#------------------------------------------------------------------------------
#$Date: 2016-03-21 13:16:33 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178696 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/07/4080772.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4080772
loop_
_publ_author_name
'You, Hongxing'
'Wang, Yongyong'
'Zhao, Xiaoli'
'Chen, Shengjie'
'Liu, Ye'
_publ_section_title
;
 Stable Ionic Rh(I,II,III) Complexes Ligated by an Imidazolium-Substituted
 Phosphine with π-Acceptor Character: Synthesis, Characterization, and
 Application to Hydroformylation
;
_journal_issue                   9
_journal_name_full               Organometallics
_journal_page_first              2698
_journal_paper_doi               10.1021/om400171t
_journal_volume                  32
_journal_year                    2013
_chemical_formula_sum            'C24 H30 F6 N2 O4 P2 Rh'
_chemical_formula_weight         689.35
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           18
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2 2ab'
_symmetry_space_group_name_H-M   'P 21 21 2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   15.0023(5)
_cell_length_b                   15.6987(5)
_cell_length_c                   12.3254(4)
_cell_measurement_temperature    296(2)
_cell_volume                     2902.84(16)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0285
_diffrn_reflns_av_sigmaI/netI    0.0177
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            34074
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.65
_exptl_absorpt_coefficient_mu    0.769
_exptl_absorpt_correction_T_max  0.8490
_exptl_absorpt_correction_T_min  0.7587
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.577
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1396
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.22
_refine_diff_density_max         0.486
_refine_diff_density_min         -0.273
_refine_diff_density_rms         0.061
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.02(4)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     331
_refine_ls_number_reflns         5123
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.070
_refine_ls_R_factor_all          0.0390
_refine_ls_R_factor_gt           0.0325
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0576P)²+1.4720P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0906
_refine_ls_wR_factor_ref         0.0978
_reflns_number_gt                4564
_reflns_number_total             5123
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om400171t_si_002.cif
_cod_data_source_block           3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.3.1 from 2005-06-27.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P2(1)2(1)2
_cod_database_code               4080772
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x+1/2, y+1/2, -z'
'x+1/2, -y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Rh1 Rh 0.580932(17) 1.003385(17) 0.27866(2) 0.04310(11) Uani 1 1 d .
P1 P 0.74251(7) 1.01269(6) 0.26237(8) 0.0472(2) Uani 1 1 d .
P2 P 0.5000 1.0000 -0.20661(15) 0.0751(4) Uani 1 2 d S
P3 P 1.0000 1.0000 -0.1214(2) 0.1405(14) Uani 1 2 d S
O1 O 0.4307(3) 0.90312(17) 0.3925(2) 0.0522(8) Uani 1 1 d .
O2 O 0.5801(3) 0.91556(17) 0.4002(2) 0.0515(7) Uani 1 1 d .
O3 O 0.4220(3) 1.09328(17) 0.1675(2) 0.0547(7) Uani 1 1 d .
O4 O 0.5713(3) 1.09282(18) 0.1603(3) 0.0569(8) Uani 1 1 d .
F1 F 0.4106(3) 0.9498(3) -0.2035(6) 0.1546(19) Uani 1 1 d .
F2 F 0.5528(3) 0.9120(2) -0.2062(3) 0.1079(12) Uani 1 1 d .
F3 F 0.5000 1.0000 -0.3331(4) 0.159(3) Uani 1 2 d S
F4 F 0.5000 1.0000 -0.0790(4) 0.153(3) Uani 1 2 d S
F5 F 0.9497(9) 1.0443(10) -0.2032(7) 0.389(8) Uani 1 1 d .
F6 F 0.9493(3) 1.0489(4) -0.0235(5) 0.163(2) Uani 1 1 d .
F7 F 0.9280(5) 0.9304(6) -0.1096(6) 0.244(4) Uani 1 1 d .
N1 N 0.7506(3) 1.0559(2) 0.0397(3) 0.0636(10) Uani 1 1 d .
N2 N 0.7725(4) 1.1670(3) 0.1412(4) 0.0875(14) Uani 1 1 d .
