#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/17/4071788.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4071788
loop_
_publ_author_name
'Adams, Richard D.'
'Trufan, Eszter'
_publ_section_title
;
 Diruthenium−Tin Complexes from the Reaction of Ph2SnH2with
 Ru(CO)5and Their Reactions with Bis(tri-tert-butylphosphine)platinum
;
_journal_issue                   16
_journal_name_full               Organometallics
_journal_page_first              4108
_journal_paper_doi               10.1021/om800385w
_journal_volume                  27
_journal_year                    2008
_chemical_formula_sum            'C31.25 H39.5 Cl0.5 O7 P Pt Ru2 Sn'
_chemical_formula_weight         1091.74
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 99.409(1)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.9915(5)
_cell_length_b                   11.7343(3)
_cell_length_c                   19.2385(6)
_cell_measurement_reflns_used    5903
_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      24.83
_cell_measurement_theta_min      2.28
_cell_volume                     3784.23(19)
_computing_cell_refinement       'SAINT+  V6.45 (Bruker, 2003)'
_computing_data_collection       'SMART V5.632 (Bruker, 2005)'
_computing_data_reduction        'SAINT+  V6.45'
_computing_molecular_graphics    'SHELXTL V6.1 (Sheldrick, 2000)'
_computing_publication_material  'SHELXTL V6.1'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker SMART APEX CCD diffractometer'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0489
_diffrn_reflns_av_sigmaI/netI    0.0412
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            33236
_diffrn_reflns_theta_full        26.02
_diffrn_reflns_theta_max         26.02
_diffrn_reflns_theta_min         1.21
_diffrn_standards_decay_%        <1
_exptl_absorpt_coefficient_mu    5.238
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.744
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS, Bruker, 1997)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.916
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2090
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.362
_refine_diff_density_min         -0.636
_refine_diff_density_rms         0.240
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.079
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     418
_refine_ls_number_reflns         7462
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.079
_refine_ls_R_factor_all          0.0534
_refine_ls_R_factor_gt           0.0376
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0485P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0877
_refine_ls_wR_factor_ref         0.1014
_reflns_number_gt                6013
_reflns_number_total             7462
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om800385w-file003.cif
_cod_data_source_block           etruh2ss
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_original_formula_sum        'C31.25 H39.50 Cl0.50 O7 P Pt Ru2 Sn'
_cod_database_code               4071788
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt 0.277284(16) 0.70932(2) 0.413178(14) 0.04229(9) Uani 1 1 d .
Sn1 Sn 0.26077(3) 0.51947(4) 0.28590(3) 0.04770(14) Uani 1 1 d .
Ru1 Ru 0.39005(4) 0.64830(5) 0.31846(3) 0.04822(16) Uani 1 1 d .
Ru2 Ru 0.33058(4) 0.48769(5) 0.41797(3) 0.04909(16) Uani 1 1 d .
P1 P 0.23996(11) 0.90386(14) 0.42010(9) 0.0414(4) Uani 1 1 d .
O10 O 0.2127(5) 0.6073(5) 0.5337(4) 0.094(2) Uani 1 1 d .
O11 O 0.5279(5) 0.7856(7) 0.4011(5) 0.126(3) Uani 1 1 d .
O12 O 0.3586(5) 0.7857(6) 0.1829(4) 0.105(3) Uani 1 1 d .
O13 O 0.4914(5) 0.4806(6) 0.2529(5) 0.111(3) Uani 1 1 d .
O21 O 0.4162(5) 0.5120(7) 0.5702(4) 0.111(3) Uani 1 1 d .
O22 O 0.1831(4) 0.3552(6) 0.4366(4) 0.096(2) Uani 1 1 d .
O23 O 0.4257(5) 0.2798(5) 0.3894(4) 0.102(2) Uani 1 1 d .
C10 C 0.2369(5) 0.6399(6) 0.4855(4) 0.062(2) Uani 1 1 d .
C11 C 0.4775(5) 0.7349(8) 0.3717(6) 0.077(3) Uani 1 1 d .
