#------------------------------------------------------------------------------
#$Date: 2016-03-21 09:18:06 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178621 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/32/4073250.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4073250
loop_
_publ_author_name
'Liu, Bin'
'Chen, Wanzhi'
'Jin, Shouwen'
_publ_section_title
;
 Synthesis, Structural Characterization, and Luminescence of New Silver
 Aggregates Containing Short Ag−Ag Contacts Stabilized by
 Functionalized Bis(N-heterocyclic carbene) Ligands
;
_journal_issue                   15
_journal_name_full               Organometallics
_journal_page_first              3660
_journal_paper_doi               10.1021/om0701928
_journal_volume                  26
_journal_year                    2007
_chemical_formula_sum            'C56 H59 Ag4 F24 N15 O P4'
_chemical_formula_weight         1969.54
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 96.041(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   12.2810(18)
_cell_length_b                   21.320(3)
_cell_length_c                   15.260(3)
_cell_measurement_reflns_used    6060
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      27.22
_cell_measurement_theta_min      2.248
_cell_volume                     3973.4(11)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0388
_diffrn_reflns_av_sigmaI/netI    0.0500
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            20318
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.65
_exptl_absorpt_coefficient_mu    1.154
_exptl_absorpt_correction_T_max  0.7937
_exptl_absorpt_correction_T_min  0.6074
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.646
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1944
_exptl_crystal_size_max          0.48
_exptl_crystal_size_mid          0.42
_exptl_crystal_size_min          0.21
_refine_diff_density_max         1.487
_refine_diff_density_min         -0.638
_refine_diff_density_rms         0.140
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.065
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     508
_refine_ls_number_reflns         6991
_refine_ls_number_restraints     104
_refine_ls_restrained_S_all      1.062
_refine_ls_R_factor_all          0.1087
_refine_ls_R_factor_gt           0.0584
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1288P)²+20.3021P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1659
_refine_ls_wR_factor_ref         0.2417
_reflns_number_gt                4397
_reflns_number_total             6991
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om0701928-file001.cif
_cod_data_source_block           070116e
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        3973.4(10)
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               4073250
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.58236(5) 0.55737(3) 0.61331(4) 0.0374(2) Uani 1 1 d .
Ag2 Ag 0.52378(6) 0.55717(3) 0.43201(5) 0.0450(3) Uani 1 1 d .
F1 F 0.0879(7) 0.5735(4) 0.4778(8) 0.119(3) Uani 1 1 d .
F2 F 0.2379(8) 0.6901(5) 0.4770(12) 0.183(7) Uani 1 1 d .
F3 F 0.2693(6) 0.5884(4) 0.4807(6) 0.101(3) Uani 1 1 d .
F4 F 0.1726(9) 0.6328(6) 0.5800(7) 0.143(4) Uani 1 1 d .
F5 F 0.0593(6) 0.6744(5) 0.4752(8) 0.126(4) Uani 1 1 d .
F6 F 0.1578(9) 0.6301(7) 0.3765(7) 0.161(5) Uani 1 1 d .
F7 F 0.8520(9) 0.3558(4) 0.0754(6) 0.123(4) Uani 1 1 d .
F8 F 0.7695(10) 0.4596(5) -0.0587(7) 0.148(5) Uani 1 1 d .
F9 F 0.9245(8) 0.4377(7) 0.0188(8) 0.166(6) Uani 1 1 d .
F10 F 0.7848(11) 0.4476(5) 0.0889(7) 0.143(4) Uani 1 1 d .
F11 F 0.6983(8) 0.3763(6) -0.0056(8) 0.150(5) Uani 1 1 d .
F12 F 0.8360(11) 0.3640(6) -0.0698(7) 0.161(5) Uani 1 1 d .
N1 N 0.5114(7) 0.6387(4) 0.7030(6) 0.054(2) Uani 1 1 d .
N2 N 0.6237(6) 0.6808(3) 0.5010(5) 0.0412(18) Uani 1 1 d .
N3 N 0.7538(6) 0.6151(3) 0.5113(5) 0.0391(17) Uani 1 1 d .
N4 N 0.7673(7) 0.5564(4) 0.6834(5) 0.048(2) Uani 1 1 d .
