#------------------------------------------------------------------------------
#$Date: 2016-03-21 11:16:47 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178686 $
#$URL: svn://www.crystallography.net/cod/cif/4/07/97/4079760.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4079760
loop_
_publ_author_name
'Adams, Richard D.'
'Kan, Yuwei'
'Zhang, Qiang'
_publ_section_title
;
 Osmium--Germanium and Osmium--Germanium--Gold Carbonyl Cluster Complexes:
 Syntheses, Structures, Bonding, and Reactivity
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              8639
_journal_paper_doi               10.1021/om301074w
_journal_volume                  31
_journal_year                    2012
_chemical_formula_sum            'C49 H37 Au Ge O10 Os3 P'
_chemical_formula_weight         1656.91
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 105.2990(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   25.6478(7)
_cell_length_b                   13.3284(4)
_cell_length_c                   31.3682(9)
_cell_measurement_reflns_used    9050
_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      24.56
_cell_measurement_theta_min      2.33
_cell_volume                     10343.0(5)
_computing_cell_refinement       'SAINT+  V6.45 (Bruker, 2003)'
_computing_data_collection       'SMART V5.632 (Bruker, 2005)'
_computing_data_reduction        'SAINT+  V6.45'
_computing_molecular_graphics    'SHELXTL V6.1 (Sheldrick, 2000)'
_computing_publication_material  'SHELXTL V6.1'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART APEX CCD diffractometer'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0696
_diffrn_reflns_av_sigmaI/netI    0.0427
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_number            62788
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         1.74
_diffrn_standards_decay_%        <1
_exptl_absorpt_coefficient_mu    10.829
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.628
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS, Bruker, 1997)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.128
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             6120
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.332
_refine_diff_density_min         -0.735
_refine_diff_density_rms         0.135
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.072
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     572
_refine_ls_number_reflns         9143
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.072
_refine_ls_R_factor_all          0.0585
_refine_ls_R_factor_gt           0.0397
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0329P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0747
_refine_ls_wR_factor_ref         0.0810
_reflns_number_gt                7237
_reflns_number_total             9143
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om301074w_si_001.cif
_cod_data_source_block           4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-Scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               4079760
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Au1 Au 0.075925(13) 0.68904(3) 0.094895(12) 0.05210(11) Uani 1 1 d .
Os1 Os 0.174799(13) 0.65033(3) 0.085812(11) 0.04379(10) Uani 1 1 d .
Os2 Os 0.270393(13) 0.68222(2) 0.156306(11) 0.04406(10) Uani 1 1 d .
Os3 Os 0.280302(13) 0.58610(3) 0.080745(11) 0.04580(10) Uani 1 1 d .
Ge1 Ge 0.17143(4) 0.71909(7) 0.15926(3) 0.0455(2) Uani 1 1 d .
P1 P -0.01241(9) 0.6908(2) 0.09696(8) 0.0577(6) Uani 1 1 d .
C1 C 0.2726(3) 0.4826(6) 0.1277(3) 0.044(2) Uani 1 1 d .
C2 C 0.2715(3) 0.3709(6) 0.1273(3) 0.047(2) Uani 1 1 d .
C3 C 0.2810(3) 0.3211(6) 0.0916(3) 0.054(2) Uani 1 1 d .
H3 H 0.2871 0.3569 0.0680 0.065 Uiso 1 1 calc R
C4 C 0.2814(4) 0.2146(8) 0.0912(4) 0.074(3) Uani 1 1 d .
H4 H 0.2876 0.1803 0.0672 0.089 Uiso 1 1 calc R
C5 C 0.2725(5) 0.1627(8) 0.1263(5) 0.092(4) Uani 1 1 d .
H5 H 0.2728 0.0929 0.1263 0.110 Uiso 1 1 calc R
C6 C 0.2634(5) 0.2133(8) 0.1608(4) 0.089(4) Uani 1 1 d .
H6 H 0.2572 0.1774 0.1844 0.107 Uiso 1 1 calc R
C7 C 0.2630(4) 0.3178(7) 0.1622(3) 0.066(3) Uani 1 1 d .
H7 H 0.2570 0.3510 0.1866 0.079 Uiso 1 1 calc R
C11 C 0.1619(3) 0.5208(7) 0.1092(3) 0.050(2) Uani 1 1 d .
C12 C 0.1295(4) 0.6127(7) 0.0305(3) 0.062(3) Uani 1 1 d .
C13 C 0.1837(3) 0.7808(7) 0.0610(3) 0.053(2) Uani 1 1 d .
