#------------------------------------------------------------------------------
#$Date: 2016-03-21 15:14:41 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178741 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/52/4085265.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4085265
loop_
_publ_author_name
'Hicks, Jamie'
'Jones, Cameron'
_publ_section_title
;
 Low-Coordinate Cobalt(I) Complexes Stabilized by an Extremely Bulky Amide
 Ligand
;
_journal_issue                   11
_journal_name_full               Organometallics
_journal_page_first              2118
_journal_paper_doi               10.1021/om501233f
_journal_volume                  34
_journal_year                    2015
_chemical_formula_sum            'C72 H63 Co N Si'
_chemical_formula_weight         1029.25
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 106.420(6)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.9259(9)
_cell_length_b                   18.1348(11)
_cell_length_c                   23.0194(13)
_cell_measurement_temperature    123(2)
_cell_volume                     5576.3(6)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      123(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker Apex X8'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0406
_diffrn_reflns_av_sigmaI/netI    0.0608
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            21335
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         2.16
_exptl_absorpt_coefficient_mu    0.374
_exptl_absorpt_correction_T_max  0.953
_exptl_absorpt_correction_T_min  0.934
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Sortav (Blessing)'
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.226
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2172
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.13
_refine_diff_density_max         0.412
_refine_diff_density_min         -0.472
_refine_diff_density_rms         0.058
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.010
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     677
_refine_ls_number_reflns         10314
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.010
_refine_ls_R_factor_all          0.0733
_refine_ls_R_factor_gt           0.0474
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0491P)²+3.4065P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1071
_refine_ls_wR_factor_ref         0.1205
_reflns_number_gt                7666
_reflns_number_total             10314
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om501233f_si_002.cif
_cod_data_source_block           compound5
_cod_depositor_comments
'Adding full bibliography for 4085265--4085269.cif.'
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               4085265
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Co1 Co 0.96375(3) 0.101990(19) 0.181313(15) 0.02517(11) Uani 1 1 d .
Si1 Si 0.76651(5) 0.18506(4) 0.18102(3) 0.01701(15) Uani 1 1 d .
N1 N 0.89074(14) 0.17032(11) 0.21615(8) 0.0175(4) Uani 1 1 d .
C1 C 0.94692(16) 0.20985(13) 0.26868(9) 0.0155(5) Uani 1 1 d .
C2 C 0.95412(17) 0.18309(13) 0.32755(10) 0.0171(5) Uani 1 1 d .
C3 C 1.00439(17) 0.22388(13) 0.37816(10) 0.0191(5) Uani 1 1 d .
H3 H 1.0079 0.2049 0.4172 0.023 Uiso 1 1 calc R
C4 C 1.04962(17) 0.29110(13) 0.37403(10) 0.0192(5) Uani 1 1 d .
C5 C 1.04407(17) 0.31631(13) 0.31618(10) 0.0197(5) Uani 1 1 d .
H5 H 1.0744 0.3622 0.3120 0.024 Uiso 1 1 calc R
C6 C 0.99570(17) 0.27704(13) 0.26402(10) 0.0171(5) Uani 1 1 d .
C7 C 1.1049(2) 0.33317(15) 0.43012(11) 0.0273(6) Uani 1 1 d .
H7A H 1.1738 0.3148 0.4446 0.041 Uiso 1 1 calc R
H7B H 1.0711 0.3262 0.4617 0.041 Uiso 1 1 calc R
H7C H 1.1058 0.3857 0.4204 0.041 Uiso 1 1 calc R
C8 C 0.91199(18) 0.10775(13) 0.33634(10) 0.0190(5) Uani 1 1 d .
H8 H 0.8542 0.0986 0.2998 0.023 Uiso 1 1 calc R
C9 C 0.86944(17) 0.10807(13) 0.39100(10) 0.0183(5) Uani 1 1 d .
C10 C 0.9120(2) 0.06970(15) 0.44414(11) 0.0271(6) Uani 1 1 d .
H10 H 0.9685 0.0390 0.4470 0.033 Uiso 1 1 calc R
C11 C 0.8728(2) 0.07563(16) 0.49333(11) 0.0323(6) Uani 1 1 d .
H11 H 0.9026 0.0488 0.5294 0.039 Uiso 1 1 calc R
C12 C 0.7917(2) 0.11981(15) 0.49022(12) 0.0296(6) Uani 1 1 d .
