#------------------------------------------------------------------------------
#$Date: 2016-03-21 14:49:46 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178725 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/36/4083671.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4083671
loop_
_publ_author_name
'White, Colin P.'
'Braddock-Wilking, Janet'
'Corey, Joyce Y.'
'Xu, Huan'
'Redekop, Evgeniy'
'Sedinkin, Sergey'
'Rath, Nigam P.'
_publ_section_title
;
 Activation of Group 14 El−H Bonds at Platinum(0)
;
_journal_issue                   8
_journal_name_full               Organometallics
_journal_page_first              1996
_journal_paper_doi               10.1021/om061180+
_journal_volume                  26
_journal_year                    2007
_chemical_formula_sum            'C67 H60 P2 Pt2 Si2'
_chemical_formula_weight         1373.45
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                112.4280(10)
_cell_angle_beta                 98.0400(10)
_cell_angle_gamma                102.7360(10)
_cell_formula_units_Z            1
_cell_length_a                   9.9959(2)
_cell_length_b                   12.5390(2)
_cell_length_c                   12.8678(2)
_cell_measurement_reflns_used    9655
_cell_measurement_temperature    170(2)
_cell_measurement_theta_max      29.12
_cell_measurement_theta_min      2.38
_cell_volume                     1408.57(5)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker-SHELXTL (Sheldrick, 2003)'
_computing_publication_material  'Bruker-SHELXTL (Sheldrick, 2003)'
_computing_structure_refinement  'Bruker-SHELXTL (Sheldrick, 2003)'
_computing_structure_solution    'Bruker-SHELXTL (Sheldrick, 2003)'
_diffrn_ambient_temperature      170(2)
_diffrn_measured_fraction_theta_full 0.968
_diffrn_measured_fraction_theta_max 0.968
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'normal-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0205
_diffrn_reflns_av_sigmaI/netI    0.0327
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            13351
_diffrn_reflns_theta_full        28.00
_diffrn_reflns_theta_max         28.00
_diffrn_reflns_theta_min         1.84
_exptl_absorpt_coefficient_mu    5.101
_exptl_absorpt_correction_T_max  0.5353
_exptl_absorpt_correction_T_min  0.4286
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.619
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rectangular
_exptl_crystal_F_000             676
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.14
_refine_diff_density_max         3.170
_refine_diff_density_min         -1.354
_refine_diff_density_rms         0.111
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.027
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     341
_refine_ls_number_reflns         6577
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.040
_refine_ls_R_factor_all          0.0345
_refine_ls_R_factor_gt           0.0286
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0413P)²+0.9555P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0685
_refine_ls_wR_factor_ref         0.0716
_reflns_number_gt                5891
_reflns_number_total             6577
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om061180%2Bsi20070207_032911.cif
_cod_data_source_block           w3205
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/automatic-downloads/retrospective/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'no' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        1408.57(4)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4083671
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.097737(14) -0.399915(12) 1.513959(12) 0.02871(6) Uani 1 1 d . . .
P1 P 0.24405(10) -0.24664(8) 1.49654(8) 0.02628(18) Uani 1 1 d . . .
Si1 Si 0.04282(11) -0.45808(9) 1.66594(9) 0.0299(2) Uani 1 1 d . . .
C1 C -0.0336(4) -0.3631(4) 1.7796(3) 0.0340(8) Uani 1 1 d . . .
C2 C 0.0469(5) -0.2468(4) 1.8609(4) 0.0440(10) Uani 1 1 d . . .
H2A H 0.1411 -0.2157 1.8576 0.053 Uiso 1 1 calc R . .
C3 C -0.0067(6) -0.1754(5) 1.9462(4) 0.0581(13) Uani 1 1 d . . .
H3A H 0.0506 -0.0969 2.0009 0.070 Uiso 1 1 calc R . .
C4 C -0.1441(6) -0.2191(5) 1.9512(4) 0.0617(14) Uani 1 1 d . . .
H4A H -0.1818 -0.1702 2.0089 0.074 Uiso 1 1 calc R . .
