#------------------------------------------------------------------------------
#$Date: 2016-03-21 10:25:19 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178650 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/61/4076159.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4076159
loop_
_publ_author_name
'Song, Li-Cheng'
'Jin, Guo-Xia'
'Wang, Hu-Ting'
'Zhang, Wen-Xiong'
'Hu, Qing-Mei'
_publ_section_title
;
 Self-Assembly of Cationic Pd(II)/Pt(II) Metallomacrocycles Containing
 Tetrahedral C2Co2Clusters from Rigid Cluster-Bridged Bipyridine
 (4-C5H4N)2C2Co2(CO)6and Diphosphine- or Diarsine-Chelated Pd(II)/Pt(II)
 Complexes [M(dppb)(H2O)2][OTf]2(M = Pd, Pt), [Pd(dpab)(H2O)(OTf)][OTf],
 and [Pt(dpab)(H2O)2][OTf]2
;
_journal_issue                   26
_journal_name_full               Organometallics
_journal_page_first              6464
_journal_paper_doi               10.1021/om050668s
_journal_volume                  24
_journal_year                    2005
_chemical_formula_sum            'C104 H80 As4 Cl24 Co4 F12 N4 O24 Pd2 S4'
_chemical_formula_weight         3724.96
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                113.761(4)
_cell_angle_beta                 102.740(4)
_cell_angle_gamma                97.570(4)
_cell_formula_units_Z            1
_cell_length_a                   13.947(4)
_cell_length_b                   17.222(5)
_cell_length_c                   18.691(5)
_cell_measurement_reflns_used    965
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.78
_cell_measurement_theta_min      2.51
_cell_volume                     3883.5(19)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0450
_diffrn_reflns_av_sigmaI/netI    0.1273
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            22391
_diffrn_reflns_theta_full        26.46
_diffrn_reflns_theta_max         26.46
_diffrn_reflns_theta_min         1.25
_exptl_absorpt_coefficient_mu    2.028
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.293774
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_density_diffrn    1.593
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1836
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.334
_refine_diff_density_min         -0.726
_refine_diff_density_rms         0.158
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.996
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     911
_refine_ls_number_reflns         15787
_refine_ls_number_restraints     170
_refine_ls_restrained_S_all      1.010
_refine_ls_R_factor_all          0.1650
_refine_ls_R_factor_gt           0.0724
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1341P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1927
_refine_ls_wR_factor_ref         0.2508
_reflns_number_gt                7648
_reflns_number_total             15787
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om050668ssi20050803_051601.cif
_cod_data_source_block           040309a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'NONE' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        3883.2(19)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4076159
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pd1 Pd 0.72827(5) 0.30692(4) 0.20275(4) 0.0338(2) Uani 1 1 d . . .
Co1 Co 0.78292(11) 0.77345(10) 0.56186(9) 0.0603(5) Uani 1 1 d . . .
Co2 Co 0.90289(12) 0.80906(9) 0.49358(9) 0.0592(4) Uani 1 1 d . . .
As1 As 0.58747(7) 0.33470(6) 0.12626(6) 0.0395(3) Uani 1 1 d . . .
As2 As 0.71014(7) 0.16517(6) 0.09705(6) 0.0398(3) Uani 1 1 d . . .
O1 O 0.6909(10) 0.6644(8) 0.6248(9) 0.126(5) Uani 1 1 d . . .
O2 O 0.8469(9) 0.9445(7) 0.7079(6) 0.124(4) Uani 1 1 d . . .
O3 O 0.5925(8) 0.7761(9) 0.4582(7) 0.140(5) Uani 1 1 d . . .
O4 O 1.0662(9) 0.7701(7) 0.4192(7) 0.107(4) Uani 1 1 d . . .
O5 O 1.0063(10) 0.9925(6) 0.6127(7) 0.128(4) Uani 1 1 d . . .
O6 O 0.7564(10) 0.8188(9) 0.3604(6) 0.155(6) Uani 1 1 d . . .
N1 N 0.7575(5) 0.4339(4) 0.2971(4) 0.0312(16) Uani 1 1 d . . .
N2 N 1.1514(5) 0.7119(4) 0.7225(4) 0.0303(16) Uani 1 1 d . . .
C1 C 0.7270(11) 0.7070(11) 0.6018(9) 0.081(4) Uani 1 1 d . . .
C2 C 0.8202(10) 0.8810(9) 0.6538(8) 0.079(4) Uani 1 1 d . . .
C3 C 0.6666(11) 0.7779(10) 0.4987(9) 0.093(5) Uani 1 1 d . . .
C4 C 1.0042(12) 0.7857(8) 0.4465(8) 0.078(4) Uani 1 1 d . . .
C5 C 0.9668(12) 0.9255(8) 0.5675(9) 0.087(4) Uani 1 1 d . . .
C6 C 0.8127(11) 0.8167(9) 0.4115(8) 0.085(4) Uani 1 1 d . . .
C7 C 0.7238(10) 0.4546(8) 0.3611(6) 0.065(3) Uani 1 1 d . . .
H7 H 0.6817 0.4110 0.3652 0.078 Uiso 1 1 calc R . .
C8 C 0.7489(10) 0.5384(7) 0.4217(6) 0.066(3) Uani 1 1 d . . .
H8 H 0.7232 0.5505 0.4659 0.079 Uiso 1 1 calc R . .
C9 C 0.8118(7) 0.6058(6) 0.4189(5) 0.040(2) Uani 1 1 d . . .
C10 C 0.8437(8) 0.5837(7) 0.3520(6) 0.058(3) Uani 1 1 d . . .
H10 H 0.8844 0.6264 0.3457 0.070 Uiso 1 1 calc R . .
C11 C 0.8162(8) 0.4981(7) 0.2929(6) 0.059(3) Uani 1 1 d . . .
H11 H 0.8400 0.4846 0.2476 0.071 Uiso 1 1 calc R . .
C12 C 0.8425(7) 0.6956(6) 0.4844(5) 0.047(2) Uani 1 1 d . . .
C13 C 0.9130(7) 0.7438(6) 0.5588(6) 0.044(2) Uani 1 1 d . . .
C14 C 1.0551(7) 0.6765(7) 0.7099(6) 0.050(3) Uani 1 1 d . . .
H14 H 1.0398 0.6444 0.7375 0.060 Uiso 1 1 calc R . .
C15 C 0.9754(7) 0.6863(7) 0.6556(6) 0.051(3) Uani 1 1 d . . .
