#------------------------------------------------------------------------------
#$Date: 2016-03-21 09:18:06 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178621 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/32/4073246.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4073246
loop_
_publ_author_name
'Liu, Bin'
'Chen, Wanzhi'
'Jin, Shouwen'
_publ_section_title
;
 Synthesis, Structural Characterization, and Luminescence of New Silver
 Aggregates Containing Short Ag−Ag Contacts Stabilized by
 Functionalized Bis(N-heterocyclic carbene) Ligands
;
_journal_issue                   15
_journal_name_full               Organometallics
_journal_page_first              3660
_journal_paper_doi               10.1021/om0701928
_journal_volume                  26
_journal_year                    2007
_chemical_formula_sum            'C46 H48 Ag4 F24 N16 P4'
_chemical_formula_weight         1836.36
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                102.710(3)
_cell_angle_beta                 99.325(3)
_cell_angle_gamma                109.119(3)
_cell_formula_units_Z            1
_cell_length_a                   11.537(2)
_cell_length_b                   11.903(2)
_cell_length_c                   15.777(3)
_cell_measurement_reflns_used    4054
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      26.604
_cell_measurement_theta_min      2.501
_cell_volume                     1931.4(6)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0228
_diffrn_reflns_av_sigmaI/netI    0.0541
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            9888
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.89
_exptl_absorpt_coefficient_mu    1.180
_exptl_absorpt_correction_T_max  0.6188
_exptl_absorpt_correction_T_min  0.5736
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.579
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             900
_exptl_crystal_size_max          0.53
_exptl_crystal_size_mid          0.48
_exptl_crystal_size_min          0.45
_refine_diff_density_max         0.986
_refine_diff_density_min         -0.510
_refine_diff_density_rms         0.072
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.925
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     397
_refine_ls_number_reflns         6667
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.925
_refine_ls_R_factor_all          0.0621
_refine_ls_R_factor_gt           0.0375
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0517P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0890
_refine_ls_wR_factor_ref         0.0975
_reflns_number_gt                4548
_reflns_number_total             6667
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om0701928-file001.cif
_cod_data_source_block           061221f
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4073246
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 1.02582(3) 0.93390(3) 0.40573(2) 0.04515(12) Uani 1 1 d .
Ag2 Ag 0.91465(4) 0.89585(3) 0.21738(3) 0.06677(14) Uani 1 1 d .
F1 F 0.5147(4) 0.8638(5) 0.8155(4) 0.191(2) Uani 1 1 d .
F2 F 0.2360(4) 0.6746(4) 0.7304(3) 0.1576(17) Uani 1 1 d .
F3 F 0.4218(5) 0.7036(5) 0.6987(4) 0.183(2) Uani 1 1 d .
F4 F 0.3535(6) 0.8582(5) 0.7201(4) 0.184(2) Uani 1 1 d .
F5 F 0.3310(5) 0.8352(4) 0.8509(3) 0.1590(18) Uani 1 1 d .
F6 F 0.3941(5) 0.6797(4) 0.8291(3) 0.1538(17) Uani 1 1 d .
F7 F 0.3913(3) 0.8283(2) 0.2869(2) 0.0826(9) Uani 1 1 d .
F8 F 0.1455(3) 0.5840(2) 0.2318(2) 0.0991(11) Uani 1 1 d .
F9 F 0.3289(3) 0.6388(3) 0.1923(2) 0.1049(12) Uani 1 1 d .
F10 F 0.2085(3) 0.7501(3) 0.1804(2) 0.1107(12) Uani 1 1 d .
F11 F 0.2080(3) 0.7759(3) 0.3229(2) 0.1027(11) Uani 1 1 d .
F12 F 0.3308(3) 0.6627(3) 0.3357(2) 0.0823(9) Uani 1 1 d .
N1 N 0.7267(3) 0.8161(3) 0.3554(2) 0.0430(8) Uani 1 1 d .
N2 N 0.8043(3) 0.6865(3) 0.3024(2) 0.0449(9) Uani 1 1 d .
N3 N 0.8877(4) 0.7031(3) 0.1390(3) 0.0576(10) Uani 1 1 d .
N4 N 1.3115(3) 1.0730(3) 0.5135(2) 0.0397(8) Uani 1 1 d .
