#------------------------------------------------------------------------------
#$Date: 2016-03-21 09:59:01 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178631 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/42/4074216.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4074216
loop_
_publ_author_name
'Bravo-Zhivotovskii, Dmitry'
'Molev, Gregory'
'Kravchenko, Victoria'
'Botoshansky, Mark'
'Schmidt, Asher'
'Apeloig, Yitzhak'
_publ_section_title
;
 Novel Aggregation Motif ofgem-Dilithiosilanes:  Coaggregation of
 Two R2SiLi2Molecules with Two RLi Molecules
;
_journal_issue                   20
_journal_name_full               Organometallics
_journal_page_first              4719
_journal_paper_doi               10.1021/om060469o
_journal_volume                  25
_journal_year                    2006
_chemical_formula_sum            'C24 H57 Li3 Si4'
_chemical_formula_weight         478.88
_chemical_name_common            Dimitry-80new
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 105.34(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.820(2)
_cell_length_b                   22.377(4)
_cell_length_c                   12.775(3)
_cell_measurement_reflns_used    19610
_cell_measurement_temperature    140(2)
_cell_measurement_theta_max      25.0
_cell_measurement_theta_min      1.82
_cell_volume                     3258.6(12)
_computing_cell_refinement       'DENZO SMN (Otwinowski & Minor 1997)'
_computing_data_collection       'Collect (Nonius, 2001)'
_computing_data_reduction        'DENZO SMN (Otwinowski & Minor 1997)'
_computing_molecular_graphics    'TEXSAN  (MSC, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      140(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       phi-scan
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1720
_diffrn_reflns_av_sigmaI/netI    0.1721
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            18916
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.82
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.191
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    0.976
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1064
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.03
_refine_diff_density_max         2.859
_refine_diff_density_min         -0.464
_refine_diff_density_rms         0.124
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.086
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     280
_refine_ls_number_reflns         5723
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.086
_refine_ls_R_factor_all          0.2247
_refine_ls_R_factor_gt           0.1270
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1931P)²+0.1007P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3127
_refine_ls_wR_factor_ref         0.3594
_reflns_number_gt                2850
_reflns_number_total             5723
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om060469osi20060713_041504.cif
_cod_data_source_block           Dimitry80
_cod_original_cell_volume        3258.6(11)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4074216
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Si1 Si 0.06207(17) 0.09432(9) 0.52701(16) 0.0228(5) Uani 1 1 d .
Si2 Si -0.0026(2) 0.17944(10) 0.60791(18) 0.0324(6) Uani 1 1 d .
Si3 Si 0.2503(2) 0.09105(11) 0.4999(2) 0.0382(7) Uani 1 1 d .
Si4 Si 0.23733(19) -0.05738(10) 0.82298(17) 0.0319(6) Uani 1 1 d .
C1 C 0.1134(9) 0.2404(4) 0.6489(8) 0.061(3) Uani 1 1 d .
H1A H 0.1815 0.2245 0.6997 0.092 Uiso 1 1 calc R
H1B H 0.0824 0.2729 0.6820 0.092 Uiso 1 1 calc R
H1C H 0.1345 0.2546 0.5857 0.092 Uiso 1 1 calc R
C2 C -0.1286(8) 0.2204(4) 0.5076(7) 0.046(2) Uani 1 1 d .
C3 C -0.0837(9) 0.2465(4) 0.4200(8) 0.057(3) Uani 1 1 d .
H3A H -0.0468 0.2158 0.3881 0.085 Uiso 1 1 calc R
H3B H -0.0276 0.2771 0.4495 0.085 Uiso 1 1 calc R
H3C H -0.1477 0.2634 0.3655 0.085 Uiso 1 1 calc R
C4 C -0.1854(9) 0.2713(4) 0.5568(9) 0.062(3) Uani 1 1 d .
H4A H -0.2157 0.2557 0.6140 0.093 Uiso 1 1 calc R
H4B H -0.2483 0.2885 0.5015 0.093 Uiso 1 1 calc R
H4C H -0.1277 0.3014 0.5855 0.093 Uiso 1 1 calc R
C5 C -0.2312(8) 0.1759(4) 0.4558(7) 0.047(2) Uani 1 1 d .