C5 C -0.2267(6) -0.3341(5) 1.8723(5) 0.0559(13) Uani 1 1 d . . .
H5A H -0.3209 -0.3644 1.8760 0.067 Uiso 1 1 calc R . .
C6 C -0.1717(5) -0.4045(4) 1.7884(4) 0.0427(10) Uani 1 1 d . . .
H6A H -0.2292 -0.4835 1.7350 0.051 Uiso 1 1 calc R . .
C7 C 0.1827(4) -0.4995(3) 1.7431(3) 0.0318(8) Uani 1 1 d . . .
C8 C 0.1869(5) -0.4961(4) 1.8531(4) 0.0401(9) Uani 1 1 d . . .
H8A H 0.1184 -0.4696 1.8923 0.048 Uiso 1 1 calc R . .
C9 C 0.2890(5) -0.5305(4) 1.9064(4) 0.0531(12) Uani 1 1 d . . .
H9A H 0.2897 -0.5280 1.9812 0.064 Uiso 1 1 calc R . .
C10 C 0.3896(5) -0.5683(4) 1.8506(5) 0.0595(14) Uani 1 1 d . . .
H10A H 0.4599 -0.5916 1.8872 0.071 Uiso 1 1 calc R . .
C11 C 0.3884(5) -0.5723(4) 1.7425(5) 0.0561(13) Uani 1 1 d . . .
H11A H 0.4581 -0.5979 1.7046 0.067 Uiso 1 1 calc R . .
C12 C 0.2857(5) -0.5391(4) 1.6883(4) 0.0434(10) Uani 1 1 d . . .
H12A H 0.2852 -0.5432 1.6130 0.052 Uiso 1 1 calc R . .
C13 C 0.4275(4) -0.2193(3) 1.5684(3) 0.0289(7) Uani 1 1 d . . .
C14 C 0.4724(5) -0.3200(4) 1.5548(4) 0.0398(9) Uani 1 1 d . . .
H14A H 0.4082 -0.3988 1.5101 0.048 Uiso 1 1 calc R . .
C15 C 0.6109(5) -0.3060(4) 1.6065(4) 0.0486(11) Uani 1 1 d . . .
H15A H 0.6415 -0.3752 1.5955 0.058 Uiso 1 1 calc R . .
C16 C 0.7043(5) -0.1917(4) 1.6739(4) 0.0466(11) Uani 1 1 d . . .
H16A H 0.7986 -0.1821 1.7097 0.056 Uiso 1 1 calc R . .
C17 C 0.6596(5) -0.0921(4) 1.6886(4) 0.0456(10) Uani 1 1 d . . .
H17A H 0.7233 -0.0135 1.7353 0.055 Uiso 1 1 calc R . .
C18 C 0.5216(4) -0.1051(4) 1.6358(4) 0.0382(9) Uani 1 1 d . . .
H18A H 0.4921 -0.0355 1.6460 0.046 Uiso 1 1 calc R . .
C19 C 0.2579(4) -0.2514(3) 1.3546(3) 0.0289(7) Uani 1 1 d . . .
C20 C 0.3870(4) -0.2210(3) 1.3273(3) 0.0335(8) Uani 1 1 d . . .
H20A H 0.4730 -0.2004 1.3826 0.040 Uiso 1 1 calc R . .
C21 C 0.3904(5) -0.2208(4) 1.2200(4) 0.0415(10) Uani 1 1 d . . .
H21A H 0.4789 -0.2004 1.2021 0.050 Uiso 1 1 calc R . .
C22 C 0.2660(5) -0.2500(4) 1.1389(4) 0.0443(10) Uani 1 1 d . . .
H22A H 0.2687 -0.2493 1.0657 0.053 Uiso 1 1 calc R . .
C23 C 0.1378(5) -0.2802(4) 1.1653(4) 0.0458(10) Uani 1 1 d . . .
H23A H 0.0521 -0.3005 1.1099 0.055 Uiso 1 1 calc R . .
C24 C 0.1335(4) -0.2810(4) 1.2719(4) 0.0380(9) Uani 1 1 d . . .
