#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/40/4084016.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4084016
loop_
_publ_author_name
'Li, Ying-Zhou'
'Ganguly, Rakesh'
'Leong, Weng Kee'
_publ_section_title
;
 Binuclear Oxidative Addition of Sb--Cl Bonds: A Facile Synthetic Route to
 Main Group--Transition Element Clusters and Rings
;
_journal_issue                   14
_journal_name_full               Organometallics
_journal_page_first              3867
_journal_paper_doi               10.1021/om500565d
_journal_volume                  33
_journal_year                    2014
_chemical_formula_sum            'C34.9 H21.8 Cl3.8 O10 Os3 Sb2'
_chemical_formula_weight         1549.93
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                102.033(2)
_cell_angle_beta                 101.686(2)
_cell_angle_gamma                106.124(2)
_cell_formula_units_Z            2
_cell_length_a                   11.5786(5)
_cell_length_b                   14.0291(6)
_cell_length_c                   14.9583(6)
_cell_measurement_reflns_used    9686
_cell_measurement_temperature    103(2)
_cell_measurement_theta_max      28.69
_cell_measurement_theta_min      2.42
_cell_volume                     2193.46(17)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      103(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0536
_diffrn_reflns_av_sigmaI/netI    0.0424
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            41146
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         2.42
_exptl_absorpt_coefficient_mu    10.154
_exptl_absorpt_correction_T_max  0.4300
_exptl_absorpt_correction_T_min  0.1063
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.347
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1412
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.10
_refine_diff_density_max         2.356
_refine_diff_density_min         -3.430
_refine_diff_density_rms         0.257
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.131
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     600
_refine_ls_number_reflns         8976
_refine_ls_number_restraints     380
_refine_ls_restrained_S_all      1.125
_refine_ls_R_factor_all          0.0686
_refine_ls_R_factor_gt           0.0535
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0411P)²+48.3663P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1274
_refine_ls_wR_factor_ref         0.1365
_reflns_number_gt                7465
_reflns_number_total             8976
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om500565d_si_003.cif
_cod_data_source_block           lwk227
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 4084009--4084020.cif.
;
_cod_original_cell_volume        2193.45(16)
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'C34.90 H21.80 Cl3.80 O10 Os3 Sb2'
_cod_database_code               4084016
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Os1 Os 0.29676(5) 0.82283(3) 0.85100(3) 0.02888(12) Uani 1 1 d D . .
Os2 Os 0.32631(5) 0.78552(6) 0.53869(4) 0.04822(18) Uani 1 1 d D . .
Os3 Os 0.29009(5) 0.58256(5) 0.57732(4) 0.04731(17) Uani 1 1 d D A .
Sb4 Sb 0.23320(7) 0.85822(6) 0.68028(5) 0.02959(18) Uani 1 1 d . A .
Sb5 Sb 0.37114(7) 0.66955(6) 0.76783(5) 0.02892(18) Uani 1 1 d . A .
O12 O 0.3761(14) 0.7769(9) 1.0405(7) 0.078(4) Uani 1 1 d . . .
O14 O 0.1855(15) 0.9838(10) 0.9317(8) 0.081(4) Uani 1 1 d . . .
O22 O 0.3662(9) 0.9934(12) 0.4910(10) 0.086(5) Uani 1 1 d . . .
O23 O 0.0628(8) 0.6817(10) 0.4037(7) 0.065(3) Uani 1 1 d D . .
O24 O 0.4482(12) 0.6960(15) 0.3915(9) 0.113(6) Uani 1 1 d . . .
O31 O 0.5594(8) 0.6157(8) 0.5688(8) 0.057(3) Uani 1 1 d D A .
O32 O 0.1928(11) 0.4870(13) 0.3611(8) 0.106(6) Uani 1 1 d . A .
O34 O 0.2587(13) 0.3691(8) 0.6103(10) 0.084(4) Uani 1 1 d . A .