H5A H -0.2606 0.1584 0.5121 0.071 Uiso 1 1 calc R
H5B H -0.2025 0.1449 0.4177 0.071 Uiso 1 1 calc R
H5C H -0.2933 0.1971 0.4061 0.071 Uiso 1 1 calc R
C6 C -0.0427(7) 0.1605(4) 0.7392(6) 0.036(2) Uani 1 1 d .
C7 C -0.0336(12) 0.2163(5) 0.8164(9) 0.084(4) Uani 1 1 d .
H7A H 0.0431 0.2336 0.8295 0.126 Uiso 1 1 calc R
H7B H -0.0470 0.2039 0.8841 0.126 Uiso 1 1 calc R
H7C H -0.0915 0.2454 0.7826 0.126 Uiso 1 1 calc R
C8 C -0.1650(9) 0.1365(6) 0.7252(9) 0.076(4) Uani 1 1 d .
H8A H -0.2208 0.1635 0.6811 0.115 Uiso 1 1 calc R
H8B H -0.1803 0.1326 0.7950 0.115 Uiso 1 1 calc R
H8C H -0.1716 0.0980 0.6907 0.115 Uiso 1 1 calc R
C9 C 0.0400(9) 0.1150(4) 0.8081(7) 0.055(3) Uani 1 1 d .
H9A H 0.1194 0.1287 0.8206 0.082 Uiso 1 1 calc R
H9B H 0.0314 0.0773 0.7709 0.082 Uiso 1 1 calc R
H9C H 0.0214 0.1103 0.8764 0.082 Uiso 1 1 calc R
C10 C 0.2867(10) 0.0078(4) 0.4920(10) 0.067(3) Uani 1 1 d .
H10A H 0.2257 -0.0112 0.4374 0.101 Uiso 1 1 calc R
H10B H 0.2926 -0.0107 0.5610 0.101 Uiso 1 1 calc R
H10C H 0.3600 0.0038 0.4736 0.101 Uiso 1 1 calc R
C11 C 0.3812(7) 0.1208(4) 0.6124(7) 0.044(2) Uani 1 1 d .
C12 C 0.4001(11) 0.1862(5) 0.6092(10) 0.091(5) Uani 1 1 d .
H12A H 0.3284 0.2067 0.6080 0.137 Uiso 1 1 calc R
H12B H 0.4240 0.1962 0.5451 0.137 Uiso 1 1 calc R
H12C H 0.4600 0.1981 0.6723 0.137 Uiso 1 1 calc R
C13 C 0.3555(8) 0.1070(4) 0.7244(7) 0.050(2) Uani 1 1 d .
H13A H 0.3426 0.0649 0.7300 0.075 Uiso 1 1 calc R
H13B H 0.2869 0.1286 0.7295 0.075 Uiso 1 1 calc R
H13C H 0.4214 0.1192 0.7823 0.075 Uiso 1 1 calc R
C14 C 0.4952(10) 0.0872(6) 0.6148(11) 0.087(4) Uani 1 1 d .
H14A H 0.4823 0.0450 0.6182 0.130 Uiso 1 1 calc R
H14B H 0.5556 0.0994 0.6773 0.130 Uiso 1 1 calc R
H14C H 0.5189 0.0963 0.5502 0.130 Uiso 1 1 calc R
C15 C 0.2567(8) 0.1172(5) 0.3558(8) 0.058(3) Uani 1 1 d .
C16 C 0.1834(11) 0.0789(7) 0.2711(10) 0.105(5) Uani 1 1 d .
H16A H 0.1050 0.0776 0.2794 0.157 Uiso 1 1 calc R
H16B H 0.2154 0.0392 0.2777 0.157 Uiso 1 1 calc R
H16C H 0.1818 0.0947 0.2009 0.157 Uiso 1 1 calc R
C17 C 0.3798(9) 0.1170(5) 0.3384(9) 0.069(3) Uani 1 1 d .
H17A H 0.4296 0.1433 0.3900 0.104 Uiso 1 1 calc R
H17B H 0.3759 0.1304 0.2661 0.104 Uiso 1 1 calc R
H17C H 0.4112 0.0773 0.3482 0.104 Uiso 1 1 calc R
C18 C 0.2074(10) 0.1832(6) 0.3378(11) 0.095(5) Uani 1 1 d .
