#------------------------------------------------------------------------------
#$Date: 2016-03-21 11:11:41 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178683 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/94/4079400.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4079400
loop_
_publ_author_name
'Arii, Hidekazu'
'Hashimoto, Rei'
'Mochida, Kunio'
'Kawashima, Takayuki'
_publ_section_title
;
 Syntheses of Di- and Trinuclear Platinum Complexes with Multibridged
 Germanium Centers Derived from Unsymmetrical Digermanes
;
_journal_issue                   18
_journal_name_full               Organometallics
_journal_page_first              6635
_journal_paper_doi               10.1021/om3007147
_journal_volume                  31
_journal_year                    2012
_chemical_formula_sum            'C70 H74 Ge3 P4 Pt2'
_chemical_formula_weight         1647.12
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           11
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yb'
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 113.173(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   11.7251(15)
_cell_length_b                   24.701(3)
_cell_length_c                   11.8731(15)
_cell_measurement_reflns_used    6890
_cell_measurement_temperature    123
_cell_measurement_theta_max      27.42
_cell_measurement_theta_min      2.49
_cell_volume                     3161.3(7)
_computing_cell_refinement       'APEX2 (Bruker AXS, 2006)'
_computing_data_collection       'APEX2 (Bruker AXS, 2006)'
_computing_data_reduction        'SAINT (Bruker AXS, 2004)'
_computing_molecular_graphics    'XSHEL (Bruker AXS,2002)'
_computing_publication_material  'XCIF (Bruker AXS, 2001)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      123
_diffrn_detector_area_resol_mean 8.333
_diffrn_measured_fraction_theta_full 0.969
_diffrn_measured_fraction_theta_max 0.969
_diffrn_measurement_device_type  'Bruker APEXII CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  'Bruker Helios multilayer confocal mirror'
_diffrn_radiation_source         'Bruker TXS fine-focus rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0292
_diffrn_reflns_av_sigmaI/netI    0.0386
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            17744
_diffrn_reflns_theta_full        27.44
_diffrn_reflns_theta_max         27.44
_diffrn_reflns_theta_min         1.65
_exptl_absorpt_coefficient_mu    5.962
_exptl_absorpt_correction_T_max  0.6470
_exptl_absorpt_correction_T_min  0.3818
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details
;
SADABS Sheldrick 1996
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.730
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1612
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.889
_refine_diff_density_min         -0.647
_refine_diff_density_rms         0.116
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.027
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     387
_refine_ls_number_reflns         7160
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.027
_refine_ls_R_factor_all          0.0388
_refine_ls_R_factor_gt           0.0265
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0256P)²+0.6819P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0544
_refine_ls_wR_factor_ref         0.0579
_reflns_number_gt                5871
_reflns_number_total             7160
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om3007147_si_002.cif
_cod_data_source_block           complex4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      'P2(1)/m  '
_cod_database_code               4079400
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt 0.821863(12) 0.167761(5) 0.801909(12) 0.01421(4) Uani 1 1 d .
Ge1 Ge 0.76616(5) 0.2500 0.67043(4) 0.01559(11) Uani 1 2 d S
Ge2 Ge 0.54036(5) 0.2500 0.60149(5) 0.01911(12) Uani 1 2 d S
Ge3 Ge 0.87703(5) 0.2500 0.92703(4) 0.01568(11) Uani 1 2 d S
P1 P 0.82074(9) 0.09157(4) 0.68879(8) 0.0186(2) Uani 1 1 d .
P2 P 0.83566(9) 0.10930(4) 0.95425(8) 0.0192(2) Uani 1 1 d .
C1 C 0.7950(3) 0.03231(14) 0.7708(3) 0.0231(8) Uani 1 1 d .
H1A H 0.7051 0.0275 0.7491 0.028 Uiso 1 1 calc R
H1B H 0.8269 -0.0007 0.7458 0.028 Uiso 1 1 calc R
C2 C 0.8621(3) 0.04051(14) 0.9098(3) 0.0242(9) Uani 1 1 d .
H2A H 0.9522 0.0345 0.9345 0.029 Uiso 1 1 calc R
H2B H 0.8314 0.0137 0.9532 0.029 Uiso 1 1 calc R
C3 C 0.7215(3) 0.07598(14) 0.5292(3) 0.0212(8) Uani 1 1 d .
