#------------------------------------------------------------------------------
#$Date: 2016-03-21 09:25:51 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178623 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/34/4073499.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4073499
loop_
_publ_author_name
'Cai, Shuyi'
'Jin, Guo-Xin'
_publ_section_title
;
 Trinuclear Rh2M Complexes (M = Ni, Pd) Bridged by Butyl Selenolato and
 Carborane Diselenolato Ligands
;
_journal_issue                   22
_journal_name_full               Organometallics
_journal_page_first              5442
_journal_paper_doi               10.1021/om7004035
_journal_volume                  26
_journal_year                    2007
_chemical_formula_sum            'C33 H70 B20 Cl2 Pd Rh2 Se6'
_chemical_formula_weight         1539.97
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 101.274(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.421(3)
_cell_length_b                   21.371(7)
_cell_length_c                   24.034(6)
_cell_measurement_reflns_used    616
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      20.365
_cell_measurement_theta_min      2.444
_cell_volume                     5753(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0710
_diffrn_reflns_av_sigmaI/netI    0.1712
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            10934
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.73
_diffrn_standards_decay_%        4.16
_exptl_absorpt_coefficient_mu    4.791
_exptl_absorpt_correction_T_max  0.7005
_exptl_absorpt_correction_T_min  0.6458
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_density_diffrn    1.778
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2968
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.730
_refine_diff_density_min         -0.406
_refine_diff_density_rms         0.089
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.639
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     306
_refine_ls_number_reflns         5080
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.639
_refine_ls_R_factor_all          0.1219
_refine_ls_R_factor_gt           0.0384
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0135P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0564
_refine_ls_wR_factor_ref         0.0665
_reflns_number_gt                1987
_reflns_number_total             5080
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om7004035-file004.cif
_cod_data_source_block           f51219c
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               4073499
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x, -y, z+1/2'
'x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z+1/2'
'-x, -y, -z'
'-x, y, -z-1/2'
'-x+1/2, -y+1/2, -z'
'-x+1/2, y+1/2, -z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pd1 Pd 1.0000 0.17258(4) 0.2500 0.0451(3) Uani 1 2 d S
Rh1 Rh 1.03586(5) 0.18010(3) 0.10185(2) 0.04641(19) Uani 1 1 d .
Se1 Se 1.01856(7) 0.09869(4) 0.17266(3) 0.0447(2) Uani 1 1 d .
Se2 Se 0.81793(7) 0.18190(5) 0.06792(3) 0.0681(3) Uani 1 1 d .
Se3 Se 1.03120(8) 0.25089(4) 0.18221(3) 0.0616(3) Uani 1 1 d .
C1 C 0.8563(7) 0.0667(3) 0.1477(3) 0.050(2) Uani 1 1 d .
C2 C 0.7654(7) 0.1041(4) 0.0983(3) 0.054(2) Uani 1 1 d .
C3 C 0.8858(8) 0.2981(4) 0.1722(3) 0.088(3) Uani 1 1 d .
H3A H 0.8185 0.2706 0.1592 0.106 Uiso 1 1 calc R
H3B H 0.8769 0.3159 0.2083 0.106 Uiso 1 1 calc R
C4 C 0.8860(10) 0.3499(5) 0.1296(4) 0.121(4) Uani 1 1 d .
H4A H 0.9638 0.3698 0.1370 0.145 Uiso 1 1 calc R
H4B H 0.8740 0.3317 0.0920 0.145 Uiso 1 1 calc R
C5 C 0.7964(10) 0.3970(5) 0.1303(4) 0.124(4) Uani 1 1 d .
H5A H 0.7191 0.3765 0.1250 0.148 Uiso 1 1 calc R
H5B H 0.7954 0.4246 0.0982 0.148 Uiso 1 1 calc R
C6 C 0.8113(10) 0.4355(4) 0.1823(4) 0.143(5) Uani 1 1 d .
H6A H 0.7972 0.4102 0.2134 0.214 Uiso 1 1 calc R
H6B H 0.7554 0.4695 0.1764 0.214 Uiso 1 1 calc R
H6C H 0.8911 0.4518 0.1910 0.214 Uiso 1 1 calc R
C7 C 1.2219(7) 0.1738(6) 0.0997(3) 0.067(3) Uani 1 1 d .
