#------------------------------------------------------------------------------
#$Date: 2016-03-21 10:56:22 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178674 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/85/4078542.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4078542
loop_
_publ_author_name
'Sanden, Tanja'
'Gamer, Michael T.'
'Fagin, Anatoly A.'
'Chudakova, Valentina A.'
'Konchenko, Sergey N.'
'Fedushkin, Igor L.'
'Roesky, Peter W.'
_publ_section_title
;
 Synthesis of Unsupported Ln--Ga Bonds by Salt Metathesis and Ga--Ga Bond
 Reduction
;
_journal_issue                   11
_journal_name_full               Organometallics
_journal_page_first              4331
_journal_paper_doi               10.1021/om300309b
_journal_volume                  31
_journal_year                    2012
_chemical_formula_moiety
'0.5(C176 H224 Eu2 Ga4 N8 O8), 2(C4 H8 O), 0.5(C14 H16)'
_chemical_formula_sum            'C103 H136 Eu Ga2 N4 O6'
_chemical_formula_weight         1817.56
_chemical_name_systematic
;
 ? 
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2012-02-17
_audit_creation_method
;
  Olex2 1.1
  (compiled 2011.11.01 svn.r2039, GUI svn.r3906)
;
_cell_angle_alpha                90.00
_cell_angle_beta                 99.49(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   12.611(3)
_cell_length_b                   15.433(3)
_cell_length_c                   24.211(5)
_cell_measurement_reflns_used    28483
_cell_measurement_temperature    150
_cell_measurement_theta_max      27.24
_cell_measurement_theta_min      1.32
_cell_volume                     4647.6(18)
_computing_molecular_graphics
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement
;
SHELXL, G.M. Sheldrick, Acta Cryst.
2008). A64, 112-122
;
_computing_structure_solution
;
SHELXS, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_diffrn_ambient_temperature      150
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'STOE IPDS 2'
_diffrn_measurement_method       'area detector'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0512
_diffrn_reflns_av_unetI/netI     0.0470
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            35152
_diffrn_reflns_theta_full        26.74
_diffrn_reflns_theta_max         26.74
_diffrn_reflns_theta_min         1.57
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    1.297
_exptl_absorpt_correction_T_max  0.8841
_exptl_absorpt_correction_T_min  0.6967
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   'STOE X-RED & X-SHAPE'
_exptl_crystal_colour            'dark red'
_exptl_crystal_density_diffrn    1.299
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1910
_exptl_crystal_size_max          0.363
_exptl_crystal_size_mid          0.232
_exptl_crystal_size_min          0.106
_refine_diff_density_max         0.822
_refine_diff_density_min         -0.707
_refine_diff_density_rms         0.066
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.005
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     518
_refine_ls_number_reflns         9858
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.005
_refine_ls_R_factor_all          0.0541
_refine_ls_R_factor_gt           0.0359
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0411P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0744
_refine_ls_wR_factor_ref         0.0786
_reflns_number_gt                7744
_reflns_number_total             9858
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om300309b_si_002.cif
_cod_data_source_block           2
_cod_original_cell_volume        4647.3(16)
_cod_database_code               4078542
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x+1/2, y+1/2, -z+1/2'
3 '-x, -y, -z'
4 'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu Eu 0.5000 0.5000 1.0000 0.02416(6) Uani 1 2 d S . .
Ga Ga 0.48822(2) 0.37669(2) 0.886587(11) 0.02662(8) Uani 1 1 d . . .
O1 O 0.40196(17) 0.62442(13) 0.94718(8) 0.0337(5) Uani 1 1 d . . .
C2 C 0.45393(19) 0.32083(16) 0.77637(10) 0.0211(5) Uani 1 1 d . . .
C1 C 0.51527(19) 0.25591(17) 0.80507(10) 0.0207(5) Uani 1 1 d . . .
C14 C 0.5505(2) 0.12813(18) 0.91145(11) 0.0280(6) Uani 1 1 d . . .
C25 C 0.3667(2) 0.46088(17) 0.78185(10) 0.0223(5) Uani 1 1 d . . .
C10 C 0.5944(2) 0.11291(17) 0.76818(11) 0.0255(5) Uani 1 1 d . . .
H10 H 0.6309 0.0914 0.8030 0.031 Uiso 1 1 calc R . .