C12 C 0.3493(15) 0.7932(12) 0.9713(11) 0.051(4) Uani 1 1 d U A .
C14 C 0.2257(14) 0.9253(12) 0.9021(10) 0.048(3) Uani 1 1 d U A .
C22 C 0.3493(15) 0.9154(14) 0.5102(12) 0.059(4) Uani 1 1 d U A .
C23 C 0.1604(10) 0.7186(12) 0.4541(9) 0.050(4) Uani 1 1 d DU A .
C24 C 0.4022(17) 0.7264(15) 0.4460(13) 0.068(5) Uani 1 1 d U A .
C31 C 0.4605(10) 0.6045(11) 0.5740(11) 0.048(3) Uani 1 1 d DU . .
C32 C 0.2297(16) 0.5242(14) 0.4414(12) 0.063(4) Uani 1 1 d U . .
C34 C 0.2668(17) 0.4486(14) 0.5988(12) 0.062(4) Uani 1 1 d U . .
O11 O 0.5483(13) 0.9911(13) 0.8925(15) 0.048(4) Uani 0.627(10) 1 d PDU A 1
C11 C 0.4550(16) 0.9288(18) 0.877(2) 0.038(5) Uani 0.627(10) 1 d PDU A 1
Cl13 Cl 0.0995(5) 0.6834(4) 0.8154(4) 0.0338(14) Uani 0.627(10) 1 d PU A 1
Cl21 Cl 0.5212(5) 0.8484(5) 0.6627(4) 0.0385(15) Uani 0.627(10) 1 d PU A 1
O33 O 0.0326(12) 0.5942(13) 0.5877(12) 0.039(3) Uani 0.627(10) 1 d PDU A 1
C33 C 0.1272(15) 0.586(2) 0.586(2) 0.036(4) Uani 0.627(10) 1 d PDU A 1
Cl11 Cl 0.4938(10) 0.9600(8) 0.8765(8) 0.040(3) Uani 0.373(10) 1 d PU A 2
O13 O 0.0492(18) 0.6532(16) 0.819(2) 0.038(4) Uani 0.373(10) 1 d PDU A 2
C13 C 0.139(3) 0.718(3) 0.831(3) 0.036(5) Uani 0.373(10) 1 d PDU A 2
O21 O 0.5819(15) 0.865(2) 0.6869(15) 0.038(4) Uani 0.373(10) 1 d PDU A 2
C21 C 0.487(2) 0.837(4) 0.632(3) 0.038(5) Uani 0.373(10) 1 d PDU A 2
Cl33 Cl 0.0933(9) 0.5968(8) 0.5992(7) 0.033(2) Uani 0.373(10) 1 d PU A 2
C411 C 0.2943(15) 1.0237(12) 0.7164(11) 0.053(4) Uani 1 1 d U . .
C412 C 0.2132(19) 1.0746(15) 0.7381(14) 0.072(5) Uani 1 1 d U A .
H412 H 0.1296 1.0347 0.7325 0.087 Uiso 1 1 calc R . .
C413 C 0.248(2) 1.1830(19) 0.7682(18) 0.101(7) Uani 1 1 d U . .
H413 H 0.1913 1.2170 0.7832 0.122 Uiso 1 1 calc R A .
C414 C 0.367(3) 1.236(2) 0.7747(19) 0.111(8) Uani 1 1 d U A .
H414 H 0.3923 1.3089 0.7954 0.133 Uiso 1 1 calc R . .
C415 C 0.446(2) 1.1985(18) 0.7564(16) 0.090(6) Uani 1 1 d U . .
H415 H 0.5283 1.2428 0.7631 0.108 Uiso 1 1 calc R A .
C416 C 0.4150(18) 1.0824(14) 0.7233(13) 0.069(5) Uani 1 1 d U A .
H416 H 0.4747 1.0518 0.7081 0.083 Uiso 1 1 calc R . .
C421 C 0.0394(11) 0.8396(9) 0.6279(8) 0.032(3) Uani 1 1 d U . .
