#------------------------------------------------------------------------------
#$Date: 2016-03-21 11:13:33 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178684 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/95/4079567.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4079567
loop_
_publ_author_name
'Hu, Ting'
'Zhao, Liang'
'Mak, Thomas C. W.'
_publ_section_title
;
 Assembly of Silver-Organic Frameworks and Discrete Molecules Containing
 Embedded 1,3-Butadiyne-1,4-diide with Ancillary Heteroaromatic N-Donor
 Ligands
;
_journal_issue                   21
_journal_name_full               Organometallics
_journal_page_first              7539
_journal_paper_doi               10.1021/om300838r
_journal_volume                  31
_journal_year                    2012
_chemical_formula_sum            'C43 H29 Ag14 F30 N6 O26'
_chemical_formula_weight         3125.90
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                109.657(2)
_cell_angle_beta                 92.874(2)
_cell_angle_gamma                98.726(2)
_cell_formula_units_Z            1
_cell_length_a                   7.7662(8)
_cell_length_b                   13.7809(13)
_cell_length_c                   18.9613(18)
_cell_measurement_reflns_used    39471
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      55.744
_cell_measurement_theta_min      4.525
_cell_volume                     1877.8(3)
_computing_cell_refinement       SAINT(Bruker,2001)
_computing_data_collection       APEX2(Bruker,2003)
_computing_data_reduction        APEX2(Bruker,2003)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0800
_diffrn_reflns_av_sigmaI/netI    0.0629
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -4
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            37741
_diffrn_reflns_theta_full        27.92
_diffrn_reflns_theta_max         27.92
_diffrn_reflns_theta_min         2.27
_exptl_absorpt_coefficient_mu    3.710
_exptl_absorpt_correction_T_max  0.5548
_exptl_absorpt_correction_T_min  0.5241
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.764
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1465
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.15
_refine_diff_density_max         3.650
_refine_diff_density_min         -1.654
_refine_diff_density_rms         0.213
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.959
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     562
_refine_ls_number_reflns         8937
_refine_ls_number_restraints     48
_refine_ls_restrained_S_all      0.956
_refine_ls_R_factor_all          0.0856
_refine_ls_R_factor_gt           0.0678
_refine_ls_shift/su_max          0.026
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1220P)²+11.0886P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1837
_refine_ls_wR_factor_ref         0.2083
_reflns_number_gt                6788
_reflns_number_total             8937
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om300838r_si_002.cif
_cod_data_source_block           4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4079567
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag -0.2276(5) 0.4523(2) 0.60821(19) 0.0543(5) Uani 0.50 1 d P . .
Ag2 Ag 0.04348(12) 0.73424(6) 0.67153(4) 0.0694(2) Uani 1 1 d . . .
Ag3 Ag 0.11773(11) 0.56587(7) 0.71403(4) 0.0729(3) Uani 1 1 d . . .
Ag4 Ag 0.36991(9) 0.66439(5) 0.62256(4) 0.05094(18) Uani 1 1 d . . .
Ag5 Ag 0.50322(11) 0.54644(6) 0.71781(4) 0.0651(2) Uani 1 1 d . . .
Ag6 Ag 0.35288(12) 0.35290(6) 0.62004(5) 0.0721(3) Uani 1 1 d . . .
Ag7 Ag 0.10332(10) 1.00213(5) 0.81676(4) 0.05646(19) Uani 1 1 d . . .
Ag1' Ag -0.2258(6) 0.4853(4) 0.6192(3) 0.1141(18) Uani 0.50 1 d P . .
C1 C 0.0419(10) 0.5685(6) 0.6064(4) 0.0447(15) Uani 1 1 d . . .
C2 C 0.0099(9) 0.5232(6) 0.5383(4) 0.0405(14) Uani 1 1 d . . .
C3 C 0.4727(10) 0.4890(6) 0.5971(4) 0.0419(15) Uani 1 1 d . . .
C4 C 0.4918(9) 0.4988(5) 0.5351(4) 0.0346(12) Uani 1 1 d . . .
