#------------------------------------------------------------------------------
#$Date: 2016-03-21 09:18:06 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178621 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/32/4073247.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4073247
loop_
_publ_author_name
'Liu, Bin'
'Chen, Wanzhi'
'Jin, Shouwen'
_publ_section_title
;
 Synthesis, Structural Characterization, and Luminescence of New Silver
 Aggregates Containing Short Ag−Ag Contacts Stabilized by
 Functionalized Bis(N-heterocyclic carbene) Ligands
;
_journal_issue                   15
_journal_name_full               Organometallics
_journal_page_first              3660
_journal_paper_doi               10.1021/om0701928
_journal_volume                  26
_journal_year                    2007
_chemical_formula_sum            'C38 H40 Ag4 F24 N12 O2 P4'
_chemical_formula_weight         1708.18
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                102.25(3)
_cell_angle_beta                 99.82(3)
_cell_angle_gamma                108.88(3)
_cell_formula_units_Z            1
_cell_length_a                   11.61(2)
_cell_length_b                   12.02(3)
_cell_length_c                   15.74(3)
_cell_measurement_reflns_used    1070
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      18.777
_cell_measurement_theta_min      2.504
_cell_volume                     1962(7)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.863
_diffrn_measured_fraction_theta_max 0.863
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.2461
_diffrn_reflns_av_sigmaI/netI    0.8643
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            8225
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         2.91
_exptl_absorpt_coefficient_mu    1.157
_exptl_absorpt_correction_T_max  0.7530
_exptl_absorpt_correction_T_min  0.6945
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.447
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             832
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.26
_refine_diff_density_max         0.892
_refine_diff_density_min         -0.505
_refine_diff_density_rms         0.120
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.851
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     379
_refine_ls_number_reflns         5966
_refine_ls_number_restraints     951
_refine_ls_restrained_S_all      0.798
_refine_ls_R_factor_all          0.3868
_refine_ls_R_factor_gt           0.0928
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1585
_refine_ls_wR_factor_ref         0.3014
_reflns_number_gt                1228
_reflns_number_total             5966
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om0701928-file001.cif
_cod_data_source_block           060730b
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        1961(7)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4073247
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.5887(2) 0.60339(17) 0.78396(14) 0.0662(9) Uani 1 1 d .
Ag2 Ag 0.47501(17) 0.56472(15) 0.59466(11) 0.0384(6) Uani 1 1 d .
F1 F 0.8882(14) 0.3220(13) 0.2867(10) 0.080(4) Uani 1 1 d U
F2 F 0.7197(16) 0.2492(14) 0.1774(12) 0.101(5) Uani 1 1 d U
F3 F 0.7012(15) 0.2755(13) 0.3242(10) 0.092(5) Uani 1 1 d U
F4 F 0.6444(14) 0.0769(12) 0.2397(11) 0.089(5) Uani 1 1 d U
F5 F 0.8313(13) 0.1594(13) 0.3353(11) 0.084(5) Uani 1 1 d U
F6 F 0.8213(16) 0.1423(14) 0.1943(12) 0.109(5) Uani 1 1 d U
F7 F 0.107(2) 0.8192(19) 0.1688(15) 0.142(6) Uani 1 1 d U
F8 F 0.087(2) 0.786(2) 0.3113(16) 0.163(7) Uani 1 1 d U
F9 F -0.013(2) 0.643(2) 0.1883(16) 0.156(7) Uani 1 1 d U
F10 F 0.179(2) 0.6731(18) 0.1619(14) 0.138(6) Uani 1 1 d U
F11 F 0.283(2) 0.835(2) 0.2740(15) 0.158(7) Uani 1 1 d U
F12 F 0.167(2) 0.6619(18) 0.3001(15) 0.133(6) Uani 1 1 d U
N1 N 0.6947(19) 0.8124(16) 0.6966(13) 0.049(4) Uani 1 1 d U
N2 N 0.7779(17) 0.6767(16) 0.6440(12) 0.047(4) Uani 1 1 d U
N3 N 0.1918(19) 0.4300(16) 0.4894(14) 0.046(4) Uani 1 1 d U
N4 N 0.2136(19) 0.4332(16) 0.6288(14) 0.053(4) Uani 1 1 d U
N5 N 0.6203(19) 0.7934(17) 0.8652(14) 0.058(4) Uani 1 1 d U
N6 N 0.4639(17) 0.4126(15) 0.7608(11) 0.055(3) Uani 1 1 d DU
O1 O 0.816(3) 0.5826(18) 0.8453(11) 0.132(10) Uani 1 1 d .
