#------------------------------------------------------------------------------
#$Date: 2016-03-21 10:31:56 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178655 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/66/4076678.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4076678
loop_
_publ_author_name
'Müller, Christian'
'Lachicotte, Rene J.'
'Jones, William D.'
_publ_section_title
;
 Chelating P,N versus P,P Ligands:  Differing Reactivity of
 Donor-Stabilized Pt(η2-PhC⋮CPh) Complexes Toward
 Diphenylacetylene
;
_journal_issue                   6
_journal_name_full               Organometallics
_journal_page_first              1118
_journal_paper_doi               10.1021/om010924a
_journal_volume                  21
_journal_year                    2002
_chemical_formula_sum            'C55 H57 N P Pt2'
_chemical_formula_weight         1153.17
_chemical_name_common            (P-N)Pt(C4Ph4)-Pt(PhCCPh)
_chemical_name_systematic
; 
? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                100.9160(10)
_cell_angle_beta                 104.8530(10)
_cell_angle_gamma                99.3400(10)
_cell_formula_units_Z            2
_cell_length_a                   10.7273(6)
_cell_length_b                   12.2851(7)
_cell_length_c                   18.8806(10)
_cell_measurement_temperature    193(2)
_cell_volume                     2302.5(2)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      193(2)
_diffrn_measured_fraction_theta_full 0.902
_diffrn_measured_fraction_theta_max 0.902
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'normal-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0235
_diffrn_reflns_av_sigmaI/netI    0.0640
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            14652
_diffrn_reflns_theta_full        28.25
_diffrn_reflns_theta_max         28.25
_diffrn_reflns_theta_min         1.73
_exptl_absorpt_coefficient_mu    6.141
_exptl_absorpt_correction_T_max  0.707
_exptl_absorpt_correction_T_min  0.928
_exptl_absorpt_correction_type   'Empirical "SADABS"'
_exptl_crystal_colour            Red
_exptl_crystal_density_diffrn    1.663
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Plate
_exptl_crystal_F_000             1130
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.22
_refine_diff_density_max         2.133
_refine_diff_density_min         -1.535
_refine_diff_density_rms         0.150
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.985
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     532
_refine_ls_number_reflns         10292
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.985
_refine_ls_R_factor_all          0.0668
_refine_ls_R_factor_gt           0.0419
_refine_ls_shift/su_max          0.985
_refine_ls_shift/su_mean         0.026
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0358P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0739
_refine_ls_wR_factor_ref         0.0797
_reflns_number_gt                7846
_reflns_number_total             10292
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om010924a.cif
_cod_data_source_block           sad_joncm09
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'na' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4076678
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt -0.23723(2) 0.953533(18) 0.246476(12) 0.02472(7) Uani 1 1 d .
Pt2 Pt 0.03705(2) 0.967867(18) 0.223576(12) 0.02225(7) Uani 1 1 d .
P1 P -0.43166(15) 0.83785(13) 0.16697(9) 0.0268(3) Uani 1 1 d .
N1 N -0.3644(5) 1.0816(4) 0.2494(3) 0.0404(14) Uani 1 1 d .
C1 C -0.5561(6) 0.9188(5) 0.1796(4) 0.0421(17) Uani 1 1 d .
H1A H -0.6363 0.8923 0.1354 0.051 Uiso 1 1 calc R
H1B H -0.5813 0.9098 0.2254 0.051 Uiso 1 1 calc R
C2 C -0.4942(7) 1.0406(6) 0.1874(5) 0.063(2) Uani 1 1 d .
H2A H -0.5559 1.0887 0.1984 0.075 Uiso 1 1 calc R
H2B H -0.4793 1.0493 0.1390 0.075 Uiso 1 1 calc R
C3 C -0.4424(6) 0.8147(5) 0.0645(3) 0.0339(15) Uani 1 1 d .