C422 C 0.0034(13) 0.8706(10) 0.5473(9) 0.039(3) Uani 1 1 d U A .
H422 H 0.0637 0.8940 0.5151 0.047 Uiso 1 1 calc R . .
C423 C -0.1168(13) 0.8683(11) 0.5132(10) 0.047(3) Uani 1 1 d U . .
H423 H -0.1406 0.8871 0.4566 0.056 Uiso 1 1 calc R A .
C424 C -0.2037(13) 0.8377(10) 0.5632(10) 0.043(3) Uani 1 1 d U A .
H424 H -0.2864 0.8384 0.5419 0.051 Uiso 1 1 calc R . .
C425 C -0.1701(14) 0.8063(11) 0.6438(11) 0.050(3) Uani 1 1 d U . .
H425 H -0.2299 0.7836 0.6766 0.059 Uiso 1 1 calc R A .
C426 C -0.0464(12) 0.8085(10) 0.6762(9) 0.037(3) Uani 1 1 d U A .
H426 H -0.0220 0.7884 0.7319 0.044 Uiso 1 1 calc R . .
C511 C 0.5679(13) 0.6910(11) 0.8190(10) 0.044(3) Uani 1 1 d U . .
C512 C 0.6541(16) 0.7829(14) 0.8733(12) 0.061(4) Uani 1 1 d U A .
H512 H 0.6288 0.8414 0.8906 0.073 Uiso 1 1 calc R . .
C513 C 0.780(2) 0.7920(17) 0.9040(15) 0.080(5) Uani 1 1 d U . .
H513 H 0.8395 0.8558 0.9439 0.095 Uiso 1 1 calc R A .
C514 C 0.8140(18) 0.7118(15) 0.8773(13) 0.068(5) Uani 1 1 d U A .
H514 H 0.9003 0.7198 0.8978 0.081 Uiso 1 1 calc R . .
C515 C 0.7370(17) 0.6216(15) 0.8243(13) 0.068(5) Uani 1 1 d U . .
H515 H 0.7678 0.5663 0.8074 0.082 Uiso 1 1 calc R A .
C516 C 0.6025(16) 0.6048(14) 0.7904(12) 0.062(4) Uani 1 1 d U A .
H516 H 0.5438 0.5399 0.7519 0.075 Uiso 1 1 calc R . .
C521 C 0.3030(12) 0.5491(10) 0.8332(10) 0.039(3) Uani 1 1 d U . .
C522 C 0.3749(14) 0.5516(11) 0.9194(10) 0.045(3) Uani 1 1 d U A .
H522 H 0.4552 0.6028 0.9476 0.054 Uiso 1 1 calc R . .
C523 C 0.3295(15) 0.4786(12) 0.9652(12) 0.054(4) Uani 1 1 d U . .
H523 H 0.3761 0.4824 1.0267 0.065 Uiso 1 1 calc R A .
C524 C 0.2164(17) 0.4006(14) 0.9208(13) 0.064(4) Uani 1 1 d U A .
H524 H 0.1887 0.3469 0.9491 0.077 Uiso 1 1 calc R . .
C525 C 0.1423(16) 0.4002(12) 0.8342(12) 0.057(4) Uani 1 1 d U . .
H525 H 0.0621 0.3489 0.8053 0.069 Uiso 1 1 calc R A .
C526 C 0.1877(13) 0.4761(10) 0.7908(10) 0.040(3) Uani 1 1 d U A .
H526 H 0.1385 0.4769 0.7321 0.048 Uiso 1 1 calc R . .