H21 H 0.8734 0.6537 0.8681 0.159 Uiso 1 1 d R
H22 H 0.8383 0.5495 0.8009 0.159 Uiso 1 1 d R
P1 P 0.7655(7) 0.2040(6) 0.2615(6) 0.062(2) Uani 1 1 d U
P2 P 0.1275(10) 0.7349(8) 0.2286(8) 0.100(3) Uani 1 1 d U
C1 C 0.667(2) 0.6859(19) 0.6491(15) 0.048(4) Uani 1 1 d U
C2 C 0.809(2) 0.867(2) 0.7139(16) 0.056(4) Uani 1 1 d U
H2 H 0.8486 0.9508 0.7417 0.067 Uiso 1 1 calc R
C3 C 0.878(2) 0.7908(19) 0.6879(15) 0.053(4) Uani 1 1 d U
H3 H 0.9648 0.8110 0.6972 0.064 Uiso 1 1 calc R
C4 C 0.212(2) 0.433(2) 0.4036(16) 0.052(5) Uani 1 1 d U
H4A H 0.2890 0.5015 0.4109 0.062 Uiso 1 1 calc R
H4B H 0.1430 0.4454 0.3684 0.062 Uiso 1 1 calc R
C5 C 0.286(2) 0.4623(19) 0.5627(17) 0.046(4) Uani 1 1 d U
C6 C 0.078(2) 0.382(2) 0.5017(18) 0.054(4) Uani 1 1 d U
H6 H 0.0033 0.3475 0.4559 0.064 Uiso 1 1 calc R
C7 C 0.084(2) 0.3891(19) 0.5897(17) 0.054(4) Uani 1 1 d U
H7 H 0.0177 0.3697 0.6171 0.065 Uiso 1 1 calc R
C8 C 0.612(2) 0.869(2) 0.7253(16) 0.058(4) Uani 1 1 d U
H8A H 0.5262 0.8166 0.6928 0.069 Uiso 1 1 calc R
H8B H 0.6312 0.9464 0.7110 0.069 Uiso 1 1 calc R
C9 C 0.625(2) 0.891(2) 0.8251(18) 0.056(4) Uani 1 1 d U
C10 C 0.645(2) 1.002(2) 0.8834(18) 0.063(5) Uani 1 1 d U
H10 H 0.6495 1.0673 0.8597 0.076 Uiso 1 1 calc R
C11 C 0.657(2) 1.021(2) 0.9674(19) 0.067(5) Uani 1 1 d U
H11 H 0.6807 1.1011 1.0038 0.081 Uiso 1 1 calc R
C12 C 0.635(2) 0.922(2) 1.0064(19) 0.071(5) Uani 1 1 d U
H12 H 0.6261 0.9303 1.0648 0.085 Uiso 1 1 calc R
C13 C 0.627(2) 0.816(2) 0.9517(19) 0.069(4) Uani 1 1 d U
H13 H 0.6272 0.7529 0.9775 0.083 Uiso 1 1 calc R
C14 C 0.278(2) 0.468(2) 0.7234(17) 0.052(4) Uani 1 1 d U
H14A H 0.2197 0.4719 0.7600 0.062 Uiso 1 1 calc R
H14B H 0.3451 0.5485 0.7402 0.062 Uiso 1 1 calc R
C15 C 0.3349(19) 0.3706(18) 0.7395(11) 0.056(4) Uani 1 1 d DU
C16 C 0.262(2) 0.2514(17) 0.7303(12) 0.063(4) Uani 1 1 d DU
H16 H 0.1751 0.2295 0.7154 0.075 Uiso 1 1 calc R
C17 C 0.307(2) 0.161(2) 0.7415(13) 0.067(5) Uani 1 1 d DU
H17 H 0.2577 0.0800 0.7360 0.080 Uiso 1 1 calc R
C18 C 0.440(2) 0.2086(19) 0.7622(13) 0.067(5) Uani 1 1 d DU
H18 H 0.4790 0.1539 0.7698 0.080 Uiso 1 1 calc R
C19 C 0.519(2) 0.3281(17) 0.7727(12) 0.061(4) Uani 1 1 d DU
H19 H 0.6057 0.3510 0.7873 0.074 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N6 Ag1 N5 139.7(7) . .
