#------------------------------------------------------------------------------
#$Date: 2016-03-21 09:51:33 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178629 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/40/4074043.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4074043
loop_
_publ_author_name
'Turculet, Laura'
'McDonald, Robert'
_publ_section_title
;
 Mono-, Di-, and Trinuclear Complexes Featuring the New Bis(phosphido)
 Ligand 4,5-Bis(tert-butylphosphido)-9,9-dimethylxanthene ([POP]2−)
;
_journal_issue                   27
_journal_name_full               Organometallics
_journal_page_first              6821
_journal_paper_doi               10.1021/om700843n
_journal_volume                  26
_journal_year                    2007
_chemical_formula_moiety         'C27 H40 K2 O2 P2'
_chemical_formula_sum            'C27 H40 K2 O2 P2'
_chemical_formula_weight         536.73
_chemical_name_systematic
;  
 ?  
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 113.6089(15)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.5425(13)
_cell_length_b                   22.708(2)
_cell_length_c                   11.3647(12)
_cell_measurement_reflns_used    2312
_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      23.37
_cell_measurement_theta_min      2.52
_cell_volume                     2965.9(5)
_computing_cell_refinement       'Bruker SAINT (Bruker, 1997)'
_computing_data_collection       'Bruker SMART (Bruker, 1997)'
_computing_data_reduction        'Bruker SAINT (Bruker, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL (Bruker, 1997)'
_computing_publication_material  'Bruker SHELXTL (Bruker, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'DIRDIF-96 (Beurskens et al., 1996)'
_diffrn_ambient_temperature      193(2)
_diffrn_detector_area_resol_mean 8.192
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type
'Bruker PLATFORM diffractometer/SMART 1000 CCD area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0536
_diffrn_reflns_av_sigmaI/netI    0.0672
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            16439
_diffrn_reflns_theta_full        26.40
_diffrn_reflns_theta_max         26.40
_diffrn_reflns_theta_min         1.77
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.448
_exptl_absorpt_correction_T_max  0.9566
_exptl_absorpt_correction_T_min  0.8308
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.202
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1144
_exptl_crystal_size_max          0.43
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.601
_refine_diff_density_min         -0.346
_refine_diff_density_rms         0.072
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     294
_refine_ls_number_reflns         6089
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.022
_refine_ls_R_factor_all          0.1076
_refine_ls_R_factor_gt           0.0557
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0775P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1285
_refine_ls_wR_factor_ref         0.1511
_reflns_number_gt                3642
_reflns_number_total             6089
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            om700843n-file001.cif
_cod_data_source_block           dal0630
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4074043
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
K1 K 0.07693(6) 0.21617(4) 0.41128(6) 0.0454(2) Uani 1 1 d . . .
K2 K 0.31348(6) 0.17557(3) 0.18803(7) 0.0418(2) Uani 1 1 d . . .
P1 P 0.03787(6) 0.18488(4) 0.12887(7) 0.0320(2) Uani 1 1 d . . .
P2 P 0.35080(7) 0.22394(4) 0.47458(7) 0.0326(2) Uani 1 1 d . . .
O1 O 0.17219(16) 0.28648(8) 0.26704(18) 0.0324(5) Uani 1 1 d . . .
O2 O 0.3871(2) 0.06094(12) 0.2620(3) 0.0730(8) Uani 1 1 d D . .
C1 C 0.1441(3) 0.41165(14) 0.1974(3) 0.0413(8) Uani 1 1 d . . .
C2 C 0.1746(3) 0.43527(16) 0.0866(3) 0.0572(10) Uani 1 1 d . . .
H2A H 0.2066 0.4032 0.0529 0.069 Uiso 1 1 calc R . .
H2B H 0.2324 0.4668 0.1190 0.069 Uiso 1 1 calc R . .
H2C H 0.1042 0.4507 0.0179 0.069 Uiso 1 1 calc R . .
C3 C 0.0993(4) 0.46274(17) 0.2547(4) 0.0695(12) Uani 1 1 d . . .
H3A H 0.0809 0.4479 0.3254 0.083 Uiso 1 1 calc R . .
H3B H 0.0291 0.4796 0.1881 0.083 Uiso 1 1 calc R . .
H3C H 0.1595 0.4932 0.2870 0.083 Uiso 1 1 calc R . .
C11 C -0.0111(3) 0.26084(13) 0.1081(3) 0.0325(7) Uani 1 1 d . . .
C12 C 0.0686(2) 0.30658(13) 0.1721(3) 0.0305(7) Uani 1 1 d . . .
C13 C 0.0492(3) 0.36595(14) 0.1410(3) 0.0358(7) Uani 1 1 d . . .
C14 C -0.0596(3) 0.38175(16) 0.0485(3) 0.0510(9) Uani 1 1 d . . .
H14 H -0.0758 0.4219 0.0243 0.061 Uiso 1 1 calc R . .
C15 C -0.1437(3) 0.33977(16) -0.0081(3) 0.0518(10) Uani 1 1 d . . .
H15 H -0.2184 0.3515 -0.0681 0.062 Uiso 1 1 calc R . .
C16 C -0.1211(3) 0.28135(15) 0.0211(3) 0.0415(8) Uani 1 1 d . . .
H16 H -0.1815 0.2535 -0.0185 0.050 Uiso 1 1 calc R . .
C17 C -0.0873(3) 0.13837(15) 0.0202(3) 0.0442(8) Uani 1 1 d . . .
C18 C -0.1243(3) 0.15136(17) -0.1229(3) 0.0610(11) Uani 1 1 d . . .
H18A H -0.1892 0.1256 -0.1733 0.073 Uiso 1 1 calc R . .
H18B H -0.0586 0.1442 -0.1469 0.073 Uiso 1 1 calc R . .
H18C H -0.1487 0.1926 -0.1401 0.073 Uiso 1 1 calc R . .
C19 C -0.1921(3) 0.13778(19) 0.0572(4) 0.0697(12) Uani 1 1 d . . .
H19A H -0.2540 0.1134 -0.0039 0.084 Uiso 1 1 calc R . .
H19B H -0.2206 0.1781 0.0555 0.084 Uiso 1 1 calc R . .