C4 C 0.3823(2) 0.33754(19) 0.66794(11) 0.0280(6) Uani 1 1 d . . .
H4 H 0.3460 0.3914 0.6688 0.034 Uiso 1 1 calc R . .
C12 C 0.4861(2) 0.21854(17) 0.71221(10) 0.0218(5) Uani 1 1 d . . .
C13 C 0.6048(2) 0.20172(17) 0.89538(10) 0.0235(5) Uani 1 1 d . . .
C11 C 0.5379(2) 0.18937(17) 0.76571(10) 0.0218(5) Uani 1 1 d . . .
C29 C 0.3633(3) 0.60415(19) 0.74260(12) 0.0330(6) Uani 1 1 d . . .
H29 H 0.3988 0.6512 0.7281 0.040 Uiso 1 1 calc R . .
C31 C 0.1957(2) 0.38851(19) 0.80122(13) 0.0339(6) Uani 1 1 d . . .
H31 H 0.2436 0.3366 0.8028 0.041 Uiso 1 1 calc R . .
C26 C 0.2562(2) 0.46497(18) 0.78167(11) 0.0257(5) Uani 1 1 d . . .
C7 C 0.4886(2) 0.17510(18) 0.66237(11) 0.0275(6) Uani 1 1 d . . .
C8 C 0.5465(2) 0.09514(19) 0.66656(12) 0.0315(6) Uani 1 1 d . . .
H8 H 0.5497 0.0618 0.6339 0.038 Uiso 1 1 calc R . .
C27 C 0.2014(2) 0.54110(19) 0.76372(12) 0.0305(6) Uani 1 1 d . . .
H27 H 0.1264 0.5452 0.7644 0.037 Uiso 1 1 calc R . .
C6 C 0.4348(2) 0.2160(2) 0.61275(11) 0.0336(6) Uani 1 1 d . . .
H6 H 0.4337 0.1890 0.5774 0.040 Uiso 1 1 calc R . .
C5 C 0.3847(2) 0.2939(2) 0.61604(11) 0.0329(6) Uani 1 1 d . . .
H5 H 0.3499 0.3203 0.5824 0.039 Uiso 1 1 calc R . .
C3 C 0.4338(2) 0.29972(17) 0.71659(10) 0.0220(5) Uani 1 1 d . . .
C19 C 0.4310(2) 0.11656(19) 0.89250(12) 0.0331(6) Uani 1 1 d . . .
H19 H 0.4119 0.1464 0.8555 0.040 Uiso 1 1 calc R . .
C18 C 0.7160(2) 0.21312(19) 0.91404(11) 0.0283(6) Uani 1 1 d . . .
C30 C 0.4215(2) 0.53001(18) 0.76116(11) 0.0273(6) Uani 1 1 d . . .
C34 C 0.5423(3) 0.5250(2) 0.76194(14) 0.0394(7) Uani 1 1 d . . .
H34 H 0.5623 0.4623 0.7618 0.047 Uiso 1 1 calc R . .
C28 C 0.2546(3) 0.61031(19) 0.74497(12) 0.0342(7) Uani 1 1 d . . .
H28 H 0.2167 0.6623 0.7337 0.041 Uiso 1 1 calc R . .
O3 O 0.8173(3) 0.27511(18) 0.63485(13) 0.0720(9) Uani 1 1 d . . .
C22 C 0.7745(2) 0.2919(2) 0.89697(12) 0.0320(6) Uani 1 1 d . . .
H22 H 0.7259 0.3428 0.8983 0.038 Uiso 1 1 calc R . .
C17 C 0.7710(2) 0.1498(2) 0.94905(12) 0.0364(7) Uani 1 1 d . . .
H17 H 0.8460 0.1562 0.9618 0.044 Uiso 1 1 calc R . .
C20 C 0.3960(3) 0.0221(2) 0.88402(15) 0.0465(8) Uani 1 1 d . . .
H20A H 0.4404 -0.0067 0.8599 0.070 Uiso 1 1 calc R . .
H20B H 0.3204 0.0197 0.8664 0.070 Uiso 1 1 calc R . .
H20C H 0.4049 -0.0073 0.9204 0.070 Uiso 1 1 calc R . .
C9 C 0.5972(2) 0.06663(19) 0.71777(12) 0.0302(6) Uani 1 1 d . . .
