#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/39/4083901.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4083901
loop_
_publ_author_name
'Hoffmann, Florian'
'Wagler, Jörg'
'Roewer, Gerhard'
_publ_section_title
;
 Cyclopentadienone and Hydroxycyclopentadienyl Cobalt Complexes from
 the Reaction of an Alkynylphenylsilane with Co2(CO)8
;
_journal_issue                   20
_journal_name_full               Organometallics
_journal_page_first              5622
_journal_paper_doi               10.1021/om500488w
_journal_volume                  33
_journal_year                    2014
_chemical_formula_moiety         'C58 H72 Co2 O6 Si4'
_chemical_formula_sum            'C58 H72 Co2 O6 Si4'
_chemical_formula_weight         1095.38
_chemical_melting_point          443
_chemical_name_common
;
di-mu-carbonyl-dicarbonyl-bis[2,5-bis(phenyldimethylsilyl)-3,4-dipropyl-
cyclopentadienone]dicobalt 
;
_chemical_name_systematic
; 
 di-mu-carbonyl-dicarbonyl-bis[(2,3,4,5-eta)-2,5-bis[dimethyl(phenyl)silyl]-
3,4-dipropyl-cyclopenta-2,4-dien-1-one]bis[cobalt(0)](Co-Co)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.082(5)
_cell_angle_beta                 96.135(5)
_cell_angle_gamma                111.999(5)
_cell_formula_units_Z            2
_cell_length_a                   11.5600(10)
_cell_length_b                   12.8939(13)
_cell_length_c                   20.363(2)
_cell_measurement_reflns_used    6528
_cell_measurement_temperature    93(2)
_cell_measurement_theta_max      26.97
_cell_measurement_theta_min      2.20
_cell_volume                     2795.2(5)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'ORTEP32 (Farugia)'
_computing_publication_material  'Ciftab (Sheldrick)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      93(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0403
_diffrn_reflns_av_sigmaI/netI    0.0540
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            28808
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         1.91
_exptl_absorpt_coefficient_mu    0.727
_exptl_absorpt_correction_T_max  0.9374
_exptl_absorpt_correction_T_min  0.8799
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.301
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       polyhedron
_exptl_crystal_F_000             1156
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.09
_refine_diff_density_max         0.688
_refine_diff_density_min         -0.381
_refine_diff_density_rms         0.066
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     634
_refine_ls_number_reflns         9903
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.0607
_refine_ls_R_factor_gt           0.0371
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0448P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0836
_refine_ls_wR_factor_ref         0.0902
_reflns_number_gt                7487
_reflns_number_total             9903
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om500488w_si_001.cif
_cod_data_source_block           fh23_compound_3
_cod_original_cell_volume        2795.3(5)
_cod_original_sg_symbol_Hall     -P1
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4083901
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Co11 Co 0.02874(3) 0.59423(3) 0.030391(16) 0.01200(9) Uani 0.97 1 d P 1
Co12 Co 0.0010(10) 0.5947(10) -0.0206(6) 0.01200(9) Uani 0.03 1 d P 2
Si1 Si -0.18056(7) 0.68781(6) 0.11273(4) 0.02014(18) Uani 1 1 d . .
Si2 Si 0.34249(7) 0.81271(6) 0.06340(4) 0.01917(17) Uani 1 1 d . .
O1 O -0.23368(16) 0.44801(15) 0.01834(8) 0.0183(4) Uani 1 1 d . .
O2 O -0.01743(17) 0.72858(16) -0.07939(9) 0.0253(5) Uani 1 1 d . .
O3 O 0.09178(16) 0.85933(15) 0.08440(9) 0.0219(4) Uani 1 1 d . .
C1 C -0.1712(3) 0.8374(2) 0.00757(14) 0.0256(7) Uani 1 1 d . .
H1 H -0.1070 0.8919 0.0363 0.031 Uiso 1 1 calc R .
C2 C -0.2057(3) 0.8670(3) -0.05543(15) 0.0303(7) Uani 1 1 d . .
H2 H -0.1646 0.9409 -0.0692 0.036 Uiso 1 1 calc R .
C3 C -0.2986(3) 0.7897(3) -0.09715(15) 0.0307(7) Uani 1 1 d . .
H3 H -0.3218 0.8103 -0.1398 0.037 Uiso 1 1 calc R .
C4 C -0.3595(3) 0.6809(3) -0.07767(15) 0.0310(7) Uani 1 1 d . .
H4 H -0.4241 0.6273 -0.1067 0.037 Uiso 1 1 calc R .
C5 C -0.3243(3) 0.6524(2) -0.01548(14) 0.0256(7) Uani 1 1 d . .
H5 H -0.3658 0.5781 -0.0023 0.031 Uiso 1 1 calc R .
C6 C -0.2295(2) 0.7290(2) 0.02908(13) 0.0199(6) Uani 1 1 d . .
C7 C -0.1459(3) 0.8042(2) 0.17602(14) 0.0286(7) Uani 1 1 d . .
H7A H -0.0792 0.8716 0.1631 0.043 Uiso 1 1 d R .
H7B H -0.1186 0.7821 0.2191 0.043 Uiso 1 1 d R .
H7C H -0.2219 0.8200 0.1790 0.043 Uiso 1 1 d R .
C8 C -0.3120(2) 0.5625(2) 0.13709(14) 0.0271(7) Uani 1 1 d . .
H8A H -0.3883 0.5791 0.1356 0.041 Uiso 1 1 d R .
H8B H -0.2898 0.5437 0.1821 0.041 Uiso 1 1 d R .
H8C H -0.3270 0.4991 0.1064 0.041 Uiso 1 1 d R .
C9 C 0.2597(3) 0.9087(2) -0.04993(14) 0.0268(7) Uani 1 1 d . .
H9 H 0.2355 0.9496 -0.0189 0.032 Uiso 1 1 calc R .
C10 C 0.2349(3) 0.9209(3) -0.11715(14) 0.0315(7) Uani 1 1 d . .
H10 H 0.1940 0.9699 -0.1315 0.038 Uiso 1 1 calc R .
C11 C 0.2690(3) 0.8626(3) -0.16325(15) 0.0353(8) Uani 1 1 d . .
H11 H 0.2493 0.8694 -0.2091 0.042 Uiso 1 1 calc R .
C12 C 0.3325(3) 0.7937(2) -0.14200(14) 0.0320(7) Uani 1 1 d . .
H12 H 0.3585 0.7548 -0.1734 0.038 Uiso 1 1 calc R .
C13 C 0.3579(3) 0.7821(2) -0.07481(14) 0.0259(7) Uani 1 1 d . .
H13 H 0.4023 0.7356 -0.0609 0.031 Uiso 1 1 calc R .
C14 C 0.3199(2) 0.8369(2) -0.02702(13) 0.0198(6) Uani 1 1 d . .
C15 C 0.3911(2) 0.9473(2) 0.11165(14) 0.0246(6) Uani 1 1 d . .
H15A H 0.3832 0.9325 0.1585 0.037 Uiso 1 1 d R .
H15B H 0.3371 0.9873 0.0956 0.037 Uiso 1 1 d R .
H15C H 0.4786 0.9931 0.1063 0.037 Uiso 1 1 d R .
C16 C 0.4700(2) 0.7564(2) 0.07893(14) 0.0284(7) Uani 1 1 d . .
H16A H 0.5472 0.8091 0.0637 0.043 Uiso 1 1 d R .
H16B H 0.4445 0.6840 0.0549 0.043 Uiso 1 1 d R .
H16C H 0.4850 0.7467 0.1264 0.043 Uiso 1 1 d R .
C17 C -0.1290(2) 0.4708(2) 0.01056(12) 0.0150(5) Uani 1 1 d . .
C18 C 0.0023(2) 0.6775(2) -0.03709(13) 0.0182(6) Uani 1 1 d . .
C19 C 0.0854(2) 0.7625(2) 0.09455(12) 0.0167(6) Uani 1 1 d . .
C20 C 0.1855(2) 0.7179(2) 0.08943(12) 0.0169(6) Uani 1 1 d . .
C21 C 0.1450(2) 0.6126(2) 0.11935(12) 0.0169(6) Uani 1 1 d . .
C22 C 0.0144(2) 0.5809(2) 0.13196(12) 0.0162(6) Uani 1 1 d . .
C23 C -0.0279(2) 0.6665(2) 0.10976(12) 0.0165(6) Uani 1 1 d . .