H19C H -0.1686 0.1215 0.1438 0.084 Uiso 1 1 calc R . .
C20 C -0.0349(3) 0.07609(15) 0.0431(4) 0.0616(11) Uani 1 1 d . . .
H20A H -0.0930 0.0479 -0.0112 0.074 Uiso 1 1 calc R . .
H20B H -0.0116 0.0654 0.1336 0.074 Uiso 1 1 calc R . .
H20C H 0.0333 0.0752 0.0216 0.074 Uiso 1 1 calc R . .
C21 C 0.3600(2) 0.30018(13) 0.4331(3) 0.0300(7) Uani 1 1 d . . .
C22 C 0.2612(2) 0.32644(13) 0.3328(3) 0.0307(7) Uani 1 1 d . . .
C23 C 0.2523(3) 0.38543(14) 0.3003(3) 0.0363(8) Uani 1 1 d . . .
C24 C 0.3488(3) 0.42116(15) 0.3661(3) 0.0453(9) Uani 1 1 d . . .
H24 H 0.3452 0.4621 0.3475 0.054 Uiso 1 1 calc R . .
C25 C 0.4489(3) 0.39780(15) 0.4573(3) 0.0477(9) Uani 1 1 d . . .
H25 H 0.5151 0.4222 0.4973 0.057 Uiso 1 1 calc R . .
C26 C 0.4540(3) 0.33960(15) 0.4911(3) 0.0403(8) Uani 1 1 d . . .
H26 H 0.5237 0.3251 0.5562 0.048 Uiso 1 1 calc R . .
C27 C 0.4981(2) 0.20228(14) 0.6007(3) 0.0342(7) Uani 1 1 d . . .
C28 C 0.5348(3) 0.23387(16) 0.7294(3) 0.0438(9) Uani 1 1 d . . .
H28A H 0.6121 0.2201 0.7875 0.053 Uiso 1 1 calc R . .
H28B H 0.4785 0.2254 0.7670 0.053 Uiso 1 1 calc R . .
H28C H 0.5375 0.2764 0.7162 0.053 Uiso 1 1 calc R . .
C29 C 0.5966(3) 0.20649(16) 0.5513(3) 0.0455(9) Uani 1 1 d . . .
H29A H 0.6709 0.1956 0.6205 0.055 Uiso 1 1 calc R . .
H29B H 0.6013 0.2469 0.5236 0.055 Uiso 1 1 calc R . .
H29C H 0.5798 0.1796 0.4786 0.055 Uiso 1 1 calc R . .
C30 C 0.4827(3) 0.13731(15) 0.6243(3) 0.0493(9) Uani 1 1 d . . .
H30A H 0.5552 0.1220 0.6899 0.059 Uiso 1 1 calc R . .
H30B H 0.4635 0.1152 0.5443 0.059 Uiso 1 1 calc R . .
H30C H 0.4196 0.1330 0.6537 0.059 Uiso 1 1 calc R . .
C31 C 0.4853(4) 0.03083(19) 0.2725(5) 0.0820(14) Uani 1 1 d . A .
H31A H 0.4725 0.0120 0.1893 0.098 Uiso 1 1 calc R . .
H31B H 0.5019 -0.0006 0.3379 0.098 Uiso 1 1 calc R . .
C32 C 0.5860(3) 0.07146(17) 0.3098(4) 0.0672(12) Uani 1 1 d . . .
H32A H 0.6550 0.0496 0.3148 0.081 Uiso 1 1 calc R A .
H32B H 0.6004 0.0888 0.3937 0.081 Uiso 1 1 calc R . .
H32C H 0.5690 0.1028 0.2455 0.081 Uiso 1 1 calc R . .
C33A C 0.2821(10) 0.0276(6) 0.2295(9) 0.103(3) Uiso 0.67 1 d PD A 1
H33A H 0.2771 -0.0023 0.1640 0.123 Uiso 0.67 1 calc PR A 1
H33B H 0.2143 0.0542 0.1918 0.123 Uiso 0.67 1 calc PR A 1
C34A C 0.2780(6) -0.0016(3) 0.3414(7) 0.096(2) Uiso 0.67 1 d PD A 1
H34A H 0.2073 -0.0256 0.3152 0.115 Uiso 0.67 1 calc PR A 1
H34B H 0.2774 0.0281 0.4037 0.115 Uiso 0.67 1 calc PR A 1
H34C H 0.3465 -0.0269 0.3806 0.115 Uiso 0.67 1 calc PR A 1
C33B C 0.297(2) 0.0176(11) 0.2347(17) 0.103(3) Uiso 0.33 1 d PD A 2
H33C H 0.3322 -0.0222 0.2471 0.123 Uiso 0.33 1 calc PR A 2
H33D H 0.2419 0.0212 0.1439 0.123 Uiso 0.33 1 calc PR A 2
C34B C 0.2348(11) 0.0246(7) 0.3174(14) 0.096(2) Uiso 0.33 1 d PD A 2
H34D H 0.1661 -0.0010 0.2871 0.115 Uiso 0.33 1 calc PR A 2
H34E H 0.2103 0.0657 0.3153 0.115 Uiso 0.33 1 calc PR A 2
H34F H 0.2858 0.0138 0.4056 0.115 Uiso 0.33 1 calc PR A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 K1 C11 135.40(8) . 4_566
O1 K1 C12 146.44(7) . 4_566
C11 K1 C12 27.47(8) 4_566 4_566
O1 K1 P1 58.01(4) . .
C11 K1 P1 151.34(6) 4_566 .
C12 K1 P1 154.94(6) 4_566 .
O1 K1 C16 141.25(8) . 4_566
C11 K1 C16 26.30(8) 4_566 4_566
C12 K1 C16 44.70(8) 4_566 4_566
P1 K1 C16 125.30(6) . 4_566
O1 K1 P2 56.37(4) . .
C11 K1 P2 121.15(6) 4_566 .
C12 K1 P2 103.94(6) 4_566 .
P1 K1 P2 87.50(3) . .
C16 K1 P2 146.95(6) 4_566 .
O1 K1 C11 43.95(6) . .