C21 C 0.2831(4) 0.7159(7) 0.2167(3) 0.062(3) Uani 1 1 d .
C22 C 0.2742(3) 0.8183(7) 0.1425(3) 0.055(2) Uani 1 1 d .
C23 C 0.3442(4) 0.6590(7) 0.1520(4) 0.064(3) Uani 1 1 d .
C31 C 0.2389(4) 0.5189(7) 0.0300(3) 0.059(2) Uani 1 1 d .
C32 C 0.3475(4) 0.5302(8) 0.0788(3) 0.065(3) Uani 1 1 d .
C33 C 0.2920(3) 0.7101(7) 0.0514(3) 0.054(2) Uani 1 1 d .
C34 C 0.1502(4) 0.6435(7) 0.2048(3) 0.055(2) Uani 1 1 d .
C35 C 0.1772(5) 0.5570(7) 0.2230(3) 0.073(3) Uani 1 1 d .
H35 H 0.2070 0.5350 0.2140 0.087 Uiso 1 1 calc R
C36 C 0.1601(7) 0.5034(9) 0.2546(4) 0.113(5) Uani 1 1 d .
H36 H 0.1784 0.4452 0.2662 0.136 Uiso 1 1 calc R
C37 C 0.1169(7) 0.5337(12) 0.2692(5) 0.128(6) Uani 1 1 d .
H37 H 0.1069 0.4977 0.2912 0.154 Uiso 1 1 calc R
C38 C 0.0885(6) 0.6174(11) 0.2512(4) 0.102(4) Uani 1 1 d .
H38 H 0.0583 0.6376 0.2601 0.123 Uiso 1 1 calc R
C39 C 0.1056(4) 0.6715(8) 0.2197(3) 0.073(3) Uani 1 1 d .
H39 H 0.0865 0.7288 0.2079 0.088 Uiso 1 1 calc R
C40 C 0.1587(3) 0.8596(6) 0.1703(3) 0.050(2) Uani 1 1 d .
C41 C 0.1665(4) 0.8945(8) 0.2129(3) 0.074(3) Uani 1 1 d .
H41 H 0.1786 0.8504 0.2364 0.089 Uiso 1 1 calc R
C42 C 0.1567(5) 0.9948(9) 0.2216(4) 0.097(4) Uani 1 1 d .
H42 H 0.1617 1.0180 0.2504 0.116 Uiso 1 1 calc R
C43 C 0.1392(5) 1.0589(9) 0.1852(5) 0.102(4) Uani 1 1 d .
H43 H 0.1323 1.1260 0.1900 0.123 Uiso 1 1 calc R
C44 C 0.1318(5) 1.0248(8) 0.1423(4) 0.095(4) Uani 1 1 d .
H44 H 0.1215 1.0686 0.1184 0.114 Uiso 1 1 calc R
C45 C 0.1397(4) 0.9283(8) 0.1360(4) 0.074(3) Uani 1 1 d .
H45 H 0.1322 0.9049 0.1071 0.089 Uiso 1 1 calc R
C46 C -0.0284(4) 0.7808(7) 0.1339(3) 0.057(2) Uani 1 1 d .
C47 C -0.0689(4) 0.7672(9) 0.1547(3) 0.081(3) Uani 1 1 d .
H47 H -0.0894 0.7088 0.1493 0.097 Uiso 1 1 calc R
C48 C -0.0800(5) 0.8374(11) 0.1835(4) 0.089(4) Uani 1 1 d .
H48 H -0.1070 0.8252 0.1977 0.107 Uiso 1 1 calc R
C49 C -0.0510(5) 0.9253(11) 0.1912(4) 0.101(4) Uani 1 1 d .
H49 H -0.0588 0.9735 0.2101 0.121 Uiso 1 1 calc R
C50 C -0.0109(5) 0.9416(9) 0.1710(4) 0.099(4) Uani 1 1 d .
H50 H 0.0094 1.0003 0.1767 0.118 Uiso 1 1 calc R
C51 C -0.0003(4) 0.8718(8) 0.1425(4) 0.078(3) Uani 1 1 d .
H51 H 0.0265 0.8852 0.1283 0.093 Uiso 1 1 calc R
C52 C -0.0303(4) 0.5697(8) 0.1137(3) 0.066(3) Uani 1 1 d .
C53 C 0.0077(6) 0.5162(9) 0.1440(4) 0.106(4) Uani 1 1 d .
H53 H 0.0423 0.5421 0.1549 0.127 Uiso 1 1 calc R
C54 C -0.0054(7) 0.4227(11) 0.1586(6) 0.150(7) Uani 1 1 d .