H3A H -0.4229 0.7385 0.0488 0.041 Uiso 1 1 calc R
C4 C -0.5773(7) 0.8135(6) 0.0116(4) 0.0480(19) Uani 1 1 d .
H4A H -0.5733 0.8003 -0.0406 0.072 Uiso 1 1 calc R
H4B H -0.6006 0.8868 0.0256 0.072 Uiso 1 1 calc R
H4C H -0.6443 0.7526 0.0158 0.072 Uiso 1 1 calc R
C5 C -0.3355(7) 0.9024(6) 0.0532(4) 0.0428(17) Uani 1 1 d .
H5A H -0.3418 0.8890 -0.0006 0.064 Uiso 1 1 calc R
H5B H -0.2481 0.8955 0.0818 0.064 Uiso 1 1 calc R
H5C H -0.3479 0.9790 0.0712 0.064 Uiso 1 1 calc R
C6 C -0.4975(6) 0.6980(5) 0.1813(3) 0.0321(14) Uani 1 1 d .
H6A H -0.4397 0.6464 0.1677 0.039 Uiso 1 1 calc R
C7 C -0.4825(7) 0.7108(6) 0.2652(3) 0.0445(18) Uani 1 1 d .
H7A H -0.5171 0.6372 0.2737 0.067 Uiso 1 1 calc R
H7B H -0.5319 0.7661 0.2816 0.067 Uiso 1 1 calc R
H7C H -0.3887 0.7374 0.2940 0.067 Uiso 1 1 calc R
C8 C -0.6376(6) 0.6416(5) 0.1333(4) 0.0393(16) Uani 1 1 d .
H8A H -0.6641 0.5684 0.1448 0.059 Uiso 1 1 calc R
H8B H -0.6423 0.6293 0.0798 0.059 Uiso 1 1 calc R
H8C H -0.6973 0.6907 0.1442 0.059 Uiso 1 1 calc R
C9 C -0.3860(9) 1.1035(7) 0.3232(5) 0.070(3) Uani 1 1 d .
H9A H -0.4415 1.1592 0.3258 0.106 Uiso 1 1 calc R
H9B H -0.3007 1.1334 0.3624 0.106 Uiso 1 1 calc R
H9C H -0.4303 1.0325 0.3312 0.106 Uiso 1 1 calc R
C10 C -0.3139(8) 1.1925(6) 0.2357(5) 0.059(2) Uani 1 1 d .
H10A H -0.3782 1.2404 0.2381 0.088 Uiso 1 1 calc R
H10B H -0.3004 1.1807 0.1857 0.088 Uiso 1 1 calc R
H10C H -0.2297 1.2301 0.2743 0.088 Uiso 1 1 calc R
C11 C 0.0916(5) 0.9488(5) 0.1287(3) 0.0247(13) Uani 1 1 d .
C12 C 0.1358(6) 1.0532(5) 0.1674(3) 0.0273(13) Uani 1 1 d .
C13 C 0.0824(5) 0.8678(5) 0.0592(3) 0.0252(13) Uani 1 1 d .
C14 C 0.1067(6) 0.9042(5) -0.0032(3) 0.0292(14) Uani 1 1 d .
H14A H 0.1295 0.9833 -0.0003 0.035 Uiso 1 1 calc R
C15 C 0.0979(6) 0.8274(6) -0.0684(3) 0.0357(16) Uani 1 1 d .
H15A H 0.1135 0.8543 -0.1100 0.043 Uiso 1 1 calc R
C16 C 0.0669(7) 0.7116(6) -0.0746(4) 0.0420(17) Uani 1 1 d .
H16A H 0.0611 0.6591 -0.1199 0.050 Uiso 1 1 calc R
C17 C 0.0441(7) 0.6735(5) -0.0127(4) 0.0426(17) Uani 1 1 d .
H17A H 0.0222 0.5943 -0.0158 0.051 Uiso 1 1 calc R
C18 C 0.0536(6) 0.7514(5) 0.0530(3) 0.0317(14) Uani 1 1 d .
