#------------------------------------------------------------------------------
#$Date: 2016-03-21 10:36:45 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178659 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/70/4077063.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4077063
loop_
_publ_author_name
'Martín, Marta'
'Sola, Eduardo'
'Lahoz, Fernando J.'
'Oro, Luis A.'
_publ_section_title
;
 Trans Additions of Silanes to 1-Alkynes Catalyzed by Ruthenium
 Complexes:  Role of in Situ Formed Polynuclear Aggregates
;
_journal_issue                   20
_journal_name_full               Organometallics
_journal_page_first              4027
_journal_paper_doi               10.1021/om0205243
_journal_volume                  21
_journal_year                    2002
_chemical_formula_moiety         'C32 H73 Cl O2 P2 Ru2 Si2, 0.5(C6 H14)'
_chemical_formula_sum            'C35 H80 Cl O2 P2 Ru2 Si2'
_chemical_formula_weight         888.70
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                108.263(2)
_cell_angle_beta                 91.088(2)
_cell_angle_gamma                101.615(2)
_cell_formula_units_Z            2
_cell_length_a                   11.5346(11)
_cell_length_b                   11.7231(11)
_cell_length_c                   17.5248(17)
_cell_measurement_reflns_used    2997
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      22.54
_cell_measurement_theta_min      2.27
_cell_volume                     2195.7(4)
_computing_cell_refinement       'SAINT+ v. 6.01 (Bruker AXS, 2000)'
_computing_data_collection       'SMART v. 5.611 (Bruker AXS, 2000)'
_computing_data_reduction        'SAINT+ v. 6.01 (Bruker AXS, 2000)'
_computing_molecular_graphics    'XP program, SHELXTL v6.10,Bruker2000'
_computing_publication_material  'XCIF program, SHELXTLv6.10,BrukerAXS'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.26
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker SMART APEX CCD system'
_diffrn_measurement_method       'ω rotations with narrow frames'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0776
_diffrn_reflns_av_sigmaI/netI    0.1402
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            22063
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         1.81
_diffrn_standards_decay_%        'no decay'
_exptl_absorpt_coefficient_mu    0.903
_exptl_absorpt_correction_T_max  0.9422
_exptl_absorpt_correction_T_min  0.7424
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
; SADABS: Area-Detector Absorption Correction. (1996)  Bruker-AXS 
  within SAINT+ package, v. 6.01.
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.344
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             938
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.04
_refine_diff_density_max         0.685
_refine_diff_density_min         -1.104
_refine_diff_density_rms         0.122
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.908
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     457
_refine_ls_number_reflns         7726
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      0.908
_refine_ls_R_factor_all          0.0926
_refine_ls_R_factor_gt           0.0537
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0163P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0880
_refine_ls_wR_factor_ref         0.0970
_reflns_number_gt                5057
_reflns_number_total             7726
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om0205243.cif
_cod_data_source_block           compound9
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4077063
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ru1 Ru 0.18097(5) -0.07035(5) 0.23779(3) 0.01425(15) Uani 1 1 d D
Ru2 Ru 0.35659(5) 0.14500(5) 0.23747(3) 0.01416(15) Uani 1 1 d D
H1 H 0.346(3) -0.014(3) 0.230(3) 0.016(16) Uiso 1 1 d D
Cl1 Cl 0.14268(13) 0.11720(14) 0.22330(10) 0.0157(4) Uani 1 1 d .
P1 P -0.02077(15) -0.14787(16) 0.25100(11) 0.0175(4) Uani 1 1 d .
P2 P 0.40025(15) 0.33478(16) 0.21031(10) 0.0164(4) Uani 1 1 d .
Si1 Si 0.20509(16) -0.19000(18) 0.10514(11) 0.0178(5) Uani 1 1 d .
Si2 Si 0.40860(16) 0.20717(17) 0.37813(11) 0.0164(4) Uani 1 1 d .
O1 O 0.2698(4) -0.2617(4) 0.2847(3) 0.0224(12) Uani 1 1 d .
O2 O 0.6031(4) 0.1057(4) 0.2178(3) 0.0248(12) Uani 1 1 d .
C1 C 0.2338(5) -0.1862(6) 0.2652(4) 0.0140(15) Uani 1 1 d .
