#------------------------------------------------------------------------------
#$Date: 2016-03-21 15:20:55 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178744 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/55/4085556.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4085556
loop_
_publ_author_name
'Massard, Alexandre'
'Braunstein, Pierre'
'Danopoulos, Andreas A.'
'Choua, Sylvie'
'Rabu, Pierre'
_publ_section_title
;
 Studies on Three-Coordinate [Co{N(SiMe3)2}2L] Complexes, L =
 N-Heterocyclic Carbene
;
_journal_issue                   11
_journal_name_full               Organometallics
_journal_page_first              2429
_journal_paper_doi               10.1021/om501178p
_journal_volume                  34
_journal_year                    2015
_chemical_formula_moiety         'C51 H72 Co N4'
_chemical_formula_sum            'C51 H72 Co N4'
_chemical_formula_weight         800.05
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 112.3690(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   21.6856(8)
_cell_length_b                   9.3146(3)
_cell_length_c                   24.5721(9)
_cell_measurement_reflns_used    6804
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      29.45
_cell_measurement_theta_min      2.41
_cell_volume                     4589.9(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0689
_diffrn_reflns_av_unetI/netI     0.0583
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            32793
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.027
_diffrn_reflns_theta_min         1.792
_diffrn_source                   'fine focus sealed tube'
_exptl_absorpt_coefficient_mu    0.411
_exptl_absorpt_correction_T_max  0.7460
_exptl_absorpt_correction_T_min  0.6591
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.158
_exptl_crystal_description       prism
_exptl_crystal_F_000             1732
_exptl_crystal_size_max          0.320
_exptl_crystal_size_mid          0.250
_exptl_crystal_size_min          0.200
_refine_diff_density_max         0.946
_refine_diff_density_min         -0.515
_refine_diff_density_rms         0.064
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     266
_refine_ls_number_reflns         6675
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.047
_refine_ls_R_factor_all          0.1070
_refine_ls_R_factor_gt           0.0666
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0565P)²+7.3352P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1345
_refine_ls_wR_factor_ref         0.1520
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4632
_reflns_number_total             6675
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            om501178p_si_002.cif
_cod_data_source_block           complex10pbad140930
_cod_depositor_comments
'Adding full bibliography for 4085549--4085557.cif.'
_cod_database_code               4085556
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.880
_shelx_estimated_absorpt_t_max   0.922
_shelxl_version_number           2013-4
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
C1 C 1.0000 0.6524(3) 0.2500 0.0239(6) Uani 1 2 d S T P
C2 C 1.01482(12) 0.4188(3) 0.27952(10) 0.0318(5) Uani 1 1 d . . .
H2 H 1.0273 0.3369 0.3044 0.038 Uiso 1 1 calc R U .
C3 C 1.05215(12) 0.5979(2) 0.35881(9) 0.0314(5) Uani 1 1 d . . .
C4 C 1.00948(16) 0.6114(3) 0.38850(11) 0.0468(7) Uani 1 1 d . . .
C5 C 1.0400(2) 0.6317(4) 0.44987(13) 0.0749(12) Uani 1 1 d . . .
H5 H 1.0129 0.6427 0.4722 0.090 Uiso 1 1 calc R U .
C6 C 1.1083(3) 0.6356(4) 0.47796(14) 0.0865(15) Uani 1 1 d . . .
H6 H 1.1279 0.6459 0.5195 0.104 Uiso 1 1 calc R U .
C7 C 1.1474(2) 0.6251(4) 0.44699(14) 0.0753(12) Uani 1 1 d . . .
H7 H 1.1944 0.6313 0.4672 0.090 Uiso 1 1 calc R U .
C8 C 1.12179(14) 0.6054(3) 0.38652(12) 0.0465(7) Uani 1 1 d . . .
C9 C 0.93492(17) 0.6060(4) 0.35785(14) 0.0617(10) Uani 1 1 d . . .
H9 H 0.9233 0.6297 0.3154 0.074 Uiso 1 1 calc R U .
C10 C 0.9009(2) 0.7159(5) 0.3835(2) 0.0984(16) Uani 1 1 d . . .
