#------------------------------------------------------------------------------
#$Date: 2016-03-21 13:12:26 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178693 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/04/4080409.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4080409
loop_
_publ_author_name
'Shuster, Vladimir'
'Gambarotta, Sandro'
'Nikiforov, Grigory B.'
'Budzelaar, Peter H. M.'
_publ_section_title
;
 Heterometallic Aluminum--Chromium Phenazine and Thiophenazine Complexes.
 Formation of a Tetranuclear Chromium(I) Sandwich Complex
;
_journal_issue                   8
_journal_name_full               Organometallics
_journal_page_first              2329
_journal_paper_doi               10.1021/om3012097
_journal_volume                  32
_journal_year                    2013
_chemical_formula_sum            'C44 H72 Cl2 Li4 N2 O8'
_chemical_formula_weight         855.70
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.347(4)
_cell_angle_beta                 102.760(5)
_cell_angle_gamma                109.161(4)
_cell_formula_units_Z            1
_cell_length_a                   10.272(3)
_cell_length_b                   11.348(4)
_cell_length_c                   11.912(4)
_cell_measurement_reflns_used    4344
_cell_measurement_temperature    203(2)
_cell_measurement_theta_max      24.65
_cell_measurement_theta_min      2.23
_cell_volume                     1199.4(7)
_computing_cell_refinement       'APEX II, Bruker (2009)'
_computing_data_collection       'APEX II, Bruker (2009)'
_computing_data_reduction        'XPREP, Bruker (2009)'
_computing_molecular_graphics    'SHELXTL, Bruker (2004)'
_computing_publication_material  'SHELXTL, Bruker (2004)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      203(2)
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0488
_diffrn_reflns_av_sigmaI/netI    0.0658
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            11860
_diffrn_reflns_theta_full        24.78
_diffrn_reflns_theta_max         24.78
_diffrn_reflns_theta_min         1.87
_exptl_absorpt_coefficient_mu    0.185
_exptl_absorpt_correction_T_max  0.9982
_exptl_absorpt_correction_T_min  0.9818
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS, Bruker (2003)'
_exptl_crystal_colour            pink
_exptl_crystal_density_diffrn    1.185
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needles
_exptl_crystal_F_000             460
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.01
_refine_diff_density_max         0.297
_refine_diff_density_min         -0.288
_refine_diff_density_rms         0.051
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     271
_refine_ls_number_reflns         4049
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.025
_refine_ls_R_factor_all          0.1100
_refine_ls_R_factor_gt           0.0548
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0838P)²+0.2539P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1347
_refine_ls_wR_factor_ref         0.1643
_reflns_number_gt                2420
_reflns_number_total             4049
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om3012097_si_001.cif
_cod_data_source_block           sg838
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'n/a' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4080409
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cl1 Cl 0.36432(9) 0.95529(8) 0.22851(8) 0.0437(3) Uani 1 1 d .
Li1 Li 0.2876(6) 0.7364(5) 0.2330(5) 0.0402(13) Uani 1 1 d .
Li2 Li 0.2181(6) 0.7989(5) 0.0294(5) 0.0403(13) Uani 1 1 d .
N1 N 0.1290(3) 0.6244(2) 0.0669(2) 0.0310(6) Uani 1 1 d .
O1 O 0.2185(3) 0.7153(2) 0.3720(2) 0.0564(7) Uani 1 1 d .
O2 O 0.4674(3) 0.7095(2) 0.2821(2) 0.0571(7) Uani 1 1 d .
O3 O 0.0669(2) 0.8305(2) -0.0797(2) 0.0459(6) Uani 1 1 d .
O4 O 0.3462(2) 0.7986(2) -0.0717(2) 0.0460(6) Uani 1 1 d .
C1 C 0.1368(3) 0.5097(3) -0.0043(3) 0.0268(7) Uani 1 1 d .
C2 C 0.2704(3) 0.5109(3) -0.0111(3) 0.0344(8) Uani 1 1 d .
H2A H 0.3548 0.5896 0.0331 0.041 Uiso 1 1 calc R
C3 C 0.2848(4) 0.4005(3) -0.0807(3) 0.0397(8) Uani 1 1 d .