C5 C -0.2490(11) 0.8569(7) 0.6794(5) 0.0521(18) Uani 1 1 d . . .
C6 C -0.3353(15) 0.9532(10) 0.6933(7) 0.074(3) Uani 1 1 d . . .
C7 C 0.3846(11) 0.8217(6) 0.7986(5) 0.0490(17) Uani 1 1 d . . .
C8 C 0.4849(13) 0.8842(9) 0.8761(6) 0.067(2) Uani 1 1 d . . .
C9 C 0.2418(12) 0.7825(6) 0.5255(5) 0.0514(18) Uani 1 1 d . . .
C10 C 0.2628(18) 0.8422(9) 0.4694(7) 0.075(3) Uani 1 1 d . . .
C11 C 0.3149(15) 0.5849(9) 0.8616(5) 0.069(3) Uani 1 1 d . A .
C12 C 0.308(2) 0.5861(12) 0.9436(9) 0.094(4) Uani 1 1 d U . .
C13 C -0.1302(17) 0.3856(9) 0.7405(7) 0.078(3) Uani 1 1 d . A .
C14 C -0.156(4) 0.3299(17) 0.7975(13) 0.136(7) Uani 1 1 d . . .
C15 C 0.0463(12) 0.9191(7) 0.9491(5) 0.055(2) Uani 1 1 d . . .
H15 H 0.0775 0.8605 0.9142 0.066 Uiso 1 1 calc R . .
C16 C -0.0182(13) 1.0825(7) 0.9790(6) 0.061(2) Uani 1 1 d . . .
C17 C -0.062(3) 1.1613(18) 0.9491(13) 0.075(6) Uani 0.50 1 d P . .
H17A H -0.0710 1.1338 0.8951 0.112 Uiso 0.50 1 calc PR . .
H17B H 0.0280 1.2226 0.9676 0.112 Uiso 0.50 1 calc PR . .
H17C H -0.1719 1.1796 0.9649 0.112 Uiso 0.50 1 calc PR . .
C18 C 0.338(2) 0.2655(8) 0.7504(6) 0.092(5) Uani 1 1 d . . .
H18 H 0.3972 0.3333 0.7767 0.111 Uiso 1 1 calc R . .
C19 C 0.2964(18) 0.2007(9) 0.7896(6) 0.082(4) Uani 1 1 d . . .
C20 C 0.1823(12) 0.0722(6) 0.6793(5) 0.0534(19) Uani 1 1 d . . .
H20 H 0.1265 0.0040 0.6521 0.064 Uiso 1 1 calc R . .
C21 C 0.2269(12) 0.1388(7) 0.6414(5) 0.0546(19) Uani 1 1 d . . .
H21 H 0.2049 0.1142 0.5892 0.066 Uiso 1 1 calc R . .
C22 C 0.346(3) 0.2354(13) 0.8726(8) 0.179(13) Uani 1 1 d . . .
H22A H 0.4296 0.2995 0.8886 0.269 Uiso 1 1 calc R . .
H22B H 0.3961 0.1825 0.8842 0.269 Uiso 1 1 calc R . .
H22C H 0.2432 0.2467 0.8983 0.269 Uiso 1 1 calc R . .
F1 F -0.318(2) 1.0120(9) 0.7640(7) 0.167(5) Uani 1 1 d . . .
F2 F -0.5017(13) 0.9306(9) 0.6763(9) 0.160(5) Uani 1 1 d . . .
F3 F -0.2679(18) 1.0094(9) 0.6569(9) 0.163(5) Uani 1 1 d . . .
F4 F 0.4617(14) 0.9801(7) 0.9026(5) 0.133(4) Uani 1 1 d . . .
F5 F 0.4253(15) 0.8477(11) 0.9274(5) 0.147(4) Uani 1 1 d . . .
F6 F 0.6528(9) 0.8856(9) 0.8775(5) 0.134(4) Uani 1 1 d . . .