C11 K1 C11 132.11(8) 4_566 .
C12 K1 C11 158.62(8) 4_566 .
P1 K1 C11 32.46(6) . .
C16 K1 C11 114.31(8) 4_566 .
P2 K1 C11 95.53(6) . .
O1 K1 C13 162.82(7) . 4_566
C11 K1 C13 46.27(8) 4_566 4_566
C12 K1 C13 24.61(7) 4_566 4_566
P1 K1 C13 130.77(6) . 4_566
C16 K1 C13 50.48(8) 4_566 4_566
P2 K1 C13 106.97(6) . 4_566
C11 K1 C13 152.25(8) . 4_566
O1 K1 C12 24.07(6) . .
C11 K1 C12 127.66(8) 4_566 .
C12 K1 C12 152.05(5) 4_566 .
P1 K1 C12 50.96(5) . .
C16 K1 C12 121.71(8) 4_566 .
P2 K1 C12 80.38(5) . .
C11 K1 C12 24.49(7) . .
C13 K1 C12 172.14(7) 4_566 .
O1 K1 C15 155.42(7) . 4_566
C11 K1 C15 43.76(8) 4_566 4_566
C12 K1 C15 48.92(8) 4_566 4_566
P1 K1 C15 111.87(6) . 4_566
C16 K1 C15 23.14(8) 4_566 4_566
P2 K1 C15 148.17(6) . 4_566
C11 K1 C15 114.49(8) . 4_566
C13 K1 C15 41.25(8) 4_566 4_566
C12 K1 C15 131.45(8) . 4_566
O1 K1 P1 104.67(5) . 4_566
C11 K1 P1 30.99(6) 4_566 4_566
C12 K1 P1 49.96(6) 4_566 4_566
P1 K1 P1 149.05(3) . 4_566
C16 K1 P1 50.60(6) 4_566 4_566
P2 K1 P1 104.14(3) . 4_566
C11 K1 P1 116.83(6) . 4_566
C13 K1 P1 73.71(6) 4_566 4_566
C12 K1 P1 102.10(6) . 4_566
C15 K1 P1 72.49(6) 4_566 4_566
O1 K1 C14 171.93(7) . 4_566
C11 K1 C14 51.16(8) 4_566 4_566
C12 K1 C14 41.62(8) 4_566 4_566
P1 K1 C14 113.95(6) . 4_566
C16 K1 C14 41.21(9) 4_566 4_566
P2 K1 C14 126.80(6) . 4_566
C11 K1 C14 129.15(8) . 4_566
C13 K1 C14 23.25(7) 4_566 4_566
C12 K1 C14 151.10(8) . 4_566
C15 K1 C14 22.60(8) 4_566 4_566
P1 K1 C14 82.12(6) 4_566 4_566
O2 K2 C21 105.91(8) . 4_565
O2 K2 P1 108.69(6) . .
C21 K2 P1 111.28(5) 4_565 .
O2 K2 P2 96.62(7) . .
C21 K2 P2 145.89(6) 4_565 .
P1 K2 P2 84.32(3) . .
O2 K2 C26 84.62(9) . 4_565
C21 K2 C26 24.63(7) 4_565 4_565
P1 K2 C26 131.55(6) . 4_565
P2 K2 C26 141.80(6) . 4_565
O2 K2 O1 139.42(7) . .
C21 K2 O1 114.32(6) 4_565 .
P1 K2 O1 51.94(4) . .
P2 K2 O1 51.21(4) . .
C26 K2 O1 135.75(7) 4_565 .
O2 K2 P2 134.51(7) . 4_565
C21 K2 P2 30.92(5) 4_565 4_565
P1 K2 P2 103.92(3) . 4_565
P2 K2 P2 117.63(2) . 4_565
C26 K2 P2 49.90(6) 4_565 4_565
O1 K2 P2 85.90(4) . 4_565
C11 P1 C17 107.33(14) . .
C11 P1 K1 79.83(9) . .
C17 P1 K1 123.13(11) . .
C11 P1 K2 111.39(10) . .
C17 P1 K2 129.52(11) . .
K1 P1 K2 94.93(3) . .
C11 P1 K1 55.69(9) . 4_565
C17 P1 K1 102.20(11) . 4_565
K1 P1 K1 124.58(3) . 4_565
K2 P1 K1 75.59(2) . 4_565
C21 P2 C27 107.50(13) . .
C21 P2 K1 99.67(9) . .
C27 P2 K1 141.70(10) . .
C21 P2 K2 93.44(9) . .
C27 P2 K2 111.81(10) . .
K1 P2 K2 92.55(3) . .
C21 P2 K2 66.22(9) . 4_566
C27 P2 K2 90.31(10) . 4_566
K1 P2 K2 76.32(2) . 4_566
K2 P2 K2 154.15(3) . 4_566
C12 O1 C22 119.9(2) . .
C12 O1 K1 98.75(15) . .
C22 O1 K1 118.77(16) . .
C12 O1 K2 117.48(16) . .
C22 O1 K2 103.42(15) . .
K1 O1 K2 96.83(6) . .
C31 O2 C33A 117.4(7) . .
C31 O2 C33B 106.1(13) . .
C31 O2 K2 132.2(2) . .
C33A O2 K2 104.9(7) . .
C33B O2 K2 116.1(14) . .
C13 C1 C23 111.5(3) . .
C13 C1 C3 109.7(3) . .
C23 C1 C3 109.6(3) . .
C13 C1 C2 107.5(3) . .
C23 C1 C2 109.0(3) . .
C3 C1 C2 109.4(3) . .
C16 C11 C12 113.9(3) . .
C16 C11 P1 126.0(2) . .
C12 C11 P1 119.7(2) . .
C16 C11 K1 88.16(18) . 4_565
C12 C11 K1 81.79(17) . 4_565
P1 C11 K1 93.32(12) . 4_565
C16 C11 K1 130.5(2) . .
C12 C11 K1 79.61(16) . .
P1 C11 K1 67.72(9) . .
K1 C11 K1 141.25(10) 4_565 .
C13 C12 O1 121.9(3) . .
C13 C12 C11 124.3(3) . .