H15 H 0.9086 0.6595 0.6465 0.061 Uiso 1 1 calc R . .
C16 C 0.9966(7) 0.7351(6) 0.6165(5) 0.038(2) Uani 1 1 d . . .
C17 C 1.0976(7) 0.7721(6) 0.6302(6) 0.044(2) Uani 1 1 d . . .
H17 H 1.1148 0.8056 0.6042 0.053 Uiso 1 1 calc R . .
C18 C 1.1713(7) 0.7587(6) 0.6825(5) 0.041(2) Uani 1 1 d . . .
H18 H 1.2387 0.7832 0.6908 0.049 Uiso 1 1 calc R . .
C19 C 0.5417(7) 0.4268(6) 0.1995(6) 0.048(2) Uani 1 1 d . . .
C20 C 0.4797(11) 0.4098(9) 0.2397(10) 0.099(5) Uani 1 1 d . . .
H20 H 0.4602 0.3531 0.2335 0.119 Uiso 1 1 calc R . .
C21 C 0.4443(13) 0.4757(11) 0.2905(12) 0.128(7) Uani 1 1 d . . .
H21 H 0.3975 0.4621 0.3148 0.153 Uiso 1 1 calc R . .
C22 C 0.4773(13) 0.5597(12) 0.3051(11) 0.115(6) Uani 1 1 d . . .
H22 H 0.4559 0.6043 0.3412 0.139 Uiso 1 1 calc R . .
C23 C 0.5417(11) 0.5776(8) 0.2665(9) 0.083(4) Uani 1 1 d . . .
H23 H 0.5638 0.6348 0.2749 0.099 Uiso 1 1 calc R . .
C24 C 0.5749(9) 0.5117(7) 0.2148(6) 0.059(3) Uani 1 1 d . . .
H24 H 0.6208 0.5252 0.1898 0.070 Uiso 1 1 calc R . .
C25 C 0.6158(8) 0.3769(7) 0.0504(6) 0.049(2) Uani 1 1 d . . .
C26 C 0.7122(8) 0.3969(8) 0.0479(6) 0.060(3) Uani 1 1 d . . .
H26 H 0.7651 0.3882 0.0817 0.072 Uiso 1 1 calc R . .
C27 C 0.7315(11) 0.4300(10) -0.0047(9) 0.088(4) Uani 1 1 d . . .
H27 H 0.7977 0.4461 -0.0049 0.106 Uiso 1 1 calc R . .
C28 C 0.6512(15) 0.4394(10) -0.0578(9) 0.101(5) Uani 1 1 d . . .
H28 H 0.6631 0.4597 -0.0950 0.122 Uiso 1 1 calc R . .
C29 C 0.5554(12) 0.4186(10) -0.0545(8) 0.086(4) Uani 1 1 d . . .
H29 H 0.5022 0.4250 -0.0899 0.104 Uiso 1 1 calc R . .
C30 C 0.5349(10) 0.3887(8) -0.0010(7) 0.074(4) Uani 1 1 d . . .
H30 H 0.4691 0.3762 0.0014 0.089 Uiso 1 1 calc R . .
C31 C 0.4600(7) 0.2434(7) 0.0671(7) 0.060(3) Uani 1 1 d . . .
H31A H 0.4537 0.2092 0.0970 0.072 Uiso 1 1 calc R . .
H31B H 0.4042 0.2716 0.0673 0.072 Uiso 1 1 calc R . .
C32 C 0.4492(8) 0.1825(8) -0.0192(7) 0.063(3) Uani 1 1 d . . .
H32A H 0.4364 0.2137 -0.0521 0.076 Uiso 1 1 calc R . .
H32B H 0.3896 0.1349 -0.0387 0.076 Uiso 1 1 calc R . .
C33 C 0.5401(7) 0.1419(7) -0.0356(6) 0.058(3) Uani 1 1 d . . .
H33A H 0.5203 0.0985 -0.0925 0.069 Uiso 1 1 calc R . .
H33B H 0.5962 0.1876 -0.0274 0.069 Uiso 1 1 calc R . .
C34 C 0.5757(7) 0.0997(6) 0.0181(6) 0.053(3) Uani 1 1 d . . .
H34A H 0.5783 0.0406 -0.0159 0.063 Uiso 1 1 calc R . .
H34B H 0.5274 0.0961 0.0475 0.063 Uiso 1 1 calc R . .
C35 C 0.7533(8) 0.0857(6) 0.1402(6) 0.050(3) Uani 1 1 d . . .
C36 C 0.6896(9) 0.0499(7) 0.1719(7) 0.062(3) Uani 1 1 d . . .
H36 H 0.6266 0.0622 0.1714 0.075 Uiso 1 1 calc R . .
C37 C 0.7224(13) -0.0052(8) 0.2047(8) 0.091(5) Uani 1 1 d . . .
H37 H 0.6817 -0.0313 0.2262 0.109 Uiso 1 1 calc R . .
C38 C 0.8198(15) -0.0201(11) 0.2040(10) 0.108(6) Uani 1 1 d . . .
H38 H 0.8423 -0.0574 0.2249 0.130 Uiso 1 1 calc R . .
C39 C 0.8793(14) 0.0163(11) 0.1752(10) 0.100(5) Uani 1 1 d . . .
H39 H 0.9437 0.0067 0.1775 0.120 Uiso 1 1 calc R . .
C40 C 0.8460(10) 0.0688(8) 0.1416(7) 0.072(4) Uani 1 1 d . . .
H40 H 0.8873 0.0933 0.1194 0.087 Uiso 1 1 calc R . .
C41 C 0.7929(7) 0.1657(7) 0.0298(6) 0.049(2) Uani 1 1 d . . .
C42 C 0.7806(10) 0.0939(9) -0.0421(8) 0.080(4) Uani 1 1 d . . .
H42 H 0.7310 0.0438 -0.0569 0.096 Uiso 1 1 calc R . .
C43 C 0.8390(13) 0.0918(12) -0.0949(10) 0.109(5) Uani 1 1 d . . .
H43 H 0.8289 0.0416 -0.1432 0.130 Uiso 1 1 calc R . .
C44 C 0.9116(13) 0.1665(13) -0.0729(9) 0.107(6) Uani 1 1 d . . .
H44 H 0.9510 0.1678 -0.1068 0.128 Uiso 1 1 calc R . .
C45 C 0.9253(11) 0.2372(12) -0.0022(10) 0.098(5) Uani 1 1 d . . .