H18A H 0.2542 0.2089 0.3926 0.143 Uiso 1 1 calc R
H18B H 0.1276 0.1838 0.3424 0.143 Uiso 1 1 calc R
H18C H 0.2103 0.1970 0.2674 0.143 Uiso 1 1 calc R
C19 C 0.3863(7) -0.0778(4) 0.8051(7) 0.041(2) Uani 1 1 d .
H19A H 0.3781 -0.0908 0.7318 0.061 Uiso 1 1 calc R
H19B H 0.4197 -0.1095 0.8543 0.061 Uiso 1 1 calc R
H19C H 0.4369 -0.0435 0.8201 0.061 Uiso 1 1 calc R
C20 C 0.1685(9) -0.1387(4) 0.8312(8) 0.054(3) Uani 1 1 d .
H20A H 0.0910 -0.1345 0.8409 0.080 Uiso 1 1 calc R
H20B H 0.2171 -0.1602 0.8915 0.080 Uiso 1 1 calc R
H20C H 0.1645 -0.1601 0.7653 0.080 Uiso 1 1 calc R
C21 C 0.2575(7) -0.0319(5) 0.9700(7) 0.046(2) Uani 1 1 d .
C22 C 0.1409(7) -0.0281(4) 0.9964(7) 0.042(2) Uani 1 1 d .
H22A H 0.1054 -0.0670 0.9897 0.063 Uiso 1 1 calc R
H22B H 0.0906 -0.0010 0.9470 0.063 Uiso 1 1 calc R
H22C H 0.1525 -0.0139 1.0694 0.063 Uiso 1 1 calc R
C23 C 0.3394(8) -0.0751(5) 1.0540(7) 0.054(3) Uani 1 1 d .
H23A H 0.4147 -0.0775 1.0389 0.081 Uiso 1 1 calc R
H23B H 0.3047 -0.1142 1.0481 0.081 Uiso 1 1 calc R
H23C H 0.3489 -0.0601 1.1262 0.081 Uiso 1 1 calc R
C24 C 0.3161(9) 0.0302(4) 0.9826(8) 0.061(3) Uani 1 1 d .
H24A H 0.3910 0.0274 0.9670 0.091 Uiso 1 1 calc R
H24B H 0.3267 0.0441 1.0557 0.091 Uiso 1 1 calc R
H24C H 0.2671 0.0578 0.9331 0.091 Uiso 1 1 calc R
Li1 Li 0.1027(13) -0.0164(7) 0.5171(18) 0.062(5) Uani 1 1 d .
Li2 Li -0.0498(15) 0.0919(7) 0.3245(12) 0.051(4) Uani 1 1 d .
Li3 Li 0.1480(13) 0.0427(7) 0.7152(11) 0.044(4) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Si3 Si1 Si2 120.97(12) . .
Si3 Si1 Li1 76.2(3) . .
Si2 Si1 Li1 152.7(5) . .
Si3 Si1 Li1 130.0(4) . 3_556
Si2 Si1 Li1 109.0(4) . 3_556
Li1 Si1 Li1 57.8(6) . 3_556
Si3 Si1 Li2 96.1(4) . .
Si2 Si1 Li2 108.3(4) . .
Li1 Si1 Li2 89.0(6) . .
Li1 Si1 Li2 66.9(6) 3_556 .
Si3 Si1 Li3 88.2(4) . .
Si2 Si1 Li3 92.6(3) . .
Li1 Si1 Li3 65.3(6) . .
Li1 Si1 Li3 89.4(6) 3_556 .
Li2 Si1 Li3 152.2(5) . .
C1 Si2 C6 104.2(4) . .
C1 Si2 C2 102.5(4) . .
C6 Si2 C2 111.3(4) . .
C1 Si2 Si1 113.6(4) . .
C6 Si2 Si1 112.7(3) . .
C2 Si2 Si1 111.9(3) . .
C11 Si3 C10 103.1(5) . .
C11 Si3 C15 112.0(4) . .
C10 Si3 C15 100.1(5) . .
C11 Si3 Si1 119.0(3) . .
