#------------------------------------------------------------------------------
#$Date: 2016-03-21 10:49:17 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178669 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/80/4078003.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4078003
loop_
_publ_author_name
'Townsend, Nell S.'
'Green, Michael'
'Russell, Christopher A.'
_publ_section_title
;
 Cationic Gold(I) Complexes of
 2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene
;
_journal_issue                   7
_journal_name_full               Organometallics
_journal_page_first              2543
_journal_paper_doi               10.1021/om201265n
_journal_volume                  31
_journal_year                    2012
_chemical_formula_moiety         'C42 H61 Au N2 P3, F6 Sb, C H2 Cl2'
_chemical_formula_sum            'C43 H63 Au Cl2 F6 N2 P3 Sb'
_chemical_formula_weight         1204.48
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           176
_symmetry_cell_setting           hexagonal
_symmetry_space_group_name_Hall  '-P 6c'
_symmetry_space_group_name_H-M   'P 63/m'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            6
_cell_length_a                   24.1530(6)
_cell_length_b                   24.1530(6)
_cell_length_c                   16.6932(8)
_cell_measurement_reflns_used    3487
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      19.91
_cell_measurement_theta_min      2.58
_cell_volume                     8433.6(5)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0989
_diffrn_reflns_av_sigmaI/netI    0.0556
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_number            31989
_diffrn_reflns_theta_full        21.97
_diffrn_reflns_theta_max         21.97
_diffrn_reflns_theta_min         0.97
_exptl_absorpt_coefficient_mu    3.314
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6615
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS-2008/1
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.423
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             3588
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.042
_exptl_crystal_size_min          0.033
_refine_diff_density_max         2.140
_refine_diff_density_min         -1.803
_refine_diff_density_rms         0.178
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.063
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     322
_refine_ls_number_reflns         3589
_refine_ls_number_restraints     156
_refine_ls_restrained_S_all      1.041
_refine_ls_R_factor_all          0.0972
_refine_ls_R_factor_gt           0.0646
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1115P)²+56.6480P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1738
_refine_ls_wR_factor_ref         0.1976
_reflns_number_gt                2546
_reflns_number_total             3589
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om201265n_si_001.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Hexagonal' changed to 'hexagonal'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_database_code               4078003
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-x, -y, z+1/2'
'y, -x+y, z+1/2'
'x-y, x, z+1/2'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'x, y, -z-1/2'
'-y, x-y, -z-1/2'
'-x+y, -x, -z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.69183(4) 0.03973(3) 0.2500 0.0409(3) Uani 1 2 d S . .
N2 N 0.6341(7) -0.0957(5) 0.3143(6) 0.060(3) Uani 1 1 d . . .
P1 P 0.7393(2) 0.1490(2) 0.2500 0.0398(12) Uani 1 2 d S . .
P2 P 0.79539(19) 0.27521(18) 0.3444(3) 0.0582(11) Uani 1 1 d . . .
C1 C 0.6521(11) -0.0559(10) 0.2500 0.057(6) Uani 1 2 d S . .
C2 C 0.6084(11) -0.1583(7) 0.2892(10) 0.100(7) Uani 1 1 d . . .
H2 H 0.5934 -0.1948 0.3228 0.120 Uiso 1 1 calc R . .
C3 C 0.6464(8) -0.0747(6) 0.3970(8) 0.056(4) Uani 1 1 d . A .
C4 C 0.5996(8) -0.0695(6) 0.4374(9) 0.058(4) Uani 1 1 d . . .
C5 C 0.6123(9) -0.0508(7) 0.5168(10) 0.073(5) Uani 1 1 d . A .
H5 H 0.5817 -0.0459 0.5471 0.088 Uiso 1 1 calc R . .
C6 C 0.6678(11) -0.0393(8) 0.5523(12) 0.089(6) Uani 1 1 d . . .
H6 H 0.6752 -0.0275 0.6072 0.106 Uiso 1 1 calc R A .
C7 C 0.7126(10) -0.0448(8) 0.5093(12) 0.087(6) Uani 1 1 d . A .
