#------------------------------------------------------------------------------
#$Date: 2016-03-21 10:25:19 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178650 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/61/4076160.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4076160
loop_
_publ_author_name
'Song, Li-Cheng'
'Jin, Guo-Xia'
'Wang, Hu-Ting'
'Zhang, Wen-Xiong'
'Hu, Qing-Mei'
_publ_section_title
;
 Self-Assembly of Cationic Pd(II)/Pt(II) Metallomacrocycles Containing
 Tetrahedral C2Co2Clusters from Rigid Cluster-Bridged Bipyridine
 (4-C5H4N)2C2Co2(CO)6and Diphosphine- or Diarsine-Chelated Pd(II)/Pt(II)
 Complexes [M(dppb)(H2O)2][OTf]2(M = Pd, Pt), [Pd(dpab)(H2O)(OTf)][OTf],
 and [Pt(dpab)(H2O)2][OTf]2
;
_journal_issue                   26
_journal_name_full               Organometallics
_journal_page_first              6464
_journal_paper_doi               10.1021/om050668s
_journal_volume                  24
_journal_year                    2005
_chemical_formula_sum            'C104 H80 As4 Cl24 Co4 F12 N4 O24 Pt2 S4'
_chemical_formula_weight         3902.34
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                113.920(6)
_cell_angle_beta                 102.869(6)
_cell_angle_gamma                97.178(7)
_cell_formula_units_Z            1
_cell_length_a                   13.927(5)
_cell_length_b                   16.983(6)
_cell_length_c                   18.688(7)
_cell_measurement_reflns_used    898
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      23.34
_cell_measurement_theta_min      2.50
_cell_volume                     3822(2)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0493
_diffrn_reflns_av_sigmaI/netI    0.1358
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            22289
_diffrn_reflns_theta_full        26.48
_diffrn_reflns_theta_max         26.48
_diffrn_reflns_theta_min         1.25
_exptl_absorpt_coefficient_mu    3.653
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.512779
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_density_diffrn    1.695
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1900
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.22
_refine_diff_density_max         1.629
_refine_diff_density_min         -1.448
_refine_diff_density_rms         0.162
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.969
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     911
_refine_ls_number_reflns         15529
_refine_ls_number_restraints     200
_refine_ls_restrained_S_all      0.979
_refine_ls_R_factor_all          0.1285
_refine_ls_R_factor_gt           0.0611
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0869P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1445
_refine_ls_wR_factor_ref         0.1815
_reflns_number_gt                8862
_reflns_number_total             15529
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om050668ssi20050803_052019.cif
_cod_data_source_block           040415d
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'NONE' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4076160
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.73345(3) 0.30742(2) 0.20352(2) 0.03362(13) Uani 1 1 d . . .
Co1 Co 0.78343(12) 0.77975(10) 0.55993(9) 0.0570(4) Uani 1 1 d . . .
Co2 Co 0.90564(13) 0.81624(10) 0.49356(9) 0.0573(4) Uani 1 1 d . . .
As1 As 0.59168(7) 0.33619(6) 0.12936(6) 0.0382(3) Uani 1 1 d . . .
As2 As 0.71576(7) 0.16370(6) 0.09890(6) 0.0387(3) Uani 1 1 d . . .
O1 O 0.6872(10) 0.6653(8) 0.6179(9) 0.123(5) Uani 1 1 d . . .
O2 O 0.8468(10) 0.9504(7) 0.7075(7) 0.123(4) Uani 1 1 d . . .
O3 O 0.5974(10) 0.7893(9) 0.4569(8) 0.144(5) Uani 1 1 d . . .
O4 O 1.0706(9) 0.7772(8) 0.4215(7) 0.107(4) Uani 1 1 d . . .
O5 O 1.0076(11) 1.0015(7) 0.6107(7) 0.135(5) Uani 1 1 d . . .
O6 O 0.7584(12) 0.8287(9) 0.3607(7) 0.152(6) Uani 1 1 d . . .
N1 N 0.7637(5) 0.4377(5) 0.2967(4) 0.0307(18) Uani 1 1 d . . .
N2 N 1.1472(5) 0.7129(4) 0.7199(4) 0.0325(18) Uani 1 1 d . . .
C1 C 0.7227(11) 0.7077(9) 0.5964(10) 0.080(4) Uani 1 1 d . . .
C2 C 0.8192(11) 0.8833(10) 0.6513(8) 0.082(4) Uani 1 1 d . . .
C3 C 0.6667(12) 0.7882(11) 0.4941(10) 0.094(5) Uani 1 1 d . . .
C4 C 1.0043(12) 0.7928(8) 0.4480(8) 0.068(4) Uani 1 1 d . . .
C5 C 0.9674(11) 0.9319(9) 0.5654(9) 0.075(4) Uani 1 1 d . . .
C6 C 0.8155(13) 0.8250(10) 0.4107(9) 0.095(5) Uani 1 1 d . . .
C7 C 0.7357(10) 0.4552(8) 0.3645(7) 0.065(4) Uani 1 1 d . . .
H7 H 0.7004 0.4098 0.3714 0.078 Uiso 1 1 calc R . .
C8 C 0.7605(10) 0.5424(7) 0.4244(7) 0.066(4) Uani 1 1 d . . .
H8 H 0.7379 0.5546 0.4702 0.079 Uiso 1 1 calc R . .
C9 C 0.8153(7) 0.6102(6) 0.4201(6) 0.037(2) Uani 1 1 d . . .
C10 C 0.8411(8) 0.5884(7) 0.3481(6) 0.049(3) Uani 1 1 d . . .
H10 H 0.8755 0.6327 0.3394 0.059 Uiso 1 1 calc R . .
C11 C 0.8161(8) 0.5019(7) 0.2897(6) 0.052(3) Uani 1 1 d . . .
H11 H 0.8374 0.4884 0.2433 0.063 Uiso 1 1 calc R . .
C12 C 0.8434(7) 0.7006(6) 0.4836(6) 0.042(2) Uani 1 1 d . . .
C13 C 0.9138(8) 0.7489(6) 0.5584(6) 0.044(2) Uani 1 1 d . . .
C14 C 1.0496(7) 0.6766(6) 0.7068(6) 0.043(3) Uani 1 1 d . . .
H14 H 1.0339 0.6436 0.7338 0.052 Uiso 1 1 calc R . .
C15 C 0.9727(7) 0.6877(7) 0.6539(6) 0.046(3) Uani 1 1 d . . .