C8 C 1.1653(9) 0.1275(5) 0.0614(4) 0.070(3) Uani 1 1 d .
C9 C 1.0832(8) 0.1571(5) 0.0193(4) 0.066(3) Uani 1 1 d .
C10 C 1.0919(9) 0.2230(5) 0.0296(4) 0.069(3) Uani 1 1 d .
C11 C 1.1827(10) 0.2323(5) 0.0773(5) 0.075(3) Uani 1 1 d .
C12 C 1.3233(7) 0.1600(5) 0.1507(4) 0.142(5) Uani 1 1 d .
H12A H 1.3982 0.1726 0.1418 0.214 Uiso 1 1 calc R
H12B H 1.3253 0.1159 0.1588 0.214 Uiso 1 1 calc R
H12C H 1.3096 0.1827 0.1832 0.214 Uiso 1 1 calc R
C13 C 1.1867(8) 0.0579(4) 0.0674(4) 0.118(4) Uani 1 1 d .
H13A H 1.1219 0.0360 0.0440 0.177 Uiso 1 1 calc R
H13B H 1.1918 0.0459 0.1063 0.177 Uiso 1 1 calc R
H13C H 1.2601 0.0476 0.0557 0.177 Uiso 1 1 calc R
C14 C 1.0038(8) 0.1288(5) -0.0306(3) 0.143(5) Uani 1 1 d .
H14A H 0.9734 0.0897 -0.0199 0.215 Uiso 1 1 calc R
H14B H 1.0482 0.1218 -0.0601 0.215 Uiso 1 1 calc R
H14C H 0.9385 0.1567 -0.0442 0.215 Uiso 1 1 calc R
C15 C 1.0324(9) 0.2750(5) -0.0064(4) 0.157(6) Uani 1 1 d .
H15A H 0.9751 0.2948 0.0122 0.236 Uiso 1 1 calc R
H15B H 0.9926 0.2587 -0.0424 0.236 Uiso 1 1 calc R
H15C H 1.0911 0.3051 -0.0123 0.236 Uiso 1 1 calc R
C16 C 1.2355(9) 0.2930(4) 0.1021(4) 0.150(5) Uani 1 1 d .
H16A H 1.2480 0.2911 0.1427 0.225 Uiso 1 1 calc R
H16B H 1.1818 0.3267 0.0886 0.225 Uiso 1 1 calc R
H16C H 1.3105 0.3000 0.0907 0.225 Uiso 1 1 calc R
B3 B 0.7415(8) 0.1054(5) 0.1668(4) 0.062(3) Uani 1 1 d .
H3 H 0.7510 0.1471 0.1941 0.075 Uiso 1 1 calc R
B4 B 0.7820(9) 0.0292(5) 0.1935(4) 0.066(3) Uani 1 1 d .
H4 H 0.8174 0.0211 0.2389 0.079 Uiso 1 1 calc R
B5 B 0.8380(10) -0.0131(4) 0.1399(4) 0.068(3) Uani 1 1 d .
H5 H 0.9098 -0.0480 0.1506 0.082 Uiso 1 1 calc R
B6 B 0.8273(9) 0.0361(4) 0.0802(4) 0.059(3) Uani 1 1 d .
H6 H 0.8924 0.0336 0.0521 0.071 Uiso 1 1 calc R
B7 B 0.6222(9) 0.0955(5) 0.1073(4) 0.074(3) Uani 1 1 d .
H7 H 0.5522 0.1312 0.0960 0.089 Uiso 1 1 calc R
B8 B 0.6315(9) 0.0466(5) 0.1677(4) 0.074(3) Uani 1 1 d .
H8 H 0.5669 0.0500 0.1960 0.089 Uiso 1 1 calc R
B9 B 0.6909(10) -0.0252(6) 0.1510(4) 0.093(4) Uani 1 1 d .
H9 H 0.6652 -0.0693 0.1690 0.111 Uiso 1 1 calc R
B10 B 0.7179(10) -0.0222(6) 0.0805(4) 0.083(4) Uani 1 1 d .