N5 N 0.4287(6) 0.5154(4) 0.7424(5) 0.0442(19) Uani 1 1 d .
N6 N 0.5611(6) 0.4512(3) 0.7589(5) 0.0377(17) Uani 1 1 d .
N7 N 0.5658(6) 0.3457(4) 0.6312(5) 0.0423(18) Uani 1 1 d .
N8 N 0.193(2) 0.4409(14) 0.6913(19) 0.116(8) Uani 0.50 1 d PDU
P1 P 0.1638(3) 0.63172(16) 0.4783(3) 0.0717(10) Uani 1 1 d .
P2 P 0.8118(3) 0.40884(15) 0.0082(2) 0.0613(8) Uani 1 1 d .
O1 O 0.339(2) 0.3427(11) 0.9010(12) 0.120(5) Uani 0.50 1 d PDU
C1 C 0.5663(11) 0.6923(5) 0.7248(8) 0.067(3) Uani 1 1 d .
H1 H 0.6317 0.6996 0.7008 0.081 Uiso 1 1 calc R
C2 C 0.5309(15) 0.7364(6) 0.7802(10) 0.095(5) Uani 1 1 d .
H2 H 0.5726 0.7716 0.7969 0.115 Uiso 1 1 calc R
C3 C 0.4335(17) 0.7265(8) 0.8093(12) 0.119(6) Uani 1 1 d .
H3 H 0.4055 0.7567 0.8447 0.143 Uiso 1 1 calc R
C4 C 0.3736(12) 0.6735(6) 0.7889(9) 0.085(4) Uani 1 1 d .
H4 H 0.3064 0.6670 0.8105 0.102 Uiso 1 1 calc R
C5 C 0.4164(9) 0.6300(5) 0.7349(7) 0.051(2) Uani 1 1 d .
C6 C 0.5143(8) 0.7098(5) 0.4956(7) 0.048(2) Uani 1 1 d .
H6A H 0.5211 0.7525 0.5171 0.058 Uiso 1 1 calc R
H6B H 0.4692 0.6868 0.5332 0.058 Uiso 1 1 calc R
C7 C 0.6455(7) 0.6189(4) 0.5132(6) 0.036(2) Uani 1 1 d .
C8 C 0.7980(9) 0.6736(5) 0.5003(7) 0.057(3) Uani 1 1 d .
H8 H 0.8717 0.6829 0.4983 0.068 Uiso 1 1 calc R
C9 C 0.7171(9) 0.7138(5) 0.4931(7) 0.057(3) Uani 1 1 d .
H9 H 0.7223 0.7568 0.4843 0.068 Uiso 1 1 calc R
C10 C 0.8188(8) 0.5588(5) 0.5358(7) 0.046(2) Uani 1 1 d .
H10A H 0.8842 0.5586 0.5054 0.055 Uiso 1 1 calc R
H10B H 0.7764 0.5216 0.5184 0.055 Uiso 1 1 calc R
C11 C 0.8500(7) 0.5581(4) 0.6333(6) 0.040(2) Uani 1 1 d .
C12 C 0.9582(8) 0.5607(6) 0.6697(8) 0.065(3) Uani 1 1 d .
H12 H 1.0146 0.5627 0.6337 0.078 Uiso 1 1 calc R
C13 C 0.9810(10) 0.5603(6) 0.7598(9) 0.076(4) Uani 1 1 d .
H13 H 1.0531 0.5613 0.7853 0.091 Uiso 1 1 calc R
C14 C 0.8967(11) 0.5585(5) 0.8115(8) 0.067(3) Uani 1 1 d .
H14 H 0.9101 0.5590 0.8726 0.080 Uiso 1 1 calc R
C15 C 0.7922(9) 0.5559(5) 0.7707(7) 0.056(3) Uani 1 1 d .
H15 H 0.7349 0.5535 0.8059 0.068 Uiso 1 1 calc R
C16 C 0.3603(8) 0.5679(5) 0.7103(8) 0.052(3) Uani 1 1 d .
H16A H 0.2910 0.5660 0.7354 0.062 Uiso 1 1 calc R
H16B H 0.3452 0.5652 0.6467 0.062 Uiso 1 1 calc R
C17 C 0.5081(7) 0.4910(4) 0.7005(6) 0.0355(19) Uani 1 1 d .
