#------------------------------------------------------------------------------
#$Date: 2016-03-21 09:51:33 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178629 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/40/4074063.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4074063
loop_
_publ_author_name
'Vela, Javier'
'Lief, Graham R.'
'Shen, Zhongliang'
'Jordan, Richard F.'
_publ_section_title
;
 Ethylene Polymerization by Palladium Alkyl Complexes Containing
 Bis(aryl)phosphino-toluenesulfonate Ligands
;
_journal_issue                   26
_journal_name_full               Organometallics
_journal_page_first              6624
_journal_paper_doi               10.1021/om700869c
_journal_volume                  26
_journal_year                    2007
_chemical_formula_moiety         'C30 H36 N O5 P Pd S Si, C1.5 H3 Cl3'
_chemical_formula_sum            'C31.5 H39 Cl3 N O5 P Pd S Si'
_chemical_formula_weight         815.53
_chemical_melting_point          459
_chemical_name_common            1a
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 104.454(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.269(2)
_cell_length_b                   18.043(3)
_cell_length_c                   16.306(3)
_cell_measurement_reflns_used    33584
_cell_measurement_temperature    80(2)
_cell_measurement_theta_max      25.03
_cell_measurement_theta_min      1.71
_cell_volume                     3495.4(10)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      80(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0294
_diffrn_reflns_av_sigmaI/netI    0.0273
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            33584
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         1.71
_exptl_absorpt_coefficient_mu    0.940
_exptl_absorpt_correction_T_max  0.87
_exptl_absorpt_correction_T_min  0.794
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
; 
Blessing,R. H. Acta Cryst. 1995, A51, 33-38 
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.556
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             1675
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.15
_refine_diff_density_max         2.121
_refine_diff_density_min         -0.886
_refine_diff_density_rms         0.086
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     421
_refine_ls_number_reflns         6177
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.023
_refine_ls_R_factor_all          0.0366
_refine_ls_R_factor_gt           0.0325
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0583P)²+2.8405P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0918
_refine_ls_wR_factor_ref         0.0936
_reflns_number_gt                5467
_reflns_number_total             6177
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om700869c-file003.cif
_cod_data_source_block           gram01s
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        3495.6(11)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               4074063
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.6130(3) -0.02488(17) 0.4245(2) 0.0231(7) Uani 1 1 d .
H1 H 0.5558 -0.0088 0.3772 0.028 Uiso 1 1 calc R
C2 C 0.5853(3) -0.07516(18) 0.4800(2) 0.0314(8) Uani 1 1 d .
H2 H 0.5108 -0.0938 0.4706 0.038 Uiso 1 1 calc R
C3 C 0.6683(3) -0.09770(19) 0.5495(2) 0.0349(9) Uani 1 1 d .
H3 H 0.6518 -0.1318 0.5891 0.042 Uiso 1 1 calc R
C4 C 0.7743(3) -0.07013(18) 0.5602(2) 0.0325(8) Uani 1 1 d .
H4 H 0.8327 -0.0847 0.6076 0.039 Uiso 1 1 calc R
C5 C 0.7962(3) -0.02105(17) 0.5018(2) 0.0242(7) Uani 1 1 d .
H5 H 0.8707 -0.0028 0.5096 0.029 Uiso 1 1 calc R
C6 C 0.8978(2) 0.03566(16) 0.34815(19) 0.0180(6) Uani 1 1 d .
H6A H 0.9380 0.0697 0.3182 0.022 Uiso 1 1 calc R
H6B H 0.9403 0.0346 0.4083 0.022 Uiso 1 1 calc R
C7 C 0.7678(3) -0.11270(18) 0.2901(2) 0.0286(8) Uani 1 1 d .
H7A H 0.7055 -0.0843 0.2546 0.043 Uiso 1 1 calc R
H7B H 0.7533 -0.1212 0.3458 0.043 Uiso 1 1 calc R
H7C H 0.7743 -0.1605 0.2630 0.043 Uiso 1 1 calc R
C8 C 1.0170(3) -0.11539(19) 0.3721(2) 0.0328(8) Uani 1 1 d .