H7 H 0.7513 -0.0356 0.5352 0.105 Uiso 1 1 calc R . .
C8 C 0.7044(9) -0.0632(8) 0.4288(10) 0.073(5) Uani 1 1 d . . .
C9A C 0.5355(8) -0.0837(7) 0.3998(10) 0.074(4) Uani 0.42(3) 1 d PDU A 1
H9A H 0.5330 -0.1119 0.3544 0.089 Uiso 0.42(3) 1 calc PR A 1
C10A C 0.4748(15) -0.129(2) 0.445(3) 0.088(13) Uani 0.42(3) 1 d PDU A 1
H10A H 0.4632 -0.1049 0.4813 0.132 Uiso 0.42(3) 1 calc PR A 1
H10B H 0.4822 -0.1594 0.4761 0.132 Uiso 0.42(3) 1 calc PR A 1
H10C H 0.4400 -0.1530 0.4068 0.132 Uiso 0.42(3) 1 calc PR A 1
C11A C 0.5306(17) -0.0320(14) 0.354(2) 0.064(10) Uani 0.42(3) 1 d PDU A 1
H11A H 0.5696 -0.0069 0.3224 0.096 Uiso 0.42(3) 1 calc PR A 1
H11B H 0.5253 -0.0039 0.3916 0.096 Uiso 0.42(3) 1 calc PR A 1
H11C H 0.4936 -0.0519 0.3178 0.096 Uiso 0.42(3) 1 calc PR A 1
C9B C 0.5355(8) -0.0837(7) 0.3998(10) 0.074(4) Uani 0.58(3) 1 d PDU A 2
H9B H 0.5438 -0.0729 0.3416 0.089 Uiso 0.58(3) 1 calc PR A 2
C10B C 0.4867(18) -0.1543(10) 0.405(2) 0.107(13) Uani 0.58(3) 1 d PDU A 2
H10D H 0.4877 -0.1756 0.3554 0.160 Uiso 0.58(3) 1 calc PR A 2
H10E H 0.4440 -0.1598 0.4122 0.160 Uiso 0.58(3) 1 calc PR A 2
H10F H 0.4969 -0.1732 0.4506 0.160 Uiso 0.58(3) 1 calc PR A 2
C11B C 0.5128(13) -0.0403(11) 0.4351(16) 0.068(8) Uani 0.58(3) 1 d PDU A 2
H11D H 0.4761 -0.0450 0.4043 0.102 Uiso 0.58(3) 1 calc PR A 2
H11E H 0.5475 0.0042 0.4326 0.102 Uiso 0.58(3) 1 calc PR A 2
H11F H 0.5001 -0.0523 0.4910 0.102 Uiso 0.58(3) 1 calc PR A 2
C12A C 0.7552(11) -0.0700(8) 0.3813(14) 0.111(4) Uani 0.76(3) 1 d PDU A 1
C13A C 0.7642(17) -0.1246(14) 0.407(2) 0.115(6) Uani 0.76(3) 1 d PDU A 1
H13A H 0.7815 -0.1169 0.4616 0.172 Uiso 0.76(3) 1 calc PR A 1
H13B H 0.7941 -0.1281 0.3705 0.172 Uiso 0.76(3) 1 calc PR A 1
H13C H 0.7230 -0.1644 0.4058 0.172 Uiso 0.76(3) 1 calc PR A 1
C14A C 0.8165(14) -0.0075(13) 0.381(2) 0.118(7) Uani 0.76(3) 1 d PDU A 1
H14A H 0.8129 0.0223 0.3449 0.177 Uiso 0.76(3) 1 calc PR A 1
H14B H 0.8515 -0.0141 0.3639 0.177 Uiso 0.76(3) 1 calc PR A 1
H14C H 0.8253 0.0103 0.4358 0.177 Uiso 0.76(3) 1 calc PR A 1
C12B C 0.7552(11) -0.0700(8) 0.3813(14) 0.111(4) Uani 0.24(3) 1 d PDU A 2
C13B C 0.791(4) -0.080(5) 0.449(4) 0.116(9) Uani 0.24(3) 1 d PDU A 2
H13D H 0.8362 -0.0610 0.4348 0.174 Uiso 0.24(3) 1 calc PR A 2
H13E H 0.7729 -0.1264 0.4576 0.174 Uiso 0.24(3) 1 calc PR A 2
H13F H 0.7864 -0.0607 0.4980 0.174 Uiso 0.24(3) 1 calc PR A 2
C14B C 0.810(4) -0.012(4) 0.344(7) 0.115(9) Uani 0.24(3) 1 d PDU A 2
H14D H 0.8241 0.0248 0.3790 0.173 Uiso 0.24(3) 1 calc PR A 2
H14E H 0.7968 -0.0034 0.2920 0.173 Uiso 0.24(3) 1 calc PR A 2
H14F H 0.8459 -0.0201 0.3350 0.173 Uiso 0.24(3) 1 calc PR A 2
C15 C 0.7585(6) 0.1927(6) 0.3374(8) 0.046(3) Uani 1 1 d . . .