H10A H 0.9030 0.6826 0.4220 0.148 Uiso 1 1 calc R U .
H10B H 0.8542 0.7268 0.3569 0.148 Uiso 1 1 calc R U .
H10C H 0.9237 0.8085 0.3879 0.148 Uiso 1 1 calc R U .
C11 C 0.9077(2) 0.4597(5) 0.3613(2) 0.0976(16) Uani 1 1 d . . .
H11A H 0.9306 0.3879 0.3467 0.146 Uiso 1 1 calc R U .
H11B H 0.8598 0.4576 0.3372 0.146 Uiso 1 1 calc R U .
H11C H 0.9148 0.4381 0.4023 0.146 Uiso 1 1 calc R U .
C12 C 1.16739(14) 0.5881(4) 0.35344(16) 0.0663(10) Uani 1 1 d . . .
H12 H 1.1430 0.6209 0.3120 0.080 Uiso 1 1 calc R U .
C13 C 1.23174(18) 0.6759(5) 0.3802(3) 0.119(2) Uani 1 1 d . . .
H13A H 1.2207 0.7758 0.3851 0.178 Uiso 1 1 calc R U .
H13B H 1.2563 0.6723 0.3539 0.178 Uiso 1 1 calc R U .
H13C H 1.2594 0.6356 0.4186 0.178 Uiso 1 1 calc R U .
C14 C 1.1870(2) 0.4318(5) 0.3523(2) 0.0834(12) Uani 1 1 d . . .
H14A H 1.2082 0.3960 0.3927 0.125 Uiso 1 1 calc R U .
H14B H 1.2184 0.4240 0.3324 0.125 Uiso 1 1 calc R U .
H14C H 1.1471 0.3747 0.3310 0.125 Uiso 1 1 calc R U .
C15 C 0.89013(11) 1.0083(2) 0.14376(10) 0.0291(5) Uani 1 1 d . . .
C16 C 0.87012(12) 1.0447(3) 0.08303(10) 0.0334(5) Uani 1 1 d . . .
C17 C 0.80457(13) 1.0862(3) 0.05129(11) 0.0415(6) Uani 1 1 d . . .
H17 H 0.7914 1.1099 0.0108 0.050 Uiso 1 1 calc R U .
C18 C 0.75819(13) 1.0938(3) 0.07695(13) 0.0475(7) Uani 1 1 d . . .
H18 H 0.7137 1.1223 0.0545 0.057 Uiso 1 1 calc R U .
C19 C 0.77726(13) 1.0593(3) 0.13563(12) 0.0436(6) Uani 1 1 d . . .
H19 H 0.7453 1.0649 0.1533 0.052 Uiso 1 1 calc R U .
C20 C 0.84196(12) 1.0167(3) 0.16962(11) 0.0342(5) Uani 1 1 d . . .
C21 C 0.92066(13) 1.0444(3) 0.05429(10) 0.0393(6) Uani 1 1 d . . .
H21 H 0.9519 0.9626 0.0716 0.047 Uiso 1 1 calc R U .
C22 C 0.96195(16) 1.1818(4) 0.06917(13) 0.0535(8) Uani 1 1 d . . .
H22A H 0.9330 1.2643 0.0522 0.080 Uiso 1 1 calc R U .
H22B H 0.9967 1.1766 0.0529 0.080 Uiso 1 1 calc R U .
H22C H 0.9827 1.1928 0.1120 0.080 Uiso 1 1 calc R U .
C23 C 0.89045(17) 1.0220(4) -0.01256(12) 0.0603(9) Uani 1 1 d . . .
H23A H 0.8618 1.1038 -0.0313 0.090 Uiso 1 1 calc R U .
H23B H 0.8639 0.9336 -0.0217 0.090 Uiso 1 1 calc R U .
H23C H 0.9263 1.0142 -0.0274 0.090 Uiso 1 1 calc R U .
C24 C 0.86019(13) 0.9851(3) 0.23446(11) 0.0418(6) Uani 1 1 d . . .