H15 H 0.9056 0.6612 0.6445 0.055 Uiso 1 1 calc R . .
C16 C 0.9950(7) 0.7385(6) 0.6145(5) 0.036(2) Uani 1 1 d . . .
C17 C 1.0949(7) 0.7749(6) 0.6295(6) 0.039(2) Uani 1 1 d . . .
H17 H 1.1125 0.8098 0.6046 0.047 Uiso 1 1 calc R . .
C18 C 1.1688(8) 0.7603(6) 0.6808(6) 0.045(3) Uani 1 1 d . . .
H18 H 1.2364 0.7842 0.6890 0.054 Uiso 1 1 calc R . .
C19 C 0.5461(8) 0.4297(7) 0.2038(6) 0.049(3) Uani 1 1 d . . .
C20 C 0.4910(12) 0.4107(10) 0.2512(11) 0.106(6) Uani 1 1 d . . .
H20 H 0.4773 0.3535 0.2466 0.127 Uiso 1 1 calc R . .
C21 C 0.4578(14) 0.4737(12) 0.3030(12) 0.141(9) Uani 1 1 d . . .
H21 H 0.4201 0.4613 0.3340 0.169 Uiso 1 1 calc R . .
C22 C 0.4830(13) 0.5636(13) 0.3093(12) 0.124(7) Uani 1 1 d . . .
H22 H 0.4561 0.6075 0.3415 0.149 Uiso 1 1 calc R . .
C23 C 0.5413(12) 0.5829(10) 0.2712(9) 0.085(4) Uani 1 1 d . . .
H23 H 0.5614 0.6412 0.2801 0.103 Uiso 1 1 calc R . .
C24 C 0.5746(10) 0.5154(8) 0.2160(8) 0.067(3) Uani 1 1 d . . .
H24 H 0.6161 0.5290 0.1879 0.081 Uiso 1 1 calc R . .
C25 C 0.6153(8) 0.3762(7) 0.0508(6) 0.049(3) Uani 1 1 d . . .
C26 C 0.7113(9) 0.3965(8) 0.0465(7) 0.063(3) Uani 1 1 d . . .
H26 H 0.7657 0.3909 0.0819 0.075 Uiso 1 1 calc R . .
C27 C 0.7279(12) 0.4249(10) -0.0092(9) 0.088(5) Uani 1 1 d . . .
H27 H 0.7933 0.4386 -0.0120 0.106 Uiso 1 1 calc R . .
C28 C 0.6484(14) 0.4332(11) -0.0605(9) 0.099(5) Uani 1 1 d . . .
H28 H 0.6593 0.4507 -0.0998 0.119 Uiso 1 1 calc R . .
C29 C 0.5546(12) 0.4164(11) -0.0551(9) 0.093(5) Uani 1 1 d . . .
H29 H 0.5009 0.4246 -0.0888 0.112 Uiso 1 1 calc R . .
C30 C 0.5377(10) 0.3867(9) 0.0006(8) 0.074(4) Uani 1 1 d . . .
H30 H 0.4722 0.3739 0.0036 0.088 Uiso 1 1 calc R . .
C31 C 0.4675(8) 0.2429(7) 0.0736(7) 0.059(3) Uani 1 1 d . . .
H31A H 0.4655 0.2081 0.1038 0.071 Uiso 1 1 calc R . .
H31B H 0.4106 0.2705 0.0761 0.071 Uiso 1 1 calc R . .
C32 C 0.4521(8) 0.1794(8) -0.0163(8) 0.071(4) Uani 1 1 d . . .
H32A H 0.4374 0.2108 -0.0492 0.085 Uiso 1 1 calc R . .
H32B H 0.3934 0.1309 -0.0347 0.085 Uiso 1 1 calc R . .
C33 C 0.5432(8) 0.1406(7) -0.0316(7) 0.057(3) Uani 1 1 d . . .
H33A H 0.5242 0.0968 -0.0886 0.068 Uiso 1 1 calc R . .
H33B H 0.5979 0.1878 -0.0234 0.068 Uiso 1 1 calc R . .
C34 C 0.5833(8) 0.0973(7) 0.0222(7) 0.054(3) Uani 1 1 d . . .
H34A H 0.5870 0.0378 -0.0124 0.065 Uiso 1 1 calc R . .
H34B H 0.5363 0.0924 0.0523 0.065 Uiso 1 1 calc R . .
C35 C 0.7580(9) 0.0823(7) 0.1414(7) 0.051(3) Uani 1 1 d . . .
C36 C 0.6947(10) 0.0468(7) 0.1728(7) 0.063(3) Uani 1 1 d . . .
H36 H 0.6314 0.0596 0.1706 0.075 Uiso 1 1 calc R . .
C37 C 0.7226(14) -0.0069(10) 0.2070(10) 0.091(5) Uani 1 1 d . . .
H37 H 0.6798 -0.0279 0.2305 0.109 Uiso 1 1 calc R . .
C38 C 0.8104(19) -0.0298(11) 0.2071(11) 0.110(7) Uani 1 1 d . . .
H38 H 0.8274 -0.0686 0.2287 0.132 Uiso 1 1 calc R . .
C39 C 0.8751(16) 0.0028(12) 0.1762(10) 0.120(7) Uani 1 1 d . . .
H39 H 0.9371 -0.0125 0.1780 0.144 Uiso 1 1 calc R . .
C40 C 0.8489(11) 0.0622(9) 0.1398(9) 0.082(4) Uani 1 1 d . . .
H40 H 0.8917 0.0846 0.1172 0.099 Uiso 1 1 calc R . .
C41 C 0.7981(8) 0.1656(7) 0.0302(6) 0.046(3) Uani 1 1 d . . .
C42 C 0.7786(12) 0.0907(9) -0.0441(9) 0.091(5) Uani 1 1 d . . .
H42 H 0.7273 0.0415 -0.0583 0.109 Uiso 1 1 calc R . .
C43 C 0.8345(15) 0.0883(13) -0.0974(11) 0.120(7) Uani 1 1 d . . .
H43 H 0.8218 0.0385 -0.1472 0.144 Uiso 1 1 calc R . .
C44 C 0.9106(15) 0.1638(14) -0.0730(11) 0.117(6) Uani 1 1 d . . .
H44 H 0.9485 0.1646 -0.1080 0.141 Uiso 1 1 calc R . .
C45 C 0.9318(11) 0.2388(12) 0.0031(11) 0.103(5) Uani 1 1 d . . .
H45 H 0.9851 0.2873 0.0193 0.123 Uiso 1 1 calc R . .