O1 C12 C11 113.8(2) . .
C13 C12 K1 89.32(18) . 4_565
O1 C12 K1 108.23(17) . 4_565
C11 C12 K1 70.74(16) . 4_565
C13 C12 K1 137.8(2) . .
O1 C12 K1 57.18(13) . .
C11 C12 K1 75.90(17) . .
K1 C12 K1 132.64(10) 4_565 .
C12 C13 C14 117.3(3) . .
C12 C13 C1 122.0(3) . .
C14 C13 C1 120.6(3) . .
C12 C13 K1 66.07(17) . 4_565
C14 C13 K1 86.0(2) . 4_565
C1 C13 K1 113.80(19) . 4_565
C15 C14 C13 120.6(3) . .
C15 C14 K1 76.9(2) . 4_565
C13 C14 K1 70.72(19) . 4_565
C16 C15 C14 120.8(3) . .
C16 C15 K1 66.49(19) . 4_565
C14 C15 K1 80.5(2) . 4_565
C15 C16 C11 122.5(3) . .
C15 C16 K1 90.4(2) . 4_565
C11 C16 K1 65.55(17) . 4_565
C18 C17 C19 111.4(3) . .
C18 C17 C20 106.5(3) . .
C19 C17 C20 107.5(3) . .
C18 C17 P1 114.0(2) . .
C19 C17 P1 114.0(3) . .
C20 C17 P1 102.5(2) . .
C26 C21 C22 113.6(3) . .
C26 C21 P2 127.7(2) . .
C22 C21 P2 118.7(2) . .
C26 C21 K2 83.71(18) . 4_566
C22 C21 K2 103.50(18) . 4_566
P2 C21 K2 82.87(10) . 4_566
C23 C22 O1 121.6(3) . .
C23 C22 C21 124.5(3) . .
O1 C22 C21 113.9(3) . .
C22 C23 C24 117.3(3) . .
C22 C23 C1 122.6(3) . .
C24 C23 C1 120.1(3) . .
C25 C24 C23 120.8(3) . .
C26 C25 C24 120.6(3) . .
C25 C26 C21 122.9(3) . .
C25 C26 K2 107.8(2) . 4_566
C21 C26 K2 71.66(17) . 4_566
C28 C27 C30 107.3(3) . .
C28 C27 C29 109.9(3) . .
C30 C27 C29 107.3(3) . .
C28 C27 P2 115.6(2) . .
C30 C27 P2 103.3(2) . .
C29 C27 P2 112.8(2) . .
O2 C31 C32 110.3(3) . .
O2 C33A C34A 111.5(7) . .
O2 C33B C34B 111.5(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
K1 O1 2.869(2) .
K1 C11 2.911(3) 4_566
K1 C12 3.051(3) 4_566
K1 P1 3.1282(11) .
K1 C16 3.196(3) 4_566
K1 P2 3.2200(11) .
K1 C11 3.328(3) .
K1 C13 3.338(3) 4_566
K1 C12 3.375(3) .
K1 C15 3.485(4) 4_566
K1 P1 3.5177(11) 4_566
K1 C14 3.528(4) 4_566
K2 O2 2.777(3) .
K2 C21 3.224(3) 4_565
K2 P1 3.2535(10) .
K2 P2 3.2878(11) .
K2 C26 3.376(3) 4_565
K2 O1 3.401(2) .
K2 P2 3.4957(11) 4_565
P1 C11 1.814(3) .
P1 C17 1.885(3) .
P2 C21 1.810(3) .
P2 C27 1.895(3) .
O1 C12 1.392(3) .
O1 C22 1.400(3) .
O2 C31 1.371(5) .
O2 C33A 1.433(6) .
O2 C33B 1.433(6) .
C1 C13 1.514(4) .
C1 C23 1.515(4) .
C1 C3 1.542(5) .
C1 C2 1.551(4) .
C11 C16 1.416(4) .
C11 C12 1.422(4) .
C12 C13 1.390(4) .
C13 C14 1.396(4) .
C14 C15 1.375(5) .
C15 C16 1.369(5) .
C17 C18 1.531(5) .
C17 C19 1.532(5) .
C17 C20 1.537(5) .
C21 C26 1.416(4) .
C21 C22 1.435(4) .
C22 C23 1.382(4) .
C23 C24 1.399(4) .
C24 C25 1.374(5) .
C25 C26 1.370(5) .
C27 C28 1.525(4) .
C27 C30 1.525(5) .
C27 C29 1.551(4) .
C31 C32 1.482(5) .
C33A C34A 1.453(10) .
C33B C34B 1.453(10) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 K1 P1 C11 -53.17(11) . .
C11 K1 P1 C11 74.2(2) 4_566 .
C12 K1 P1 C11 137.20(17) 4_566 .
C16 K1 P1 C11 80.02(13) 4_566 .
P2 K1 P1 C11 -104.38(10) . .
C13 K1 P1 C11 145.25(12) 4_566 .
C12 K1 P1 C11 -24.75(11) . .
C15 K1 P1 C11 101.61(12) 4_566 .
P1 K1 P1 C11 9.38(12) 4_566 .
C14 K1 P1 C11 126.07(12) 4_566 .
O1 K1 P1 C17 -157.31(14) . .
C11 K1 P1 C17 -29.9(2) 4_566 .
C12 K1 P1 C17 33.1(2) 4_566 .
C16 K1 P1 C17 -24.12(16) 4_566 .
P2 K1 P1 C17 151.48(13) . .
C11 K1 P1 C17 -104.14(16) . .
C13 K1 P1 C17 41.10(15) 4_566 .
C12 K1 P1 C17 -128.89(14) . .
C15 K1 P1 C17 -2.54(15) 4_566 .
P1 K1 P1 C17 -94.77(14) 4_566 .
C14 K1 P1 C17 21.93(15) 4_566 .
O1 K1 P1 K2 57.71(5) . .
C11 K1 P1 K2 -174.87(14) 4_566 .
C12 K1 P1 K2 -111.92(14) 4_566 .
C16 K1 P1 K2 -169.10(8) 4_566 .
P2 K1 P1 K2 6.50(3) . .
