#------------------------------------------------------------------------------
#$Date: 2016-03-21 09:06:11 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178617 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/28/4072818.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4072818
loop_
_publ_author_name
'Cobley, Christopher J.'
'Froese, Robert D. J.'
'Klosin, Jerzy'
'Qin, Cheng'
'Whiteker, Gregory T.'
'Abboud, Khalil A.'
_publ_section_title
;
 Effect of the Dihedral Angle of Biaryl-Bridged Bisphosphite Ligands on
 Enantioselectivity and Regioselectivity of Asymmetric Hydroformylation
;
_journal_issue                   12
_journal_name_full               Organometallics
_journal_page_first              2986
_journal_paper_doi               10.1021/om061065z
_journal_volume                  26
_journal_year                    2007
_chemical_formula_sum            'C84 H116 O6 P2 Rh2'
_chemical_formula_weight         1489.53
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                91.730(1)
_cell_angle_beta                 104.682(1)
_cell_angle_gamma                100.154(1)
_cell_formula_units_Z            1
_cell_length_a                   11.1580(6)
_cell_length_b                   12.8010(7)
_cell_length_c                   14.2385(8)
_cell_measurement_reflns_used    7504
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      28.0
_cell_measurement_theta_min      2.0
_cell_volume                     1930.52(18)
_computing_cell_refinement       'Bruker SMART & SAINT (Bruker 1998)'
_computing_data_collection       'Bruker SMART (Bruker 1998)'
_computing_data_reduction        'Bruker SHELXTL (Bruker 2000)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type  'SMART CCD area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'normal-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0467
_diffrn_reflns_av_sigmaI/netI    0.0606
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            17523
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         1.92
_diffrn_standards_decay_%        none
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.520
_exptl_absorpt_correction_T_max  0.9777
_exptl_absorpt_correction_T_min  0.9009
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details
'based on measured indexed crystal faces, SHELXTL (Bruker 1998)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.281
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plates
_exptl_crystal_F_000             788
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.04
_refine_diff_density_max         1.191
_refine_diff_density_min         -0.562
_refine_diff_density_rms         0.086
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     492
_refine_ls_number_reflns         8659
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.0600
_refine_ls_R_factor_gt           0.0441
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0509P)²+0.8064P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0997
_refine_ls_wR_factor_ref         0.1067
_reflns_number_gt                7056
_reflns_number_total             8659
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            om061065zsi20061120_040019.cif
_cod_data_source_block           Rh-dimer
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4072818
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh Rh 0.18183(2) 0.597180(18) 0.000001(17) 0.02334(8) Uani 1 1 d . . .
P1 P 0.13434(7) 0.44507(6) 0.07083(5) 0.02305(16) Uani 1 1 d . . .
O1 O 0.23065(19) 0.36886(15) 0.05694(14) 0.0266(4) Uani 1 1 d . . .
O2 O 0.15083(17) 0.44464(15) 0.18948(14) 0.0249(4) Uani 1 1 d . . .
O3 O 0.00336(18) 0.37937(15) 0.03180(15) 0.0270(4) Uani 1 1 d . . .
C1 C 0.2835(3) 0.2960(2) 0.1169(2) 0.0242(6) Uani 1 1 d . . .
C2 C 0.2757(3) 0.1938(2) 0.0738(2) 0.0262(6) Uani 1 1 d . . .
C3 C 0.3449(3) 0.1277(2) 0.1311(2) 0.0282(6) Uani 1 1 d . . .
H3A H 0.3421 0.0583 0.1038 0.034 Uiso 1 1 calc R . .
C4 C 0.4186(3) 0.1571(2) 0.2265(2) 0.0282(6) Uani 1 1 d . . .
C5 C 0.4211(3) 0.2583(2) 0.2653(2) 0.0263(6) Uani 1 1 d . . .
H5A H 0.4694 0.2800 0.3303 0.032 Uiso 1 1 calc R . .
C6 C 0.3545(3) 0.3298(2) 0.2114(2) 0.0248(6) Uani 1 1 d . . .
C7 C 0.3695(3) 0.4394(2) 0.2571(2) 0.0241(6) Uani 1 1 d . . .