C24 C 0.2259(2) 0.5479(2) 0.14184(12) 0.0176(6) Uani 1 1 d . .
H24A H 0.2876 0.5562 0.1101 0.021 Uiso 1 1 calc R .
H24B H 0.1725 0.4674 0.1426 0.021 Uiso 1 1 calc R .
C25 C 0.2960(3) 0.5900(3) 0.21140(13) 0.0257(7) Uani 1 1 d . .
H25A H 0.3477 0.6709 0.2108 0.031 Uiso 1 1 calc R .
H25B H 0.2341 0.5803 0.2432 0.031 Uiso 1 1 calc R .
C26 C 0.3794(3) 0.5277(3) 0.23393(14) 0.0337(8) Uani 1 1 d . .
H26A H 0.3288 0.4474 0.2333 0.050 Uiso 1 1 d R .
H26B H 0.4192 0.5540 0.2790 0.050 Uiso 1 1 d R .
H26C H 0.4443 0.5413 0.2042 0.050 Uiso 1 1 d R .
C27 C -0.0571(2) 0.4802(2) 0.16912(12) 0.0180(6) Uani 1 1 d . .
H27A H -0.0209 0.4222 0.1653 0.022 Uiso 1 1 calc R .
H27B H -0.1459 0.4482 0.1493 0.022 Uiso 1 1 calc R .
C28 C -0.0513(3) 0.5123(2) 0.24271(13) 0.0234(6) Uani 1 1 d . .
H28A H 0.0377 0.5454 0.2621 0.028 Uiso 1 1 calc R .
H28B H -0.0880 0.5699 0.2462 0.028 Uiso 1 1 calc R .
C29 C -0.1209(3) 0.4130(3) 0.28201(13) 0.0296(7) Uani 1 1 d . .
H29A H -0.2100 0.3825 0.2646 0.044 Uiso 1 1 d R .
H29B H -0.1120 0.4372 0.3286 0.044 Uiso 1 1 d R .
H29C H -0.0856 0.3553 0.2783 0.044 Uiso 1 1 d R .
Co2 Co 0.99295(3) 0.92103(3) 0.459895(16) 0.01294(9) Uani 1 1 d . .
Si3 Si 0.71163(7) 0.67547(6) 0.40539(4) 0.01755(17) Uani 1 1 d . .
Si4 Si 1.23098(7) 0.90837(6) 0.35545(4) 0.01735(17) Uani 1 1 d . .
O4 O 1.07105(17) 0.76623(16) 0.54345(9) 0.0257(5) Uani 1 1 d . .
O5 O 1.23284(16) 1.10636(15) 0.48037(9) 0.0215(4) Uani 1 1 d . .
O6 O 0.98503(16) 0.69482(15) 0.37221(8) 0.0189(4) Uani 1 1 d . .
C30 C 1.3672(3) 1.1126(3) 0.29472(15) 0.0297(7) Uani 1 1 d . .
H30 H 1.3101 1.0813 0.2562 0.036 Uiso 1 1 calc R .
C31 C 1.4645(3) 1.2181(3) 0.29283(18) 0.0394(9) Uani 1 1 d . .
H31 H 1.4726 1.2583 0.2534 0.047 Uiso 1 1 calc R .
C32 C 1.5479(3) 1.2625(3) 0.34849(18) 0.0404(8) Uani 1 1 d . .
H32 H 1.6132 1.3339 0.3472 0.048 Uiso 1 1 calc R .
C33 C 1.5386(3) 1.2056(3) 0.40572(16) 0.0357(8) Uani 1 1 d . .
H33 H 1.5976 1.2367 0.4436 0.043 Uiso 1 1 calc R .
C34 C 1.4421(2) 1.1024(2) 0.40758(14) 0.0273(7) Uani 1 1 d . .
H34 H 1.4356 1.0634 0.4474 0.033 Uiso 1 1 calc R .
C35 C 1.3537(2) 1.0535(2) 0.35259(13) 0.0207(6) Uani 1 1 d . .
C36 C 1.2059(3) 0.8341(2) 0.27341(14) 0.0295(7) Uani 1 1 d . .
H36A H 1.1745 0.8740 0.2394 0.044 Uiso 1 1 d R .
H36B H 1.1443 0.7576 0.2749 0.044 Uiso 1 1 d R .
H36C H 1.2855 0.8318 0.2627 0.044 Uiso 1 1 d R .
C37 C 1.2880(3) 0.8351(3) 0.42246(15) 0.0309(7) Uani 1 1 d . .
H37A H 1.2265 0.7586 0.4243 0.046 Uiso 1 1 d R .
H37B H 1.2990 0.8755 0.4649 0.046 Uiso 1 1 d R .
H37C H 1.3686 0.8326 0.4135 0.046 Uiso 1 1 d R .
C38 C 0.8168(3) 0.5361(2) 0.47903(15) 0.0305(7) Uani 1 1 d . .
H38 H 0.8426 0.5224 0.4382 0.037 Uiso 1 1 calc R .
C39 C 0.8462(3) 0.4852(3) 0.53529(17) 0.0428(9) Uani 1 1 d . .
H39 H 0.8910 0.4371 0.5326 0.051 Uiso 1 1 calc R .
C40 C 0.8103(3) 0.5049(3) 0.59422(18) 0.0498(10) Uani 1 1 d . .
H40 H 0.8313 0.4710 0.6327 0.060 Uiso 1 1 calc R .
C41 C 0.7436(3) 0.5738(3) 0.59854(16) 0.0495(10) Uani 1 1 d . .
H41 H 0.7185 0.5865 0.6397 0.059 Uiso 1 1 calc R .
C42 C 0.7133(3) 0.6246(3) 0.54215(15) 0.0342(7) Uani 1 1 d . .
H42 H 0.6672 0.6716 0.5452 0.041 Uiso 1 1 calc R .
C43 C 0.7503(2) 0.6066(2) 0.48113(13) 0.0231(6) Uani 1 1 d . .
C44 C 0.5678(2) 0.7051(2) 0.41438(14) 0.0250(7) Uani 1 1 d . .
H44A H 0.4992 0.6356 0.4229 0.038 Uiso 1 1 d R .
H44B H 0.5436 0.7358 0.3736 0.038 Uiso 1 1 d R .
H44C H 0.5852 0.7595 0.4514 0.038 Uiso 1 1 d R .
C45 C 0.6797(2) 0.5808(2) 0.33076(13) 0.0224(6) Uani 1 1 d . .
H45A H 0.7520 0.5597 0.3273 0.034 Uiso 1 1 d R .
H45B H 0.6655 0.6196 0.2912 0.034 Uiso 1 1 d R .
H45C H 0.6050 0.5134 0.3345 0.034 Uiso 1 1 d R .
C46 C 1.0403(2) 0.8265(2) 0.51229(13) 0.0185(6) Uani 1 1 d . .
C47 C 1.1283(2) 1.0584(2) 0.48890(12) 0.0157(6) Uani 1 1 d . .
C48 C 0.9710(2) 0.7847(2) 0.37561(12) 0.0153(6) Uani 1 1 d . .
C49 C 0.8550(2) 0.8021(2) 0.38987(12) 0.0144(5) Uani 1 1 d . .
C50 C 0.8733(2) 0.9137(2) 0.37384(12) 0.0143(5) Uani 1 1 d . .
C51 C 1.0041(2) 0.9738(2) 0.36258(11) 0.0136(5) Uani 1 1 d . .
C52 C 1.0684(2) 0.8988(2) 0.37080(12) 0.0146(6) Uani 1 1 d . .
C53 C 0.7712(2) 0.9607(2) 0.36372(12) 0.0185(6) Uani 1 1 d . .
H53A H 0.8098 1.0435 0.3667 0.022 Uiso 1 1 calc R .
H53B H 0.7158 0.9361 0.3992 0.022 Uiso 1 1 calc R .
C54 C 0.6926(2) 0.9220(2) 0.29642(13) 0.0226(6) Uani 1 1 d . .
H54A H 0.7452 0.9557 0.2608 0.027 Uiso 1 1 calc R .
H54B H 0.6636 0.8396 0.2908 0.027 Uiso 1 1 calc R .
C55 C 0.5791(3) 0.9562(3) 0.29078(14) 0.0342(8) Uani 1 1 d . .
H55A H 0.5247 0.9197 0.3245 0.051 Uiso 1 1 d R .