H24 H 0.8952 0.9086 0.2458 0.050 Uiso 1 1 calc R U .
C25 C 0.80221(18) 0.9296(6) 0.24959(16) 0.0944(16) Uani 1 1 d . . .
H25A H 0.7677 1.0039 0.2405 0.142 Uiso 1 1 calc R U .
H25B H 0.8184 0.9062 0.2916 0.142 Uiso 1 1 calc R U .
H25C H 0.7834 0.8434 0.2264 0.142 Uiso 1 1 calc R U .
C26 C 0.89055(16) 1.1167(4) 0.27137(13) 0.0580(8) Uani 1 1 d . . .
H26A H 0.9289 1.1493 0.2629 0.087 Uiso 1 1 calc R U .
H26B H 0.9051 1.0924 0.3132 0.087 Uiso 1 1 calc R U .
H26C H 0.8572 1.1934 0.2619 0.087 Uiso 1 1 calc R U .
N1 N 1.02361(9) 0.5610(2) 0.29699(7) 0.0246(4) Uani 1 1 d . . .
N2 N 0.95456(10) 0.9652(2) 0.17669(9) 0.0330(5) Uani 1 1 d . . .
Co1 Co 1.0000 0.87335(5) 0.2500 0.02470(13) Uani 1 2 d S T P
H2N H 0.9797(14) 0.966(3) 0.1568(12) 0.043(8) Uiso 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C1 N1 103.0(3) . 2_755
N1 C1 Co1 128.50(13) . .
N1 C1 Co1 128.50(13) 2_755 .
C2 C2 N1 106.71(12) 2_755 .
C2 C2 H2 126.6 2_755 .
N1 C2 H2 126.6 . .
C4 C3 C8 123.5(2) . .
C4 C3 N1 118.0(2) . .
C8 C3 N1 118.2(2) . .
C3 C4 C5 116.1(3) . .
C3 C4 C9 122.7(2) . .
C5 C4 C9 121.2(3) . .
C6 C5 C4 121.2(3) . .
C6 C5 H5 119.4 . .
C4 C5 H5 119.4 . .
C7 C6 C5 120.4(3) . .
C7 C6 H6 119.8 . .
C5 C6 H6 119.8 . .
C6 C7 C8 122.4(4) . .
C6 C7 H7 118.8 . .
C8 C7 H7 118.8 . .
C7 C8 C3 116.5(3) . .
C7 C8 C12 120.9(3) . .
C3 C8 C12 122.6(2) . .
C11 C9 C4 112.0(3) . .
C11 C9 C10 108.8(3) . .
C4 C9 C10 111.5(3) . .
C11 C9 H9 108.1 . .
C4 C9 H9 108.1 . .
C10 C9 H9 108.1 . .
C9 C10 H10A 109.5 . .
C9 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C9 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C9 C11 H11A 109.5 . .
C9 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C9 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C8 C12 C14 111.0(3) . .
C8 C12 C13 112.9(4) . .
C14 C12 C13 107.6(3) . .
C8 C12 H12 108.4 . .
C14 C12 H12 108.4 . .
C13 C12 H12 108.4 . .
C12 C13 H13A 109.5 . .
C12 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C12 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
C12 C14 H14A 109.5 . .
C12 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C12 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
N2 C15 C20 120.5(2) . .
N2 C15 C16 121.2(2) . .
C20 C15 C16 118.3(2) . .
C17 C16 C15 119.4(2) . .
C17 C16 C21 120.4(2) . .
C15 C16 C21 120.1(2) . .
C18 C17 C16 121.8(2) . .
C18 C17 H17 119.1 . .
C16 C17 H17 119.1 . .
C17 C18 C19 119.1(2) . .
C17 C18 H18 120.4 . .
C19 C18 H18 120.4 . .
C18 C19 C20 121.8(3) . .
C18 C19 H19 119.1 . .
C20 C19 H19 119.1 . .
C19 C20 C15 119.6(2) . .
C19 C20 C24 119.1(2) . .
C15 C20 C24 121.2(2) . .