N5 N 1.2869(3) 1.0629(3) 0.3752(2) 0.0394(8) Uani 1 1 d .
N6 N 1.0456(3) 1.0928(3) 0.2466(2) 0.0522(9) Uani 1 1 d .
P1 P 0.37501(18) 0.77114(16) 0.77457(14) 0.0984(6) Uani 1 1 d .
P2 P 0.26749(11) 0.70648(11) 0.25851(9) 0.0595(4) Uani 1 1 d .
C1 C 0.7147(4) 0.9306(4) 0.4013(3) 0.0456(10) Uani 1 1 d .
H1A H 0.7927 1.0005 0.4100 0.055 Uiso 1 1 calc R
H1B H 0.6467 0.9426 0.3641 0.055 Uiso 1 1 calc R
C2 C 0.8371(4) 0.8071(4) 0.3485(2) 0.0386(9) Uani 1 1 d .
C3 C 0.6763(4) 0.6236(4) 0.2815(3) 0.0624(13) Uani 1 1 d .
H3 H 0.6320 0.5400 0.2501 0.075 Uiso 1 1 calc R
C4 C 0.6266(4) 0.7053(4) 0.3148(3) 0.0603(13) Uani 1 1 d .
H4 H 0.5413 0.6900 0.3111 0.072 Uiso 1 1 calc R
C5 C 0.8924(4) 0.6322(4) 0.2716(3) 0.0487(11) Uani 1 1 d .
H5A H 0.8777 0.5545 0.2861 0.058 Uiso 1 1 calc R
H5B H 0.9787 0.6882 0.3029 0.058 Uiso 1 1 calc R
C6 C 0.8768(4) 0.6087(4) 0.1720(3) 0.0479(11) Uani 1 1 d .
C7 C 0.8553(4) 0.4907(4) 0.1175(3) 0.0618(13) Uani 1 1 d .
H7 H 0.8481 0.4253 0.1422 0.074 Uiso 1 1 calc R
C8 C 0.8450(5) 0.4722(5) 0.0280(4) 0.0801(17) Uani 1 1 d .
H8 H 0.8296 0.3939 -0.0094 0.096 Uiso 1 1 calc R
C9 C 0.8575(6) 0.5698(7) -0.0058(4) 0.096(2) Uani 1 1 d .
H9 H 0.8531 0.5601 -0.0665 0.116 Uiso 1 1 calc R
C10 C 0.8767(6) 0.6834(5) 0.0513(4) 0.0910(19) Uani 1 1 d .
H10 H 0.8823 0.7493 0.0275 0.109 Uiso 1 1 calc R
C11 C 1.2205(4) 1.0354(3) 0.4354(3) 0.0374(9) Uani 1 1 d .
C12 C 1.4154(4) 1.1155(4) 0.4135(3) 0.0539(12) Uani 1 1 d .
H12 H 1.4789 1.1412 0.3844 0.065 Uiso 1 1 calc R
C13 C 1.4313(4) 1.1227(4) 0.4999(3) 0.0555(12) Uani 1 1 d .
H13 H 1.5082 1.1549 0.5431 0.067 Uiso 1 1 calc R
C14 C 1.2295(4) 1.0377(4) 0.2802(3) 0.0468(11) Uani 1 1 d .
H14A H 1.1644 0.9546 0.2576 0.056 Uiso 1 1 calc R
H14B H 1.2937 1.0410 0.2469 0.056 Uiso 1 1 calc R
C15 C 1.1716(4) 1.1308(4) 0.2652(3) 0.0499(11) Uani 1 1 d .
C16 C 1.2460(5) 1.2496(5) 0.2708(4) 0.0816(16) Uani 1 1 d .
H16 H 1.3336 1.2734 0.2824 0.098 Uiso 1 1 calc R
C17 C 1.1917(7) 1.3339(5) 0.2594(5) 0.108(2) Uani 1 1 d .
H17 H 1.2412 1.4150 0.2631 0.129 Uiso 1 1 calc R
C18 C 1.0642(6) 1.2952(5) 0.2426(4) 0.100(2) Uani 1 1 d .