H12 H 0.7661 0.1247 0.5242 0.036 Uiso 1 1 calc R
C13 C 0.7474(2) 0.15737(16) 0.43686(13) 0.0350(7) Uani 1 1 d .
H13 H 0.6900 0.1872 0.4338 0.042 Uiso 1 1 calc R
C14 C 0.78656(19) 0.15140(16) 0.38828(12) 0.0294(6) Uani 1 1 d .
H14 H 0.7559 0.1777 0.3521 0.035 Uiso 1 1 calc R
C15 C 0.98708(19) 0.04548(14) 0.33861(10) 0.0220(5) Uani 1 1 d .
C16 C 0.9530(2) -0.02678(15) 0.32827(11) 0.0302(6) Uani 1 1 d .
H16 H 0.8835 -0.0368 0.3197 0.036 Uiso 1 1 calc R
C17 C 1.0192(3) -0.08438(16) 0.33030(12) 0.0392(8) Uani 1 1 d .
H17 H 0.9945 -0.1333 0.3228 0.047 Uiso 1 1 calc R
C18 C 1.1208(3) -0.07131(17) 0.34313(12) 0.0415(8) Uani 1 1 d .
H18 H 1.1661 -0.1109 0.3445 0.050 Uiso 1 1 calc R
C19 C 1.1558(2) 0.00033(17) 0.35395(12) 0.0375(7) Uani 1 1 d .
H19 H 1.2255 0.0100 0.3631 0.045 Uiso 1 1 calc R
C20 C 1.0892(2) 0.05827(15) 0.35153(11) 0.0275(6) Uani 1 1 d .
H20 H 1.1140 0.1072 0.3588 0.033 Uiso 1 1 calc R
C21 C 0.99888(18) 0.30528(13) 0.20202(10) 0.0190(5) Uani 1 1 d .
H21 H 0.9400 0.2829 0.1717 0.023 Uiso 1 1 calc R
C22 C 0.98565(19) 0.38870(14) 0.19556(10) 0.0237(6) Uani 1 1 d .
C23 C 1.0658(2) 0.43720(15) 0.20904(11) 0.0315(6) Uani 1 1 d .
H23 H 1.1322 0.4189 0.2233 0.038 Uiso 1 1 calc R
C24 C 1.0491(3) 0.51290(17) 0.20171(13) 0.0418(8) Uani 1 1 d .
H24 H 1.1042 0.5460 0.2118 0.050 Uiso 1 1 calc R
C25 C 0.9527(3) 0.54011(17) 0.17980(13) 0.0419(8) Uani 1 1 d .
H25 H 0.9417 0.5917 0.1743 0.050 Uiso 1 1 calc R
C26 C 0.8731(2) 0.49229(16) 0.16604(12) 0.0369(7) Uani 1 1 d .
H26 H 0.8068 0.5106 0.1508 0.044 Uiso 1 1 calc R
C27 C 0.8896(2) 0.41704(15) 0.17446(11) 0.0281(6) Uani 1 1 d .
H27 H 0.8340 0.3844 0.1656 0.034 Uiso 1 1 calc R
C28 C 1.09170(18) 0.27894(14) 0.18514(10) 0.0214(5) Uani 1 1 d .
C29 C 1.0949(2) 0.28421(14) 0.12530(11) 0.0253(6) Uani 1 1 d .
H29 H 1.0380 0.3023 0.0953 0.030 Uiso 1 1 calc R
C30 C 1.1793(2) 0.26363(15) 0.10881(12) 0.0305(6) Uani 1 1 d .
H30 H 1.1798 0.2676 0.0677 0.037 Uiso 1 1 calc R
C31 C 1.2629(2) 0.23744(16) 0.15171(13) 0.0365(7) Uani 1 1 d .
H31 H 1.3212 0.2241 0.1406 0.044 Uiso 1 1 calc R
C32 C 1.2603(2) 0.23096(19) 0.21053(13) 0.0441(8) Uani 1 1 d .
H32 H 1.3170 0.2121 0.2403 0.053 Uiso 1 1 calc R
C33 C 1.1754(2) 0.25170(17) 0.22721(12) 0.0352(7) Uani 1 1 d .