H10 H 0.7103 -0.0632 0.0524 0.099 Uiso 1 1 calc R
B11 B 0.6747(10) 0.0535(5) 0.0554(4) 0.081(4) Uani 1 1 d .
H11 H 0.6383 0.0623 0.0103 0.097 Uiso 1 1 calc R
B12 B 0.5943(11) 0.0147(6) 0.0988(5) 0.104(5) Uani 1 1 d .
H12 H 0.5040 -0.0034 0.0823 0.125 Uiso 1 1 calc R
C17 C 0.5000 0.3531(10) 0.2500 0.264(16) Uani 1 2 d S
Cl1 Cl 0.5703(4) 0.3034(3) 0.21297(19) 0.319(3) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Se3 Pd1 Se3 92.05(6) 6_756 .
Se3 Pd1 Se1 174.04(4) 6_756 .
Se3 Pd1 Se1 83.68(3) . .
Se3 Pd1 Se1 83.68(3) 6_756 6_756
Se3 Pd1 Se1 174.04(4) . 6_756
Se1 Pd1 Se1 100.88(5) . 6_756
C7 Rh1 C10 63.7(3) . .
C7 Rh1 C11 37.7(3) . .
C10 Rh1 C11 37.5(3) . .
C7 Rh1 C9 63.0(3) . .
C10 Rh1 C9 38.1(3) . .
C11 Rh1 C9 62.4(3) . .
C7 Rh1 C8 37.8(3) . .
C10 Rh1 C8 62.5(3) . .
C11 Rh1 C8 62.0(3) . .
C9 Rh1 C8 36.5(3) . .
C7 Rh1 Se3 103.4(3) . .
C10 Rh1 Se3 115.1(3) . .
C11 Rh1 Se3 91.9(3) . .
C9 Rh1 Se3 152.5(3) . .
C8 Rh1 Se3 140.4(3) . .
C7 Rh1 Se2 159.5(2) . .
C10 Rh1 Se2 99.5(3) . .
C11 Rh1 Se2 132.9(3) . .
C9 Rh1 Se2 96.6(3) . .
C8 Rh1 Se2 125.3(3) . .
Se3 Rh1 Se2 94.28(4) . .
C7 Rh1 Se1 100.7(3) . .
C10 Rh1 Se1 157.9(3) . .
C11 Rh1 Se1 135.5(3) . .
C9 Rh1 Se1 121.9(3) . .
C8 Rh1 Se1 95.4(2) . .
Se3 Rh1 Se1 82.84(4) . .
Se2 Rh1 Se1 91.57(4) . .
C1 Se1 Rh1 103.5(2) . .
C1 Se1 Pd1 103.7(2) . .
Rh1 Se1 Pd1 95.63(4) . .
C2 Se2 Rh1 103.1(2) . .
C3 Se3 Pd1 102.2(2) . .
C3 Se3 Rh1 112.1(2) . .
Pd1 Se3 Rh1 97.61(5) . .
C2 C1 B3 62.5(5) . .
C2 C1 B4 111.9(6) . .
B3 C1 B4 63.0(5) . .
C2 C1 B6 61.3(5) . .
B3 C1 B6 115.2(6) . .
B4 C1 B6 113.6(6) . .
C2 C1 B5 111.1(6) . .
B3 C1 B5 115.4(7) . .
B4 C1 B5 62.8(5) . .
B6 C1 B5 61.6(5) . .
C2 C1 Se1 118.9(5) . .
B3 C1 Se1 119.1(5) . .
B4 C1 Se1 121.7(5) . .
B6 C1 Se1 114.7(5) . .
B5 C1 Se1 117.8(6) . .
C1 C2 B11 110.9(6) . .
C1 C2 B7 110.3(6) . .
B11 C2 B7 61.4(6) . .
C1 C2 B6 62.1(5) . .
B11 C2 B6 62.5(5) . .
B7 C2 B6 113.4(7) . .
C1 C2 B3 60.5(5) . .
B11 C2 B3 113.5(7) . .
B7 C2 B3 62.9(5) . .
B6 C2 B3 114.1(6) . .
C1 C2 Se2 119.4(5) . .
B11 C2 Se2 120.6(5) . .