C2 C 0.5076(6) 0.1237(6) 0.2266(4) 0.0146(15) Uani 1 1 d .
C3 C 0.3676(5) -0.1717(6) 0.0833(4) 0.0199(17) Uani 1 1 d .
H3A H 0.3714(6) -0.2189(18) 0.027(2) 0.021(6) Uiso 1 1 calc R
H3B H 0.3997(13) -0.085(3) 0.0898(4) 0.021(6) Uiso 1 1 calc R
C4 C 0.4484(6) -0.2126(7) 0.1364(4) 0.029(2) Uani 1 1 d .
H4A H 0.446(3) -0.167(3) 0.1920(18) 0.035(5) Uiso 1 1 calc R
H4B H 0.529(3) -0.197(3) 0.1221(17) 0.035(5) Uiso 1 1 calc R
H4C H 0.421(2) -0.299(3) 0.1279(18) 0.035(5) Uiso 1 1 calc R
C5 C 0.1287(6) -0.1391(6) 0.0289(4) 0.027(2) Uani 1 1 d .
H5A H 0.053(3) -0.1746(16) 0.0227(4) 0.021(6) Uiso 1 1 calc R
H5B H 0.1339(6) -0.060(3) 0.0491(10) 0.021(6) Uiso 1 1 calc R
C6 C 0.1767(6) -0.1664(7) -0.0562(4) 0.035(2) Uani 1 1 d .
H6A H 0.258(3) -0.123(3) -0.0511(5) 0.035(5) Uiso 1 1 calc R
H6B H 0.130(3) -0.140(3) -0.0903(14) 0.035(5) Uiso 1 1 calc R
H6C H 0.172(3) -0.253(3) -0.0793(13) 0.035(5) Uiso 1 1 calc R
C7 C 0.1526(6) -0.3616(6) 0.0807(4) 0.0244(19) Uani 1 1 d .
H7A H 0.1850(14) -0.3825(11) 0.1167(16) 0.021(6) Uiso 1 1 calc R
H7B H 0.078(3) -0.3768(9) 0.0846(5) 0.021(6) Uiso 1 1 calc R
C8 C 0.1763(7) -0.4449(6) -0.0029(4) 0.035(2) Uani 1 1 d .
H8A H 0.137(3) -0.425(2) -0.0456(14) 0.035(5) Uiso 1 1 calc R
H8B H 0.145(3) -0.532(3) -0.0081(10) 0.035(5) Uiso 1 1 calc R
H8C H 0.262(3) -0.431(3) -0.0080(10) 0.035(5) Uiso 1 1 calc R
C9 C -0.1231(5) -0.1995(6) 0.1582(4) 0.0180(16) Uani 1 1 d .
H9 H -0.081(2) -0.253(3) 0.113(2) 0.013(9) Uiso 1 1 calc R
C10 C -0.1385(6) -0.0905(6) 0.1313(4) 0.028(2) Uani 1 1 d .
H10A H -0.174(3) -0.1200(10) 0.0781(18) 0.022(3) Uiso 1 1 calc R
H10B H -0.064(2) -0.039(2) 0.134(2) 0.022(3) Uiso 1 1 calc R
H10C H -0.187(3) -0.046(2) 0.1659(16) 0.022(3) Uiso 1 1 calc R
C11 C -0.2462(5) -0.2796(6) 0.1571(4) 0.028(2) Uani 1 1 d .
H11A H -0.2904(18) -0.2339(18) 0.2027(18) 0.022(3) Uiso 1 1 calc R
H11B H -0.2369(6) -0.360(3) 0.165(2) 0.022(3) Uiso 1 1 calc R
H11C H -0.2931(18) -0.298(3) 0.1030(17) 0.022(3) Uiso 1 1 calc R
C12 C -0.0603(6) -0.2755(6) 0.2935(4) 0.0189(16) Uani 1 1 d .
H12 H -0.1529 -0.2865 0.3005 0.023 Uiso 1 1 d R
C13 C -0.0359(6) -0.3954(6) 0.2377(4) 0.0231(18) Uani 1 1 d .
H13A H 0.051(3) -0.3871(12) 0.2344(16) 0.022(3) Uiso 1 1 calc R
H13B H -0.076(3) -0.4140(18) 0.1830(17) 0.022(3) Uiso 1 1 calc R
H13C H -0.067(3) -0.463(2) 0.2593(13) 0.022(3) Uiso 1 1 calc R
C14 C -0.0009(6) -0.2444(6) 0.3790(4) 0.030(2) Uani 1 1 d .