H33 H 1.1752 0.2470 0.2683 0.042 Uiso 1 1 calc R
C34 C 0.69794(17) 0.22784(13) 0.23284(10) 0.0189(5) Uani 1 1 d .
C35 C 0.73567(19) 0.29030(14) 0.26744(11) 0.0234(5) Uani 1 1 d .
H35 H 0.7972 0.3110 0.2653 0.028 Uiso 1 1 calc R
C36 C 0.6848(2) 0.32277(15) 0.30510(12) 0.0288(6) Uani 1 1 d .
H36 H 0.7120 0.3652 0.3281 0.035 Uiso 1 1 calc R
C37 C 0.59541(19) 0.29383(15) 0.30915(11) 0.0278(6) Uani 1 1 d .
H37 H 0.5615 0.3154 0.3354 0.033 Uiso 1 1 calc R
C38 C 0.55580(19) 0.23317(15) 0.27465(12) 0.0283(6) Uani 1 1 d .
H38 H 0.4936 0.2134 0.2766 0.034 Uiso 1 1 calc R
C39 C 0.60609(18) 0.20068(14) 0.23695(11) 0.0246(6) Uani 1 1 d .
H39 H 0.5773 0.1590 0.2134 0.029 Uiso 1 1 calc R
C40 C 0.74247(18) 0.24961(13) 0.11382(10) 0.0197(5) Uani 1 1 d .
C41 C 0.6607(2) 0.29792(15) 0.10088(11) 0.0299(6) Uani 1 1 d .
H41 H 0.6162 0.2969 0.1255 0.036 Uiso 1 1 calc R
C42 C 0.6432(2) 0.34737(17) 0.05278(12) 0.0386(7) Uani 1 1 d .
H42 H 0.5876 0.3800 0.0450 0.046 Uiso 1 1 calc R
C43 C 0.7067(2) 0.34891(17) 0.01633(12) 0.0358(7) Uani 1 1 d .
H43 H 0.6955 0.3831 -0.0162 0.043 Uiso 1 1 calc R
C44 C 0.7862(2) 0.30098(16) 0.02703(11) 0.0297(6) Uani 1 1 d .
H44 H 0.8293 0.3015 0.0016 0.036 Uiso 1 1 calc R
C45 C 0.80346(19) 0.25165(14) 0.07512(10) 0.0230(5) Uani 1 1 d .
H45 H 0.8583 0.2185 0.0818 0.028 Uiso 1 1 calc R
C46 C 0.70413(17) 0.09542(13) 0.15154(10) 0.0197(5) Uani 1 1 d .
C47 C 0.67207(18) 0.07874(15) 0.08974(11) 0.0241(6) Uani 1 1 d .
H47 H 0.6802 0.1146 0.0614 0.029 Uiso 1 1 calc R
C48 C 0.62899(19) 0.01170(15) 0.06858(12) 0.0289(6) Uani 1 1 d .
H48 H 0.6094 0.0017 0.0263 0.035 Uiso 1 1 calc R
C49 C 0.61430(19) -0.04084(15) 0.10870(12) 0.0305(6) Uani 1 1 d .
H49 H 0.5851 -0.0870 0.0942 0.037 Uiso 1 1 calc R
C50 C 0.64246(19) -0.02575(15) 0.17029(12) 0.0286(6) Uani 1 1 d .
H50 H 0.6307 -0.0610 0.1980 0.034 Uiso 1 1 calc R
C51 C 0.68778(18) 0.04086(14) 0.19116(11) 0.0229(5) Uani 1 1 d .
H51 H 0.7085 0.0500 0.2335 0.027 Uiso 1 1 calc R
C52 C 0.9111(2) 0.00163(15) 0.13150(12) 0.0318(6) Uani 1 1 d .
H52 H 0.8502 -0.0245 0.1262 0.038 Uiso 1 1 calc R
C53 C 0.9187(2) 0.05609(16) 0.09026(11) 0.0328(6) Uani 1 1 d .
H53 H 0.8628 0.0666 0.0566 0.039 Uiso 1 1 calc R
C54 C 1.0068(2) 0.09498(16) 0.09795(12) 0.0351(7) Uani 1 1 d .
H54 H 1.0111 0.1320 0.0696 0.042 Uiso 1 1 calc R
C55 C 1.0892(2) 0.07999(17) 0.14717(14) 0.0391(7) Uani 1 1 d .