F7 F 0.229(3) 0.9306(9) 0.4944(8) 0.260(12) Uani 1 1 d . . .
F8 F 0.1287(19) 0.8023(15) 0.4159(8) 0.189(6) Uani 1 1 d . . .
F9 F 0.381(2) 0.8275(13) 0.4297(9) 0.194(7) Uani 1 1 d . . .
F10 F 0.433(3) 0.555(2) 0.9710(13) 0.131(5) Uani 0.499(10) 1 d PU A 1
F11 F 0.343(4) 0.684(2) 0.9902(14) 0.138(5) Uani 0.499(10) 1 d PU A 1
F12 F 0.148(3) 0.5597(17) 0.9603(12) 0.119(4) Uani 0.499(10) 1 d PU A 1
F10' F 0.204(3) 0.641(2) 0.9799(13) 0.131(5) Uani 0.501(10) 1 d PU A 2
F11' F 0.475(3) 0.635(2) 0.9793(14) 0.138(5) Uani 0.501(10) 1 d PU A 2
F12' F 0.299(3) 0.4905(17) 0.9453(12) 0.119(4) Uani 0.501(10) 1 d PU A 2
F13 F -0.234(3) 0.3804(14) 0.8513(8) 0.232(10) Uani 1 1 d . . .
F14 F -0.029(3) 0.312(3) 0.8240(17) 0.342(19) Uani 1 1 d . . .
F15 F -0.260(4) 0.2405(12) 0.7670(11) 0.258(12) Uani 1 1 d . . .
N1 N 0.2152(9) 0.1005(5) 0.7532(4) 0.0509(15) Uani 1 1 d . . .
N2 N 0.3004(12) 0.2374(6) 0.6771(5) 0.063(2) Uani 1 1 d . . .
N3 N 0.0306(9) 1.0004(6) 0.9286(4) 0.0505(15) Uani 1 1 d . . .
O1 O -0.1040(9) 0.8720(5) 0.7149(4) 0.0704(19) Uani 1 1 d . . .
O2 O -0.3249(9) 0.7742(6) 0.6315(4) 0.0681(18) Uani 1 1 d . . .
O3 O 0.2354(8) 0.8390(5) 0.7886(3) 0.0573(15) Uani 1 1 d . . .
O4 O 0.4640(8) 0.7600(5) 0.7558(4) 0.0590(15) Uani 1 1 d . . .
O5 O 0.1411(12) 0.8112(6) 0.5715(5) 0.079(2) Uani 1 1 d . . .
O6 O 0.3270(10) 0.7106(5) 0.5146(4) 0.0648(16) Uani 1 1 d . . .
O7 O 0.1858(12) 0.6098(8) 0.8366(4) 0.090(3) Uani 1 1 d . . .
O8 O 0.4424(11) 0.5555(7) 0.8327(4) 0.075(2) Uani 1 1 d . . .
O9 O -0.2528(12) 0.4090(8) 0.7145(5) 0.088(2) Uani 1 1 d . . .
O10 O 0.0280(16) 0.3993(9) 0.7263(7) 0.115(3) Uani 1 1 d U . .
O1W O 0.7813(9) 0.6726(6) 0.7684(5) 0.0745(19) Uani 1 1 d . . .
H1WA H 0.8414 0.6529 0.7980 0.112 Uiso 1 1 d R A .
H1WB H 0.7583 0.7327 0.7922 0.112 Uiso 1 1 d R . .
O2W O 0.2184(15) 0.2289(10) 0.5041(5) 0.125(4) Uani 1 1 d . . .
H2WA H 0.1247 0.2461 0.4910 0.187 Uiso 1 1 d R . .
H2WB H 0.2886 0.2263 0.4708 0.187 Uiso 1 1 d R . .
O3W O 0.8322(19) 0.6423(11) 0.9020(8) 0.140(5) Uani 1 1 d . . .
H3WA H 0.9312 0.6691 0.8933 0.209 Uiso 1 1 d R . .