C10 Si3 Si1 105.8(3) . .
C15 Si3 Si1 113.9(3) . .
C11 Si3 Li1 125.9(5) . .
C10 Si3 Li1 51.1(4) . .
C15 Si3 Li1 118.4(5) . .
Si1 Si3 Li1 54.8(3) . .
C19 Si4 C21 108.2(4) . .
C19 Si4 C20 101.0(4) . .
C21 Si4 C20 99.5(4) . .
C19 Si4 Li2 118.7(5) . 3_556
C21 Si4 Li2 131.0(5) . 3_556
C20 Si4 Li2 59.5(4) . 3_556
C19 Si4 Li3 113.0(4) . .
C21 Si4 Li3 100.6(4) . .
C20 Si4 Li3 132.1(4) . .
Li2 Si4 Li3 74.6(5) 3_556 .
Si2 C1 H1A 109.5 . .
Si2 C1 H1B 109.5 . .
H1A C1 H1B 109.5 . .
Si2 C1 H1C 109.5 . .
H1A C1 H1C 109.5 . .
H1B C1 H1C 109.5 . .
C3 C2 C4 107.4(8) . .
C3 C2 C5 108.8(7) . .
C4 C2 C5 105.6(8) . .
C3 C2 Si2 108.8(7) . .
C4 C2 Si2 115.2(6) . .
C5 C2 Si2 110.7(6) . .
C2 C3 H3A 109.5 . .
C2 C3 H3B 109.5 . .
H3A C3 H3B 109.5 . .
C2 C3 H3C 109.5 . .
H3A C3 H3C 109.5 . .
H3B C3 H3C 109.5 . .
C2 C4 H4A 109.5 . .
C2 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
C2 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
C2 C5 H5A 109.5 . .
C2 C5 H5B 109.5 . .
H5A C5 H5B 109.5 . .
C2 C5 H5C 109.5 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
C8 C6 C9 106.2(8) . .
C8 C6 C7 105.1(8) . .
C9 C6 C7 104.0(8) . .
C8 C6 Si2 115.4(6) . .
C9 C6 Si2 112.7(6) . .
C7 C6 Si2 112.5(7) . .
C6 C7 H7A 109.5 . .
C6 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C6 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C6 C8 H8A 109.5 . .
C6 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C6 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C6 C9 H9A 109.5 . .
C6 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C6 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
Si3 C10 H10A 109.5 . .
Si3 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
Si3 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C12 C11 C14 110.2(9) . .
C12 C11 C13 106.6(9) . .
C14 C11 C13 105.4(8) . .
C12 C11 Si3 114.6(7) . .
C14 C11 Si3 111.9(7) . .
C13 C11 Si3 107.5(6) . .
C11 C12 H12A 109.5 . .
C11 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C11 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C11 C13 H13A 109.5 . .
C11 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C11 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
C11 C14 H14A 109.5 . .
C11 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C11 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C16 C15 C17 106.9(9) . .
C16 C15 C18 108.4(10) . .
C17 C15 C18 108.0(9) . .
C16 C15 Si3 110.9(8) . .
C17 C15 Si3 114.3(7) . .
C18 C15 Si3 108.2(7) . .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C15 C17 H17A 109.5 . .
C15 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C15 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C15 C18 H18A 109.5 . .
C15 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C15 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
Si4 C19 H19A 109.5 . .
Si4 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
Si4 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
Si4 C20 H20A 109.5 . .
Si4 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
Si4 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C22 C21 C24 109.8(8) . .
C22 C21 C23 108.5(7) . .
C24 C21 C23 107.7(8) . .
C22 C21 Si4 110.6(6) . .
C24 C21 Si4 107.9(6) . .
C23 C21 Si4 112.3(7) . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C21 C23 H23A 109.5 . .
C21 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C21 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C21 C24 H24A 109.5 . .
C21 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C21 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
Li1 Li1 Si1 61.8(6) 3_556 .
Li1 Li1 Si1 60.5(6) 3_556 3_556
Si1 Li1 Si1 122.2(6) . 3_556
Li1 Li1 Li3 87.9(10) 3_556 .
Si1 Li1 Li3 58.9(5) . .
Si1 Li1 Li3 118.4(7) 3_556 .