H55B H 0.5320 0.9333 0.2468 0.051 Uiso 1 1 d R .
H55C H 0.6077 1.0377 0.2974 0.051 Uiso 1 1 d R .
C56 C 1.0582(2) 1.0910(2) 0.34004(12) 0.0168(6) Uani 1 1 d . .
H56A H 1.1485 1.1249 0.3571 0.020 Uiso 1 1 calc R .
H56B H 1.0155 1.1360 0.3587 0.020 Uiso 1 1 calc R .
C57 C 1.0439(2) 1.0954(2) 0.26414(12) 0.0200(6) Uani 1 1 d . .
H57A H 1.0824 1.0469 0.2452 0.024 Uiso 1 1 calc R .
H57B H 0.9536 1.0660 0.2472 0.024 Uiso 1 1 calc R .
C58 C 1.1064(3) 1.2145(2) 0.24205(14) 0.0297(7) Uani 1 1 d . .
H58A H 1.0695 1.2629 0.2614 0.044 Uiso 1 1 d R .
H58B H 1.0931 1.2149 0.1937 0.044 Uiso 1 1 d R .
H58C H 1.1967 1.2423 0.2568 0.044 Uiso 1 1 d R .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C18 Co11 C17 98.72(10) . 2_565
C18 Co11 C17 95.42(11) . .
C17 Co11 C17 96.83(10) 2_565 .
C18 Co11 C21 139.85(11) . .
C17 Co11 C21 89.08(10) 2_565 .
C17 Co11 C21 122.84(10) . .
C18 Co11 C22 139.46(10) . .
C17 Co11 C22 120.18(10) 2_565 .
C17 Co11 C22 91.08(10) . .
C21 Co11 C22 40.80(9) . .
C18 Co11 C23 100.29(10) . .
C17 Co11 C23 156.11(10) 2_565 .
C17 Co11 C23 95.65(10) . .
C21 Co11 C23 67.04(9) . .
C22 Co11 C23 39.19(9) . .
C18 Co11 C20 100.84(11) . .
C17 Co11 C20 94.81(10) 2_565 .
C17 Co11 C20 158.31(10) . .
C21 Co11 C20 39.06(10) . .
C22 Co11 C20 67.24(10) . .
C23 Co11 C20 67.49(9) . .
C18 Co11 C19 83.85(10) . .
C17 Co11 C19 131.21(10) 2_565 .
C17 Co11 C19 131.64(9) . .
C21 Co11 C19 62.42(9) . .
C22 Co11 C19 62.71(9) . .
C23 Co11 C19 38.20(9) . .
C20 Co11 C19 38.03(8) . .
C18 Co11 Co11 100.68(8) . 2_565
C17 Co11 Co11 48.48(8) 2_565 2_565
C17 Co11 Co11 48.35(7) . 2_565
C21 Co11 Co11 113.39(7) . 2_565
C22 Co11 Co11 113.11(7) . 2_565
C23 Co11 Co11 139.67(7) . 2_565
C20 Co11 Co11 139.80(7) . 2_565
C19 Co11 Co11 175.46(6) . 2_565
C18 Co12 C17 130.9(8) . .
C18 Co12 C17 132.9(8) . 2_565
C17 Co12 C17 96.1(5) . 2_565
C18 Co12 O2 16.5(4) . .
C17 Co12 O2 128.0(6) . .
C17 Co12 O2 132.4(6) 2_565 .
C18 Co12 Co12 178.5(11) . 2_565
C17 Co12 Co12 48.9(4) . 2_565
C17 Co12 Co12 47.2(4) 2_565 2_565
O2 Co12 Co12 165.0(8) . 2_565
C8 Si1 C7 108.45(13) . .
C8 Si1 C6 108.86(13) . .
C7 Si1 C6 110.52(13) . .
C8 Si1 C23 114.40(12) . .
C7 Si1 C23 105.97(12) . .
C6 Si1 C23 108.60(11) . .
C15 Si2 C16 108.47(13) . .
C15 Si2 C14 109.65(12) . .
C16 Si2 C14 108.96(12) . .
C15 Si2 C20 106.89(12) . .
C16 Si2 C20 114.20(12) . .
C14 Si2 C20 108.59(11) . .
C6 C1 C2 121.3(3) . .
C6 C1 H1 119.4 . .
C2 C1 H1 119.4 . .
C3 C2 C1 120.0(3) . .
C3 C2 H2 120.0 . .
C1 C2 H2 120.0 . .
C2 C3 C4 120.6(3) . .
C2 C3 H3 119.7 . .
C4 C3 H3 119.7 . .
C5 C4 C3 118.9(3) . .
C5 C4 H4 120.6 . .
C3 C4 H4 120.6 . .
C4 C5 C6 122.5(3) . .
C4 C5 H5 118.7 . .
C6 C5 H5 118.7 . .
C1 C6 C5 116.7(3) . .
C1 C6 Si1 121.4(2) . .
C5 C6 Si1 121.9(2) . .
Si1 C7 H7A 109.5 . .
Si1 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
Si1 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
Si1 C8 H8A 109.5 . .
Si1 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
Si1 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C10 C9 C14 121.2(3) . .
C10 C9 H9 119.4 . .
C14 C9 H9 119.4 . .
C11 C10 C9 120.6(3) . .
C11 C10 H10 119.7 . .
C9 C10 H10 119.7 . .
C10 C11 C12 119.5(3) . .
C10 C11 H11 120.3 . .
C12 C11 H11 120.3 . .
C13 C12 C11 119.8(3) . .
C13 C12 H12 120.1 . .
C11 C12 H12 120.1 . .
C12 C13 C14 121.9(3) . .
C12 C13 H13 119.1 . .
C14 C13 H13 119.1 . .
C13 C14 C9 117.0(3) . .
C13 C14 Si2 122.1(2) . .
C9 C14 Si2 120.9(2) . .
Si2 C15 H15A 109.5 . .
Si2 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
Si2 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
Si2 C16 H16A 109.5 . .
Si2 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
Si2 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
O1 C17 Co12 136.6(4) . .
O1 C17 Co11 138.5(2) . 2_565
Co12 C17 Co11 75.4(3) . 2_565
O1 C17 Co11 138.3(2) . .
Co11 C17 Co11 83.17(10) 2_565 .
O1 C17 Co12 139.6(4) . 2_565
Co12 C17 Co12 83.9(5) . 2_565
Co11 C17 Co12 74.1(4) . 2_565
Co12 C18 O2 147.4(7) . .
O2 C18 Co11 178.3(2) . .
O3 C19 C20 127.0(2) . .
O3 C19 C23 126.2(2) . .
C20 C19 C23 106.7(2) . .
O3 C19 Co11 136.33(19) . .
C20 C19 Co11 63.27(13) . .
C23 C19 Co11 62.82(13) . .
C21 C20 C19 106.0(2) . .
C21 C20 Si2 133.01(19) . .
C19 C20 Si2 119.68(18) . .
C21 C20 Co11 68.21(15) . .
C19 C20 Co11 78.69(14) . .
Si2 C20 Co11 128.63(13) . .
C20 C21 C22 109.5(2) . .
C20 C21 C24 126.2(2) . .
C22 C21 C24 124.0(2) . .
C20 C21 Co11 72.72(15) . .
C22 C21 Co11 69.64(14) . .
C24 C21 Co11 128.83(18) . .
C23 C22 C21 108.5(2) . .
C23 C22 C27 126.3(2) . .
C21 C22 C27 124.8(2) . .
C23 C22 Co11 72.20(14) . .
C21 C22 Co11 69.56(13) . .
C27 C22 Co11 129.08(18) . .
C22 C23 C19 106.4(2) . .
C22 C23 Si1 133.1(2) . .
C19 C23 Si1 119.19(18) . .
C22 C23 Co11 68.60(13) . .
C19 C23 Co11 78.98(14) . .
Si1 C23 Co11 128.12(13) . .
C21 C24 C25 111.1(2) . .
C21 C24 H24A 109.4 . .
C25 C24 H24A 109.4 . .
C21 C24 H24B 109.4 . .
C25 C24 H24B 109.4 . .
H24A C24 H24B 108.0 . .
C26 C25 C24 111.7(2) . .
C26 C25 H25A 109.3 . .
C24 C25 H25A 109.3 . .
C26 C25 H25B 109.3 . .
C24 C25 H25B 109.3 . .
H25A C25 H25B 107.9 . .
