#------------------------------------------------------------------------------
#$Date: 2016-03-21 14:54:51 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178729 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/40/4084007.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4084007
loop_
_publ_author_name
'Garci, Amine'
'Dobrov, Anatoly A.'
'Riedel, Tina'
'Orhan, Ersin'
'Dyson, Paul J.'
'Arion, Vladimir B.'
'Therrien, Bruno'
_publ_section_title
;
 Strategy to Optimize the Biological Activity of Arene Ruthenium
 Metalla-Assemblies
;
_journal_issue                   14
_journal_name_full               Organometallics
_journal_page_first              3813
_journal_paper_doi               10.1021/om5005176
_journal_volume                  33
_journal_year                    2014
_chemical_formula_moiety         'C26 H38 Cl2 N2 O4 Ru2'
_chemical_formula_sum            'C26 H38 Cl2 N2 O4 Ru2'
_chemical_formula_weight         715.62
_chemical_name_systematic
; 
miu₂diethyl-1,2-diazenato(2-)-kappaN,kappaN'-dicarboxylate-kappaO,kappaO'-dichlorido-
bis(eta⁶-p-cymene)-di-ruthenium(II) 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                71.004(3)
_cell_angle_beta                 70.609(4)
_cell_angle_gamma                65.188(3)
_cell_formula_units_Z            1
_cell_length_a                   8.5335(5)
_cell_length_b                   9.4426(5)
_cell_length_c                   10.4007(6)
_cell_measurement_reflns_used    7390
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      25.60
_cell_measurement_theta_min      2.43
_cell_volume                     700.39(7)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker Apex2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker X8 APEXII CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0810
_diffrn_reflns_av_sigmaI/netI    0.0400
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            34585
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.49
_diffrn_reflns_theta_min         2.43
_exptl_absorpt_coefficient_mu    1.303
_exptl_absorpt_correction_T_max  0.8807
_exptl_absorpt_correction_T_min  0.7993
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.697
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             362
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.449
_refine_diff_density_min         -1.003
_refine_diff_density_rms         0.135
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.092
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     164
_refine_ls_number_reflns         3188
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.092
_refine_ls_R_factor_all          0.0434
_refine_ls_R_factor_gt           0.0341
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0537P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0846
_refine_ls_wR_factor_ref         0.0891
_reflns_number_gt                2761
_reflns_number_total             3188
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om5005176_si_001.cif
_cod_data_source_block           ANDO839
_cod_depositor_comments
'Adding full bibliography for 4084007--4084008.cif.'
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4084007
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ru1 Ru 0.56793(3) 0.68006(3) 0.58349(2) 0.01446(10) Uani 1 1 d .
Cl1 Cl 0.76024(11) 0.70717(9) 0.35140(8) 0.02040(17) Uani 1 1 d .
O1 O 0.3681(3) 0.7773(2) 0.4704(2) 0.0167(4) Uani 1 1 d .
O2 O 0.2624(3) 0.7197(2) 0.3268(2) 0.0177(5) Uani 1 1 d .
N1 N 0.4476(3) 0.5187(3) 0.4520(3) 0.0150(5) Uani 1 1 d .
C1 C 0.3630(4) 0.6737(3) 0.4192(3) 0.0152(6) Uani 1 1 d .
C2 C 0.1964(5) 0.8898(3) 0.2661(3) 0.0216(7) Uani 1 1 d .
H2A H 0.1591 0.9511 0.3389 0.026 Uiso 1 1 calc R
H2B H 0.0917 0.9155 0.2300 0.026 Uiso 1 1 calc R
C3 C 0.3387(5) 0.9378(4) 0.1483(4) 0.0298(8) Uani 1 1 d .
H3A H 0.2921 1.0526 0.1084 0.045 Uiso 1 1 calc R
H3B H 0.3744 0.8780 0.0758 0.045 Uiso 1 1 calc R
H3C H 0.4416 0.9138 0.1844 0.045 Uiso 1 1 calc R
C4 C 0.7511(4) 0.7241(4) 0.6614(3) 0.0190(6) Uani 1 1 d .
C5 C 0.5996(4) 0.8656(4) 0.6468(3) 0.0176(6) Uani 1 1 d .