C4 C 0.6471(3) 0.03026(15) 0.4913(3) 0.0256(8) Uani 1 1 d .
H4 H 0.6484 0.0039 0.5502 0.031 Uiso 1 1 calc R
C5 C 0.5713(4) 0.02241(17) 0.3694(4) 0.0307(9) Uani 1 1 d .
H5 H 0.5207 -0.0090 0.3451 0.037 Uiso 1 1 calc R
C6 C 0.5692(4) 0.06009(17) 0.2834(4) 0.0341(10) Uani 1 1 d .
H6 H 0.5162 0.0550 0.1997 0.041 Uiso 1 1 calc R
C7 C 0.6440(4) 0.10539(16) 0.3184(4) 0.0340(10) Uani 1 1 d .
H7 H 0.6435 0.1311 0.2587 0.041 Uiso 1 1 calc R
C8 C 0.7200(4) 0.11333(15) 0.4411(3) 0.0280(9) Uani 1 1 d .
H8 H 0.7714 0.1445 0.4649 0.034 Uiso 1 1 calc R
C9 C 0.9744(3) 0.07994(14) 0.6892(3) 0.0222(8) Uani 1 1 d .
C10 C 1.0585(4) 0.12255(16) 0.7187(4) 0.0323(9) Uani 1 1 d .
H10 H 1.0374 0.1564 0.7435 0.039 Uiso 1 1 calc R
C11 C 1.1725(4) 0.11586(18) 0.7121(4) 0.0390(11) Uani 1 1 d .
H11 H 1.2288 0.1454 0.7310 0.047 Uiso 1 1 calc R
C12 C 1.2057(4) 0.06709(18) 0.6785(4) 0.0351(10) Uani 1 1 d .
H12 H 1.2844 0.0631 0.6739 0.042 Uiso 1 1 calc R
C13 C 1.1255(4) 0.02439(18) 0.6518(4) 0.0404(11) Uani 1 1 d .
H13 H 1.1490 -0.0097 0.6307 0.048 Uiso 1 1 calc R
C14 C 1.0097(4) 0.03093(17) 0.6555(4) 0.0385(11) Uani 1 1 d .
H14 H 0.9534 0.0013 0.6346 0.046 Uiso 1 1 calc R
C15 C 0.6856(3) 0.10726(15) 0.9688(3) 0.0229(8) Uani 1 1 d .
C16 C 0.6430(4) 0.15440(16) 1.0014(4) 0.0299(9) Uani 1 1 d .
H16 H 0.6946 0.1856 1.0215 0.036 Uiso 1 1 calc R
C17 C 0.5270(4) 0.15727(18) 1.0055(4) 0.0371(10) Uani 1 1 d .
H17 H 0.5008 0.1897 1.0310 0.044 Uiso 1 1 calc R
C18 C 0.4492(4) 0.11298(19) 0.9724(4) 0.0403(11) Uani 1 1 d .
H18 H 0.3688 0.1150 0.9736 0.048 Uiso 1 1 calc R
C19 C 0.4887(4) 0.06595(19) 0.9379(4) 0.0396(11) Uani 1 1 d .
H19 H 0.4350 0.0355 0.9144 0.047 Uiso 1 1 calc R
C20 C 0.6065(4) 0.06246(17) 0.9368(4) 0.0331(10) Uani 1 1 d .
H20 H 0.6334 0.0295 0.9142 0.040 Uiso 1 1 calc R
C21 C 0.9523(3) 0.11308(14) 1.1117(3) 0.0227(8) Uani 1 1 d .
C22 C 1.0747(4) 0.11728(15) 1.1274(4) 0.0291(9) Uani 1 1 d .
H22 H 1.0958 0.1191 1.0580 0.035 Uiso 1 1 calc R
C23 C 1.1688(4) 0.11880(16) 1.2462(4) 0.0348(10) Uani 1 1 d .
H23 H 1.2534 0.1210 1.2568 0.042 Uiso 1 1 calc R
C24 C 1.1387(4) 0.11720(16) 1.3457(4) 0.0371(11) Uani 1 1 d .