H9 H 0.6360 0.0136 0.7196 0.036 Uiso 1 1 calc R . .
C16 C 0.7181(3) 0.0782(2) 0.96544(13) 0.0417(8) Uani 1 1 d . . .
H16 H 0.7565 0.0361 0.9895 0.050 Uiso 1 1 calc R . .
C23 C 0.8796(3) 0.3123(3) 0.93553(15) 0.0484(8) Uani 1 1 d . . .
H23A H 0.8667 0.3159 0.9743 0.073 Uiso 1 1 calc R . .
H23B H 0.9078 0.3678 0.9246 0.073 Uiso 1 1 calc R . .
H23C H 0.9320 0.2664 0.9325 0.073 Uiso 1 1 calc R . .
C36 C 0.6036(3) 0.5653(3) 0.81599(18) 0.0596(10) Uani 1 1 d . . .
H36A H 0.5861 0.6271 0.8171 0.089 Uiso 1 1 calc R . .
H36B H 0.6811 0.5585 0.8168 0.089 Uiso 1 1 calc R . .
H36C H 0.5828 0.5361 0.8485 0.089 Uiso 1 1 calc R . .
C21 C 0.3677(3) 0.1606(3) 0.93314(18) 0.0606(11) Uani 1 1 d . . .
H21A H 0.3851 0.1332 0.9700 0.091 Uiso 1 1 calc R . .
H21B H 0.2905 0.1547 0.9193 0.091 Uiso 1 1 calc R . .
H21C H 0.3868 0.2222 0.9362 0.091 Uiso 1 1 calc R . .
C32 C 0.1714(3) 0.4043(3) 0.86037(14) 0.0497(9) Uani 1 1 d . . .
H32A H 0.2387 0.4151 0.8860 0.075 Uiso 1 1 calc R . .
H32B H 0.1359 0.3532 0.8729 0.075 Uiso 1 1 calc R . .
H32C H 0.1240 0.4547 0.8600 0.075 Uiso 1 1 calc R . .
C46 C 0.7692(4) 0.4177(2) 0.65174(18) 0.0583(10) Uani 1 1 d . . .
H46A H 0.7223 0.4582 0.6271 0.070 Uiso 1 1 calc R . .
H46B H 0.8186 0.4517 0.6796 0.070 Uiso 1 1 calc R . .
C33 C 0.0922(3) 0.3678(2) 0.76097(16) 0.0463(8) Uani 1 1 d . . .
H33A H 0.0407 0.4152 0.7615 0.069 Uiso 1 1 calc R . .
H33B H 0.0612 0.3139 0.7726 0.069 Uiso 1 1 calc R . .
H33C H 0.1083 0.3610 0.7230 0.069 Uiso 1 1 calc R . .
C35 C 0.5775(4) 0.5670(3) 0.71116(19) 0.0689(12) Uani 1 1 d . . .
H35A H 0.5341 0.5441 0.6769 0.103 Uiso 1 1 calc R . .
H35B H 0.6535 0.5540 0.7110 0.103 Uiso 1 1 calc R . .
H35C H 0.5676 0.6299 0.7128 0.103 Uiso 1 1 calc R . .
C24 C 0.7956(3) 0.2844(3) 0.83691(14) 0.0510(9) Uani 1 1 d . . .
H24A H 0.8453 0.2363 0.8343 0.076 Uiso 1 1 calc R . .
H24B H 0.8274 0.3385 0.8261 0.076 Uiso 1 1 calc R . .
H24C H 0.7277 0.2735 0.8118 0.076 Uiso 1 1 calc R . .
C45 C 0.8304(4) 0.3607(3) 0.61843(18) 0.0591(10) Uani 1 1 d . . .
H45A H 0.8028 0.3676 0.5780 0.071 Uiso 1 1 calc R . .
H45B H 0.9075 0.3766 0.6254 0.071 Uiso 1 1 calc R . .
C47 C 0.7036(4) 0.3561(3) 0.68001(18) 0.0595(10) Uani 1 1 d . . .
H47A H 0.6955 0.3771 0.7177 0.071 Uiso 1 1 calc R . .
H47B H 0.6315 0.3473 0.6575 0.071 Uiso 1 1 calc R . .
C48 C 0.7681(3) 0.2752(2) 0.68352(16) 0.0519(9) Uani 1 1 d . . .
