .
C18 Co1 C11 C16 -26.6(3) 2_666 .
C18 Co1 C11 C16 153.4(3) . .
C12 Co1 C11 C16 71.8(4) 2_666 .
C12 Co1 C11 C16 -108.2(4) . .
Ni1 Co1 C11 C16 26.9(3) 2_666 .
Ni1 Co1 C11 C16 -153.1(3) . .
C11 Co1 C11 C16 -144(100) 2_666 .
C17 Co1 C11 C16 -56.3(4) 2_666 .
C17 Co1 C11 C16 123.7(4) . .
C18 Co1 C11 C12 81.6(2) 2_666 .
C18 Co1 C11 C12 -98.4(2) . .
C12 Co1 C11 C12 180.0 2_666 .
Ni1 Co1 C11 C12 135.13(16) 2_666 .
Ni1 Co1 C11 C12 -44.87(16) . .
C11 Co1 C11 C12 -36(100) 2_666 .
C17 Co1 C11 C12 51.9(3) 2_666 .
C17 Co1 C11 C12 -128.1(3) . .
C18 Co1 C11 C17 -150.26(18) 2_666 .
C18 Co1 C11 C17 29.74(18) . .
C12 Co1 C11 C17 -51.9(3) 2_666 .
C12 Co1 C11 C17 128.1(3) . .
Ni1 Co1 C11 C17 -96.75(17) 2_666 .
Ni1 Co1 C11 C17 83.25(17) . .
C11 Co1 C11 C17 92(100) 2_666 .
C17 Co1 C11 C17 180.000(2) 2_666 .
C16 C11 C12 C13 1.3(4) . .
C17 C11 C12 C13 -178.9(3) . .
Co1 C11 C12 C13 -124.1(3) . .
C16 C11 C12 Ni1 -170.9(2) . .
C17 C11 C12 Ni1 8.9(3) . .
Co1 C11 C12 Ni1 63.73(15) . .
C16 C11 C12 Co1 125.4(3) . .
C17 C11 C12 Co1 -54.8(2) . .
C18 Ni1 C12 C13 176.5(3) . .
C33 Ni1 C12 C13 -71.7(6) . .
C34 Ni1 C12 C13 40.5(4) . .
C35 Ni1 C12 C13 14.2(3) . .
C31 Ni1 C12 C13 -26.6(3) . .
C32 Ni1 C12 C13 -61.6(3) . .
Co1 Ni1 C12 C13 116.9(3) . .
C18 Ni1 C12 C11 -12.3(2) . .
C33 Ni1 C12 C11 99.5(5) . .
C34 Ni1 C12 C11 -148.3(2) . .
C35 Ni1 C12 C11 -174.6(2) . .
C31 Ni1 C12 C11 144.6(2) . .
C32 Ni1 C12 C11 109.6(2) . .
Co1 Ni1 C12 C11 -72.0(2) . .
C18 Ni1 C12 Co1 59.66(10) . .
C33 Ni1 C12 Co1 171.4(5) . .
C34 Ni1 C12 Co1 -76.3(3) . .
C35 Ni1 C12 Co1 -102.66(12) . .
C31 Ni1 C12 Co1 -143.46(11) . .
C32 Ni1 C12 Co1 -178.44(12) . .
C18 Co1 C12 C13 5.0(3) 2_666 .
C18 Co1 C12 C13 -175.0(3) . .
C12 Co1 C12 C13 44(100) 2_666 .
Ni1 Co1 C12 C13 57.1(3) 2_666 .
Ni1 Co1 C12 C13 -122.9(3) . .
C11 Co1 C12 C13 -61.6(3) 2_666 .
C11 Co1 C12 C13 118.4(3) . .
C17 Co1 C12 C13 -31.1(3) 2_666 .
C17 Co1 C12 C13 148.9(3) . .
C18 Co1 C12 C11 -113.42(18) 2_666 .
C18 Co1 C12 C11 66.58(18) . .
C12 Co1 C12 C11 -75(100) 2_666 .
Ni1 Co1 C12 C11 -61.3(2) 2_666 .