H8A H 1.0033 -0.1202 0.4286 0.049 Uiso 1 1 calc R
H8B H 1.0892 -0.0904 0.3767 0.049 Uiso 1 1 calc R
H8C H 1.0190 -0.1647 0.3474 0.049 Uiso 1 1 calc R
C9 C 0.9355(3) -0.0523(2) 0.1978(2) 0.0346(8) Uani 1 1 d .
H9A H 0.9540 -0.1016 0.1797 0.052 Uiso 1 1 calc R
H9B H 1.0000 -0.0192 0.2025 0.052 Uiso 1 1 calc R
H9C H 0.8703 -0.0324 0.1561 0.052 Uiso 1 1 calc R
C10 C 0.9054(2) 0.19102(16) 0.25293(19) 0.0167(6) Uani 1 1 d .
C11 C 0.9635(3) 0.16942(17) 0.1938(2) 0.0204(6) Uani 1 1 d .
H11 H 0.9236 0.1471 0.1423 0.025 Uiso 1 1 calc R
C12 C 1.0786(3) 0.17992(17) 0.2086(2) 0.0241(7) Uani 1 1 d .
H12 H 1.1173 0.1646 0.1678 0.029 Uiso 1 1 calc R
C13 C 1.1363(3) 0.21268(17) 0.2829(2) 0.0240(7) Uani 1 1 d .
H13 H 1.2152 0.2199 0.2931 0.029 Uiso 1 1 calc R
C14 C 1.0813(2) 0.23531(17) 0.3427(2) 0.0213(7) Uani 1 1 d .
H14 H 1.1219 0.2585 0.3935 0.026 Uiso 1 1 calc R
C15 C 0.9660(2) 0.22384(16) 0.32827(19) 0.0185(6) Uani 1 1 d .
C16 C 0.9640(3) 0.2745(2) 0.4628(2) 0.0357(9) Uani 1 1 d .
H16A H 1.0202 0.2397 0.4945 0.054 Uiso 1 1 calc R
H16B H 0.9105 0.2869 0.4965 0.054 Uiso 1 1 calc R
H16C H 1.0016 0.3198 0.4510 0.054 Uiso 1 1 calc R
C17 C 0.7142(2) 0.12692(17) 0.13547(19) 0.0196(6) Uani 1 1 d .
C18 C 0.6815(3) 0.05315(19) 0.1232(2) 0.0252(7) Uani 1 1 d .
H18 H 0.6864 0.0221 0.1710 0.030 Uiso 1 1 calc R
C19 C 0.6422(3) 0.0241(2) 0.0433(2) 0.0334(8) Uani 1 1 d .
H19 H 0.6203 -0.0264 0.0360 0.040 Uiso 1 1 calc R
C20 C 0.6349(3) 0.0692(2) -0.0262(2) 0.0368(9) Uani 1 1 d .
H20 H 0.6082 0.0492 -0.0814 0.044 Uiso 1 1 calc R
C21 C 0.6656(3) 0.1426(2) -0.0169(2) 0.0290(8) Uani 1 1 d .
H21 H 0.6596 0.1731 -0.0653 0.035 Uiso 1 1 calc R
C22 C 0.7054(2) 0.17180(18) 0.06404(19) 0.0210(7) Uani 1 1 d .
C23 C 0.7003(3) 0.2958(2) 0.0115(2) 0.0305(8) Uani 1 1 d .
H23A H 0.7370 0.2854 -0.0342 0.046 Uiso 1 1 calc R
H23B H 0.7192 0.3461 0.0328 0.046 Uiso 1 1 calc R
H23C H 0.6185 0.2914 -0.0102 0.046 Uiso 1 1 calc R
C24 C 0.6779(2) 0.24433(16) 0.24716(18) 0.0170(6) Uani 1 1 d .
C25 C 0.5681(2) 0.23925(17) 0.25777(18) 0.0181(6) Uani 1 1 d .
C26 C 0.5065(3) 0.30339(18) 0.25944(19) 0.0219(7) Uani 1 1 d .
H26 H 0.4317 0.3000 0.2655 0.026 Uiso 1 1 calc R
C27 C 0.5527(3) 0.37198(18) 0.25234(19) 0.0237(7) Uani 1 1 d .