H18A H 0.0400 0.7245 0.0950 0.038 Uiso 1 1 calc R
C19 C 0.2189(5) 1.1649(5) 0.1759(3) 0.0254(13) Uani 1 1 d .
C20 C 0.2365(6) 1.2031(6) 0.1122(4) 0.0386(16) Uani 1 1 d .
H20A H 0.1879 1.1590 0.0628 0.046 Uiso 1 1 calc R
C21 C 0.3236(7) 1.3038(6) 0.1214(4) 0.0474(19) Uani 1 1 d .
H21A H 0.3348 1.3284 0.0782 0.057 Uiso 1 1 calc R
C22 C 0.3943(7) 1.3688(6) 0.1922(4) 0.0499(19) Uani 1 1 d .
H22A H 0.4576 1.4362 0.1979 0.060 Uiso 1 1 calc R
C23 C 0.3734(7) 1.3364(6) 0.2549(4) 0.0465(18) Uani 1 1 d .
H23A H 0.4188 1.3835 0.3039 0.056 Uiso 1 1 calc R
C24 C 0.2852(6) 1.2342(5) 0.2464(4) 0.0356(15) Uani 1 1 d .
H24A H 0.2710 1.2124 0.2899 0.043 Uiso 1 1 calc R
C25 C -0.1216(5) 0.8388(5) 0.2510(3) 0.0237(13) Uani 1 1 d .
C26 C 0.0026(6) 0.8716(5) 0.3078(3) 0.0250(13) Uani 1 1 d .
C27 C 0.0392(6) 0.9959(5) 0.3447(3) 0.0271(13) Uani 1 1 d .
C28 C -0.0533(6) 1.0544(5) 0.3154(3) 0.0244(13) Uani 1 1 d .
C29 C -0.1706(6) 0.7170(5) 0.2105(4) 0.0300(14) Uani 1 1 d .
C30 C -0.1927(6) 0.6353(5) 0.2524(4) 0.0415(17) Uani 1 1 d .
H30A H -0.1747 0.6588 0.3056 0.050 Uiso 1 1 calc R
C31 C -0.2404(7) 0.5218(6) 0.2161(6) 0.062(2) Uani 1 1 d .
H31A H -0.2534 0.4679 0.2450 0.074 Uiso 1 1 calc R
C32 C -0.2689(8) 0.4857(6) 0.1406(6) 0.068(3) Uani 1 1 d .
H32A H -0.3044 0.4075 0.1165 0.081 Uiso 1 1 calc R
C33 C -0.2457(7) 0.5642(7) 0.0979(5) 0.061(2) Uani 1 1 d .
H33A H -0.2627 0.5392 0.0449 0.073 Uiso 1 1 calc R
C34 C -0.1981(6) 0.6785(5) 0.1335(4) 0.0379(16) Uani 1 1 d .
H34A H -0.1840 0.7316 0.1042 0.045 Uiso 1 1 calc R
C35 C 0.0897(6) 0.7940(5) 0.3307(3) 0.0283(13) Uani 1 1 d .
C36 C 0.1305(6) 0.7896(5) 0.4057(3) 0.0337(15) Uani 1 1 d .
H36A H 0.1024 0.8361 0.4421 0.040 Uiso 1 1 calc R
C37 C 0.2129(7) 0.7171(6) 0.4283(4) 0.0447(18) Uani 1 1 d .
H37A H 0.2421 0.7161 0.4800 0.054 Uiso 1 1 calc R
C38 C 0.2518(6) 0.6472(6) 0.3759(4) 0.0451(18) Uani 1 1 d .
H38A H 0.3072 0.5976 0.3909 0.054 Uiso 1 1 calc R
C39 C 0.2089(6) 0.6507(6) 0.3013(4) 0.0392(16) Uani 1 1 d .
H39A H 0.2335 0.6017 0.2644 0.047 Uiso 1 1 calc R
C40 C 0.1304(6) 0.7247(5) 0.2791(4) 0.0323(14) Uani 1 1 d .