Ni1 Co1 C12 C11 118.7(2) . .
C11 Co1 C12 C11 180.0 2_666 .
C17 Co1 C12 C11 -149.52(17) 2_666 .
C17 Co1 C12 C11 30.48(17) . .
C18 Co1 C12 Ni1 127.87(11) 2_666 .
C18 Co1 C12 Ni1 -52.13(11) . .
C12 Co1 C12 Ni1 167(100) 2_666 .
Ni1 Co1 C12 Ni1 180.000(2) 2_666 .
C11 Co1 C12 Ni1 61.3(2) 2_666 .
C11 Co1 C12 Ni1 -118.7(2) . .
C17 Co1 C12 Ni1 91.77(12) 2_666 .
C17 Co1 C12 Ni1 -88.23(12) . .
C11 C12 C13 C14 -1.7(4) . .
Ni1 C12 C13 C14 169.2(2) . .
Co1 C12 C13 C14 -101.9(3) . .
C12 C13 C14 C15 1.0(5) . .
C13 C14 C15 C16 0.2(5) . .
C14 C15 C16 C11 -0.6(5) . .
C12 C11 C16 C15 -0.2(5) . .
C17 C11 C16 C15 -180.0(3) . .
Co1 C11 C16 C15 79.6(4) . .
C16 C11 C17 C22 0.4(5) . .
C12 C11 C17 C22 -179.4(3) . .
Co1 C11 C17 C22 131.4(3) . .
C16 C11 C17 C18 -178.5(3) . .
C12 C11 C17 C18 1.7(4) . .
Co1 C11 C17 C18 -47.5(2) . .
C16 C11 C17 Co1 -131.0(3) . .
C12 C11 C17 Co1 49.2(2) . .
C18 Co1 C17 C22 -72.7(4) 2_666 .
C18 Co1 C17 C22 107.3(4) . .
C12 Co1 C17 C22 26.2(3) 2_666 .
C12 Co1 C17 C22 -153.8(3) . .
Ni1 Co1 C17 C22 -27.5(3) 2_666 .
Ni1 Co1 C17 C22 152.5(3) . .
C11 Co1 C17 C22 56.8(4) 2_666 .
C11 Co1 C17 C22 -123.2(4) . .
C17 Co1 C17 C22 -142(100) 2_666 .
C18 Co1 C17 C18 180.000(3) 2_666 .
C12 Co1 C17 C18 -81.2(2) 2_666 .
C12 Co1 C17 C18 98.8(2) . .
Ni1 Co1 C17 C18 -134.82(17) 2_666 .
Ni1 Co1 C17 C18 45.18(17) . .
C11 Co1 C17 C18 -50.5(3) 2_666 .
C11 Co1 C17 C18 129.5(3) . .
C17 Co1 C17 C18 110(100) 2_666 .
C18 Co1 C17 C11 50.5(3) 2_666 .
C18 Co1 C17 C11 -129.5(3) . .
C12 Co1 C17 C11 149.35(17) 2_666 .
C12 Co1 C17 C11 -30.65(17) . .
Ni1 Co1 C17 C11 95.69(16) 2_666 .
Ni1 Co1 C17 C11 -84.31(16) . .
C11 Co1 C17 C11 180.000(1) 2_666 .
C17 Co1 C17 C11 -19(100) 2_666 .
C22 C17 C18 C19 -0.8(4) . .
C11 C17 C18 C19 178.1(3) . .
Co1 C17 C18 C19 125.1(3) . .
C22 C17 C18 Ni1 169.4(2) . .
C11 C17 C18 Ni1 -11.7(3) . .
Co1 C17 C18 Ni1 -64.72(16) . .
C22 C17 C18 Co1 -125.9(3) . .
C11 C17 C18 Co1 53.1(2) . .
C12 Ni1 C18 C17 13.3(2) . .
C33 Ni1 C18 C17 -152.6(2) . .
C34 Ni1 C18 C17 169.0(2) . .
C35 Ni1 C18 C17 152.4(3) . .
C31 Ni1 C18 C17 -99.1(4) . .