C16 C 0.7404(7) 0.1567(6) 0.4192(8) 0.059(4) Uani 1 1 d . . .
C17 C 0.7751(9) 0.1161(8) 0.4245(11) 0.091(6) Uani 1 1 d . . .
H17A H 0.8206 0.1434 0.4117 0.136 Uiso 1 1 calc R . .
H17B H 0.7556 0.0806 0.3863 0.136 Uiso 1 1 calc R . .
H17C H 0.7708 0.0991 0.4789 0.136 Uiso 1 1 calc R . .
C18 C 0.6693(7) 0.1120(7) 0.4248(9) 0.066(5) Uani 1 1 d . . .
H18A H 0.6592 0.0881 0.4752 0.099 Uiso 1 1 calc R . .
H18B H 0.6551 0.0820 0.3797 0.099 Uiso 1 1 calc R . .
H18C H 0.6473 0.1368 0.4231 0.099 Uiso 1 1 calc R . .
C19 C 0.7617(9) 0.2013(8) 0.4906(8) 0.102(7) Uani 1 1 d . . .
H19A H 0.7446 0.2305 0.4858 0.152 Uiso 1 1 calc R . .
H19B H 0.8085 0.2262 0.4922 0.152 Uiso 1 1 calc R . .
H19C H 0.7457 0.1763 0.5399 0.152 Uiso 1 1 calc R . .
C20 C 0.8096(9) 0.3089(9) 0.2500 0.048(5) Uani 1 2 d S . .
C21 C 0.8396(11) 0.3831(11) 0.2500 0.070(7) Uani 1 2 d S . .
C22 C 0.7875(9) 0.3979(11) 0.2500 0.110(12) Uani 1 2 d S . .
H22A H 0.7955 0.4298 0.2914 0.165 Uiso 0.50 1 calc PR . .
H22B H 0.7469 0.3588 0.2612 0.165 Uiso 0.50 1 calc PR . .
H22C H 0.7852 0.4147 0.1975 0.165 Uiso 0.50 1 calc PR . .
C23 C 0.8827(9) 0.4136(8) 0.3227(12) 0.107(8) Uani 1 1 d . . .
H23A H 0.9032 0.4603 0.3189 0.160 Uiso 1 1 calc R . .
H23B H 0.9157 0.4013 0.3241 0.160 Uiso 1 1 calc R . .
H23C H 0.8571 0.3990 0.3717 0.160 Uiso 1 1 calc R . .
Cl1 Cl 0.9004(6) 0.1716(10) 0.2500 0.310(11) Uani 1 2 d S . .
Cl2 Cl 0.9852(9) 0.1351(9) 0.2500 0.359(16) Uani 1 2 d S . .
Sb1 Sb 0.07810(10) 0.41355(13) 0.2500 0.1042(8) Uani 1 2 d S . .
F3 F 0.0552(9) 0.4452(13) 0.3297(17) 0.37(2) Uani 1 1 d . . .