H18 H 1.0250 1.3509 0.2360 0.120 Uiso 1 1 calc R
C19 C 0.9920(5) 1.1748(5) 0.2353(4) 0.0820(17) Uani 1 1 d .
H19 H 0.9041 1.1493 0.2222 0.098 Uiso 1 1 calc R
N7 N 0.7066(5) 0.8845(5) 0.1637(4) 0.0977(17) Uani 1 1 d .
C21 C 0.6097(6) 0.8675(5) 0.1262(4) 0.0807(16) Uani 1 1 d .
C20 C 0.4839(6) 0.8455(7) 0.0778(5) 0.125(3) Uani 1 1 d .
H20A H 0.4305 0.7601 0.0667 0.188 Uiso 1 1 calc R
H20B H 0.4867 0.8637 0.0217 0.188 Uiso 1 1 calc R
H20C H 0.4504 0.8982 0.1128 0.188 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C11 Ag1 C2 166.32(14) . .
C11 Ag1 Ag2 108.86(11) . .
C2 Ag1 Ag2 61.89(10) . .
C11 Ag1 Ag1 98.00(10) . 2_776
C2 Ag1 Ag1 95.59(10) . 2_776
Ag2 Ag1 Ag1 133.261(19) . 2_776
N6 Ag2 N3 140.16(14) . .
N6 Ag2 N7 107.53(15) . .
N3 Ag2 N7 97.61(16) . .
N6 Ag2 C2 120.98(12) . .
N3 Ag2 C2 89.58(13) . .
N7 Ag2 C2 88.08(16) . .
N6 Ag2 Ag1 83.30(9) . .
N3 Ag2 Ag1 108.48(10) . .
N7 Ag2 Ag1 122.98(14) . .
C2 Ag2 Ag1 44.12(8) . .
C2 N1 C4 112.1(3) . .
C2 N1 C1 123.7(3) . .
C4 N1 C1 124.2(3) . .
C2 N2 C3 111.3(3) . .
C2 N2 C5 124.7(3) . .
C3 N2 C5 123.8(3) . .
C6 N3 C10 118.3(4) . .
C6 N3 Ag2 125.6(3) . .
C10 N3 Ag2 116.1(3) . .
C11 N4 C13 110.7(4) . .
C11 N4 C1 124.1(3) . 2_776
C13 N4 C1 125.1(3) . 2_776
C11 N5 C12 111.9(3) . .
C11 N5 C14 124.0(3) . .
C12 N5 C14 124.1(4) . .
C15 N6 C19 118.7(4) . .
C15 N6 Ag2 124.3(3) . .
C19 N6 Ag2 116.7(3) . .
F5 P1 F4 90.9(3) . .
F5 P1 F1 91.9(3) . .
F4 P1 F1 89.0(3) . .
F5 P1 F3 178.1(3) . .
F4 P1 F3 90.9(3) . .
F1 P1 F3 87.7(3) . .
F5 P1 F2 90.3(3) . .
F4 P1 F2 91.3(3) . .
F1 P1 F2 177.7(3) . .
F3 P1 F2 90.1(3) . .
F5 P1 F6 89.3(3) . .
F4 P1 F6 178.7(3) . .
F1 P1 F6 92.2(3) . .
F3 P1 F6 88.9(3) . .
F2 P1 F6 87.5(3) . .
F11 P2 F8 90.62(19) . .
F11 P2 F10 89.4(2) . .
F8 P2 F10 90.96(19) . .
F11 P2 F9 178.6(2) . .
F8 P2 F9 90.37(19) . .
F10 P2 F9 89.7(2) . .
F11 P2 F7 89.49(17) . .
F8 P2 F7 178.7(2) . .
F10 P2 F7 90.31(19) . .
F9 P2 F7 89.54(19) . .
F11 P2 F12 92.27(19) . .
F8 P2 F12 90.06(18) . .
F10 P2 F12 178.1(2) . .
F9 P2 F12 88.65(18) . .
F7 P2 F12 88.67(17) . .
N4 C1 N1 111.4(3) 2_776 .
N4 C1 H1A 109.4 2_776 .
N1 C1 H1A 109.4 . .
N4 C1 H1B 109.4 2_776 .
N1 C1 H1B 109.4 . .