C1S C 0.826(2) 0.081(4) 0.7823(17) 0.051(8) Uiso 0.25 1 d PD B 1
H1S1 H 0.7602 0.1128 0.7874 0.061 Uiso 0.25 1 calc PR B 1
H1S2 H 0.7846 0.0048 0.7575 0.061 Uiso 0.25 1 calc PR B 1
Cl1S Cl 0.9085(12) 0.1272(9) 0.7054(8) 0.038(3) Uani 0.25 1 d PDU B 1
Cl2S Cl 0.933(2) 0.1124(18) 0.8941(12) 0.072(5) Uani 0.25 1 d PDU B 1
C1S C 0.812(5) 0.047(2) 0.754(2) 0.051(8) Uiso 0.25 1 d PD C 2
H1S3 H 0.8530 0.0272 0.7042 0.061 Uiso 0.25 1 calc PR C 2
H1S4 H 0.7324 -0.0097 0.7414 0.061 Uiso 0.25 1 calc PR C 2
Cl1S Cl 0.7792(17) 0.1591(15) 0.7444(12) 0.071(5) Uani 0.25 1 d PDU C 2
Cl2S Cl 0.909(2) 0.0618(18) 0.8650(14) 0.074(5) Uani 0.25 1 d PDU C 2
C1S C 0.905(5) 0.4677(18) 0.8958(17) 0.051(8) Uiso 0.25 1 d PD . 3
H1S5 H 0.9853 0.5020 0.8842 0.061 Uiso 0.25 1 calc PR . 3
H1S6 H 0.8660 0.5208 0.9134 0.061 Uiso 0.25 1 calc PR . 3
Cl1S Cl 0.8063(15) 0.3729(12) 0.7925(11) 0.059(4) Uani 0.25 1 d PDU D 3
Cl2S Cl 0.933(2) 0.4130(17) 0.9888(13) 0.082(6) Uani 0.25 1 d PDU . 3
C1S C 0.905(12) 0.385(4) 0.968(3) 0.051(8) Uiso 0.15 1 d PD E 4
H1S7 H 0.8612 0.4012 1.0167 0.061 Uiso 0.15 1 calc PR E 4
H1S8 H 0.9941 0.4282 0.9935 0.061 Uiso 0.15 1 calc PR E 4
Cl1S Cl 0.838(3) 0.412(3) 0.864(3) 0.082(9) Uani 0.15 1 d PDU E 4
Cl2S Cl 0.889(4) 0.254(3) 0.940(3) 0.103(12) Uani 0.15 1 d PDU E 4
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Os Os -1.2165 7.6030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C11 Os1 C13 177.4(17) . .
C11 Os1 C14 90.5(10) . .
C13 Os1 C14 88.5(15) . .
C11 Os1 C12 91.1(10) . .
C13 Os1 C12 86.5(16) . .
C14 Os1 C12 95.0(6) . .
C11 Os1 Cl13 177.8(9) . .
C13 Os1 Cl13 4.0(15) . .
C14 Os1 Cl13 91.7(5) . .
C12 Os1 Cl13 88.6(5) . .
C11 Os1 Cl11 3.2(10) . .
C13 Os1 Cl11 178.4(15) . .
C14 Os1 Cl11 90.0(5) . .
C12 Os1 Cl11 94.3(5) . .
Cl13 Os1 Cl11 176.5(3) . .
C11 Os1 Sb5 94.6(9) . .
C13 Os1 Sb5 86.5(15) . .
C14 Os1 Sb5 174.0(5) . .
C12 Os1 Sb5 88.0(4) . .
Cl13 Os1 Sb5 83.21(13) . .
Cl11 Os1 Sb5 94.9(3) . .
C11 Os1 Sb4 87.9(9) . .
C13 Os1 Sb4 94.5(15) . .
C14 Os1 Sb4 88.4(4) . .
C12 Os1 Sb4 176.5(4) . .
Cl13 Os1 Sb4 92.29(14) . .
Cl11 Os1 Sb4 84.7(3) . .
Sb5 Os1 Sb4 88.73(3) . .
C22 Os2 C23 95.3(7) . .
C22 Os2 C21 92.4(16) . .
C23 Os2 C21 171.9(16) . .
C22 Os2 C24 97.2(8) . .
C23 Os2 C24 92.6(7) . .
C21 Os2 C24 88.8(16) . .