H40A H 0.1043 0.7275 0.2276 0.039 Uiso 1 1 calc R
C41 C 0.1654(6) 1.0457(5) 0.4075(3) 0.0289(14) Uani 1 1 d .
C42 C 0.1590(7) 1.0782(6) 0.4811(3) 0.0426(18) Uani 1 1 d .
H42A H 0.0753 1.0754 0.4899 0.051 Uiso 1 1 calc R
C43 C 0.2731(8) 1.1144(6) 0.5416(4) 0.056(2) Uani 1 1 d .
H43A H 0.2669 1.1337 0.5916 0.067 Uiso 1 1 calc R
C44 C 0.3954(7) 1.1226(6) 0.5299(4) 0.052(2) Uani 1 1 d .
H44A H 0.4736 1.1489 0.5714 0.063 Uiso 1 1 calc R
C45 C 0.4033(6) 1.0924(6) 0.4574(4) 0.0414(17) Uani 1 1 d .
H45A H 0.4875 1.0989 0.4489 0.050 Uiso 1 1 calc R
C46 C 0.2893(6) 1.0525(5) 0.3966(3) 0.0327(15) Uani 1 1 d .
H46A H 0.2960 1.0296 0.3470 0.039 Uiso 1 1 calc R
C47 C -0.0247(6) 1.1813(5) 0.3402(3) 0.0277(13) Uani 1 1 d .
C48 C 0.0107(6) 1.2504(5) 0.2951(4) 0.0354(15) Uani 1 1 d .
H48A H 0.0256 1.2170 0.2492 0.042 Uiso 1 1 calc R
C49 C 0.0249(7) 1.3666(6) 0.3154(4) 0.0475(19) Uani 1 1 d .
H49A H 0.0489 1.4115 0.2832 0.057 Uiso 1 1 calc R
C50 C 0.0051(8) 1.4180(6) 0.3810(4) 0.054(2) Uani 1 1 d .
H50A H 0.0130 1.4979 0.3942 0.065 Uiso 1 1 calc R
C51 C -0.0268(9) 1.3508(6) 0.4279(5) 0.066(3) Uani 1 1 d .
H51A H -0.0380 1.3852 0.4746 0.079 Uiso 1 1 calc R
C52 C -0.0424(8) 1.2344(6) 0.4070(4) 0.050(2) Uani 1 1 d .
H52A H -0.0659 1.1897 0.4395 0.060 Uiso 1 1 calc R
C1S C 0.374(3) 1.410(3) 0.491(2) 0.32(2) Uani 1 1 d .
H1SA H 0.2962 1.3534 0.4817 0.380 Uiso 1 1 calc R
C2S C 0.492(3) 1.401(2) 0.4658(11) 0.188(13) Uani 1 1 d .
H2SA H 0.4977 1.3268 0.4432 0.226 Uiso 1 1 calc R
C3S C 0.595(3) 1.488(2) 0.4711(10) 0.171(8) Uani 1 1 d .
H3SA H 0.6515 1.4685 0.4418 0.205 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
C25 Pt1 C28 78.0(2) .
C25 Pt1 N1 176.3(2) .
C28 Pt1 N1 100.7(2) .
C25 Pt1 P1 99.39(16) .
C28 Pt1 P1 176.64(15) .
N1 Pt1 P1 82.05(14) .
C25 Pt1 Pt2 50.33(15) .
C28 Pt1 Pt2 50.28(14) .
N1 Pt1 Pt2 131.27(14) .
P1 Pt1 Pt2 126.40(4) .
C12 Pt2 C11 37.7(2) .
C12 Pt2 C26 158.9(2) .
C11 Pt2 C26 140.3(2) .
C12 Pt2 C27 133.9(2) .
C11 Pt2 C27 163.4(2) .
C26 Pt2 C27 39.1(2) .
