#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/94/4079491.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4079491
loop_
_publ_author_name
'Sakaba, Hiroyuki'
'Oike, Hiroyuki'
'Arai, Yasuhiro'
'Kwon, Eunsang'
_publ_section_title
;
 Reactions of Tungsten Acetylide--Silylene Complexes with Pyridines:
 Direct Observation of Silylene/Silyl Migration in Tungsten Acetylide and
 Carbyne/Vinylidene Frameworks
;
_journal_issue                   23
_journal_name_full               Organometallics
_journal_page_first              8172
_journal_paper_doi               10.1021/om300772c
_journal_volume                  31
_journal_year                    2012
_chemical_formula_moiety         'C36 H44 N2 O2 Si2 W '
_chemical_formula_sum            'C36 H44 N2 O2 Si2 W'
_chemical_formula_weight         776.78
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                92.190(6)
_cell_angle_beta                 95.119(4)
_cell_angle_gamma                91.953(5)
_cell_formula_units_Z            2
_cell_length_a                   9.675(3)
_cell_length_b                   11.977(4)
_cell_length_c                   15.321(5)
_cell_measurement_reflns_used    5489
_cell_measurement_temperature    173.0
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      5.1
_cell_volume                     1765.7(10)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR2004
_diffrn_ambient_temperature      173.00
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       ω
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.030
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            25319
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_exptl_absorpt_coefficient_mu    3.375
_exptl_absorpt_correction_T_max  0.509
_exptl_absorpt_correction_T_min  0.336
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
;
    Higashi, T. (1999). Program for Absorption Correction.
    Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.461
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             784.00
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.13
_refine_diff_density_max         1.82
_refine_diff_density_min         -0.57
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.005
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     432
_refine_ls_number_reflns         8021
_refine_ls_R_factor_gt           0.0237
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0005Fo² + 1.0000σ(Fo²)]/(4Fo²)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0672
_reflns_number_gt                7584
_reflns_number_total             8021
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            om300772c_si_001.cif
_cod_data_source_block           6a
_cod_original_cell_volume        1765.8(10)
_cod_original_formula_sum        'C36 H44 N2 O2 Si2 W '
_cod_database_code               4079491
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 +X,+Y,+Z
2 -X,-Y,-Z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
W1 W 0.294850(10) 0.341170(10) 0.791200(10) 0.01909(2) Uani 1.00 1 d .
Si1 Si 0.01655(6) 0.05488(5) 0.74479(4) 0.01782(14) Uani 1.00 1 d .
Si2 Si 0.33519(7) -0.01320(6) 0.70495(5) 0.02199(16) Uani 1.00 1 d .
O1 O -0.0006(2) 0.42312(19) 0.73188(17) 0.0443(6) Uani 1.00 1 d .
O2 O 0.3637(2) 0.3358(2) 0.59617(14) 0.0445(6) Uani 1.00 1 d .
N1 N -0.05682(19) 0.15689(17) 0.66741(13) 0.0193(4) Uani 1.00 1 d .
N2 N -0.2264(2) 0.3759(2) 0.48502(16) 0.0336(6) Uani 1.00 1 d .
C1 C 0.2411(2) 0.1863(2) 0.76955(15) 0.0185(5) Uani 1.00 1 d .
C2 C 0.2033(2) 0.07751(19) 0.74898(15) 0.0182(5) Uani 1.00 1 d .
C3 C 0.2688(5) -0.0902(9) 0.6041(5) 0.216(4) Uani 1.00 1 d .
C4 C 0.4014(9) -0.1137(7) 0.7844(5) 0.189(3) Uani 1.00 1 d .
C5 C 0.4867(4) 0.0704(3) 0.6790(5) 0.113(2) Uani 1.00 1 d .
C6 C -0.0618(2) -0.0833(2) 0.69889(17) 0.0249(6) Uani 1.00 1 d .
C7 C -0.0354(3) -0.1803(2) 0.7449(2) 0.0382(8) Uani 1.00 1 d .
C8 C -0.1030(4) -0.2822(2) 0.7198(2) 0.0537(10) Uani 1.00 1 d .
C9 C -0.1990(4) -0.2886(3) 0.6464(2) 0.0569(11) Uani 1.00 1 d .
C10 C -0.2264(3) -0.1953(3) 0.5992(2) 0.0486(9) Uani 1.00 1 d .