C25 C26 H26A 109.5 . .
C25 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C25 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
C22 C27 C28 110.9(2) . .
C22 C27 H27A 109.5 . .
C28 C27 H27A 109.5 . .
C22 C27 H27B 109.5 . .
C28 C27 H27B 109.5 . .
H27A C27 H27B 108.0 . .
C29 C28 C27 112.6(2) . .
C29 C28 H28A 109.1 . .
C27 C28 H28A 109.1 . .
C29 C28 H28B 109.1 . .
C27 C28 H28B 109.1 . .
H28A C28 H28B 107.8 . .
C28 C29 H29A 109.5 . .
C28 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
C28 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
C46 Co2 C47 98.85(11) . .
C46 Co2 C47 99.41(11) . 2_776
C47 Co2 C47 96.56(11) . 2_776
C46 Co2 C50 138.96(11) . .
C47 Co2 C50 120.13(10) . .
C47 Co2 C50 89.06(10) 2_776 .
C46 Co2 C51 138.55(10) . .
C47 Co2 C51 88.86(10) . .
C47 Co2 C51 120.21(10) 2_776 .
C50 Co2 C51 40.83(9) . .
C46 Co2 C49 99.96(11) . .
C47 Co2 C49 156.14(10) . .
C47 Co2 C49 94.70(10) 2_776 .
C50 Co2 C49 39.07(9) . .
C51 Co2 C49 67.30(10) . .
C46 Co2 C52 99.50(10) . .
C47 Co2 C52 95.17(10) . .
C47 Co2 C52 155.88(10) 2_776 .
C50 Co2 C52 66.84(9) . .
C51 Co2 C52 39.07(9) . .
C49 Co2 C52 67.33(9) . .
C46 Co2 C48 82.76(10) . .
C47 Co2 C48 131.51(10) . .
C47 Co2 C48 131.26(10) 2_776 .
C50 Co2 C48 62.50(9) . .
C51 Co2 C48 62.70(9) . .
C49 Co2 C48 38.19(8) . .
C52 Co2 C48 37.98(9) . .
C46 Co2 Co2 103.80(8) . 2_776
C47 Co2 Co2 48.53(7) . 2_776
C47 Co2 Co2 48.04(8) 2_776 2_776
C50 Co2 Co2 111.30(7) . 2_776
C51 Co2 Co2 111.39(7) . 2_776
C49 Co2 Co2 138.28(6) . 2_776
C52 Co2 Co2 139.10(7) . 2_776
C48 Co2 Co2 173.44(6) . 2_776
C45 Si3 C44 108.45(12) . .
C45 Si3 C43 110.22(13) . .
C44 Si3 C43 109.23(12) . .
C45 Si3 C49 104.42(11) . .
C44 Si3 C49 115.03(12) . .
C43 Si3 C49 109.37(12) . .
C37 Si4 C36 111.53(14) . .
C37 Si4 C35 107.91(13) . .
C36 Si4 C35 108.91(13) . .
C37 Si4 C52 107.77(11) . .
C36 Si4 C52 104.26(12) . .
C35 Si4 C52 116.49(11) . .
C35 C30 C31 120.7(3) . .
C35 C30 H30 119.7 . .
C31 C30 H30 119.7 . .
C32 C31 C30 119.5(3) . .
C32 C31 H31 120.3 . .
C30 C31 H31 120.3 . .
C33 C32 C31 121.3(3) . .
C33 C32 H32 119.4 . .
C31 C32 H32 119.4 . .
C32 C33 C34 119.1(3) . .
C32 C33 H33 120.5 . .
C34 C33 H33 120.5 . .
C33 C34 C35 122.2(3) . .
C33 C34 H34 118.9 . .
C35 C34 H34 118.9 . .
C30 C35 C34 117.3(3) . .
C30 C35 Si4 121.8(2) . .
C34 C35 Si4 120.7(2) . .
Si4 C36 H36A 109.5 . .
Si4 C36 H36B 109.5 . .
H36A C36 H36B 109.5 . .
Si4 C36 H36C 109.5 . .
H36A C36 H36C 109.5 . .
H36B C36 H36C 109.5 . .
Si4 C37 H37A 109.5 . .
Si4 C37 H37B 109.5 . .
H37A C37 H37B 109.5 . .
Si4 C37 H37C 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
C39 C38 C43 121.7(3) . .
C39 C38 H38 119.2 . .
C43 C38 H38 119.2 . .
C40 C39 C38 119.7(3) . .
C40 C39 H39 120.2 . .
C38 C39 H39 120.2 . .
C39 C40 C41 120.6(3) . .
C39 C40 H40 119.7 . .
C41 C40 H40 119.7 . .
C40 C41 C42 119.9(3) . .
C40 C41 H41 120.0 . .
C42 C41 H41 120.0 . .
C41 C42 C43 120.5(3) . .
C41 C42 H42 119.8 . .
C43 C42 H42 119.8 . .
C38 C43 C42 117.6(3) . .
C38 C43 Si3 121.6(2) . .
C42 C43 Si3 120.8(2) . .
Si3 C44 H44A 109.5 . .
Si3 C44 H44B 109.5 . .
H44A C44 H44B 109.5 . .
Si3 C44 H44C 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
Si3 C45 H45A 109.5 . .
Si3 C45 H45B 109.5 . .
H45A C45 H45B 109.5 . .
Si3 C45 H45C 109.5 . .
H45A C45 H45C 109.5 . .
H45B C45 H45C 109.5 . .
O4 C46 Co2 177.9(2) . .
O5 C47 Co2 138.6(2) . .
O5 C47 Co2 137.9(2) . 2_776
Co2 C47 Co2 83.44(11) . 2_776
O6 C48 C52 127.0(2) . .
O6 C48 C49 126.9(2) . .
C52 C48 C49 106.0(2) . .
O6 C48 Co2 136.78(18) . .
C52 C48 Co2 62.95(13) . .
C49 C48 Co2 62.39(12) . .
C50 C49 C48 106.3(2) . .
C50 C49 Si3 133.37(18) . .
C48 C49 Si3 118.70(18) . .
C50 C49 Co2 68.43(14) . .
C48 C49 Co2 79.42(14) . .
Si3 C49 Co2 129.09(12) . .
C49 C50 C51 109.5(2) . .
C49 C50 C53 125.4(2) . .
C51 C50 C53 124.9(2) . .
C49 C50 Co2 72.50(14) . .
C51 C50 Co2 69.80(13) . .
C53 C50 Co2 128.26(17) . .
C52 C51 C50 108.5(2) . .
C52 C51 C56 125.7(2) . .
C50 C51 C56 125.6(2) . .
C52 C51 Co2 72.78(14) . .
C50 C51 Co2 69.37(13) . .
C56 C51 Co2 127.91(17) . .
C51 C52 C48 106.9(2) . .
C51 C52 Si4 133.59(19) . .
C48 C52 Si4 117.35(17) . .
C51 C52 Co2 68.15(13) . .
C48 C52 Co2 79.07(13) . .
Si4 C52 Co2 131.77(13) . .
C50 C53 C54 111.4(2) . .
C50 C53 H53A 109.3 . .
C54 C53 H53A 109.3 . .
C50 C53 H53B 109.3 . .
C54 C53 H53B 109.3 . .
H53A C53 H53B 108.0 . .
C55 C54 C53 110.8(2) . .
C55 C54 H54A 109.5 . .
C53 C54 H54A 109.5 . .
C55 C54 H54B 109.5 . .
C53 C54 H54B 109.5 . .
H54A C54 H54B 108.1 . .
C54 C55 H55A 109.5 . .
C54 C55 H55B 109.5 . .
H55A C55 H55B 109.5 . .
C54 C55 H55C 109.5 . .
H55A C55 H55C 109.5 . .
H55B C55 H55C 109.5 . .
C51 C56 C57 112.2(2) . .
C51 C56 H56A 109.2 . .
C57 C56 H56A 109.2 . .
C51 C56 H56B 109.2 . .
C57 C56 H56B 109.2 . .
H56A C56 H56B 107.9 . .
C58 C57 C56 111.4(2) . .
C58 C57 H57A 109.3 . .
C56 C57 H57A 109.3 . .
C58 C57 H57B 109.3 . .
C56 C57 H57B 109.3 . .
H57A C57 H57B 108.0 . .
C57 C58 H58A 109.5 . .
C57 C58 H58B 109.5 . .