C12 Pt2 C25 162.0(2) .
C11 Pt2 C25 126.8(2) .
C26 Pt2 C25 36.00(19) .
C27 Pt2 C25 63.7(2) .
C12 Pt2 C28 124.0(2) .
C11 Pt2 C28 156.0(2) .
C26 Pt2 C28 63.2(2) .
C27 Pt2 C28 34.80(19) .
C25 Pt2 C28 66.67(19) .
C12 Pt2 Pt1 134.26(16) .
C11 Pt2 Pt1 130.66(16) .
C26 Pt2 Pt1 65.74(15) .
C27 Pt2 Pt1 65.97(15) .
C25 Pt2 Pt1 41.29(14) .
C28 Pt2 Pt1 43.13(14) .
C1 P1 C6 103.7(3) .
C1 P1 C3 105.5(3) .
C6 P1 C3 106.4(3) .
C1 P1 Pt1 103.9(2) .
C6 P1 Pt1 121.7(2) .
C3 P1 Pt1 114.0(2) .
C9 N1 C10 107.5(6) .
C9 N1 C2 110.8(6) .
C10 N1 C2 101.4(5) .
C9 N1 Pt1 108.0(4) .
C10 N1 Pt1 117.3(4) .
C2 N1 Pt1 111.7(4) .
C2 C1 P1 106.3(5) .
C1 C2 N1 112.4(6) .
C5 C3 C4 109.7(5) .
C5 C3 P1 110.3(4) .
C4 C3 P1 115.5(5) .
C8 C6 C7 111.6(5) .
C8 C6 P1 115.2(4) .
C7 C6 P1 108.4(4) .
C12 C11 C13 145.3(6) .
C12 C11 Pt2 70.6(4) .
C13 C11 Pt2 144.1(4) .
C11 C12 C19 147.0(6) .
C11 C12 Pt2 71.7(4) .
C19 C12 Pt2 140.9(4) .
C18 C13 C14 117.2(5) .
C18 C13 C11 121.3(5) .
C14 C13 C11 121.5(5) .
C15 C14 C13 121.2(6) .
C14 C15 C16 121.2(6) .
C15 C16 C17 118.6(6) .
C18 C17 C16 119.9(6) .
C17 C18 C13 121.9(6) .
C24 C19 C20 118.1(6) .
C24 C19 C12 120.6(5) .
C20 C19 C12 121.2(5) .
C21 C20 C19 120.4(6) .
C22 C21 C20 120.7(7) .
C21 C22 C23 119.9(6) .
C22 C23 C24 120.0(6) .
C19 C24 C23 120.8(6) .
C26 C25 C29 118.2(5) .
C26 C25 Pt1 117.1(4) .
C29 C25 Pt1 123.3(4) .
C26 C25 Pt2 66.7(3) .
C29 C25 Pt2 124.4(4) .
Pt1 C25 Pt2 88.4(2) .
C25 C26 C35 125.5(5) .
C25 C26 C27 112.7(5) .
C35 C26 C27 121.8(5) .
C25 C26 Pt2 77.3(3) .
C35 C26 Pt2 119.7(4) .
C27 C26 Pt2 71.1(3) .
C28 C27 C26 113.5(5) .
C28 C27 C41 126.2(5) .
C26 C27 C41 120.3(5) .
C28 C27 Pt2 77.4(3) .
C26 C27 Pt2 69.8(3) .
C41 C27 Pt2 121.1(4) .
C27 C28 C47 120.1(5) .
C27 C28 Pt1 115.6(4) .
C47 C28 Pt1 123.9(4) .
C27 C28 Pt2 67.8(3) .
C47 C28 Pt2 119.5(4) .
Pt1 C28 Pt2 86.59(18) .
C34 C29 C30 117.7(6) .
C34 C29 C25 123.4(6) .
C30 C29 C25 119.0(6) .
C31 C30 C29 120.2(7) .
C32 C31 C30 121.5(8) .