C8 C 0.4893(3) 0.4924(2) 0.3100(2) 0.0264(6) Uani 1 1 d . . .
H8A H 0.5596 0.4589 0.3134 0.032 Uiso 1 1 calc R . .
C9 C 0.5086(3) 0.5930(2) 0.3581(2) 0.0271(6) Uani 1 1 d . A .
C10 C 0.4020(3) 0.6349(2) 0.3586(2) 0.0287(6) Uani 1 1 d . . .
H10A H 0.4131 0.7005 0.3957 0.034 Uiso 1 1 calc R . .
C11 C 0.2790(3) 0.5862(2) 0.3076(2) 0.0258(6) Uani 1 1 d . . .
C12 C 0.2677(3) 0.4914(2) 0.2511(2) 0.0241(6) Uani 1 1 d . . .
C13 C 0.1952(3) 0.1555(2) -0.0308(2) 0.0303(7) Uani 1 1 d . . .
C14 C 0.2236(3) 0.2327(3) -0.1065(2) 0.0419(8) Uani 1 1 d . . .
H14A H 0.1892 0.1967 -0.1720 0.063 Uiso 1 1 calc R . .
H14B H 0.3151 0.2560 -0.0941 0.063 Uiso 1 1 calc R . .
H14C H 0.1845 0.2948 -0.1015 0.063 Uiso 1 1 calc R . .
C15 C 0.2169(3) 0.0463(3) -0.0628(3) 0.0443(9) Uani 1 1 d . . .
H15A H 0.1935 -0.0062 -0.0187 0.066 Uiso 1 1 calc R . .
H15B H 0.3062 0.0510 -0.0608 0.066 Uiso 1 1 calc R . .
H15C H 0.1650 0.0242 -0.1293 0.066 Uiso 1 1 calc R . .
C16 C 0.0553(3) 0.1437(3) -0.0321(3) 0.0365(7) Uani 1 1 d . . .
H16A H 0.0026 0.1127 -0.0963 0.055 Uiso 1 1 calc R . .
H16B H 0.0366 0.2138 -0.0188 0.055 Uiso 1 1 calc R . .
H16C H 0.0374 0.0969 0.0178 0.055 Uiso 1 1 calc R . .
C17 C 0.4905(3) 0.0769(3) 0.2841(2) 0.0349(7) Uani 1 1 d . . .
C18 C 0.3950(4) -0.0190(3) 0.2984(3) 0.0540(10) Uani 1 1 d . . .
H18A H 0.4401 -0.0729 0.3302 0.081 Uiso 1 1 calc R . .
H18B H 0.3396 -0.0493 0.2349 0.081 Uiso 1 1 calc R . .
H18C H 0.3443 0.0039 0.3393 0.081 Uiso 1 1 calc R . .
C19 C 0.5736(4) 0.1263(3) 0.3838(3) 0.0511(10) Uani 1 1 d . . .
H19A H 0.5203 0.1469 0.4235 0.077 Uiso 1 1 calc R . .
H19B H 0.6327 0.1893 0.3752 0.077 Uiso 1 1 calc R . .
H19C H 0.6210 0.0741 0.4165 0.077 Uiso 1 1 calc R . .
C20 C 0.5771(3) 0.0397(3) 0.2268(3) 0.0421(8) Uani 1 1 d . . .
H20A H 0.6388 0.1010 0.2183 0.063 Uiso 1 1 calc R . .
H20B H 0.5263 0.0068 0.1628 0.063 Uiso 1 1 calc R . .
H20C H 0.6215 -0.0124 0.2628 0.063 Uiso 1 1 calc R . .
C21 C 0.6427(3) 0.6522(3) 0.4083(2) 0.0309(7) Uani 1 1 d . . .