C46 C 0.8730(9) 0.2394(8) 0.0530(7) 0.065(3) Uani 1 1 d . . .
H46 H 0.8838 0.2896 0.1022 0.078 Uiso 1 1 calc R . .
S1 S 0.4764(3) 0.1623(3) 0.2447(2) 0.0841(11) Uani 1 1 d D . .
O7 O 0.3995(8) 0.2128(8) 0.2552(7) 0.147(5) Uani 1 1 d D . .
O8 O 0.4540(9) 0.0912(7) 0.1634(5) 0.126(4) Uani 1 1 d D . .
O9 O 0.5772(6) 0.2183(7) 0.2753(7) 0.138(5) Uani 1 1 d D . .
C47 C 0.4737(9) 0.1084(8) 0.3142(7) 0.165(10) Uani 1 1 d D . .
F1 F 0.3792(11) 0.0580(10) 0.2894(10) 0.248(9) Uani 1 1 d D . .
F2 F 0.5452(14) 0.0620(12) 0.3072(11) 0.314(13) Uani 1 1 d D . .
F3 F 0.4930(14) 0.1756(11) 0.3908(6) 0.251(9) Uani 1 1 d D . .
S2 S 0.0194(3) 0.5299(2) 0.2022(2) 0.0761(10) Uani 1 1 d D . .
O10 O 0.0082(13) 0.4446(8) 0.2019(11) 0.087(5) Uani 0.66(3) 1 d PDU A 1
O11 O -0.0741(7) 0.5409(13) 0.1595(10) 0.113(7) Uani 0.66(3) 1 d PDU A 1
O12 O 0.0680(12) 0.6042(9) 0.2828(6) 0.125(8) Uani 0.66(3) 1 d PDU A 1
O10' O 0.043(2) 0.4681(18) 0.2351(19) 0.106(14) Uani 0.34(3) 1 d PDU A 2
O11' O -0.0813(7) 0.499(3) 0.1442(12) 0.29(5) Uani 0.34(3) 1 d PDU A 2
O12' O 0.039(2) 0.6191(9) 0.2665(13) 0.079(11) Uani 0.34(3) 1 d PDU A 2
C48 C 0.1108(8) 0.5341(7) 0.1429(6) 0.171(11) Uani 1 1 d D A .
F4 F 0.0615(16) 0.4674(13) 0.0646(8) 0.213(12) Uani 0.66(3) 1 d PDU A 1
F5 F 0.1966(10) 0.5194(18) 0.1800(14) 0.206(12) Uani 0.66(3) 1 d PDU A 1
F6 F 0.1239(15) 0.6148(9) 0.1444(13) 0.135(7) Uani 0.66(3) 1 d PDU A 1
F4' F 0.116(2) 0.4522(10) 0.0954(16) 0.112(12) Uani 0.34(3) 1 d PDU A 2
F5' F 0.2038(9) 0.581(2) 0.2027(12) 0.22(2) Uani 0.34(3) 1 d PDU A 2
F6' F 0.0803(19) 0.5828(18) 0.1031(16) 0.093(10) Uani 0.34(3) 1 d PDU A 2
C49 C 0.1581(15) 0.3139(11) 0.8579(12) 0.121(6) Uani 1 1 d . . .
H49 H 0.1342 0.3682 0.8677 0.145 Uiso 1 1 calc R . .
Cl1 Cl 0.2692(5) 0.3227(5) 0.8319(4) 0.191(3) Uani 1 1 d . . .
Cl2 Cl 0.1831(6) 0.3006(5) 0.9464(4) 0.181(3) Uani 1 1 d . . .
Cl3 Cl 0.0656(5) 0.2230(4) 0.7782(4) 0.153(2) Uani 1 1 d . . .
C50 C 0.8130(12) 0.4038(10) 0.5708(10) 0.097(5) Uani 1 1 d . . .
H50 H 0.8402 0.3882 0.6150 0.116 Uiso 1 1 calc R . .
Cl4 Cl 0.9129(3) 0.4346(3) 0.5390(3) 0.1095(14) Uani 1 1 d . . .
Cl5 Cl 0.7594(4) 0.4925(3) 0.6098(3) 0.1300(17) Uani 1 1 d . . .
Cl6 Cl 0.7259(4) 0.3129(4) 0.4925(4) 0.159(2) Uani 1 1 d . . .
C51 C 0.7967(12) 0.7939(12) 0.8569(10) 0.106(5) Uani 1 1 d . . .
H51 H 0.7307 0.7920 0.8233 0.127 Uiso 1 1 calc R . .
Cl7 Cl 0.8050(4) 0.8554(4) 0.9583(3) 0.145(2) Uani 1 1 d . . .
Cl8 Cl 0.8876(5) 0.8351(6) 0.8259(5) 0.208(3) Uani 1 1 d . . .
Cl9 Cl 0.8008(7) 0.6883(4) 0.8388(4) 0.211(4) Uani 1 1 d . . .
C52 C 0.710(4) 0.084(3) 0.520(3) 0.165(17) Uani 0.50 1 d PU . .
H52A H 0.7161 0.1481 0.5410 0.198 Uiso 0.50 1 calc PR . .
Cl10 Cl 0.7497(11) 0.0438(9) 0.4303(9) 0.185(5) Uani 0.50 1 d PU . .
Cl11 Cl 0.7637(16) 0.0614(13) 0.5939(13) 0.258(8) Uani 0.50 1 d PU . .
Cl12 Cl 0.587(2) 0.030(2) 0.4844(19) 0.378(15) Uani 0.50 1 d PU . .
C53 C 0.4139(12) 0.8347(13) 0.2726(11) 0.24(3) Uani 0.50 1 d PDU . .
H53A H 0.4280 0.8949 0.3168 0.283 Uiso 0.50 1 calc PR . .
Cl13 Cl 0.3707(11) 0.7562(10) 0.3034(9) 0.215(6) Uani 0.50 1 d PDU . .
Cl14 Cl 0.5227(9) 0.8146(11) 0.2429(11) 0.233(7) Uani 0.50 1 d PDU . .
Cl15 Cl 0.3183(10) 0.8202(10) 0.1863(9) 0.207(6) Uani 0.50 1 d PDU . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Pt1 N1 87.8(3) 2_766 .
N2 Pt1 As2 89.13(19) 2_766 .
N1 Pt1 As2 174.5(2) . .
N2 Pt1 As1 173.8(2) 2_766 .