N6 Ag1 C1 121.6(6) . .
N5 Ag1 C1 92.0(7) . .
N6 Ag1 O1 98.6(6) . .
N5 Ag1 O1 102.3(6) . .
C1 Ag1 O1 91.5(7) . .
N6 Ag1 Ag2 84.9(4) . .
N5 Ag1 Ag2 110.4(6) . .
C1 Ag1 Ag2 44.3(5) . .
O1 Ag1 Ag2 123.6(4) . .
C5 Ag2 C1 170.2(9) . .
C5 Ag2 Ag1 110.1(7) . .
C1 Ag2 Ag1 62.4(6) . .
C5 Ag2 Ag2 96.3(7) . 2_666
C1 Ag2 Ag2 93.5(6) . 2_666
Ag1 Ag2 Ag2 133.47(15) . 2_666
C2 N1 C8 123.2(19) . .
C2 N1 C1 107.3(19) . .
C8 N1 C1 129.4(19) . .
C1 N2 C3 110.6(18) . .
C1 N2 C4 123(2) . 2_666
C3 N2 C4 126.5(19) . 2_666
C6 N3 C5 114(2) . .
C6 N3 C4 123(2) . .
C5 N3 C4 123(2) . .
C7 N4 C14 128(2) . .
C7 N4 C5 111(2) . .
C14 N4 C5 120(2) . .
C13 N5 C9 118(2) . .
C13 N5 Ag1 119.6(17) . .
C9 N5 Ag1 122.4(16) . .
C15 N6 C19 116.8(19) . .
C15 N6 Ag1 125.0(13) . .
C19 N6 Ag1 118.1(14) . .
Ag1 O1 H21 109.6 . .
Ag1 O1 H22 109.4 . .
H21 O1 H22 104.9 . .
F6 P1 F5 89.3(11) . .
F6 P1 F1 87.8(9) . .
F5 P1 F1 88.9(9) . .
F6 P1 F3 173.7(12) . .
F5 P1 F3 97.0(10) . .
F1 P1 F3 91.5(8) . .
F6 P1 F2 81.1(11) . .
F5 P1 F2 169.1(11) . .
F1 P1 F2 85.6(9) . .
F3 P1 F2 92.6(10) . .
F6 P1 F4 91.0(9) . .
F5 P1 F4 86.8(9) . .
F1 P1 F4 175.6(10) . .
F3 P1 F4 90.1(9) . .
F2 P1 F4 98.4(9) . .
F10 P2 F8 167.2(18) . .
F10 P2 F7 90.7(14) . .
F8 P2 F7 101.6(15) . .
F10 P2 F9 96.0(13) . .
F8 P2 F9 87.3(14) . .
F7 P2 F9 91.4(14) . .
F10 P2 F12 90.5(14) . .
F8 P2 F12 76.9(15) . .
F7 P2 F12 172.0(12) . .
F9 P2 F12 96.3(12) . .
F10 P2 F11 84.0(13) . .
F8 P2 F11 92.5(13) . .
F7 P2 F11 89.4(12) . .
F9 P2 F11 179.2(15) . .
F12 P2 F11 82.9(12) . .