H3A H 0.3770 0.4052 -0.0837 0.048 Uiso 1 1 calc R
C4 C -0.0100(3) 0.6114(3) 0.0708(3) 0.0275(7) Uani 1 1 d .
C5 C -0.0278(3) 0.7203(3) 0.1391(3) 0.0353(8) Uani 1 1 d .
H5A H 0.0550 0.8004 0.1830 0.042 Uiso 1 1 calc R
C6 C -0.1625(4) 0.7154(3) 0.1449(3) 0.0379(8) Uani 1 1 d .
H6A H -0.1701 0.7908 0.1924 0.046 Uiso 1 1 calc R
C7 C 0.2493(6) 0.8310(4) 0.4716(4) 0.0790(14) Uani 1 1 d .
H7A H 0.2873 0.9111 0.4510 0.095 Uiso 1 1 calc R
H7B H 0.3217 0.8384 0.5451 0.095 Uiso 1 1 calc R
C8 C 0.1100(7) 0.8148(5) 0.4928(5) 0.0969(17) Uani 1 1 d .
H8A H 0.1259 0.8576 0.5799 0.116 Uiso 1 1 calc R
H8B H 0.0575 0.8534 0.4443 0.116 Uiso 1 1 calc R
C9 C 0.0285(6) 0.6704(6) 0.4534(6) 0.1046(19) Uani 1 1 d .
H9A H -0.0745 0.6450 0.4086 0.126 Uiso 1 1 calc R
H9B H 0.0343 0.6414 0.5246 0.126 Uiso 1 1 calc R
C10 C 0.0971(5) 0.6089(4) 0.3724(4) 0.0714(13) Uani 1 1 d .
H10A H 0.1297 0.5477 0.4038 0.086 Uiso 1 1 calc R
H10B H 0.0273 0.5592 0.2891 0.086 Uiso 1 1 calc R
C11 C 0.6022(4) 0.8170(4) 0.3537(4) 0.0716(13) Uani 1 1 d .
H11A H 0.5868 0.8982 0.3839 0.086 Uiso 1 1 calc R
H11B H 0.6662 0.8319 0.3040 0.086 Uiso 1 1 calc R
C12 C 0.6691(6) 0.7856(5) 0.4562(5) 0.106(2) Uani 1 1 d .
H12A H 0.7701 0.7993 0.4622 0.127 Uiso 1 1 calc R
H12B H 0.6693 0.8418 0.5333 0.127 Uiso 1 1 calc R
C13 C 0.5801(9) 0.6456(6) 0.4308(6) 0.157(4) Uani 1 1 d .
H13A H 0.6405 0.5944 0.4266 0.189 Uiso 1 1 calc R
H13B H 0.5393 0.6368 0.4968 0.189 Uiso 1 1 calc R
C14 C 0.4656(5) 0.5959(4) 0.3174(4) 0.0774(14) Uani 1 1 d .
H14A H 0.3715 0.5505 0.3266 0.093 Uiso 1 1 calc R
H14B H 0.4813 0.5325 0.2549 0.093 Uiso 1 1 calc R
C15 C 0.0924(4) 0.9419(4) -0.1209(3) 0.0505(10) Uani 1 1 d .
H15A H 0.1701 0.9518 -0.1576 0.061 Uiso 1 1 calc R
H15B H 0.1219 1.0239 -0.0518 0.061 Uiso 1 1 calc R
C16 C -0.0484(4) 0.9149(4) -0.2146(4) 0.0565(10) Uani 1 1 d .
H16A H -0.1035 0.9595 -0.1775 0.068 Uiso 1 1 calc R
H16B H -0.0304 0.9446 -0.2824 0.068 Uiso 1 1 calc R
C17 C -0.1284(4) 0.7662(4) -0.2581(3) 0.0531(10) Uani 1 1 d .
H17A H -0.1007 0.7223 -0.3249 0.064 Uiso 1 1 calc R
H17B H -0.2344 0.7393 -0.2860 0.064 Uiso 1 1 calc R
C18 C -0.0792(4) 0.7341(4) -0.1449(3) 0.0457(9) Uani 1 1 d .
H18A H -0.1421 0.7405 -0.0947 0.055 Uiso 1 1 calc R
H18B H -0.0821 0.6440 -0.1673 0.055 Uiso 1 1 calc R
C19 C 0.2916(6) 0.7336(7) -0.2000(4) 0.106(2) Uani 1 1 d .