N1 Pt1 As1 88.24(19) . .
As2 Pt1 As1 95.15(4) . .
C2 Co1 C1 99.4(7) . .
C2 Co1 C3 103.4(7) . .
C1 Co1 C3 98.5(7) . .
C2 Co1 C12 140.4(6) . .
C1 Co1 C12 102.7(5) . .
C3 Co1 C12 105.2(6) . .
C2 Co1 C13 102.1(6) . .
C1 Co1 C13 103.6(5) . .
C3 Co1 C13 142.7(6) . .
C12 Co1 C13 40.8(4) . .
C2 Co1 Co2 98.4(5) . .
C1 Co1 Co2 151.9(4) . .
C3 Co1 Co2 98.2(5) . .
C12 Co1 Co2 51.0(3) . .
C13 Co1 Co2 51.3(3) . .
C4 Co2 C5 96.9(6) . .
C4 Co2 C6 99.1(7) . .
C5 Co2 C6 102.9(6) . .
C4 Co2 C12 102.8(5) . .
C5 Co2 C12 144.7(5) . .
C6 Co2 C12 102.5(6) . .
C4 Co2 C13 102.7(5) . .
C5 Co2 C13 106.8(5) . .
C6 Co2 C13 140.4(6) . .
C12 Co2 C13 40.5(4) . .
C4 Co2 Co1 151.0(4) . .
C5 Co2 Co1 101.7(5) . .
C6 Co2 Co1 98.2(6) . .
C12 Co2 Co1 50.5(3) . .
C13 Co2 Co1 50.6(3) . .
C25 As1 C19 104.6(5) . .
C25 As1 C31 106.3(5) . .
C19 As1 C31 100.7(5) . .
C25 As1 Pt1 115.9(3) . .
C19 As1 Pt1 110.0(3) . .
C31 As1 Pt1 117.5(4) . .
C41 As2 C34 103.7(5) . .
C41 As2 C35 105.0(5) . .
C34 As2 C35 102.7(4) . .
C41 As2 Pt1 111.9(3) . .
C34 As2 Pt1 119.1(4) . .
C35 As2 Pt1 113.1(3) . .
C11 N1 C7 119.6(8) . .
C11 N1 Pt1 118.6(6) . .
C7 N1 Pt1 121.6(6) . .
C18 N2 C14 119.0(8) . .
C18 N2 Pt1 119.3(6) . 2_766
C14 N2 Pt1 121.6(6) . 2_766
O1 C1 Co1 179.8(18) . .
O2 C2 Co1 175.5(16) . .
O3 C3 Co1 176.0(18) . .
O4 C4 Co2 176.9(13) . .
O5 C5 Co2 177.5(14) . .
O6 C6 Co2 177.7(18) . .
N1 C7 C8 118.5(10) . .
N1 C7 H7 120.7 . .
C8 C7 H7 120.7 . .
C9 C8 C7 123.6(10) . .
C9 C8 H8 118.2 . .
C7 C8 H8 118.2 . .
C8 C9 C10 115.2(9) . .
C8 C9 C12 123.5(9) . .
C10 C9 C12 121.2(9) . .
C11 C10 C9 120.2(9) . .
C11 C10 H10 119.9 . .
C9 C10 H10 119.9 . .
N1 C11 C10 122.6(9) . .
N1 C11 H11 118.7 . .
C10 C11 H11 118.7 . .
C13 C12 C9 136.6(9) . .
C13 C12 Co1 69.9(6) . .
C9 C12 Co1 137.9(7) . .
C13 C12 Co2 70.2(6) . .
C9 C12 Co2 135.1(8) . .
Co1 C12 Co2 78.5(4) . .
C12 C13 C16 140.2(9) . .
C12 C13 Co1 69.3(6) . .
C16 C13 Co1 136.2(7) . .
C12 C13 Co2 69.3(6) . .
C16 C13 Co2 134.8(8) . .
Co1 C13 Co2 78.1(4) . .
N2 C14 C15 120.8(9) . .
N2 C14 H14 119.6 . .
C15 C14 H14 119.6 . .
C14 C15 C16 120.2(9) . .
C14 C15 H15 119.9 . .
C16 C15 H15 119.9 . .
C17 C16 C15 117.7(9) . .
C17 C16 C13 122.6(9) . .
C15 C16 C13 119.7(9) . .
C18 C17 C16 120.2(9) . .
C18 C17 H17 119.9 . .
C16 C17 H17 119.9 . .
N2 C18 C17 122.1(9) . .
N2 C18 H18 118.9 . .
C17 C18 H18 118.9 . .
C24 C19 C20 119.7(12) . .
C24 C19 As1 120.9(9) . .
C20 C19 As1 119.1(9) . .
C21 C20 C19 120.7(15) . .
C21 C20 H20 119.7 . .
C19 C20 H20 119.7 . .
C20 C21 C22 117.7(16) . .
C20 C21 H21 121.1 . .
C22 C21 H21 121.1 . .
C23 C22 C21 121.5(16) . .
C23 C22 H22 119.2 . .
C21 C22 H22 119.2 . .
C22 C23 C24 119.8(16) . .
C22 C23 H23 120.1 . .
C24 C23 H23 120.1 . .
C19 C24 C23 120.1(13) . .
C19 C24 H24 120.0 . .
C23 C24 H24 120.0 . .
C30 C25 C26 119.0(10) . .
C30 C25 As1 120.4(9) . .
C26 C25 As1 120.6(8) . .
C27 C26 C25 120.5(12) . .
C27 C26 H26 119.8 . .
C25 C26 H26 119.8 . .
C28 C27 C26 119.6(14) . .
C28 C27 H27 120.2 . .
C26 C27 H27 120.2 . .
C29 C28 C27 120.6(13) . .
C29 C28 H28 119.7 . .
C27 C28 H28 119.7 . .
C28 C29 C30 119.8(13) . .
C28 C29 H29 120.1 . .
C30 C29 H29 120.1 . .
C25 C30 C29 120.6(13) . .
C25 C30 H30 119.7 . .
C29 C30 H30 119.7 . .
C32 C31 As1 116.5(8) . .
C32 C31 H31A 108.2 . .
As1 C31 H31A 108.2 . .
C32 C31 H31B 108.2 . .
As1 C31 H31B 108.2 . .
H31A C31 H31B 107.3 . .
C31 C32 C33 114.2(9) . .
C31 C32 H32A 108.7 . .
C33 C32 H32A 108.7 . .
C31 C32 H32B 108.7 . .