H45 H 0.9751 0.2873 0.0128 0.118 Uiso 1 1 calc R . .
C46 C 0.8661(8) 0.2373(9) 0.0494(7) 0.069(3) Uani 1 1 d . . .
H46 H 0.8773 0.2875 0.0980 0.083 Uiso 1 1 calc R . .
S1 S 0.4739(2) 0.1683(2) 0.2380(2) 0.0759(9) Uani 1 1 d D . .
O7 O 0.3969(7) 0.2163(7) 0.2454(7) 0.123(4) Uani 1 1 d D . .
O8 O 0.4479(8) 0.0909(6) 0.1609(5) 0.126(4) Uani 1 1 d D . .
O9 O 0.5747(6) 0.2225(6) 0.2611(6) 0.116(4) Uani 1 1 d D . .
C47 C 0.4792(8) 0.1267(7) 0.3170(6) 0.141(8) Uani 1 1 d D . .
F1 F 0.3864(9) 0.0741(9) 0.2948(9) 0.218(7) Uani 1 1 d D . .
F2 F 0.5535(11) 0.0841(11) 0.3127(9) 0.262(10) Uani 1 1 d D . .
F3 F 0.4998(12) 0.1996(10) 0.3891(5) 0.246(9) Uani 1 1 d D . .
S2 S 0.0163(3) 0.5266(3) 0.2000(2) 0.0859(11) Uani 1 1 d D . .
O10 O -0.0088(14) 0.4390(7) 0.1907(12) 0.084(6) Uani 0.54(2) 1 d PDU A 1
O11 O -0.0735(9) 0.5458(14) 0.1603(11) 0.113(8) Uani 0.54(2) 1 d PDU A 1
O12 O 0.0622(14) 0.5927(12) 0.2843(6) 0.135(11) Uani 0.54(2) 1 d PDU A 1
O10' O 0.0333(19) 0.4611(15) 0.2286(17) 0.126(11) Uani 0.46(2) 1 d PDU A 2
O11' O -0.0834(8) 0.500(2) 0.1421(12) 0.46(6) Uani 0.46(2) 1 d PDU A 2
O12' O 0.0359(18) 0.6113(9) 0.2688(11) 0.106(9) Uani 0.46(2) 1 d PDU A 2
C48 C 0.1115(8) 0.5345(7) 0.1461(7) 0.205(13) Uani 1 1 d D A .
F4 F 0.0666(17) 0.4705(14) 0.0662(8) 0.194(13) Uani 0.54(2) 1 d PDU A 1
F5 F 0.1968(11) 0.518(2) 0.1827(15) 0.190(13) Uani 0.54(2) 1 d PDU A 1
F6 F 0.1286(17) 0.6156(9) 0.1502(15) 0.137(8) Uani 0.54(2) 1 d PDU A 1
F4' F 0.120(2) 0.4547(10) 0.0988(15) 0.143(11) Uani 0.46(2) 1 d PDU A 2
F5' F 0.2032(9) 0.582(2) 0.2082(12) 0.29(3) Uani 0.46(2) 1 d PDU A 2
F6' F 0.0850(19) 0.5841(18) 0.1072(17) 0.153(11) Uani 0.46(2) 1 d PDU A 2
C49 C 0.1528(15) 0.3060(12) 0.8505(12) 0.127(6) Uani 1 1 d . . .
H49 H 0.1243 0.3565 0.8564 0.152 Uiso 1 1 calc R . .
Cl1 Cl 0.2665(6) 0.3247(5) 0.8319(4) 0.212(4) Uani 1 1 d . . .
Cl2 Cl 0.1778(6) 0.3015(6) 0.9438(4) 0.206(3) Uani 1 1 d . . .
Cl3 Cl 0.0668(5) 0.2150(4) 0.7730(4) 0.170(2) Uani 1 1 d . . .
C50 C 0.8127(11) 0.4036(10) 0.5696(11) 0.106(5) Uani 1 1 d . . .
H50 H 0.8435 0.3915 0.6152 0.127 Uiso 1 1 calc R . .
Cl4 Cl 0.9093(4) 0.4345(3) 0.5355(3) 0.1285(16) Uani 1 1 d . . .
Cl5 Cl 0.7590(5) 0.4903(4) 0.6083(4) 0.156(2) Uani 1 1 d . . .
Cl6 Cl 0.7296(5) 0.3104(5) 0.4963(4) 0.180(3) Uani 1 1 d . . .
C51 C 0.8060(12) 0.8012(13) 0.8661(10) 0.111(6) Uani 1 1 d . . .
H51 H 0.7397 0.7986 0.8327 0.133 Uiso 1 1 calc R . .
Cl7 Cl 0.8122(4) 0.8559(4) 0.9642(3) 0.157(2) Uani 1 1 d . . .
Cl9 Cl 0.8118(7) 0.6960(5) 0.8461(5) 0.233(4) Uani 1 1 d . . .
Cl8 Cl 0.8959(6) 0.8437(7) 0.8352(6) 0.247(5) Uani 1 1 d . . .
C52 C 0.715(2) 0.068(3) 0.502(3) 0.154(19) Uani 0.50 1 d P . .
H52 H 0.7428 0.1317 0.5310 0.185 Uiso 0.50 1 calc PR . .
Cl10 Cl 0.7570(8) 0.0439(7) 0.4295(7) 0.132(3) Uani 0.50 1 d PU . .
Cl11 Cl 0.7607(12) 0.0398(10) 0.5768(9) 0.208(6) Uani 0.50 1 d PU . .
Cl12 Cl 0.5982(14) 0.0612(14) 0.4894(11) 0.245(7) Uani 0.50 1 d PU . .
C53 C 0.4208(11) 0.8262(14) 0.2650(12) 0.23(3) Uani 0.50 1 d PD . .
H53 H 0.4399 0.8843 0.3120 0.271 Uiso 0.50 1 calc PR . .
Cl13 Cl 0.3766(10) 0.7516(9) 0.2958(8) 0.185(5) Uani 0.50 1 d PD . .
Cl14 Cl 0.5261(7) 0.8081(9) 0.2355(8) 0.168(5) Uani 0.50 1 d PD . .
Cl15 Cl 0.3277(9) 0.8267(11) 0.1895(8) 0.194(6) Uani 0.50 1 d PD . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Pd1 N1 87.5(2) 2_766 .
N2 Pd1 As2 89.28(18) 2_766 .
N1 Pd1 As2 175.12(18) . .
N2 Pd1 As1 175.74(19) 2_766 .