H24 H 1.2024 0.1183 1.4257 0.044 Uiso 1 1 calc R
C25 C 1.0160(4) 0.11393(17) 1.3313(4) 0.0375(11) Uani 1 1 d .
H25 H 0.9954 0.1133 1.4010 0.045 Uiso 1 1 calc R
C26 C 0.9224(4) 0.11149(16) 1.2133(3) 0.0331(10) Uani 1 1 d .
H26 H 0.8381 0.1087 1.2030 0.040 Uiso 1 1 calc R
C27 C 0.8072(5) 0.2500 0.5231(4) 0.0190(11) Uani 1 2 d S
C28 C 0.7160(5) 0.2500 0.4032(5) 0.0255(12) Uani 1 2 d S
H28 H 0.6310 0.2500 0.3911 0.031 Uiso 1 2 calc SR
C29 C 0.7469(6) 0.2500 0.3027(5) 0.0318(14) Uani 1 2 d S
H29 H 0.6831 0.2500 0.2227 0.038 Uiso 1 2 calc SR
C30 C 0.8691(6) 0.2500 0.3168(5) 0.0415(16) Uani 1 2 d S
H30 H 0.8899 0.2500 0.2472 0.050 Uiso 1 2 calc SR
C31 C 0.9620(6) 0.2500 0.4346(6) 0.0397(15) Uani 1 2 d S
H31 H 1.0468 0.2500 0.4459 0.048 Uiso 1 2 calc SR
C32 C 0.9297(5) 0.2500 0.5345(5) 0.0267(12) Uani 1 2 d S
H32 H 0.9938 0.2500 0.6143 0.032 Uiso 1 2 calc SR
C33 C 0.4626(3) 0.18462(15) 0.5042(4) 0.0265(9) Uani 1 1 d .
H33A H 0.3737 0.1920 0.4555 0.032 Uiso 1 1 calc R
H33B H 0.5025 0.1769 0.4463 0.032 Uiso 1 1 calc R
C34 C 0.4741(4) 0.13481(16) 0.5843(4) 0.0354(10) Uani 1 1 d .
H34A H 0.5614 0.1292 0.6381 0.053 Uiso 1 1 calc R
H34B H 0.4429 0.1029 0.5321 0.053 Uiso 1 1 calc R
H34C H 0.4254 0.1404 0.6341 0.053 Uiso 1 1 calc R
C35 C 0.4813(6) 0.2500 0.7350(5) 0.0377(15) Uani 1 2 d S
H35A H 0.5136 0.2176 0.7868 0.045 Uiso 0.50 1 calc PR
H35B H 0.5136 0.2824 0.7868 0.045 Uiso 0.50 1 calc PR
C36 C 0.3391(6) 0.2500 0.6852(7) 0.0482(18) Uani 1 2 d S
H36A H 0.3075 0.2849 0.6462 0.072 Uiso 0.50 1 calc PR
H36B H 0.3124 0.2442 0.7528 0.072 Uiso 0.50 1 calc PR
H36C H 0.3065 0.2209 0.6249 0.072 Uiso 0.50 1 calc PR
C37 C 1.0600(5) 0.2500 1.0061(4) 0.0198(11) Uani 1 2 d S
C38 C 1.1317(5) 0.2500 0.9377(5) 0.0308(13) Uani 1 2 d S
H38 H 1.0923 0.2500 0.8508 0.037 Uiso 1 2 calc SR
C39 C 1.2608(5) 0.2500 0.9935(6) 0.0430(16) Uani 1 2 d S
H39 H 1.3088 0.2500 0.9451 0.052 Uiso 1 2 calc SR
C40 C 1.3190(6) 0.2500 1.1209(6) 0.0415(16) Uani 1 2 d S
H40 H 1.4070 0.2500 1.1592 0.050 Uiso 1 2 calc SR
C41 C 1.2516(5) 0.2500 1.1900(5) 0.0345(15) Uani 1 2 d S
H41 H 1.2919 0.2500 1.2768 0.041 Uiso 1 2 calc SR
C42 C 1.1224(5) 0.2500 1.1338(5) 0.0268(13) Uani 1 2 d S
H42 H 1.0756 0.2500 1.1834 0.032 Uiso 1 2 calc SR
H1H H 0.843(4) 0.2500 1.032(4) 0.023(14) Uiso 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P2 Pt1 P1 85.83(4) . .