C32 Ni1 C18 C17 -115.1(2) . .
Co1 Ni1 C18 C17 73.4(2) . .
C12 Ni1 C18 C19 -177.6(3) . .
C33 Ni1 C18 C19 16.4(3) . .
C34 Ni1 C18 C19 -21.9(3) . .
C35 Ni1 C18 C19 -38.5(5) . .
C31 Ni1 C18 C19 69.9(4) . .
C32 Ni1 C18 C19 53.9(3) . .
Co1 Ni1 C18 C19 -117.5(3) . .
C12 Ni1 C18 Co1 -60.06(10) . .
C33 Ni1 C18 Co1 134.00(11) . .
C34 Ni1 C18 Co1 95.62(13) . .
C35 Ni1 C18 Co1 79.0(3) . .
C31 Ni1 C18 Co1 -172.5(3) . .
C32 Ni1 C18 Co1 171.45(11) . .
C18 Co1 C18 C17 -81(100) 2_666 .
C12 Co1 C18 C17 113.82(19) 2_666 .
C12 Co1 C18 C17 -66.18(19) . .
Ni1 Co1 C18 C17 61.7(2) 2_666 .
Ni1 Co1 C18 C17 -118.3(2) . .
C11 Co1 C18 C17 150.22(18) 2_666 .
C11 Co1 C18 C17 -29.78(18) . .
C17 Co1 C18 C17 180.000(3) 2_666 .
C18 Co1 C18 C19 160(100) 2_666 .
C12 Co1 C18 C19 -5.6(3) 2_666 .
C12 Co1 C18 C19 174.4(3) . .
Ni1 Co1 C18 C19 -57.7(3) 2_666 .
Ni1 Co1 C18 C19 122.3(3) . .
C11 Co1 C18 C19 30.8(3) 2_666 .
C11 Co1 C18 C19 -149.2(3) . .
C17 Co1 C18 C19 60.6(4) 2_666 .
C17 Co1 C18 C19 -119.4(4) . .
C18 Co1 C18 Ni1 37(100) 2_666 .
C12 Co1 C18 Ni1 -127.86(10) 2_666 .
C12 Co1 C18 Ni1 52.14(10) . .
Ni1 Co1 C18 Ni1 180.0 2_666 .
C11 Co1 C18 Ni1 -91.45(12) 2_666 .
C11 Co1 C18 Ni1 88.55(12) . .
C17 Co1 C18 Ni1 -61.7(2) 2_666 .
C17 Co1 C18 Ni1 118.3(2) . .
C17 C18 C19 C20 1.7(5) . .
Ni1 C18 C19 C20 -167.0(2) . .
Co1 C18 C19 C20 103.7(3) . .
C18 C19 C20 C21 -0.4(5) . .
C19 C20 C21 C22 -1.9(5) . .
C20 C21 C22 C17 2.8(5) . .
C18 C17 C22 C21 -1.5(5) . .
C11 C17 C22 C21 179.7(3) . .
Co1 C17 C22 C21 -80.3(4) . .
C18 Ni1 C31 C32 -23.1(4) . .
C12 Ni1 C31 C32 -131.4(2) . .
C33 Ni1 C31 C32 37.0(2) . .
C34 Ni1 C31 C32 80.7(2) . .
C35 Ni1 C31 C32 117.9(3) . .
Co1 Ni1 C31 C32 167.89(15) . .
C18 Ni1 C31 C35 -141.0(3) . .
C12 Ni1 C31 C35 110.7(2) . .
C33 Ni1 C31 C35 -80.9(2) . .
C34 Ni1 C31 C35 -37.2(2) . .
C32 Ni1 C31 C35 -117.9(3) . .
Co1 Ni1 C31 C35 50.0(2) . .
C18 Ni1 C31 C36 99.2(4) . .
C12 Ni1 C31 C36 -9.1(4) . .
C33 Ni1 C31 C36 159.4(4) . .
C34 Ni1 C31 C36 -157.0(4) . .
C35 Ni1 C31 C36 -119.8(4) . .