C22 C 0.7123(6) 0.5817(5) 0.4815(5) 0.060(2) Uani 0.653(9) 1 d P A 1
H22A H 0.7165 0.5157 0.4469 0.090 Uiso 0.653(9) 1 calc PR A 1
H22B H 0.6665 0.5647 0.5311 0.090 Uiso 0.653(9) 1 calc PR A 1
H22C H 0.7980 0.6201 0.5129 0.090 Uiso 0.653(9) 1 calc PR A 1
C23 C 0.7127(7) 0.6740(7) 0.3291(5) 0.060(2) Uani 0.653(9) 1 d P A 1
H23A H 0.7972 0.7162 0.3582 0.090 Uiso 0.653(9) 1 calc PR A 1
H23B H 0.6656 0.7135 0.2792 0.090 Uiso 0.653(9) 1 calc PR A 1
H23C H 0.7202 0.6063 0.2991 0.090 Uiso 0.653(9) 1 calc PR A 1
C24 C 0.6483(6) 0.7578(5) 0.4624(6) 0.057(2) Uani 0.653(9) 1 d P A 1
H24A H 0.7367 0.7914 0.4914 0.085 Uiso 0.653(9) 1 calc PR A 1
H24B H 0.6048 0.7454 0.5140 0.085 Uiso 0.653(9) 1 calc PR A 1
H24C H 0.6072 0.8046 0.4169 0.085 Uiso 0.653(9) 1 calc PR A 1
C22' C 0.6569(12) 0.6498(14) 0.5179(9) 0.072(6) Uani 0.347(9) 1 d P A 2
H22D H 0.6415 0.5758 0.5345 0.108 Uiso 0.347(9) 1 calc PR A 2
H22E H 0.5957 0.6873 0.5360 0.108 Uiso 0.347(9) 1 calc PR A 2
H22F H 0.7426 0.6849 0.5534 0.108 Uiso 0.347(9) 1 calc PR A 2
C23' C 0.7434(10) 0.6071(14) 0.3828(13) 0.077(6) Uani 0.347(9) 1 d P A 2
H23D H 0.8254 0.6515 0.4153 0.115 Uiso 0.347(9) 1 calc PR A 2
H23E H 0.7314 0.6050 0.3121 0.115 Uiso 0.347(9) 1 calc PR A 2
H23F H 0.7407 0.5348 0.4038 0.115 Uiso 0.347(9) 1 calc PR A 2
C24' C 0.6590(13) 0.7673(10) 0.3796(14) 0.077(6) Uani 0.347(9) 1 d P A 2
H24D H 0.7313 0.8111 0.4268 0.115 Uiso 0.347(9) 1 calc PR A 2
H24E H 0.5824 0.7951 0.3790 0.115 Uiso 0.347(9) 1 calc PR A 2
H24F H 0.6735 0.7691 0.3146 0.115 Uiso 0.347(9) 1 calc PR A 2
C25 C 0.1644(3) 0.6341(3) 0.3155(2) 0.0325(7) Uani 1 1 d . . .
C26 C 0.1073(4) 0.6819(3) 0.2214(3) 0.0551(11) Uani 1 1 d . . .
H26A H 0.0387 0.7164 0.2301 0.083 Uiso 1 1 calc R . .
H26B H 0.0740 0.6253 0.1685 0.083 Uiso 1 1 calc R . .
H26C H 0.1724 0.7346 0.2051 0.083 Uiso 1 1 calc R . .
C27 C 0.2005(3) 0.7223(3) 0.3983(3) 0.0480(9) Uani 1 1 d . . .
H27A H 0.2625 0.7804 0.3851 0.072 Uiso 1 1 calc R . .
H27B H 0.2370 0.6936 0.4598 0.072 Uiso 1 1 calc R . .
H27C H 0.1251 0.7492 0.4028 0.072 Uiso 1 1 calc R . .
C28 C 0.0637(3) 0.5489(3) 0.3405(3) 0.0538(10) Uani 1 1 d . . .
H28A H -0.0090 0.5803 0.3444 0.081 Uiso 1 1 calc R . .
H28B H 0.0995 0.5223 0.4034 0.081 Uiso 1 1 calc R . .
H28C H 0.0367 0.4899 0.2898 0.081 Uiso 1 1 calc R . .
C29 C 0.3599(3) 0.5687(2) -0.0106(2) 0.0326(7) Uani 1 1 d . . .
H29A H 0.3714 0.4939 0.0008 0.039 Uiso 1 1 calc R . .
C30 C 0.3739(3) 0.6315(3) 0.0756(2) 0.0325(7) Uani 1 1 d . . .
H30A H 0.3946 0.5930 0.1359 0.039 Uiso 1 1 calc R . .