C12 C 0.3689(6) 0.7327(8) 0.2341(5) 0.070(2) Uani 1 1 d .
C13 C 0.4528(5) 0.5435(7) 0.2781(5) 0.070(2) Uani 1 1 d .
C21 C 0.3855(6) 0.5066(7) 0.5137(5) 0.070(2) Uani 1 1 d .
C22 C 0.2377(6) 0.4070(7) 0.4286(5) 0.065(2) Uani 1 1 d .
C23 C 0.3877(5) 0.3551(7) 0.3996(5) 0.069(2) Uani 1 1 d .
C31 C 0.2508(5) 0.3760(6) 0.2139(4) 0.056(2) Uani 1 1 d .
C32 C 0.3148(6) 0.3044(7) 0.2097(4) 0.066(2) Uani 1 1 d .
H32 H 0.3647 0.3197 0.2357 0.079 Uiso 1 1 calc R
C33 C 0.3029(8) 0.2072(7) 0.1650(5) 0.084(3) Uani 1 1 d .
H33 H 0.3456 0.1587 0.1622 0.101 Uiso 1 1 calc R
C34 C 0.2306(8) 0.1841(8) 0.1264(5) 0.087(3) Uani 1 1 d .
H34 H 0.2232 0.1202 0.0975 0.105 Uiso 1 1 calc R
C35 C 0.1696(7) 0.2556(9) 0.1309(5) 0.090(3) Uani 1 1 d .
H35 H 0.1201 0.2402 0.1040 0.108 Uiso 1 1 calc R
C36 C 0.1776(6) 0.3508(7) 0.1737(4) 0.065(2) Uani 1 1 d .
H36 H 0.1339 0.3978 0.1756 0.078 Uiso 1 1 calc R
C37 C 0.1453(5) 0.5988(7) 0.2570(5) 0.060(2) Uani 1 1 d .
C38 C 0.0841(6) 0.5806(9) 0.2954(6) 0.094(3) Uani 1 1 d .
H38 H 0.0920 0.5325 0.3343 0.113 Uiso 1 1 calc R
C39 C 0.0100(7) 0.6353(13) 0.2753(9) 0.126(5) Uani 1 1 d .
H39 H -0.0312 0.6229 0.3008 0.151 Uiso 1 1 calc R
C40 C -0.0008(9) 0.7055(13) 0.2192(10) 0.135(7) Uani 1 1 d .
H40 H -0.0494 0.7428 0.2068 0.162 Uiso 1 1 calc R
C41 C 0.0587(10) 0.7225(11) 0.1802(8) 0.130(5) Uani 1 1 d .
H41 H 0.0503 0.7702 0.1411 0.156 Uiso 1 1 calc R
C42 C 0.1309(7) 0.6688(9) 0.1993(6) 0.094(3) Uani 1 1 d .
H42 H 0.1709 0.6802 0.1724 0.113 Uiso 1 1 calc R
C43 C 0.2576(5) 0.9923(6) 0.3407(4) 0.057(2) Uani 1 1 d .
C44 C 0.2226(6) 0.9289(8) 0.2726(4) 0.077(3) Uani 1 1 d .
H44A H 0.2407 0.9645 0.2332 0.115 Uiso 1 1 calc R
H44B H 0.1654 0.9319 0.2662 0.115 Uiso 1 1 calc R
H44C H 0.2397 0.8509 0.2759 0.115 Uiso 1 1 calc R
C45 C 0.3464(6) 1.0039(7) 0.3413(6) 0.083(3) Uani 1 1 d .
H45A H 0.3700 0.9295 0.3416 0.124 Uiso 1 1 calc R
H45B H 0.3701 1.0449 0.3827 0.124 Uiso 1 1 calc R
H45C H 0.3555 1.0446 0.3001 0.124 Uiso 1 1 calc R
C46 C 0.2206(6) 1.1130(6) 0.3370(5) 0.072(2) Uani 1 1 d .