H14A H -0.023(3) -0.317(2) 0.3979(11) 0.022(3) Uiso 1 1 calc R
H14B H -0.028(3) -0.173(3) 0.4161(12) 0.022(3) Uiso 1 1 calc R
H14C H 0.087(3) -0.223(3) 0.3781(6) 0.022(3) Uiso 1 1 calc R
C15 C -0.0731(5) -0.0182(6) 0.3203(4) 0.0218(17) Uani 1 1 d .
H15 H -0.0781(6) 0.041(3) 0.2880(18) 0.013(9) Uiso 1 1 calc R
C16 C -0.1991(6) -0.0456(7) 0.3508(5) 0.036(2) Uani 1 1 d .
H16A H -0.2047(12) -0.112(3) 0.373(2) 0.022(3) Uiso 1 1 calc R
H16B H -0.2587(19) -0.069(3) 0.3065(14) 0.022(3) Uiso 1 1 calc R
H16C H -0.2109(14) 0.027(2) 0.3917(19) 0.022(3) Uiso 1 1 calc R
C17 C 0.0182(6) 0.0563(6) 0.3935(4) 0.0237(18) Uani 1 1 d .
H17A H -0.0063(19) 0.136(3) 0.4237(15) 0.022(3) Uiso 1 1 calc R
H17B H 0.100(2) 0.076(3) 0.3739(6) 0.022(3) Uiso 1 1 calc R
H17C H 0.021(2) 0.006(2) 0.4312(15) 0.022(3) Uiso 1 1 calc R
C18 C 0.5680(6) 0.2920(7) 0.4146(4) 0.0254(19) Uani 1 1 d .
H18A H 0.618(2) 0.244(2) 0.3863(12) 0.021(6) Uiso 1 1 calc R
H18B H 0.5819(8) 0.364(3) 0.4020(7) 0.021(6) Uiso 1 1 calc R
C19 C 0.6017(6) 0.3241(6) 0.5060(4) 0.032(2) Uani 1 1 d .
H19A H 0.556(3) 0.378(3) 0.5353(10) 0.035(5) Uiso 1 1 calc R
H19B H 0.682(3) 0.362(4) 0.5179(7) 0.035(5) Uiso 1 1 calc R
H19C H 0.587(3) 0.252(2) 0.5199(8) 0.035(5) Uiso 1 1 calc R
C20 C 0.3050(6) 0.3080(6) 0.4303(4) 0.0253(19) Uani 1 1 d .
H20A H 0.3368(13) 0.388(3) 0.4316(4) 0.021(6) Uiso 1 1 calc R
H20B H 0.233(3) 0.2818(11) 0.3989(13) 0.021(6) Uiso 1 1 calc R
C21 C 0.2803(6) 0.3108(7) 0.5169(4) 0.030(2) Uani 1 1 d .
H21A H 0.246(3) 0.230(3) 0.5167(5) 0.035(5) Uiso 1 1 calc R
H21B H 0.227(3) 0.363(3) 0.5367(12) 0.035(5) Uiso 1 1 calc R
H21C H 0.352(2) 0.341(4) 0.5504(13) 0.035(5) Uiso 1 1 calc R
C22 C 0.3885(6) 0.0719(6) 0.4178(4) 0.0235(19) Uani 1 1 d .
H22A H 0.3934(6) 0.1020(13) 0.474(2) 0.021(6) Uiso 1 1 calc R
H22B H 0.312(3) 0.023(2) 0.4000(8) 0.021(6) Uiso 1 1 calc R
C23 C 0.4795(6) -0.0104(6) 0.3922(4) 0.0261(19) Uani 1 1 d .
H23A H 0.483(3) -0.034(3) 0.3330(18) 0.035(5) Uiso 1 1 calc R
H23B H 0.455(2) -0.085(3) 0.408(2) 0.035(5) Uiso 1 1 calc R
H23C H 0.559(3) 0.0355(19) 0.420(2) 0.035(5) Uiso 1 1 calc R
C24 C 0.2771(5) 0.4146(6) 0.2051(4) 0.0163(16) Uani 1 1 d .