H5 H 0.6145 0.9644 0.5953 0.021 Uiso 1 1 calc R
C6 C 0.4284(4) 0.8598(4) 0.7081(3) 0.0187(6) Uani 1 1 d .
H6 H 0.3294 0.9556 0.6963 0.022 Uiso 1 1 calc R
C7 C 0.3971(4) 0.7149(4) 0.7876(3) 0.0180(6) Uani 1 1 d .
C8 C 0.5505(4) 0.5745(4) 0.8021(3) 0.0178(6) Uani 1 1 d .
H8 H 0.5357 0.4759 0.8545 0.021 Uiso 1 1 calc R
C9 C 0.7254(4) 0.5780(4) 0.7400(3) 0.0192(7) Uani 1 1 d .
H9 H 0.8250 0.4826 0.7512 0.023 Uiso 1 1 calc R
C10 C 0.9344(4) 0.7268(4) 0.5872(4) 0.0238(7) Uani 1 1 d .
H10A H 0.9828 0.7512 0.6474 0.036 Uiso 1 1 calc R
H10B H 0.9288 0.8088 0.5004 0.036 Uiso 1 1 calc R
H10C H 1.0110 0.6220 0.5656 0.036 Uiso 1 1 calc R
C11 C 0.2087(4) 0.7156(4) 0.8432(3) 0.0213(7) Uani 1 1 d .
H11 H 0.1410 0.7887 0.7703 0.026 Uiso 1 1 calc R
C12 C 0.1233(5) 0.7866(4) 0.9736(3) 0.0256(7) Uani 1 1 d .
H12A H 0.0011 0.7879 1.0092 0.038 Uiso 1 1 calc R
H12B H 0.1231 0.8960 0.9497 0.038 Uiso 1 1 calc R
H12C H 0.1910 0.7213 1.0455 0.038 Uiso 1 1 calc R
C13 C 0.1955(5) 0.5516(4) 0.8700(4) 0.0273(8) Uani 1 1 d .
H13A H 0.0710 0.5597 0.9057 0.041 Uiso 1 1 calc R
H13B H 0.2638 0.4758 0.9390 0.041 Uiso 1 1 calc R
H13C H 0.2432 0.5141 0.7826 0.041 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ru1 O1 75.58(9) 2_666 .
N1 Ru1 C8 91.62(10) 2_666 .
O1 Ru1 C8 128.98(11) . .
N1 Ru1 C6 142.04(11) 2_666 .
O1 Ru1 C6 91.75(10) . .
C8 Ru1 C6 68.60(11) . .
N1 Ru1 C9 103.88(10) 2_666 .
O1 Ru1 C9 167.31(11) . .
C8 Ru1 C9 38.52(12) . .
C6 Ru1 C9 80.96(12) . .
N1 Ru1 C7 106.98(11) 2_666 .
O1 Ru1 C7 97.90(10) . .
C8 Ru1 C7 38.56(11) . .
C6 Ru1 C7 38.51(11) . .
C9 Ru1 C7 69.95(12) . .
N1 Ru1 C5 171.77(10) 2_666 .
O1 Ru1 C5 111.87(10) . .
C8 Ru1 C5 80.95(11) . .
C6 Ru1 C5 37.50(12) . .
C9 Ru1 C5 68.06(11) . .
C7 Ru1 C5 69.23(12) . .
N1 Ru1 C4 135.86(11) 2_666 .
O1 Ru1 C4 147.24(10) . .
C8 Ru1 C4 68.99(12) . .
C6 Ru1 C4 68.22(12) . .
C9 Ru1 C4 37.82(11) . .
C7 Ru1 C4 82.55(12) . .
C5 Ru1 C4 37.68(11) . .
N1 Ru1 Cl1 87.35(7) 2_666 .
O1 Ru1 Cl1 82.92(6) . .
C8 Ru1 Cl1 146.66(9) . .
C6 Ru1 Cl1 127.08(8) . .
C9 Ru1 Cl1 109.77(9) . .
C7 Ru1 Cl1 165.45(8) . .
C5 Ru1 Cl1 96.89(8) . .
C4 Ru1 Cl1 88.94(9) . .
C1 O1 Ru1 112.21(18) . .
C1 O2 C2 116.6(2) . .
C1 N1 N1 111.0(3) . 2_666
C1 N1 Ru1 133.8(2) . 2_666
N1 N1 Ru1 114.5(2) 2_666 2_666
O1 C1 N1 124.9(3) . .