F4 F -0.0100(7) 0.3489(10) 0.2500 0.139(7) Uani 1 2 d S . .
F6 F 0.1608(9) 0.4658(9) 0.2500 0.30(2) Uani 1 2 d S . .
F8 F 0.0896(7) 0.3578(9) 0.3227(10) 0.172(7) Uani 1 1 d . . .
C24 C 0.9768(15) 0.2042(14) 0.2500 0.110(10) Uani 1 2 d S . .
H24A H 0.9960 0.2306 0.2984 0.132 Uiso 0.50 1 calc PR . .
H24B H 0.9960 0.2306 0.2016 0.132 Uiso 0.50 1 calc PR . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Au1 P1 178.7(6) . .
C1 N2 C2 110.2(13) . .
C1 N2 C3 124.5(12) . .
C2 N2 C3 125.0(11) . .
C15 P1 C15 115.7(9) . 10_556
C15 P1 Au1 122.2(5) . .
C15 P1 Au1 122.2(5) 10_556 .
C20 P2 C15 110.3(7) . .
N2 C1 N2 104.2(17) 10_556 .
N2 C1 Au1 127.8(8) 10_556 .
N2 C1 Au1 127.8(8) . .
C2 C2 N2 107.6(8) 10_556 .
C2 C2 H2 126.2 10_556 .
N2 C2 H2 126.2 . .
C4 C3 C8 126.0(14) . .
C4 C3 N2 117.8(15) . .
C8 C3 N2 116.3(15) . .
C3 C4 C5 116.1(15) . .
C3 C4 C9A 124.1(14) . .
C5 C4 C9A 119.8(16) . .
C6 C5 C4 121.2(18) . .
C6 C5 H5 119.4 . .
C4 C5 H5 119.4 . .
C7 C6 C5 120.2(18) . .
C7 C6 H6 119.9 . .
C5 C6 H6 119.9 . .
C6 C7 C8 123.1(19) . .
C6 C7 H7 118.5 . .
C8 C7 H7 118.5 . .
C3 C8 C7 113.5(18) . .
C3 C8 C12A 124.1(17) . .
C7 C8 C12A 122.5(19) . .
C11A C9A C10A 114(2) . .
C11A C9A C4 120.4(17) . .
C10A C9A C4 117(2) . .
C11A C9A H9A 100.0 . .
C10A C9A H9A 100.0 . .
C4 C9A H9A 100.0 . .
C9A C10A H10A 109.5 . .
C9A C10A H10B 109.5 . .
H10A C10A H10B 109.5 . .
C9A C10A H10C 109.5 . .
H10A C10A H10C 109.5 . .
H10B C10A H10C 109.5 . .
C9A C11A H11A 109.5 . .
C9A C11A H11B 109.5 . .
H11A C11A H11B 109.5 . .
C9A C11A H11C 109.5 . .
H11A C11A H11C 109.5 . .
H11B C11A H11C 109.5 . .
H10D C10B H10E 109.5 . .
H10D C10B H10F 109.5 . .
H10E C10B H10F 109.5 . .
H11D C11B H11E 109.5 . .
H11D C11B H11F 109.5 . .
H11E C11B H11F 109.5 . .
C14A C12A C13A 112(3) . .
C14A C12A C8 109(2) . .
C13A C12A C8 114.8(17) . .
C12A C13A H13A 109.5 . .
C12A C13A H13B 109.5 . .
H13A C13A H13B 109.5 . .
C12A C13A H13C 109.5 . .
H13A C13A H13C 109.5 . .
H13B C13A H13C 109.5 . .
C12A C14A H14A 109.5 . .
C12A C14A H14B 109.5 . .
H14A C14A H14B 109.5 . .
C12A C14A H14C 109.5 . .
H14A C14A H14C 109.5 . .
H14B C14A H14C 109.5 . .
H13D C13B H13E 109.5 . .
H13D C13B H13F 109.5 . .
H13E C13B H13F 109.5 . .
H14D C14B H14E 109.5 . .
H14D C14B H14F 109.5 . .