N2 C1 N1 106.4(19) . .
N2 C1 Ag2 134.3(15) . .
N1 C1 Ag2 119.0(15) . .
N2 C1 Ag1 110.9(15) . .
N1 C1 Ag1 92.8(13) . .
Ag2 C1 Ag1 73.3(7) . .
N1 C2 C3 115(2) . .
N1 C2 H2 122.5 . .
C3 C2 H2 122.5 . .
N2 C3 C2 101(2) . .
N2 C3 H3 129.7 . .
C2 C3 H3 129.7 . .
N3 C4 N2 113.0(18) . 2_666
N3 C4 H4A 109.0 . .
N2 C4 H4A 109.0 2_666 .
N3 C4 H4B 109.0 . .
N2 C4 H4B 109.0 2_666 .
H4A C4 H4B 107.8 . .
N3 C5 N4 100(2) . .
N3 C5 Ag2 133.4(19) . .
N4 C5 Ag2 124.8(17) . .
N3 C6 C7 111(2) . .
N3 C6 H6 124.4 . .
C7 C6 H6 124.4 . .
C6 C7 N4 103(2) . .
C6 C7 H7 128.7 . .
N4 C7 H7 128.7 . .
N1 C8 C9 111.8(19) . .
N1 C8 H8A 109.3 . .
C9 C8 H8A 109.3 . .
N1 C8 H8B 109.3 . .
C9 C8 H8B 109.3 . .
H8A C8 H8B 107.9 . .
C10 C9 N5 115(2) . .
C10 C9 C8 125(2) . .
N5 C9 C8 119.9(19) . .
C11 C10 C9 125(3) . .
C11 C10 H10 117.6 . .
C9 C10 H10 117.6 . .
C10 C11 C12 121(3) . .
C10 C11 H11 119.7 . .
C12 C11 H11 119.7 . .
C13 C12 C11 115(3) . .
C13 C12 H12 122.7 . .
C11 C12 H12 122.7 . .
N5 C13 C12 126(3) . .
N5 C13 H13 117.2 . .
C12 C13 H13 117.2 . .
N4 C14 C15 108.7(16) . .
N4 C14 H14A 110.0 . .
C15 C14 H14A 110.0 . .
N4 C14 H14B 110.0 . .
C15 C14 H14B 110.0 . .
H14A C14 H14B 108.3 . .
C16 C15 N6 122(2) . .
C16 C15 C14 123(2) . .
N6 C15 C14 114.6(17) . .
C15 C16 C17 125(2) . .
C15 C16 H16 117.3 . .
C17 C16 H16 117.3 . .
C16 C17 C18 110(2) . .
C16 C17 H17 125.1 . .
C18 C17 H17 125.1 . .
C19 C18 C17 128(2) . .
C19 C18 H18 116.2 . .
C17 C18 H18 116.2 . .
C18 C19 N6 118(2) . .
C18 C19 H19 120.9 . .
N6 C19 H19 120.9 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N6 2.192(18) .
Ag1 N5 2.245(19) .
Ag1 C1 2.70(2) .
Ag1 O1 2.76(2) .
Ag1 Ag2 2.918(6) .
Ag2 C5 2.05(3) .
Ag2 C1 2.13(2) .
Ag2 Ag2 3.294(6) 2_666
F1 P1 1.568(15) .
F2 P1 1.61(2) .
F3 P1 1.605(17) .
F4 P1 1.627(16) .
F5 P1 1.565(17) .
F6 P1 1.517(17) .
F7 P2 1.56(2) .
F8 P2 1.53(2) .
F9 P2 1.57(2) .
F10 P2 1.48(2) .
F11 P2 1.73(2) .
F12 P2 1.66(2) .
N1 C2 1.23(3) .
N1 C8 1.42(3) .
N1 C1 1.45(3) .
N2 C1 1.35(3) .
N2 C3 1.42(3) .
N2 C4 1.42(2) 2_666
N3 C6 1.33(3) .
N3 C5 1.34(3) .
N3 C4 1.42(3) .