H24 H 0.3141 0.4901 0.2040 0.020 Uiso 1 1 d R
C25 C 0.2264(6) 0.4498(6) 0.2865(4) 0.0219(18) Uani 1 1 d .
H25A H 0.169(3) 0.505(3) 0.2865(8) 0.022(3) Uiso 1 1 calc R
H25B H 0.2935(19) 0.495(3) 0.3304(13) 0.022(3) Uiso 1 1 calc R
H25C H 0.183(3) 0.373(2) 0.2970(10) 0.022(3) Uiso 1 1 calc R
C26 C 0.1787(6) 0.3476(6) 0.1371(4) 0.0270(19) Uani 1 1 d .
H26A H 0.146(2) 0.269(3) 0.1403(13) 0.022(3) Uiso 1 1 calc R
H26B H 0.2105(12) 0.339(3) 0.0870(15) 0.022(3) Uiso 1 1 calc R
H26C H 0.119(2) 0.393(2) 0.1419(13) 0.022(3) Uiso 1 1 calc R
C27 C 0.4552(6) 0.2968(6) 0.1081(4) 0.0197(17) Uani 1 1 d .
H27 H 0.530(5) 0.2834(10) 0.1145(5) 0.013(9) Uiso 1 1 calc R
C28 C 0.4698(6) 0.3982(6) 0.0689(4) 0.0256(19) Uani 1 1 d .
H28A H 0.493(3) 0.3689(15) 0.0174(18) 0.022(3) Uiso 1 1 calc R
H28B H 0.527(3) 0.465(2) 0.0994(15) 0.022(3) Uiso 1 1 calc R
H28C H 0.398(2) 0.421(2) 0.066(2) 0.022(3) Uiso 1 1 calc R
C29 C 0.3804(6) 0.1742(6) 0.0520(4) 0.0268(19) Uani 1 1 d .
H29A H 0.299(3) 0.1843(10) 0.0408(17) 0.022(3) Uiso 1 1 calc R
H29B H 0.376(3) 0.110(2) 0.0784(11) 0.022(3) Uiso 1 1 calc R
H29C H 0.418(2) 0.1490(18) 0.0003(17) 0.022(3) Uiso 1 1 calc R
C30 C 0.5200(5) 0.4637(6) 0.2770(4) 0.0155(16) Uani 1 1 d .
H30 H 0.5080(9) 0.4667(6) 0.330(3) 0.013(9) Uiso 1 1 calc R
C31 C 0.6427(5) 0.4350(6) 0.2613(4) 0.0176(17) Uani 1 1 d .
H31A H 0.6674(16) 0.451(3) 0.2131(18) 0.022(3) Uiso 1 1 calc R
H31B H 0.6390(8) 0.350(3) 0.255(2) 0.022(3) Uiso 1 1 calc R
H31C H 0.6987(18) 0.486(3) 0.3060(16) 0.022(3) Uiso 1 1 calc R
C32 C 0.5191(6) 0.5923(6) 0.2726(4) 0.028(2) Uani 1 1 d .
H32A H 0.577(3) 0.6418(19) 0.300(2) 0.022(3) Uiso 1 1 calc R
H32B H 0.458(3) 0.6124(17) 0.290(2) 0.022(3) Uiso 1 1 calc R
H32C H 0.522(3) 0.5911(10) 0.2258(16) 0.022(3) Uiso 1 1 calc R
C33 C 0.9031(6) 0.3006(7) 0.3246(5) 0.039(2) Uani 1 1 d .
H33A H 0.932(4) 0.355(2) 0.2954(14) 0.066(16) Uiso 1 1 calc R
H33B H 0.827(3) 0.252(4) 0.3009(14) 0.066(16) Uiso 1 1 calc R
H33C H 0.957(4) 0.249(4) 0.3233(5) 0.066(16) Uiso 1 1 calc R
C34 C 0.8933(6) 0.3755(7) 0.4121(5) 0.036(2) Uani 1 1 d .
H34A H 0.836(2) 0.425(2) 0.4126(5) 0.020(9) Uiso 1 1 calc R
H34B H 0.8633(14) 0.319(2) 0.4408(12) 0.020(9) Uiso 1 1 calc R
C35 C 1.0084(6) 0.4588(7) 0.4568(4) 0.031(2) Uani 1 1 d .