C11 K1 P1 K2 110.88(10) . .
C13 K1 P1 K2 -103.87(8) 4_566 .
C12 K1 P1 K2 86.13(6) . .
C15 K1 P1 K2 -147.52(7) 4_566 .
P1 K1 P1 K2 120.26(6) 4_566 .
C14 K1 P1 K2 -123.05(7) 4_566 .
O1 K1 P1 K1 -18.17(5) . 4_565
C11 K1 P1 K1 109.25(15) 4_566 4_565
C12 K1 P1 K1 172.20(13) 4_566 4_565
C16 K1 P1 K1 115.02(9) 4_566 4_565
P2 K1 P1 K1 -69.38(4) . 4_565
C11 K1 P1 K1 35.00(10) . 4_565
C13 K1 P1 K1 -179.76(7) 4_566 4_565
C12 K1 P1 K1 10.25(7) . 4_565
C15 K1 P1 K1 136.60(7) 4_566 4_565
P1 K1 P1 K1 44.37(9) 4_566 4_565
C14 K1 P1 K1 161.07(7) 4_566 4_565
O2 K2 P1 C11 169.68(12) . .
C21 K2 P1 C11 -74.07(12) 4_565 .
P2 K2 P1 C11 74.60(10) . .
C26 K2 P1 C11 -90.67(13) 4_565 .
O1 K2 P1 C11 30.79(11) . .
P2 K2 P1 C11 -42.50(10) 4_565 .
O2 K2 P1 C17 -52.77(16) . .
C21 K2 P1 C17 63.48(16) 4_565 .
P2 K2 P1 C17 -147.85(14) . .
C26 K2 P1 C17 46.88(17) 4_565 .
O1 K2 P1 C17 168.33(15) . .
P2 K2 P1 C17 95.05(15) 4_565 .
O2 K2 P1 K1 88.69(7) . .
C21 K2 P1 K1 -155.06(6) 4_565 .
P2 K2 P1 K1 -6.39(3) . .
C26 K2 P1 K1 -171.65(8) 4_565 .
O1 K2 P1 K1 -50.20(5) . .
P2 K2 P1 K1 -123.49(3) 4_565 .
O2 K2 P1 K1 -146.84(7) . 4_565
C21 K2 P1 K1 -30.59(6) 4_565 4_565
P2 K2 P1 K1 118.08(3) . 4_565
C26 K2 P1 K1 -47.19(8) 4_565 4_565
O1 K2 P1 K1 74.26(5) . 4_565
P2 K2 P1 K1 0.98(3) 4_565 4_565
O1 K1 P2 C21 34.95(10) . .
C11 K1 P2 C21 -91.71(12) 4_566 .
C12 K1 P2 C21 -115.05(11) 4_566 .
P1 K1 P2 C21 87.52(9) . .
C16 K1 P2 C21 -99.08(16) 4_566 .
C11 K1 P2 C21 56.03(11) . .
C13 K1 P2 C21 -140.40(11) 4_566 .
C12 K1 P2 C21 36.72(11) . .
C15 K1 P2 C21 -142.93(15) 4_566 .
P1 K1 P2 C21 -63.44(9) 4_566 .
C14 K1 P2 C21 -154.13(12) 4_566 .
O1 K1 P2 C27 170.01(18) . .
C11 K1 P2 C27 43.34(19) 4_566 .
C12 K1 P2 C27 20.00(18) 4_566 .
P1 K1 P2 C27 -137.43(17) . .
C16 K1 P2 C27 36.0(2) 4_566 .
C11 K1 P2 C27 -168.91(18) . .
C13 K1 P2 C27 -5.35(18) 4_566 .
C12 K1 P2 C27 171.78(18) . .
C15 K1 P2 C27 -7.9(2) 4_566 .
P1 K1 P2 C27 71.61(17) 4_566 .
C14 K1 P2 C27 -19.08(19) 4_566 .
O1 K1 P2 K2 -58.98(5) . .
C11 K1 P2 K2 174.35(8) 4_566 .
C12 K1 P2 K2 151.02(6) 4_566 .
P1 K1 P2 K2 -6.41(3) . .
C16 K1 P2 K2 166.99(13) 4_566 .
C11 K1 P2 K2 -37.90(6) . .
C13 K1 P2 K2 125.66(6) 4_566 .
C12 K1 P2 K2 -57.21(6) . .
C15 K1 P2 K2 123.14(12) 4_566 .
P1 K1 P2 K2 -157.37(3) 4_566 .
C14 K1 P2 K2 111.94(8) 4_566 .
O1 K1 P2 K2 97.41(5) . 4_566
C11 K1 P2 K2 -29.26(8) 4_566 4_566
C12 K1 P2 K2 -52.60(6) 4_566 4_566
P1 K1 P2 K2 149.97(3) . 4_566
C16 K1 P2 K2 -36.62(13) 4_566 4_566
C11 K1 P2 K2 118.49(6) . 4_566
C13 K1 P2 K2 -77.95(6) 4_566 4_566
C12 K1 P2 K2 99.18(6) . 4_566
C15 K1 P2 K2 -80.47(13) 4_566 4_566
P1 K1 P2 K2 -0.99(3) 4_566 4_566
C14 K1 P2 K2 -91.68(8) 4_566 4_566
O2 K2 P2 C21 158.12(11) . .
C21 K2 P2 C21 26.57(8) 4_565 .
P1 K2 P2 C21 -93.66(9) . .
C26 K2 P2 C21 68.41(13) 4_565 .
O1 K2 P2 C21 -49.29(10) . .
P2 K2 P2 C21 9.10(10) 4_565 .
O2 K2 P2 C27 47.72(12) . .
C21 K2 P2 C27 -83.83(15) 4_565 .
P1 K2 P2 C27 155.94(11) . .
C26 K2 P2 C27 -41.99(15) 4_565 .
O1 K2 P2 C27 -159.69(12) . .
P2 K2 P2 C27 -101.30(11) 4_565 .
O2 K2 P2 K1 -102.03(6) . .
C21 K2 P2 K1 126.42(10) 4_565 .
P1 K2 P2 K1 6.19(3) . .