C11 C -0.1578(2) -0.0937(2) 0.6249(2) 0.0340(7) Uani 1.00 1 d .
C12 C -0.0666(2) 0.0815(2) 0.84901(16) 0.0221(5) Uani 1.00 1 d .
C13 C -0.0036(3) 0.1529(2) 0.91608(19) 0.0360(7) Uani 1.00 1 d .
C14 C -0.0593(3) 0.1639(3) 0.9966(2) 0.0483(9) Uani 1.00 1 d .
C15 C -0.1798(3) 0.1056(2) 1.0112(2) 0.0409(8) Uani 1.00 1 d .
C16 C -0.2445(3) 0.0357(2) 0.9462(2) 0.0381(8) Uani 1.00 1 d .
C17 C -0.1889(2) 0.0225(2) 0.8654(2) 0.0316(7) Uani 1.00 1 d .
C18 C -0.1885(2) 0.1927(2) 0.66961(17) 0.0236(5) Uani 1.00 1 d .
C19 C -0.2485(2) 0.2629(2) 0.61078(17) 0.0258(6) Uani 1.00 1 d .
C20 C -0.1721(2) 0.3051(2) 0.54366(16) 0.0231(5) Uani 1.00 1 d .
C21 C -0.0345(2) 0.2674(2) 0.54183(17) 0.0249(6) Uani 1.00 1 d .
C22 C 0.0175(2) 0.1962(2) 0.60272(16) 0.0226(5) Uani 1.00 1 d .
C23 C -0.3703(3) 0.4082(3) 0.4860(2) 0.0525(10) Uani 1.00 1 d .
C24 C -0.1481(3) 0.4166(3) 0.4147(2) 0.0428(8) Uani 1.00 1 d .
C25 C 0.1095(2) 0.3892(2) 0.75169(18) 0.0275(6) Uani 1.00 1 d .
C26 C 0.3357(2) 0.3391(2) 0.67022(17) 0.0254(6) Uani 1.00 1 d .
C27 C 0.4642(2) 0.4823(2) 0.84777(18) 0.0291(6) Uani 1.00 1 d .
C28 C 0.5117(2) 0.3764(2) 0.87403(18) 0.0295(6) Uani 1.00 1 d .
C29 C 0.4156(2) 0.3319(2) 0.93197(17) 0.0285(6) Uani 1.00 1 d .
C30 C 0.3098(2) 0.4109(2) 0.93985(17) 0.0300(6) Uani 1.00 1 d .
C31 C 0.3403(3) 0.5035(2) 0.88763(19) 0.0308(6) Uani 1.00 1 d .
C32 C 0.5378(3) 0.5606(2) 0.7913(2) 0.0455(9) Uani 1.00 1 d .
C33 C 0.6459(3) 0.3260(2) 0.8540(2) 0.0413(8) Uani 1.00 1 d .
C34 C 0.4304(3) 0.2256(2) 0.9803(2) 0.0439(8) Uani 1.00 1 d .
C35 C 0.1956(3) 0.4056(3) 0.9999(2) 0.0482(9) Uani 1.00 1 d .
C36 C 0.2580(3) 0.6075(2) 0.8818(2) 0.0497(9) Uani 1.00 1 d .