C22 Os2 Cl21 94.0(5) . .
C23 Os2 Cl21 169.2(5) . .
C21 Os2 Cl21 3.5(15) . .
C24 Os2 Cl21 91.6(6) . .
C22 Os2 Sb4 87.6(5) . .
C23 Os2 Sb4 90.8(4) . .
C21 Os2 Sb4 87.1(15) . .
C24 Os2 Sb4 173.8(6) . .
Cl21 Os2 Sb4 84.10(15) . .
C22 Os2 Os3 178.5(5) . .
C23 Os2 Os3 84.0(5) . .
C21 Os2 Os3 88.4(16) . .
C24 Os2 Os3 81.6(6) . .
Cl21 Os2 Os3 86.87(15) . .
Sb4 Os2 Os3 93.74(2) . .
C31 Os3 C32 91.4(7) . .
C31 Os3 C34 93.8(7) . .
C32 Os3 C34 92.4(8) . .
C31 Os3 C33 170.1(10) . .
C32 Os3 C33 91.7(10) . .
C34 Os3 C33 95.4(11) . .
C31 Os3 Cl33 167.0(5) . .
C32 Os3 Cl33 95.7(6) . .
C34 Os3 Cl33 96.8(6) . .
C33 Os3 Cl33 4.3(9) . .
C31 Os3 Sb5 89.6(4) . .
C32 Os3 Sb5 178.0(6) . .
C34 Os3 Sb5 89.1(5) . .
C33 Os3 Sb5 87.0(8) . .
Cl33 Os3 Sb5 82.9(2) . .
C31 Os3 Os2 85.6(5) . .
C32 Os3 Os2 86.0(6) . .
C34 Os3 Os2 178.3(5) . .
C33 Os3 Os2 85.3(9) . .
Cl33 Os3 Os2 84.1(3) . .
Sb5 Os3 Os2 92.43(3) . .
C411 Sb4 C421 94.4(5) . .
C411 Sb4 Os1 102.6(4) . .
C421 Sb4 Os1 115.0(3) . .
C411 Sb4 Os2 109.3(4) . .
C421 Sb4 Os2 111.5(3) . .
Os1 Sb4 Os2 120.17(3) . .
C511 Sb5 C521 96.6(5) . .
C511 Sb5 Os1 115.5(4) . .
C521 Sb5 Os1 102.9(3) . .
C511 Sb5 Os3 110.0(4) . .
C521 Sb5 Os3 107.0(4) . .
Os1 Sb5 Os3 121.04(3) . .
O12 C12 Os1 177.9(15) . .
O14 C14 Os1 179.6(16) . .
O22 C22 Os2 177.5(16) . .
O23 C23 Os2 178.1(15) . .
O24 C24 Os2 177.1(19) . .
O31 C31 Os3 177.7(13) . .
O32 C32 Os3 178.2(18) . .
O34 C34 Os3 176.5(15) . .
O11 C11 Os1 180(4) . .
O33 C33 Os3 175(3) . .
O13 C13 Os1 177(5) . .
O21 C21 Os2 178(5) . .
C412 C411 C416 118.1(17) . .
C412 C411 Sb4 119.5(13) . .
C416 C411 Sb4 122.3(13) . .
C411 C412 C413 123(2) . .
C414 C413 C412 116(3) . .
C415 C414 C413 126(3) . .
C414 C415 C416 120(2) . .
C411 C416 C415 116.1(19) . .
C426 C421 C422 119.3(12) . .
C426 C421 Sb4 122.3(9) . .
C422 C421 Sb4 118.0(9) . .
C423 C422 C421 121.7(13) . .
C422 C423 C424 118.8(13) . .
C425 C424 C423 120.5(13) . .
C424 C425 C426 119.1(14) . .
C421 C426 C425 120.5(12) . .
C512 C511 C516 121.1(15) . .
C512 C511 Sb5 123.0(11) . .
C516 C511 Sb5 115.8(12) . .