C26 K2 P2 K1 168.26(10) 4_565 .
O1 K2 P2 K1 50.56(4) . .
P2 K2 P2 K1 108.95(3) 4_565 .
O2 K2 P2 K2 -165.22(8) . 4_566
C21 K2 P2 K2 63.23(14) 4_565 4_566
P1 K2 P2 K2 -57.00(7) . 4_566
C26 K2 P2 K2 105.07(12) 4_565 4_566
O1 K2 P2 K2 -12.63(8) . 4_566
P2 K2 P2 K2 45.76(10) 4_565 4_566
C11 K1 O1 C12 -82.14(18) 4_566 .
C12 K1 O1 C12 -122.92(14) 4_566 .
P1 K1 O1 C12 65.00(15) . .
C16 K1 O1 C12 -43.1(2) 4_566 .
P2 K1 O1 C12 175.72(17) . .
C11 K1 O1 C12 26.77(16) . .
C13 K1 O1 C12 -169.1(2) 4_566 .
C15 K1 O1 C12 -7.0(3) 4_566 .
P1 K1 O1 C12 -86.85(16) 4_566 .
C14 K1 O1 C12 60.0(6) 4_566 .
C11 K1 O1 C22 49.2(2) 4_566 .
C12 K1 O1 C22 8.4(2) 4_566 .
P1 K1 O1 C22 -163.67(19) . .
C16 K1 O1 C22 88.3(2) 4_566 .
P2 K1 O1 C22 -52.95(17) . .
C11 K1 O1 C22 158.1(2) . .
C13 K1 O1 C22 -37.8(3) 4_566 .
C12 K1 O1 C22 131.3(3) . .
C15 K1 O1 C22 124.4(2) 4_566 .
P1 K1 O1 C22 44.47(18) 4_566 .
C14 K1 O1 C22 -168.6(5) 4_566 .
C11 K1 O1 K2 158.61(9) 4_566 .
C12 K1 O1 K2 117.83(12) 4_566 .
P1 K1 O1 K2 -54.25(4) . .
C16 K1 O1 K2 -162.32(10) 4_566 .
P2 K1 O1 K2 56.47(4) . .
C11 K1 O1 K2 -92.48(9) . .
C13 K1 O1 K2 71.7(2) 4_566 .
C12 K1 O1 K2 -119.25(17) . .
C15 K1 O1 K2 -126.21(17) 4_566 .
P1 K1 O1 K2 153.90(3) 4_566 .
C14 K1 O1 K2 -59.2(5) 4_566 .
O2 K2 O1 C12 -119.63(19) . .
C21 K2 O1 C12 52.34(19) 4_565 .
P1 K2 O1 C12 -46.40(17) . .
P2 K2 O1 C12 -164.30(19) . .
C26 K2 O1 C12 67.4(2) 4_565 .
P2 K2 O1 C12 64.86(17) 4_565 .
O2 K2 O1 C22 105.76(18) . .
C21 K2 O1 C22 -82.26(17) 4_565 .
P1 K2 O1 C22 179.00(17) . .
P2 K2 O1 C22 61.10(15) . .
C26 K2 O1 C22 -67.21(18) 4_565 .
P2 K2 O1 C22 -69.75(15) 4_565 .
O2 K2 O1 K1 -16.03(12) . .
C21 K2 O1 K1 155.94(6) 4_565 .
P1 K2 O1 K1 57.20(4) . .
P2 K2 O1 K1 -60.70(4) . .
C26 K2 O1 K1 170.99(8) 4_565 .
P2 K2 O1 K1 168.45(5) 4_565 .
C21 K2 O2 C31 45.4(4) 4_565 .
P1 K2 O2 C31 165.0(3) . .
P2 K2 O2 C31 -108.7(4) . .
C26 K2 O2 C31 32.9(4) 4_565 .
O1 K2 O2 C31 -142.2(3) . .
P2 K2 O2 C31 31.5(4) 4_565 .
C21 K2 O2 C33A -106.7(3) 4_565 .
P1 K2 O2 C33A 13.0(3) . .
P2 K2 O2 C33A 99.2(3) . .
C26 K2 O2 C33A -119.2(3) 4_565 .
O1 K2 O2 C33A 65.7(4) . .
P2 K2 O2 C33A -120.5(3) 4_565 .
C21 K2 O2 C33B -104.2(5) 4_565 .
P1 K2 O2 C33B 15.5(5) . .
P2 K2 O2 C33B 101.7(5) . .
C26 K2 O2 C33B -116.7(5) 4_565 .
O1 K2 O2 C33B 68.2(5) . .
P2 K2 O2 C33B -118.1(5) 4_565 .
C17 P1 C11 C16 -3.0(3) . .
K1 P1 C11 C16 -124.7(3) . .
K2 P1 C11 C16 143.9(2) . .
K1 P1 C11 C16 90.1(3) 4_565 .
C17 P1 C11 C12 -175.6(2) . .
K1 P1 C11 C12 62.7(2) . .
K2 P1 C11 C12 -28.6(3) . .
K1 P1 C11 C12 -82.4(2) 4_565 .
C17 P1 C11 K1 -93.15(14) . 4_565
K1 P1 C11 K1 145.13(8) . 4_565
K2 P1 C11 K1 53.79(9) . 4_565
C17 P1 C11 K1 121.71(12) . .
K2 P1 C11 K1 -91.34(5) . .
K1 P1 C11 K1 -145.13(8) 4_565 .
O1 K1 C11 C16 -138.9(3) . .
C11 K1 C11 C16 -22.5(3) 4_566 .
C12 K1 C11 C16 -8.9(4) 4_566 .
P1 K1 C11 C16 119.0(3) . .
C16 K1 C11 C16 0.9(3) 4_566 .
P2 K1 C11 C16 -164.5(3) . .
C13 K1 C11 C16 51.0(4) 4_566 .
C12 K1 C11 C16 -112.6(4) . .
C15 K1 C11 C16 26.4(3) 4_566 .
P1 K1 C11 C16 -55.6(3) 4_566 .
C14 K1 C11 C16 46.8(3) 4_566 .
O1 K1 C11 C12 -26.30(15) . .