H27 H 0.5091 0.4153 0.2536 0.028 Uiso 1 1 calc R
C28 C 0.6619(3) 0.37884(17) 0.2433(2) 0.0233(7) Uani 1 1 d .
C29 C 0.7226(3) 0.31401(17) 0.24020(19) 0.0209(7) Uani 1 1 d .
H29 H 0.7970 0.3177 0.2331 0.025 Uiso 1 1 calc R
C30 C 0.7121(3) 0.45321(19) 0.2372(3) 0.0374(9) Uani 1 1 d .
H30A H 0.7831 0.4577 0.2807 0.056 Uiso 1 1 calc R
H30B H 0.6598 0.4918 0.2456 0.056 Uiso 1 1 calc R
H30C H 0.7266 0.4590 0.1810 0.056 Uiso 1 1 calc R
C31 C 0.3926(4) 0.1928(3) 0.0404(3) 0.0695(16) Uani 1 1 d .
H31A H 0.4624 0.2207 0.0655 0.083 Uiso 1 1 calc R
H31B H 0.4039 0.1412 0.0614 0.083 Uiso 1 1 calc R
C32 C 0.0863(8) 0.9721(5) 0.0161(6) 0.041(2) Uani 0.50 1 d P
H32A H 0.1212 0.9515 -0.0275 0.050 Uiso 0.50 1 calc PR
H32B H 0.1003 0.9370 0.0643 0.050 Uiso 0.50 1 calc PR
Cl1 Cl 0.28186(9) 0.23202(7) 0.07449(6) 0.0523(3) Uani 1 1 d .
Cl2 Cl 0.37115(10) 0.19222(7) -0.06742(6) 0.0580(3) Uani 1 1 d .
Cl3 Cl 0.1491(2) 1.05920(12) 0.05127(15) 0.0561(6) Uani 0.50 1 d P
Cl4 Cl 0.0594(2) 1.0183(2) 0.02642(17) 0.0672(7) Uani 0.50 1 d P
N1 N 0.7173(2) 0.00210(13) 0.43468(15) 0.0175(5) Uani 1 1 d .
O1 O 0.90517(17) 0.24135(12) 0.38502(13) 0.0216(5) Uani 1 1 d .
O2 O 0.73866(18) 0.24350(12) 0.07907(13) 0.0249(5) Uani 1 1 d .
O3 O 0.58188(16) 0.12181(11) 0.34980(13) 0.0191(4) Uani 1 1 d .
O4 O 0.39777(17) 0.17163(13) 0.28977(14) 0.0257(5) Uani 1 1 d .
O5 O 0.49871(17) 0.10816(13) 0.20005(13) 0.0250(5) Uani 1 1 d .
P1 P 0.76197(6) 0.16090(4) 0.24316(5) 0.01554(17) Uani 1 1 d .
Pd1 Pd 0.742204(17) 0.078830(12) 0.341752(13) 0.01422(9) Uani 1 1 d .
S1 S 0.50393(6) 0.15354(4) 0.27334(5) 0.01906(17) Uani 1 1 d .
Si1 Si 0.90155(7) -0.05975(5) 0.30300(6) 0.02053(19) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
N1 C1 C2 122.7(3) .
C3 C2 C1 118.6(3) .
C4 C3 C2 118.8(3) .
C3 C4 C5 119.4(3) .
N1 C5 C4 122.9(3) .
Si1 C6 Pd1 116.37(15) .
C11 C10 C15 118.4(3) .
C11 C10 P1 120.7(2) .
C15 C10 P1 119.7(2) .
C12 C11 C10 121.2(3) .
C13 C12 C11 119.4(3) .
C12 C13 C14 121.0(3) .
C13 C14 C15 119.5(3) .
O1 C15 C14 123.8(3) .
O1 C15 C10 115.7(2) .
C14 C15 C10 120.5(3) .
C18 C17 C22 118.3(3) .
C18 C17 P1 118.4(2) .
C22 C17 P1 123.3(2) .
C19 C18 C17 121.4(3) .
C18 C19 C20 119.3(3) .
C21 C20 C19 121.2(3) .
C20 C21 C22 119.4(3) .
O2 C22 C21 123.3(3) .
O2 C22 C17 116.3(3) .
C21 C22 C17 120.4(3) .
C29 C24 C25 118.7(3) .