C18 C 0.5185(9) 0.4534(5) 0.8383(7) 0.057(3) Uani 1 1 d .
H18 H 0.5438 0.4319 0.8895 0.069 Uiso 1 1 calc R
C19 C 0.4335(10) 0.4926(5) 0.8275(7) 0.062(3) Uani 1 1 d .
H19 H 0.3863 0.5027 0.8693 0.075 Uiso 1 1 calc R
C20 C 0.6572(8) 0.4132(4) 0.7433(7) 0.046(2) Uani 1 1 d .
H20A H 0.7055 0.4096 0.7976 0.055 Uiso 1 1 calc R
H20B H 0.6972 0.4338 0.6999 0.055 Uiso 1 1 calc R
C21 C 0.6229(7) 0.3490(4) 0.7111(6) 0.043(2) Uani 1 1 d .
C22 C 0.6550(9) 0.2956(5) 0.7600(8) 0.061(3) Uani 1 1 d .
H22 H 0.6944 0.2986 0.8154 0.073 Uiso 1 1 calc R
C23 C 0.6260(10) 0.2388(6) 0.7231(9) 0.073(4) Uani 1 1 d .
H23 H 0.6444 0.2021 0.7541 0.088 Uiso 1 1 calc R
C24 C 0.5700(9) 0.2357(5) 0.6409(8) 0.065(3) Uani 1 1 d .
H24 H 0.5519 0.1971 0.6149 0.078 Uiso 1 1 calc R
C25 C 0.5412(7) 0.2900(5) 0.5981(7) 0.047(2) Uani 1 1 d .
C26 C 0.134(3) 0.4243(15) 0.739(2) 0.098(7) Uani 0.50 1 d PDU
C27 C 0.074(3) 0.4059(15) 0.813(2) 0.109(8) Uani 0.50 1 d PDU
H27A H 0.1246 0.3911 0.8605 0.164 Uiso 0.50 1 calc PR
H27B H 0.0229 0.3732 0.7944 0.164 Uiso 0.50 1 calc PR
H27C H 0.0348 0.4415 0.8322 0.164 Uiso 0.50 1 calc PR
C28 C 0.366(3) 0.2905(13) 0.8499(18) 0.126(7) Uani 0.50 1 d PDU
H28A H 0.3245 0.2541 0.8648 0.151 Uiso 0.50 1 calc PR
H28B H 0.4436 0.2807 0.8630 0.151 Uiso 0.50 1 calc PR
C29 C 0.342(2) 0.3049(16) 0.7538(15) 0.106(7) Uani 0.50 1 d PDU
H29A H 0.2768 0.2830 0.7307 0.159 Uiso 0.50 1 calc PR
H29B H 0.4023 0.2917 0.7231 0.159 Uiso 0.50 1 calc PR
H29C H 0.3311 0.3492 0.7461 0.159 Uiso 0.50 1 calc PR
C30 C 0.318(3) 0.3455(18) 0.9911(17) 0.140(8) Uani 0.50 1 d PDU
H30A H 0.3248 0.3039 1.0168 0.168 Uiso 0.50 1 calc PR
H30B H 0.2428 0.3595 0.9942 0.168 Uiso 0.50 1 calc PR
C31 C 0.394(3) 0.3891(17) 1.0429(17) 0.138(10) Uani 0.50 1 d PDU
H31A H 0.4662 0.3843 1.0251 0.206 Uiso 0.50 1 calc PR
H31B H 0.3953 0.3796 1.1045 0.206 Uiso 0.50 1 calc PR
H31C H 0.3698 0.4315 1.0325 0.206 Uiso 0.50 1 calc PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C17 Ag1 C7 173.5(3) . .
C17 Ag1 N4 99.0(3) . .
C7 Ag1 N4 85.9(3) . .
C17 Ag1 N1 85.6(3) . .
C7 Ag1 N1 97.9(3) . .
N4 Ag1 N1 97.7(3) . .
C17 Ag1 Ag2 121.2(2) . .
C7 Ag1 Ag2 52.3(2) . .