C1 C 0.80981(19) 1.0559(2) 0.3702(2) 0.0581(11) Uani 1 1 d G
C2 C 0.7714(2) 1.0591(2) 0.4727(2) 0.0727(13) Uani 1 1 d G
H2A H 0.7114 1.0461 0.4816 0.087 Uiso 1 1 calc R
C3 C 0.8228(3) 1.0819(3) 0.5620(2) 0.101(2) Uani 1 1 d G
H3A H 0.7971 1.0840 0.6307 0.122 Uiso 1 1 calc R
C4 C 0.9125(3) 1.1014(3) 0.5488(3) 0.101(2) Uani 1 1 d G
H4A H 0.9468 1.1166 0.6085 0.121 Uiso 1 1 calc R
C5 C 0.95086(19) 1.0982(2) 0.4462(4) 0.099(2) Uani 1 1 d G
H5A H 1.0109 1.1112 0.4373 0.119 Uiso 1 1 calc R
C6 C 0.8995(2) 1.0754(2) 0.3569(3) 0.0788(15) Uani 1 1 d G
H6A H 0.9252 1.0733 0.2883 0.095 Uiso 1 1 calc R
C7 C 0.80435(17) 0.91608(13) 0.2309(2) 0.0505(9) Uani 1 1 d G
C8 C 0.88428(18) 0.91441(15) 0.1739(2) 0.0570(10) Uani 1 1 d G
H8A H 0.9062 0.9640 0.1424 0.068 Uiso 1 1 calc R
C9 C 0.93148(17) 0.8386(2) 0.1640(3) 0.0744(14) Uani 1 1 d G
H9A H 0.9850 0.8375 0.1259 0.089 Uiso 1 1 calc R
C10 C 0.8988(2) 0.76450(15) 0.2111(3) 0.0793(15) Uani 1 1 d G
H10A H 0.9303 0.7138 0.2045 0.095 Uiso 1 1 calc R
C11 C 0.8188(2) 0.76616(13) 0.2681(3) 0.0838(17) Uani 1 1 d G
H11A H 0.7969 0.7166 0.2996 0.101 Uiso 1 1 calc R
C12 C 0.77163(18) 0.84196(17) 0.2780(3) 0.0659(12) Uani 1 1 d G
H12A H 0.7182 0.8431 0.3162 0.079 Uiso 1 1 calc R
C13 C 0.7627(3) 1.0812(3) 0.1427(4) 0.0571(11) Uani 1 1 d .
C14 C 0.7545(4) 1.1246(4) -0.0278(5) 0.0874(17) Uani 1 1 d .
H14A H 0.7492 1.1240 -0.1030 0.105 Uiso 1 1 calc R
C15 C 0.7675(5) 1.1922(4) 0.0342(6) 0.102(2) Uani 1 1 d .
H15A H 0.7724 1.2480 0.0096 0.122 Uiso 1 1 calc R
C16 C 0.7298(4) 0.9711(3) 0.0000(4) 0.0749(14) Uani 1 1 d .
H16A H 0.7255 0.9722 -0.0777 0.112 Uiso 1 1 calc R
H16B H 0.6740 0.9527 0.0301 0.112 Uiso 1 1 calc R
H16C H 0.7760 0.9323 0.0214 0.112 Uiso 1 1 calc R
C17 C 0.7837(6) 1.2262(4) 0.2336(7) 0.125(3) Uani 1 1 d D
H17A H 0.7934 1.1936 0.2994 0.150 Uiso 1 1 calc R
H17B H 0.8359 1.2613 0.2214 0.150 Uiso 1 1 calc R
C18 C 0.7066(7) 1.2806(8) 0.2479(11) 0.216(6) Uani 1 1 d D
H18A H 0.6570 1.2471 0.2748 0.259 Uiso 1 1 calc R
H18B H 0.6896 1.3050 0.1787 0.259 Uiso 1 1 calc R
C19 C 0.7276(9) 1.3516(7) 0.3277(10) 0.190(5) Uani 1 1 d D
H19A H 0.7917 1.3579 0.3346 0.228 Uiso 1 1 calc R
H19B H 0.7035 1.4049 0.3011 0.228 Uiso 1 1 calc R
C20 C 0.6894(14) 1.3321(11) 0.4325(12) 0.328(13) Uani 1 1 d D
H20A H 0.6992 1.3790 0.4810 0.492 Uiso 1 1 calc R
H20B H 0.7171 1.2819 0.4614 0.492 Uiso 1 1 calc R
H20C H 0.6265 1.3225 0.4247 0.492 Uiso 1 1 calc R
C21 C 0.5052(4) 0.8854(2) 0.4313(3) 0.0490(9) Uani 1 1 d .
C22 C 0.5086(4) 0.8231(3) 0.5240(4) 0.0684(12) Uani 1 1 d .
H22A H 0.4494 0.8042 0.5408 0.103 Uiso 1 1 calc R
H22B H 0.5341 0.8504 0.5864 0.103 Uiso 1 1 calc R
H22C H 0.5446 0.7751 0.5039 0.103 Uiso 1 1 calc R
C23 C 0.4950(4) 1.1199(2) 0.1321(3) 0.0541(9) Uani 1 1 d .