H35A H 1.0451(15) 0.515(2) 0.4235(12) 0.020(9) Uiso 1 1 calc R
H35B H 1.069(2) 0.4046(19) 0.4612(4) 0.020(9) Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ru1 Si1 83.8(2) . .
C1 Ru1 P1 94.7(2) . .
Si1 Ru1 P1 102.20(7) . .
C1 Ru1 Cl1 167.4(2) . .
Si1 Ru1 Cl1 104.13(6) . .
P1 Ru1 Cl1 93.22(6) . .
C1 Ru1 Ru2 117.06(19) . .
Si1 Ru1 Ru2 95.08(5) . .
P1 Ru1 Ru2 145.37(5) . .
Cl1 Ru1 Ru2 53.19(4) . .
C1 Ru1 H1 82.3(12) . .
Si1 Ru1 H1 78.1(15) . .
P1 Ru1 H1 176.9(12) . .
Cl1 Ru1 H1 89.6(11) . .
Ru2 Ru1 H1 37.2(11) . .
C2 Ru2 Si2 85.6(2) . .
C2 Ru2 P2 93.1(2) . .
Si2 Ru2 P2 102.52(7) . .
C2 Ru2 Cl1 163.9(2) . .
Si2 Ru2 Cl1 105.18(6) . .
P2 Ru2 Cl1 96.06(6) . .
C2 Ru2 Ru1 115.6(2) . .
Si2 Ru2 Ru1 93.30(5) . .
P2 Ru2 Ru1 148.35(5) . .
Cl1 Ru2 Ru1 53.01(4) . .
C2 Ru2 H1 75.7(12) . .
Si2 Ru2 H1 90.5(16) . .
P2 Ru2 H1 162.2(15) . .
Cl1 Ru2 H1 92.1(12) . .
Ru1 Ru2 H1 39.9(12) . .
Ru1 Cl1 Ru2 73.80(5) . .
C15 P1 C9 105.0(3) . .
C15 P1 C12 105.4(3) . .
C9 P1 C12 103.4(3) . .
C15 P1 Ru1 106.0(2) . .
C9 P1 Ru1 116.2(2) . .
C12 P1 Ru1 119.6(2) . .
C27 P2 C24 105.6(3) . .
C27 P2 C30 105.1(3) . .
C24 P2 C30 102.3(3) . .
C27 P2 Ru2 105.1(2) . .
C24 P2 Ru2 118.9(2) . .
C30 P2 Ru2 118.6(2) . .
C7 Si1 C5 109.0(3) . .
C7 Si1 C3 103.2(3) . .
C5 Si1 C3 106.1(3) . .
C7 Si1 Ru1 115.4(2) . .
C5 Si1 Ru1 110.4(2) . .
C3 Si1 Ru1 112.2(2) . .
C20 Si2 C18 109.1(3) . .
C20 Si2 C22 107.3(3) . .
C18 Si2 C22 103.6(3) . .
C20 Si2 Ru2 107.6(2) . .
C18 Si2 Ru2 116.5(2) . .
C22 Si2 Ru2 112.4(2) . .
O1 C1 Ru1 178.7(6) . .
O2 C2 Ru2 177.5(6) . .
C4 C3 Si1 115.9(5) . .
C4 C3 H3A 108.3 . .
Si1 C3 H3A 108.3 . .
C4 C3 H3B 108.3 . .
Si1 C3 H3B 108.3 . .
H3A C3 H3B 107.4 . .
C3 C4 H4A 109.5 . .
C3 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
C3 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
C6 C5 Si1 116.6(5) . .
C6 C5 H5A 108.1 . .
Si1 C5 H5A 108.1 . .
C6 C5 H5B 108.1 . .
Si1 C5 H5B 108.1 . .
H5A C5 H5B 107.3 . .
C5 C6 H6A 109.5 . .
C5 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C5 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C8 C7 Si1 117.5(5) . .
C8 C7 H7A 107.9 . .
Si1 C7 H7A 107.9 . .
C8 C7 H7B 107.9 . .
Si1 C7 H7B 107.9 . .
H7A C7 H7B 107.2 . .
C7 C8 H8A 109.5 . .
C7 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C7 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C11 C9 C10 108.6(5) . .
C11 C9 P1 118.5(5) . .