P2 Pt1 Ge3 97.20(3) . .
P1 Pt1 Ge3 165.63(3) . .
P2 Pt1 Ge1 159.78(3) . .
P1 Pt1 Ge1 111.14(3) . .
Ge3 Pt1 Ge1 69.188(16) . .
C27 Ge1 Ge2 108.10(15) . .
C27 Ge1 Pt1 117.22(6) . 4_565
Ge2 Ge1 Pt1 101.095(17) . 4_565
C27 Ge1 Pt1 117.22(6) . .
Ge2 Ge1 Pt1 101.095(17) . .
Pt1 Ge1 Pt1 109.50(2) 4_565 .
C27 Ge1 Ge3 141.91(15) . .
Ge2 Ge1 Ge3 110.00(2) . .
Pt1 Ge1 Ge3 54.750(11) 4_565 .
Pt1 Ge1 Ge3 54.751(11) . .
C35 Ge2 C33 104.04(16) . .
C35 Ge2 C33 104.04(16) . 4_565
C33 Ge2 C33 108.8(2) . 4_565
C35 Ge2 Ge1 114.16(18) . .
C33 Ge2 Ge1 112.55(12) . .
C33 Ge2 Ge1 112.54(12) 4_565 .
C37 Ge3 Pt1 105.46(8) . 4_565
C37 Ge3 Pt1 105.46(8) . .
Pt1 Ge3 Pt1 112.12(2) 4_565 .
C37 Ge3 Ge1 117.98(15) . .
Pt1 Ge3 Ge1 56.061(11) 4_565 .
Pt1 Ge3 Ge1 56.061(11) . .
C37 Ge3 H1H 101.8(18) . .
Pt1 Ge3 H1H 115.2(7) 4_565 .
Pt1 Ge3 H1H 115.2(8) . .
Ge1 Ge3 H1H 140.2(19) . .
C9 P1 C3 101.21(17) . .
C9 P1 C1 103.87(17) . .
C3 P1 C1 102.11(17) . .
C9 P1 Pt1 110.33(12) . .
C3 P1 Pt1 128.95(12) . .
C1 P1 Pt1 107.70(12) . .
C21 P2 C15 105.26(18) . .
C21 P2 C2 101.37(16) . .
C15 P2 C2 106.09(18) . .
C21 P2 Pt1 124.80(12) . .
C15 P2 Pt1 108.80(12) . .
C2 P2 Pt1 109.04(13) . .
C2 C1 P1 109.9(2) . .
C2 C1 H1A 109.7 . .
P1 C1 H1A 109.7 . .
C2 C1 H1B 109.7 . .
P1 C1 H1B 109.7 . .
H1A C1 H1B 108.2 . .
C1 C2 P2 110.9(2) . .
C1 C2 H2A 109.5 . .
P2 C2 H2A 109.5 . .
C1 C2 H2B 109.5 . .
P2 C2 H2B 109.5 . .
H2A C2 H2B 108.0 . .
C4 C3 C8 118.4(3) . .
C4 C3 P1 124.6(3) . .
C8 C3 P1 117.0(3) . .
C5 C4 C3 121.1(4) . .
C5 C4 H4 119.5 . .
C3 C4 H4 119.5 . .
C6 C5 C4 119.9(4) . .
C6 C5 H5 120.0 . .
C4 C5 H5 120.0 . .
C5 C6 C7 120.1(4) . .
C5 C6 H6 120.0 . .
C7 C6 H6 120.0 . .
C6 C7 C8 120.0(4) . .
C6 C7 H7 120.0 . .
C8 C7 H7 120.0 . .
C3 C8 C7 120.5(4) . .
C3 C8 H8 119.7 . .
C7 C8 H8 119.7 . .
C14 C9 C10 118.1(4) . .
C14 C9 P1 122.9(3) . .
C10 C9 P1 118.9(3) . .
C11 C10 C9 120.1(4) . .
C11 C10 H10 119.9 . .