C32 Ni1 C31 C36 122.3(4) . .
Co1 Ni1 C31 C36 -69.8(4) . .
C35 C31 C32 C33 3.2(4) . .
C36 C31 C32 C33 176.9(3) . .
Ni1 C31 C32 C33 -57.2(2) . .
C35 C31 C32 Ni1 60.3(2) . .
C36 C31 C32 Ni1 -125.9(3) . .
C18 Ni1 C32 C31 169.38(19) . .
C12 Ni1 C32 C31 64.2(2) . .
C33 Ni1 C32 C31 -119.9(3) . .
C34 Ni1 C32 C31 -81.4(2) . .
C35 Ni1 C32 C31 -38.42(19) . .
Co1 Ni1 C32 C31 -105.3(7) . .
C18 Ni1 C32 C33 -70.7(2) . .
C12 Ni1 C32 C33 -175.9(2) . .
C34 Ni1 C32 C33 38.5(2) . .
C35 Ni1 C32 C33 81.5(2) . .
C31 Ni1 C32 C33 119.9(3) . .
Co1 Ni1 C32 C33 14.7(8) . .
C31 C32 C33 C34 -4.0(4) . .
Ni1 C32 C33 C34 -63.0(2) . .
C31 C32 C33 Ni1 59.0(2) . .
C18 Ni1 C33 C34 -120.2(2) . .
C12 Ni1 C33 C34 130.1(5) . .
C35 Ni1 C33 C34 37.5(2) . .
C31 Ni1 C33 C34 81.2(2) . .
C32 Ni1 C33 C34 117.2(3) . .
Co1 Ni1 C33 C34 -60.2(2) . .
C18 Ni1 C33 C32 122.7(2) . .
C12 Ni1 C33 C32 13.0(6) . .
C34 Ni1 C33 C32 -117.2(3) . .
C35 Ni1 C33 C32 -79.7(2) . .
C31 Ni1 C33 C32 -36.0(2) . .
Co1 Ni1 C33 C32 -177.40(15) . .
C32 C33 C34 C35 3.2(4) . .
Ni1 C33 C34 C35 -61.1(2) . .
C32 C33 C34 Ni1 64.2(2) . .
C18 Ni1 C34 C35 -168.9(2) . .
C12 Ni1 C34 C35 -40.1(3) . .
C33 Ni1 C34 C35 118.0(3) . .
C31 Ni1 C34 C35 37.9(2) . .
C32 Ni1 C34 C35 79.8(2) . .
Co1 Ni1 C34 C35 -103.32(19) . .
C18 Ni1 C34 C33 73.1(2) . .
C12 Ni1 C34 C33 -158.1(2) . .
C35 Ni1 C34 C33 -118.0(3) . .
C31 Ni1 C34 C33 -80.1(2) . .
C32 Ni1 C34 C33 -38.2(2) . .
Co1 Ni1 C34 C33 138.67(18) . .
C33 C34 C35 C31 -1.2(4) . .
Ni1 C34 C35 C31 -61.0(2) . .
C33 C34 C35 Ni1 59.8(2) . .
C32 C31 C35 C34 -1.2(4) . .
C36 C31 C35 C34 -175.1(3) . .
Ni1 C31 C35 C34 60.4(2) . .
C32 C31 C35 Ni1 -61.6(2) . .
C36 C31 C35 Ni1 124.6(3) . .
C18 Ni1 C35 C34 23.8(4) . .
C12 Ni1 C35 C34 158.2(2) . .
C33 Ni1 C35 C34 -38.1(2) . .
C31 Ni1 C35 C34 -118.5(3) . .
C32 Ni1 C35 C34 -81.5(2) . .
Co1 Ni1 C35 C34 91.1(2) . .
C18 Ni1 C35 C31 142.2(3) . .
C12 Ni1 C35 C31 -83.3(2) . .
C33 Ni1 C35 C31 80.3(2) . .
C34 Ni1 C35 C31 118.5(3) . .
C32 Ni1 C35 C31 36.99(19) . .
Co1 Ni1 C35 C31 -150.41(17) . .