N4 C7 1.40(3) .
N4 C14 1.45(3) .
N4 C5 1.48(3) .
N5 C13 1.31(3) .
N5 C9 1.44(3) .
N6 C15 1.369(16) .
N6 C19 1.387(16) .
O1 H21 0.8500 .
O1 H22 0.8500 .
C2 C3 1.44(3) .
C2 H2 0.9300 .
C3 H3 0.9300 .
C4 N2 1.42(2) 2_666
C4 H4A 0.9700 .
C4 H4B 0.9700 .
C6 C7 1.36(3) .
C6 H6 0.9300 .
C7 H7 0.9300 .
C8 C9 1.51(3) .
C8 H8A 0.9700 .
C8 H8B 0.9700 .
C9 C10 1.37(3) .
C10 C11 1.27(3) .
C10 H10 0.9300 .
C11 C12 1.42(3) .
C11 H11 0.9300 .
C12 C13 1.35(3) .
C12 H12 0.9300 .
C13 H13 0.9300 .
C14 C15 1.56(3) .
C14 H14A 0.9700 .
C14 H14B 0.9700 .
C15 C16 1.369(16) .
C16 C17 1.384(16) .
C16 H16 0.9300 .
C17 C18 1.404(17) .
C17 H17 0.9300 .
C18 C19 1.387(17) .
C18 H18 0.9300 .
C19 H19 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N6 Ag1 Ag2 C5 39.4(8) . .
N5 Ag1 Ag2 C5 -102.2(8) . .
C1 Ag1 Ag2 C5 -173.1(9) . .
O1 Ag1 Ag2 C5 136.4(8) . .
N6 Ag1 Ag2 C1 -147.5(8) . .
N5 Ag1 Ag2 C1 70.9(8) . .
O1 Ag1 Ag2 C1 -50.5(8) . .
N6 Ag1 Ag2 Ag2 -81.1(5) . 2_666
N5 Ag1 Ag2 Ag2 137.3(5) . 2_666
C1 Ag1 Ag2 Ag2 66.4(6) . 2_666
O1 Ag1 Ag2 Ag2 15.9(6) . 2_666
N6 Ag1 N5 C13 49(2) . .
C1 Ag1 N5 C13 -162.8(19) . .
O1 Ag1 N5 C13 -70.8(19) . .
Ag2 Ag1 N5 C13 155.9(17) . .
N6 Ag1 N5 C9 -126.9(17) . .
C1 Ag1 N5 C9 21.4(18) . .
O1 Ag1 N5 C9 113.4(17) . .
Ag2 Ag1 N5 C9 -19.9(18) . .
N5 Ag1 N6 C15 50.8(15) . .
C1 Ag1 N6 C15 -91.2(11) . .
O1 Ag1 N6 C15 171.7(9) . .
Ag2 Ag1 N6 C15 -65.1(9) . .
N5 Ag1 N6 C19 -125.8(13) . .
C1 Ag1 N6 C19 92.2(11) . .
O1 Ag1 N6 C19 -4.9(10) . .
Ag2 Ag1 N6 C19 118.3(9) . .
C3 N2 C1 N1 1(3) . .
C4 N2 C1 N1 -175.6(19) 2_666 .
C3 N2 C1 Ag2 175.0(19) . .
C4 N2 C1 Ag2 -2(4) 2_666 .
C3 N2 C1 Ag1 -98.3(18) . .
C4 N2 C1 Ag1 85(2) 2_666 .
C2 N1 C1 N2 1(3) . .
C8 N1 C1 N2 -175(2) . .
C2 N1 C1 Ag2 -173.5(17) . .
C8 N1 C1 Ag2 10(3) . .
C2 N1 C1 Ag1 114.0(18) . .
C8 N1 C1 Ag1 -62(2) . .
C5 Ag2 C1 N2 145(5) . .
Ag1 Ag2 C1 N2 103(2) . .
Ag2 Ag2 C1 N2 -35(2) 2_666 .