H19A H 0.2717 0.7943 -0.2404 0.127 Uiso 1 1 calc R
H19B H 0.1997 0.6563 -0.2225 0.127 Uiso 1 1 calc R
C20 C 0.3941(5) 0.6920(5) -0.2399(4) 0.0857(15) Uani 1 1 d .
H20A H 0.4170 0.7274 -0.3036 0.103 Uiso 1 1 calc R
H20B H 0.3541 0.5947 -0.2744 0.103 Uiso 1 1 calc R
C21 C 0.5281(5) 0.7428(4) -0.1320(4) 0.0633(11) Uani 1 1 d .
H21A H 0.6144 0.7938 -0.1489 0.076 Uiso 1 1 calc R
H21B H 0.5429 0.6694 -0.1098 0.076 Uiso 1 1 calc R
C22 C 0.4996(4) 0.8306(4) -0.0313(4) 0.0497(9) Uani 1 1 d .
H22A H 0.5283 0.8138 0.0452 0.060 Uiso 1 1 calc R
H22B H 0.5554 0.9246 -0.0171 0.060 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Li1 Cl1 Li2 69.66(18) . .
O2 Li1 O1 99.2(3) . .
O2 Li1 N1 122.1(3) . .
O1 Li1 N1 112.6(3) . .
O2 Li1 Cl1 105.1(2) . .
O1 Li1 Cl1 114.3(3) . .
N1 Li1 Cl1 103.8(2) . .
O2 Li1 Li2 120.2(3) . .
O1 Li1 Li2 140.5(3) . .
N1 Li1 Li2 50.05(17) . .
Cl1 Li1 Li2 55.28(16) . .
O4 Li2 O3 98.3(3) . .
O4 Li2 N1 116.6(3) . .
O3 Li2 N1 112.0(3) . .
O4 Li2 Cl1 107.6(2) . .
O3 Li2 Cl1 121.3(3) . .
N1 Li2 Cl1 101.8(2) . .
O4 Li2 Li1 116.7(3) . .
O3 Li2 Li1 144.5(3) . .
N1 Li2 Li1 48.22(18) . .
Cl1 Li2 Li1 55.06(16) . .
C4 N1 C1 115.7(2) . .
C4 N1 Li1 112.3(2) . .
C1 N1 Li1 118.5(2) . .
C4 N1 Li2 106.6(2) . .
C1 N1 Li2 117.0(2) . .
Li1 N1 Li2 81.7(2) . .
C7 O1 C10 108.1(3) . .
C7 O1 Li1 119.0(3) . .
C10 O1 Li1 128.5(3) . .
C11 O2 C14 107.9(3) . .
C11 O2 Li1 121.6(3) . .
C14 O2 Li1 120.5(3) . .
C15 O3 C18 109.6(2) . .
C15 O3 Li2 125.6(2) . .
C18 O3 Li2 124.1(3) . .
C19 O4 C22 107.9(3) . .
C19 O4 Li2 122.6(3) . .
C22 O4 Li2 127.8(3) . .
C2 C1 N1 120.3(3) . .
C2 C1 C4 117.8(3) . 2_565
N1 C1 C4 122.0(3) . 2_565
C1 C2 C3 122.9(3) . .
C6 C3 C2 119.1(3) 2_565 .
C5 C4 N1 119.6(3) . .
C5 C4 C1 118.1(3) . 2_565
N1 C4 C1 122.3(2) . 2_565
C6 C5 C4 122.7(3) . .
C3 C6 C5 119.5(3) 2_565 .
O1 C7 C8 105.9(4) . .
C9 C8 C7 104.5(4) . .
C8 C9 C10 106.4(4) . .
O1 C10 C9 106.5(4) . .
O2 C11 C12 108.5(4) . .
C13 C12 C11 105.5(4) . .
C14 C13 C12 108.9(4) . .
C13 C14 O2 106.7(4) . .
O3 C15 C16 106.9(3) . .
C17 C16 C15 103.5(3) . .
C16 C17 C18 102.8(3) . .
O3 C18 C17 105.6(3) . .
O4 C19 C20 110.1(4) . .
C19 C20 C21 107.9(4) . .
C20 C21 C22 104.2(3) . .