N4 Ag1 Ag2 125.1(2) . .
N1 Ag1 Ag2 119.4(2) . .
C17 Ag1 Ag2 51.8(2) . 3_666
C7 Ag1 Ag2 122.0(2) . 3_666
N4 Ag1 Ag2 119.48(19) . 3_666
N1 Ag1 Ag2 124.9(2) . 3_666
Ag2 Ag1 Ag2 71.97(3) . 3_666
C7 Ag2 C17 142.7(3) . 3_666
C7 Ag2 N7 88.1(3) . 3_666
C17 Ag2 N7 90.1(3) 3_666 3_666
C7 Ag2 Ag1 50.8(2) . .
C17 Ag2 Ag1 152.9(2) 3_666 .
N7 Ag2 Ag1 116.17(18) 3_666 .
C7 Ag2 Ag1 154.2(2) . 3_666
C17 Ag2 Ag1 50.0(2) 3_666 3_666
N7 Ag2 Ag1 116.81(17) 3_666 3_666
Ag1 Ag2 Ag1 108.03(3) . 3_666
C7 Ag2 Ag2 103.7(2) . 3_666
C17 Ag2 Ag2 101.6(2) 3_666 3_666
N7 Ag2 Ag2 139.39(19) 3_666 3_666
Ag1 Ag2 Ag2 54.51(2) . 3_666
Ag1 Ag2 Ag2 53.52(2) 3_666 3_666
C5 N1 C1 117.7(10) . .
C5 N1 Ag1 119.3(7) . .
C1 N1 Ag1 123.0(8) . .
C7 N2 C9 111.1(8) . .
C7 N2 C6 125.6(7) . .
C9 N2 C6 123.4(8) . .
C7 N3 C8 110.7(8) . .
C7 N3 C10 124.1(7) . .
C8 N3 C10 124.1(8) . .
C11 N4 C15 117.6(8) . .
C11 N4 Ag1 119.0(6) . .
C15 N4 Ag1 123.4(7) . .
C17 N5 C19 110.7(8) . .
C17 N5 C16 124.6(8) . .
C19 N5 C16 123.6(9) . .
C17 N6 C18 111.1(8) . .
C17 N6 C20 125.4(8) . .
C18 N6 C20 123.3(8) . .
C25 N7 C21 118.3(8) . .
C25 N7 Ag2 121.9(6) . 3_666
C21 N7 Ag2 118.4(6) . 3_666
F2 P1 F4 91.3(8) . .
F2 P1 F6 88.3(8) . .
F4 P1 F6 178.7(6) . .
F2 P1 F1 178.8(8) . .
F4 P1 F1 89.7(7) . .
F6 P1 F1 90.7(8) . .
F2 P1 F5 90.7(5) . .
F4 P1 F5 89.6(6) . .
F6 P1 F5 91.7(6) . .
F1 P1 F5 88.6(5) . .
F2 P1 F3 89.4(5) . .
F4 P1 F3 90.9(6) . .
F6 P1 F3 87.8(6) . .
F1 P1 F3 91.3(5) . .
F5 P1 F3 179.5(7) . .
F9 P2 F8 91.5(7) . .
F9 P2 F10 88.1(8) . .
F8 P2 F10 93.8(7) . .
F9 P2 F11 176.9(8) . .
F8 P2 F11 89.4(6) . .
F10 P2 F11 94.7(8) . .
F9 P2 F7 90.1(6) . .
F8 P2 F7 178.3(6) . .
F10 P2 F7 86.8(6) . .
F11 P2 F7 89.0(6) . .
F9 P2 F12 94.9(8) . .
F8 P2 F12 90.1(7) . .
F10 P2 F12 175.0(7) . .
F11 P2 F12 82.2(7) . .
F7 P2 F12 89.2(6) . .
C28 O1 C30 130(3) . .
N1 C1 C2 123.5(12) . .
N1 C1 H1 118.2 . .
C2 C1 H1 118.2 . .
C3 C2 C1 116.9(13) . .
C3 C2 H2 121.6 . .
C1 C2 H2 121.6 . .
C2 C3 C4 122.3(14) . .
C2 C3 H3 118.9 . .