H24A H 0.0446 -0.3020 1.2889 0.046 Uiso 1 1 calc R . .
C25 C 0.2033(4) -0.1044(3) 1.5643(3) 0.0306(8) Uani 1 1 d . . .
C26 C 0.2442(5) -0.0101(4) 1.5327(4) 0.0424(10) Uani 1 1 d . . .
H26A H 0.2939 -0.0194 1.4735 0.051 Uiso 1 1 calc R . .
C27 C 0.2135(5) 0.0975(4) 1.5863(5) 0.0528(12) Uani 1 1 d . . .
H27A H 0.2419 0.1612 1.5638 0.063 Uiso 1 1 calc R . .
C28 C 0.1418(5) 0.1120(4) 1.6722(5) 0.0579(14) Uani 1 1 d . . .
H28A H 0.1230 0.1865 1.7104 0.069 Uiso 1 1 calc R . .
C29 C 0.0973(6) 0.0184(5) 1.7027(5) 0.0617(14) Uani 1 1 d . . .
H29A H 0.0463 0.0281 1.7611 0.074 Uiso 1 1 calc R . .
C30 C 0.1267(4) -0.0904(3) 1.6485(3) 0.0454(10) Uani 1 1 d . . .
H30A H 0.0945 -0.1551 1.6690 0.054 Uiso 1 1 calc R . .
C1S C 0.4866(4) -0.0665(3) 0.9611(3) 0.052(2) Uani 0.50 1 d PRD A -1
C2S C 0.5732(4) 0.0100(3) 1.0838(3) 0.0774(19) Uani 1 1 d RD A -1
H2SA H 0.6220 -0.0213 1.1286 0.093 Uiso 1 1 calc R B -1
C3S C 0.5757(13) 0.1296(10) 1.1258(11) 0.094(6) Uani 0.50 1 d PD A -1
H3SA H 0.6308 0.1787 1.2032 0.112 Uiso 0.50 1 calc PR A -1
C4S C 0.5130(8) 0.1880(7) 1.0753(9) 0.110(3) Uani 1 1 d D A -1
H4SA H 0.5240 0.2719 1.1144 0.132 Uiso 1 1 calc R A -1
C5S C 0.4260(13) 0.1139(13) 0.9557(12) 0.076(4) Uani 0.50 1 d PD A -1
H11 H 0.158(5) -0.332(4) 1.670(4) 0.051(13) Uiso 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 Pt1 Si1 110.41(4) . 2_548
P1 Pt1 Si1 138.59(4) . .
Si1 Pt1 Si1 111.00(3) 2_548 .
P1 Pt1 Pt1 167.84(3) . 2_548
Si1 Pt1 Pt1 57.45(3) 2_548 2_548
Si1 Pt1 Pt1 53.55(3) . 2_548
P1 Pt1 H11 93.5(15) . .
Si1 Pt1 H11 156.0(15) 2_548 .
Si1 Pt1 H11 45.1(15) . .
Pt1 Pt1 H11 98.7(15) 2_548 .
C25 P1 C13 106.24(17) . .
C25 P1 C19 101.61(17) . .
C13 P1 C19 102.65(17) . .
C25 P1 Pt1 112.23(13) . .
C13 P1 Pt1 110.85(12) . .
C19 P1 Pt1 121.80(12) . .
C1 Si1 C7 106.97(17) . .
C1 Si1 Pt1 121.66(13) . 2_548
C7 Si1 Pt1 118.68(12) . 2_548
C1 Si1 Pt1 119.96(13) . .
C7 Si1 Pt1 117.06(13) . .
Pt1 Si1 Pt1 69.00(3) 2_548 .
C1 Si1 H11 91.7(16) . .
C7 Si1 H11 94.9(16) . .
Pt1 Si1 H11 116.9(15) 2_548 .
Pt1 Si1 H11 47.9(15) . .
C2 C1 C6 116.7(4) . .
C2 C1 Si1 120.9(3) . .
C6 C1 Si1 122.4(3) . .
C3 C2 C1 121.9(5) . .