H54 H 0.0199 0.3874 0.1800 0.180 Uiso 1 1 calc R
C55 C -0.0554(9) 0.3839(15) 0.1411(7) 0.165(9) Uani 1 1 d .
H55 H -0.0624 0.3192 0.1491 0.198 Uiso 1 1 calc R
C56 C -0.0949(8) 0.4337(14) 0.1131(6) 0.139(8) Uani 1 1 d .
H56 H -0.1297 0.4078 0.1036 0.167 Uiso 1 1 calc R
C57 C -0.0813(5) 0.5274(10) 0.0985(4) 0.091(4) Uani 1 1 d .
H57 H -0.1076 0.5625 0.0778 0.109 Uiso 1 1 calc R
C58 C -0.0584(4) 0.7114(8) 0.0432(3) 0.066(3) Uani 1 1 d .
C59 C -0.0474(4) 0.6628(9) 0.0078(4) 0.089(4) Uani 1 1 d .
H59 H -0.0172 0.6219 0.0118 0.107 Uiso 1 1 calc R
C60 C -0.0822(6) 0.6756(11) -0.0341(4) 0.112(5) Uani 1 1 d .
H60 H -0.0746 0.6437 -0.0581 0.134 Uiso 1 1 calc R
C61 C -0.1278(5) 0.7347(12) -0.0408(5) 0.114(5) Uani 1 1 d .
H61 H -0.1512 0.7417 -0.0689 0.136 Uiso 1 1 calc R
C62 C -0.1380(5) 0.7821(12) -0.0058(5) 0.120(5) Uani 1 1 d .
H62 H -0.1684 0.8227 -0.0098 0.144 Uiso 1 1 calc R
C63 C -0.1033(5) 0.7706(10) 0.0361(4) 0.095(4) Uani 1 1 d .
H63 H -0.1108 0.8039 0.0598 0.114 Uiso 1 1 calc R
C1S C 0.0285(10) 0.8331(19) 0.9479(8) 0.289(14) Uiso 1 1 d .
H1S1 H -0.0090 0.8190 0.9348 0.434 Uiso 1 1 calc R
H1S2 H 0.0477 0.7715 0.9566 0.434 Uiso 1 1 calc R
H1S3 H 0.0433 0.8670 0.9267 0.434 Uiso 1 1 calc R
C2S C 0.0343(10) 0.9022(19) 0.9898(8) 0.248(12) Uiso 1 1 d .
H2S1 H 0.0278 0.8636 1.0141 0.297 Uiso 1 1 calc R
H2S2 H 0.0704 0.9304 0.9990 0.297 Uiso 1 1 calc R
C3S C -0.0048(11) 0.980(2) 0.9774(7) 0.244(12) Uiso 1 1 d .
H3S1 H -0.0412 0.9546 0.9657 0.293 Uiso 1 1 calc R
H3S2 H 0.0040 1.0276 0.9570 0.293 Uiso 1 1 calc R
O1 O 0.2687(2) 0.5213(4) 0.16455(18) 0.0479(14) Uani 1 1 d .
O11 O 0.1503(2) 0.4470(5) 0.1225(2) 0.0668(18) Uani 1 1 d .
O12 O 0.1019(3) 0.5898(6) -0.0031(2) 0.101(3) Uani 1 1 d .
O13 O 0.1887(3) 0.8563(5) 0.0448(2) 0.075(2) Uani 1 1 d .
O21 O 0.2920(3) 0.7408(6) 0.2532(2) 0.093(3) Uani 1 1 d .
O22 O 0.2785(3) 0.9017(5) 0.1343(2) 0.078(2) Uani 1 1 d .
O23 O 0.3899(3) 0.6603(6) 0.1605(3) 0.088(2) Uani 1 1 d .
O31 O 0.2166(3) 0.4770(6) -0.0013(2) 0.096(3) Uani 1 1 d .
O32 O 0.3880(3) 0.4976(7) 0.0782(3) 0.108(3) Uani 1 1 d .
O33 O 0.3013(3) 0.7836(5) 0.0372(2) 0.0699(19) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Os Os -1.2165 7.6030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
P1 Au1 Os1 168.57(7) .
P1 Au1 Ge1 132.30(7) .
Os1 Au1 Ge1 54.77(2) .
C12 Os1 C13 88.8(4) .
C12 Os1 C11 89.2(4) .
C13 Os1 C11 177.0(3) .
C12 Os1 Ge1 141.5(3) .
C13 Os1 Ge1 94.4(3) .
C11 Os1 Ge1 85.8(3) .