C24 C 0.4917(5) 1.1912(3) 0.0505(4) 0.0779(14) Uani 1 1 d .
H24A H 0.4308 1.2062 0.0365 0.117 Uiso 1 1 calc R
H24B H 0.5195 1.1731 -0.0158 0.117 Uiso 1 1 calc R
H24C H 0.5228 1.2398 0.0787 0.117 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O4 Rh1 O2 175.4(2) . .
O4 Rh1 O1 89.48(12) . 2_675
O2 Rh1 O1 88.89(11) . 2_675
O4 Rh1 O3 91.73(12) . 2_675
O2 Rh1 O3 89.42(11) . 2_675
O1 Rh1 O3 173.6(2) 2_675 2_675
O4 Rh1 Rh1 87.65(13) . 2_675
O2 Rh1 Rh1 87.96(14) . 2_675
O1 Rh1 Rh1 86.89(12) 2_675 2_675
O3 Rh1 Rh1 86.91(14) 2_675 2_675
O4 Rh1 P1 88.29(13) . .
O2 Rh1 P1 96.15(14) . .
O1 Rh1 P1 95.68(12) 2_675 .
O3 Rh1 P1 90.61(14) 2_675 .
Rh1 Rh1 P1 175.18(2) 2_675 .
C1 P1 C7 100.69(15) . .
C1 P1 C13 106.08(19) . .
C7 P1 C13 103.37(16) . .
C1 P1 Rh1 121.29(11) . .
C7 P1 Rh1 118.34(10) . .
C13 P1 Rh1 105.28(16) . .
F1 P2 F1 177.2(5) . 2_675
F1 P2 F3 91.4(3) . .
F1 P2 F3 91.4(3) 2_675 .
F1 P2 F4 88.6(3) . .
F1 P2 F4 88.6(3) 2_675 .
F3 P2 F4 180.000(1) . .
F1 P2 F2 89.4(2) . .
F1 P2 F2 90.6(2) 2_675 .
F3 P2 F2 90.19(17) . .
F4 P2 F2 89.81(17) . .
F1 P2 F2 90.6(2) . 2_675
F1 P2 F2 89.4(2) 2_675 2_675
F3 P2 F2 90.19(17) . 2_675
F4 P2 F2 89.81(17) . 2_675
F2 P2 F2 179.6(3) . 2_675
F5 P3 F5 91.0(11) 2_775 .
F5 P3 F7 92.4(7) 2_775 2_775
F5 P3 F7 95.2(7) . 2_775
F5 P3 F7 95.2(7) 2_775 .
F5 P3 F7 92.4(7) . .
F7 P3 F7 169.2(6) 2_775 .
F5 P3 F6 92.7(6) 2_775 2_775
F5 P3 F6 175.9(6) . 2_775
F7 P3 F6 86.3(4) 2_775 2_775
F7 P3 F6 85.6(4) . 2_775
F5 P3 F6 175.9(6) 2_775 .
F5 P3 F6 92.7(6) . .
F7 P3 F6 85.6(4) 2_775 .
F7 P3 F6 86.3(4) . .
F6 P3 F6 83.7(4) 2_775 .
C21 O1 Rh1 120.1(3) . 2_675
C21 O2 Rh1 118.5(3) . .
C23 O3 Rh1 120.0(3) . 2_675
C23 O4 Rh1 119.5(3) . .
C13 N1 C14 109.7(4) . .
C13 N1 C16 128.3(4) . .
C14 N1 C16 121.9(4) . .
C13 N2 C15 107.0(5) . .
C13 N2 C17 128.8(5) . .
C15 N2 C17 124.2(5) . .
C2 C1 C6 120.0 . .
C2 C1 P1 116.89(18) . .
C6 C1 P1 122.62(18) . .
C1 C2 C3 120.0 . .
C1 C2 H2A 120.0 . .
C3 C2 H2A 120.0 . .
C4 C3 C2 120.0 . .
C4 C3 H3A 120.0 . .
C2 C3 H3A 120.0 . .
C3 C4 C5 120.0 . .
C3 C4 H4A 120.0 . .
C5 C4 H4A 120.0 . .
C4 C5 C6 120.0 . .
C4 C5 H5A 120.0 . .
C6 C5 H5A 120.0 . .
C5 C6 C1 120.0 . .
C5 C6 H6A 120.0 . .
C1 C6 H6A 120.0 . .
C8 C7 C12 120.0 . .
C8 C7 P1 124.28(15) . .
C12 C7 P1 115.39(15) . .
C7 C8 C9 120.0 . .
C7 C8 H8A 120.0 . .