H14E C14B H14F 109.5 . .
C16 C15 P1 118.9(9) . .
C16 C15 P2 115.0(9) . .
P1 C15 P2 126.0(8) . .
C18 C16 C19 108.7(14) . .
C18 C16 C15 110.8(11) . .
C19 C16 C15 113.0(11) . .
C18 C16 C17 108.7(12) . .
C19 C16 C17 107.6(14) . .
C15 C16 C17 108.0(13) . .
C16 C17 H17A 109.5 . .
C16 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C16 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C16 C18 H18A 109.5 . .
C16 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C16 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C16 C19 H19A 109.5 . .
C16 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
C16 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
C21 C20 P2 114.2(6) . .
C21 C20 P2 114.1(6) . 10_556
P2 C20 P2 131.7(11) . 10_556
C22 C21 C23 110.1(14) . .
C22 C21 C23 110.1(14) . 10_556
C23 C21 C23 105(2) . 10_556
C22 C21 C20 108.4(18) . .
C23 C21 C20 111.5(12) . .
C23 C21 C20 111.5(12) 10_556 .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C21 C23 H23A 109.5 . .
C21 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C21 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
F6 Sb1 F3 100.4(8) . .
F6 Sb1 F3 100.4(8) . 10_556
F3 Sb1 F3 98.5(19) . 10_556
F6 Sb1 F4 173.5(9) . .
F3 Sb1 F4 83.8(8) . .
F3 Sb1 F4 83.8(8) 10_556 .
F6 Sb1 F8 89.6(6) . .
F3 Sb1 F8 90.8(12) . .
F3 Sb1 F8 164.9(12) 10_556 .
F4 Sb1 F8 85.4(7) . .
F6 Sb1 F8 89.6(6) . 10_556
F3 Sb1 F8 164.9(12) . 10_556
F3 Sb1 F8 90.8(12) 10_556 10_556
F4 Sb1 F8 85.4(7) . 10_556
F8 Sb1 F8 77.8(10) . 10_556
Cl1 C24 Cl2 100.5(19) . .
Cl1 C24 H24A 111.7 . .
Cl2 C24 H24A 111.7 . .
Cl1 C24 H24B 111.7 . .
Cl2 C24 H24B 111.7 . .
H24A C24 H24B 109.4 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 C1 2.01(2) .
Au1 P1 2.291(5) .
N2 C1 1.359(16) .
N2 C2 1.381(18) .
N2 C3 1.449(17) .
P1 C15 1.724(13) .
P1 C15 1.724(13) 10_556
P2 C20 1.728(9) .
P2 C15 1.732(13) .
C1 N2 1.359(16) 10_556
C2 C2 1.31(3) 10_556
C2 H2 0.9500 .
C3 C4 1.38(2) .
C3 C8 1.39(2) .
C4 C5 1.39(2) .
C4 C9A 1.54(2) .
C5 C6 1.36(2) .
C5 H5 0.9500 .
C6 C7 1.36(3) .
C6 H6 0.9500 .
C7 C8 1.40(2) .
C7 H7 0.9500 .
C8 C12A 1.54(3) .
C9A C11A 1.519(18) .
C9A C10A 1.523(18) .
C9A H9A 1.0000 .
C10A H10A 0.9800 .
C10A H10B 0.9800 .
C10A H10C 0.9800 .
C11A H11A 0.9800 .
C11A H11B 0.9800 .
C11A H11C 0.9800 .
C10B H10D 0.9800 .
C10B H10E 0.9800 .
C10B H10F 0.9800 .
C11B H11D 0.9800 .
C11B H11E 0.9800 .
C11B H11F 0.9800 .
C12A C14A 1.50(2) .
C12A C13A 1.50(2) .
C13A H13A 0.9800 .
C13A H13B 0.9800 .
C13A H13C 0.9800 .
C14A H14A 0.9800 .
C14A H14B 0.9800 .
C14A H14C 0.9800 .
C13B H13D 0.9800 .
C13B H13E 0.9800 .
C13B H13F 0.9800 .