O4 C22 C21 106.6(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cl1 Li1 2.365(6) .
Cl1 Li2 2.371(6) .
Li1 O2 1.957(6) .
Li1 O1 1.976(6) .
Li1 N1 2.038(6) .
Li1 Li2 2.705(8) .
Li2 O4 1.969(6) .
Li2 O3 1.984(6) .
Li2 N1 2.095(6) .
N1 C4 1.398(4) .
N1 C1 1.404(4) .
O1 C7 1.422(5) .
O1 C10 1.425(5) .
O2 C11 1.410(4) .
O2 C14 1.448(5) .
O3 C15 1.433(4) .
O3 C18 1.428(4) .
O4 C19 1.409(5) .
O4 C22 1.432(4) .
C1 C2 1.389(4) .
C1 C4 1.429(4) 2_565
C2 C3 1.393(4) .
C3 C6 1.373(4) 2_565
C4 C5 1.392(4) .
C4 C1 1.429(4) 2_565
C5 C6 1.384(4) .
C6 C3 1.373(4) 2_565
C7 C8 1.467(7) .
C8 C9 1.467(7) .
C9 C10 1.485(6) .
C11 C12 1.447(6) .
C12 C13 1.463(7) .
C13 C14 1.418(6) .
C15 C16 1.503(5) .
C16 C17 1.504(5) .
C17 C18 1.505(5) .
C19 C20 1.413(6) .
C20 C21 1.486(6) .
C21 C22 1.507(5) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Li2 Cl1 Li1 O2 116.5(3) . .
Li2 Cl1 Li1 O1 -135.8(3) . .
Li2 Cl1 Li1 N1 -12.8(2) . .
Li1 Cl1 Li2 O4 -110.7(3) . .
Li1 Cl1 Li2 O3 137.5(3) . .
Li1 Cl1 Li2 N1 12.3(2) . .
O2 Li1 Li2 O4 5.5(4) . .
O1 Li1 Li2 O4 -179.7(4) . .
N1 Li1 Li2 O4 -102.8(3) . .
Cl1 Li1 Li2 O4 93.5(3) . .
O2 Li1 Li2 O3 175.6(4) . .
O1 Li1 Li2 O3 -9.6(8) . .
N1 Li1 Li2 O3 67.2(5) . .
Cl1 Li1 Li2 O3 -96.5(5) . .
O2 Li1 Li2 N1 108.3(3) . .
O1 Li1 Li2 N1 -76.9(5) . .
Cl1 Li1 Li2 N1 -163.7(3) . .
O2 Li1 Li2 Cl1 -87.9(3) . .
O1 Li1 Li2 Cl1 86.9(4) . .
N1 Li1 Li2 Cl1 163.7(3) . .
O2 Li1 N1 C4 150.9(3) . .
O1 Li1 N1 C4 33.2(4) . .
Cl1 Li1 N1 C4 -90.9(3) . .
Li2 Li1 N1 C4 -104.6(3) . .
O2 Li1 N1 C1 11.9(4) . .
O1 Li1 N1 C1 -105.9(3) . .
Cl1 Li1 N1 C1 130.0(2) . .
Li2 Li1 N1 C1 116.3(3) . .
O2 Li1 N1 Li2 -104.4(3) . .
O1 Li1 N1 Li2 137.9(3) . .
Cl1 Li1 N1 Li2 13.7(2) . .
O4 Li2 N1 C4 -145.9(3) . .
O3 Li2 N1 C4 -33.8(3) . .
Cl1 Li2 N1 C4 97.4(2) . .
Li1 Li2 N1 C4 110.9(3) . .
O4 Li2 N1 C1 -14.7(4) . .
O3 Li2 N1 C1 97.5(3) . .
Cl1 Li2 N1 C1 -131.4(2) . .
Li1 Li2 N1 C1 -117.8(3) . .
O4 Li2 N1 Li1 103.2(3) . .
O3 Li2 N1 Li1 -144.7(3) . .
Cl1 Li2 N1 Li1 -13.6(2) . .
O2 Li1 O1 C7 97.1(4) . .
N1 Li1 O1 C7 -132.3(4) . .
Cl1 Li1 O1 C7 -14.1(4) . .
Li2 Li1 O1 C7 -78.3(6) . .