H46A H 0.2441 1.1561 0.3775 0.108 Uiso 1 1 calc R
H46B H 0.1641 1.1071 0.3361 0.108 Uiso 1 1 calc R
H46C H 0.2306 1.1506 0.2950 0.108 Uiso 1 1 calc R
C47 C 0.3062(5) 0.9629(7) 0.5017(4) 0.061(2) Uani 1 1 d .
C48 C 0.3904(5) 0.9155(9) 0.5052(5) 0.089(3) Uani 1 1 d .
H48A H 0.4127 0.9424 0.4654 0.133 Uiso 1 1 calc R
H48B H 0.3885 0.8338 0.5045 0.133 Uiso 1 1 calc R
H48C H 0.4232 0.9407 0.5479 0.133 Uiso 1 1 calc R
C49 C 0.2749(7) 0.9163(8) 0.5670(4) 0.088(3) Uani 1 1 d .
H49A H 0.2736 0.8345 0.5651 0.132 Uiso 1 1 calc R
H49B H 0.2221 0.9448 0.5675 0.132 Uiso 1 1 calc R
H49C H 0.3095 0.9404 0.6089 0.132 Uiso 1 1 calc R
C50 C 0.3098(6) 1.0934(7) 0.5071(5) 0.081(3) Uani 1 1 d .
H50A H 0.3425 1.1150 0.5505 0.121 Uiso 1 1 calc R
H50B H 0.2569 1.1230 0.5058 0.121 Uiso 1 1 calc R
H50C H 0.3322 1.1237 0.4682 0.121 Uiso 1 1 calc R
C51 C 0.1310(5) 0.9234(6) 0.4312(4) 0.058(2) Uani 1 1 d .
C52 C 0.1105(5) 1.0381(7) 0.4617(5) 0.079(3) Uani 1 1 d .
H52A H 0.0536 1.0472 0.4551 0.118 Uiso 1 1 calc R
H52B H 0.1334 1.0987 0.4381 0.118 Uiso 1 1 calc R
H52C H 0.1316 1.0405 0.5111 0.118 Uiso 1 1 calc R
C53 C 0.1054(6) 0.8304(8) 0.4780(6) 0.084(3) Uani 1 1 d .
H53A H 0.1397 0.8314 0.5229 0.126 Uiso 1 1 calc R
H53B H 0.1091 0.7575 0.4560 0.126 Uiso 1 1 calc R
H53C H 0.0514 0.8435 0.4845 0.126 Uiso 1 1 calc R
C54 C 0.0774(5) 0.9075(8) 0.3594(5) 0.089(3) Uani 1 1 d .
H54A H 0.0924 0.8391 0.3376 0.133 Uiso 1 1 calc R
H54B H 0.0836 0.9716 0.3298 0.133 Uiso 1 1 calc R
H54C H 0.0228 0.9020 0.3660 0.133 Uiso 1 1 calc R
C1S C 1.0210(17) 0.416(2) 0.4810(14) 0.046(6) Uiso 0.25 1 d P
H1S1 H 1.0724 0.4035 0.4664 0.055 Uiso 0.25 1 calc PR
H1S2 H 0.9944 0.3433 0.4842 0.055 Uiso 0.25 1 calc PR
Cl1S Cl 0.9702(7) 0.4988(10) 0.4339(7) 0.220(6) Uani 0.50 1 d P
H1 H 0.315(3) 0.758(4) 0.363(3) 0.025(14) Uiso 1 1 d .
H2 H 0.406(4) 0.563(6) 0.408(4) 0.07(2) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C10 Pt1 P1 104.3(2) . .
C10 Pt1 Ru2 73.6(2) . .
P1 Pt1 Ru2 174.18(5) . .
C10 Pt1 Ru1 136.3(2) . .
P1 Pt1 Ru1 118.36(5) . .
Ru2 Pt1 Ru1 63.009(18) . .
C10 Pt1 H1 174(2) . .
P1 Pt1 H1 78(2) . .
Ru2 Pt1 H1 103(2) . .
Ru1 Pt1 H1 40(2) . .
C37 Sn1 C31 101.3(3) . .
C37 Sn1 Ru2 123.6(2) . .
C31 Sn1 Ru2 118.6(2) . .