H55 H 1.1496 0.1070 0.1527 0.047 Uiso 1 1 calc R
C56 C 1.0826(2) 0.02492(17) 0.18854(13) 0.0385(7) Uani 1 1 d .
H56 H 1.1388 0.0142 0.2220 0.046 Uiso 1 1 calc R
C57 C 0.9937(2) -0.01420(15) 0.18070(12) 0.0352(7) Uani 1 1 d .
H57 H 0.9893 -0.0516 0.2088 0.042 Uiso 1 1 calc R
C58 C 0.5777(3) -0.1427(3) -0.0626(2) 0.0787(14) Uani 1 1 d .
H58 H 0.5128 -0.1640 -0.0744 0.094 Uiso 1 1 calc R
C59 C 0.6439(3) -0.1689(3) -0.0147(2) 0.0738(12) Uani 1 1 d .
H59 H 0.6265 -0.2086 0.0072 0.089 Uiso 1 1 calc R
C60 C 0.7372(3) -0.1396(3) 0.00371(17) 0.0627(11) Uani 1 1 d .
H60 H 0.7838 -0.1590 0.0389 0.075 Uiso 1 1 calc R
C61 C 0.7661(3) -0.0834(2) -0.02663(19) 0.0642(11) Uani 1 1 d .
H61 H 0.8320 -0.0638 -0.0132 0.077 Uiso 1 1 calc R
C62 C 0.6953(4) -0.0547(2) -0.0790(2) 0.0785(14) Uani 1 1 d .
H62 H 0.7119 -0.0156 -0.1019 0.094 Uiso 1 1 calc R
C63 C 0.5975(3) -0.0877(3) -0.09540(19) 0.0728(14) Uani 1 1 d .
H63 H 0.5472 -0.0702 -0.1297 0.087 Uiso 1 1 calc R
C64 C 0.8361(3) 0.2147(2) -0.12022(15) 0.0539(9) Uani 1 1 d .
H64 H 0.7799 0.1881 -0.1441 0.065 Uiso 1 1 calc R
C65 C 0.8404(3) 0.2905(2) -0.12425(14) 0.0558(9) Uani 1 1 d .
H65 H 0.7867 0.3165 -0.1512 0.067 Uiso 1 1 calc R
C66 C 0.9216(3) 0.3287(2) -0.08961(15) 0.0565(10) Uani 1 1 d .
H66 H 0.9244 0.3809 -0.0929 0.068 Uiso 1 1 calc R
C67 C 0.9977(3) 0.2917(3) -0.05078(16) 0.0572(10) Uani 1 1 d .
H67 H 1.0533 0.3184 -0.0264 0.069 Uiso 1 1 calc R
C68 C 0.9958(2) 0.2181(2) -0.04619(14) 0.0544(10) Uani 1 1 d .
H68 H 1.0502 0.1933 -0.0189 0.065 Uiso 1 1 calc R
C69 C 0.9158(3) 0.1778(2) -0.08062(15) 0.0555(9) Uani 1 1 d .
H69 H 0.9151 0.1256 -0.0773 0.067 Uiso 1 1 calc R
C70 C 0.9758(2) 0.45833(16) 0.04389(12) 0.0341(7) Uani 1 1 d .
H70 H 0.9594 0.4298 0.0744 0.041 Uiso 1 1 calc R
C71 C 1.0733(2) 0.46144(16) 0.04149(12) 0.0341(7) Uani 1 1 d .
H71 H 1.1240 0.4346 0.0700 0.041 Uiso 1 1 calc R
C72 C 1.0976(2) 0.50369(16) -0.00239(13) 0.0360(7) Uani 1 1 d .
H72 H 1.1651 0.5064 -0.0038 0.043 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
N1 Co1 C56 151.80(9) .
N1 Co1 C55 148.93(10) .
C56 Co1 C55 38.19(12) .
N1 Co1 C57 139.78(9) .
C56 Co1 C57 37.95(12) .
C55 Co1 C57 68.63(11) .
N1 Co1 C52 128.67(9) .
C56 Co1 C52 68.28(11) .
C55 Co1 C52 80.70(11) .
C57 Co1 C52 37.78(11) .
N1 Co1 C54 136.04(10) .
C56 Co1 C54 68.22(11) .
C55 Co1 C54 37.64(12) .
C57 Co1 C54 80.45(10) .