C31 C 0.4146(3) 0.7503(3) 0.0930(3) 0.0382(8) Uani 1 1 d . . .
H31A H 0.5080 0.7680 0.1140 0.046 Uiso 1 1 calc R . .
H31B H 0.3827 0.7752 0.1468 0.046 Uiso 1 1 calc R . .
C32 C 0.3685(3) 0.8102(3) 0.0039(3) 0.0372(8) Uani 1 1 d . . .
H32A H 0.3730 0.8856 0.0249 0.045 Uiso 1 1 calc R . .
H32B H 0.4242 0.8084 -0.0400 0.045 Uiso 1 1 calc R . .
C33 C 0.2337(3) 0.7611(2) -0.0506(2) 0.0326(7) Uani 1 1 d . . .
H33A H 0.1715 0.8081 -0.0488 0.039 Uiso 1 1 calc R . .
C34 C 0.1975(3) 0.6884(3) -0.1291(2) 0.0343(7) Uani 1 1 d . . .
H34A H 0.1146 0.6927 -0.1751 0.041 Uiso 1 1 calc R . .
C35 C 0.2852(3) 0.6405(3) -0.1750(3) 0.0422(8) Uani 1 1 d . . .
H35A H 0.3190 0.6925 -0.2163 0.051 Uiso 1 1 calc R . .
H35B H 0.2364 0.5767 -0.2178 0.051 Uiso 1 1 calc R . .
C36 C 0.3959(3) 0.6087(3) -0.1008(3) 0.0376(8) Uani 1 1 d . . .
H36A H 0.4266 0.5523 -0.1319 0.045 Uiso 1 1 calc R . .
H36B H 0.4658 0.6711 -0.0814 0.045 Uiso 1 1 calc R . .
C37 C -0.0322(11) 0.1934(9) 0.3583(8) 0.087(3) Uani 0.86(2) 1 d PD B 3
H37A H -0.0631 0.2541 0.3750 0.104 Uiso 0.86(2) 1 calc PR B 3
C38 C -0.0717(8) 0.0981(13) 0.3910(7) 0.087(3) Uani 0.86(2) 1 d PD B 3
H38A H -0.1302 0.0931 0.4296 0.105 Uiso 0.86(2) 1 calc PR B 3
C39 C -0.0286(9) 0.0098(9) 0.3690(7) 0.078(3) Uani 0.86(2) 1 d PD B 3
H39A H -0.0552 -0.0560 0.3935 0.093 Uiso 0.86(2) 1 calc PR B 3
C40 C 0.0537(8) 0.0165(6) 0.3112(6) 0.067(2) Uani 0.86(2) 1 d PD B 3
H40A H 0.0837 -0.0448 0.2948 0.081 Uiso 0.86(2) 1 calc PR B 3
C41 C 0.0929(5) 0.1141(10) 0.2767(4) 0.061(2) Uani 0.86(2) 1 d PD B 3
H41A H 0.1486 0.1193 0.2358 0.073 Uiso 0.86(2) 1 calc PR B 3
C42 C 0.0504(7) 0.2034(8) 0.3024(8) 0.070(3) Uani 0.86(2) 1 d PD B 3
H42A H 0.0787 0.2707 0.2810 0.084 Uiso 0.86(2) 1 calc PR B 3
C37' C -0.067(5) 0.139(3) 0.389(3) 0.035(9) Uiso 0.14(2) 1 d PD B 4
H37B H -0.1101 0.1639 0.4327 0.042 Uiso 0.14(2) 1 calc PR B 4
C38' C -0.068(5) 0.034(3) 0.380(3) 0.047(11) Uiso 0.14(2) 1 d PD B 4
H38B H -0.1216 -0.0149 0.4080 0.057 Uiso 0.14(2) 1 calc PR B 4
C39' C 0.008(5) -0.001(2) 0.331(3) 0.048(10) Uiso 0.14(2) 1 d PD B 4
H39B H 0.0136 -0.0737 0.3262 0.058 Uiso 0.14(2) 1 calc PR B 4
C40' C 0.078(4) 0.073(4) 0.287(3) 0.044(11) Uiso 0.14(2) 1 d PD B 4
H40B H 0.1444 0.0534 0.2642 0.053 Uiso 0.14(2) 1 calc PR B 4
C41' C 0.054(5) 0.175(3) 0.277(3) 0.033(9) Uiso 0.14(2) 1 d PD B 4
H41B H 0.0776 0.2176 0.2286 0.040 Uiso 0.14(2) 1 calc PR B 4
C42' C -0.008(6) 0.213(3) 0.341(4) 0.054(13) Uiso 0.14(2) 1 d PD B 4
H42B H -0.0095 0.2866 0.3503 0.065 Uiso 0.14(2) 1 calc PR B 4
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 Rh C30 154.22(11) 2_565 .