H1A C1 H1B 108.0 . .
N1 C2 N2 103.7(3) . .
N1 C2 Ag1 131.7(3) . .
N2 C2 Ag1 124.1(3) . .
N1 C2 Ag2 110.8(3) . .
N2 C2 Ag2 94.9(2) . .
Ag1 C2 Ag2 74.00(12) . .
C4 C3 N2 106.8(4) . .
C4 C3 H3 126.6 . .
N2 C3 H3 126.6 . .
C3 C4 N1 106.1(4) . .
C3 C4 H4 126.9 . .
N1 C4 H4 126.9 . .
N2 C5 C6 111.6(3) . .
N2 C5 H5A 109.3 . .
C6 C5 H5A 109.3 . .
N2 C5 H5B 109.3 . .
C6 C5 H5B 109.3 . .
H5A C5 H5B 108.0 . .
N3 C6 C7 121.6(4) . .
N3 C6 C5 118.1(4) . .
C7 C6 C5 120.3(5) . .
C8 C7 C6 119.4(5) . .
C8 C7 H7 120.3 . .
C6 C7 H7 120.3 . .
C9 C8 C7 119.0(5) . .
C9 C8 H8 120.5 . .
C7 C8 H8 120.5 . .
C8 C9 C10 118.8(6) . .
C8 C9 H9 120.6 . .
C10 C9 H9 120.6 . .
N3 C10 C9 122.9(6) . .
N3 C10 H10 118.5 . .
C9 C10 H10 118.5 . .
N5 C11 N4 103.7(3) . .
N5 C11 Ag1 125.6(3) . .
N4 C11 Ag1 130.1(3) . .
C13 C12 N5 106.8(4) . .
C13 C12 H12 126.6 . .
N5 C12 H12 126.6 . .
C12 C13 N4 106.9(4) . .
C12 C13 H13 126.5 . .
N4 C13 H13 126.5 . .
N5 C14 C15 111.3(3) . .
N5 C14 H14A 109.4 . .
C15 C14 H14A 109.4 . .
N5 C14 H14B 109.4 . .
C15 C14 H14B 109.4 . .
H14A C14 H14B 108.0 . .
N6 C15 C16 121.4(4) . .
N6 C15 C14 117.5(4) . .
C16 C15 C14 121.1(4) . .
C17 C16 C15 120.2(5) . .
C17 C16 H16 119.9 . .
C15 C16 H16 119.9 . .
C18 C17 C16 117.8(6) . .
C18 C17 H17 121.1 . .
C16 C17 H17 121.1 . .
C17 C18 C19 120.6(5) . .
C17 C18 H18 119.7 . .
C19 C18 H18 119.7 . .
N6 C19 C18 121.2(5) . .
N6 C19 H19 119.4 . .
C18 C19 H19 119.4 . .
C21 N7 Ag2 168.8(5) . .
N7 C21 C20 179.8(9) . .
C21 C20 H20A 109.5 . .
C21 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C21 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C11 2.087(4) .
Ag1 C2 2.108(4) .
Ag1 Ag2 2.9107(6) .
Ag1 Ag1 3.2875(7) 2_776
Ag2 N6 2.230(4) .
Ag2 N3 2.247(4) .
Ag2 N7 2.361(5) .
Ag2 C2 2.671(4) .
F1 P1 1.555(5) .
F2 P1 1.567(5) .
F3 P1 1.563(4) .
F4 P1 1.539(5) .
F5 P1 1.529(4) .
F6 P1 1.575(5) .
F7 P2 1.579(3) .
F8 P2 1.574(3) .
F9 P2 1.576(3) .
F10 P2 1.579(3) .
F11 P2 1.554(3) .
F12 P2 1.590(3) .
N1 C2 1.332(5) .
N1 C4 1.369(5) .
N1 C1 1.458(5) .
N2 C2 1.352(5) .
N2 C3 1.364(5) .
N2 C5 1.462(5) .
N3 C6 1.318(6) .
N3 C10 1.329(6) .
N4 C11 1.360(5) .
N4 C13 1.387(5) .
N4 C1 1.431(5) 2_776
N5 C11 1.344(5) .
N5 C12 1.375(5) .
N5 C14 1.457(5) .