H1 H -0.2404 0.1677 0.7138 0.028 Uiso 1.00 1 c R
H2 H 0.0203 0.2917 0.4989 0.030 Uiso 1.00 1 c R
H3 H -0.3397 0.2832 0.6147 0.031 Uiso 1.00 1 c R
H4 H 0.5898 0.6170 0.8279 0.053 Uiso 1.00 1 c R
H5 H 0.0294 -0.1765 0.7937 0.046 Uiso 1.00 1 c R
H6 H 0.1080 0.1734 0.6001 0.027 Uiso 1.00 1 c R
H7 H -0.1766 -0.0313 0.5922 0.040 Uiso 1.00 1 c R
H8 H 0.0769 0.1938 0.9069 0.043 Uiso 1.00 1 c R
H9 H -0.2335 -0.0256 0.8219 0.039 Uiso 1.00 1 c R
H10 H -0.3262 -0.0034 0.9557 0.048 Uiso 1.00 1 c R
H11 H -0.0149 0.2112 1.0407 0.058 Uiso 1.00 1 c R
H12 H -0.2904 -0.2002 0.5500 0.057 Uiso 1.00 1 c R
H13 H -0.2166 0.1135 1.0650 0.051 Uiso 1.00 1 c R
H14 H -0.0845 -0.3454 0.7516 0.066 Uiso 1.00 1 c R
H15 H -0.2451 -0.3564 0.6293 0.069 Uiso 1.00 1 c R
H16 H 0.3541 0.2162 1.0156 0.052 Uiso 1.00 1 c R
H17 H 0.5161 0.2293 1.0173 0.052 Uiso 1.00 1 c R
H18 H 0.4304 0.1634 0.9389 0.052 Uiso 1.00 1 c R
H19 H 0.6564 0.2570 0.8834 0.049 Uiso 1.00 1 c R
H20 H 0.7219 0.3770 0.8740 0.049 Uiso 1.00 1 c R
H21 H 0.6454 0.3120 0.7919 0.049 Uiso 1.00 1 c R
H22 H -0.0968 0.4842 0.4345 0.053 Uiso 1.00 1 c R
H23 H -0.2112 0.4313 0.3648 0.053 Uiso 1.00 1 c R
H24 H -0.0849 0.3609 0.3985 0.053 Uiso 1.00 1 c R
H25 H 0.4707 0.5953 0.7522 0.054 Uiso 1.00 1 c R
H26 H 0.5997 0.5194 0.7578 0.053 Uiso 1.00 1 c R
H27 H 0.2986 0.6581 0.8433 0.059 Uiso 1.00 1 c R
H28 H 0.2584 0.6429 0.9391 0.059 Uiso 1.00 1 c R
H29 H 0.1641 0.5879 0.8594 0.059 Uiso 1.00 1 c R
H30 H 0.1420 0.4713 0.9945 0.058 Uiso 1.00 1 c R
H31 H 0.2351 0.4013 1.0594 0.058 Uiso 1.00 1 c R
H32 H 0.1367 0.3405 0.9842 0.058 Uiso 1.00 1 c R
H33 H -0.4294 0.3568 0.4488 0.065 Uiso 1.00 1 c R
H34 H -0.3792 0.4823 0.4651 0.065 Uiso 1.00 1 c R
H35 H -0.3970 0.4066 0.5448 0.065 Uiso 1.00 1 c R
H36 H 0.4733 0.0927 0.6194 0.141 Uiso 1.00 1 c R
H37 H 0.5680 0.0268 0.6863 0.140 Uiso 1.00 1 c R
H38 H 0.4982 0.1357 0.7176 0.140 Uiso 1.00 1 c R
H39 H 0.2283 -0.1607 0.6184 0.250 Uiso 1.00 1 c R
H40 H 0.3435 -0.1028 0.5681 0.250 Uiso 1.00 1 c R
H41 H 0.1995 -0.0477 0.5729 0.250 Uiso 1.00 1 c R
H42 H 0.4813 -0.0813 0.8193 0.247 Uiso 1.00 1 c R
H43 H 0.4270 -0.1801 0.7537 0.247 Uiso 1.00 1 c R
H44 H 0.3304 -0.1324 0.8219 0.247 Uiso 1.00 1 c R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.003 0.002
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.000 0.000
;
International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.4)
;
N N 0.006 0.003
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
O O 0.011 0.006
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Si Si 0.082 0.070
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