O3 Rh C29 163.96(11) 2_565 .
C30 Rh C29 38.86(12) . .
O3 Rh C34 85.94(10) 2_565 .
C30 Rh C34 97.44(12) . .
C29 Rh C34 81.31(12) . .
O3 Rh P1 92.39(6) 2_565 .
C30 Rh P1 95.84(9) . .
C29 Rh P1 94.45(9) . .
C34 Rh P1 152.58(9) . .
O3 Rh C33 87.35(10) 2_565 .
C30 Rh C33 81.23(12) . .
C29 Rh C33 87.83(11) . .
C34 Rh C33 35.23(12) . .
P1 Rh C33 172.16(9) . .
O3 P1 O1 106.07(11) . .
O3 P1 O2 101.16(11) . .
O1 P1 O2 100.78(10) . .
O3 P1 Rh 117.25(8) . .
O1 P1 Rh 107.93(8) . .
O2 P1 Rh 121.61(8) . .
C1 O1 P1 130.84(18) . .
C12 O2 P1 117.70(17) . .
P1 O3 Rh 137.83(12) . 2_565
C6 C1 O1 119.5(2) . .
C6 C1 C2 122.8(3) . .
O1 C1 C2 117.2(3) . .
C3 C2 C1 116.0(3) . .
C3 C2 C13 121.2(3) . .
C1 C2 C13 122.8(3) . .
C2 C3 C4 124.0(3) . .
C5 C4 C3 117.2(3) . .
C5 C4 C17 123.1(3) . .
C3 C4 C17 119.7(3) . .
C4 C5 C6 122.0(3) . .
C1 C6 C5 118.0(3) . .
C1 C6 C7 123.8(2) . .
C5 C6 C7 118.1(3) . .
C8 C7 C12 118.0(3) . .
C8 C7 C6 119.2(2) . .
C12 C7 C6 122.7(3) . .
C9 C8 C7 121.9(3) . .
C10 C9 C8 117.1(3) . .
C10 C9 C21 122.7(3) . .
C8 C9 C21 120.2(3) . .
C9 C10 C11 123.9(3) . .
C10 C11 C12 116.0(3) . .
C10 C11 C25 121.2(3) . .
C12 C11 C25 122.9(3) . .
O2 C12 C7 118.3(2) . .
O2 C12 C11 119.5(2) . .
C7 C12 C11 122.1(3) . .
C15 C13 C16 107.7(3) . .
C15 C13 C14 107.4(3) . .
C16 C13 C14 109.1(3) . .
C15 C13 C2 111.3(2) . .
C16 C13 C2 108.3(3) . .
C14 C13 C2 112.9(3) . .
C19 C17 C18 109.1(3) . .
C19 C17 C20 107.6(3) . .
C18 C17 C20 109.5(3) . .
C19 C17 C4 112.0(3) . .
C18 C17 C4 109.0(3) . .
C20 C17 C4 109.5(3) . .
C23' C21 C24 130.2(6) . .
C23' C21 C22' 109.6(10) . .
C24 C21 C22' 64.1(7) . .
C23' C21 C23 47.2(8) . .
C24 C21 C23 108.2(5) . .
C22' C21 C23 145.2(6) . .
C23' C21 C24' 106.3(10) . .
C24 C21 C24' 47.2(7) . .
C22' C21 C24' 110.4(10) . .
C23 C21 C24' 65.1(8) . .
C23' C21 C9 114.8(5) . .
C24 C21 C9 114.2(3) . .
C22' C21 C9 106.4(5) . .