H3WB H 0.7259 0.6190 0.8835 0.209 Uiso 1 1 d R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O9 Ag1 C1 116.5(3) . .
O9 Ag1 C3 96.3(3) . 1_455
C1 Ag1 C3 125.6(3) . 1_455
O9 Ag1 C2 140.0(3) . .
C1 Ag1 C2 28.0(2) . .
C3 Ag1 C2 119.6(3) 1_455 .
O9 Ag1 Ag3 74.1(3) . .
C1 Ag1 Ag3 42.4(2) . .
C3 Ag1 Ag3 135.5(2) 1_455 .
C2 Ag1 Ag3 68.08(18) . .
O9 Ag1 Ag5 61.4(2) . 1_455
C1 Ag1 Ag5 118.0(2) . 1_455
C3 Ag1 Ag5 42.98(18) 1_455 1_455
C2 Ag1 Ag5 136.0(2) . 1_455
Ag3 Ag1 Ag5 98.68(8) . 1_455
C1 Ag2 O1 150.0(3) . .
C1 Ag2 O3 125.3(3) . .
O1 Ag2 O3 80.6(2) . .
C1 Ag2 O5 98.1(3) . .
O1 Ag2 O5 86.8(3) . .
O3 Ag2 O5 106.3(3) . .
C1 Ag2 Ag3 47.6(2) . .
O1 Ag2 Ag3 137.9(2) . .
O3 Ag2 Ag3 82.49(16) . .
O5 Ag2 Ag3 135.08(17) . .
C1 Ag2 Ag4 59.9(2) . .
O1 Ag2 Ag4 147.5(2) . .
O3 Ag2 Ag4 82.49(14) . .
O5 Ag2 Ag4 71.67(18) . .
Ag3 Ag2 Ag4 65.88(3) . .
C1 Ag3 O7 163.6(3) . .
C1 Ag3 O10 113.3(4) . .
O7 Ag3 O10 80.7(4) . .
C1 Ag3 Ag2 50.4(2) . .
O7 Ag3 Ag2 113.3(3) . .
O10 Ag3 Ag2 150.9(3) . .
C1 Ag3 Ag1' 49.8(2) . .
O7 Ag3 Ag1' 131.3(3) . .
O10 Ag3 Ag1' 76.9(3) . .
Ag2 Ag3 Ag1' 74.85(11) . .
C1 Ag3 Ag5 106.6(2) . .
O7 Ag3 Ag5 79.9(2) . .
O10 Ag3 Ag5 93.1(3) . .
Ag2 Ag3 Ag5 113.92(4) . .
Ag1' Ag3 Ag5 143.40(10) . .
C1 Ag3 Ag1 51.4(2) . .
O7 Ag3 Ag1 132.5(3) . .
O10 Ag3 Ag1 71.0(3) . .
Ag2 Ag3 Ag1 81.43(7) . .
Ag1' Ag3 Ag1 7.62(14) . .
Ag5 Ag3 Ag1 137.28(7) . .
C1 Ag3 Ag4 56.5(2) . .
O7 Ag3 Ag4 119.0(3) . .
O10 Ag3 Ag4 138.4(3) . .
Ag2 Ag3 Ag4 58.68(3) . .
Ag1' Ag3 Ag4 106.29(10) . .
Ag5 Ag3 Ag4 59.06(2) . .
Ag1 Ag3 Ag4 107.34(8) . .
O6 Ag4 O4 135.4(2) . .
O6 Ag4 C3 114.4(2) . .
O4 Ag4 C3 104.2(2) . .
O6 Ag4 O2 81.2(2) . 1_655
O4 Ag4 O2 72.9(2) . 1_655
C3 Ag4 O2 96.3(2) . 1_655
O6 Ag4 C1 92.8(3) . .
O4 Ag4 C1 109.3(2) . .
C3 Ag4 C1 89.8(2) . .
O2 Ag4 C1 172.7(3) 1_655 .
O6 Ag4 Ag2 89.44(17) . .