W W -0.849 6.872
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
C(1) W(1) C(25) 92.36(9) yes
C(1) W(1) C(26) 85.74(10) yes
C(1) W(1) C(27) 149.77(9) yes
C(1) W(1) C(28) 115.25(9) yes
C(1) W(1) C(29) 99.62(9) yes
C(1) W(1) C(30) 116.96(9) yes
C(1) W(1) C(31) 151.66(9) yes
C(25) W(1) C(26) 87.65(11) yes
C(25) W(1) C(27) 117.66(9) yes
C(25) W(1) C(28) 149.90(9) yes
C(25) W(1) C(29) 132.69(10) yes
C(25) W(1) C(30) 99.47(10) yes
C(25) W(1) C(31) 92.21(10) yes
C(26) W(1) C(27) 98.23(9) yes
C(26) W(1) C(28) 105.29(10) yes
C(26) W(1) C(29) 138.47(10) yes
C(26) W(1) C(30) 155.61(9) yes
C(26) W(1) C(31) 122.39(10) yes
C(27) W(1) C(28) 34.76(9) yes
C(27) W(1) C(29) 58.14(9) yes
C(27) W(1) C(30) 57.77(9) yes
C(27) W(1) C(31) 34.44(9) yes
C(28) W(1) C(29) 35.49(9) yes
C(28) W(1) C(30) 58.37(9) yes
C(28) W(1) C(31) 57.83(9) yes
C(29) W(1) C(30) 34.96(9) yes
C(29) W(1) C(31) 57.96(9) yes
C(30) W(1) C(31) 34.75(9) yes
N(1) Si(1) C(2) 105.42(9) yes
N(1) Si(1) C(6) 103.72(10) yes
N(1) Si(1) C(12) 105.65(10) yes
C(2) Si(1) C(6) 118.46(11) yes
C(2) Si(1) C(12) 117.10(10) yes
C(6) Si(1) C(12) 105.01(11) yes
C(2) Si(2) C(3) 112.4(2) yes
C(2) Si(2) C(4) 112.4(3) yes
C(2) Si(2) C(5) 110.74(17) yes
C(3) Si(2) C(4) 108.5(4) yes
C(3) Si(2) C(5) 106.7(3) yes
C(4) Si(2) C(5) 105.8(3) yes
Si(1) N(1) C(18) 122.08(17) yes
Si(1) N(1) C(22) 121.08(15) yes
C(18) N(1) C(22) 116.8(2) yes
C(20) N(2) C(23) 120.5(2) yes
C(20) N(2) C(24) 121.7(2) yes
C(23) N(2) C(24) 117.7(2) yes
W(1) C(1) C(2) 176.55(19) yes
Si(1) C(2) Si(2) 129.29(12) yes
Si(1) C(2) C(1) 111.20(17) yes
Si(2) C(2) C(1) 117.65(17) yes
Si(1) C(6) C(7) 119.42(19) yes
Si(1) C(6) C(11) 123.2(2) yes
C(7) C(6) C(11) 117.0(2) yes
C(6) C(7) C(8) 121.9(2) yes
C(7) C(8) C(9) 119.2(3) yes
C(8) C(9) C(10) 120.4(3) yes
C(9) C(10) C(11) 119.9(3) yes
C(6) C(11) C(10) 121.6(2) yes
Si(1) C(12) C(13) 121.48(19) yes
Si(1) C(12) C(17) 120.82(18) yes
C(13) C(12) C(17) 117.5(2) yes
C(12) C(13) C(14) 121.1(2) yes
C(13) C(14) C(15) 120.5(3) yes
C(14) C(15) C(16) 119.7(3) yes
C(15) C(16) C(17) 120.5(2) yes
C(12) C(17) C(16) 120.8(2) yes
N(1) C(18) C(19) 123.7(2) yes
C(18) C(19) C(20) 120.1(2) yes
N(2) C(20) C(19) 122.1(2) yes
N(2) C(20) C(21) 122.0(2) yes
C(19) C(20) C(21) 115.9(2) yes
C(20) C(21) C(22) 120.4(2) yes
N(1) C(22) C(21) 123.2(2) yes
W(1) C(25) O(1) 175.9(2) yes
W(1) C(26) O(2) 178.2(2) yes
W(1) C(27) C(28) 71.60(14) yes
W(1) C(27) C(31) 72.95(15) yes
W(1) C(27) C(32) 123.81(19) yes
C(28) C(27) C(31) 108.4(2) yes
C(28) C(27) C(32) 125.4(2) yes
C(31) C(27) C(32) 126.1(2) yes
W(1) C(28) C(27) 73.64(15) yes
W(1) C(28) C(29) 72.21(14) yes