C9 C10 H10 119.9 . .
C12 C11 C10 120.9(4) . .
C12 C11 H11 119.5 . .
C10 C11 H11 119.5 . .
C13 C12 C11 119.8(4) . .
C13 C12 H12 120.1 . .
C11 C12 H12 120.1 . .
C12 C13 C14 119.8(4) . .
C12 C13 H13 120.1 . .
C14 C13 H13 120.1 . .
C13 C14 C9 121.2(4) . .
C13 C14 H14 119.4 . .
C9 C14 H14 119.4 . .
C16 C15 C20 118.0(4) . .
C16 C15 P2 118.0(3) . .
C20 C15 P2 123.7(3) . .
C15 C16 C17 121.5(4) . .
C15 C16 H16 119.2 . .
C17 C16 H16 119.2 . .
C18 C17 C16 120.0(4) . .
C18 C17 H17 120.0 . .
C16 C17 H17 120.0 . .
C19 C18 C17 119.6(4) . .
C19 C18 H18 120.2 . .
C17 C18 H18 120.2 . .
C18 C19 C20 120.6(4) . .
C18 C19 H19 119.7 . .
C20 C19 H19 119.7 . .
C19 C20 C15 120.3(4) . .
C19 C20 H20 119.9 . .
C15 C20 H20 119.9 . .
C22 C21 C26 119.5(3) . .
C22 C21 P2 117.5(3) . .
C26 C21 P2 123.0(3) . .
C21 C22 C23 120.1(4) . .
C21 C22 H22 119.9 . .
C23 C22 H22 119.9 . .
C24 C23 C22 120.0(4) . .
C24 C23 H23 120.0 . .
C22 C23 H23 120.0 . .
C23 C24 C25 120.5(4) . .
C23 C24 H24 119.8 . .
C25 C24 H24 119.8 . .
C24 C25 C26 119.6(4) . .
C24 C25 H25 120.2 . .
C26 C25 H25 120.2 . .
C21 C26 C25 120.2(4) . .
C21 C26 H26 119.9 . .
C25 C26 H26 119.9 . .
C32 C27 C28 116.4(5) . .
C32 C27 Ge1 120.9(4) . .
C28 C27 Ge1 122.7(4) . .
C29 C28 C27 121.6(5) . .
C29 C28 H28 119.2 . .
C27 C28 H28 119.2 . .
C28 C29 C30 120.7(5) . .
C28 C29 H29 119.6 . .
C30 C29 H29 119.6 . .
C29 C30 C31 119.2(6) . .
C29 C30 H30 120.4 . .
C31 C30 H30 120.4 . .
C32 C31 C30 119.4(6) . .
C32 C31 H31 120.3 . .
C30 C31 H31 120.3 . .
C31 C32 C27 122.7(5) . .
C31 C32 H32 118.7 . .
C27 C32 H32 118.7 . .
C34 C33 Ge2 112.6(3) . .
C34 C33 H33A 109.1 . .
Ge2 C33 H33A 109.1 . .
C34 C33 H33B 109.1 . .
Ge2 C33 H33B 109.1 . .
H33A C33 H33B 107.8 . .
C33 C34 H34A 109.5 . .
C33 C34 H34B 109.5 . .
H34A C34 H34B 109.5 . .
C33 C34 H34C 109.5 . .
H34A C34 H34C 109.5 . .
H34B C34 H34C 109.5 . .
C36 C35 Ge2 111.3(4) . .
C36 C35 H35A 109.4 . .
Ge2 C35 H35A 109.4 . .
C36 C35 H35B 109.4 . .
Ge2 C35 H35B 109.4 . .
H35A C35 H35B 108.0 . .
C35 C36 H36A 109.5 . .
C35 C36 H36B 109.5 . .
H36A C36 H36B 109.5 . .
C35 C36 H36C 109.5 . .
H36A C36 H36C 109.5 . .
H36B C36 H36C 109.5 . .
C38 C37 C42 117.2(5) . .
C38 C37 Ge3 121.3(4) . .
C42 C37 Ge3 121.4(4) . .
C37 C38 C39 121.3(5) . .
C37 C38 H38 119.4 . .
C39 C38 H38 119.4 . .