C3 C2 H2A 119.0 . .
C1 C2 H2A 119.0 . .
C2 C3 C4 119.6(5) . .
C2 C3 H3A 120.2 . .
C4 C3 H3A 120.2 . .
C3 C4 C5 120.0(5) . .
C3 C4 H4A 120.0 . .
C5 C4 H4A 120.0 . .
C6 C5 C4 119.8(5) . .
C6 C5 H5A 120.1 . .
C4 C5 H5A 120.1 . .
C5 C6 C1 122.0(5) . .
C5 C6 H6A 119.0 . .
C1 C6 H6A 119.0 . .
C8 C7 C12 117.5(4) . .
C8 C7 Si1 122.7(3) . .
C12 C7 Si1 119.8(3) . .
C9 C8 C7 121.3(4) . .
C9 C8 H8A 119.3 . .
C7 C8 H8A 119.3 . .
C10 C9 C8 119.9(5) . .
C10 C9 H9A 120.1 . .
C8 C9 H9A 120.1 . .
C9 C10 C11 120.1(4) . .
C9 C10 H10A 119.9 . .
C11 C10 H10A 119.9 . .
C10 C11 C12 120.3(5) . .
C10 C11 H11A 119.9 . .
C12 C11 H11A 119.9 . .
C11 C12 C7 120.9(4) . .
C11 C12 H12A 119.5 . .
C7 C12 H12A 119.5 . .
C18 C13 C14 119.2(4) . .
C18 C13 P1 123.6(3) . .
C14 C13 P1 117.2(3) . .
C15 C14 C13 120.3(4) . .
C15 C14 H14A 119.9 . .
C13 C14 H14A 119.9 . .
C14 C15 C16 120.3(4) . .
C14 C15 H15A 119.9 . .
C16 C15 H15A 119.9 . .
C17 C16 C15 119.5(4) . .
C17 C16 H16A 120.3 . .
C15 C16 H16A 120.3 . .
C16 C17 C18 120.7(4) . .
C16 C17 H17A 119.6 . .
C18 C17 H17A 119.6 . .
C13 C18 C17 120.1(4) . .
C13 C18 H18A 120.0 . .
C17 C18 H18A 120.0 . .
C20 C19 C24 118.5(4) . .
C20 C19 P1 123.1(3) . .
C24 C19 P1 118.3(3) . .
C21 C20 C19 120.4(4) . .
C21 C20 H20A 119.8 . .
C19 C20 H20A 119.8 . .
C22 C21 C20 120.4(4) . .
C22 C21 H21A 119.8 . .
C20 C21 H21A 119.8 . .
C23 C22 C21 119.5(4) . .
C23 C22 H22A 120.2 . .
C21 C22 H22A 120.2 . .
C22 C23 C24 120.4(4) . .
C22 C23 H23A 119.8 . .
C24 C23 H23A 119.8 . .
C23 C24 C19 120.8(4) . .
C23 C24 H24A 119.6 . .
C19 C24 H24A 119.6 . .
C30 C25 C26 118.7(4) . .
C30 C25 P1 119.3(3) . .
C26 C25 P1 121.9(3) . .
C27 C26 C25 120.8(4) . .
C27 C26 H26A 119.6 . .
C25 C26 H26A 119.6 . .
C28 C27 C26 120.0(5) . .
C28 C27 H27A 120.0 . .
C26 C27 H27A 120.0 . .
C27 C28 C29 120.0(4) . .
C27 C28 H28A 120.0 . .
C29 C28 H28A 120.0 . .
C28 C29 C30 120.3(5) . .
C28 C29 H29A 119.8 . .
C30 C29 H29A 119.8 . .
C25 C30 C29 120.1(4) . .
C25 C30 H30A 120.0 . .
C29 C30 H30A 120.0 . .
C3S C2S C1S 114.2(6) . .
C3S C2S H2SA 122.9 . .
C1S C2S H2SA 122.9 . .
C4S C3S C2S 130.6(11) . .
C4S C3S H3SA 114.7 . .
C2S C3S H3SA 114.7 . .