B7 C2 Se2 120.8(6) . .
B6 C2 Se2 117.0(5) . .
B3 C2 Se2 117.5(6) . .
C4 C3 Se3 110.8(7) . .
C4 C3 H3A 109.5 . .
Se3 C3 H3A 109.5 . .
C4 C3 H3B 109.5 . .
Se3 C3 H3B 109.5 . .
H3A C3 H3B 108.1 . .
C5 C4 C3 114.2(9) . .
C5 C4 H4A 108.7 . .
C3 C4 H4A 108.7 . .
C5 C4 H4B 108.7 . .
C3 C4 H4B 108.7 . .
H4A C4 H4B 107.6 . .
C4 C5 C6 115.8(10) . .
C4 C5 H5A 108.3 . .
C6 C5 H5A 108.3 . .
C4 C5 H5B 108.3 . .
C6 C5 H5B 108.3 . .
H5A C5 H5B 107.4 . .
C5 C6 H6A 109.5 . .
C5 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C5 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C11 C7 C8 107.6(8) . .
C11 C7 C12 127.7(11) . .
C8 C7 C12 123.9(11) . .
C11 C7 Rh1 73.1(5) . .
C8 C7 Rh1 74.4(5) . .
C12 C7 Rh1 126.1(6) . .
C9 C8 C7 108.2(9) . .
C9 C8 C13 126.2(11) . .
C7 C8 C13 125.6(10) . .
C9 C8 Rh1 71.2(5) . .
C7 C8 Rh1 67.8(5) . .
C13 C8 Rh1 124.4(6) . .
C8 C9 C10 107.9(9) . .
C8 C9 C14 128.5(11) . .
C10 C9 C14 123.4(11) . .
C8 C9 Rh1 72.3(5) . .
C10 C9 Rh1 69.3(5) . .
C14 C9 Rh1 126.7(6) . .
C11 C10 C9 107.2(9) . .
C11 C10 C15 123.4(12) . .
C9 C10 C15 128.8(11) . .
C11 C10 Rh1 72.0(5) . .
C9 C10 Rh1 72.6(5) . .
C15 C10 Rh1 127.5(6) . .
C7 C11 C10 108.6(9) . .
C7 C11 C16 123.1(11) . .
C10 C11 C16 128.4(12) . .
C7 C11 Rh1 69.2(5) . .
C10 C11 Rh1 70.4(5) . .
C16 C11 Rh1 127.0(6) . .
C7 C12 H12A 109.5 . .
C7 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C7 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C8 C13 H13A 109.5 . .
C8 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C8 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
C9 C14 H14A 109.5 . .
C9 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C9 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C10 C15 H15A 109.5 . .
C10 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C10 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
C11 C16 H16A 109.5 . .
C11 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C11 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C1 B3 C2 57.0(4) . .
C1 B3 B4 59.2(5) . .
C2 B3 B4 104.6(7) . .
C1 B3 B8 104.2(7) . .
C2 B3 B8 104.1(6) . .
B4 B3 B8 58.9(6) . .
C1 B3 B7 103.7(7) . .
C2 B3 B7 58.0(5) . .
B4 B3 B7 106.6(7) . .
B8 B3 B7 59.7(5) . .
C1 B3 H3 124.6 . .
C2 B3 H3 124.7 . .
B4 B3 H3 122.5 . .
B8 B3 H3 123.5 . .
B7 B3 H3 123.1 . .
C1 B4 B8 104.4(7) . .
C1 B4 B9 104.4(6) . .
B8 B4 B9 60.2(6) . .
C1 B4 B3 57.8(5) . .
B8 B4 B3 60.6(6) . .
B9 B4 B3 108.3(7) . .
C1 B4 B5 58.9(5) . .
B8 B4 B5 108.4(7) . .
B9 B4 B5 60.0(6) . .
B3 B4 B5 107.9(6) . .
C1 B4 H4 125.3 . .
B8 B4 H4 122.0 . .
B9 B4 H4 122.3 . .
B3 B4 H4 121.5 . .
B5 B4 H4 121.3 . .
C1 B5 B6 59.1(5) . .
C1 B5 B9 103.1(7) . .