H58A C58 H58B 109.5 . .
C57 C58 H58C 109.5 . .
H58A C58 H58C 109.5 . .
H58B C58 H58C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Co11 C18 1.815(3) .
Co11 C17 1.916(2) 2_565
Co11 C17 1.920(3) .
Co11 C21 2.094(3) .
Co11 C22 2.095(2) .
Co11 C23 2.142(2) .
Co11 C20 2.153(3) .
Co11 C19 2.364(3) .
Co11 Co11 2.5464(7) 2_565
Co12 C18 1.114(12) .
Co12 C17 1.903(12) .
Co12 C17 1.954(11) 2_565
Co12 O2 2.164(12) .
Co12 Co12 2.58(2) 2_565
Si1 C8 1.868(3) .
Si1 C7 1.873(3) .
Si1 C6 1.877(3) .
Si1 C23 1.892(2) .
Si2 C15 1.854(3) .
Si2 C16 1.871(3) .
Si2 C14 1.875(3) .
Si2 C20 1.901(3) .
O1 C17 1.163(3) .
O2 C18 1.140(3) .
O3 C19 1.242(3) .
C1 C6 1.399(4) .
C1 C2 1.399(4) .
C1 H1 0.9500 .
C2 C3 1.367(4) .
C2 H2 0.9500 .
C3 C4 1.394(4) .
C3 H3 0.9500 .
C4 C5 1.381(4) .
C4 H4 0.9500 .
C5 C6 1.405(4) .
C5 H5 0.9500 .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9799 .
C9 C10 1.390(4) .
C9 C14 1.405(4) .
C9 H9 0.9500 .
C10 C11 1.379(4) .
C10 H10 0.9500 .
C11 C12 1.392(4) .
C11 H11 0.9500 .
C12 C13 1.388(4) .
C12 H12 0.9500 .
C13 C14 1.400(4) .
C13 H13 0.9500 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C16 H16A 0.9801 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C17 Co11 1.916(2) 2_565
C17 Co12 1.954(11) 2_565
C19 C20 1.485(3) .
C19 C23 1.489(4) .
C20 C21 1.421(4) .
C21 C22 1.460(3) .
C21 C24 1.508(3) .
C22 C23 1.422(3) .
C22 C27 1.508(3) .
C24 C25 1.543(3) .
C24 H24A 0.9900 .
C24 H24B 0.9900 .
C25 C26 1.507(4) .
C25 H25A 0.9900 .
C25 H25B 0.9900 .
C26 H26A 0.9800 .
C26 H26B 0.9800 .
C26 H26C 0.9800 .
C27 C28 1.542(3) .
C27 H27A 0.9900 .
C27 H27B 0.9900 .
C28 C29 1.515(4) .
C28 H28A 0.9900 .
C28 H28B 0.9900 .
C29 H29A 0.9800 .
C29 H29B 0.9799 .
C29 H29C 0.9800 .
Co2 C46 1.817(3) .
Co2 C47 1.912(3) .
Co2 C47 1.927(2) 2_776
Co2 C50 2.092(2) .
Co2 C51 2.098(2) .
Co2 C49 2.145(3) .
Co2 C52 2.159(2) .
Co2 C48 2.380(2) .
Co2 Co2 2.5548(7) 2_776
Si3 C45 1.864(3) .
Si3 C44 1.866(3) .
Si3 C43 1.877(3) .
Si3 C49 1.898(3) .
Si4 C37 1.862(3) .
Si4 C36 1.864(3) .
Si4 C35 1.883(3) .
Si4 C52 1.896(2) .
O4 C46 1.137(3) .
O5 C47 1.166(3) .
O6 C48 1.232(3) .
C30 C35 1.395(4) .
C30 C31 1.407(4) .
C30 H30 0.9500 .
C31 C32 1.376(5) .
C31 H31 0.9500 .
C32 C33 1.370(4) .
C32 H32 0.9500 .
C33 C34 1.383(4) .
C33 H33 0.9500 .
C34 C35 1.402(4) .
C34 H34 0.9500 .
C36 H36A 0.9800 .
C36 H36B 0.9800 .
C36 H36C 0.9800 .
C37 H37A 0.9800 .
C37 H37B 0.9800 .
C37 H37C 0.9800 .
C38 C39 1.394(4) .
C38 C43 1.396(4) .
C38 H38 0.9500 .
C39 C40 1.364(5) .
C39 H39 0.9500 .
C40 C41 1.385(5) .
C40 H40 0.9500 .
C41 C42 1.400(4) .
C41 H41 0.9500 .
C42 C43 1.403(4) .
C42 H42 0.9500 .
C44 H44A 0.9800 .
C44 H44B 0.9800 .
C44 H44C 0.9800 .
C45 H45A 0.9800 .
C45 H45B 0.9801 .
C45 H45C 0.9800 .
C47 Co2 1.927(2) 2_776
C48 C52 1.491(4) .
C48 C49 1.497(3) .
C49 C50 1.418(3) .
C50 C51 1.461(3) .
C50 C53 1.513(3) .
C51 C52 1.424(3) .
C51 C56 1.497(3) .
C53 C54 1.531(3) .
C53 H53A 0.9900 .
C53 H53B 0.9900 .
C54 C55 1.527(3) .
C54 H54A 0.9900 .
C54 H54B 0.9900 .
C55 H55A 0.9800 .
C55 H55B 0.9800 .
C55 H55C 0.9800 .
C56 C57 1.540(3) .
C56 H56A 0.9900 .
C56 H56B 0.9900 .
C57 C58 1.524(4) .
C57 H57A 0.9900 .
C57 H57B 0.9900 .
C58 H58A 0.9801 .
C58 H58B 0.9800 .
C58 H58C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C17 Co12 O2 C18 106.6(14) . .
C17 Co12 O2 C18 -99.5(15) 2_565 .
Co12 Co12 O2 C18 179(4) 2_565 .
C6 C1 C2 C3 0.5(4) . .
C1 C2 C3 C4 -0.2(4) . .
C2 C3 C4 C5 -0.1(4) . .
C3 C4 C5 C6 0.2(4) . .
C2 C1 C6 C5 -0.4(4) . .
C2 C1 C6 Si1 178.4(2) . .
C4 C5 C6 C1 0.1(4) . .
C4 C5 C6 Si1 -178.7(2) . .
C8 Si1 C6 C1 158.45(19) . .
C7 Si1 C6 C1 39.4(2) . .
C23 Si1 C6 C1 -76.4(2) . .
C8 Si1 C6 C5 -22.8(2) . .
C7 Si1 C6 C5 -141.8(2) . .
C23 Si1 C6 C5 102.3(2) . .
C14 C9 C10 C11 0.0(5) . .
C9 C10 C11 C12 -2.1(5) . .
C10 C11 C12 C13 1.7(4) . .
C11 C12 C13 C14 0.8(4) . .
C12 C13 C14 C9 -2.9(4) . .
C12 C13 C14 Si2 175.1(2) . .
C10 C9 C14 C13 2.5(4) . .
C10 C9 C14 Si2 -175.5(2) . .
C15 Si2 C14 C13 140.2(2) . .
C16 Si2 C14 C13 21.7(3) . .
C20 Si2 C14 C13 -103.3(2) . .
C15 Si2 C14 C9 -41.9(3) . .
C16 Si2 C14 C9 -160.5(2) . .
C20 Si2 C14 C9 74.5(2) . .
C18 Co12 C17 O1 2.8(15) . .
C17 Co12 C17 O1 -179.2(3) 2_565 .
O2 Co12 C17 O1 -18.3(11) . .
Co12 Co12 C17 O1 -179.2(3) 2_565 .
C18 Co12 C17 Co11 151.0(12) . 2_565
C17 Co12 C17 Co11 -31.0(3) 2_565 2_565
O2 Co12 C17 Co11 129.9(7) . 2_565
Co12 Co12 C17 Co11 -31.0(3) 2_565 2_565
C18 Co12 C17 Co11 -108.3(13) . .
C17 Co12 C17 Co11 69.7(5) 2_565 .
O2 Co12 C17 Co11 -129.4(10) . .
Co12 Co12 C17 Co11 69.7(5) 2_565 .
C18 Co12 C17 Co12 -178.0(15) . 2_565
C17 Co12 C17 Co12 0.0 2_565 2_565
O2 Co12 C17 Co12 160.9(10) . 2_565
C18 Co11 C17 O1 -79.0(3) . .