N1 Pd1 As1 89.13(17) . .
As2 Pd1 As1 94.28(4) . .
C1 Co1 C3 97.9(7) . .
C1 Co1 C2 99.2(6) . .
C3 Co1 C2 103.1(6) . .
C1 Co1 C13 103.8(5) . .
C3 Co1 C13 142.9(5) . .
C2 Co1 C13 102.6(5) . .
C1 Co1 C12 104.2(5) . .
C3 Co1 C12 105.2(5) . .
C2 Co1 C12 140.1(5) . .
C13 Co1 C12 40.5(4) . .
C1 Co1 Co2 152.5(4) . .
C3 Co1 Co2 99.4(5) . .
C2 Co1 Co2 97.5(5) . .
C13 Co1 Co2 50.9(3) . .
C12 Co1 Co2 50.5(3) . .
C6 Co2 C4 99.4(6) . .
C6 Co2 C5 103.8(6) . .
C4 Co2 C5 97.0(6) . .
C6 Co2 C12 102.7(5) . .
C4 Co2 C12 102.4(5) . .
C5 Co2 C12 144.0(5) . .
C6 Co2 C13 140.7(6) . .
C4 Co2 C13 102.2(5) . .
C5 Co2 C13 105.7(5) . .
C12 Co2 C13 40.6(4) . .
C6 Co2 Co1 98.5(5) . .
C4 Co2 Co1 150.8(4) . .
C5 Co2 Co1 100.9(5) . .
C12 Co2 Co1 51.0(3) . .
C13 Co2 Co1 50.8(3) . .
C25 As1 C19 103.7(4) . .
C25 As1 C31 106.3(5) . .
C19 As1 C31 100.4(4) . .
C25 As1 Pd1 115.4(3) . .
C19 As1 Pd1 109.7(3) . .
C31 As1 Pd1 119.3(4) . .
C41 As2 C35 103.6(5) . .
C41 As2 C34 103.4(4) . .
C35 As2 C34 104.3(4) . .
C41 As2 Pd1 112.9(3) . .
C35 As2 Pd1 112.3(3) . .
C34 As2 Pd1 118.9(3) . .
C7 N1 C11 117.2(9) . .
C7 N1 Pd1 125.1(7) . .
C11 N1 Pd1 117.7(6) . .
C14 N2 C18 118.0(8) . .
C14 N2 Pd1 122.7(6) . 2_766
C18 N2 Pd1 119.2(6) . 2_766
O1 C1 Co1 178.3(16) . .
O2 C2 Co1 176.5(13) . .
O3 C3 Co1 176.3(16) . .
O4 C4 Co2 177.9(14) . .
O5 C5 Co2 177.3(14) . .
O6 C6 Co2 178.0(14) . .
N1 C7 C8 121.9(10) . .
N1 C7 H7 119.1 . .
C8 C7 H7 119.1 . .
C7 C8 C9 121.4(10) . .
C7 C8 H8 119.3 . .
C9 C8 H8 119.3 . .
C10 C9 C8 115.9(9) . .
C10 C9 C12 121.6(10) . .
C8 C9 C12 122.5(9) . .
C9 C10 C11 120.0(10) . .
C9 C10 H10 120.0 . .
C11 C10 H10 120.0 . .
N1 C11 C10 123.5(10) . .
N1 C11 H11 118.3 . .
C10 C11 H11 118.3 . .
C13 C12 C9 138.6(8) . .
C13 C12 Co2 70.2(6) . .
C9 C12 Co2 134.4(7) . .
C13 C12 Co1 69.5(5) . .
C9 C12 Co1 137.2(8) . .
Co2 C12 Co1 78.5(4) . .
C12 C13 C16 140.7(8) . .
C12 C13 Co1 70.0(5) . .
C16 C13 Co1 135.3(7) . .
C12 C13 Co2 69.2(6) . .
C16 C13 Co2 134.9(7) . .
Co1 C13 Co2 78.3(3) . .
N2 C14 C15 121.5(9) . .
N2 C14 H14 119.2 . .
C15 C14 H14 119.2 . .
C16 C15 C14 119.8(9) . .
C16 C15 H15 120.1 . .
C14 C15 H15 120.1 . .
C15 C16 C17 118.2(8) . .
C15 C16 C13 119.5(9) . .
C17 C16 C13 122.2(8) . .
C18 C17 C16 119.0(9) . .
C18 C17 H17 120.5 . .
C16 C17 H17 120.5 . .
N2 C18 C17 123.4(9) . .
N2 C18 H18 118.3 . .
C17 C18 H18 118.3 . .
C20 C19 C24 118.1(11) . .
C20 C19 As1 120.8(9) . .
C24 C19 As1 121.0(8) . .
C19 C20 C21 120.7(13) . .
C19 C20 H20 119.6 . .
C21 C20 H20 119.6 . .
C22 C21 C20 120.7(15) . .
C22 C21 H21 119.7 . .
C20 C21 H21 119.7 . .
C23 C22 C21 118.8(15) . .
C23 C22 H22 120.6 . .
C21 C22 H22 120.6 . .
C22 C23 C24 120.3(14) . .
C22 C23 H23 119.8 . .
C24 C23 H23 119.8 . .
C19 C24 C23 121.2(12) . .
C19 C24 H24 119.4 . .
C23 C24 H24 119.4 . .
C26 C25 C30 120.8(10) . .
C26 C25 As1 120.7(7) . .
C30 C25 As1 118.5(9) . .
C25 C26 C27 119.9(11) . .
C25 C26 H26 120.1 . .
C27 C26 H26 120.1 . .
C26 C27 C28 119.7(13) . .
C26 C27 H27 120.1 . .
C28 C27 H27 120.1 . .
C29 C28 C27 119.3(12) . .
C29 C28 H28 120.3 . .
C27 C28 H28 120.3 . .
C28 C29 C30 122.0(13) . .
C28 C29 H29 119.0 . .
C30 C29 H29 119.0 . .
C29 C30 C25 118.3(13) . .
C29 C30 H30 120.9 . .
C25 C30 H30 120.9 . .
C32 C31 As1 115.7(7) . .
C32 C31 H31A 108.4 . .
As1 C31 H31A 108.4 . .
C32 C31 H31B 108.4 . .
As1 C31 H31B 108.4 . .
H31A C31 H31B 107.4 . .
C31 C32 C33 117.1(8) . .
C31 C32 H32A 108.0 . .
C33 C32 H32A 108.0 . .
C31 C32 H32B 108.0 . .