O1 C1 O2 120.1(2) . .
N1 C1 O2 114.9(3) . .
O2 C2 C3 110.5(3) . .
O2 C2 H2A 109.6 . .
C3 C2 H2A 109.6 . .
O2 C2 H2B 109.6 . .
C3 C2 H2B 109.6 . .
H2A C2 H2B 108.1 . .
C2 C3 H3A 109.5 . .
C2 C3 H3B 109.5 . .
H3A C3 H3B 109.5 . .
C2 C3 H3C 109.5 . .
H3A C3 H3C 109.5 . .
H3B C3 H3C 109.5 . .
C9 C4 C5 118.8(3) . .
C9 C4 C10 120.4(3) . .
C5 C4 C10 120.7(3) . .
C9 C4 Ru1 69.78(18) . .
C5 C4 Ru1 70.83(18) . .
C10 C4 Ru1 127.9(2) . .
C6 C5 C4 120.4(3) . .
C6 C5 Ru1 69.88(17) . .
C4 C5 Ru1 71.49(17) . .
C6 C5 H5 119.8 . .
C4 C5 H5 119.8 . .
Ru1 C5 H5 131.7 . .
C5 C6 C7 122.5(3) . .
C5 C6 Ru1 72.61(18) . .
C7 C6 Ru1 71.19(17) . .
C5 C6 H6 118.7 . .
C7 C6 H6 118.7 . .
Ru1 C6 H6 130.2 . .
C8 C7 C6 116.3(3) . .
C8 C7 C11 123.9(3) . .
C6 C7 C11 119.6(3) . .
C8 C7 Ru1 69.59(17) . .
C6 C7 Ru1 70.29(17) . .
C11 C7 Ru1 127.3(2) . .
C9 C8 C7 121.9(3) . .
C9 C8 Ru1 71.79(17) . .
C7 C8 Ru1 71.85(17) . .
C9 C8 H8 119.1 . .
C7 C8 H8 119.1 . .
Ru1 C8 H8 130.0 . .
C4 C9 C8 120.1(3) . .
C4 C9 Ru1 72.39(17) . .
C8 C9 Ru1 69.68(17) . .
C4 C9 H9 119.9 . .
C8 C9 H9 119.9 . .
Ru1 C9 H9 130.6 . .
C4 C10 H10A 109.5 . .
C4 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C4 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C7 C11 C13 113.3(3) . .
C7 C11 C12 109.4(3) . .
C13 C11 C12 112.0(3) . .
C7 C11 H11 107.3 . .
C13 C11 H11 107.3 . .
C12 C11 H11 107.3 . .
C11 C12 H12A 109.5 . .
C11 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C11 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C11 C13 H13A 109.5 . .
C11 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C11 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ru1 N1 2.090(2) 2_666
Ru1 O1 2.110(2) .
Ru1 C8 2.147(3) .
Ru1 C6 2.165(3) .
Ru1 C9 2.175(3) .
Ru1 C7 2.177(3) .
Ru1 C5 2.200(3) .
Ru1 C4 2.209(3) .
Ru1 Cl1 2.4301(8) .
O1 C1 1.278(4) .
O2 C1 1.346(4) .
O2 C2 1.453(3) .
N1 C1 1.316(4) .
N1 N1 1.422(5) 2_666
N1 Ru1 2.090(2) 2_666
C2 C3 1.514(5) .
C2 H2A 0.9900 .
C2 H2B 0.9900 .
C3 H3A 0.9800 .
C3 H3B 0.9800 .
C3 H3C 0.9800 .
C4 C9 1.421(4) .
C4 C5 1.424(4) .
C4 C10 1.503(5) .
C5 C6 1.404(5) .
C5 H5 0.9500 .
C6 C7 1.432(4) .
C6 H6 0.9500 .
C7 C8 1.428(4) .
C7 C11 1.515(5) .
C8 C9 1.426(5) .
C8 H8 0.9500 .
C9 H9 0.9500 .
C10 H10A 0.9800 .
C10 H10B 0.9800 .
C10 H10C 0.9800 .
C11 C13 1.527(5) .
C11 C12 1.532(5) .
C11 H11 1.0000 .
C12 H12A 0.9800 .
C12 H12B 0.9800 .