C12 Os1 Au1 77.1(3) .
C13 Os1 Au1 94.9(2) .
C11 Os1 Au1 82.6(2) .
Ge1 Os1 Au1 64.37(2) .
C12 Os1 Os2 160.8(3) .
C13 Os1 Os2 90.5(2) .
C11 Os1 Os2 92.1(2) .
Ge1 Os1 Os2 57.71(2) .
Au1 Os1 Os2 122.067(16) .
C12 Os1 Os3 103.3(3) .
C13 Os1 Os3 91.9(2) .
C11 Os1 Os3 90.7(2) .
Ge1 Os1 Os3 114.87(2) .
Au1 Os1 Os3 173.262(17) .
Os2 Os1 Os3 57.476(12) .
C22 Os2 C21 89.8(4) .
C22 Os2 C23 91.6(4) .
C21 Os2 C23 101.1(4) .
C22 Os2 O1 172.8(3) .
C21 Os2 O1 96.9(3) .
C23 Os2 O1 84.4(3) .
C22 Os2 Ge1 86.3(3) .
C21 Os2 Ge1 80.3(3) .
C23 Os2 Ge1 177.5(3) .
O1 Os2 Ge1 97.56(14) .
C22 Os2 Os3 103.2(3) .
C21 Os2 Os3 159.9(3) .
C23 Os2 Os3 63.8(3) .
O1 Os2 Os3 69.65(14) .
Ge1 Os2 Os3 115.33(2) .
C22 Os2 Os1 92.9(3) .
C21 Os2 Os1 134.0(3) .
C23 Os2 Os1 124.7(3) .
O1 Os2 Os1 84.54(14) .
Ge1 Os2 Os1 54.11(2) .
Os3 Os2 Os1 61.536(12) .
C32 Os3 C31 95.8(4) .
C32 Os3 C33 93.6(4) .
C31 Os3 C33 97.2(4) .
C32 Os3 C1 91.1(4) .
C31 Os3 C1 98.4(3) .
C33 Os3 C1 163.1(4) .
C32 Os3 C23 78.5(4) .
C31 Os3 C23 173.1(3) .
C33 Os3 C23 87.1(3) .
C1 Os3 C23 78.0(3) .
C32 Os3 Os2 120.0(3) .
C31 Os3 Os2 141.6(3) .
C33 Os3 Os2 94.2(3) .
C1 Os3 Os2 69.5(2) .
C23 Os3 Os2 42.7(2) .
C32 Os3 Os1 174.0(3) .
C31 Os3 Os1 82.0(3) .
C33 Os3 Os1 92.2(3) .
C1 Os3 Os1 83.8(2) .
C23 Os3 Os1 103.3(2) .
Os2 Os3 Os1 60.988(12) .
C34 Ge1 C40 105.9(4) .
C34 Ge1 Os1 125.0(3) .
C40 Ge1 Os1 124.4(3) .
C34 Ge1 Os2 113.1(3) .
C40 Ge1 Os2 113.4(2) .
Os1 Ge1 Os2 68.18(2) .
C34 Ge1 Au1 95.5(3) .
C40 Ge1 Au1 96.4(3) .
Os1 Ge1 Au1 60.87(2) .
Os2 Ge1 Au1 129.04(3) .
C46 P1 C52 107.1(4) .
C46 P1 C58 107.3(5) .
C52 P1 C58 104.9(5) .
C46 P1 Au1 115.1(3) .
C52 P1 Au1 109.4(3) .
C58 P1 Au1 112.5(3) .
O1 C1 C2 113.7(7) .
O1 C1 Os3 114.5(6) .
C2 C1 Os3 131.8(6) .
C7 C2 C3 120.0(8) .
C7 C2 C1 121.1(8) .
C3 C2 C1 118.9(8) .
C2 C3 C4 119.5(9) .
C5 C4 C3 119.8(10) .
C6 C5 C4 119.6(10) .
C5 C6 C7 122.0(11) .
C2 C7 C6 119.2(10) .
O11 C11 Os1 174.7(7) .
O12 C12 Os1 180.0(14) .
O13 C13 Os1 177.3(8) .
O21 C21 Os2 176.7(9) .
O22 C22 Os2 177.5(8) .
O23 C23 Os2 160.4(10) .
O23 C23 Os3 126.1(8) .
Os2 C23 Os3 73.5(3) .
O31 C31 Os3 176.1(9) .
O32 C32 Os3 179.0(11) .
O33 C33 Os3 175.0(9) .
C35 C34 C39 116.7(9) .