C23 C21 C9 107.4(3) . .
C24' C21 C9 109.4(6) . .
C23' C21 C22 62.3(8) . .
C24 C21 C22 108.1(5) . .
C22' C21 C22 50.7(7) . .
C23 C21 C22 108.7(5) . .
C24' C21 C22 139.8(6) . .
C9 C21 C22 110.1(3) . .
C26 C25 C27 107.7(3) . .
C26 C25 C11 111.3(3) . .
C27 C25 C11 111.6(3) . .
C26 C25 C28 110.0(3) . .
C27 C25 C28 105.7(3) . .
C11 C25 C28 110.4(3) . .
C30 C29 C36 125.3(3) . .
C30 C29 Rh 69.75(17) . .
C36 C29 Rh 113.8(2) . .
C29 C30 C31 127.3(3) . .
C29 C30 Rh 71.39(17) . .
C31 C30 Rh 108.3(2) . .
C30 C31 C32 113.8(3) . .
C33 C32 C31 111.0(3) . .
C34 C33 C32 126.2(3) . .
C34 C33 Rh 71.14(18) . .
C32 C33 Rh 109.3(2) . .
C33 C34 C35 125.5(3) . .
C33 C34 Rh 73.64(18) . .
C35 C34 Rh 106.3(2) . .
C34 C35 C36 113.6(3) . .
C29 C36 C35 112.5(3) . .
C42 C37 C38 121.2(8) . .
C37 C38 C39 120.9(7) . .
C38 C39 C40 119.6(7) . .
C39 C40 C41 119.4(6) . .
C42 C41 C40 119.9(6) . .
C37 C42 C41 119.0(8) . .
C38' C37' C42' 125(3) . .
C37' C38' C39' 118(2) . .
C38' C39' C40' 118(2) . .
C39' C40' C41' 121(2) . .
C40' C41' C42' 117(2) . .
C37' C42' C41' 117(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rh O3 2.0779(19) 2_565
Rh C30 2.101(3) .
Rh C29 2.123(3) .
Rh C34 2.234(3) .
Rh P1 2.2616(8) .
Rh C33 2.265(3) .
P1 O3 1.510(2) .
P1 O1 1.616(2) .
P1 O2 1.653(2) .
O1 C1 1.391(3) .
O2 C12 1.394(3) .
O3 Rh 2.0779(19) 2_565
C1 C6 1.389(4) .
C1 C2 1.407(4) .
C2 C3 1.390(4) .
C2 C13 1.545(4) .
C3 C4 1.399(4) .
C4 C5 1.385(4) .
C4 C17 1.541(4) .
C5 C6 1.405(4) .
C6 C7 1.493(4) .
C7 C8 1.397(4) .
C7 C12 1.400(4) .
C8 C9 1.395(4) .
C9 C10 1.390(4) .
C9 C21 1.533(4) .
C10 C11 1.401(4) .
C11 C12 1.404(4) .
C11 C25 1.539(4) .
C13 C15 1.536(4) .
C13 C16 1.537(4) .
C13 C14 1.537(4) .
C17 C19 1.532(5) .
C17 C18 1.533(5) .
C17 C20 1.537(5) .
C21 C23' 1.467(12) .
C21 C24 1.519(6) .
C21 C22' 1.530(12) .
C21 C23 1.533(7) .
C21 C24' 1.533(12) .
C21 C22 1.548(6) .
C25 C26 1.527(5) .
C25 C27 1.531(5) .
C25 C28 1.541(5) .
C29 C30 1.405(5) .
C29 C36 1.519(4) .
C30 C31 1.502(4) .
C31 C32 1.526(5) .
C32 C33 1.519(4) .
C33 C34 1.362(5) .
C34 C35 1.508(5) .
C35 C36 1.532(5) .
C37 C42 1.355(11) .
C37 C38 1.359(13) .
C38 C39 1.362(12) .
C39 C40 1.374(10) .
C40 C41 1.395(9) .
C41 C42 1.386(11) .
C37' C38' 1.35(2) .
C37' C42' 1.35(2) .
C38' C39' 1.36(2) .
C39' C40' 1.38(2) .
C40' C41' 1.39(2) .
C41' C42' 1.40(2) .