C48 Co2 C41 C46 -153.3(3) . .
C48 Co2 C41 C46 26.7(3) 2_665 .
C42 Co2 C41 C46 -71.4(4) 2_665 .
C42 Co2 C41 C46 108.6(4) . .
Ni2 Co2 C41 C46 -26.5(3) 2_665 .
Ni2 Co2 C41 C46 153.5(3) . .
C41 Co2 C41 C46 109(100) 2_665 .
C47 Co2 C41 C46 57.0(4) 2_665 .
C47 Co2 C41 C46 -123.0(4) . .
C48 Co2 C41 C42 98.1(2) . .
C48 Co2 C41 C42 -81.9(2) 2_665 .
C42 Co2 C41 C42 180.0 2_665 .
Ni2 Co2 C41 C42 -135.13(16) 2_665 .
Ni2 Co2 C41 C42 44.87(16) . .
C41 Co2 C41 C42 0(100) 2_665 .
C47 Co2 C41 C42 -51.6(3) 2_665 .
C47 Co2 C41 C42 128.4(3) . .
C48 Co2 C41 C47 -30.28(18) . .
C48 Co2 C41 C47 149.72(18) 2_665 .
C42 Co2 C41 C47 51.6(3) 2_665 .
C42 Co2 C41 C47 -128.4(3) . .
Ni2 Co2 C41 C47 96.51(17) 2_665 .
Ni2 Co2 C41 C47 -83.49(17) . .
C41 Co2 C41 C47 -128(100) 2_665 .
C47 Co2 C41 C47 180.0 2_665 .
C46 C41 C42 C43 -1.5(5) . .
C47 C41 C42 C43 177.1(3) . .
Co2 C41 C42 C43 122.7(3) . .
C46 C41 C42 Ni2 171.9(2) . .
C47 C41 C42 Ni2 -9.5(3) . .
Co2 C41 C42 Ni2 -63.86(16) . .
C46 C41 C42 Co2 -124.2(3) . .
C47 C41 C42 Co2 54.3(2) . .
C48 Ni2 C42 C43 -175.3(3) . .
C64 Ni2 C42 C43 -29.5(10) . .
C63 Ni2 C42 C43 76.9(4) . .
C62 Ni2 C42 C43 47.0(3) . .
C61 Ni2 C42 C43 5.7(3) . .
C65 Ni2 C42 C43 -28.9(4) . .
Co2 Ni2 C42 C43 -116.3(3) . .
C48 Ni2 C42 C41 12.2(2) . .
C64 Ni2 C42 C41 158.0(7) . .
C63 Ni2 C42 C41 -95.6(3) . .
C62 Ni2 C42 C41 -125.5(2) . .
C61 Ni2 C42 C41 -166.8(2) . .
C65 Ni2 C42 C41 158.6(2) . .
Co2 Ni2 C42 C41 71.2(2) . .
C48 Ni2 C42 Co2 -59.05(10) . .
C64 Ni2 C42 Co2 86.8(8) . .
C63 Ni2 C42 Co2 -166.85(17) . .
C62 Ni2 C42 Co2 163.26(10) . .
C61 Ni2 C42 Co2 121.97(11) . .
C65 Ni2 C42 Co2 87.41(16) . .
C48 Co2 C42 C43 175.4(3) . .
C48 Co2 C42 C43 -4.6(3) 2_665 .
C42 Co2 C42 C43 88(95) 2_665 .
Ni2 Co2 C42 C43 -56.3(3) 2_665 .
Ni2 Co2 C42 C43 123.7(3) . .
C41 Co2 C42 C43 -117.5(3) . .
C41 Co2 C42 C43 62.5(3) 2_665 .
C47 Co2 C42 C43 31.9(3) 2_665 .
C47 Co2 C42 C43 -148.1(3) . .
C48 Co2 C42 C41 -67.15(18) . .
C48 Co2 C42 C41 112.85(18) 2_665 .
C42 Co2 C42 C41 -154(95) 2_665 .
Ni2 Co2 C42 C41 61.2(2) 2_665 .