C35 C34 Ge1 121.9(7) .
C39 C34 Ge1 121.4(8) .
C36 C35 C34 120.3(11) .
C37 C36 C35 121.7(13) .
C38 C37 C36 119.5(13) .
C37 C38 C39 118.9(13) .
C38 C39 C34 122.7(11) .
C41 C40 C45 117.1(9) .
C41 C40 Ge1 120.7(7) .
C45 C40 Ge1 122.2(7) .
C40 C41 C42 121.7(11) .
C41 C42 C43 117.2(11) .
C44 C43 C42 121.6(11) .
C45 C44 C43 118.3(12) .
C44 C45 C40 123.9(11) .
C47 C46 C51 115.9(10) .
C47 C46 P1 123.3(8) .
C51 C46 P1 120.8(8) .
C48 C47 C46 122.2(11) .
C49 C48 C47 119.7(12) .
C50 C49 C48 119.7(12) .
C49 C50 C51 120.1(12) .
C50 C51 C46 122.4(11) .
C53 C52 C57 117.4(11) .
C53 C52 P1 118.8(8) .
C57 C52 P1 123.8(10) .
C52 C53 C54 120.2(13) .
C55 C54 C53 119.3(17) .
C56 C55 C54 123.4(19) .
C55 C56 C57 116.6(17) .
C52 C57 C56 122.8(14) .
C63 C58 C59 118.8(10) .
C63 C58 P1 123.8(9) .
C59 C58 P1 117.4(8) .
C58 C59 C60 119.2(11) .
C61 C60 C59 121.4(13) .
C62 C61 C60 118.7(13) .
C61 C62 C63 120.3(13) .
C58 C63 C62 121.5(12) .
C3S C2S C1S 107(2) .
C2S C3S C3S 94(2) 5_577
C1 O1 Os2 106.3(5) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 P1 2.284(2) .
Au1 Os1 2.6757(5) .
Au1 Ge1 2.7618(10) .
Os1 C12 1.884(10) .
Os1 C13 1.942(10) .
Os1 C11 1.939(10) .
Os1 Ge1 2.5021(9) .
Os1 Os2 2.8671(5) .
Os1 Os3 2.8822(5) .
Os2 C22 1.874(10) .
Os2 C21 1.891(10) .
Os2 C23 1.957(10) .
Os2 O1 2.162(5) .
Os2 Ge1 2.6107(9) .
Os2 Os3 2.7643(5) .
Os3 C32 1.894(10) .
Os3 C31 1.890(11) .
Os3 C33 1.954(10) .
Os3 C1 2.066(8) .
Os3 C23 2.587(11) .
Ge1 C34 1.940(9) .
Ge1 C40 1.948(9) .
P1 C46 1.789(10) .
P1 C52 1.794(11) .
P1 C58 1.805(10) .
C1 O1 1.293(9) .
C1 C2 1.488(11) .
C2 C7 1.369(12) .
C2 C3 1.377(11) .
C3 C4 1.419(12) .
C4 C5 1.367(14) .
C5 C6 1.348(15) .
C6 C7 1.394(13) .
C11 O11 1.138(10) .
C12 O12 1.146(10) .
C13 O13 1.151(10) .
C21 O21 1.153(10) .
C22 O22 1.153(10) .
C23 O23 1.132(10) .
C31 O31 1.143(10) .
C32 O32 1.129(10) .
C33 O33 1.127(10) .
C34 C35 1.388(13) .
C34 C39 1.395(12) .
C35 C36 1.384(13) .
C36 C37 1.365(17) .
C37 C38 1.370(19) .
C38 C39 1.386(15) .
C40 C41 1.377(12) .
C40 C45 1.399(13) .
C41 C42 1.401(14) .
C42 C43 1.402(16) .
C43 C44 1.387(16) .
C44 C45 1.324(14) .
C46 C47 1.377(13) .
C46 C51 1.400(13) .
C47 C48 1.382(14) .
C48 C49 1.375(16) .
C49 C50 1.360(16) .
C50 C51 1.367(14) .
C52 C53 1.369(14) .
C52 C57 1.389(13) .
C53 C54 1.399(16) .
C54 C55 1.36(2) .
C55 C56 1.33(2) .
C56 C57 1.40(2) .
C58 C63 1.365(13) .
C58 C59 1.377(13) .
C59 C60 1.390(15) .
C60 C61 1.380(17) .
C61 C62 1.351(17) .
C62 C63 1.388(15) .
C1S C2S 1.58(3) .
C2S C3S 1.42(3) .
C3S C3S 1.47(4) 5_577