C11 K1 C11 C12 90.1(2) 4_566 .
C12 K1 C11 C12 103.8(2) 4_566 .
P1 K1 C11 C12 -128.3(2) . .
C16 K1 C11 C12 113.55(17) 4_566 .
P2 K1 C11 C12 -51.86(17) . .
C13 K1 C11 C12 163.68(17) 4_566 .
C15 K1 C11 C12 138.99(17) 4_566 .
P1 K1 C11 C12 57.05(17) 4_566 .
C14 K1 C11 C12 159.39(16) 4_566 .
O1 K1 C11 P1 102.04(12) . .
C11 K1 C11 P1 -141.52(7) 4_566 .
C12 K1 C11 P1 -127.9(2) 4_566 .
C16 K1 C11 P1 -118.11(10) 4_566 .
P2 K1 C11 P1 76.48(9) . .
C13 K1 C11 P1 -68.0(2) 4_566 .
C12 K1 C11 P1 128.3(2) . .
C15 K1 C11 P1 -92.67(11) 4_566 .
P1 K1 C11 P1 -174.61(7) 4_566 .
C14 K1 C11 P1 -72.27(13) 4_566 .
O1 K1 C11 K1 36.27(14) . 4_565
C11 K1 C11 K1 152.72(19) 4_566 4_565
C12 K1 C11 K1 166.35(18) 4_566 4_565
P1 K1 C11 K1 -65.76(15) . 4_565
C16 K1 C11 K1 176.13(15) 4_566 4_565
P2 K1 C11 K1 10.72(17) . 4_565
C13 K1 C11 K1 -133.75(18) 4_566 4_565
C12 K1 C11 K1 62.58(19) . 4_565
C15 K1 C11 K1 -158.43(16) 4_566 4_565
P1 K1 C11 K1 119.63(15) 4_566 4_565
C14 K1 C11 K1 -138.03(16) 4_566 4_565
C22 O1 C12 C13 -1.1(4) . .
K1 O1 C12 C13 129.5(2) . .
K2 O1 C12 C13 -128.0(2) . .
C22 O1 C12 C11 176.4(2) . .
K1 O1 C12 C11 -53.1(2) . .
K2 O1 C12 C11 49.4(3) . .
C22 O1 C12 K1 99.9(2) . 4_565
K1 O1 C12 K1 -129.51(10) . 4_565
K2 O1 C12 K1 -27.05(19) . 4_565
C22 O1 C12 K1 -130.6(3) . .
K2 O1 C12 K1 102.46(13) . .
C16 C11 C12 C13 -9.0(4) . .
P1 C11 C12 C13 164.5(2) . .
K1 C11 C12 C13 75.3(3) 4_565 .
K1 C11 C12 C13 -138.8(3) . .
C16 C11 C12 O1 173.7(2) . .
P1 C11 C12 O1 -12.9(3) . .
K1 C11 C12 O1 -102.0(2) 4_565 .
K1 C11 C12 O1 43.8(2) . .
C16 C11 C12 K1 -84.3(2) . 4_565
P1 C11 C12 K1 89.1(2) . 4_565
K1 C11 C12 K1 145.85(8) . 4_565
C16 C11 C12 K1 129.9(3) . .
P1 C11 C12 K1 -56.71(18) . .
K1 C11 C12 K1 -145.85(8) 4_565 .
O1 K1 C12 C13 -103.0(3) . .
C11 K1 C12 C13 15.5(3) 4_566 .
C12 K1 C12 C13 -5.0(5) 4_566 .
P1 K1 C12 C13 158.8(3) . .
C16 K1 C12 C13 46.8(3) 4_566 .
P2 K1 C12 C13 -106.6(3) . .
C11 K1 C12 C13 125.9(4) . .
C13 K1 C12 C13 52.9(7) 4_566 .
C15 K1 C12 C13 73.1(3) 4_566 .
P1 K1 C12 C13 -4.1(3) 4_566 .
C14 K1 C12 C13 91.6(3) 4_566 .
C11 K1 C12 O1 118.53(16) 4_566 .
C12 K1 C12 O1 98.0(2) 4_566 .
P1 K1 C12 O1 -98.23(16) . .
C16 K1 C12 O1 149.84(15) 4_566 .
P2 K1 C12 O1 -3.61(14) . .
C11 K1 C12 O1 -131.0(3) . .
C13 K1 C12 O1 155.9(5) 4_566 .
C15 K1 C12 O1 176.14(15) 4_566 .
P1 K1 C12 O1 98.93(15) 4_566 .
C14 K1 C12 O1 -165.43(17) 4_566 .
O1 K1 C12 C11 131.0(3) . .
C11 K1 C12 C11 -110.4(2) 4_566 .
C12 K1 C12 C11 -130.9(2) 4_566 .
P1 K1 C12 C11 32.82(15) . .
C16 K1 C12 C11 -79.11(19) 4_566 .
P2 K1 C12 C11 127.44(17) . .
C13 K1 C12 C11 -73.1(6) 4_566 .
C15 K1 C12 C11 -52.8(2) 4_566 .
P1 K1 C12 C11 -130.02(16) 4_566 .
C14 K1 C12 C11 -34.4(3) 4_566 .
O1 K1 C12 K1 84.96(18) . 4_565
C11 K1 C12 K1 -156.51(11) 4_566 4_565
C12 K1 C12 K1 -177.01(9) 4_566 4_565
P1 K1 C12 K1 -13.27(9) . 4_565
C16 K1 C12 K1 -125.20(12) 4_566 4_565
P2 K1 C12 K1 81.35(12) . 4_565
C11 K1 C12 K1 -46.09(16) . 4_565
C13 K1 C12 K1 -119.2(5) 4_566 4_565
C15 K1 C12 K1 -98.90(14) 4_566 4_565
P1 K1 C12 K1 -176.11(10) 4_566 4_565
C14 K1 C12 K1 -80.5(2) 4_566 4_565
O1 C12 C13 C14 -177.2(3) . .
C11 C12 C13 C14 5.7(5) . .
K1 C12 C13 C14 71.7(3) 4_565 .
K1 C12 C13 C14 -102.5(3) . .