C33 C32 H32B 108.7 . .
H32A C32 H32B 107.6 . .
C34 C33 C32 115.4(10) . .
C34 C33 H33A 108.4 . .
C32 C33 H33A 108.4 . .
C34 C33 H33B 108.4 . .
C32 C33 H33B 108.4 . .
H33A C33 H33B 107.5 . .
C33 C34 As2 112.2(7) . .
C33 C34 H34A 109.2 . .
As2 C34 H34A 109.2 . .
C33 C34 H34B 109.2 . .
As2 C34 H34B 109.2 . .
H34A C34 H34B 107.9 . .
C40 C35 C36 121.5(12) . .
C40 C35 As2 119.8(10) . .
C36 C35 As2 118.7(9) . .
C37 C36 C35 121.2(14) . .
C37 C36 H36 119.4 . .
C35 C36 H36 119.4 . .
C38 C37 C36 120.5(17) . .
C38 C37 H37 119.7 . .
C36 C37 H37 119.7 . .
C37 C38 C39 120.5(18) . .
C37 C38 H38 119.7 . .
C39 C38 H38 119.7 . .
C38 C39 C40 120.8(18) . .
C38 C39 H39 119.6 . .
C40 C39 H39 119.6 . .
C35 C40 C39 115.4(15) . .
C35 C40 H40 122.3 . .
C39 C40 H40 122.3 . .
C46 C41 C42 121.2(11) . .
C46 C41 As2 120.8(8) . .
C42 C41 As2 118.0(9) . .
C43 C42 C41 120.9(14) . .
C43 C42 H42 119.6 . .
C41 C42 H42 119.6 . .
C42 C43 C44 117.1(16) . .
C42 C43 H43 121.4 . .
C44 C43 H43 121.4 . .
C43 C44 C45 121.9(14) . .
C43 C44 H44 119.1 . .
C45 C44 H44 119.1 . .
C46 C45 C44 119.1(14) . .
C46 C45 H45 120.5 . .
C44 C45 H45 120.5 . .
C45 C46 C41 119.7(12) . .
C45 C46 H46 120.1 . .
C41 C46 H46 120.1 . .
O9 S1 O8 113.5(6) . .
O9 S1 O7 112.5(7) . .
O8 S1 O7 114.1(6) . .
O9 S1 C47 105.2(5) . .
O8 S1 C47 106.1(5) . .
O7 S1 C47 104.4(5) . .
F2 C47 F1 113.7(10) . .
F2 C47 F3 113.4(10) . .
F1 C47 F3 109.9(10) . .
F2 C47 S1 106.2(7) . .
F1 C47 S1 107.0(7) . .
F3 C47 S1 106.1(7) . .
O10 S2 O12' 133.0(11) . .
O10 S2 O11 112.5(8) . .
O12' S2 O11 89.8(14) . .
O10 S2 O11' 88.8(15) . .
O12' S2 O11' 113.4(10) . .
O11 S2 O11' 25.3(16) . .
O10 S2 O10' 25.2(13) . .
O12' S2 O10' 111.9(9) . .
O11 S2 O10' 133.5(12) . .
O11' S2 O10' 112.3(10) . .
O10 S2 O12 114.2(8) . .
O12' S2 O12 23.7(13) . .
O11 S2 O12 112.6(8) . .
O11' S2 O12 134.3(14) . .
O10' S2 O12 90.5(13) . .
O10 S2 C48 106.2(5) . .
O12' S2 C48 106.1(7) . .
O11 S2 C48 106.4(5) . .
O11' S2 C48 106.4(7) . .
O10' S2 C48 106.1(7) . .
O12 S2 C48 104.0(6) . .
F4' C48 F6 139.1(11) . .
F4' C48 F5 72.2(13) . .
F6 C48 F5 113.5(10) . .
F4' C48 F6' 116.0(10) . .
F6 C48 F6' 34.0(10) . .
F5 C48 F6' 140.2(12) . .
F4' C48 F4 41.9(12) . .
F6 C48 F4 111.6(9) . .
F5 C48 F4 113.4(10) . .
F6' C48 F4 79.3(12) . .
F4' C48 F5' 110.3(10) . .
F6 C48 F5' 76.4(13) . .
F5 C48 F5' 40.2(14) . .
F6' C48 F5' 109.2(10) . .
F4 C48 F5' 146.3(12) . .
F4' C48 S2 110.0(7) . .
F6 C48 S2 106.8(7) . .
F5 C48 S2 106.7(7) . .
F6' C48 S2 106.2(7) . .
F4 C48 S2 104.1(7) . .
F5' C48 S2 104.5(7) . .
Cl2 C49 Cl1 108.4(12) . .
Cl2 C49 Cl3 110.3(9) . .
Cl1 C49 Cl3 109.7(10) . .
Cl2 C49 H49 109.5 . .
Cl1 C49 H49 109.5 . .
Cl3 C49 H49 109.5 . .
Cl6 C50 Cl5 111.9(10) . .
Cl6 C50 Cl4 110.7(9) . .
Cl5 C50 Cl4 109.8(9) . .
Cl6 C50 H50 108.1 . .
Cl5 C50 H50 108.1 . .
Cl4 C50 H50 108.1 . .
Cl8 C51 Cl9 108.9(11) . .
Cl8 C51 Cl7 114.6(11) . .
Cl9 C51 Cl7 109.7(10) . .
Cl8 C51 H51 107.8 . .
Cl9 C51 H51 107.8 . .
Cl7 C51 H51 107.8 . .
Cl11 C52 Cl12 107(3) . .
Cl11 C52 Cl10 117(3) . .
Cl12 C52 Cl10 103(3) . .
Cl11 C52 H52A 110.0 . .
Cl12 C52 H52A 110.0 . .
Cl10 C52 H52A 110.0 . .
Cl13 C53 Cl14 109.9(9) . .
Cl13 C53 Cl15 107.1(8) . .
Cl14 C53 Cl15 108.0(8) . .
Cl13 C53 H53A 110.6 . .
Cl14 C53 H53A 110.6 . .
Cl15 C53 H53A 110.6 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 N2 2.100(7) 2_766
Pt1 N1 2.103(7) .
Pt1 As2 2.3677(12) .
Pt1 As1 2.3727(12) .
Co1 C2 1.796(14) .
Co1 C1 1.831(18) .
Co1 C3 1.868(16) .
Co1 C12 1.948(10) .
Co1 C13 1.954(10) .
Co1 Co2 2.474(3) .
Co2 C4 1.776(16) .