Ni2 Co2 C42 C41 -118.8(2) . .
C41 Co2 C42 C41 180.0 2_665 .
C47 Co2 C42 C41 149.42(17) 2_665 .
C47 Co2 C42 C41 -30.58(17) . .
C48 Co2 C42 Ni2 51.61(11) . .
C48 Co2 C42 Ni2 -128.39(11) 2_665 .
C42 Co2 C42 Ni2 -35(95) 2_665 .
Ni2 Co2 C42 Ni2 180.0 2_665 .
C41 Co2 C42 Ni2 118.8(2) . .
C41 Co2 C42 Ni2 -61.2(2) 2_665 .
C47 Co2 C42 Ni2 -91.82(12) 2_665 .
C47 Co2 C42 Ni2 88.18(12) . .
C41 C42 C43 C44 2.1(5) . .
Ni2 C42 C43 C44 -170.2(3) . .
Co2 C42 C43 C44 100.4(3) . .
C42 C43 C44 C45 -1.6(5) . .
C43 C44 C45 C46 0.4(5) . .
C44 C45 C46 C41 0.1(5) . .
C42 C41 C46 C45 0.4(5) . .
C47 C41 C46 C45 -177.9(3) . .
Co2 C41 C46 C45 -79.4(4) . .
C46 C41 C47 C52 -0.3(5) . .
C42 C41 C47 C52 -178.8(3) . .
Co2 C41 C47 C52 -129.4(3) . .
C46 C41 C47 C48 178.1(3) . .
C42 C41 C47 C48 -0.4(4) . .
Co2 C41 C47 C48 48.9(2) . .
C46 C41 C47 Co2 129.2(3) . .
C42 C41 C47 Co2 -49.3(2) . .
C48 Co2 C47 C52 -109.2(4) . .
C48 Co2 C47 C52 70.8(4) 2_665 .
C42 Co2 C47 C52 -27.4(3) 2_665 .
C42 Co2 C47 C52 152.6(3) . .
Ni2 Co2 C47 C52 26.3(3) 2_665 .
Ni2 Co2 C47 C52 -153.7(3) . .
C41 Co2 C47 C52 122.0(4) . .
C41 Co2 C47 C52 -58.0(4) 2_665 .
C47 Co2 C47 C52 151(100) 2_665 .
C48 Co2 C47 C48 180.000(1) 2_665 .
C42 Co2 C47 C48 81.9(2) 2_665 .
C42 Co2 C47 C48 -98.1(2) . .
Ni2 Co2 C47 C48 135.52(17) 2_665 .
Ni2 Co2 C47 C48 -44.48(17) . .
C41 Co2 C47 C48 -128.8(3) . .
C41 Co2 C47 C48 51.2(3) 2_665 .
C47 Co2 C47 C48 -100(100) 2_665 .
C48 Co2 C47 C41 128.8(3) . .
C48 Co2 C47 C41 -51.2(3) 2_665 .
C42 Co2 C47 C41 -149.38(17) 2_665 .
C42 Co2 C47 C41 30.62(17) . .
Ni2 Co2 C47 C41 -95.72(17) 2_665 .
Ni2 Co2 C47 C41 84.28(17) . .
C41 Co2 C47 C41 180.0 2_665 .
C47 Co2 C47 C41 29(100) 2_665 .
C52 C47 C48 C49 1.2(5) . .
C41 C47 C48 C49 -177.2(3) . .
Co2 C47 C48 C49 -123.3(3) . .
C52 C47 C48 Ni2 -171.3(2) . .
C41 C47 C48 Ni2 10.3(3) . .
Co2 C47 C48 Ni2 64.18(15) . .
C52 C47 C48 Co2 124.5(3) . .
C41 C47 C48 Co2 -53.9(2) . .
C42 Ni2 C48 C47 -12.5(2) . .
C64 Ni2 C48 C47 173.0(2) . .
C63 Ni2 C48 C47 131.6(2) . .
C62 Ni2 C48 C47 104.0(3) . .
C61 Ni2 C48 C47 162.5(6) . .