O4 Ag4 Ag2 80.17(15) . .
C3 Ag4 Ag2 132.14(17) . .
O2 Ag4 Ag2 129.22(17) 1_655 .
C1 Ag4 Ag2 46.14(17) . .
O6 Ag4 Ag5 157.13(17) . .
O4 Ag4 Ag5 61.56(16) . .
C3 Ag4 Ag5 43.91(16) . .
O2 Ag4 Ag5 92.96(18) 1_655 .
C1 Ag4 Ag5 94.14(18) . .
Ag2 Ag4 Ag5 110.90(3) . .
O6 Ag4 Ag3 133.81(18) . .
O4 Ag4 Ag3 72.67(17) . .
C3 Ag4 Ag3 79.96(17) . .
O2 Ag4 Ag3 143.22(16) 1_655 .
C1 Ag4 Ag3 41.79(17) . .
Ag2 Ag4 Ag3 55.44(3) . .
Ag5 Ag4 Ag3 59.06(3) . .
C3 Ag5 O8 157.1(3) . .
C3 Ag5 O1W 111.1(3) . .
O8 Ag5 O1W 91.6(3) . .
C3 Ag5 Ag6 50.8(2) . .
O8 Ag5 Ag6 108.0(2) . .
O1W Ag5 Ag6 145.35(18) . .
C3 Ag5 Ag1' 53.2(2) . 1_655
O8 Ag5 Ag1' 138.6(2) . 1_655
O1W Ag5 Ag1' 70.0(2) . 1_655
Ag6 Ag5 Ag1' 76.61(10) . 1_655
C3 Ag5 Ag4 55.91(19) . .
O8 Ag5 Ag4 127.9(2) . .
O1W Ag5 Ag4 94.73(19) . .
Ag6 Ag5 Ag4 94.97(3) . .
Ag1' Ag5 Ag4 91.40(11) 1_655 .
C3 Ag5 Ag3 88.65(19) . .
O8 Ag5 Ag3 77.2(2) . .
O1W Ag5 Ag3 134.18(17) . .
Ag6 Ag5 Ag3 79.09(4) . .
Ag1' Ag5 Ag3 141.85(10) 1_655 .
Ag4 Ag5 Ag3 61.88(2) . .
C3 Ag5 Ag1 51.8(2) . 1_655
O8 Ag5 Ag1 136.6(2) . 1_655
O1W Ag5 Ag1 75.86(19) . 1_655
Ag6 Ag5 Ag1 70.23(7) . 1_655
Ag1' Ag5 Ag1 7.05(15) 1_655 1_655
Ag4 Ag5 Ag1 94.87(8) . 1_655
Ag3 Ag5 Ag1 139.72(7) . 1_655
C3 Ag6 N2 160.1(3) . .
C3 Ag6 O2W 106.8(3) . .
N2 Ag6 O2W 91.5(4) . .
C3 Ag6 Ag5 50.5(2) . .
N2 Ag6 Ag5 112.2(2) . .
O2W Ag6 Ag5 156.0(3) . .
N1 Ag7 N3 145.5(3) 1_565 .
N1 Ag7 O1 98.4(3) 1_565 .
N3 Ag7 O1 110.6(3) . .
N1 Ag7 O3 111.1(3) 1_565 .
N3 Ag7 O3 93.8(2) . .
O1 Ag7 O3 76.8(2) . .
C1 Ag1' C3 139.9(4) . 1_455
C1 Ag1' O9 119.6(4) . .
C3 Ag1' O9 96.8(3) 1_455 .
C1 Ag1' C2 28.7(3) . .
C3 Ag1' C2 125.2(3) 1_455 .
O9 Ag1' C2 137.0(3) . .
C1 Ag1' Ag5 134.1(3) . 1_455
C3 Ag1' Ag5 46.4(2) 1_455 1_455
O9 Ag1' Ag5 64.5(2) . 1_455
C2 Ag1' Ag5 152.1(3) . 1_455
C1 Ag1' Ag3 44.9(2) . .