O1 C12 C13 C1 7.1(4) . .
C11 C12 C13 C1 -170.1(3) . .
K1 C12 C13 C1 -104.1(3) 4_565 .
K1 C12 C13 C1 81.8(4) . .
O1 C12 C13 K1 111.2(3) . 4_565
C11 C12 C13 K1 -66.0(3) . 4_565
K1 C12 C13 K1 -174.2(3) . 4_565
C23 C1 C13 C12 -7.2(4) . .
C3 C1 C13 C12 -128.8(3) . .
C2 C1 C13 C12 112.3(3) . .
C23 C1 C13 C14 177.2(3) . .
C3 C1 C13 C14 55.6(4) . .
C2 C1 C13 C14 -63.3(4) . .
C23 C1 C13 K1 -82.8(3) . 4_565
C3 C1 C13 K1 155.5(2) . 4_565
C2 C1 C13 K1 36.6(3) . 4_565
C12 C13 C14 C15 0.5(5) . .
C1 C13 C14 C15 176.4(3) . .
K1 C13 C14 C15 61.0(3) 4_565 .
C12 C13 C14 K1 -60.4(2) . 4_565
C1 C13 C14 K1 115.4(3) . 4_565
C13 C14 C15 C16 -2.8(6) . .
K1 C14 C15 C16 55.2(3) 4_565 .
C13 C14 C15 K1 -57.9(3) . 4_565
C14 C15 C16 C11 -1.1(6) . .
K1 C15 C16 C11 60.9(3) 4_565 .
C14 C15 C16 K1 -62.0(4) . 4_565
C12 C11 C16 C15 6.5(5) . .
P1 C11 C16 C15 -166.4(3) . .
K1 C11 C16 C15 -73.7(3) 4_565 .
K1 C11 C16 C15 103.3(4) . .
C12 C11 C16 K1 80.2(2) . 4_565
P1 C11 C16 K1 -92.8(2) . 4_565
K1 C11 C16 K1 177.0(3) . 4_565
C11 P1 C17 C18 63.8(3) . .
K1 P1 C17 C18 152.8(2) . .
K2 P1 C17 C18 -75.0(3) . .
K1 P1 C17 C18 6.2(3) 4_565 .
C11 P1 C17 C19 -65.7(3) . .
K1 P1 C17 C19 23.4(3) . .
K2 P1 C17 C19 155.5(2) . .
K1 P1 C17 C19 -123.2(3) 4_565 .
C11 P1 C17 C20 178.5(2) . .
K1 P1 C17 C20 -92.5(2) . .
K2 P1 C17 C20 39.7(3) . .
K1 P1 C17 C20 120.9(2) 4_565 .
C27 P2 C21 C26 -6.0(3) . .
K1 P2 C21 C26 146.6(3) . .
K2 P2 C21 C26 -120.2(3) . .
K2 P2 C21 C26 76.3(3) 4_566 .
C27 P2 C21 C22 176.1(2) . .
K1 P2 C21 C22 -31.2(2) . .
K2 P2 C21 C22 62.0(2) . .
K2 P2 C21 C22 -101.5(2) 4_566 .
C27 P2 C21 K2 -82.37(11) . 4_566
K1 P2 C21 K2 70.29(5) . 4_566
K2 P2 C21 K2 163.47(4) . 4_566
C12 O1 C22 C23 -4.3(4) . .
K1 O1 C22 C23 -125.4(2) . .
K2 O1 C22 C23 128.9(3) . .
C12 O1 C22 C21 176.5(2) . .
K1 O1 C22 C21 55.4(3) . .
K2 O1 C22 C21 -50.3(3) . .
C26 C21 C22 C23 -4.8(4) . .
P2 C21 C22 C23 173.3(2) . .
K2 C21 C22 C23 84.1(3) 4_566 .
C26 C21 C22 O1 174.4(2) . .
P2 C21 C22 O1 -7.5(3) . .
K2 C21 C22 O1 -96.7(2) 4_566 .
O1 C22 C23 C24 -176.0(3) . .
C21 C22 C23 C24 3.1(5) . .
O1 C22 C23 C1 3.6(5) . .
C21 C22 C23 C1 -177.3(3) . .
C13 C1 C23 C22 2.0(4) . .
C3 C1 C23 C22 123.6(3) . .
C2 C1 C23 C22 -116.6(3) . .
C13 C1 C23 C24 -178.5(3) . .
C3 C1 C23 C24 -56.8(4) . .
C2 C1 C23 C24 63.0(4) . .
C22 C23 C24 C25 1.3(5) . .
C1 C23 C24 C25 -178.3(3) . .
C23 C24 C25 C26 -3.8(5) . .
C24 C25 C26 C21 1.8(5) . .
C24 C25 C26 K2 -77.5(4) . 4_566
C22 C21 C26 C25 2.3(5) . .
P2 C21 C26 C25 -175.7(3) . .
K2 C21 C26 C25 -99.7(3) 4_566 .
C22 C21 C26 K2 102.0(2) . 4_566
P2 C21 C26 K2 -75.9(2) . 4_566
C21 P2 C27 C28 65.5(3) . .
K1 P2 C27 C28 -67.6(3) . .
K2 P2 C27 C28 166.7(2) . .
K2 P2 C27 C28 0.4(2) 4_566 .
C21 P2 C27 C30 -177.6(2) . .
K1 P2 C27 C30 49.3(3) . .
K2 P2 C27 C30 -76.4(2) . .
K2 P2 C27 C30 117.3(2) 4_566 .
C21 P2 C27 C29 -62.0(3) . .
K1 P2 C27 C29 164.89(17) . .
K2 P2 C27 C29 39.2(3) . .
K2 P2 C27 C29 -127.1(2) 4_566 .
C33A O2 C31 C32 -178.5(5) . .
C33B O2 C31 C32 -176.1(8) . .
K2 O2 C31 C32 32.2(6) . .
C31 O2 C33A C34A 81.2(9) . .
K2 O2 C33A C34A -121.8(9) . .
C31 O2 C33B C34B 131.7(19) . .
K2 O2 C33B C34B -71(2) . .