C65 Ni2 C48 C47 -157.9(2) . .
Co2 Ni2 C48 C47 -71.5(2) . .
C42 Ni2 C48 C49 176.0(3) . .
C64 Ni2 C48 C49 1.4(3) . .
C63 Ni2 C48 C49 -40.0(3) . .
C62 Ni2 C48 C49 -67.6(4) . .
C61 Ni2 C48 C49 -9.0(8) . .
C65 Ni2 C48 C49 30.5(4) . .
Co2 Ni2 C48 C49 117.0(3) . .
C42 Ni2 C48 Co2 59.03(11) . .
C64 Ni2 C48 Co2 -115.52(11) . .
C63 Ni2 C48 Co2 -156.94(10) . .
C62 Ni2 C48 Co2 175.46(14) . .
C61 Ni2 C48 Co2 -126.0(6) . .
C65 Ni2 C48 Co2 -86.44(16) . .
C48 Co2 C48 C47 124(100) 2_665 .
C42 Co2 C48 C47 -112.8(2) 2_665 .
C42 Co2 C48 C47 67.2(2) . .
Ni2 Co2 C48 C47 -60.9(2) 2_665 .
Ni2 Co2 C48 C47 119.1(2) . .
C41 Co2 C48 C47 30.41(18) . .
C41 Co2 C48 C47 -149.59(18) 2_665 .
C47 Co2 C48 C47 180.000(1) 2_665 .
C48 Co2 C48 C49 -119(100) 2_665 .
C42 Co2 C48 C49 4.7(3) 2_665 .
C42 Co2 C48 C49 -175.3(3) . .
Ni2 Co2 C48 C49 56.7(3) 2_665 .
Ni2 Co2 C48 C49 -123.3(3) . .
C41 Co2 C48 C49 148.0(3) . .
C41 Co2 C48 C49 -32.0(3) 2_665 .
C47 Co2 C48 C49 -62.4(4) 2_665 .
C47 Co2 C48 C49 117.6(4) . .
C48 Co2 C48 Ni2 5(100) 2_665 .
C42 Co2 C48 Ni2 128.05(11) 2_665 .
C42 Co2 C48 Ni2 -51.95(11) . .
Ni2 Co2 C48 Ni2 180.0 2_665 .
C41 Co2 C48 Ni2 -88.73(12) . .
C41 Co2 C48 Ni2 91.27(12) 2_665 .
C47 Co2 C48 Ni2 60.9(2) 2_665 .
C47 Co2 C48 Ni2 -119.1(2) . .
C47 C48 C49 C50 -1.1(5) . .
Ni2 C48 C49 C50 170.2(2) . .
Co2 C48 C49 C50 -100.0(3) . .
C48 C49 C50 C51 0.1(5) . .
C49 C50 C51 C52 0.9(5) . .
C50 C51 C52 C47 -0.7(5) . .
C48 C47 C52 C51 -0.3(5) . .
C41 C47 C52 C51 177.9(3) . .
Co2 C47 C52 C51 79.9(4) . .
C48 Ni2 C61 C65 48.0(7) . .
C42 Ni2 C61 C65 -137.2(2) . .
C64 Ni2 C61 C65 36.8(2) . .
C63 Ni2 C61 C65 81.1(2) . .
C62 Ni2 C61 C65 118.0(3) . .
Co2 Ni2 C61 C65 -71.9(2) . .
C48 Ni2 C61 C62 -70.0(7) . .
C42 Ni2 C61 C62 104.8(2) . .
C64 Ni2 C61 C62 -81.2(2) . .
C63 Ni2 C61 C62 -36.90(19) . .
C65 Ni2 C61 C62 -118.0(3) . .
Co2 Ni2 C61 C62 170.07(16) . .
C48 Ni2 C61 C66 169.4(6) . .
C42 Ni2 C61 C66 -15.8(3) . .
C64 Ni2 C61 C66 158.3(4) . .
C63 Ni2 C61 C66 -157.4(4) . .
C62 Ni2 C61 C66 -120.5(4) . .