C37 Sn1 Ru1 119.8(2) . .
C31 Sn1 Ru1 124.6(2) . .
Ru2 Sn1 Ru1 68.31(2) . .
C13 Ru1 C12 91.7(4) . .
C13 Ru1 C11 97.1(4) . .
C12 Ru1 C11 101.6(4) . .
C13 Ru1 H1 176.6(15) . .
C12 Ru1 H1 89.0(15) . .
C11 Ru1 H1 86.0(15) . .
C13 Ru1 Sn1 91.9(3) . .
C12 Ru1 Sn1 93.5(3) . .
C11 Ru1 Sn1 162.1(3) . .
H1 Ru1 Sn1 84.7(15) . .
C13 Ru1 Pt1 152.6(3) . .
C12 Ru1 Pt1 110.7(3) . .
C11 Ru1 Pt1 93.8(3) . .
H1 Ru1 Pt1 25.1(14) . .
Sn1 Ru1 Pt1 71.769(18) . .
C13 Ru1 Ru2 97.3(3) . .
C12 Ru1 Ru2 148.1(3) . .
C11 Ru1 Ru2 107.6(3) . .
H1 Ru1 Ru2 80.4(14) . .
Sn1 Ru1 Ru2 55.73(2) . .
Pt1 Ru1 Ru2 55.377(16) . .
C13 Ru1 H1 176.6(15) . .
C12 Ru1 H1 89.0(15) . .
C11 Ru1 H1 86.0(15) . .
H1 Ru1 H1 0(3) . .
Sn1 Ru1 H1 84.7(15) . .
Pt1 Ru1 H1 25.1(14) . .
Ru2 Ru1 H1 80.4(14) . .
C13 Ru1 H2 91(2) . .
C12 Ru1 H2 177(2) . .
C11 Ru1 H2 80(2) . .
H1 Ru1 H2 88(2) . .
Sn1 Ru1 H2 85(2) . .
Pt1 Ru1 H2 66(2) . .
Ru2 Ru1 H2 30(2) . .
H1 Ru1 H2 88(2) . .
C22 Ru2 C23 94.1(4) . .
C22 Ru2 C21 103.7(4) . .
C23 Ru2 C21 95.1(4) . .
C22 Ru2 Sn1 85.6(3) . .
C23 Ru2 Sn1 95.7(3) . .
C21 Ru2 Sn1 165.2(3) . .
C22 Ru2 Pt1 101.7(2) . .
C23 Ru2 Pt1 160.9(3) . .
C21 Ru2 Pt1 91.6(2) . .
Sn1 Ru2 Pt1 75.012(19) . .
C22 Ru2 Ru1 140.1(3) . .
C23 Ru2 Ru1 99.3(3) . .
C21 Ru2 Ru1 112.2(3) . .
Sn1 Ru2 Ru1 55.95(2) . .
Pt1 Ru2 Ru1 61.614(17) . .
C22 Ru2 H2 177(3) . .
C23 Ru2 H2 89(3) . .
C21 Ru2 H2 77(3) . .
Sn1 Ru2 H2 93(3) . .
Pt1 Ru2 H2 75(3) . .
Ru1 Ru2 H2 38(3) . .
C47 P1 C43 108.2(4) . .
C47 P1 C51 108.5(4) . .
C43 P1 C51 107.8(4) . .
C47 P1 Pt1 105.5(3) . .
C43 P1 Pt1 113.5(2) . .
C51 P1 Pt1 113.1(2) . .
O10 C10 Pt1 173.1(7) . .
O11 C11 Ru1 178.7(11) . .
O12 C12 Ru1 177.6(9) . .
O13 C13 Ru1 179.1(9) . .
O21 C21 Ru2 176.4(9) . .
O22 C22 Ru2 177.4(9) . .
O23 C23 Ru2 176.0(8) . .
C36 C31 C32 118.7(7) . .
C36 C31 Sn1 119.4(6) . .
C32 C31 Sn1 121.8(6) . .
C31 C32 C33 119.1(9) . .
C31 C32 H32 120.5 . .
C33 C32 H32 120.5 . .