C52 Co1 C54 67.61(10) .
N1 Co1 C53 127.43(9) .
C56 Co1 C53 80.25(10) .
C55 Co1 C53 67.59(11) .
C57 Co1 C53 67.80(11) .
C52 Co1 C53 37.46(10) .
C54 Co1 C53 37.09(11) .
N1 Si1 C46 109.77(10) .
N1 Si1 C34 112.90(10) .
C46 Si1 C34 108.57(10) .
N1 Si1 C40 113.86(10) .
C46 Si1 C40 106.46(10) .
C34 Si1 C40 104.92(10) .
C1 N1 Si1 123.96(15) .
C1 N1 Co1 116.67(14) .
Si1 N1 Co1 119.23(10) .
C6 C1 C2 117.5(2) .
C6 C1 N1 121.76(19) .
C2 C1 N1 120.7(2) .
C3 C2 C1 120.1(2) .
C3 C2 C8 119.2(2) .
C1 C2 C8 120.58(19) .
C4 C3 C2 122.7(2) .
C3 C4 C5 116.8(2) .
C3 C4 C7 121.1(2) .
C5 C4 C7 122.0(2) .
C4 C5 C6 122.7(2) .
C5 C6 C1 120.0(2) .
C5 C6 C21 119.9(2) .
C1 C6 C21 120.07(19) .
C2 C8 C15 112.43(19) .
C2 C8 C9 110.97(18) .
C15 C8 C9 113.16(18) .
C14 C9 C10 117.9(2) .
C14 C9 C8 118.4(2) .
C10 C9 C8 123.6(2) .
C9 C10 C11 120.7(2) .
C12 C11 C10 120.6(2) .
C11 C12 C13 119.2(2) .
C14 C13 C12 120.0(2) .
C13 C14 C9 121.6(2) .
C20 C15 C16 118.2(2) .
C20 C15 C8 122.2(2) .
C16 C15 C8 119.5(2) .
C17 C16 C15 120.9(3) .
C18 C17 C16 120.6(3) .
C17 C18 C19 119.1(3) .
C18 C19 C20 120.3(3) .
C15 C20 C19 120.9(3) .
C22 C21 C28 111.88(19) .
C22 C21 C6 112.86(18) .
C28 C21 C6 112.49(19) .
C23 C22 C27 118.7(2) .
C23 C22 C21 122.7(2) .
C27 C22 C21 118.6(2) .
C22 C23 C24 120.1(3) .
C25 C24 C23 120.4(3) .
C26 C25 C24 119.7(3) .
C25 C26 C27 119.9(3) .
C22 C27 C26 121.2(3) .
C33 C28 C29 117.5(2) .
C33 C28 C21 122.8(2) .
C29 C28 C21 119.7(2) .
C30 C29 C28 121.3(2) .
C31 C30 C29 120.4(2) .
C32 C31 C30 119.0(2) .
C31 C32 C33 120.6(3) .
C28 C33 C32 121.2(2) .
C39 C34 C35 116.7(2) .
C39 C34 Si1 122.17(19) .
C35 C34 Si1 121.04(17) .
C36 C35 C34 121.4(2) .
C37 C36 C35 120.6(2) .
C38 C37 C36 119.2(2) .
C37 C38 C39 120.5(2) .
C38 C39 C34 121.6(2) .
C45 C40 C41 116.9(2) .
C45 C40 Si1 122.65(19) .
C41 C40 Si1 120.41(18) .
C42 C41 C40 121.4(2) .
C43 C42 C41 119.9(3) .
C44 C43 C42 120.0(2) .
C43 C44 C45 120.0(2) .
C44 C45 C40 121.7(2) .
C47 C46 C51 116.3(2) .
C47 C46 Si1 122.48(19) .
C51 C46 Si1 121.18(17) .
C48 C47 C46 122.1(2) .
C49 C48 C47 120.2(2) .
C48 C49 C50 119.6(2) .
C51 C50 C49 119.7(2) .
C50 C51 C46 122.0(2) .
C53 C52 C57 119.6(3) .
C53 C52 Co1 71.69(16) .
C57 C52 Co1 70.47(16) .
C54 C53 C52 120.6(3) .
C54 C53 Co1 71.21(15) .
C52 C53 Co1 70.85(15) .
C53 C54 C55 120.1(3) .