C3S C4S C5S 115.9(10) . .
C3S C4S H4SA 122.1 . .
C5S C4S H4SA 122.1 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 P1 2.2504(9) .
Pt1 Si1 2.3119(10) 2_548
Pt1 Si1 2.4228(10) .
Pt1 Pt1 2.6832(3) 2_548
Pt1 H11 1.80(5) .
P1 C25 1.827(4) .
P1 C13 1.829(4) .
P1 C19 1.830(4) .
Si1 C1 1.877(4) .
Si1 C7 1.880(4) .
Si1 Pt1 2.3119(10) 2_548
Si1 H11 1.72(5) .
C1 C2 1.397(6) .
C1 C6 1.401(6) .
C2 C3 1.385(7) .
C2 H2A 0.9500 .
C3 C4 1.382(8) .
C3 H3A 0.9500 .
C4 C5 1.384(8) .
C4 H4A 0.9500 .
C5 C6 1.378(6) .
C5 H5A 0.9500 .
C6 H6A 0.9500 .
C7 C8 1.394(6) .
C7 C12 1.401(6) .
C8 C9 1.387(6) .
C8 H8A 0.9500 .
C9 C10 1.380(8) .
C9 H9A 0.9500 .
C10 C11 1.371(8) .
C10 H10A 0.9500 .
C11 C12 1.387(6) .
C11 H11A 0.9500 .
C12 H12A 0.9500 .
C13 C18 1.385(5) .
C13 C14 1.389(5) .
C14 C15 1.392(6) .
C14 H14A 0.9500 .
C15 C16 1.383(6) .
C15 H15A 0.9500 .
C16 C17 1.372(6) .
C16 H16A 0.9500 .
C17 C18 1.395(6) .
C17 H17A 0.9500 .
C18 H18A 0.9500 .
C19 C20 1.395(5) .
C19 C24 1.393(5) .
C20 C21 1.388(6) .
C20 H20A 0.9500 .
C21 C22 1.384(7) .
C21 H21A 0.9500 .
C22 C23 1.380(6) .
C22 H22A 0.9500 .
C23 C24 1.382(6) .
C23 H23A 0.9500 .
C24 H24A 0.9500 .
C25 C30 1.391(5) .
C25 C26 1.391(6) .
C26 C27 1.386(6) .
C26 H26A 0.9500 .
C27 C28 1.376(7) .
C27 H27A 0.9500 .
C28 C29 1.379(8) .
C28 H28A 0.9500 .
C29 C30 1.394(6) .
C29 H29A 0.9500 .
C30 H30A 0.9500 .
C1S C2S 1.5030 .
C2S C3S 1.379(11) .
C2S H2SA 0.9500 .
C3S C4S 1.342(11) .
C3S H3SA 0.9500 .
C4S C5S 1.472(12) .
C4S H4SA 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Si1 Pt1 P1 C25 113.56(14) 2_548 .
Si1 Pt1 P1 C25 -65.48(14) . .
Pt1 Pt1 P1 C25 110.81(17) 2_548 .
Si1 Pt1 P1 C13 -127.83(13) 2_548 .
Si1 Pt1 P1 C13 53.14(14) . .
Pt1 Pt1 P1 C13 -130.58(16) 2_548 .
Si1 Pt1 P1 C19 -7.04(15) 2_548 .
Si1 Pt1 P1 C19 173.92(14) . .
Pt1 Pt1 P1 C19 -9.8(2) 2_548 .
P1 Pt1 Si1 C1 63.71(16) . .
Si1 Pt1 Si1 C1 -115.32(16) 2_548 .
Pt1 Pt1 Si1 C1 -115.32(16) 2_548 .
P1 Pt1 Si1 C7 -68.57(14) . .
Si1 Pt1 Si1 C7 112.40(14) 2_548 .
Pt1 Pt1 Si1 C7 112.40(14) 2_548 .
P1 Pt1 Si1 Pt1 179.03(4) . 2_548
Si1 Pt1 Si1 Pt1 0.0 2_548 2_548
C7 Si1 C1 C2 68.8(4) . .