C34 C33 C32 121.2(10) . .
C34 C33 H33 119.4 . .
C32 C33 H33 119.4 . .
C35 C34 C33 118.6(9) . .
C35 C34 H34 120.7 . .
C33 C34 H34 120.7 . .
C34 C35 C36 122.7(10) . .
C34 C35 H35 118.7 . .
C36 C35 H35 118.7 . .
C35 C36 C31 119.8(9) . .
C35 C36 H36 120.1 . .
C31 C36 H36 120.1 . .
C42 C37 C38 118.2(9) . .
C42 C37 Sn1 120.1(7) . .
C38 C37 Sn1 121.7(8) . .
C37 C38 C39 119.9(13) . .
C37 C38 H38 120.1 . .
C39 C38 H38 120.1 . .
C40 C39 C38 119.8(15) . .
C40 C39 H39 120.1 . .
C38 C39 H39 120.1 . .
C39 C40 C41 120.8(15) . .
C39 C40 H40 119.6 . .
C41 C40 H40 119.6 . .
C40 C41 C42 119.6(15) . .
C40 C41 H41 120.2 . .
C42 C41 H41 120.2 . .
C37 C42 C41 121.7(13) . .
C37 C42 H42 119.2 . .
C41 C42 H42 119.2 . .
C45 C43 C44 107.2(7) . .
C45 C43 C46 108.4(7) . .
C44 C43 C46 107.7(7) . .
C45 C43 P1 109.2(6) . .
C44 C43 P1 109.2(5) . .
C46 C43 P1 114.8(6) . .
C43 C44 H44A 109.5 . .
C43 C44 H44B 109.5 . .
H44A C44 H44B 109.5 . .
C43 C44 H44C 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
C43 C45 H45A 109.5 . .
C43 C45 H45B 109.5 . .
H45A C45 H45B 109.5 . .
C43 C45 H45C 109.5 . .
H45A C45 H45C 109.5 . .
H45B C45 H45C 109.5 . .
C43 C46 H46A 109.5 . .
C43 C46 H46B 109.5 . .
H46A C46 H46B 109.5 . .
C43 C46 H46C 109.5 . .
H46A C46 H46C 109.5 . .
H46B C46 H46C 109.5 . .
C48 C47 C50 109.5(7) . .
C48 C47 C49 106.3(8) . .
C50 C47 C49 108.3(7) . .
C48 C47 P1 109.1(5) . .
C50 C47 P1 115.4(6) . .
C49 C47 P1 107.8(6) . .
C47 C48 H48A 109.5 . .
C47 C48 H48B 109.5 . .
H48A C48 H48B 109.5 . .
C47 C48 H48C 109.5 . .
H48A C48 H48C 109.5 . .
H48B C48 H48C 109.5 . .
C47 C49 H49A 109.5 . .
C47 C49 H49B 109.5 . .
H49A C49 H49B 109.5 . .
C47 C49 H49C 109.5 . .
H49A C49 H49C 109.5 . .
H49B C49 H49C 109.5 . .
C47 C50 H50A 109.5 . .
C47 C50 H50B 109.5 . .
H50A C50 H50B 109.5 . .
C47 C50 H50C 109.5 . .
H50A C50 H50C 109.5 . .
H50B C50 H50C 109.5 . .
C53 C51 C52 107.4(7) . .
C53 C51 C54 105.1(7) . .
C52 C51 C54 108.2(7) . .
C53 C51 P1 110.8(6) . .
C52 C51 P1 115.7(6) . .
C54 C51 P1 109.1(6) . .
C51 C52 H52A 109.5 . .
C51 C52 H52B 109.5 . .
H52A C52 H52B 109.5 . .
C51 C52 H52C 109.5 . .
H52A C52 H52C 109.5 . .
H52B C52 H52C 109.5 . .
C51 C53 H53A 109.5 . .
C51 C53 H53B 109.5 . .
H53A C53 H53B 109.5 . .
C51 C53 H53C 109.5 . .
H53A C53 H53C 109.5 . .
H53B C53 H53C 109.5 . .