C511 C512 C513 120.4(17) . .
C514 C513 C512 119(2) . .
C515 C514 C513 124(2) . .
C514 C515 C516 120.5(17) . .
C511 C516 C515 115.0(16) . .
C526 C521 C522 121.5(13) . .
C526 C521 Sb5 119.7(10) . .
C522 C521 Sb5 118.8(10) . .
C521 C522 C523 119.7(14) . .
C524 C523 C522 119.5(15) . .
C523 C524 C525 120.3(16) . .
C526 C525 C524 119.1(16) . .
C521 C526 C525 119.7(14) . .
Cl2S C1S Cl1S 107.9(11) . .
Cl1S C1S Cl2S 112.9(12) . .
Cl2S C1S Cl1S 110.4(12) . .
Cl2S C1S Cl2S 73.4(15) . 2_767
Cl1S C1S Cl2S 166(4) . 2_767
C1S Cl2S C1S 106.6(15) . 2_767
C1S Cl2S Cl2S 63.0(12) . 2_767
C1S Cl2S Cl2S 43.6(8) 2_767 2_767
Cl1S C1S Cl2S 108.3(13) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Os1 C11 1.917(12) .
Os1 C13 1.919(12) .
Os1 C14 1.945(15) .
Os1 C12 1.946(16) .
Os1 Cl13 2.432(6) .
Os1 Cl11 2.441(11) .
Os1 Sb5 2.6946(8) .
Os1 Sb4 2.6981(9) .
Os2 C22 1.916(18) .
Os2 C23 1.921(10) .
Os2 C21 1.928(12) .
Os2 C24 1.950(18) .
Os2 Cl21 2.414(5) .
Os2 Sb4 2.7062(10) .
Os2 Os3 2.9560(10) .
Os3 C31 1.923(10) .
Os3 C32 1.925(18) .
Os3 C34 1.927(19) .
Os3 C33 1.929(11) .
Os3 Cl33 2.421(10) .
Os3 Sb5 2.7058(9) .
Sb4 C411 2.143(15) .
Sb4 C421 2.143(12) .
Sb5 C511 2.164(14) .
Sb5 C521 2.167(13) .
O12 C12 1.109(18) .
O14 C14 1.109(17) .
O22 C22 1.16(2) .
O23 C23 1.131(11) .
O24 C24 1.13(2) .
O31 C31 1.133(11) .
O32 C32 1.142(19) .
O34 C34 1.14(2) .
O11 C11 1.129(12) .
O33 C33 1.138(12) .
O13 C13 1.130(13) .
O21 C21 1.137(13) .
C411 C412 1.38(2) .
C411 C416 1.38(2) .
C412 C413 1.41(3) .
C413 C414 1.34(3) .
C414 C415 1.22(3) .
C415 C416 1.51(3) .
C421 C426 1.371(17) .
C421 C422 1.389(17) .
C422 C423 1.371(19) .
C423 C424 1.40(2) .
C424 C425 1.39(2) .
C425 C426 1.406(19) .
C511 C512 1.36(2) .
C511 C516 1.39(2) .
C512 C513 1.39(3) .
C513 C514 1.31(3) .
C514 C515 1.30(2) .
C515 C516 1.47(2) .
C521 C526 1.364(18) .
C521 C522 1.374(19) .
C522 C523 1.39(2) .
C523 C524 1.38(2) .
C524 C525 1.40(2) .
C525 C526 1.39(2) .
C1S Cl2S 1.754(10) .
C1S Cl1S 1.755(10) .
C1S Cl1S 1.742(10) .
C1S Cl2S 1.744(10) .
C1S Cl2S 1.739(10) .
C1S Cl1S 1.745(10) .
C1S Cl2S 2.25(3) 2_767
Cl2S C1S 2.25(3) 2_767
Cl2S Cl2S 2.42(5) 2_767
C1S Cl1S 1.747(10) .
C1S Cl2S 1.748(10) .