C14B H14D 0.9800 .
C14B H14E 0.9800 .
C14B H14F 0.9800 .
C15 C16 1.559(19) .
C16 C18 1.51(2) .
C16 C19 1.52(2) .
C16 C17 1.58(2) .
C17 H17A 0.9800 .
C17 H17B 0.9800 .
C17 H17C 0.9800 .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9800 .
C20 C21 1.56(3) .
C20 P2 1.728(9) 10_556
C21 C22 1.47(3) .
C21 C23 1.53(2) .
C21 C23 1.53(2) 10_556
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
Cl1 C24 1.60(3) .
Cl2 C24 1.78(3) .
Sb1 F6 1.749(19) .
Sb1 F3 1.755(17) .
Sb1 F3 1.755(17) 10_556
Sb1 F4 1.908(16) .
Sb1 F8 1.934(15) .
Sb1 F8 1.934(15) 10_556
C24 H24A 0.9900 .
C24 H24B 0.9900 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C1 Au1 P1 C15 -89.8(6) . .
C1 Au1 P1 C15 89.8(6) . 10_556
C2 N2 C1 N2 3(2) . 10_556
C3 N2 C1 N2 176.8(11) . 10_556
C2 N2 C1 Au1 179.6(16) . .
C3 N2 C1 Au1 -6(3) . .
P1 Au1 C1 N2 -91.9(18) . 10_556
P1 Au1 C1 N2 91.9(18) . .
C1 N2 C2 C2 -1.7(16) . 10_556
C3 N2 C2 C2 -175.8(13) . 10_556
C1 N2 C3 C4 93(2) . .
C2 N2 C3 C4 -93(2) . .
C1 N2 C3 C8 -88(2) . .
C2 N2 C3 C8 85(2) . .
C8 C3 C4 C5 0(2) . .
N2 C3 C4 C5 178.5(12) . .
C8 C3 C4 C9A -179.1(13) . .
N2 C3 C4 C9A -1(2) . .
C3 C4 C5 C6 -1(2) . .
C9A C4 C5 C6 178.5(14) . .
C4 C5 C6 C7 1(3) . .
C5 C6 C7 C8 -1(3) . .
C4 C3 C8 C7 0(2) . .
N2 C3 C8 C7 -178.4(13) . .
C4 C3 C8 C12A 179.7(14) . .
N2 C3 C8 C12A 1(2) . .
C6 C7 C8 C3 1(2) . .
C6 C7 C8 C12A -179.2(16) . .
C3 C4 C9A C11A -86(2) . .
C5 C4 C9A C11A 95(2) . .
C3 C4 C9A C10A 129(3) . .
C5 C4 C9A C10A -51(3) . .
C3 C8 C12A C14A 121(2) . .
C7 C8 C12A C14A -59(3) . .
C3 C8 C12A C13A -111(3) . .
C7 C8 C12A C13A 69(3) . .
C15 P1 C15 C16 177.7(7) 10_556 .
Au1 P1 C15 C16 -2.6(13) . .
C15 P1 C15 P2 -0.7(16) 10_556 .
Au1 P1 C15 P2 179.0(6) . .
C20 P2 C15 C16 -177.4(11) . .
C20 P2 C15 P1 1.1(13) . .
P1 C15 C16 C18 -59.2(16) . .
P2 C15 C16 C18 119.4(12) . .
P1 C15 C16 C19 178.6(13) . .
P2 C15 C16 C19 -2.8(18) . .
P1 C15 C16 C17 59.8(14) . .
P2 C15 C16 C17 -121.6(11) . .
C15 P2 C20 C21 177.0(14) . .
C15 P2 C20 P2 -1.8(18) . 10_556
P2 C20 C21 C22 -89.5(11) . .
P2 C20 C21 C22 89.5(11) 10_556 .
P2 C20 C21 C23 32(2) . .
P2 C20 C21 C23 -149.2(14) 10_556 .
P2 C20 C21 C23 149.2(14) . 10_556
P2 C20 C21 C23 -32(2) 10_556 10_556