C51 C54 H54A 109.5 . .
C51 C54 H54B 109.5 . .
H54A C54 H54B 109.5 . .
C51 C54 H54C 109.5 . .
H54A C54 H54C 109.5 . .
H54B C54 H54C 109.5 . .
Cl1S C1S Cl1S 97.6(16) . 3_766
Cl1S C1S H1S1 112.2 . .
Cl1S C1S H1S1 112.2 3_766 .
Cl1S C1S H1S2 112.2 . .
Cl1S C1S H1S2 112.2 3_766 .
H1S1 C1S H1S2 109.8 . .
C1S Cl1S C1S 82.4(16) . 3_766
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C10 1.839(8) .
Pt1 P1 2.3788(17) .
Pt1 Ru2 2.7504(6) .
Pt1 Ru1 2.9404(6) .
Pt1 H1 1.37(5) .
Sn1 C37 2.161(8) .
Sn1 C31 2.170(7) .
Sn1 Ru2 2.6488(8) .
Sn1 Ru1 2.6557(8) .
Ru1 C13 1.877(8) .
Ru1 C12 1.884(10) .
Ru1 C11 1.948(10) .
Ru1 H1 2.09(5) .
Ru1 Ru2 2.9782(8) .
Ru1 H1 2.09(5) .
Ru1 H2 1.97(7) .
Ru2 C22 1.881(10) .
Ru2 C23 1.897(9) .
Ru2 C21 1.936(10) .
Ru2 H2 1.60(7) .
P1 C47 1.907(8) .
P1 C43 1.910(8) .
P1 C51 1.912(8) .
O10 C10 1.140(9) .
O11 C11 1.117(10) .
O12 C12 1.154(10) .
O13 C13 1.146(9) .
O21 C21 1.128(10) .
O22 C22 1.140(10) .
O23 C23 1.130(9) .
C31 C36 1.385(11) .
C31 C32 1.387(11) .
C32 C33 1.422(12) .
C32 H32 0.9300 .
C33 C34 1.355(15) .
C33 H33 0.9300 .
C34 C35 1.347(15) .
C34 H34 0.9300 .
C35 C36 1.382(12) .
C35 H35 0.9300 .
C36 H36 0.9300 .
C37 C42 1.369(13) .
C37 C38 1.387(13) .
C38 C39 1.409(16) .
C38 H38 0.9300 .
C39 C40 1.35(2) .
C39 H39 0.9300 .
C40 C41 1.37(2) .
C40 H40 0.9300 .
C41 C42 1.375(16) .
C41 H41 0.9300 .
C42 H42 0.9300 .
C43 C45 1.514(12) .
C43 C44 1.540(12) .
C43 C46 1.546(10) .
C44 H44A 0.9600 .
C44 H44B 0.9600 .
C44 H44C 0.9600 .
C45 H45A 0.9600 .
C45 H45B 0.9600 .
C45 H45C 0.9600 .
C46 H46A 0.9600 .
C46 H46B 0.9600 .
C46 H46C 0.9600 .
C47 C48 1.526(12) .
C47 C50 1.534(11) .
C47 C49 1.542(12) .
C48 H48A 0.9600 .
C48 H48B 0.9600 .
C48 H48C 0.9600 .
C49 H49A 0.9600 .
C49 H49B 0.9600 .
C49 H49C 0.9600 .
C50 H50A 0.9600 .
C50 H50B 0.9600 .
C50 H50C 0.9600 .
C51 C53 1.522(11) .
C51 C52 1.532(10) .
C51 C54 1.536(12) .
C52 H52A 0.9600 .
C52 H52B 0.9600 .
C52 H52C 0.9600 .
C53 H53A 0.9600 .
C53 H53B 0.9600 .
C53 H53C 0.9600 .
C54 H54A 0.9600 .
C54 H54B 0.9600 .
C54 H54C 0.9600 .
C1S Cl1S 1.50(3) .
C1S Cl1S 1.90(3) 3_766
C1S H1S1 0.9700 .
C1S H1S2 0.9700 .
Cl1S C1S 1.90(3) 3_766