Pt1 Si1 C1 C2 -150.2(3) 2_548 .
Pt1 Si1 C1 C2 -67.7(4) . .
C7 Si1 C1 C6 -110.5(3) . .
Pt1 Si1 C1 C6 30.5(4) 2_548 .
Pt1 Si1 C1 C6 113.0(3) . .
C6 C1 C2 C3 -0.1(6) . .
Si1 C1 C2 C3 -179.4(4) . .
C1 C2 C3 C4 -0.6(8) . .
C2 C3 C4 C5 0.8(8) . .
C3 C4 C5 C6 -0.3(8) . .
C4 C5 C6 C1 -0.4(7) . .
C2 C1 C6 C5 0.6(6) . .
Si1 C1 C6 C5 179.9(4) . .
C1 Si1 C7 C8 20.5(4) . .
Pt1 Si1 C7 C8 -121.9(3) 2_548 .
Pt1 Si1 C7 C8 158.5(3) . .
C1 Si1 C7 C12 -161.3(3) . .
Pt1 Si1 C7 C12 56.2(3) 2_548 .
Pt1 Si1 C7 C12 -23.4(4) . .
C12 C7 C8 C9 0.0(6) . .
Si1 C7 C8 C9 178.1(3) . .
C7 C8 C9 C10 0.4(7) . .
C8 C9 C10 C11 -0.2(8) . .
C9 C10 C11 C12 -0.4(8) . .
C10 C11 C12 C7 0.8(7) . .
C8 C7 C12 C11 -0.6(6) . .
Si1 C7 C12 C11 -178.8(4) . .
C25 P1 C13 C18 -15.7(4) . .
C19 P1 C13 C18 90.6(4) . .
Pt1 P1 C13 C18 -137.9(3) . .
C25 P1 C13 C14 163.5(3) . .
C19 P1 C13 C14 -90.3(3) . .
Pt1 P1 C13 C14 41.3(3) . .
C18 C13 C14 C15 -1.2(6) . .
P1 C13 C14 C15 179.6(4) . .
C13 C14 C15 C16 1.4(7) . .
C14 C15 C16 C17 -0.5(8) . .
C15 C16 C17 C18 -0.5(7) . .
C14 C13 C18 C17 0.2(6) . .
P1 C13 C18 C17 179.4(3) . .
C16 C17 C18 C13 0.6(7) . .
C25 P1 C19 C20 101.3(3) . .
C13 P1 C19 C20 -8.5(3) . .
Pt1 P1 C19 C20 -133.1(3) . .
C25 P1 C19 C24 -75.4(3) . .
C13 P1 C19 C24 174.8(3) . .
Pt1 P1 C19 C24 50.2(3) . .
C24 C19 C20 C21 -0.1(6) . .
P1 C19 C20 C21 -176.9(3) . .
C19 C20 C21 C22 0.3(6) . .
C20 C21 C22 C23 -0.3(7) . .
C21 C22 C23 C24 0.1(7) . .
C22 C23 C24 C19 0.1(7) . .
C20 C19 C24 C23 -0.1(6) . .
P1 C19 C24 C23 176.8(3) . .
C13 P1 C25 C30 -100.5(3) . .
C19 P1 C25 C30 152.5(3) . .
Pt1 P1 C25 C30 20.8(3) . .
C13 P1 C25 C26 80.8(4) . .
C19 P1 C25 C26 -26.3(4) . .
Pt1 P1 C25 C26 -158.0(3) . .
C30 C25 C26 C27 2.0(6) . .
P1 C25 C26 C27 -179.2(4) . .
C25 C26 C27 C28 0.1(7) . .
C26 C27 C28 C29 -1.7(8) . .
C27 C28 C29 C30 1.2(8) . .
C26 C25 C30 C29 -2.6(6) . .
P1 C25 C30 C29 178.7(4) . .
C28 C29 C30 C25 1.0(7) . .
C1S C2S C3S C4S 0.5(14) . .
C2S C3S C4S C5S 0.4(16) . .