C3 Ag1' Ag3 151.2(3) 1_455 .
O9 Ag1' Ag3 75.9(3) . .
C2 Ag1' Ag3 70.93(18) . .
Ag5 Ag1' Ag3 107.23(17) 1_455 .
C2 C1 Ag3 149.7(7) . .
C2 C1 Ag2 128.3(6) . .
Ag3 C1 Ag2 82.0(3) . .
C2 C1 Ag1' 88.0(5) . .
Ag3 C1 Ag1' 85.3(3) . .
Ag2 C1 Ag1' 103.9(3) . .
C2 C1 Ag1 82.5(5) . .
Ag3 C1 Ag1 86.2(3) . .
Ag2 C1 Ag1 113.5(3) . .
Ag1' C1 Ag1 9.68(18) . .
C2 C1 Ag4 103.5(5) . .
Ag3 C1 Ag4 81.7(2) . .
Ag2 C1 Ag4 74.0(2) . .
Ag1' C1 Ag4 167.0(4) . .
Ag1 C1 Ag4 164.8(4) . .
C1 C2 C2 174.6(10) . 2_566
C1 C2 Ag1' 63.4(5) . .
C2 C2 Ag1' 122.0(7) 2_566 .
C1 C2 Ag1 69.5(5) . .
C2 C2 Ag1 115.7(7) 2_566 .
Ag1' C2 Ag1 9.57(16) . .
C4 C3 Ag5 152.8(6) . .
C4 C3 Ag6 128.4(6) . .
Ag5 C3 Ag6 78.7(2) . .
C4 C3 Ag1' 92.0(5) . 1_655
Ag5 C3 Ag1' 80.4(3) . 1_655
Ag6 C3 Ag1' 101.3(3) . 1_655
C4 C3 Ag1 91.5(5) . 1_655
Ag5 C3 Ag1 85.3(3) . 1_655
Ag6 C3 Ag1 93.9(3) . 1_655
Ag1' C3 Ag1 9.92(17) 1_655 1_655
C4 C3 Ag4 81.2(4) . .
Ag5 C3 Ag4 80.2(2) . .
Ag6 C3 Ag4 129.1(3) . .
Ag1' C3 Ag4 119.9(3) 1_655 .
Ag1 C3 Ag4 129.6(3) 1_655 .
C3 C4 C4 175.5(9) . 2_666
O1 C5 O2 126.6(9) . .
O1 C5 C6 115.7(9) . .
O2 C5 C6 117.5(9) . .
F2 C6 F1 102.8(13) . .
F2 C6 F3 109.5(12) . .
F1 C6 F3 107.6(13) . .
F2 C6 C5 113.3(10) . .
F1 C6 C5 112.8(10) . .
F3 C6 C5 110.4(10) . .
O4 C7 O3 129.5(8) . .
O4 C7 C8 114.7(8) . .
O3 C7 C8 115.8(7) . .
F4 C8 F6 107.5(11) . .
F4 C8 F5 101.6(11) . .
F6 C8 F5 108.9(11) . .
F4 C8 C7 113.9(9) . .
F6 C8 C7 113.3(8) . .
F5 C8 C7 111.0(9) . .
O5 C9 O6 130.1(9) . .
O5 C9 C10 115.1(8) . .
O6 C9 C10 114.8(8) . .
F9 C10 F7 118.7(14) . .
F9 C10 F8 98.6(14) . .
F7 C10 F8 96.7(15) . .
F9 C10 C9 117.4(10) . .
F7 C10 C9 113.1(10) . .
F8 C10 C9 108.0(11) . .
O7 C11 O8 131.5(9) . .
O7 C11 C12 114.0(11) . .
O8 C11 C12 114.4(10) . .
F10 C12 F10' 127(2) . .
F10 C12 F12 117.6(19) . .
F10' C12 F12 48.6(13) . .
F10 C12 F11 96.9(19) . .
F10' C12 F11 51.3(15) . .