Li1 Li1 Li2 84.8(9) 3_556 3_556
Si1 Li1 Li2 117.9(8) . 3_556
Si1 Li1 Li2 56.8(4) 3_556 3_556
Li3 Li1 Li2 70.0(7) . 3_556
Li1 Li1 Si3 108.2(9) 3_556 .
Si1 Li1 Si3 49.0(3) . .
Si1 Li1 Si3 161.4(9) 3_556 .
Li3 Li1 Si3 73.2(5) . .
Li2 Li1 Si3 140.4(8) 3_556 .
C20 Li2 Si1 150.7(7) 3_556 .
C20 Li2 Si4 47.2(4) 3_556 3_556
Si1 Li2 Si4 147.3(7) . 3_556
C20 Li2 Li1 132.4(8) 3_556 3_556
Si1 Li2 Li1 56.4(5) . 3_556
Si4 Li2 Li1 91.9(6) 3_556 3_556
C20 Li2 Li3 99.9(6) 3_556 3_556
Si1 Li2 Li3 104.2(6) . 3_556
Si4 Li2 Li3 53.8(4) 3_556 3_556
Li1 Li2 Li3 54.2(5) 3_556 3_556
Si1 Li3 Si4 147.2(6) . .
Si1 Li3 Li1 55.9(5) . .
Si4 Li3 Li1 91.5(6) . .
Si1 Li3 Li2 103.4(5) . 3_556
Si4 Li3 Li2 51.6(4) . 3_556
Li1 Li3 Li2 55.8(5) . 3_556
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Si1 Si3 2.342(3) .
Si1 Si2 2.387(3) .
Si1 Li1 2.532(15) .
Si1 Li1 2.564(14) 3_556
Si1 Li2 2.575(15) .
Si1 Li3 2.618(14) .
Si2 C1 1.907(9) .
Si2 C6 1.907(8) .
Si2 C2 1.921(8) .
Si3 C11 1.931(9) .
Si3 C10 1.920(9) .
Si3 C15 1.952(9) .
Si3 Li1 3.012(14) .
Si4 C19 1.891(8) .
Si4 C21 1.917(9) .
Si4 C20 2.006(9) .
Si4 Li2 2.618(16) 3_556
Si4 Li3 2.693(15) .
C1 H1A 0.9600 .
C1 H1B 0.9600 .
C1 H1C 0.9600 .
C2 C3 1.480(13) .
C2 C4 1.537(12) .
C2 C5 1.574(12) .
C3 H3A 0.9600 .
C3 H3B 0.9600 .
C3 H3C 0.9600 .
C4 H4A 0.9600 .
C4 H4B 0.9600 .
C4 H4C 0.9600 .
C5 H5A 0.9600 .
C5 H5B 0.9600 .
C5 H5C 0.9600 .
C6 C8 1.507(13) .
C6 C9 1.520(12) .
C6 C7 1.578(12) .
C7 H7A 0.9600 .
C7 H7B 0.9600 .
C7 H7C 0.9600 .
C8 H8A 0.9600 .
C8 H8B 0.9600 .
C8 H8C 0.9600 .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
C11 C12 1.483(14) .
C11 C14 1.536(14) .
C11 C13 1.570(12) .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C13 H13A 0.9600 .
C13 H13B 0.9600 .
C13 H13C 0.9600 .
C14 H14A 0.9600 .
C14 H14B 0.9600 .
C14 H14C 0.9600 .
C15 C16 1.470(15) .
C15 C17 1.530(12) .
C15 C18 1.582(15) .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C17 H17A 0.9600 .
C17 H17B 0.9600 .
C17 H17C 0.9600 .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C21 C22 1.505(11) .
C21 C24 1.542(13) .
C21 C23 1.573(11) .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
Li1 Li1 2.46(3) 3_556
Li1 Si1 2.564(14) 3_556
Li1 Li3 2.78(2) .
Li1 Li2 2.83(2) 3_556
Li2 C20 2.355(18) 3_556
Li2 Si4 2.618(16) 3_556
Li2 Li1 2.83(2) 3_556
Li2 Li3 3.22(2) 3_556
Li3 Li2 3.22(2) 3_556