W(1) C(28) C(33) 125.19(19) yes
C(27) C(28) C(29) 107.7(2) yes
C(27) C(28) C(33) 126.2(2) yes
C(29) C(28) C(33) 125.7(2) yes
W(1) C(29) C(28) 72.29(14) yes
W(1) C(29) C(30) 73.22(14) yes
W(1) C(29) C(34) 123.46(19) yes
C(28) C(29) C(30) 107.7(2) yes
C(28) C(29) C(34) 126.0(2) yes
C(30) C(29) C(34) 126.2(2) yes
W(1) C(30) C(29) 71.83(14) yes
W(1) C(30) C(31) 73.16(15) yes
W(1) C(30) C(35) 125.97(19) yes
C(29) C(30) C(31) 107.9(2) yes
C(29) C(30) C(35) 126.6(2) yes
C(31) C(30) C(35) 125.1(2) yes
W(1) C(31) C(27) 72.61(15) yes
W(1) C(31) C(30) 72.09(14) yes
W(1) C(31) C(36) 124.1(2) yes
C(27) C(31) C(30) 108.3(2) yes
C(27) C(31) C(36) 126.9(2) yes
C(30) C(31) C(36) 124.7(2) yes
Si(2) C(3) H(39) 109.3 no
Si(2) C(3) H(40) 109.6 no
Si(2) C(3) H(41) 109.5 no
H(39) C(3) H(40) 109.5 no
H(39) C(3) H(41) 109.5 no
H(40) C(3) H(41) 109.5 no
Si(2) C(4) H(42) 109.7 no
Si(2) C(4) H(43) 109.4 no
Si(2) C(4) H(44) 109.3 no
H(42) C(4) H(43) 109.5 no
H(42) C(4) H(44) 109.5 no
H(43) C(4) H(44) 109.5 no
Si(2) C(5) H(36) 109.5 no
Si(2) C(5) H(37) 109.5 no
Si(2) C(5) H(38) 109.4 no
H(36) C(5) H(37) 109.5 no
H(36) C(5) H(38) 109.5 no
H(37) C(5) H(38) 109.5 no
C(6) C(7) H(5) 119.1 no
C(8) C(7) H(5) 119.0 no
C(7) C(8) H(14) 120.5 no
C(9) C(8) H(14) 120.3 no
C(8) C(9) H(15) 119.8 no
C(10) C(9) H(15) 119.8 no
C(9) C(10) H(12) 120.0 no
C(11) C(10) H(12) 120.1 no
C(6) C(11) H(7) 119.3 no
C(10) C(11) H(7) 119.1 no
C(12) C(13) H(8) 119.5 no
C(14) C(13) H(8) 119.5 no
C(13) C(14) H(11) 119.7 no
C(15) C(14) H(11) 119.8 no
C(14) C(15) H(13) 120.1 no
C(16) C(15) H(13) 120.2 no
C(15) C(16) H(10) 119.8 no
C(17) C(16) H(10) 119.7 no
C(12) C(17) H(9) 119.5 no
C(16) C(17) H(9) 119.7 no
N(1) C(18) H(1) 118.1 no
C(19) C(18) H(1) 118.3 no
C(18) C(19) H(3) 119.9 no
C(20) C(19) H(3) 120.0 no
C(20) C(21) H(2) 119.7 no
C(22) C(21) H(2) 119.9 no
N(1) C(22) H(6) 118.4 no
C(21) C(22) H(6) 118.4 no
N(2) C(23) H(33) 109.5 no
N(2) C(23) H(34) 109.4 no
N(2) C(23) H(35) 109.5 no
H(33) C(23) H(34) 109.5 no
H(33) C(23) H(35) 109.5 no
H(34) C(23) H(35) 109.5 no
N(2) C(24) H(22) 109.5 no
N(2) C(24) H(23) 109.5 no
N(2) C(24) H(24) 109.4 no
H(22) C(24) H(23) 109.5 no
H(22) C(24) H(24) 109.5 no
H(23) C(24) H(24) 109.5 no
C(27) C(32) H(4) 109.5 no
C(27) C(32) H(25) 109.5 no
C(27) C(32) H(26) 109.5 no
H(4) C(32) H(25) 109.5 no
H(4) C(32) H(26) 109.5 no
H(25) C(32) H(26) 109.5 no
C(28) C(33) H(19) 109.5 no
C(28) C(33) H(20) 109.4 no
C(28) C(33) H(21) 109.4 no
H(19) C(33) H(20) 109.5 no
H(19) C(33) H(21) 109.5 no
H(20) C(33) H(21) 109.5 no
C(29) C(34) H(16) 109.4 no
C(29) C(34) H(17) 109.5 no
C(29) C(34) H(18) 109.5 no