C29 C24 P1 120.2(2) .
C25 C24 P1 121.1(2) .
C26 C25 C24 119.5(3) .
C26 C25 S1 117.4(2) .
C24 C25 S1 123.1(2) .
C27 C26 C25 120.7(3) .
C26 C27 C28 121.1(3) .
C27 C28 C29 117.9(3) .
C27 C28 C30 120.9(3) .
C29 C28 C30 121.2(3) .
C24 C29 C28 122.0(3) .
Cl2 C31 Cl1 113.4(3) .
Cl4 C32 Cl3 110.9(6) 3_575
C5 N1 C1 117.5(3) .
C5 N1 Pd1 125.7(2) .
C1 N1 Pd1 116.8(2) .
C15 O1 C16 117.4(2) .
C22 O2 C23 117.4(2) .
S1 O3 Pd1 119.73(11) .
C10 P1 C17 105.01(14) .
C10 P1 C24 107.06(13) .
C17 P1 C24 105.25(13) .
C10 P1 Pd1 114.31(10) .
C17 P1 Pd1 113.84(10) .
C24 P1 Pd1 110.71(9) .
C6 Pd1 N1 90.81(11) .
C6 Pd1 O3 173.64(10) .
N1 Pd1 O3 83.97(8) .
C6 Pd1 P1 91.23(9) .
N1 Pd1 P1 177.94(7) .
O3 Pd1 P1 94.01(6) .
O4 S1 O5 115.59(13) .
O4 S1 O3 110.88(12) .
O5 S1 O3 111.38(13) .
O4 S1 C25 106.48(14) .
O5 S1 C25 107.80(13) .
O3 S1 C25 103.86(13) .
C7 Si1 C8 107.83(16) .
C7 Si1 C9 108.93(17) .
C8 Si1 C9 106.46(17) .
C7 Si1 C6 114.03(14) .
C8 Si1 C6 110.20(15) .
C9 Si1 C6 109.11(16) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.340(4) .
C1 C2 1.383(4) .
C2 C3 1.382(5) .
C3 C4 1.363(5) .
C4 C5 1.375(5) .
C5 N1 1.334(4) .
C6 Si1 1.877(3) .
C6 Pd1 2.041(3) .
C7 Si1 1.865(3) .
C8 Si1 1.868(3) .
C9 Si1 1.868(4) .
C10 C11 1.391(4) .
C10 C15 1.399(4) .
C10 P1 1.811(3) .
C11 C12 1.384(4) .
C12 C13 1.374(5) .
C13 C14 1.380(5) .
C14 C15 1.391(4) .
C15 O1 1.363(4) .
C16 O1 1.425(4) .
C17 C18 1.390(5) .
C17 C22 1.401(4) .
C17 P1 1.814(3) .
C18 C19 1.375(5) .
C19 C20 1.379(5) .
C20 C21 1.375(5) .
C21 C22 1.391(4) .
C22 O2 1.360(4) .
C23 O2 1.438(4) .
C24 C29 1.388(4) .
C24 C25 1.403(4) .
C24 P1 1.835(3) .
C25 C26 1.386(4) .
C25 S1 1.782(3) .
C26 C27 1.378(5) .
C27 C28 1.389(4) .
C28 C29 1.395(4) .
C28 C30 1.491(5) .
C31 Cl2 1.711(4) .
C31 Cl1 1.742(5) .
C32 Cl4 1.757(9) 3_575
C32 Cl3 1.781(9) .
Cl4 Cl4 1.636(6) 3_575
Cl4 C32 1.757(9) 3_575
N1 Pd1 2.130(2) .
O3 S1 1.484(2) .
O3 Pd1 2.149(2) .
O4 S1 1.431(2) .
O5 S1 1.437(2) .