C65 Ni2 C61 C66 121.4(4) . .
Co2 Ni2 C61 C66 49.5(3) . .
C65 C61 C62 C63 -1.4(4) . .
C66 C61 C62 C63 -173.7(3) . .
Ni2 C61 C62 C63 60.2(2) . .
C65 C61 C62 Ni2 -61.6(2) . .
C66 C61 C62 Ni2 126.1(3) . .
C48 Ni2 C62 C63 45.9(3) . .
C42 Ni2 C62 C63 151.5(2) . .
C64 Ni2 C62 C63 -38.5(2) . .
C61 Ni2 C62 C63 -118.8(3) . .
C65 Ni2 C62 C63 -81.5(2) . .
Co2 Ni2 C62 C63 -147.9(3) . .
C48 Ni2 C62 C61 164.7(2) . .
C42 Ni2 C62 C61 -89.6(2) . .
C64 Ni2 C62 C61 80.3(2) . .
C63 Ni2 C62 C61 118.8(3) . .
C65 Ni2 C62 C61 37.36(19) . .
Co2 Ni2 C62 C61 -29.1(4) . .
C61 C62 C63 C64 -0.6(4) . .
Ni2 C62 C63 C64 60.1(2) . .
C61 C62 C63 Ni2 -60.7(2) . .
C48 Ni2 C63 C62 -148.8(2) . .
C42 Ni2 C63 C62 -47.8(3) . .
C64 Ni2 C63 C62 118.1(3) . .
C61 Ni2 C63 C62 37.50(19) . .
C65 Ni2 C63 C62 80.1(2) . .
Co2 Ni2 C63 C62 159.38(17) . .
C48 Ni2 C63 C64 93.1(2) . .
C42 Ni2 C63 C64 -165.8(2) . .
C62 Ni2 C63 C64 -118.1(3) . .
C61 Ni2 C63 C64 -80.6(2) . .
C65 Ni2 C63 C64 -37.99(19) . .
Co2 Ni2 C63 C64 41.3(3) . .
C62 C63 C64 C65 2.5(4) . .
Ni2 C63 C64 C65 63.9(2) . .
C62 C63 C64 Ni2 -61.4(2) . .
C48 Ni2 C64 C65 145.7(2) . .
C42 Ni2 C64 C65 0.7(9) . .
C63 Ni2 C64 C65 -116.8(3) . .
C62 Ni2 C64 C65 -79.7(2) . .
C61 Ni2 C64 C65 -36.6(2) . .
Co2 Ni2 C64 C65 82.3(2) . .
C48 Ni2 C64 C63 -97.6(2) . .
C42 Ni2 C64 C63 117.5(8) . .
C62 Ni2 C64 C63 37.04(19) . .
C61 Ni2 C64 C63 80.2(2) . .
C65 Ni2 C64 C63 116.8(3) . .
Co2 Ni2 C64 C63 -160.97(16) . .
C63 C64 C65 C61 -3.3(4) . .
Ni2 C64 C65 C61 59.0(2) . .
C63 C64 C65 Ni2 -62.3(2) . .
C62 C61 C65 C64 2.9(4) . .
C66 C61 C65 C64 175.2(3) . .
Ni2 C61 C65 C64 -57.8(2) . .
C62 C61 C65 Ni2 60.7(2) . .
C66 C61 C65 Ni2 -127.0(3) . .
C48 Ni2 C65 C64 -48.9(3) . .
C42 Ni2 C65 C64 -179.8(2) . .
C63 Ni2 C65 C64 39.2(2) . .
C62 Ni2 C65 C64 81.7(2) . .
C61 Ni2 C65 C64 119.7(3) . .
Co2 Ni2 C65 C64 -114.30(19) . .
C48 Ni2 C65 C61 -168.52(19) . .
C42 Ni2 C65 C61 60.5(3) . .
C64 Ni2 C65 C61 -119.7(3) . .
C63 Ni2 C65 C61 -80.5(2) . .
C62 Ni2 C65 C61 -37.9(2) . .
Co2 Ni2 C65 C61 126.04(18) . .