C4 C3 H3 118.9 . .
C3 C4 C5 117.5(13) . .
C3 C4 H4 121.2 . .
C5 C4 H4 121.2 . .
N1 C5 C4 122.0(11) . .
N1 C5 C16 115.2(9) . .
C4 C5 C16 122.7(11) . .
N2 C6 C25 111.7(8) . 3_666
N2 C6 H6A 109.3 . .
C25 C6 H6A 109.3 3_666 .
N2 C6 H6B 109.3 . .
C25 C6 H6B 109.3 3_666 .
H6A C6 H6B 107.9 . .
N3 C7 N2 103.8(7) . .
N3 C7 Ag1 113.6(6) . .
N2 C7 Ag1 126.4(7) . .
N3 C7 Ag2 123.7(6) . .
N2 C7 Ag2 112.5(6) . .
Ag1 C7 Ag2 76.9(3) . .
C9 C8 N3 107.3(9) . .
C9 C8 H8 126.4 . .
N3 C8 H8 126.4 . .
C8 C9 N2 107.1(9) . .
C8 C9 H9 126.4 . .
N2 C9 H9 126.4 . .
N3 C10 C11 109.7(8) . .
N3 C10 H10A 109.7 . .
C11 C10 H10A 109.7 . .
N3 C10 H10B 109.7 . .
C11 C10 H10B 109.7 . .
H10A C10 H10B 108.2 . .
N4 C11 C12 121.8(9) . .
N4 C11 C10 116.0(8) . .
C12 C11 C10 122.2(9) . .
C13 C12 C11 119.1(11) . .
C13 C12 H12 120.4 . .
C11 C12 H12 120.4 . .
C14 C13 C12 119.4(11) . .
C14 C13 H13 120.3 . .
C12 C13 H13 120.3 . .
C13 C14 C15 118.0(12) . .
C13 C14 H14 121.0 . .
C15 C14 H14 121.0 . .
N4 C15 C14 124.0(11) . .
N4 C15 H15 118.0 . .
C14 C15 H15 118.0 . .
N5 C16 C5 110.8(8) . .
N5 C16 H16A 109.5 . .
C5 C16 H16A 109.5 . .
N5 C16 H16B 109.5 . .
C5 C16 H16B 109.5 . .
H16A C16 H16B 108.1 . .
N5 C17 N6 104.9(7) . .
N5 C17 Ag1 114.2(6) . .
N6 C17 Ag1 127.0(6) . .
N5 C17 Ag2 122.8(6) . 3_666
N6 C17 Ag2 109.4(6) . 3_666
Ag1 C17 Ag2 78.2(3) . 3_666
C19 C18 N6 106.2(9) . .
C19 C18 H18 126.9 . .
N6 C18 H18 126.9 . .
C18 C19 N5 107.0(10) . .
C18 C19 H19 126.5 . .
N5 C19 H19 126.5 . .
N6 C20 C21 110.7(8) . .
N6 C20 H20A 109.5 . .
C21 C20 H20A 109.5 . .
N6 C20 H20B 109.5 . .
C21 C20 H20B 109.5 . .
H20A C20 H20B 108.1 . .
N7 C21 C22 122.3(9) . .
N7 C21 C20 116.6(8) . .
C22 C21 C20 121.0(9) . .
C23 C22 C21 117.1(10) . .
C23 C22 H22 121.5 . .
C21 C22 H22 121.5 . .
C22 C23 C24 120.4(10) . .
C22 C23 H23 119.8 . .
C24 C23 H23 119.8 . .
C25 C24 C23 118.7(10) . .
C25 C24 H24 120.7 . .
C23 C24 H24 120.7 . .
N7 C25 C24 123.2(9) . .
N7 C25 C6 115.0(8) . 3_666
C24 C25 C6 121.6(9) . 3_666
N8 C26 C27 170(4) . .
C26 C27 H27A 109.5 . .
C26 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
C26 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
O1 C28 C29 110.0(17) . .
O1 C28 H28A 109.7 . .
C29 C28 H28A 109.7 . .
O1 C28 H28B 109.7 . .
C29 C28 H28B 109.7 . .
H28A C28 H28B 108.2 . .
C28 C29 H29A 109.5 . .