H48A H 0.8232 0.2750 0.7178 0.062 Uiso 1 1 calc R . .
H48B H 0.7214 0.2238 0.6841 0.062 Uiso 1 1 calc R . .
C15 C 0.6096(3) 0.0678(2) 0.94680(12) 0.0366(7) Uani 1 1 d . . .
H15 H 0.5741 0.0184 0.9583 0.044 Uiso 1 1 calc R . .
N1 N 0.54596(17) 0.26727(14) 0.86217(8) 0.0229(4) Uani 1 1 d . . .
N2 N 0.42676(17) 0.38908(14) 0.80727(8) 0.0229(4) Uani 1 1 d . . .
C37 C 0.3585(3) 0.6295(2) 0.88826(12) 0.0421(8) Uani 1 1 d . . .
H37A H 0.2797 0.6210 0.8819 0.050 Uiso 1 1 calc R . .
H37B H 0.3913 0.5849 0.8670 0.050 Uiso 1 1 calc R . .
C38 C 0.3867(3) 0.7200(2) 0.87040(13) 0.0425(8) Uani 1 1 d . . .
H38A H 0.3267 0.7451 0.8437 0.051 Uiso 1 1 calc R . .
H38B H 0.4520 0.7188 0.8526 0.051 Uiso 1 1 calc R . .
C40 C 0.3807(3) 0.7090(2) 0.96834(12) 0.0418(8) Uani 1 1 d . . .
H40A H 0.4267 0.7198 1.0049 0.050 Uiso 1 1 calc R . .
H40B H 0.3044 0.7142 0.9730 0.050 Uiso 1 1 calc R . .
C39 C 0.4064(3) 0.7719(2) 0.92502(14) 0.0429(8) Uani 1 1 d . . .
H39A H 0.4821 0.7914 0.9338 0.052 Uiso 1 1 calc R . .
H39B H 0.3587 0.8232 0.9226 0.052 Uiso 1 1 calc R . .
O2 O 0.67778(18) 0.55926(15) 0.98473(10) 0.0449(6) Uani 1 1 d . . .
C41 C 0.7050(3) 0.6472(2) 0.97412(19) 0.0565(10) Uani 1 1 d . . .
H41A H 0.6950 0.6848 1.0060 0.068 Uiso 1 1 calc R . .
H41B H 0.6590 0.6691 0.9399 0.068 Uiso 1 1 calc R . .
C44 C 0.7694(3) 0.5065(3) 0.9810(3) 0.0835(16) Uani 1 1 d . . .
H44A H 0.7587 0.4743 0.9451 0.100 Uiso 1 1 calc R . .
H44B H 0.7809 0.4641 1.0121 0.100 Uiso 1 1 calc R . .
C42 C 0.8195(4) 0.6465(4) 0.9668(3) 0.0876(16) Uani 1 1 d . . .
H42A H 0.8255 0.6567 0.9271 0.105 Uiso 1 1 calc R . .
H42B H 0.8598 0.6926 0.9898 0.105 Uiso 1 1 calc R . .
C43 C 0.8612(4) 0.5637(4) 0.9843(2) 0.0855(16) Uani 1 1 d . . .
H43A H 0.9008 0.5663 1.0231 0.103 Uiso 1 1 calc R . .
H43B H 0.9109 0.5430 0.9594 0.103 Uiso 1 1 calc R . .