C9 C8 H8A 120.0 . .
C10 C9 C8 120.0 . .
C10 C9 H9A 120.0 . .
C8 C9 H9A 120.0 . .
C11 C10 C9 120.0 . .
C11 C10 H10A 120.0 . .
C9 C10 H10A 120.0 . .
C10 C11 C12 120.0 . .
C10 C11 H11A 120.0 . .
C12 C11 H11A 120.0 . .
C11 C12 C7 120.0 . .
C11 C12 H12A 120.0 . .
C7 C12 H12A 120.0 . .
N1 C13 N2 107.2(4) . .
N1 C13 P1 124.0(3) . .
N2 C13 P1 127.3(4) . .
C15 C14 N1 106.8(5) . .
C15 C14 H14A 126.6 . .
N1 C14 H14A 126.6 . .
C14 C15 N2 109.3(5) . .
C14 C15 H15A 125.4 . .
N2 C15 H15A 125.4 . .
N1 C16 H16A 109.5 . .
N1 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
N1 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C18 C17 N2 112.0(7) . .
C18 C17 H17A 109.2 . .
N2 C17 H17A 109.2 . .
C18 C17 H17B 109.2 . .
N2 C17 H17B 109.2 . .
H17A C17 H17B 107.9 . .
C17 C18 C19 110.2(9) . .
C17 C18 H18A 109.6 . .
C19 C18 H18A 109.6 . .
C17 C18 H18B 109.6 . .
C19 C18 H18B 109.6 . .
H18A C18 H18B 108.1 . .
C20 C19 C18 109.9(12) . .
C20 C19 H19A 109.7 . .
C18 C19 H19A 109.7 . .
C20 C19 H19B 109.7 . .
C18 C19 H19B 109.7 . .
H19A C19 H19B 108.2 . .
C19 C20 H20A 109.5 . .
C19 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C19 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
O1 C21 O2 126.2(3) . .
O1 C21 C22 117.8(5) . .
O2 C21 C22 116.0(5) . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
O3 C23 O4 125.6(3) . .
O3 C23 C24 116.9(5) . .
O4 C23 C24 117.4(5) . .
C23 C24 H24A 109.5 . .
C23 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C23 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rh1 O4 2.030(3) .
Rh1 O2 2.036(3) .
Rh1 O1 2.038(3) 2_675
Rh1 O3 2.045(3) 2_675
Rh1 Rh1 2.4307(5) 2_675
Rh1 P1 2.4368(10) .
P1 C1 1.801(2) .
P1 C7 1.820(2) .
P1 C13 1.851(4) .
P2 F1 1.557(5) .
P2 F1 1.557(5) 2_675
P2 F3 1.559(6) .
P2 F4 1.573(5) .
P2 F2 1.593(3) .
P2 F2 1.593(3) 2_675
P3 F5 1.438(7) 2_775
P3 F5 1.438(7) .
P3 F7 1.543(7) 2_775
P3 F7 1.544(7) .
P3 F6 1.621(6) 2_775
P3 F6 1.621(6) .
O1 C21 1.246(7) .
O1 Rh1 2.038(3) 2_675
O2 C21 1.279(7) .
O3 C23 1.251(7) .
O3 Rh1 2.045(3) 2_675
O4 C23 1.269(7) .
N1 C13 1.343(6) .
N1 C14 1.363(6) .
N1 C16 1.452(6) .
N2 C13 1.354(6) .
N2 C15 1.378(8) .
N2 C17 1.479(8) .
C1 C2 1.3900 .
C1 C6 1.3900 .
C2 C3 1.3900 .
C2 H2A 0.9300 .
C3 C4 1.3900 .
C3 H3A 0.9300 .
C4 C5 1.3900 .
C4 H4A 0.9300 .
C5 C6 1.3900 .
C5 H5A 0.9300 .
C6 H6A 0.9300 .
C7 C8 1.3900 .
C7 C12 1.3900 .
C8 C9 1.3900 .
C8 H8A 0.9300 .
C9 C10 1.3900 .
C9 H9A 0.9300 .
C10 C11 1.3900 .
C10 H10A 0.9300 .
C11 C12 1.3900 .
C11 H11A 0.9300 .
C12 H12A 0.9300 .
C14 C15 1.323(9) .
C14 H14A 0.9300 .
C15 H15A 0.9300 .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C17 C18 1.448(8) .
C17 H17A 0.9700 .
C17 H17B 0.9700 .
C18 C19 1.519(8) .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C19 C20 1.446(9) .
C19 H19A 0.9700 .
C19 H19B 0.9700 .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C21 C22 1.504(5) .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C23 C24 1.506(5) .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
O4 Rh1 P1 C1 112.37(15) .