C17 Co11 C17 O1 -178.5(3) 2_565 .
C21 Co11 C17 O1 88.1(3) . .
C22 Co11 C17 O1 60.9(3) . .
C23 Co11 C17 O1 21.9(3) . .
C20 Co11 C17 O1 59.5(4) . .
C19 Co11 C17 O1 7.5(4) . .
Co11 Co11 C17 O1 -178.5(3) 2_565 .
C18 Co11 C17 Co12 26.3(6) . .
C17 Co11 C17 Co12 -73.2(6) 2_565 .
C21 Co11 C17 Co12 -166.6(6) . .
C22 Co11 C17 Co12 166.2(6) . .
C23 Co11 C17 Co12 127.2(6) . .
C20 Co11 C17 Co12 164.8(7) . .
C19 Co11 C17 Co12 112.8(6) . .
Co11 Co11 C17 Co12 -73.2(6) 2_565 .
C18 Co11 C17 Co11 99.49(10) . 2_565
C17 Co11 C17 Co11 0.0 2_565 2_565
C21 Co11 C17 Co11 -93.33(11) . 2_565
C22 Co11 C17 Co11 -120.58(9) . 2_565
C23 Co11 C17 Co11 -159.58(9) . 2_565
C20 Co11 C17 Co11 -122.0(2) . 2_565
C19 Co11 C17 Co11 -173.93(9) . 2_565
C18 Co11 C17 Co12 130.4(4) . 2_565
C17 Co11 C17 Co12 31.0(3) 2_565 2_565
C21 Co11 C17 Co12 -62.4(4) . 2_565
C22 Co11 C17 Co12 -89.6(4) . 2_565
C23 Co11 C17 Co12 -128.6(4) . 2_565
C20 Co11 C17 Co12 -91.0(4) . 2_565
C19 Co11 C17 Co12 -143.0(4) . 2_565
Co11 Co11 C17 Co12 31.0(3) 2_565 2_565
C17 Co12 C18 O2 -86.9(14) . .
C17 Co12 C18 O2 95.8(14) 2_565 .
C17 Co12 C18 Co11 90.1(13) . .
C17 Co12 C18 Co11 -87.2(14) 2_565 .
O2 Co12 C18 Co11 176.9(4) . .
C17 Co11 C18 Co12 49.0(10) 2_565 .
C17 Co11 C18 Co12 -48.8(10) . .
C21 Co11 C18 Co12 148.0(10) . .
C22 Co11 C18 Co12 -146.9(10) . .
C23 Co11 C18 Co12 -145.6(10) . .
C20 Co11 C18 Co12 145.6(10) . .
C19 Co11 C18 Co12 179.8(10) . .
Co11 Co11 C18 Co12 -0.2(10) 2_565 .
C18 Co11 C19 O3 0.3(3) . .
C17 Co11 C19 O3 96.5(3) 2_565 .
C17 Co11 C19 O3 -91.5(3) . .
C21 Co11 C19 O3 157.7(3) . .
C22 Co11 C19 O3 -156.0(3) . .
C23 Co11 C19 O3 -115.0(3) . .
C20 Co11 C19 O3 116.7(3) . .
C18 Co11 C19 C20 -116.39(16) . .
C17 Co11 C19 C20 -20.16(19) 2_565 .
C17 Co11 C19 C20 151.81(15) . .
C21 Co11 C19 C20 41.06(14) . .
C22 Co11 C19 C20 87.31(15) . .
C23 Co11 C19 C20 128.3(2) . .
C18 Co11 C19 C23 115.29(16) . .
C17 Co11 C19 C23 -148.48(15) 2_565 .
C17 Co11 C19 C23 23.5(2) . .
C21 Co11 C19 C23 -87.25(16) . .
C22 Co11 C19 C23 -41.00(14) . .
C20 Co11 C19 C23 -128.3(2) . .
O3 C19 C20 C21 167.4(3) . .
C23 C19 C20 C21 -16.4(3) . .
Co11 C19 C20 C21 -63.18(17) . .
O3 C19 C20 Si2 -1.2(4) . .
C23 C19 C20 Si2 175.01(17) . .
Co11 C19 C20 Si2 128.23(18) . .
O3 C19 C20 Co11 -129.4(3) . .
C23 C19 C20 Co11 46.78(17) . .
C15 Si2 C20 C21 -119.0(3) . .
C16 Si2 C20 C21 1.0(3) . .
C14 Si2 C20 C21 122.8(3) . .
C15 Si2 C20 C19 45.9(2) . .
C16 Si2 C20 C19 165.90(19) . .
C14 Si2 C20 C19 -72.3(2) . .
C15 Si2 C20 Co11 145.52(15) . .
C16 Si2 C20 Co11 -94.51(18) . .
C14 Si2 C20 Co11 27.29(19) . .
C18 Co11 C20 C21 177.57(14) . .
C17 Co11 C20 C21 -82.58(15) 2_565 .
C17 Co11 C20 C21 39.7(3) . .
C22 Co11 C20 C21 38.21(14) . .
C23 Co11 C20 C21 80.82(15) . .
C19 Co11 C20 C21 112.5(2) . .
Co11 Co11 C20 C21 -61.18(17) 2_565 .
C18 Co11 C20 C19 65.07(15) . .
C17 Co11 C20 C19 164.92(14) 2_565 .
C17 Co11 C20 C19 -72.8(3) . .
C21 Co11 C20 C19 -112.5(2) . .
C22 Co11 C20 C19 -74.30(15) . .
C23 Co11 C20 C19 -31.68(14) . .
Co11 Co11 C20 C19 -173.68(10) 2_565 .
C18 Co11 C20 Si2 -54.05(18) . .
C17 Co11 C20 Si2 45.80(17) 2_565 .
C17 Co11 C20 Si2 168.1(2) . .
C21 Co11 C20 Si2 128.4(2) . .
C22 Co11 C20 Si2 166.59(19) . .
C23 Co11 C20 Si2 -150.80(19) . .
C19 Co11 C20 Si2 -119.1(2) . .
Co11 Co11 C20 Si2 67.2(2) 2_565 .
C19 C20 C21 C22 10.2(3) . .
Si2 C20 C21 C22 176.6(2) . .
Co11 C20 C21 C22 -60.23(17) . .
C19 C20 C21 C24 -163.6(2) . .
Si2 C20 C21 C24 2.7(4) . .
Co11 C20 C21 C24 125.9(3) . .
C19 C20 C21 Co11 70.47(17) . .
Si2 C20 C21 Co11 -123.1(2) . .
C18 Co11 C21 C20 -3.7(2) . .
C17 Co11 C21 C20 98.78(15) 2_565 .
C17 Co11 C21 C20 -163.68(14) . .
C22 Co11 C21 C20 -119.2(2) . .
C23 Co11 C21 C20 -82.08(15) . .
C19 Co11 C21 C20 -39.96(13) . .
Co11 Co11 C21 C20 141.96(12) 2_565 .
C18 Co11 C21 C22 115.50(19) . .
C17 Co11 C21 C22 -142.01(16) 2_565 .
C17 Co11 C21 C22 -44.47(18) . .
C23 Co11 C21 C22 37.13(15) . .
C20 Co11 C21 C22 119.2(2) . .
C19 Co11 C21 C22 79.25(15) . .
Co11 Co11 C21 C22 -98.83(14) 2_565 .
C18 Co11 C21 C24 -126.6(2) . .
C17 Co11 C21 C24 -24.1(2) 2_565 .
C17 Co11 C21 C24 73.4(2) . .
C22 Co11 C21 C24 117.9(3) . .
C23 Co11 C21 C24 155.0(3) . .
C20 Co11 C21 C24 -122.9(3) . .
C19 Co11 C21 C24 -162.9(3) . .
Co11 Co11 C21 C24 19.0(2) 2_565 .
C20 C21 C22 C23 0.1(3) . .
C24 C21 C22 C23 174.2(2) . .
Co11 C21 C22 C23 -62.03(17) . .
C20 C21 C22 C27 -173.8(2) . .
C24 C21 C22 C27 0.3(4) . .
Co11 C21 C22 C27 124.1(2) . .
C20 C21 C22 Co11 62.14(18) . .
C24 C21 C22 Co11 -123.8(2) . .
C18 Co11 C22 C23 2.0(2) . .
C17 Co11 C22 C23 163.83(15) 2_565 .