C49 C 0.4285(11) 0.6001(8) 0.5070(5) 0.100(4) Uiso 0.50 1 d PD A -1
H49A H 0.3560 0.5997 0.4849 0.150 Uiso 0.50 1 calc PR A -1
H49B H 0.4674 0.6513 0.4973 0.150 Uiso 0.50 1 calc PR A -1
H49C H 0.4235 0.6017 0.5470 0.150 Uiso 0.50 1 calc PR A -1
C55 C 0.5092(4) 0.4576(3) 0.53591(15) 0.0423(15) Uiso 0.50 1 d PGD A -1
H55 H 0.4871 0.4654 0.5712 0.051 Uiso 0.50 1 calc PR A -1
C50 C 0.4866(5) 0.5208(3) 0.4948(2) 0.074(3) Uiso 0.50 1 d PG A -1
C51 C 0.5190(5) 0.5094(3) 0.44307(17) 0.063(2) Uiso 0.50 1 d PGD A -1
H51 H 0.5035 0.5526 0.4149 0.076 Uiso 0.50 1 calc PR A -1
C52 C 0.5739(5) 0.4347(4) 0.43253(17) 0.062(2) Uiso 0.50 1 d PG A -1
H52 H 0.5961 0.4269 0.3972 0.075 Uiso 0.50 1 calc PR A -1
C53 C 0.5966(5) 0.3715(3) 0.4737(2) 0.063(2) Uiso 0.50 1 d PG A -1
H53 H 0.6342 0.3204 0.4665 0.076 Uiso 0.50 1 calc PR A -1
C54 C 0.5642(4) 0.3829(3) 0.52537(19) 0.0523(18) Uiso 0.50 1 d PG A -1
H54 H 0.5797 0.3397 0.5535 0.063 Uiso 0.50 1 calc PR A -1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ga Eu Ga 180.0 3_667 .
O1 Eu Ga 93.77(5) . .
O1 Eu Ga 86.23(5) 3_667 .
O1 Eu Ga 86.23(5) . 3_667
O1 Eu Ga 93.77(5) 3_667 3_667
O1 Eu O1 179.998(1) . 3_667
O2 Eu Ga 90.36(6) 3_667 3_667
O2 Eu Ga 89.64(6) . 3_667
O2 Eu Ga 90.36(6) . .
O2 Eu Ga 89.64(6) 3_667 .
O2 Eu O1 88.67(8) . 3_667
O2 Eu O1 91.33(8) 3_667 3_667
O2 Eu O1 91.33(8) . .
O2 Eu O1 88.67(8) 3_667 .
O2 Eu O2 180.0 . 3_667
N1 Ga Eu 140.44(6) . .
N2 Ga Eu 135.30(6) . .
N2 Ga N1 84.00(9) . .
C37 O1 Eu 128.18(17) . .
C37 O1 C40 103.8(2) . .
C40 O1 Eu 127.92(16) . .
C1 C2 C3 109.1(2) . .
N2 C2 C1 117.0(2) . .
N2 C2 C3 133.9(2) . .
C2 C1 C11 109.6(2) . .
C2 C1 N1 116.9(2) . .
N1 C1 C11 133.5(2) . .
C13 C14 C19 121.0(2) . .
C15 C14 C13 118.1(3) . .
C15 C14 C19 120.8(3) . .
C26 C25 C30 120.9(2) . .
C26 C25 N2 119.8(2) . .
C30 C25 N2 119.1(2) . .
C11 C10 C9 118.7(2) . .
C3 C4 C5 118.5(3) . .
C11 C12 C3 111.0(2) . .
C7 C12 C11 124.5(2) . .
C7 C12 C3 124.5(2) . .
C14 C13 N1 119.8(2) . .
C18 C13 C14 120.8(2) . .
C18 C13 N1 119.3(2) . .
C10 C11 C1 137.0(2) . .
C10 C11 C12 117.9(2) . .
C12 C11 C1 105.1(2) . .
C28 C29 C30 121.0(3) . .
C26 C31 C32 110.8(3) . .
C26 C31 C33 112.5(3) . .
C33 C31 C32 110.3(3) . .
C25 C26 C31 121.0(2) . .
C25 C26 C27 118.8(3) . .
C27 C26 C31 120.1(2) . .
C12 C7 C8 116.2(2) . .
C12 C7 C6 116.3(3) . .
C6 C7 C8 127.5(2) . .
C9 C8 C7 119.9(2) . .
C28 C27 C26 120.8(3) . .
C5 C6 C7 120.0(3) . .
C6 C5 C4 122.8(3) . .
C4 C3 C2 137.0(3) . .
C4 C3 C12 117.8(2) . .
C12 C3 C2 105.2(2) . .
C14 C19 C20 113.9(3) . .
C14 C19 C21 110.7(3) . .
C21 C19 C20 110.0(3) . .
C13 C18 C22 121.0(2) . .
C17 C18 C13 118.3(3) . .
C17 C18 C22 120.7(3) . .
C25 C30 C34 120.4(2) . .
C29 C30 C25 118.3(3) . .
C29 C30 C34 121.2(3) . .
C30 C34 C36 110.6(3) . .
C35 C34 C30 113.2(3) . .