F12 C12 F11 98.4(17) . .
F10 C12 F12' 56.0(15) . .
F10' C12 F12' 117.4(19) . .
F12 C12 F12' 74.2(15) . .
F11 C12 F12' 139.3(19) . .
F10 C12 F11' 46.5(14) . .
F10' C12 F11' 106(2) . .
F12 C12 F11' 139.8(19) . .
F11 C12 F11' 57.6(15) . .
F12' C12 F11' 102.4(17) . .
F10 C12 C11 117.0(16) . .
F10' C12 C11 114.1(16) . .
F12 C12 C11 113.9(15) . .
F11 C12 C11 109.1(16) . .
F12' C12 C11 110.4(15) . .
F11' C12 C11 104.8(15) . .
O9 C13 O10 128.2(12) . .
O9 C13 C14 119.3(15) . .
O10 C13 C14 112.5(14) . .
F14 C14 F13 108(3) . .
F14 C14 F15 106(2) . .
F13 C14 F15 104(3) . .
F14 C14 C13 117(2) . .
F13 C14 C13 111.1(16) . .
F15 C14 C13 110.3(18) . .
N3 C15 C16 122.9(8) . 2_577
N3 C15 H15 118.6 . .
C16 C15 H15 118.6 2_577 .
N3 C16 C15 119.6(8) . 2_577
N3 C16 C17 114.7(11) . .
C15 C16 C17 125.1(11) 2_577 .
C16 C17 H17A 109.5 . .
C16 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C16 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
N2 C18 C19 123.5(9) . .
N2 C18 H18 118.3 . .
C19 C18 H18 118.3 . .
C18 C19 N1 120.1(9) . .
C18 C19 C22 121.5(10) . .
N1 C19 C22 118.3(9) . .
N1 C20 C21 122.6(8) . .
N1 C20 H20 118.7 . .
C21 C20 H20 118.7 . .
N2 C21 C20 121.5(8) . .
N2 C21 H21 119.2 . .
C20 C21 H21 119.2 . .
C19 C22 H22A 109.5 . .
C19 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C19 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C20 N1 C19 115.9(7) . .
C20 N1 Ag7 122.5(5) . 1_545
C19 N1 Ag7 120.7(6) . 1_545
C18 N2 C21 116.2(8) . .
C18 N2 Ag6 120.6(6) . .
C21 N2 Ag6 123.2(6) . .
C15 N3 C16 117.6(7) . .
C15 N3 Ag7 120.3(6) . .
C16 N3 Ag7 122.0(6) . .
C5 O1 Ag2 113.3(6) . .
C5 O1 Ag7 143.2(6) . .
Ag2 O1 Ag7 103.4(2) . .
C5 O2 Ag4 131.2(6) . 1_455
C7 O3 Ag2 120.4(5) . .
C7 O3 Ag7 134.4(6) . .
Ag2 O3 Ag7 97.0(2) . .
C7 O4 Ag4 125.0(6) . .
C9 O5 Ag2 128.3(6) . .
C9 O6 Ag4 112.4(6) . .
C11 O7 Ag3 121.1(7) . .
C11 O8 Ag5 125.5(7) . .
C13 O9 Ag1 118.6(9) . .
C13 O9 Ag1' 121.2(9) . .
Ag1 O9 Ag1' 10.35(17) . .
C13 O10 Ag3 112.3(9) . .
Ag5 O1W H1WA 109.9 . .
Ag5 O1W H1WB 109.2 . .
H1WA O1W H1WB 109.5 . .
Ag6 O2W H2WA 110.2 . .
Ag6 O2W H2WB 109.1 . .
H2WA O2W H2WB 109.5 . .
H3WA O3W H3WB 143.2 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 O9 2.295(10) .
Ag1 C1 2.444(8) .
Ag1 C3 2.469(8) 1_455
Ag1 C2 2.586(8) .
Ag1 Ag3 3.122(4) .
Ag1 Ag5 3.133(4) 1_455
Ag2 C1 2.199(8) .