C5 Ag2 C1 N1 -42(6) . .
Ag1 Ag2 C1 N1 -83.9(16) . .
Ag2 Ag2 C1 N1 137.9(16) 2_666 .
C5 Ag2 C1 Ag1 42(5) . .
Ag2 Ag2 C1 Ag1 -138.2(3) 2_666 .
N6 Ag1 C1 N2 -92.9(16) . .
N5 Ag1 C1 N2 110.6(16) . .
O1 Ag1 C1 N2 8.2(15) . .
Ag2 Ag1 C1 N2 -131.8(17) . .
N6 Ag1 C1 N1 158.4(12) . .
N5 Ag1 C1 N1 1.9(14) . .
O1 Ag1 C1 N1 -100.5(13) . .
Ag2 Ag1 C1 N1 119.5(15) . .
N6 Ag1 C1 Ag2 38.9(9) . .
N5 Ag1 C1 Ag2 -117.6(7) . .
O1 Ag1 C1 Ag2 140.0(6) . .
C8 N1 C2 C3 173(2) . .
C1 N1 C2 C3 -3(3) . .
C1 N2 C3 C2 -3(2) . .
C4 N2 C3 C2 174(2) 2_666 .
N1 C2 C3 N2 4(3) . .
C6 N3 C4 N2 -86(3) . 2_666
C5 N3 C4 N2 86(2) . 2_666
C6 N3 C5 N4 -3(2) . .
C4 N3 C5 N4 -175.6(17) . .
C6 N3 C5 Ag2 -167.7(17) . .
C4 N3 C5 Ag2 20(3) . .
C7 N4 C5 N3 -1(2) . .
C14 N4 C5 N3 -172.4(16) . .
C7 N4 C5 Ag2 165.1(15) . .
C14 N4 C5 Ag2 -6(3) . .
C1 Ag2 C5 N3 134(5) . .
Ag1 Ag2 C5 N3 172.6(19) . .
Ag2 Ag2 C5 N3 -46(2) 2_666 .
C1 Ag2 C5 N4 -28(6) . .
Ag1 Ag2 C5 N4 11.2(18) . .
Ag2 Ag2 C5 N4 152.2(16) 2_666 .
C5 N3 C6 C7 7(3) . .
C4 N3 C6 C7 179.2(18) . .
N3 C6 C7 N4 -7(2) . .
C14 N4 C7 C6 175.1(19) . .
C5 N4 C7 C6 5(2) . .
C2 N1 C8 C9 -73(3) . .
C1 N1 C8 C9 103(3) . .
C13 N5 C9 C10 4(3) . .
Ag1 N5 C9 C10 179.8(17) . .
C13 N5 C9 C8 -178(2) . .
Ag1 N5 C9 C8 -2(3) . .
N1 C8 C9 C10 128(3) . .
N1 C8 C9 N5 -50(3) . .
N5 C9 C10 C11 -1(4) . .
C8 C9 C10 C11 -179(2) . .
C9 C10 C11 C12 -8(4) . .
C10 C11 C12 C13 13(4) . .
C9 N5 C13 C12 2(4) . .
Ag1 N5 C13 C12 -174(2) . .
C11 C12 C13 N5 -11(4) . .
C7 N4 C14 C15 109(2) . .
C5 N4 C14 C15 -81(2) . .
C19 N6 C15 C16 0.1(5) . .
Ag1 N6 C15 C16 -176.6(12) . .
C19 N6 C15 C14 -177.8(16) . .
Ag1 N6 C15 C14 5.5(16) . .
N4 C14 C15 C16 -66(2) . .
N4 C14 C15 N6 111.6(16) . .
N6 C15 C16 C17 0.4(6) . .
C14 C15 C16 C17 178.2(18) . .
C15 C16 C17 C18 -1.0(11) . .
C16 C17 C18 C19 1.2(16) . .
C17 C18 C19 N6 -0.8(17) . .
C15 N6 C19 C18 0.1(11) . .
Ag1 N6 C19 C18 177.0(12) . .