C33 C32 H32B 108.0 . .
H32A C32 H32B 107.3 . .
C34 C33 C32 113.9(10) . .
C34 C33 H33A 108.8 . .
C32 C33 H33A 108.8 . .
C34 C33 H33B 108.8 . .
C32 C33 H33B 108.8 . .
H33A C33 H33B 107.7 . .
C33 C34 As2 112.0(7) . .
C33 C34 H34A 109.2 . .
As2 C34 H34A 109.2 . .
C33 C34 H34B 109.2 . .
As2 C34 H34B 109.2 . .
H34A C34 H34B 107.9 . .
C40 C35 C36 121.2(11) . .
C40 C35 As2 120.2(10) . .
C36 C35 As2 118.6(8) . .
C35 C36 C37 118.2(12) . .
C35 C36 H36 120.9 . .
C37 C36 H36 120.9 . .
C36 C37 C38 117.6(14) . .
C36 C37 H37 121.2 . .
C38 C37 H37 121.2 . .
C39 C38 C37 122.8(15) . .
C39 C38 H38 118.6 . .
C37 C38 H38 118.6 . .
C38 C39 C40 119.3(17) . .
C38 C39 H39 120.3 . .
C40 C39 H39 120.3 . .
C35 C40 C39 120.9(15) . .
C35 C40 H40 119.6 . .
C39 C40 H40 119.6 . .
C46 C41 C42 116.7(10) . .
C46 C41 As2 122.0(8) . .
C42 C41 As2 121.4(8) . .
C41 C42 C43 123.4(13) . .
C41 C42 H42 118.3 . .
C43 C42 H42 118.3 . .
C44 C43 C42 117.8(14) . .
C44 C43 H43 121.1 . .
C42 C43 H43 121.1 . .
C45 C44 C43 119.6(14) . .
C45 C44 H44 120.2 . .
C43 C44 H44 120.2 . .
C44 C45 C46 121.4(14) . .
C44 C45 H45 119.3 . .
C46 C45 H45 119.3 . .
C41 C46 C45 121.2(13) . .
C41 C46 H46 119.4 . .
C45 C46 H46 119.4 . .
O7 S1 O8 113.8(6) . .
O7 S1 O9 113.7(6) . .
O8 S1 O9 113.4(6) . .
O7 S1 C47 104.6(5) . .
O8 S1 C47 105.1(5) . .
O9 S1 C47 104.9(5) . .
F2 C47 F1 113.5(9) . .
F2 C47 F3 113.9(9) . .
F1 C47 F3 112.7(9) . .
F2 C47 S1 105.3(6) . .
F1 C47 S1 105.5(6) . .
F3 C47 S1 104.9(7) . .
O10 S2 O12' 132.8(10) . .
O10 S2 O11' 83.3(14) . .
O12' S2 O11' 113.3(10) . .
O10 S2 O12 114.2(8) . .
O12' S2 O12 24.6(12) . .
O11' S2 O12 133.7(13) . .
O10 S2 O10' 29.3(11) . .
O12' S2 O10' 110.3(9) . .
O11' S2 O10' 111.1(10) . .
O12 S2 O10' 87.7(12) . .
O10 S2 O11 109.5(8) . .
O12' S2 O11 87.9(13) . .
O11' S2 O11 27.9(15) . .
O12 S2 O11 111.2(9) . .
O10' S2 O11 134.4(11) . .
O10 S2 C48 108.7(6) . .
O12' S2 C48 107.1(6) . .
O11' S2 C48 108.1(8) . .
O12 S2 C48 105.9(6) . .
O10' S2 C48 106.7(7) . .
O11 S2 C48 107.0(6) . .
F4' C48 F6 138.4(11) . .
F4' C48 F5 69.8(12) . .
F6 C48 F5 112.2(10) . .
F4' C48 F6' 116.2(10) . .
F6 C48 F6' 34.7(11) . .
F5 C48 F6' 138.8(12) . .
F4' C48 F4 42.7(11) . .
F6 C48 F4 111.6(10) . .
F5 C48 F4 111.5(10) . .
F6' C48 F4 78.9(12) . .
F4' C48 F5' 109.6(10) . .
F6 C48 F5' 74.3(13) . .
F5 C48 F5' 41.8(13) . .
F6' C48 F5' 107.9(10) . .
F4 C48 F5' 145.4(12) . .
F4' C48 S2 110.5(7) . .
F6 C48 S2 107.9(7) . .
F5 C48 S2 108.3(7) . .
F6' C48 S2 106.8(7) . .
F4 C48 S2 104.8(7) . .
F5' C48 S2 105.3(7) . .
Cl3 C49 Cl1 113.0(11) . .
Cl3 C49 Cl2 112.6(10) . .
Cl1 C49 Cl2 107.5(12) . .
Cl3 C49 H49 107.8 . .
Cl1 C49 H49 107.8 . .
Cl2 C49 H49 107.8 . .
Cl6 C50 Cl4 111.3(10) . .
Cl6 C50 Cl5 114.4(9) . .
Cl4 C50 Cl5 109.3(9) . .
Cl6 C50 H50 107.2 . .
Cl4 C50 H50 107.2 . .
Cl5 C50 H50 107.2 . .
Cl7 C51 Cl8 116.2(12) . .
Cl7 C51 Cl9 108.9(10) . .
Cl8 C51 Cl9 108.5(10) . .
Cl7 C51 H51 107.7 . .
Cl8 C51 H51 107.7 . .
Cl9 C51 H51 107.7 . .
Cl10 C52 Cl12 120(3) . .
Cl10 C52 Cl11 120(2) . .
Cl12 C52 Cl11 109(2) . .
Cl10 C52 H52 101.1 . .
Cl12 C52 H52 101.1 . .
Cl11 C52 H52 101.1 . .
Cl15 C53 Cl14 111.6(9) . .
Cl15 C53 Cl13 110.2(9) . .
Cl14 C53 Cl13 111.7(9) . .
Cl15 C53 H53 107.7 . .
Cl14 C53 H53 107.7 . .
Cl13 C53 H53 107.7 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pd1 N2 2.085(7) 2_766
Pd1 N1 2.096(7) .
Pd1 As2 2.3784(12) .
Pd1 As1 2.3852(12) .
Co1 C1 1.785(18) .
Co1 C3 1.814(13) .
Co1 C2 1.855(13) .
Co1 C13 1.954(9) .
Co1 C12 1.960(9) .
Co1 Co2 2.471(3) .
Co2 C6 1.818(12) .