N6 C15 1.332(5) .
N6 C19 1.343(5) .
C1 N4 1.431(5) 2_776
C1 H1A 0.9700 .
C1 H1B 0.9700 .
C3 C4 1.336(6) .
C3 H3 0.9300 .
C4 H4 0.9300 .
C5 C6 1.503(6) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C6 C7 1.395(6) .
C7 C8 1.359(7) .
C7 H7 0.9300 .
C8 C9 1.359(8) .
C8 H8 0.9300 .
C9 C10 1.375(8) .
C9 H9 0.9300 .
C10 H10 0.9300 .
C12 C13 1.325(6) .
C12 H12 0.9300 .
C13 H13 0.9300 .
C14 C15 1.510(6) .
C14 H14A 0.9700 .
C14 H14B 0.9700 .
C15 C16 1.367(6) .
C16 C17 1.374(7) .
C16 H16 0.9300 .
C17 C18 1.350(8) .
C17 H17 0.9300 .
C18 C19 1.370(7) .
C18 H18 0.9300 .
C19 H19 0.9300 .
N7 C21 1.107(6) .
C21 C20 1.436(8) .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C11 Ag1 Ag2 N6 -41.05(14) . .
C2 Ag1 Ag2 N6 149.97(15) . .
Ag1 Ag1 Ag2 N6 80.51(10) 2_776 .
C11 Ag1 Ag2 N3 99.84(15) . .
C2 Ag1 Ag2 N3 -69.15(16) . .
Ag1 Ag1 Ag2 N3 -138.60(11) 2_776 .
C11 Ag1 Ag2 N7 -147.62(18) . .
C2 Ag1 Ag2 N7 43.40(19) . .
Ag1 Ag1 Ag2 N7 -26.06(15) 2_776 .
C11 Ag1 Ag2 C2 168.99(15) . .
Ag1 Ag1 Ag2 C2 -69.45(12) 2_776 .
N6 Ag2 N3 C6 125.7(4) . .
N7 Ag2 N3 C6 -104.9(4) . .
C2 Ag2 N3 C6 -16.9(4) . .
Ag1 Ag2 N3 C6 23.7(4) . .
N6 Ag2 N3 C10 -57.3(5) . .
N7 Ag2 N3 C10 72.0(4) . .
C2 Ag2 N3 C10 160.0(4) . .
Ag1 Ag2 N3 C10 -159.4(4) . .
N3 Ag2 N6 C15 -43.0(4) . .
N7 Ag2 N6 C15 -169.6(3) . .
C2 Ag2 N6 C15 91.9(3) . .
Ag1 Ag2 N6 C15 67.9(3) . .
N3 Ag2 N6 C19 129.9(4) . .
N7 Ag2 N6 C19 3.4(4) . .
C2 Ag2 N6 C19 -95.2(4) . .
Ag1 Ag2 N6 C19 -119.2(4) . .
C2 N1 C1 N4 -105.1(4) . 2_776
C4 N1 C1 N4 74.6(5) . 2_776
C4 N1 C2 N2 -0.3(5) . .
C1 N1 C2 N2 179.4(4) . .
C4 N1 C2 Ag1 -172.8(3) . .
C1 N1 C2 Ag1 6.9(6) . .
C4 N1 C2 Ag2 100.4(3) . .
C1 N1 C2 Ag2 -79.9(4) . .
C3 N2 C2 N1 0.2(5) . .
C5 N2 C2 N1 175.0(4) . .
C3 N2 C2 Ag1 173.5(3) . .
C5 N2 C2 Ag1 -11.7(6) . .
C3 N2 C2 Ag2 -112.5(3) . .
C5 N2 C2 Ag2 62.3(4) . .
C11 Ag1 C2 N1 -153.6(5) . .
Ag2 Ag1 C2 N1 -103.8(4) . .
Ag1 Ag1 C2 N1 33.0(4) 2_776 .
C11 Ag1 C2 N2 35.1(8) . .
Ag2 Ag1 C2 N2 85.0(3) . .
Ag1 Ag1 C2 N2 -138.3(3) 2_776 .
C11 Ag1 C2 Ag2 -49.9(6) . .
Ag1 Ag1 C2 Ag2 136.75(5) 2_776 .