B6 B5 B9 107.0(7) . .
C1 B5 B10 104.6(7) . .
B6 B5 B10 59.6(5) . .
B9 B5 B10 60.1(6) . .
C1 B5 B4 58.3(5) . .
B6 B5 B4 107.8(7) . .
B9 B5 B4 58.9(6) . .
B10 B5 B4 107.7(8) . .
C1 B5 H5 125.1 . .
B6 B5 H5 121.6 . .
B9 B5 H5 123.5 . .
B10 B5 H5 122.3 . .
B4 B5 H5 121.9 . .
C2 B6 C1 56.6(4) . .
C2 B6 B5 105.4(6) . .
C1 B6 B5 59.3(5) . .
C2 B6 B10 105.7(7) . .
C1 B6 B10 105.7(7) . .
B5 B6 B10 60.8(5) . .
C2 B6 B11 58.5(5) . .
C1 B6 B11 103.5(7) . .
B5 B6 B11 107.8(7) . .
B10 B6 B11 59.8(6) . .
C2 B6 H6 124.2 . .
C1 B6 H6 124.8 . .
B5 B6 H6 121.5 . .
B10 B6 H6 122.1 . .
B11 B6 H6 123.0 . .
C2 B7 B11 59.3(5) . .
C2 B7 B12 104.4(8) . .
B11 B7 B12 59.3(6) . .
C2 B7 B8 105.2(7) . .
B11 B7 B8 108.0(8) . .
B12 B7 B8 59.8(6) . .
C2 B7 B3 59.1(5) . .
B11 B7 B3 108.7(7) . .
B12 B7 B3 107.5(8) . .
B8 B7 B3 60.0(5) . .
C2 B7 H7 124.4 . .
B11 B7 H7 121.3 . .
B12 B7 H7 123.1 . .
B8 B7 H7 122.3 . .
B3 B7 H7 121.3 . .
B4 B8 B9 59.9(6) . .
B4 B8 B12 106.9(8) . .
B9 B8 B12 58.7(6) . .
B4 B8 B7 108.2(7) . .
B9 B8 B7 106.9(8) . .
B12 B8 B7 59.7(6) . .
B4 B8 B3 60.4(5) . .
B9 B8 B3 108.0(8) . .
B12 B8 B3 107.6(7) . .
B7 B8 B3 60.3(5) . .
B4 B8 H8 121.7 . .
B9 B8 H8 122.4 . .
B12 B8 H8 122.7 . .
B7 B8 H8 121.8 . .
B3 B8 H8 121.4 . .
B12 B9 B4 108.6(9) . .
B12 B9 B8 60.9(7) . .
B4 B9 B8 59.9(6) . .
B12 B9 B5 108.0(7) . .
B4 B9 B5 61.2(5) . .
B8 B9 B5 109.2(8) . .
B12 B9 B10 59.7(6) . .
B4 B9 B10 109.7(8) . .
B8 B9 B10 109.4(8) . .
B5 B9 B10 60.4(6) . .
B12 B9 H9 121.8 . .
B4 B9 H9 120.9 . .
B8 B9 H9 120.9 . .
B5 B9 H9 121.2 . .
B10 B9 H9 120.9 . .
B12 B10 B11 59.1(7) . .
B12 B10 B6 106.9(8) . .
B11 B10 B6 60.1(6) . .
B12 B10 B9 58.5(6) . .
B11 B10 B9 105.6(9) . .
B6 B10 B9 106.5(7) . .
B12 B10 B5 106.4(8) . .
B11 B10 B5 107.1(8) . .
B6 B10 B5 59.6(5) . .
B9 B10 B5 59.5(5) . .
B12 B10 H10 122.9 . .
B11 B10 H10 122.5 . .
B6 B10 H10 122.1 . .
B9 B10 H10 123.2 . .
B5 B10 H10 122.3 . .
C2 B11 B12 105.7(7) . .
C2 B11 B7 59.3(5) . .
B12 B11 B7 61.0(7) . .
C2 B11 B10 106.3(7) . .
B12 B11 B10 60.0(6) . .
B7 B11 B10 110.0(8) . .
C2 B11 B6 59.0(5) . .
B12 B11 B6 107.5(8) . .