C28 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
C28 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
O1 C30 C31 111.5(18) . .
O1 C30 H30A 109.3 . .
C31 C30 H30A 109.3 . .
O1 C30 H30B 109.3 . .
C31 C30 H30B 109.3 . .
H30A C30 H30B 108.0 . .
C30 C31 H31A 109.5 . .
C30 C31 H31B 109.5 . .
H31A C31 H31B 109.5 . .
C30 C31 H31C 109.5 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C17 2.205(8) .
Ag1 C7 2.215(9) .
Ag1 N4 2.406(8) .
Ag1 N1 2.427(8) .
Ag1 Ag2 2.7844(10) .
Ag1 Ag2 2.8198(10) 3_666
Ag2 C7 2.261(8) .
Ag2 C17 2.265(9) 3_666
Ag2 N7 2.491(8) 3_666
Ag2 Ag1 2.8198(10) 3_666
Ag2 Ag2 3.2930(15) 3_666
F1 P1 1.553(9) .
F2 P1 1.543(10) .
F3 P1 1.588(8) .
F4 P1 1.545(10) .
F5 P1 1.570(8) .
F6 P1 1.548(11) .
F7 P2 1.570(8) .
F8 P2 1.539(9) .
F9 P2 1.508(9) .
F10 P2 1.549(10) .
F11 P2 1.552(9) .
F12 P2 1.578(10) .
N1 C5 1.323(13) .
N1 C1 1.351(13) .
N2 C7 1.354(11) .
N2 C9 1.361(12) .
N2 C6 1.473(12) .
N3 C7 1.336(11) .
N3 C8 1.378(12) .
N3 C10 1.467(11) .
N4 C11 1.335(13) .
N4 C15 1.335(13) .
N5 C17 1.328(11) .
N5 C19 1.382(13) .
N5 C16 1.453(12) .
N6 C17 1.346(10) .
N6 C18 1.370(13) .
N6 C20 1.472(12) .
N7 C25 1.313(12) .
N7 C21 1.342(11) .
N7 Ag2 2.491(8) 3_666
N8 C26 1.128(18) .
O1 C28 1.421(18) .
O1 C30 1.429(18) .
C1 C2 1.365(17) .
C1 H1 0.9300 .
C2 C3 1.34(2) .
C2 H2 0.9300 .
C3 C4 1.37(2) .
C3 H3 0.9300 .
C4 C5 1.382(15) .
C4 H4 0.9300 .
C5 C16 1.521(14) .
C6 C25 1.518(14) 3_666
C6 H6A 0.9700 .
C6 H6B 0.9700 .
C8 C9 1.307(15) .
C8 H8 0.9300 .
C9 H9 0.9300 .
C10 C11 1.497(13) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C11 C12 1.387(14) .
C12 C13 1.373(18) .
C12 H12 0.9300 .
C13 C14 1.367(19) .
C13 H13 0.9300 .
C14 C15 1.368(15) .
C14 H14 0.9300 .
C15 H15 0.9300 .
C16 H16A 0.9700 .
C16 H16B 0.9700 .
C17 Ag2 2.265(9) 3_666
C18 C19 1.334(15) .
C18 H18 0.9300 .
C19 H19 0.9300 .
C20 C21 1.499(13) .
C20 H20A 0.9700 .
C20 H20B 0.9700 .
C21 C22 1.395(14) .
C22 C23 1.366(16) .
C22 H22 0.9300 .
C23 C24 1.367(16) .
C23 H23 0.9300 .
C24 C25 1.359(14) .
C24 H24 0.9300 .
C25 C6 1.518(14) 3_666
C26 C27 1.469(19) .
C27 H27A 0.9600 .
C27 H27B 0.9600 .
C27 H27C 0.9600 .
C28 C29 1.498(18) .
C28 H28A 0.9700 .
C28 H28B 0.9700 .
C29 H29A 0.9600 .
C29 H29B 0.9600 .
C29 H29C 0.9600 .
C30 C31 1.487(19) .
C30 H30A 0.9700 .
C30 H30B 0.9700 .
C31 H31A 0.9600 .
C31 H31B 0.9600 .
C31 H31C 0.9600 .