C35 C34 C36 110.1(3) . .
C27 C28 C29 120.0(3) . .
C45 O3 C48 108.8(3) . .
C18 C22 C23 114.4(3) . .
C18 C22 C24 111.6(2) . .
C23 C22 C24 109.2(3) . .
C16 C17 C18 121.2(3) . .
C8 C9 C10 122.8(3) . .
C15 C16 C17 119.9(3) . .
C45 C46 C47 104.2(3) . .
O3 C45 C46 108.0(3) . .
C48 C47 C46 102.8(3) . .
O3 C48 C47 105.3(3) . .
C16 C15 C14 121.7(3) . .
C1 N1 Ga 110.63(16) . .
C1 N1 C13 120.6(2) . .
C13 N1 Ga 128.66(16) . .
C2 N2 Ga 111.51(16) . .
C2 N2 C25 121.8(2) . .
C25 N2 Ga 126.61(16) . .
O1 C37 C38 105.2(3) . .
C37 C38 C39 104.3(2) . .
O1 C40 C39 105.2(2) . .
C40 C39 C38 104.0(3) . .
C41 O2 Eu 128.2(2) . .
C44 O2 Eu 123.7(2) . .
C44 O2 C41 107.9(3) . .
O2 C41 C42 106.4(3) . .
O2 C44 C43 107.3(4) . .
C43 C42 C41 106.9(4) . .
C42 C43 C44 106.2(4) . .
C50 C55 C54 120.0 . .
C55 C50 C49 119.1(5) . .
C55 C50 C51 120.0 . .
C51 C50 C49 120.9(5) . .
C52 C51 C50 120.0 . .
C53 C52 C51 120.0 . .
C54 C53 C52 120.0 . .
C53 C54 C55 120.0 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu Ga 3.3239(6) .
Eu Ga 3.3239(6) 3_667
Eu O1 2.516(2) .
Eu O1 2.516(2) 3_667
Eu O2 2.505(2) 3_667
Eu O2 2.505(2) .
Ga N1 1.968(2) .
Ga N2 1.958(2) .
O1 C37 1.443(3) .
O1 C40 1.444(4) .
C2 C1 1.381(3) .
C2 C3 1.464(3) .
C2 N2 1.368(3) .
C1 C11 1.461(3) .
C1 N1 1.384(3) .
C14 C13 1.413(4) .
C14 C19 1.512(4) .
C14 C15 1.394(4) .
C25 C26 1.395(4) .
C25 C30 1.407(4) .
C25 N2 1.423(3) .
C10 C11 1.374(4) .
C10 C9 1.420(4) .
C4 C5 1.430(4) .
C4 C3 1.377(4) .
C12 C11 1.424(3) .
C12 C7 1.386(3) .
C12 C3 1.428(4) .
C13 C18 1.412(4) .
C13 N1 1.422(3) .
C29 C30 1.393(4) .
C29 C28 1.385(4) .
C31 C26 1.522(4) .
C31 C32 1.533(5) .
C31 C33 1.528(4) .
C26 C27 1.396(4) .
C7 C8 1.428(4) .
C7 C6 1.426(4) .
C8 C9 1.371(4) .
C27 C28 1.378(4) .
C6 C5 1.368(4) .
C19 C20 1.527(4) .
C19 C21 1.525(5) .
C18 C22 1.515(4) .
C18 C17 1.400(4) .
C30 C34 1.522(4) .
C34 C36 1.537(5) .
C34 C35 1.519(5) .
O3 C45 1.397(5) .
O3 C48 1.420(4) .
C22 C23 1.523(4) .
C22 C24 1.525(4) .
C17 C16 1.383(5) .
C16 C15 1.378(5) .
C46 C45 1.492(5) .
C46 C47 1.498(5) .
C47 C48 1.484(5) .
C37 C38 1.521(5) .
C38 C39 1.531(5) .
C40 C39 1.503(5) .
O2 C41 1.433(4) .
O2 C44 1.429(4) .
C41 C42 1.483(6) .
C44 C43 1.448(7) .
C42 C43 1.420(7) .
C49 C50 1.481(13) .
C55 C50 1.3900 .
C55 C54 1.3900 .
C50 C51 1.3900 .
C51 C52 1.3900 .
C52 C53 1.3900 .
C53 C54 1.3900 .