C10 C9 P1 111.3(4) . .
C11 C9 H9 105.8 . .
C10 C9 H9 105.8 . .
P1 C9 H9 105.8 . .
C9 C10 H10A 109.5 . .
C9 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C9 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C9 C11 H11A 109.5 . .
C9 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C9 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C13 C12 C14 110.9(5) . .
C13 C12 P1 112.0(5) . .
C14 C12 P1 113.1(5) . .
C13 C12 H12 109.5 . .
C14 C12 H12 105.1 . .
P1 C12 H12 105.8 . .
C12 C13 H13A 109.5 . .
C12 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C12 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
C12 C14 H14A 109.5 . .
C12 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C12 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C17 C15 C16 109.1(6) . .
C17 C15 P1 112.3(4) . .
C16 C15 P1 117.9(5) . .
C17 C15 H15 105.5 . .
C16 C15 H15 105.5 . .
P1 C15 H15 105.5 . .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C15 C17 H17A 109.5 . .
C15 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C15 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C19 C18 Si2 115.4(5) . .
C19 C18 H18A 108.4 . .
Si2 C18 H18A 108.4 . .
C19 C18 H18B 108.4 . .
Si2 C18 H18B 108.4 . .
H18A C18 H18B 107.5 . .
C18 C19 H19A 109.5 . .
C18 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
C18 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
C21 C20 Si2 116.7(5) . .
C21 C20 H20A 108.1 . .
Si2 C20 H20A 108.1 . .
C21 C20 H20B 108.1 . .
Si2 C20 H20B 108.1 . .
H20A C20 H20B 107.3 . .
C20 C21 H21A 109.5 . .
C20 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C20 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
C23 C22 Si2 114.9(5) . .
C23 C22 H22A 108.5 . .
Si2 C22 H22A 108.5 . .
C23 C22 H22B 108.5 . .
Si2 C22 H22B 108.5 . .
H22A C22 H22B 107.5 . .
C22 C23 H23A 109.5 . .
C22 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C22 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C25 C24 C26 111.1(5) . .
C25 C24 P2 109.5(4) . .
C26 C24 P2 116.4(5) . .
C25 C24 H24 100.4 . .
C26 C24 H24 113.4 . .
P2 C24 H24 104.6 . .
C24 C25 H25A 109.5 . .
C24 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
C24 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
C24 C26 H26A 109.5 . .
C24 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C24 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
C28 C27 C29 111.8(5) . .
C28 C27 P2 116.2(5) . .
C29 C27 P2 110.4(5) . .
C28 C27 H27 105.9 . .
C29 C27 H27 105.9 . .
P2 C27 H27 105.9 . .
C27 C28 H28A 109.5 . .
C27 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C27 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
C27 C29 H29A 109.5 . .
C27 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
C27 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
C31 C30 C32 110.1(5) . .
C31 C30 P2 110.7(4) . .
C32 C30 P2 115.5(4) . .
C31 C30 H30 106.7 . .
C32 C30 H30 106.7 . .
P2 C30 H30 106.7 . .
C30 C31 H31A 109.5 . .
C30 C31 H31B 109.5 . .
H31A C31 H31B 109.5 . .
C30 C31 H31C 109.5 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
C30 C32 H32A 109.5 . .
C30 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
C30 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
C34 C33 H33A 109.5 . .
C34 C33 H33B 109.5 . .
H33A C33 H33B 109.5 . .
C34 C33 H33C 109.5 . .
H33A C33 H33C 109.5 . .
H33B C33 H33C 109.5 . .
C35 C34 C33 114.9(6) . .
C35 C34 H34A 108.5 . .
C33 C34 H34A 108.5 . .
C35 C34 H34B 108.5 . .
C33 C34 H34B 108.5 . .
H34A C34 H34B 107.5 . .
C34 C35 C35 112.8(7) . 2_766
C34 C35 H35A 109.0 . .
C35 C35 H35A 109.0 2_766 .
C34 C35 H35B 109.0 . .
C35 C35 H35B 109.0 2_766 .
H35A C35 H35B 107.8 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ru1 C1 1.783(7) .
Ru1 Si1 2.364(2) .
Ru1 P1 2.3654(18) .
Ru1 Cl1 2.4145(17) .
Ru1 Ru2 2.9029(8) .