N6 Ag2 C2 N1 93.8(3) . .
N3 Ag2 C2 N1 -113.2(3) . .
N7 Ag2 C2 N1 -15.6(3) . .
Ag1 Ag2 C2 N1 129.2(3) . .
N6 Ag2 C2 N2 -159.6(2) . .
N3 Ag2 C2 N2 -6.6(2) . .
N7 Ag2 C2 N2 91.1(2) . .
Ag1 Ag2 C2 N2 -124.1(3) . .
N6 Ag2 C2 Ag1 -35.44(17) . .
N3 Ag2 C2 Ag1 117.58(13) . .
N7 Ag2 C2 Ag1 -144.79(15) . .
C2 N2 C3 C4 -0.1(5) . .
C5 N2 C3 C4 -174.9(4) . .
N2 C3 C4 N1 -0.1(5) . .
C2 N1 C4 C3 0.3(5) . .
C1 N1 C4 C3 -179.4(4) . .
C2 N2 C5 C6 -105.2(4) . .
C3 N2 C5 C6 69.0(5) . .
C10 N3 C6 C7 0.6(7) . .
Ag2 N3 C6 C7 177.4(3) . .
C10 N3 C6 C5 178.6(4) . .
Ag2 N3 C6 C5 -4.5(5) . .
N2 C5 C6 N3 56.0(5) . .
N2 C5 C6 C7 -125.9(4) . .
N3 C6 C7 C8 -0.2(7) . .
C5 C6 C7 C8 -178.2(4) . .
C6 C7 C8 C9 0.8(8) . .
C7 C8 C9 C10 -1.7(9) . .
C6 N3 C10 C9 -1.6(9) . .
Ag2 N3 C10 C9 -178.8(5) . .
C8 C9 C10 N3 2.2(10) . .
C12 N5 C11 N4 0.2(4) . .
C14 N5 C11 N4 179.2(3) . .
C12 N5 C11 Ag1 -171.5(3) . .
C14 N5 C11 Ag1 7.5(5) . .
C13 N4 C11 N5 0.1(4) . .
C1 N4 C11 N5 175.9(3) 2_776 .
C13 N4 C11 Ag1 171.3(3) . .
C1 N4 C11 Ag1 -12.9(5) 2_776 .
C2 Ag1 C11 N5 36.4(8) . .
Ag2 Ag1 C11 N5 -9.1(3) . .
Ag1 Ag1 C11 N5 -150.3(3) 2_776 .
C2 Ag1 C11 N4 -133.1(6) . .
Ag2 Ag1 C11 N4 -178.5(3) . .
Ag1 Ag1 C11 N4 40.3(3) 2_776 .
C11 N5 C12 C13 -0.4(5) . .
C14 N5 C12 C13 -179.4(4) . .
N5 C12 C13 N4 0.5(5) . .
C11 N4 C13 C12 -0.4(5) . .
C1 N4 C13 C12 -176.1(4) 2_776 .
C11 N5 C14 C15 76.4(5) . .
C12 N5 C14 C15 -104.8(4) . .
C19 N6 C15 C16 -1.6(7) . .
Ag2 N6 C15 C16 171.2(4) . .
C19 N6 C15 C14 178.3(4) . .
Ag2 N6 C15 C14 -8.9(5) . .
N5 C14 C15 N6 -105.1(4) . .
N5 C14 C15 C16 74.8(5) . .
N6 C15 C16 C17 1.6(8) . .
C14 C15 C16 C17 -178.2(5) . .
C15 C16 C17 C18 -0.1(10) . .
C16 C17 C18 C19 -1.5(11) . .
C15 N6 C19 C18 0.0(8) . .
Ag2 N6 C19 C18 -173.4(5) . .
C17 C18 C19 N6 1.6(10) . .
N6 Ag2 N7 C21 116(3) . .
N3 Ag2 N7 C21 -33(3) . .
C2 Ag2 N7 C21 -122(3) . .
Ag1 Ag2 N7 C21 -151(3) . .
Ag2 N7 C21 C20 -178(100) . .
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
1 -0.025 -0.025 0.000 284.4 -4.9
2 0.071 0.500 0.500 316.2 -1.9