H(16) C(34) H(17) 109.5 no
H(16) C(34) H(18) 109.5 no
H(17) C(34) H(18) 109.5 no
C(30) C(35) H(30) 109.5 no
C(30) C(35) H(31) 109.5 no
C(30) C(35) H(32) 109.3 no
H(30) C(35) H(31) 109.5 no
H(30) C(35) H(32) 109.5 no
H(31) C(35) H(32) 109.5 no
C(31) C(36) H(27) 109.7 no
C(31) C(36) H(28) 109.4 no
C(31) C(36) H(29) 109.3 no
H(27) C(36) H(28) 109.5 no
H(27) C(36) H(29) 109.5 no
H(28) C(36) H(29) 109.5 no
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
W(1) C(1) 1.918(2) yes
W(1) C(25) 1.954(2) yes
W(1) C(26) 1.929(2) yes
W(1) C(27) 2.396(2) yes
W(1) C(28) 2.369(2) yes
W(1) C(29) 2.368(2) yes
W(1) C(30) 2.386(2) yes
W(1) C(31) 2.400(2) yes
Si(1) N(1) 1.850(2) yes
Si(1) C(2) 1.813(2) yes
Si(1) C(6) 1.881(2) yes
Si(1) C(12) 1.873(2) yes
Si(2) C(2) 1.859(2) yes
Si(2) C(3) 1.823(9) yes
Si(2) C(4) 1.835(8) yes
Si(2) C(5) 1.829(5) yes
O(1) C(25) 1.172(3) yes
O(2) C(26) 1.189(3) yes
N(1) C(18) 1.361(3) yes
N(1) C(22) 1.364(3) yes
N(2) C(20) 1.344(3) yes
N(2) C(23) 1.459(4) yes
N(2) C(24) 1.460(4) yes
C(1) C(2) 1.359(3) yes
C(6) C(7) 1.402(4) yes
C(6) C(11) 1.399(3) yes
C(7) C(8) 1.389(4) yes
C(8) C(9) 1.391(5) yes
C(9) C(10) 1.375(5) yes
C(10) C(11) 1.392(4) yes
C(12) C(13) 1.394(3) yes
C(12) C(17) 1.405(3) yes
C(13) C(14) 1.392(4) yes
C(14) C(15) 1.378(5) yes
C(15) C(16) 1.369(4) yes
C(16) C(17) 1.398(4) yes
C(18) C(19) 1.362(3) yes
C(19) C(20) 1.418(3) yes
C(20) C(21) 1.423(3) yes
C(21) C(22) 1.362(3) yes
C(27) C(28) 1.423(3) yes
C(27) C(31) 1.420(4) yes
C(27) C(32) 1.503(4) yes
C(28) C(29) 1.444(4) yes
C(28) C(33) 1.502(4) yes
C(29) C(30) 1.428(4) yes
C(29) C(34) 1.502(4) yes
C(30) C(31) 1.429(3) yes
C(30) C(35) 1.501(4) yes
C(31) C(36) 1.503(4) yes
C(3) H(39) 0.960 no
C(3) H(40) 0.960 no
C(3) H(41) 0.960 no
C(4) H(42) 0.960 no
C(4) H(43) 0.960 no
C(4) H(44) 0.960 no
C(5) H(36) 0.960 no
C(5) H(37) 0.960 no
C(5) H(38) 0.960 no
C(7) H(5) 0.930 no
C(8) H(14) 0.930 no
C(9) H(15) 0.930 no
C(10) H(12) 0.930 no
C(11) H(7) 0.930 no
C(13) H(8) 0.930 no
C(14) H(11) 0.930 no
C(15) H(13) 0.930 no
C(16) H(10) 0.930 no
C(17) H(9) 0.930 no
C(18) H(1) 0.930 no
C(19) H(3) 0.930 no
C(21) H(2) 0.930 no
C(22) H(6) 0.930 no
C(23) H(33) 0.960 no
C(23) H(34) 0.960 no
C(23) H(35) 0.960 no
C(24) H(22) 0.960 no
C(24) H(23) 0.960 no
C(24) H(24) 0.960 no
C(32) H(4) 0.960 no
C(32) H(25) 0.960 no
C(32) H(26) 0.960 no
C(33) H(19) 0.960 no
C(33) H(20) 0.960 no
C(33) H(21) 0.960 no
C(34) H(16) 0.960 no
C(34) H(17) 0.960 no
C(34) H(18) 0.960 no
C(35) H(30) 0.960 no
C(35) H(31) 0.960 no
C(35) H(32) 0.960 no
C(36) H(27) 0.960 no
C(36) H(28) 0.960 no
C(36) H(29) 0.960 no