C31 C32 C33 119.6(7) .
C34 C33 C32 119.6(8) .
C33 C34 C29 121.5(7) .
C40 C35 C36 118.5(6) .
C40 C35 C26 121.7(5) .
C36 C35 C26 119.7(6) .
C35 C36 C37 120.4(6) .
C38 C37 C36 120.4(6) .
C39 C38 C37 118.7(6) .
C38 C39 C40 120.9(7) .
C35 C40 C39 120.9(6) .
C46 C41 C42 118.2(6) .
C46 C41 C27 122.8(5) .
C42 C41 C27 118.8(5) .
C43 C42 C41 120.8(6) .
C44 C43 C42 120.4(7) .
C45 C44 C43 119.4(6) .
C44 C45 C46 120.5(7) .
C41 C46 C45 120.7(6) .
C52 C47 C48 116.9(6) .
C52 C47 C28 120.8(5) .
C48 C47 C28 122.1(5) .
C49 C48 C47 121.5(6) .
C50 C49 C48 121.1(7) .
C49 C50 C51 118.3(6) .
C52 C51 C50 120.4(7) .
C51 C52 C47 121.6(7) .
C3S C1S C2S 101(3) 2_686
C3S C2S C1S 128(3) .
C1S C3S C2S 130(3) 2_686
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C25 2.023(6) .
Pt1 C28 2.098(6) .
Pt1 N1 2.245(5) .
Pt1 P1 2.2908(15) .
Pt1 Pt2 3.0640(3) .
Pt2 C12 1.995(6) .
Pt2 C11 2.008(6) .
Pt2 C26 2.222(5) .
Pt2 C27 2.241(5) .
Pt2 C25 2.359(5) .
Pt2 C28 2.361(5) .
P1 C1 1.826(6) .
P1 C6 1.845(6) .
P1 C3 1.871(6) .
N1 C9 1.454(9) .
N1 C10 1.477(9) .
N1 C2 1.508(9) .
C1 C2 1.498(9) .
C3 C5 1.528(8) .
C3 C4 1.529(8) .
C6 C8 1.512(8) .
C6 C7 1.525(8) .
C11 C12 1.294(8) .
C11 C13 1.458(8) .
C12 C19 1.466(8) .
C13 C18 1.388(8) .
C13 C14 1.407(8) .
C14 C15 1.373(8) .
C15 C16 1.382(9) .
C16 C17 1.401(9) .
C17 C18 1.386(8) .
C19 C24 1.376(8) .
C19 C20 1.415(8) .
C20 C21 1.376(9) .
C21 C22 1.371(10) .
C22 C23 1.378(9) .
C23 C24 1.399(9) .
C25 C26 1.422(7) .
C25 C29 1.485(8) .
C26 C35 1.486(8) .
C26 C27 1.494(8) .
C27 C28 1.381(8) .
C27 C41 1.499(8) .
C28 C47 1.495(7) .
C29 C34 1.378(8) .
C29 C30 1.416(8) .
C30 C31 1.379(9) .
C31 C32 1.348(12) .
C32 C33 1.400(11) .
C33 C34 1.385(9) .
C35 C40 1.375(8) .
C35 C36 1.384(8) .
C36 C37 1.401(9) .
C37 C38 1.377(10) .
C38 C39 1.376(9) .
C39 C40 1.386(8) .
C41 C46 1.388(8) .
C41 C42 1.394(8) .
C42 C43 1.383(9) .
C43 C44 1.377(10) .
C44 C45 1.377(9) .
C45 C46 1.388(8) .
C47 C52 1.381(8) .
C47 C48 1.387(8) .
C48 C49 1.378(8) .
C49 C50 1.363(9) .
C50 C51 1.387(10) .
C51 C52 1.380(9) .
C1S C3S 1.26(3) 2_686
C1S C2S 1.47(4) .
C2S C3S 1.37(2) .
C3S C1S 1.26(3) 2_686