Co2 C4 1.829(17) .
Co2 C5 1.865(14) .
Co2 C12 1.947(11) .
Co2 C13 1.960(10) .
As1 C25 1.923(10) .
As1 C19 1.924(10) .
As1 C31 1.962(10) .
As2 C41 1.886(10) .
As2 C35 1.944(10) .
As2 C34 1.961(9) .
O1 C1 1.107(17) .
O2 C2 1.092(14) .
O3 C3 1.127(14) .
O4 C4 1.107(16) .
O5 C5 1.092(14) .
O6 C6 1.112(13) .
N1 C7 1.315(12) .
N1 C11 1.326(12) .
N2 C14 1.327(11) .
N2 C18 1.344(11) .
N2 Pd1 2.085(6) 2_766
C7 C8 1.364(14) .
C7 H7 0.9300 .
C8 C9 1.387(14) .
C8 H8 0.9300 .
C9 C10 1.347(13) .
C9 C12 1.464(12) .
C10 C11 1.376(14) .
C10 H10 0.9300 .
C11 H11 0.9300 .
C12 C13 1.356(12) .
C13 C16 1.472(12) .
C14 C15 1.408(13) .
C14 H14 0.9300 .
C15 C16 1.361(13) .
C15 H15 0.9300 .
C16 C17 1.389(13) .
C17 C18 1.367(12) .
C17 H17 0.9300 .
C18 H18 0.9300 .
C19 C20 1.340(16) .
C19 C24 1.363(14) .
C20 C21 1.385(18) .
C20 H20 0.9300 .
C21 C22 1.35(2) .
C21 H21 0.9300 .
C22 C23 1.35(2) .
C22 H22 0.9300 .
C23 C24 1.374(16) .
C23 H23 0.9300 .
C24 H24 0.9300 .
C25 C26 1.359(14) .
C25 C30 1.406(14) .
C26 C27 1.376(16) .
C26 H26 0.9300 .
C27 C28 1.40(2) .
C27 H27 0.9300 .
C28 C29 1.36(2) .
C28 H28 0.9300 .
C29 C30 1.358(17) .
C29 H29 0.9300 .
C30 H30 0.9300 .
C31 C32 1.488(15) .
C31 H31A 0.9700 .
C31 H31B 0.9700 .
C32 C33 1.556(15) .
C32 H32A 0.9700 .
C32 H32B 0.9700 .
C33 C34 1.499(14) .
C33 H33A 0.9700 .
C33 H33B 0.9700 .
C34 H34A 0.9700 .
C34 H34B 0.9700 .
C35 C40 1.359(15) .
C35 C36 1.378(15) .
C36 C37 1.394(16) .
C36 H36 0.9300 .
C37 C38 1.42(2) .
C37 H37 0.9300 .
C38 C39 1.30(2) .
C38 H38 0.9300 .
C39 C40 1.366(19) .
C39 H39 0.9300 .
C40 H40 0.9300 .
C41 C46 1.356(15) .
C41 C42 1.367(15) .
C42 C43 1.404(18) .
C42 H42 0.9300 .
C43 C44 1.38(2) .
C43 H43 0.9300 .
C44 C45 1.34(2) .
C44 H44 0.9300 .
C45 C46 1.401(17) .
C45 H45 0.9300 .
C46 H46 0.9300 .
S1 O7 1.436(7) .
S1 O8 1.443(7) .
S1 O9 1.448(7) .
S1 C47 1.876(7) .
C47 F2 1.345(9) .
C47 F1 1.349(9) .
C47 F3 1.359(9) .
S2 O10 1.432(8) .
S2 O12' 1.443(9) .
S2 O11' 1.444(9) .
S2 O12 1.451(8) .
S2 O10' 1.455(9) .
S2 O11 1.457(8) .
S2 C48 1.858(7) .
C48 F4' 1.339(9) .
C48 F6 1.352(9) .
C48 F5 1.357(9) .
C48 F6' 1.363(9) .
C48 F4 1.385(9) .
C48 F5' 1.398(9) .
C49 Cl3 1.70(2) .
C49 Cl1 1.714(19) .
C49 Cl2 1.737(18) .
C49 H49 0.9800 .
C50 Cl6 1.684(16) .
C50 Cl4 1.721(17) .
C50 Cl5 1.726(15) .
C50 H50 0.9800 .
C51 Cl7 1.665(17) .
C51 Cl8 1.691(17) .
C51 Cl9 1.712(19) .
C51 H51 0.9800 .
C52 Cl10 1.52(5) .
C52 Cl12 1.58(3) .
C52 Cl11 1.68(4) .
C52 H52 0.9800 .
C53 Cl15 1.697(10) .
C53 Cl14 1.702(10) .
C53 Cl13 1.705(10) .
C53 H53 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
C1 Co1 Co2 C6 125.9(11) .
C3 Co1 Co2 C6 -2.5(6) .
C2 Co1 Co2 C6 -107.2(6) .
C13 Co1 Co2 C6 152.6(5) .
C12 Co1 Co2 C6 99.5(5) .
C1 Co1 Co2 C4 -1.3(13) .
C3 Co1 Co2 C4 -129.7(10) .
C2 Co1 Co2 C4 125.6(9) .
C13 Co1 Co2 C4 25.4(9) .
C12 Co1 Co2 C4 -27.8(9) .
C1 Co1 Co2 C5 -128.2(11) .
C3 Co1 Co2 C5 103.4(6) .
C2 Co1 Co2 C5 -1.2(6) .
C13 Co1 Co2 C5 -101.4(6) .
C12 Co1 Co2 C5 -154.6(6) .
C1 Co1 Co2 C12 26.4(11) .
C3 Co1 Co2 C12 -102.0(6) .
C2 Co1 Co2 C12 153.4(5) .
C13 Co1 Co2 C12 53.2(5) .
C1 Co1 Co2 C13 -26.7(11) .
C3 Co1 Co2 C13 -155.1(6) .
C2 Co1 Co2 C13 100.2(5) .
C12 Co1 Co2 C13 -53.2(5) .
N2 Pd1 As1 C25 130(3) 2_766
N1 Pd1 As1 C25 93.5(4) .
As2 Pd1 As1 C25 -83.0(3) .
N2 Pd1 As1 C19 14(3) 2_766
N1 Pd1 As1 C19 -23.1(4) .
As2 Pd1 As1 C19 160.4(3) .
N2 Pd1 As1 C31 -101(3) 2_766
N1 Pd1 As1 C31 -138.0(4) .