B7 B11 B6 108.8(7) . .
B10 B11 B6 60.0(6) . .
C2 B11 H11 123.9 . .
B12 B11 H11 122.3 . .
B7 B11 H11 120.2 . .
B10 B11 H11 121.4 . .
B6 B11 H11 121.7 . .
B9 B12 B11 109.6(9) . .
B9 B12 B10 61.7(7) . .
B11 B12 B10 60.9(6) . .
B9 B12 B7 109.0(8) . .
B11 B12 B7 59.6(6) . .
B10 B12 B7 109.5(8) . .
B9 B12 B8 60.4(6) . .
B11 B12 B8 108.8(8) . .
B10 B12 B8 110.7(8) . .
B7 B12 B8 60.5(6) . .
B9 B12 H12 120.7 . .
B11 B12 H12 121.4 . .
B10 B12 H12 119.8 . .
B7 B12 H12 121.5 . .
B8 B12 H12 120.8 . .
Cl1 C17 Cl1 102.0(12) . 6_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pd1 Se3 2.4102(12) 6_756
Pd1 Se3 2.4102(12) .
Pd1 Se1 2.4795(11) .
Pd1 Se1 2.4795(11) 6_756
Rh1 C7 2.140(8) .
Rh1 C10 2.168(8) .
Rh1 C11 2.189(9) .
Rh1 C9 2.211(8) .
Rh1 C8 2.226(8) .
Rh1 Se3 2.4621(12) .
Rh1 Se2 2.4634(12) .
Rh1 Se1 2.4686(11) .
Se1 C1 1.955(7) .
Se2 C2 1.957(8) .
Se3 C3 1.918(8) .
C1 C2 1.627(9) .
C1 B3 1.688(11) .
C1 B4 1.714(11) .
C1 B6 1.721(10) .
C1 B5 1.725(11) .
C2 B11 1.700(12) .
C2 B7 1.700(11) .
C2 B6 1.709(11) .
C2 B3 1.720(11) .
C3 C4 1.507(10) .
C3 H3A 0.9700 .
C3 H3B 0.9700 .
C4 C5 1.437(11) .
C4 H4A 0.9700 .
C4 H4B 0.9700 .
C5 C6 1.479(10) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C6 H6A 0.9600 .
C6 H6B 0.9600 .
C6 H6C 0.9600 .
C7 C11 1.399(11) .
C7 C8 1.417(11) .
C7 C12 1.541(9) .
C8 C9 1.390(10) .
C8 C13 1.509(11) .
C9 C10 1.431(11) .
C9 C14 1.484(10) .
C10 C11 1.402(11) .
C10 C15 1.488(10) .
C11 C16 1.504(11) .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C13 H13A 0.9600 .
C13 H13B 0.9600 .
C13 H13C 0.9600 .
C14 H14A 0.9600 .
C14 H14B 0.9600 .
C14 H14C 0.9600 .
C15 H15A 0.9600 .
C15 H15B 0.9600 .
C15 H15C 0.9600 .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
B3 B4 1.777(13) .
B3 B8 1.781(13) .
B3 B7 1.785(12) .
B3 H3 1.1000 .
B4 B8 1.750(13) .
B4 B9 1.750(14) .
B4 B5 1.792(13) .
B4 H4 1.1000 .
B5 B6 1.764(12) .
B5 B9 1.771(14) .
B5 B10 1.786(13) .
B5 H5 1.1000 .
B6 B10 1.765(13) .
B6 B11 1.767(14) .
B6 H6 1.1000 .
B7 B11 1.735(14) .
B7 B12 1.760(15) .
B7 B8 1.775(13) .
B7 H7 1.1000 .
B8 B9 1.755(15) .
B8 B12 1.762(14) .
B8 H8 1.1000 .
B9 B12 1.725(15) .
B9 B10 1.781(14) .
B9 H9 1.1000 .
B10 B12 1.747(15) .
B10 B11 1.761(15) .
B10 H10 1.1000 .
B11 B12 1.730(14) .
B11 H11 1.1000 .
B12 H12 1.1000 .
C17 Cl1 1.686(14) .
C17 Cl1 1.686(14) 6_656