C38 C39 C40 119.6(6) . .
C38 C39 H39 120.2 . .
C40 C39 H39 120.2 . .
C41 C40 C39 120.5(6) . .
C41 C40 H40 119.7 . .
C39 C40 H40 119.7 . .
C40 C41 C42 119.8(5) . .
C40 C41 H41 120.1 . .
C42 C41 H41 120.1 . .
C41 C42 C37 121.6(6) . .
C41 C42 H42 119.2 . .
C37 C42 H42 119.2 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 P2 2.2700(9) .
Pt1 P1 2.3092(9) .
Pt1 Ge3 2.4486(4) .
Pt1 Ge1 2.4875(4) .
Ge1 C27 1.988(5) .
Ge1 Ge2 2.4442(8) .
Ge1 Pt1 2.4875(4) 4_565
Ge1 Ge3 2.8027(8) .
Ge2 C35 1.963(6) .
Ge2 C33 1.986(4) .
Ge2 C33 1.986(4) 4_565
Ge3 C37 1.975(5) .
Ge3 Pt1 2.4486(4) 4_565
Ge3 H1H 1.45(5) .
P1 C9 1.823(4) .
P1 C3 1.832(4) .
P1 C1 1.847(4) .
P2 C21 1.834(4) .
P2 C15 1.835(4) .
P2 C2 1.841(4) .
C1 C2 1.537(5) .
C1 H1A 0.9900 .
C1 H1B 0.9900 .
C2 H2A 0.9900 .
C2 H2B 0.9900 .
C3 C4 1.389(5) .
C3 C8 1.390(5) .
C4 C5 1.383(5) .
C4 H4 0.9500 .
C5 C6 1.375(6) .
C5 H5 0.9500 .
C6 C7 1.381(6) .
C6 H6 0.9500 .
C7 C8 1.390(5) .
C7 H7 0.9500 .
C8 H8 0.9500 .
C9 C14 1.388(5) .
C9 C10 1.389(5) .
C10 C11 1.379(6) .
C10 H10 0.9500 .
C11 C12 1.373(6) .
C11 H11 0.9500 .
C12 C13 1.365(6) .
C12 H12 0.9500 .
C13 C14 1.386(6) .
C13 H13 0.9500 .
C14 H14 0.9500 .
C15 C16 1.381(5) .
C15 C20 1.397(5) .
C16 C17 1.382(6) .
C16 H16 0.9500 .
C17 C18 1.379(6) .
C17 H17 0.9500 .
C18 C19 1.372(6) .
C18 H18 0.9500 .
C19 C20 1.389(6) .
C19 H19 0.9500 .
C20 H20 0.9500 .
C21 C22 1.377(5) .
C21 C26 1.383(6) .
C22 C23 1.408(5) .
C22 H22 0.9500 .
C23 C24 1.361(6) .
C23 H23 0.9500 .
C24 C25 1.382(6) .
C24 H24 0.9500 .
C25 C26 1.400(5) .
C25 H25 0.9500 .
C26 H26 0.9500 .
C27 C32 1.388(7) .
C27 C28 1.405(7) .
C28 C29 1.376(8) .
C28 H28 0.9500 .
C29 C30 1.375(9) .
C29 H29 0.9500 .
C30 C31 1.394(8) .
C30 H30 0.9500 .
C31 C32 1.380(8) .
C31 H31 0.9500 .
C32 H32 0.9500 .
C33 C34 1.528(5) .
C33 H33A 0.9900 .
C33 H33B 0.9900 .
C34 H34A 0.9800 .
C34 H34B 0.9800 .
C34 H34C 0.9800 .
C35 C36 1.534(9) .
C35 H35A 0.9900 .
C35 H35B 0.9900 .
C36 H36A 0.9800 .
C36 H36B 0.9800 .
C36 H36C 0.9800 .
C37 C38 1.380(8) .
C37 C42 1.401(7) .
C38 C39 1.393(8) .
C38 H38 0.9500 .
C39 C40 1.393(8) .
C39 H39 0.9500 .
C40 C41 1.344(9) .
C40 H40 0.9500 .
C41 C42 1.394(8) .
C41 H41 0.9500 .
C42 H42 0.9500 .