O2 Li1 O1 C10 -109.3(4) . .
N1 Li1 O1 C10 21.2(5) . .
Cl1 Li1 O1 C10 139.4(3) . .
Li2 Li1 O1 C10 75.2(6) . .
O1 Li1 O2 C11 -91.5(4) . .
N1 Li1 O2 C11 144.4(3) . .
Cl1 Li1 O2 C11 26.9(4) . .
Li2 Li1 O2 C11 85.2(4) . .
O1 Li1 O2 C14 49.7(4) . .
N1 Li1 O2 C14 -74.4(4) . .
Cl1 Li1 O2 C14 168.1(3) . .
Li2 Li1 O2 C14 -133.6(3) . .
O4 Li2 O3 C15 -57.7(4) . .
N1 Li2 O3 C15 179.1(3) . .
Cl1 Li2 O3 C15 58.8(4) . .
Li1 Li2 O3 C15 131.2(5) . .
O4 Li2 O3 C18 111.3(3) . .
N1 Li2 O3 C18 -11.8(4) . .
Cl1 Li2 O3 C18 -132.2(3) . .
Li1 Li2 O3 C18 -59.7(6) . .
O3 Li2 O4 C19 -42.6(5) . .
N1 Li2 O4 C19 77.2(5) . .
Cl1 Li2 O4 C19 -169.3(4) . .
Li1 Li2 O4 C19 131.6(4) . .
O3 Li2 O4 C22 154.1(3) . .
N1 Li2 O4 C22 -86.1(4) . .
Cl1 Li2 O4 C22 27.4(4) . .
Li1 Li2 O4 C22 -31.7(4) . .
C4 N1 C1 C2 -178.0(3) . .
Li1 N1 C1 C2 -40.2(4) . .
Li2 N1 C1 C2 55.1(4) . .
C4 N1 C1 C4 1.5(4) . 2_565
Li1 N1 C1 C4 139.2(3) . 2_565
Li2 N1 C1 C4 -125.5(3) . 2_565
N1 C1 C2 C3 -179.6(3) . .
C4 C1 C2 C3 0.9(4) 2_565 .
C1 C2 C3 C6 -0.6(5) . 2_565
C1 N1 C4 C5 -179.9(3) . .
Li1 N1 C4 C5 39.8(4) . .
Li2 N1 C4 C5 -47.9(3) . .
C1 N1 C4 C1 -1.5(4) . 2_565
Li1 N1 C4 C1 -141.8(3) . 2_565
Li2 N1 C4 C1 130.5(3) . 2_565
N1 C4 C5 C6 178.6(3) . .
C1 C4 C5 C6 0.1(5) 2_565 .
C4 C5 C6 C3 -0.5(5) . 2_565
C10 O1 C7 C8 -27.8(5) . .
Li1 O1 C7 C8 130.7(4) . .
O1 C7 C8 C9 29.0(6) . .
C7 C8 C9 C10 -19.5(6) . .
C7 O1 C10 C9 15.3(5) . .
Li1 O1 C10 C9 -140.5(4) . .
C8 C9 C10 O1 3.1(6) . .
C14 O2 C11 C12 -15.7(5) . .
Li1 O2 C11 C12 129.8(4) . .
O2 C11 C12 C13 9.5(7) . .
C11 C12 C13 C14 0.4(8) . .
C12 C13 C14 O2 -9.7(8) . .
C11 O2 C14 C13 15.7(6) . .
Li1 O2 C14 C13 -130.2(5) . .
C18 O3 C15 C16 2.0(4) . .
Li2 O3 C15 C16 172.3(3) . .
O3 C15 C16 C17 -22.1(4) . .
C15 C16 C17 C18 32.7(4) . .
C15 O3 C18 C17 19.2(4) . .
Li2 O3 C18 C17 -151.4(3) . .
C16 C17 C18 O3 -32.3(4) . .
C22 O4 C19 C20 15.1(6) . .
Li2 O4 C19 C20 -151.1(4) . .
O4 C19 C20 C21 -4.8(7) . .
C19 C20 C21 C22 -6.7(6) . .
C19 O4 C22 C21 -18.9(5) . .
Li2 O4 C22 C21 146.3(3) . .
C20 C21 C22 O4 15.5(4) . .