As2 Pd1 As1 C31 45.5(4) .
N2 Pd1 As2 C41 -87.7(4) 2_766
N1 Pd1 As2 C41 -39(2) .
As1 Pd1 As2 C41 94.7(3) .
N2 Pd1 As2 C35 29.0(4) 2_766
N1 Pd1 As2 C35 77(2) .
As1 Pd1 As2 C35 -148.7(4) .
N2 Pd1 As2 C34 151.1(4) 2_766
N1 Pd1 As2 C34 -161(2) .
As1 Pd1 As2 C34 -26.6(4) .
N2 Pd1 N1 C7 -83.5(8) 2_766
As2 Pd1 N1 C7 -132(2) .
As1 Pd1 N1 C7 93.9(8) .
N2 Pd1 N1 C11 95.1(7) 2_766
As2 Pd1 N1 C11 47(2) .
As1 Pd1 N1 C11 -87.5(7) .
C3 Co1 C1 O1 50(46) .
C2 Co1 C1 O1 155(45) .
C13 Co1 C1 O1 -100(45) .
C12 Co1 C1 O1 -58(46) .
Co2 Co1 C1 O1 -79(46) .
C1 Co1 C2 O2 118(23) .
C3 Co1 C2 O2 -141(23) .
C13 Co1 C2 O2 12(23) .
C12 Co1 C2 O2 -7(23) .
Co2 Co1 C2 O2 -40(23) .
C1 Co1 C3 O3 -42(23) .
C2 Co1 C3 O3 -144(23) .
C13 Co1 C3 O3 84(23) .
C12 Co1 C3 O3 65(23) .
Co2 Co1 C3 O3 116(23) .
C6 Co2 C4 O4 -149(40) .
C5 Co2 C4 O4 106(40) .
C12 Co2 C4 O4 -43(40) .
C13 Co2 C4 O4 -2(40) .
Co1 Co2 C4 O4 -22(40) .
C6 Co2 C5 O5 177(100) .
C4 Co2 C5 O5 -81(36) .
C12 Co2 C5 O5 41(36) .
C13 Co2 C5 O5 24(36) .
Co1 Co2 C5 O5 76(36) .
C4 Co2 C6 O6 87(42) .
C5 Co2 C6 O6 -174(100) .
C12 Co2 C6 O6 -18(42) .
C13 Co2 C6 O6 -36(43) .
Co1 Co2 C6 O6 -70(42) .
C11 N1 C7 C8 -1.0(17) .
Pd1 N1 C7 C8 177.6(9) .
N1 C7 C8 C9 -0.3(19) .
C7 C8 C9 C10 1.7(17) .
C7 C8 C9 C12 -177.9(10) .
C8 C9 C10 C11 -1.9(16) .
C12 C9 C10 C11 177.7(9) .
C7 N1 C11 C10 0.7(16) .
Pd1 N1 C11 C10 -177.9(9) .
C9 C10 C11 N1 0.8(17) .
C10 C9 C12 C13 -97.4(16) .
C8 C9 C12 C13 82.2(17) .
C10 C9 C12 Co2 15.8(14) .
C8 C9 C12 Co2 -164.6(9) .
C10 C9 C12 Co1 146.2(10) .
C8 C9 C12 Co1 -34.2(15) .
C6 Co2 C12 C13 -162.9(7) .
C4 Co2 C12 C13 94.4(7) .
C5 Co2 C12 C13 -26.4(11) .
Co1 Co2 C12 C13 -72.2(5) .
C6 Co2 C12 C9 57.4(10) .
C4 Co2 C12 C9 -45.3(10) .
C5 Co2 C12 C9 -166.1(10) .
C13 Co2 C12 C9 -139.7(12) .
Co1 Co2 C12 C9 148.1(10) .
C6 Co2 C12 Co1 -90.7(5) .
C4 Co2 C12 Co1 166.6(4) .
C5 Co2 C12 Co1 45.7(10) .
C13 Co2 C12 Co1 72.2(5) .
C1 Co1 C12 C13 -94.8(7) .
C3 Co1 C12 C13 162.8(8) .
C2 Co1 C12 C13 29.2(11) .
Co2 Co1 C12 C13 73.0(6) .
C1 Co1 C12 C9 46.0(11) .
C3 Co1 C12 C9 -56.5(12) .
C2 Co1 C12 C9 169.9(10) .
C13 Co1 C12 C9 140.8(13) .
Co2 Co1 C12 C9 -146.3(11) .
C1 Co1 C12 Co2 -167.8(5) .
C3 Co1 C12 Co2 89.8(6) .
C2 Co1 C12 Co2 -43.8(8) .
C13 Co1 C12 Co2 -73.0(6) .
C9 C12 C13 C16 -1(3) .
Co2 C12 C13 C16 -136.8(15) .
Co1 C12 C13 C16 138.5(15) .
C9 C12 C13 Co1 -139.6(15) .
Co2 C12 C13 Co1 84.7(3) .
C9 C12 C13 Co2 135.7(15) .
Co1 C12 C13 Co2 -84.7(3) .
C1 Co1 C13 C12 95.8(8) .
C3 Co1 C13 C12 -28.4(12) .
C2 Co1 C13 C12 -161.3(7) .
Co2 Co1 C13 C12 -71.9(6) .
C1 Co1 C13 C16 -47.6(11) .
C3 Co1 C13 C16 -171.7(11) .
C2 Co1 C13 C16 55.3(11) .
C12 Co1 C13 C16 -143.4(13) .
Co2 Co1 C13 C16 144.7(11) .
C1 Co1 C13 Co2 167.7(5) .
C3 Co1 C13 Co2 43.5(10) .
C2 Co1 C13 Co2 -89.4(5) .
C12 Co1 C13 Co2 71.9(6) .
C6 Co2 C13 C12 26.9(10) .
C4 Co2 C13 C12 -94.9(7) .
C5 Co2 C13 C12 164.2(7) .
Co1 Co2 C13 C12 72.8(5) .
C6 Co2 C13 C16 169.1(9) .
C4 Co2 C13 C16 47.3(10) .
C5 Co2 C13 C16 -53.6(10) .
C12 Co2 C13 C16 142.2(12) .
Co1 Co2 C13 C16 -145.0(10) .
C6 Co2 C13 Co1 -45.9(8) .
C4 Co2 C13 Co1 -167.7(5) .
C5 Co2 C13 Co1 91.4(6) .
C12 Co2 C13 Co1 -72.8(5) .