C12 H12C 0.9800 .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
N1 Ru1 O1 C1 -11.39(19) 2_666
C8 Ru1 O1 C1 -91.6(2) .
C6 Ru1 O1 C1 -155.2(2) .
C9 Ru1 O1 C1 -100.6(5) .
C7 Ru1 O1 C1 -117.0(2) .
C5 Ru1 O1 C1 172.3(2) .
C4 Ru1 O1 C1 154.5(2) .
Cl1 Ru1 O1 C1 77.67(19) .
Ru1 O1 C1 N1 11.7(4) .
Ru1 O1 C1 O2 -169.9(2) .
N1 N1 C1 O1 -2.5(5) 2_666
Ru1 N1 C1 O1 167.1(2) 2_666
N1 N1 C1 O2 179.0(3) 2_666
Ru1 N1 C1 O2 -11.4(4) 2_666
C2 O2 C1 O1 13.7(4) .
C2 O2 C1 N1 -167.7(3) .
C1 O2 C2 C3 80.5(3) .
N1 Ru1 C4 C9 -40.0(3) 2_666
O1 Ru1 C4 C9 159.74(18) .
C8 Ru1 C4 C9 29.33(19) .
C6 Ru1 C4 C9 103.8(2) .
C7 Ru1 C4 C9 66.71(19) .
C5 Ru1 C4 C9 132.1(3) .
Cl1 Ru1 C4 C9 -125.13(18) .
N1 Ru1 C4 C5 -172.17(16) 2_666
O1 Ru1 C4 C5 27.6(3) .
C8 Ru1 C4 C5 -102.8(2) .
C6 Ru1 C4 C5 -28.33(17) .
C9 Ru1 C4 C5 -132.1(3) .
C7 Ru1 C4 C5 -65.43(19) .
Cl1 Ru1 C4 C5 102.73(17) .
N1 Ru1 C4 C10 73.4(3) 2_666
O1 Ru1 C4 C10 -86.9(3) .
C8 Ru1 C4 C10 142.7(3) .
C6 Ru1 C4 C10 -142.8(3) .
C9 Ru1 C4 C10 113.4(3) .
C7 Ru1 C4 C10 -179.9(3) .
C5 Ru1 C4 C10 -114.5(3) .
Cl1 Ru1 C4 C10 -11.7(3) .
C9 C4 C5 C6 -0.6(4) .
C10 C4 C5 C6 175.4(3) .
Ru1 C4 C5 C6 52.0(3) .
C9 C4 C5 Ru1 -52.5(3) .
C10 C4 C5 Ru1 123.4(3) .
N1 Ru1 C5 C6 -92.2(8) 2_666
O1 Ru1 C5 C6 62.03(19) .
C8 Ru1 C5 C6 -66.46(18) .
C9 Ru1 C5 C6 -104.28(19) .
C7 Ru1 C5 C6 -28.31(17) .
C4 Ru1 C5 C6 -133.6(3) .
Cl1 Ru1 C5 C6 147.15(16) .
N1 Ru1 C5 C4 41.5(8) 2_666
O1 Ru1 C5 C4 -164.33(16) .
C8 Ru1 C5 C4 67.18(19) .
C6 Ru1 C5 C4 133.6(3) .
C9 Ru1 C5 C4 29.36(18) .
C7 Ru1 C5 C4 105.3(2) .
Cl1 Ru1 C5 C4 -79.22(17) .
C4 C5 C6 C7 0.4(5) .
Ru1 C5 C6 C7 53.1(3) .
C4 C5 C6 Ru1 -52.7(3) .
N1 Ru1 C6 C5 166.54(16) 2_666
O1 Ru1 C6 C5 -124.91(17) .
C8 Ru1 C6 C5 103.49(19) .
C9 Ru1 C6 C5 65.54(18) .
C7 Ru1 C6 C5 134.6(3) .
C4 Ru1 C6 C5 28.45(17) .
Cl1 Ru1 C6 C5 -42.5(2) .
N1 Ru1 C6 C7 32.0(3) 2_666
O1 Ru1 C6 C7 100.50(18) .
C8 Ru1 C6 C7 -31.10(18) .
C9 Ru1 C6 C7 -69.05(19) .
C5 Ru1 C6 C7 -134.6(3) .
C4 Ru1 C6 C7 -106.1(2) .