Ag2 O1 2.301(6) .
Ag2 O3 2.468(6) .
Ag2 O5 2.560(8) .
Ag2 Ag3 2.8254(12) .
Ag2 Ag4 2.9310(11) .
Ag3 C1 2.109(8) .
Ag3 O7 2.209(7) .
Ag3 O10 2.388(12) .
Ag3 Ag1' 2.977(5) .
Ag3 Ag5 3.0454(13) .
Ag3 Ag4 3.1313(10) .
Ag4 O6 2.363(7) .
Ag4 O4 2.436(6) .
Ag4 C3 2.559(7) .
Ag4 O2 2.576(7) 1_655
Ag4 C1 2.638(8) .
Ag4 Ag5 3.0453(10) .
Ag5 C3 2.143(7) .
Ag5 O8 2.219(7) .
Ag5 O1W 2.478(8) .
Ag5 Ag6 2.7249(11) .
Ag5 Ag1' 2.917(5) 1_655
Ag5 Ag1 3.133(4) 1_655
Ag6 C3 2.153(8) .
Ag6 N2 2.208(7) .
Ag6 O2W 2.355(10) .
Ag7 N1 2.212(7) 1_565
Ag7 N3 2.229(7) .
Ag7 O1 2.454(7) .
Ag7 O3 2.517(6) .
Ag1' C1 2.282(9) .
Ag1' C3 2.369(8) 1_455
Ag1' O9 2.380(10) .
Ag1' C2 2.551(9) .
Ag1' Ag5 2.917(5) 1_455
C1 C2 1.224(11) .
C2 C2 1.365(14) 2_566
C3 C4 1.240(10) .
C3 Ag1' 2.369(8) 1_655
C3 Ag1 2.469(8) 1_655
C4 C4 1.355(13) 2_666
C5 O1 1.233(11) .
C5 O2 1.232(11) .
C5 C6 1.527(14) .
C6 F2 1.281(15) .
C6 F1 1.301(17) .
C6 F3 1.273(15) .
C7 O4 1.227(10) .
C7 O3 1.237(10) .
C7 C8 1.529(13) .
C8 F4 1.291(14) .
C8 F6 1.300(12) .
C8 F5 1.311(16) .
C9 O5 1.208(11) .
C9 O6 1.241(10) .
C9 C10 1.548(13) .
C10 F9 1.214(15) .
C10 F7 1.226(14) .
C10 F8 1.326(19) .
C11 O7 1.231(13) .
C11 O8 1.213(13) .
C11 C12 1.551(18) .
C12 F10 1.27(3) .
C12 F10' 1.26(3) .
C12 F12 1.33(2) .
C12 F11 1.32(3) .
C12 F12' 1.32(2) .
C12 F11' 1.39(3) .
C13 O9 1.186(14) .
C13 O10 1.270(17) .
C13 C14 1.53(2) .
C14 F14 1.18(3) .
C14 F13 1.26(3) .
C14 F15 1.30(3) .
C15 N3 1.323(11) .
C15 C16 1.399(12) 2_577
C15 H15 0.9300 .
C16 N3 1.333(11) .
C16 C15 1.399(12) 2_577
C16 C17 1.46(2) .
C17 H17A 0.9600 .
C17 H17B 0.9600 .
C17 H17C 0.9600 .
C18 N2 1.316(13) .
C18 C19 1.356(15) .
C18 H18 0.9300 .
C19 N1 1.354(12) .
C19 C22 1.492(15) .
C20 N1 1.322(11) .
C20 C21 1.359(12) .
C20 H20 0.9300 .
C21 N2 1.319(12) .
C21 H21 0.9300 .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
N1 Ag7 2.212(7) 1_545
O2 Ag4 2.576(7) 1_455
O1W H1WA 0.8499 .
O1W H1WB 0.8500 .
O2W H2WA 0.8499 .
O2W H2WB 0.8500 .
O3W H3WA 0.8500 .
O3W H3WB 0.8499 .