C18 N2 C14 C15 0.7(14) .
Pd1 N2 C14 C15 -176.4(7) 2_766
N2 C14 C15 C16 -1.8(15) .
C14 C15 C16 C17 1.7(14) .
C14 C15 C16 C13 179.0(9) .
C12 C13 C16 C15 -68.4(18) .
Co1 C13 C16 C15 49.4(13) .
Co2 C13 C16 C15 176.4(8) .
C12 C13 C16 C17 108.8(16) .
Co1 C13 C16 C17 -133.4(9) .
Co2 C13 C16 C17 -6.4(14) .
C15 C16 C17 C18 -0.4(13) .
C13 C16 C17 C18 -177.7(8) .
C14 N2 C18 C17 0.6(13) .
Pd1 N2 C18 C17 177.8(7) 2_766
C16 C17 C18 N2 -0.7(14) .
C25 As1 C19 C20 154.1(11) .
C31 As1 C19 C20 44.3(11) .
Pd1 As1 C19 C20 -82.2(11) .
C25 As1 C19 C24 -28.9(9) .
C31 As1 C19 C24 -138.7(9) .
Pd1 As1 C19 C24 94.9(8) .
C24 C19 C20 C21 5(2) .
As1 C19 C20 C21 -178.0(14) .
C19 C20 C21 C22 -5(3) .
C20 C21 C22 C23 3(3) .
C21 C22 C23 C24 -2(3) .
C20 C19 C24 C23 -3.5(18) .
As1 C19 C24 C23 179.4(9) .
C22 C23 C24 C19 2(2) .
C19 As1 C25 C26 113.9(9) .
C31 As1 C25 C26 -140.7(9) .
Pd1 As1 C25 C26 -6.0(10) .
C19 As1 C25 C30 -64.6(10) .
C31 As1 C25 C30 40.7(10) .
Pd1 As1 C25 C30 175.4(8) .
C30 C25 C26 C27 0.9(18) .
As1 C25 C26 C27 -177.6(10) .
C25 C26 C27 C28 -3(2) .
C26 C27 C28 C29 2(2) .
C27 C28 C29 C30 0(3) .
C28 C29 C30 C25 -2(2) .
C26 C25 C30 C29 1.4(18) .
As1 C25 C30 C29 179.9(10) .
C25 As1 C31 C32 41.6(10) .
C19 As1 C31 C32 149.3(9) .
Pd1 As1 C31 C32 -91.0(9) .
As1 C31 C32 C33 48.1(14) .
C31 C32 C33 C34 51.6(14) .
C32 C33 C34 As2 -111.0(8) .
C41 As2 C34 C33 -58.9(8) .
C35 As2 C34 C33 -166.9(7) .
Pd1 As2 C34 C33 67.1(8) .
C41 As2 C35 C40 21.4(9) .
C34 As2 C35 C40 129.3(9) .
Pd1 As2 C35 C40 -100.7(8) .
C41 As2 C35 C36 -161.0(8) .
C34 As2 C35 C36 -53.2(9) .
Pd1 As2 C35 C36 76.9(8) .
C40 C35 C36 C37 -0.8(16) .
As2 C35 C36 C37 -178.3(8) .
C35 C36 C37 C38 0.7(17) .
C36 C37 C38 C39 1(2) .
C37 C38 C39 C40 -2(3) .
C36 C35 C40 C39 -0.6(18) .
As2 C35 C40 C39 176.9(10) .
C38 C39 C40 C35 2(2) .
C35 As2 C41 C46 -111.4(9) .
C34 As2 C41 C46 140.0(9) .
Pd1 As2 C41 C46 10.3(10) .
C35 As2 C41 C42 69.7(10) .
C34 As2 C41 C42 -38.9(11) .
Pd1 As2 C41 C42 -168.6(9) .
C46 C41 C42 C43 0(2) .
As2 C41 C42 C43 178.7(12) .
C41 C42 C43 C44 -1(2) .
C42 C43 C44 C45 1(3) .
C43 C44 C45 C46 -1(3) .
C42 C41 C46 C45 0.5(18) .
As2 C41 C46 C45 -178.5(10) .
C44 C45 C46 C41 0(2) .
O7 S1 C47 F2 -177.9(10) .
O8 S1 C47 F2 61.9(10) .
O9 S1 C47 F2 -58.0(10) .
O7 S1 C47 F1 61.7(10) .
O8 S1 C47 F1 -58.5(9) .
O9 S1 C47 F1 -178.3(9) .
O7 S1 C47 F3 -57.5(10) .
O8 S1 C47 F3 -177.7(9) .
O9 S1 C47 F3 62.4(9) .
O10 S2 C48 F4' 11.8(15) .
O12' S2 C48 F4' 160.6(16) .
O11' S2 C48 F4' -77.0(18) .
O12 S2 C48 F4' 134.9(16) .
O10' S2 C48 F4' 42.5(16) .
O11 S2 C48 F4' -106.3(15) .
O10 S2 C48 F6 175.5(13) .
O12' S2 C48 F6 -35.8(15) .
O11' S2 C48 F6 86.6(18) .
O12 S2 C48 F6 -61.4(14) .
O10' S2 C48 F6 -153.9(15) .
O11 S2 C48 F6 57.3(14) .
O10 S2 C48 F5 -62.8(14) .
O12' S2 C48 F5 86.0(16) .
O11' S2 C48 F5 -151.7(18) .
O12 S2 C48 F5 60.3(15) .
O10' S2 C48 F5 -32.1(16) .
O11 S2 C48 F5 179.0(15) .
O10 S2 C48 F6' 139.0(15) .
O12' S2 C48 F6' -72.2(16) .
O11' S2 C48 F6' 50.2(19) .
O12 S2 C48 F6' -97.9(16) .
O10' S2 C48 F6' 169.7(16) .
O11 S2 C48 F6' 20.9(16) .
O10 S2 C48 F4 56.4(14) .
O12' S2 C48 F4 -154.9(15) .
O11' S2 C48 F4 -32.5(18) .
O12 S2 C48 F4 179.4(15) .
O10' S2 C48 F4 87.0(16) .
O11 S2 C48 F4 -61.8(15) .
O10 S2 C48 F5' -106.4(16) .
O12' S2 C48 F5' 42.3(17) .
O11' S2 C48 F5' 164.7(19) .
O12 S2 C48 F5' 16.7(17) .
O10' S2 C48 F5' -75.7(17) .
O11 S2 C48 F5' 135.4(17) .