Cl1 Ru1 C6 C7 -177.05(14) .
C5 C6 C7 C8 0.1(4) .
Ru1 C6 C7 C8 53.8(2) .
C5 C6 C7 C11 -176.2(3) .
Ru1 C6 C7 C11 -122.5(3) .
C5 C6 C7 Ru1 -53.7(3) .
N1 Ru1 C7 C8 70.39(19) 2_666
O1 Ru1 C7 C8 147.65(17) .
C6 Ru1 C7 C8 -129.5(3) .
C9 Ru1 C7 C8 -28.56(18) .
C5 Ru1 C7 C8 -101.9(2) .
C4 Ru1 C7 C8 -65.41(19) .
Cl1 Ru1 C7 C8 -120.1(3) .
N1 Ru1 C7 C6 -160.10(17) 2_666
O1 Ru1 C7 C6 -82.83(18) .
C8 Ru1 C7 C6 129.5(3) .
C9 Ru1 C7 C6 100.9(2) .
C5 Ru1 C7 C6 27.63(18) .
C4 Ru1 C7 C6 64.11(19) .
Cl1 Ru1 C7 C6 9.4(4) .
N1 Ru1 C7 C11 -47.3(3) 2_666
O1 Ru1 C7 C11 29.9(3) .
C8 Ru1 C7 C11 -117.7(3) .
C6 Ru1 C7 C11 112.8(3) .
C9 Ru1 C7 C11 -146.3(3) .
C5 Ru1 C7 C11 140.4(3) .
C4 Ru1 C7 C11 176.9(3) .
Cl1 Ru1 C7 C11 122.2(3) .
C6 C7 C8 C9 -0.4(4) .
C11 C7 C8 C9 175.8(3) .
Ru1 C7 C8 C9 53.8(3) .
C6 C7 C8 Ru1 -54.1(2) .
C11 C7 C8 Ru1 122.0(3) .
N1 Ru1 C8 C9 110.48(18) 2_666
O1 Ru1 C8 C9 -176.83(15) .
C6 Ru1 C8 C9 -102.8(2) .
C7 Ru1 C8 C9 -133.9(3) .
C5 Ru1 C8 C9 -65.96(18) .
C4 Ru1 C8 C9 -28.83(18) .
Cl1 Ru1 C8 C9 22.8(3) .
N1 Ru1 C8 C7 -115.67(18) 2_666
O1 Ru1 C8 C7 -43.0(2) .
C6 Ru1 C8 C7 31.06(18) .
C9 Ru1 C8 C7 133.9(3) .
C5 Ru1 C8 C7 67.89(19) .
C4 Ru1 C8 C7 105.0(2) .
Cl1 Ru1 C8 C7 156.70(15) .
C5 C4 C9 C8 0.3(4) .
C10 C4 C9 C8 -175.7(3) .
Ru1 C4 C9 C8 -52.7(3) .
C5 C4 C9 Ru1 53.0(3) .
C10 C4 C9 Ru1 -122.9(3) .
C7 C8 C9 C4 0.2(5) .
Ru1 C8 C9 C4 54.0(3) .
C7 C8 C9 Ru1 -53.8(3) .
N1 Ru1 C9 C4 152.52(18) 2_666
O1 Ru1 C9 C4 -121.5(4) .
C8 Ru1 C9 C4 -132.8(3) .
C6 Ru1 C9 C4 -65.9(2) .
C7 Ru1 C9 C4 -104.2(2) .
C5 Ru1 C9 C4 -29.25(19) .
Cl1 Ru1 C9 C4 60.33(19) .
N1 Ru1 C9 C8 -74.71(18) 2_666
O1 Ru1 C9 C8 11.3(5) .
C6 Ru1 C9 C8 66.83(18) .
C7 Ru1 C9 C8 28.59(17) .
C5 Ru1 C9 C8 103.5(2) .
C4 Ru1 C9 C8 132.8(3) .
Cl1 Ru1 C9 C8 -166.90(15) .
C8 C7 C11 C13 -20.2(4) .
C6 C7 C11 C13 155.8(3) .
Ru1 C7 C11 C13 68.9(3) .
C8 C7 C11 C12 105.6(3) .
C6 C7 C11 C12 -78.4(3) .
Ru1 C7 C11 C12 -165.3(2) .