Ru1 H1 1.91(4) .
Ru2 C2 1.814(7) .
Ru2 Si2 2.3685(19) .
Ru2 P2 2.3772(19) .
Ru2 Cl1 2.4204(16) .
Ru2 H1 1.80(4) .
P1 C15 1.841(7) .
P1 C9 1.851(6) .
P1 C12 1.855(6) .
P2 C27 1.862(7) .
P2 C24 1.868(6) .
P2 C30 1.884(6) .
Si1 C7 1.886(7) .
Si1 C5 1.894(7) .
Si1 C3 1.903(6) .
Si2 C20 1.896(7) .
Si2 C18 1.897(7) .
Si2 C22 1.898(7) .
O1 C1 1.185(7) .
O2 C2 1.166(7) .
C3 C4 1.546(8) .
C3 H3A 0.9736 .
C3 H3B 0.9736 .
C4 H4A 0.9583 .
C4 H4B 0.9583 .
C4 H4C 0.9583 .
C5 C6 1.560(9) .
C5 H5A 0.8726 .
C5 H5B 0.8726 .
C6 H6A 0.9579 .
C6 H6B 0.9579 .
C6 H6C 0.9579 .
C7 C8 1.550(9) .
C7 H7A 0.8496 .
C7 H7B 0.8496 .
C8 H8A 0.9828 .
C8 H8B 0.9828 .
C8 H8C 0.9828 .
C9 C11 1.532(8) .
C9 C10 1.533(8) .
C9 H9 1.0442 .
C10 H10A 0.9419 .
C10 H10B 0.9419 .
C10 H10C 0.9419 .
C11 H11A 1.0212 .
C11 H11B 1.0212 .
C11 H11C 1.0212 .
C12 C13 1.523(8) .
C12 C14 1.537(8) .
C12 H12 1.0644 .
C13 H13A 0.9942 .
C13 H13B 0.9942 .
C13 H13C 0.9942 .
C14 H14A 0.9929 .
C14 H14B 0.9929 .
C14 H14C 0.9929 .
C15 C17 1.547(8) .
C15 C16 1.565(8) .
C15 H15 1.0346 .
C16 H16A 0.9601 .
C16 H16B 0.9601 .
C16 H16C 0.9601 .
C17 H17A 1.0208 .
C17 H17B 1.0208 .
C17 H17C 1.0208 .
C18 C19 1.548(8) .
C18 H18A 0.9271 .
C18 H18B 0.9271 .
C19 H19A 0.9345 .
C19 H19B 0.9345 .
C19 H19C 0.9345 .
C20 C21 1.540(9) .
C20 H20A 0.9318 .
C20 H20B 0.9318 .
C21 H21A 0.9458 .
C21 H21B 0.9458 .
C21 H21C 0.9458 .
C22 C23 1.545(8) .
C22 H22A 0.9325 .
C22 H22B 0.9325 .
C23 H23A 0.9894 .
C23 H23B 0.9894 .
C23 H23C 0.9894 .
C24 C25 1.519(9) .
C24 C26 1.526(8) .
C24 H24 0.9076 .
C25 H25A 1.0151 .
C25 H25B 1.0151 .
C25 H25C 1.0151 .
C26 H26A 0.9415 .
C26 H26B 0.9415 .
C26 H26C 0.9415 .
C27 C28 1.533(8) .
C27 C29 1.536(8) .
C27 H27 0.9197 .
C28 H28A 0.9250 .
C28 H28B 0.9250 .
C28 H28C 0.9250 .
C29 H29A 0.9967 .
C29 H29B 0.9967 .
C29 H29C 0.9967 .
C30 C31 1.530(8) .
C30 C32 1.536(8) .
C30 H30 0.9255 .
C31 H31A 0.9582 .
C31 H31B 0.9582 .
C31 H31C 0.9582 .
C32 H32A 0.8173 .
C32 H32B 0.8173 .
C32 H32C 0.8173 .
C33 C34 1.528(9) .
C33 H33A 0.9476 .
C33 H33B 0.9476 .
C33 H33C 0.9476 .
C34 C35 1.513(9) .
C34 H34A 0.9635 .
C34 H34B 0.9635 .
C35 C35 1.561(13) 2_766
C35 H35A 1.0490 .
C35 H35B 1.0490 .