Co2 C5 1.824(13) .
Co2 C6 1.834(16) .
Co2 C12 1.961(10) .
Co2 C13 1.972(10) .
As1 C25 1.920(10) .
As1 C19 1.927(11) .
As1 C31 1.939(10) .
As2 C41 1.910(10) .
As2 C34 1.929(10) .
As2 C35 1.942(11) .
O1 C1 1.077(17) .
O2 C2 1.135(15) .
O3 C3 1.064(15) .
O4 C4 1.152(16) .
O5 C5 1.112(14) .
O6 C6 1.113(16) .
N1 C11 1.301(11) .
N1 C7 1.339(12) .
N2 C18 1.337(11) .
N2 C14 1.345(11) .
N2 Pt1 2.100(7) 2_766
C7 C8 1.386(15) .
C7 H7 0.9300 .
C8 C9 1.342(14) .
C8 H8 0.9300 .
C9 C10 1.385(13) .
C9 C12 1.444(13) .
C10 C11 1.369(13) .
C10 H10 0.9300 .
C11 H11 0.9300 .
C12 C13 1.360(13) .
C13 C16 1.442(13) .
C14 C15 1.375(13) .
C14 H14 0.9300 .
C15 C16 1.391(13) .
C15 H15 0.9300 .
C16 C17 1.366(13) .
C17 C18 1.364(13) .
C17 H17 0.9300 .
C18 H18 0.9300 .
C19 C24 1.369(15) .
C19 C20 1.397(17) .
C20 C21 1.33(2) .
C20 H20 0.9300 .
C21 C22 1.47(2) .
C21 H21 0.9300 .
C22 C23 1.29(2) .
C22 H22 0.9300 .
C23 C24 1.407(19) .
C23 H23 0.9300 .
C24 H24 0.9300 .
C25 C30 1.347(15) .
C25 C26 1.368(15) .
C26 C27 1.364(16) .
C26 H26 0.9300 .
C27 C28 1.36(2) .
C27 H27 0.9300 .
C28 C29 1.34(2) .
C28 H28 0.9300 .
C29 C30 1.377(17) .
C29 H29 0.9300 .
C30 H30 0.9300 .
C31 C32 1.531(16) .
C31 H31A 0.9700 .
C31 H31B 0.9700 .
C32 C33 1.531(16) .
C32 H32A 0.9700 .
C32 H32B 0.9700 .
C33 C34 1.523(15) .
C33 H33A 0.9700 .
C33 H33B 0.9700 .
C34 H34A 0.9700 .
C34 H34B 0.9700 .
C35 C40 1.355(17) .
C35 C36 1.367(16) .
C36 C37 1.357(18) .
C36 H36 0.9300 .
C37 C38 1.33(2) .
C37 H37 0.9300 .
C38 C39 1.35(3) .
C38 H38 0.9300 .
C39 C40 1.47(2) .
C39 H39 0.9300 .
C40 H40 0.9300 .
C41 C46 1.372(14) .
C41 C42 1.391(15) .
C42 C43 1.385(19) .
C42 H42 0.9300 .
C43 C44 1.40(2) .
C43 H43 0.9300 .
C44 C45 1.41(2) .
C44 H44 0.9300 .
C45 C46 1.369(18) .
C45 H45 0.9300 .
C46 H46 0.9300 .
S1 O9 1.438(7) .
S1 O8 1.440(7) .
S1 O7 1.452(7) .
S1 C47 1.871(7) .
C47 F2 1.343(9) .
C47 F1 1.343(9) .
C47 F3 1.360(9) .
S2 O10 1.436(8) .
S2 O12' 1.445(9) .
S2 O11 1.445(8) .
S2 O11' 1.448(9) .
S2 O10' 1.452(9) .
S2 O12 1.452(8) .
S2 C48 1.878(7) .
C48 F4' 1.333(9) .
C48 F6 1.347(9) .
C48 F5 1.349(9) .
C48 F6' 1.364(9) .
C48 F4 1.382(9) .
C48 F5' 1.392(9) .
C49 Cl2 1.724(18) .
C49 Cl1 1.730(19) .
C49 Cl3 1.745(19) .
C49 H49 0.9800 .
C50 Cl6 1.705(16) .
C50 Cl5 1.729(17) .
C50 Cl4 1.732(17) .
C50 H50 0.9800 .
C51 Cl8 1.692(17) .
C51 Cl9 1.697(18) .
C51 Cl7 1.721(17) .
C51 H51 0.9800 .
C52 Cl11 1.63(5) .
C52 Cl12 1.68(5) .
C52 Cl10 1.78(5) .
C52 H52A 0.9800 .
C53 Cl13 1.745(10) .
C53 Cl14 1.753(10) .
C53 Cl15 1.753(10) .
C53 H53A 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
C2 Co1 Co2 C4 125.4(10) .
C1 Co1 Co2 C4 -3.6(14) .
C3 Co1 Co2 C4 -129.7(10) .
C12 Co1 Co2 C4 -26.7(10) .
C13 Co1 Co2 C4 26.5(10) .
C2 Co1 Co2 C5 -3.4(6) .
C1 Co1 Co2 C5 -132.4(11) .
C3 Co1 Co2 C5 101.6(7) .
C12 Co1 Co2 C5 -155.4(6) .
C13 Co1 Co2 C5 -102.2(6) .
C2 Co1 Co2 C6 -108.5(6) .
C1 Co1 Co2 C6 122.5(11) .
C3 Co1 Co2 C6 -3.5(7) .
C12 Co1 Co2 C6 99.5(6) .
C13 Co1 Co2 C6 152.7(6) .
C2 Co1 Co2 C12 152.0(6) .
C1 Co1 Co2 C12 23.0(11) .
C3 Co1 Co2 C12 -103.0(6) .
C13 Co1 Co2 C12 53.2(5) .
C2 Co1 Co2 C13 98.8(6) .
C1 Co1 Co2 C13 -30.2(11) .
C3 Co1 Co2 C13 -156.2(6) .
C12 Co1 Co2 C13 -53.2(5) .
N2 Pt1 As1 C25 144.9(17) 2_766
N1 Pt1 As1 C25 93.9(4) .
As2 Pt1 As1 C25 -81.8(4) .
N2 Pt1 As1 C19 26.6(17) 2_766
N1 Pt1 As1 C19 -24.4(4) .
As2 Pt1 As1 C19 159.8(3) .
N2 Pt1 As1 C31 -87.8(17) 2_766
N1 Pt1 As1 C31 -138.8(4) .