C53 C54 Co1 71.70(15) .
C55 C54 Co1 70.23(15) .
C54 C55 C56 119.7(3) .
C54 C55 Co1 72.13(16) .
C56 C55 Co1 70.53(15) .
C57 C56 C55 120.1(3) .
C57 C56 Co1 71.52(16) .
C55 C56 Co1 71.27(17) .
C56 C57 C52 119.8(3) .
C56 C57 Co1 70.53(16) .
C52 C57 Co1 71.75(16) .
C59 C58 C63 122.8(5) .
C58 C59 C60 120.3(5) .
C59 C60 C61 122.0(4) .
C60 C61 C62 118.4(4) .
C61 C62 C63 116.7(4) .
C58 C63 C62 119.8(4) .
C65 C64 C69 118.8(3) .
C66 C65 C64 120.5(4) .
C67 C66 C65 119.7(4) .
C68 C67 C66 121.1(4) .
C67 C68 C69 120.9(4) .
C68 C69 C64 119.1(4) .
C72 C70 C71 120.1(2) 3_765
C70 C71 C72 120.0(3) .
C70 C72 C71 119.9(3) 3_765
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Co1 N1 1.9166(19) .
Co1 C56 2.136(3) .
Co1 C55 2.146(3) .
Co1 C57 2.149(3) .
Co1 C52 2.165(3) .
Co1 C54 2.170(2) .
Co1 C53 2.176(3) .
Si1 N1 1.711(2) .
Si1 C46 1.877(3) .
Si1 C34 1.892(2) .
Si1 C40 1.893(2) .
N1 C1 1.433(3) .
C1 C6 1.414(3) .
C1 C2 1.416(3) .
C2 C3 1.390(3) .
C2 C8 1.523(3) .
C3 C4 1.388(3) .
C4 C5 1.389(3) .
C4 C7 1.510(3) .
C5 C6 1.395(3) .
C6 C21 1.529(3) .
C8 C15 1.530(3) .
C8 C9 1.535(3) .
C9 C14 1.383(4) .
C9 C10 1.386(3) .
C10 C11 1.393(3) .
C11 C12 1.370(4) .
C12 C13 1.388(4) .
C13 C14 1.380(4) .
C15 C20 1.387(4) .
C15 C16 1.391(4) .
C16 C17 1.385(4) .
C17 C18 1.382(5) .
C18 C19 1.385(4) .
C19 C20 1.392(4) .
C21 C22 1.526(3) .
C21 C28 1.528(3) .
C22 C23 1.386(4) .
C22 C27 1.387(4) .
C23 C24 1.395(4) .
C24 C25 1.384(5) .
C25 C26 1.372(4) .
C26 C27 1.388(4) .
C28 C33 1.380(4) .
C28 C29 1.394(3) .
C29 C30 1.385(4) .
C30 C31 1.380(4) .
C31 C32 1.369(4) .
C32 C33 1.394(4) .
C34 C39 1.399(3) .
C34 C35 1.399(3) .
C35 C36 1.396(3) .
C36 C37 1.378(4) .
C37 C38 1.377(4) .
C38 C39 1.391(3) .
C40 C45 1.394(3) .
C40 C41 1.400(4) .
C41 C42 1.392(4) .
C42 C43 1.381(4) .
C43 C44 1.373(4) .
C44 C45 1.390(3) .
C46 C47 1.398(3) .
C46 C51 1.407(3) .
C47 C48 1.382(4) .
C48 C49 1.382(4) .
C49 C50 1.387(4) .
C50 C51 1.385(4) .
C52 C53 1.394(4) .
C52 C57 1.397(4) .
C53 C54 1.382(4) .
C54 C55 1.392(4) .
C55 C56 1.401(4) .
C56 C57 1.393(4) .
C58 C59 1.311(6) .
C58 C63 1.325(6) .
C59 C60 1.356(6) .
C60 C61 1.359(6) .
C61 C62 1.423(6) .
C62 C63 1.437(7) .
C64 C65 1.381(5) .
C64 C69 1.392(5) .
C65 C66 1.373(5) .
C66 C67 1.355(5) .
C67 C68 1.341(5) .
C68 C69 1.380(5) .
C70 C72 1.372(4) 3_765
C70 C71 1.375(4) .
C71 C72 1.384(4) .
C72 C70 1.372(4) 3_765