C17 Co11 C22 C23 -97.63(16) . .
C21 Co11 C22 C23 118.4(2) . .
C20 Co11 C22 C23 81.81(16) . .
C19 Co11 C22 C23 39.94(14) . .
Co11 Co11 C22 C23 -142.01(13) 2_565 .
C18 Co11 C22 C21 -116.43(19) . .
C17 Co11 C22 C21 45.40(19) 2_565 .
C17 Co11 C22 C21 143.94(16) . .
C23 Co11 C22 C21 -118.4(2) . .
C20 Co11 C22 C21 -36.62(14) . .
C19 Co11 C22 C21 -78.48(16) . .
Co11 Co11 C22 C21 99.56(14) 2_565 .
C18 Co11 C22 C27 124.7(2) . .
C17 Co11 C22 C27 -73.5(2) 2_565 .
C17 Co11 C22 C27 25.1(2) . .
C21 Co11 C22 C27 -118.9(3) . .
C23 Co11 C22 C27 122.7(3) . .
C20 Co11 C22 C27 -155.5(2) . .
C19 Co11 C22 C27 162.6(2) . .
Co11 Co11 C22 C27 -19.3(2) 2_565 .
C21 C22 C23 C19 -10.4(3) . .
C27 C22 C23 C19 163.4(2) . .
Co11 C22 C23 C19 -70.77(17) . .
C21 C22 C23 Si1 -176.9(2) . .
C27 C22 C23 Si1 -3.1(4) . .
Co11 C22 C23 Si1 122.8(2) . .
C21 C22 C23 Co11 60.36(17) . .
C27 C22 C23 Co11 -125.9(3) . .
O3 C19 C23 C22 -167.2(2) . .
C20 C19 C23 C22 16.6(3) . .
Co11 C19 C23 C22 63.59(16) . .
O3 C19 C23 Si1 1.5(4) . .
C20 C19 C23 Si1 -174.73(16) . .
Co11 C19 C23 Si1 -127.71(18) . .
O3 C19 C23 Co11 129.2(3) . .
C20 C19 C23 Co11 -47.02(17) . .
C8 Si1 C23 C22 -11.6(3) . .
C7 Si1 C23 C22 107.8(3) . .
C6 Si1 C23 C22 -133.4(3) . .
C8 Si1 C23 C19 -176.66(19) . .
C7 Si1 C23 C19 -57.2(2) . .
C6 Si1 C23 C19 61.5(2) . .
C8 Si1 C23 Co11 84.12(19) . .
C7 Si1 C23 Co11 -156.45(16) . .
C6 Si1 C23 Co11 -37.7(2) . .
C18 Co11 C23 C22 -178.68(16) . .
C17 Co11 C23 C22 -36.5(3) 2_565 .
C17 Co11 C23 C22 84.75(16) . .
C21 Co11 C23 C22 -38.62(15) . .
C20 Co11 C23 C22 -81.12(16) . .
C19 Co11 C23 C22 -112.7(2) . .
Co11 Co11 C23 C22 61.00(18) 2_565 .
C18 Co11 C23 C19 -66.01(16) . .
C17 Co11 C23 C19 76.2(3) 2_565 .
C17 Co11 C23 C19 -162.58(15) . .
C21 Co11 C23 C19 74.06(15) . .
C22 Co11 C23 C19 112.7(2) . .
C20 Co11 C23 C19 31.55(14) . .
Co11 Co11 C23 C19 173.67(10) 2_565 .
C18 Co11 C23 Si1 52.60(19) . .
C17 Co11 C23 Si1 -165.2(2) 2_565 .
C17 Co11 C23 Si1 -43.97(18) . .
C21 Co11 C23 Si1 -167.3(2) . .
C22 Co11 C23 Si1 -128.7(3) . .
C20 Co11 C23 Si1 150.2(2) . .
C19 Co11 C23 Si1 118.6(2) . .
Co11 Co11 C23 Si1 -67.7(2) 2_565 .
C20 C21 C24 C25 83.3(3) . .
C22 C21 C24 C25 -89.7(3) . .
Co11 C21 C24 C25 -179.96(19) . .
C21 C24 C25 C26 -178.8(2) . .
C23 C22 C27 C28 -78.2(3) . .
C21 C22 C27 C28 94.6(3) . .
Co11 C22 C27 C28 -174.40(18) . .
C22 C27 C28 C29 -179.4(2) . .
C35 C30 C31 C32 0.7(4) . .
C30 C31 C32 C33 0.5(4) . .
C31 C32 C33 C34 -1.0(4) . .
C32 C33 C34 C35 0.4(4) . .
C31 C30 C35 C34 -1.3(4) . .
C31 C30 C35 Si4 -176.1(2) . .
C33 C34 C35 C30 0.8(4) . .
C33 C34 C35 Si4 175.6(2) . .
C37 Si4 C35 C30 153.5(2) . .
C36 Si4 C35 C30 32.3(2) . .
C52 Si4 C35 C30 -85.2(2) . .
C37 Si4 C35 C34 -21.1(2) . .
C36 Si4 C35 C34 -142.3(2) . .
C52 Si4 C35 C34 100.2(2) . .
C43 C38 C39 C40 -0.4(5) . .
C38 C39 C40 C41 0.8(5) . .
C39 C40 C41 C42 -0.5(5) . .
C40 C41 C42 C43 -0.2(5) . .
C39 C38 C43 C42 -0.2(4) . .
C39 C38 C43 Si3 179.7(2) . .
C41 C42 C43 C38 0.6(4) . .
C41 C42 C43 Si3 -179.3(2) . .
C45 Si3 C43 C38 34.8(3) . .
C44 Si3 C43 C38 153.8(2) . .
C49 Si3 C43 C38 -79.5(3) . .
C45 Si3 C43 C42 -145.3(2) . .
C44 Si3 C43 C42 -26.2(3) . .
C49 Si3 C43 C42 100.5(2) . .
C46 Co2 C47 O5 79.1(3) . .
C47 Co2 C47 O5 179.7(4) 2_776 .
C50 Co2 C47 O5 -87.6(3) . .
C51 Co2 C47 O5 -60.0(3) . .
C49 Co2 C47 O5 -62.6(4) . .
C52 Co2 C47 O5 -21.4(3) . .
C48 Co2 C47 O5 -9.1(4) . .
Co2 Co2 C47 O5 179.7(4) 2_776 .
C46 Co2 C47 Co2 -100.63(10) . 2_776
C47 Co2 C47 Co2 0.0 2_776 2_776
C50 Co2 C47 Co2 92.73(11) . 2_776
C51 Co2 C47 Co2 120.29(9) . 2_776
C49 Co2 C47 Co2 117.7(2) . 2_776
C52 Co2 C47 Co2 158.89(9) . 2_776
C48 Co2 C47 Co2 171.24(8) . 2_776
C46 Co2 C48 O6 0.6(3) . .
C47 Co2 C48 O6 96.1(3) . .
C47 Co2 C48 O6 -95.5(3) 2_776 .
C50 Co2 C48 O6 -156.8(3) . .
C51 Co2 C48 O6 157.0(3) . .
C49 Co2 C48 O6 -115.7(3) . .
C52 Co2 C48 O6 116.3(3) . .
C46 Co2 C48 C52 -115.67(15) . .
C47 Co2 C48 C52 -20.24(19) . .
C47 Co2 C48 C52 148.14(15) 2_776 .
C50 Co2 C48 C52 86.92(15) . .
C51 Co2 C48 C52 40.65(14) . .
C49 Co2 C48 C52 128.0(2) . .
C46 Co2 C48 C49 116.34(15) . .
C47 Co2 C48 C49 -148.23(15) . .
C47 Co2 C48 C49 20.15(19) 2_776 .
C50 Co2 C48 C49 -41.07(14) . .
C51 Co2 C48 C49 -87.34(15) . .
C52 Co2 C48 C49 -128.0(2) . .
O6 C48 C49 C50 -166.9(2) . .
C52 C48 C49 C50 16.7(3) . .
Co2 C48 C49 C50 63.62(16) . .
O6 C48 C49 Si3 0.5(3) . .
C52 C48 C49 Si3 -175.88(16) . .
Co2 C48 C49 Si3 -128.99(17) . .
O6 C48 C49 Co2 129.5(2) . .
C52 C48 C49 Co2 -46.89(16) . .
C45 Si3 C49 C50 107.7(3) . .