As2 Pt1 As1 C31 45.4(4) .
N2 Pt1 As2 C41 -90.2(4) 2_766
N1 Pt1 As2 C41 -33.9(19) .
As1 Pt1 As2 C41 94.3(3) .
N2 Pt1 As2 C34 148.8(4) 2_766
N1 Pt1 As2 C34 -154.9(19) .
As1 Pt1 As2 C34 -26.6(4) .
N2 Pt1 As2 C35 28.1(4) 2_766
N1 Pt1 As2 C35 84.3(19) .
As1 Pt1 As2 C35 -147.4(4) .
N2 Pt1 N1 C11 100.2(8) 2_766
As2 Pt1 N1 C11 44(2) .
As1 Pt1 N1 C11 -84.6(7) .
N2 Pt1 N1 C7 -75.7(9) 2_766
As2 Pt1 N1 C7 -132.0(17) .
As1 Pt1 N1 C7 99.5(9) .
C2 Co1 C1 O1 -87(100) .
C3 Co1 C1 O1 168(100) .
C12 Co1 C1 O1 60(100) .
C13 Co1 C1 O1 18(100) .
Co2 Co1 C1 O1 42(100) .
C1 Co1 C2 O2 153(18) .
C3 Co1 C2 O2 -106(18) .
C12 Co1 C2 O2 30(19) .
C13 Co1 C2 O2 47(18) .
Co2 Co1 C2 O2 -5(18) .
C2 Co1 C3 O3 -116(24) .
C1 Co1 C3 O3 -14(24) .
C12 Co1 C3 O3 92(24) .
C13 Co1 C3 O3 112(24) .
Co2 Co1 C3 O3 143(24) .
C5 Co2 C4 O4 80(23) .
C6 Co2 C4 O4 -176(100) .
C12 Co2 C4 O4 -70(23) .
C13 Co2 C4 O4 -29(23) .
Co1 Co2 C4 O4 -50(23) .
C4 Co2 C5 O5 -68(36) .
C6 Co2 C5 O5 -169(35) .
C12 Co2 C5 O5 56(36) .
C13 Co2 C5 O5 37(36) .
Co1 Co2 C5 O5 90(36) .
C4 Co2 C6 O6 135(40) .
C5 Co2 C6 O6 -126(40) .
C12 Co2 C6 O6 29(40) .
C13 Co2 C6 O6 12(40) .
Co1 Co2 C6 O6 -22(40) .
C11 N1 C7 C8 2.4(17) .
Pt1 N1 C7 C8 178.3(9) .
N1 C7 C8 C9 -3(2) .
C7 C8 C9 C10 3.9(18) .
C7 C8 C9 C12 -178.3(11) .
C8 C9 C10 C11 -3.9(16) .
C12 C9 C10 C11 178.3(10) .
C7 N1 C11 C10 -2.6(16) .
Pt1 N1 C11 C10 -178.6(8) .
C9 C10 C11 N1 3.5(17) .
C8 C9 C12 C13 77.9(17) .
C10 C9 C12 C13 -104.5(15) .
C8 C9 C12 Co1 -37.1(17) .
C10 C9 C12 Co1 140.5(10) .
C8 C9 C12 Co2 -170.8(10) .
C10 C9 C12 Co2 6.8(16) .
C2 Co1 C12 C13 26.2(11) .
C1 Co1 C12 C13 -96.2(7) .
C3 Co1 C12 C13 161.1(8) .
Co2 Co1 C12 C13 72.9(6) .
C2 Co1 C12 C9 164.6(11) .
C1 Co1 C12 C9 42.2(12) .
C3 Co1 C12 C9 -60.4(12) .
C13 Co1 C12 C9 138.4(14) .
Co2 Co1 C12 C9 -148.6(12) .
C2 Co1 C12 Co2 -46.8(9) .
C1 Co1 C12 Co2 -169.1(5) .
C3 Co1 C12 Co2 88.2(6) .
C13 Co1 C12 Co2 -72.9(6) .
C4 Co2 C12 C13 94.6(7) .
C5 Co2 C12 C13 -27.7(12) .
C6 Co2 C12 C13 -162.9(8) .
Co1 Co2 C12 C13 -72.5(6) .
C4 Co2 C12 C9 -42.5(11) .
C5 Co2 C12 C9 -164.8(11) .
C6 Co2 C12 C9 60.0(11) .
C13 Co2 C12 C9 -137.1(13) .
Co1 Co2 C12 C9 150.4(11) .
C4 Co2 C12 Co1 167.1(5) .
C5 Co2 C12 Co1 44.8(10) .
C6 Co2 C12 Co1 -90.4(6) .
C13 Co2 C12 Co1 72.5(6) .
C9 C12 C13 C16 -1(2) .
Co1 C12 C13 C16 138.9(15) .
Co2 C12 C13 C16 -136.5(15) .
C9 C12 C13 Co1 -139.7(14) .
Co2 C12 C13 Co1 84.7(3) .
C9 C12 C13 Co2 135.7(13) .
Co1 C12 C13 Co2 -84.7(3) .
C2 Co1 C13 C12 -163.3(7) .
C1 Co1 C13 C12 93.7(7) .
C3 Co1 C13 C12 -31.0(12) .
Co2 Co1 C13 C12 -72.2(6) .
C2 Co1 C13 C16 54.2(11) .
C1 Co1 C13 C16 -48.8(11) .
C3 Co1 C13 C16 -173.5(11) .
C12 Co1 C13 C16 -142.5(13) .
Co2 Co1 C13 C16 145.3(11) .
C2 Co1 C13 Co2 -91.1(5) .
C1 Co1 C13 Co2 165.9(5) .
C3 Co1 C13 Co2 41.2(10) .
C12 Co1 C13 Co2 72.2(6) .
C4 Co2 C13 C12 -95.0(7) .
C5 Co2 C13 C12 163.7(7) .
C6 Co2 C13 C12 26.8(11) .
Co1 Co2 C13 C12 72.2(6) .
C4 Co2 C13 C16 46.6(11) .
C5 Co2 C13 C16 -54.7(11) .
C6 Co2 C13 C16 168.3(10) .
C12 Co2 C13 C16 141.6(13) .
Co1 Co2 C13 C16 -146.2(11) .
C4 Co2 C13 Co1 -167.2(4) .
C5 Co2 C13 Co1 91.5(6) .
C6 Co2 C13 Co1 -45.4(9) .