P1 Pd1 2.2430(8) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
N1 C1 C2 C3 0.9(5)
C1 C2 C3 C4 -0.6(5)
C2 C3 C4 C5 -0.2(5)
C3 C4 C5 N1 0.9(5)
C15 C10 C11 C12 0.0(4)
P1 C10 C11 C12 -167.6(2)
C10 C11 C12 C13 -0.4(5)
C11 C12 C13 C14 -0.1(5)
C12 C13 C14 C15 0.9(5)
C13 C14 C15 O1 177.1(3)
C13 C14 C15 C10 -1.3(4)
C11 C10 C15 O1 -177.7(3)
P1 C10 C15 O1 -10.0(4)
C11 C10 C15 C14 0.8(4)
P1 C10 C15 C14 168.6(2)
C22 C17 C18 C19 0.5(5)
P1 C17 C18 C19 178.7(3)
C17 C18 C19 C20 -0.1(5)
C18 C19 C20 C21 -0.4(6)
C19 C20 C21 C22 0.5(5)
C20 C21 C22 O2 179.3(3)
C20 C21 C22 C17 -0.1(5)
C18 C17 C22 O2 -179.8(3)
P1 C17 C22 O2 2.1(4)
C18 C17 C22 C21 -0.4(4)
P1 C17 C22 C21 -178.5(2)
C29 C24 C25 C26 1.2(4)
P1 C24 C25 C26 -179.2(2)
C29 C24 C25 S1 -176.4(2)
P1 C24 C25 S1 3.2(4)
C24 C25 C26 C27 -1.2(4)
S1 C25 C26 C27 176.6(2)
C25 C26 C27 C28 0.0(5)
C26 C27 C28 C29 1.1(5)
C26 C27 C28 C30 -178.9(3)
C25 C24 C29 C28 -0.1(4)
P1 C24 C29 C28 -179.7(2)
C27 C28 C29 C24 -1.1(5)
C30 C28 C29 C24 179.0(3)
C4 C5 N1 C1 -0.6(5)
C4 C5 N1 Pd1 179.2(2)
C2 C1 N1 C5 -0.3(4)
C2 C1 N1 Pd1 179.9(2)
C14 C15 O1 C16 1.2(4)
C10 C15 O1 C16 179.6(3)
C21 C22 O2 C23 19.0(4)
C17 C22 O2 C23 -161.6(3)
C11 C10 P1 C17 -15.5(3)
C15 C10 P1 C17 177.0(2)
C11 C10 P1 C24 -127.0(2)
C15 C10 P1 C24 65.5(3)
C11 C10 P1 Pd1 110.0(2)
C15 C10 P1 Pd1 -57.5(3)
C18 C17 P1 C10 119.3(2)
C22 C17 P1 C10 -62.6(3)
C18 C17 P1 C24 -127.9(2)
C22 C17 P1 C24 50.2(3)
C18 C17 P1 Pd1 -6.4(3)
C22 C17 P1 Pd1 171.6(2)
C29 C24 P1 C10 12.1(3)
C25 C24 P1 C10 -167.5(2)
C29 C24 P1 C17 -99.2(3)
C25 C24 P1 C17 81.2(3)
C29 C24 P1 Pd1 137.3(2)
C25 C24 P1 Pd1 -42.3(3)
Si1 C6 Pd1 N1 70.34(16)
Si1 C6 Pd1 P1 -109.38(15)
C5 N1 Pd1 C6 37.1(3)
C1 N1 Pd1 C6 -143.1(2)
C5 N1 Pd1 O3 -139.2(3)
C1 N1 Pd1 O3 40.6(2)
S1 O3 Pd1 N1 -146.93(15)
S1 O3 Pd1 P1 32.65(13)
C10 P1 Pd1 C6 -31.68(14)
C17 P1 Pd1 C6 89.00(13)
C24 P1 Pd1 C6 -152.68(13)
C10 P1 Pd1 O3 144.72(12)
C17 P1 Pd1 O3 -94.60(12)
C24 P1 Pd1 O3 23.72(12)
Pd1 O3 S1 O4 173.80(13)
Pd1 O3 S1 O5 43.58(17)
Pd1 O3 S1 C25 -72.19(16)
C26 C25 S1 O4 -3.2(3)
C24 C25 S1 O4 174.4(2)
C26 C25 S1 O5 121.4(2)
C24 C25 S1 O5 -61.0(3)
C26 C25 S1 O3 -120.4(2)
C24 C25 S1 O3 57.3(3)
Pd1 C6 Si1 C7 -18.3(2)
Pd1 C6 Si1 C8 -139.74(17)
Pd1 C6 Si1 C9 103.71(19)