C44 Si3 C49 C50 -11.0(3) . .
C43 Si3 C49 C50 -134.3(2) . .
C45 Si3 C49 C48 -55.5(2) . .
C44 Si3 C49 C48 -174.24(18) . .
C43 Si3 C49 C48 62.4(2) . .
C45 Si3 C49 Co2 -155.60(15) . .
C44 Si3 C49 Co2 85.67(18) . .
C43 Si3 C49 Co2 -37.66(19) . .
C46 Co2 C49 C50 -176.90(14) . .
C47 Co2 C49 C50 -35.3(3) . .
C47 Co2 C49 C50 82.67(15) 2_776 .
C51 Co2 C49 C50 -38.19(14) . .
C52 Co2 C49 C50 -80.69(15) . .
C48 Co2 C49 C50 -112.39(19) . .
Co2 Co2 C49 C50 58.99(17) 2_776 .
C46 Co2 C49 C48 -64.51(15) . .
C47 Co2 C49 C48 77.1(3) . .
C47 Co2 C49 C48 -164.94(14) 2_776 .
C50 Co2 C49 C48 112.4(2) . .
C51 Co2 C49 C48 74.20(14) . .
C52 Co2 C49 C48 31.71(13) . .
Co2 Co2 C49 C48 171.38(10) 2_776 .
C46 Co2 C49 Si3 54.03(17) . .
C47 Co2 C49 Si3 -164.40(18) . .
C47 Co2 C49 Si3 -46.40(17) 2_776 .
C50 Co2 C49 Si3 -129.1(2) . .
C51 Co2 C49 Si3 -167.26(18) . .
C52 Co2 C49 Si3 150.25(18) . .
C48 Co2 C49 Si3 118.5(2) . .
Co2 Co2 C49 Si3 -70.08(19) 2_776 .
C48 C49 C50 C51 -11.0(3) . .
Si3 C49 C50 C51 -175.71(19) . .
Co2 C49 C50 C51 60.28(17) . .
C48 C49 C50 C53 163.8(2) . .
Si3 C49 C50 C53 -0.9(4) . .
Co2 C49 C50 C53 -124.9(2) . .
C48 C49 C50 Co2 -71.26(16) . .
Si3 C49 C50 Co2 124.0(2) . .
C46 Co2 C50 C49 4.7(2) . .
C47 Co2 C50 C49 164.30(14) . .
C47 Co2 C50 C49 -98.65(15) 2_776 .
C51 Co2 C50 C49 119.27(19) . .
C52 Co2 C50 C49 82.06(15) . .
C48 Co2 C50 C49 40.13(13) . .
Co2 Co2 C50 C49 -142.25(12) 2_776 .
C46 Co2 C50 C51 -114.62(18) . .
C47 Co2 C50 C51 45.03(17) . .
C47 Co2 C50 C51 142.08(15) 2_776 .
C49 Co2 C50 C51 -119.27(19) . .
C52 Co2 C50 C51 -37.21(14) . .
C48 Co2 C50 C51 -79.15(14) . .
Co2 Co2 C50 C51 98.48(13) 2_776 .
C46 Co2 C50 C53 126.3(2) . .
C47 Co2 C50 C53 -74.1(2) . .
C47 Co2 C50 C53 23.0(2) 2_776 .
C51 Co2 C50 C53 -119.1(3) . .
C49 Co2 C50 C53 121.6(3) . .
C52 Co2 C50 C53 -156.3(3) . .
C48 Co2 C50 C53 161.8(3) . .
Co2 Co2 C50 C53 -20.6(2) 2_776 .
C49 C50 C51 C52 0.7(3) . .
C53 C50 C51 C52 -174.1(2) . .
Co2 C50 C51 C52 62.67(17) . .
C49 C50 C51 C56 175.5(2) . .
C53 C50 C51 C56 0.7(4) . .
Co2 C50 C51 C56 -122.5(2) . .
C49 C50 C51 Co2 -61.95(17) . .
C53 C50 C51 Co2 123.2(2) . .
C46 Co2 C51 C52 -2.5(2) . .
C47 Co2 C51 C52 99.64(15) . .
C47 Co2 C51 C52 -163.43(15) 2_776 .
C50 Co2 C51 C52 -118.1(2) . .
C49 Co2 C51 C52 -81.52(15) . .
C48 Co2 C51 C52 -39.49(14) . .
Co2 Co2 C51 C52 143.65(13) 2_776 .
C46 Co2 C51 C50 115.61(18) . .
C47 Co2 C51 C50 -142.26(15) . .
C47 Co2 C51 C50 -45.33(18) 2_776 .
C49 Co2 C51 C50 36.58(14) . .
C52 Co2 C51 C50 118.1(2) . .
C48 Co2 C51 C50 78.61(15) . .
Co2 Co2 C51 C50 -98.25(13) 2_776 .
C46 Co2 C51 C56 -124.7(2) . .
C47 Co2 C51 C56 -22.5(2) . .
C47 Co2 C51 C56 74.4(2) 2_776 .
C50 Co2 C51 C56 119.7(3) . .
C49 Co2 C51 C56 156.3(2) . .
C52 Co2 C51 C56 -122.2(3) . .
C48 Co2 C51 C56 -161.7(2) . .
Co2 Co2 C51 C56 21.5(2) 2_776 .
C50 C51 C52 C48 9.9(3) . .
C56 C51 C52 C48 -164.9(2) . .
Co2 C51 C52 C48 70.44(16) . .
C50 C51 C52 Si4 172.0(2) . .
C56 C51 C52 Si4 -2.8(4) . .
Co2 C51 C52 Si4 -127.5(2) . .
C50 C51 C52 Co2 -60.50(16) . .
C56 C51 C52 Co2 124.7(2) . .
O6 C48 C52 C51 167.3(2) . .
C49 C48 C52 C51 -16.4(3) . .
Co2 C48 C52 C51 -62.96(15) . .
O6 C48 C52 Si4 1.8(3) . .
C49 C48 C52 Si4 178.19(16) . .
Co2 C48 C52 Si4 131.60(17) . .
O6 C48 C52 Co2 -129.8(2) . .
C49 C48 C52 Co2 46.58(16) . .
C37 Si4 C52 C51 142.9(3) . .
C36 Si4 C52 C51 -98.5(3) . .
C35 Si4 C52 C51 21.5(3) . .
C37 Si4 C52 C48 -56.6(2) . .
C36 Si4 C52 C48 62.1(2) . .
C35 Si4 C52 C48 -177.91(18) . .
C37 Si4 C52 Co2 43.6(2) . .
C36 Si4 C52 Co2 162.20(17) . .
C35 Si4 C52 Co2 -77.8(2) . .
C46 Co2 C52 C51 178.33(16) . .
C47 Co2 C52 C51 -81.78(15) . .
C47 Co2 C52 C51 37.1(3) 2_776 .
C50 Co2 C52 C51 38.85(15) . .
C49 Co2 C52 C51 81.43(15) . .
C48 Co2 C52 C51 113.3(2) . .
Co2 Co2 C52 C51 -57.44(18) 2_776 .
C46 Co2 C52 C48 65.03(15) . .
C47 Co2 C52 C48 164.92(14) . .
C47 Co2 C52 C48 -76.2(3) 2_776 .
C50 Co2 C52 C48 -74.45(15) . .
C51 Co2 C52 C48 -113.3(2) . .
C49 Co2 C52 C48 -31.87(13) . .
Co2 Co2 C52 C48 -170.74(10) 2_776 .
C46 Co2 C52 Si4 -52.03(19) . .
C47 Co2 C52 Si4 47.86(18) . .
C47 Co2 C52 Si4 166.7(2) 2_776 .
C50 Co2 C52 Si4 168.5(2) . .
C51 Co2 C52 Si4 129.6(3) . .
C49 Co2 C52 Si4 -148.9(2) . .
C48 Co2 C52 Si4 -117.1(2) . .
Co2 Co2 C52 Si4 72.2(2) 2_776 .
C49 C50 C53 C54 -76.3(3) . .
C51 C50 C53 C54 97.8(3) . .
Co2 C50 C53 C54 -171.45(19) . .
C50 C53 C54 C55 172.0(2) . .
C52 C51 C56 C57 86.7(3) . .
C50 C51 C56 C57 -87.2(3) . .
Co2 C51 C56 C57 -177.69(16) . .
C51 C56 C57 C58 -176.6(2) . .