C12 Co2 C13 Co1 -72.2(6) .
C18 N2 C14 C15 0.1(14) .
Pt1 N2 C14 C15 -177.4(7) 2_766
N2 C14 C15 C16 -1.4(16) .
C14 C15 C16 C17 0.9(15) .
C14 C15 C16 C13 179.3(9) .
C12 C13 C16 C17 109.6(15) .
Co1 C13 C16 C17 -133.2(10) .
Co2 C13 C16 C17 -5.0(15) .
C12 C13 C16 C15 -68.7(18) .
Co1 C13 C16 C15 48.5(14) .
Co2 C13 C16 C15 176.7(8) .
C15 C16 C17 C18 0.7(14) .
C13 C16 C17 C18 -177.7(9) .
C14 N2 C18 C17 1.6(14) .
Pt1 N2 C18 C17 179.1(7) 2_766
C16 C17 C18 N2 -2.0(15) .
C25 As1 C19 C24 -27.1(10) .
C31 As1 C19 C24 -137.2(10) .
Pt1 As1 C19 C24 98.1(9) .
C25 As1 C19 C20 158.9(11) .
C31 As1 C19 C20 48.7(12) .
Pt1 As1 C19 C20 -76.0(11) .
C24 C19 C20 C21 6(2) .
As1 C19 C20 C21 -179.7(15) .
C19 C20 C21 C22 -1(3) .
C20 C21 C22 C23 -5(3) .
C21 C22 C23 C24 6(3) .
C20 C19 C24 C23 -5.4(19) .
As1 C19 C24 C23 -179.4(10) .
C22 C23 C24 C19 -1(2) .
C19 As1 C25 C30 -64.6(11) .
C31 As1 C25 C30 41.5(11) .
Pt1 As1 C25 C30 174.1(9) .
C19 As1 C25 C26 113.7(10) .
C31 As1 C25 C26 -140.2(10) .
Pt1 As1 C25 C26 -7.6(11) .
C30 C25 C26 C27 -2(2) .
As1 C25 C26 C27 -180.0(10) .
C25 C26 C27 C28 0(2) .
C26 C27 C28 C29 2(3) .
C27 C28 C29 C30 -3(3) .
C26 C25 C30 C29 1(2) .
As1 C25 C30 C29 179.3(12) .
C28 C29 C30 C25 1(3) .
C25 As1 C31 C32 38.9(11) .
C19 As1 C31 C32 147.6(9) .
Pt1 As1 C31 C32 -92.9(9) .
As1 C31 C32 C33 49.8(14) .
C31 C32 C33 C34 52.3(13) .
C32 C33 C34 As2 -111.6(9) .
C41 As2 C34 C33 -59.6(9) .
C35 As2 C34 C33 -168.7(8) .
Pt1 As2 C34 C33 65.5(9) .
C41 As2 C35 C40 19.2(11) .
C34 As2 C35 C40 127.3(10) .
Pt1 As2 C35 C40 -103.1(10) .
C41 As2 C35 C36 -161.1(9) .
C34 As2 C35 C36 -52.9(10) .
Pt1 As2 C35 C36 76.7(9) .
C40 C35 C36 C37 3.1(19) .
As2 C35 C36 C37 -176.7(10) .
C35 C36 C37 C38 -3(2) .
C36 C37 C38 C39 3(3) .
C37 C38 C39 C40 -2(3) .
C36 C35 C40 C39 -2.0(18) .
As2 C35 C40 C39 177.8(9) .
C38 C39 C40 C35 1(2) .
C34 As2 C41 C46 142.9(10) .
C35 As2 C41 C46 -109.6(10) .
Pt1 As2 C41 C46 13.4(10) .
C34 As2 C41 C42 -36.0(11) .
C35 As2 C41 C42 71.5(11) .
Pt1 As2 C41 C42 -165.5(9) .
C46 C41 C42 C43 0(2) .
As2 C41 C42 C43 179.0(14) .
C41 C42 C43 C44 0(3) .
C42 C43 C44 C45 1(3) .
C43 C44 C45 C46 -3(3) .
C44 C45 C46 C41 3(2) .
C42 C41 C46 C45 -2(2) .
As2 C41 C46 C45 179.3(11) .
O9 S1 C47 F2 -60.5(11) .
O8 S1 C47 F2 60.1(11) .
O7 S1 C47 F2 -179.1(11) .
O9 S1 C47 F1 177.7(10) .
O8 S1 C47 F1 -61.7(11) .
O7 S1 C47 F1 59.1(11) .
O9 S1 C47 F3 60.5(11) .
O8 S1 C47 F3 -178.9(10) .
O7 S1 C47 F3 -58.1(11) .
O10 S2 C48 F4' 19.8(15) .
O12' S2 C48 F4' 165.1(17) .
O11 S2 C48 F4' -100.3(16) .
O11' S2 C48 F4' -73.8(19) .
O10' S2 C48 F4' 46.0(18) .
O12 S2 C48 F4' 140.6(15) .
O10 S2 C48 F6 -178.6(11) .
O12' S2 C48 F6 -33.2(15) .
O11 S2 C48 F6 61.4(12) .
O11' S2 C48 F6 87.8(17) .
O10' S2 C48 F6 -152.3(15) .
O12 S2 C48 F6 -57.7(12) .
O10 S2 C48 F5 -56.9(13) .
O12' S2 C48 F5 88.5(16) .
O11 S2 C48 F5 -176.9(13) .
O11' S2 C48 F5 -150.5(18) .
O10' S2 C48 F5 -30.7(16) .
O12 S2 C48 F5 63.9(13) .
O10 S2 C48 F6' 146.0(14) .
O12' S2 C48 F6' -68.7(16) .
O11 S2 C48 F6' 25.9(15) .
O11' S2 C48 F6' 52.4(18) .
O10' S2 C48 F6' 172.2(17) .
O12 S2 C48 F6' -93.2(14) .
O10 S2 C48 F4 63.2(13) .
O12' S2 C48 F4 -151.4(15) .
O11 S2 C48 F4 -56.8(13) .
O11' S2 C48 F4 -30.4(17) .
O10' S2 C48 F4 89.5(16) .
O12 S2 C48 F4 -175.9(12) .
O10 S2 C48 F5' -98.7(16) .
O12' S2 C48 F5' 46.7(18) .
O11 S2 C48 F5' 141.3(17) .
O11' S2 C48 F5' 168(2) .
O10' S2 C48 F5' -72.4(18) .
O12 S2 C48 F5' 22.2(16) .