O2 Rh1 P1 C1 -66.43(15) .
O1 Rh1 P1 C1 23.06(15) 2_675
O3 Rh1 P1 C1 -155.92(15) 2_675
Rh1 Rh1 P1 C1 145.1(3) 2_675
O4 Rh1 P1 C7 -122.58(15) .
O2 Rh1 P1 C7 58.62(14) .
O1 Rh1 P1 C7 148.12(14) 2_675
O3 Rh1 P1 C7 -30.86(14) 2_675
Rh1 Rh1 P1 C7 -89.9(3) 2_675
O4 Rh1 P1 C13 -7.76(17) .
O2 Rh1 P1 C13 173.44(16) .
O1 Rh1 P1 C13 -97.07(18) 2_675
O3 Rh1 P1 C13 83.95(17) 2_675
Rh1 Rh1 P1 C13 25.0(4) 2_675
O4 Rh1 O2 C21 20.3(16) .
O1 Rh1 O2 C21 89.6(3) 2_675
O3 Rh1 O2 C21 -84.2(3) 2_675
Rh1 Rh1 O2 C21 2.7(3) 2_675
P1 Rh1 O2 C21 -174.8(3) .
O2 Rh1 O4 C23 -12.4(17) .
O1 Rh1 O4 C23 -81.7(3) 2_675
O3 Rh1 O4 C23 92.1(3) 2_675
Rh1 Rh1 O4 C23 5.2(3) 2_675
P1 Rh1 O4 C23 -177.4(3) .
C7 P1 C1 C2 -113.6(2) .
C13 P1 C1 C2 139.0(2) .
Rh1 P1 C1 C2 19.2(2) .
C7 P1 C1 C6 58.3(2) .
C13 P1 C1 C6 -49.1(2) .
Rh1 P1 C1 C6 -168.85(15) .
C6 C1 C2 C3 0.0 .
P1 C1 C2 C3 172.2(2) .
C1 C2 C3 C4 0.0 .
C2 C3 C4 C5 0.0 .
C3 C4 C5 C6 0.0 .
C4 C5 C6 C1 0.0 .
C2 C1 C6 C5 0.0 .
P1 C1 C6 C5 -171.7(3) .
C1 P1 C7 C8 -75.2(2) .
C13 P1 C7 C8 34.4(3) .
Rh1 P1 C7 C8 150.23(15) .
C1 P1 C7 C12 98.15(18) .
C13 P1 C7 C12 -152.3(2) .
Rh1 P1 C7 C12 -36.46(19) .
C12 C7 C8 C9 0.0 .
P1 C7 C8 C9 173.0(2) .
C7 C8 C9 C10 0.0 .
C8 C9 C10 C11 0.0 .
C9 C10 C11 C12 0.0 .
C10 C11 C12 C7 0.0 .
C8 C7 C12 C11 0.0 .
P1 C7 C12 C11 -173.6(2) .
C14 N1 C13 N2 1.4(6) .
C16 N1 C13 N2 -174.5(5) .
C14 N1 C13 P1 168.5(4) .
C16 N1 C13 P1 -7.3(7) .
C15 N2 C13 N1 -1.0(6) .
C17 N2 C13 N1 177.0(6) .
C15 N2 C13 P1 -167.7(4) .
C17 N2 C13 P1 10.4(9) .
C1 P1 C13 N1 156.4(4) .
C7 P1 C13 N1 50.9(4) .
Rh1 P1 C13 N1 -73.9(4) .
C1 P1 C13 N2 -39.0(5) .
C7 P1 C13 N2 -144.5(5) .
Rh1 P1 C13 N2 90.7(5) .
C13 N1 C14 C15 -1.2(7) .
C16 N1 C14 C15 175.0(5) .
N1 C14 C15 N2 0.5(8) .
C13 N2 C15 C14 0.3(8) .
C17 N2 C15 C14 -177.9(6) .
C13 N2 C17 C18 -111.4(10) .
C15 N2 C17 C18 66.4(11) .
N2 C17 C18 C19 -168.6(9) .
C17 C18 C19 C20 -102.0(17) .
Rh1 O1 C21 O2 -6.4(5) 2_675
Rh1 O1 C21 C22 173.1(3) 2_675
Rh1 O2 C21 O1 1.6(5) .
Rh1 O2 C21 C22 -177.9(3) .
Rh1 O3 C23 O4 -1.1(5) 2_675
Rh1 O3 C23 C24 180.0(3) 2_675
Rh1 O4 C23 O3 -3.7(5) .
Rh1 O4 C23 C24 175.2(3) .