C16 C21 C22 110.5(2) . .
C16 C21 C23 114.2(2) . .
C22 C21 C23 110.1(2) . .
C16 C21 H21 107.2 . .
C22 C21 H21 107.2 . .
C23 C21 H21 107.2 . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C21 C23 H23A 109.5 . .
C21 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C21 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C20 C24 C26 110.6(2) . .
C20 C24 C25 114.3(2) . .
C26 C24 C25 109.7(3) . .
C20 C24 H24 107.3 . .
C26 C24 H24 107.3 . .
C25 C24 H24 107.3 . .
C24 C25 H25A 109.5 . .
C24 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
C24 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
C24 C26 H26A 109.5 . .
C24 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C24 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
C1 N1 C2 111.80(18) . .
C1 N1 C3 127.74(19) . .
C2 N1 C3 120.41(18) . .
C15 N2 Co1 137.04(18) . .
C15 N2 H2N 112.6(19) . .
Co1 N2 H2N 109.2(19) . .
N2 Co1 N2 126.39(13) 2_755 .
N2 Co1 C1 116.81(7) 2_755 .
N2 Co1 C1 116.80(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.368(3) .
C1 N1 1.368(3) 2_755
C1 Co1 2.058(3) .
C2 C2 1.345(4) 2_755
C2 N1 1.384(3) .
C2 H2 0.9500 .
C3 C4 1.385(4) .
C3 C8 1.402(4) .
C3 N1 1.447(3) .
C4 C5 1.410(4) .
C4 C9 1.502(4) .
C5 C6 1.376(6) .
C5 H5 0.9500 .
C6 C7 1.341(6) .
C6 H6 0.9500 .
C7 C8 1.386(4) .
C7 H7 0.9500 .
C8 C12 1.509(5) .
C9 C11 1.500(6) .
C9 C10 1.530(5) .
C9 H9 1.0000 .
C10 H10A 0.9800 .
C10 H10B 0.9800 .
C10 H10C 0.9800 .
C11 H11A 0.9800 .
C11 H11B 0.9800 .
C11 H11C 0.9800 .
C12 C14 1.520(6) .
C12 C13 1.533(5) .
C12 H12 1.0000 .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 N2 1.381(3) .
C15 C20 1.416(3) .
C15 C16 1.427(3) .
C16 C17 1.391(3) .
C16 C21 1.513(4) .
C17 C18 1.377(4) .
C17 H17 0.9500 .
C18 C19 1.378(4) .
C18 H18 0.9500 .
C19 C20 1.390(3) .
C19 H19 0.9500 .
C20 C24 1.517(4) .
C21 C22 1.525(4) .
C21 C23 1.533(3) .
C21 H21 1.0000 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
C24 C26 1.518(4) .
C24 C25 1.530(4) .
C24 H24 1.0000 .
C25 H25A 0.9800 .
C25 H25B 0.9800 .
C25 H25C 0.9800 .
C26 H26A 0.9800 .
C26 H26B 0.9800 .
C26 H26C 0.9800 .
N2 Co1 1.896(2) .
N2 H2N 0.86(3) .
Co1 N2 1.896(2) 2_755
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C8 C3 C4 C5 -0.9(4) . .
N1 C3 C4 C5 173.2(2) . .
C8 C3 C4 C9 178.8(3) . .
N1 C3 C4 C9 -7.1(4) . .
C3 C4 C5 C6 -0.8(5) . .
C9 C4 C5 C6 179.5(3) . .
C4 C5 C6 C7 2.2(6) . .
C5 C6 C7 C8 -2.1(6) . .
C6 C7 C8 C3 0.4(5) . .
C6 C7 C8 C12 -177.6(3) . .
C4 C3 C8 C7 1.1(4) . .
N1 C3 C8 C7 -173.0(2) . .
C4 C3 C8 C12 179.1(3) . .
N1 C3 C8 C12 4.9(4) . .
C3 C4 C9 C11 97.5(4) . .
C5 C4 C9 C11 -82.9(4) . .
C3 C4 C9 C10 -140.4(3) . .
C5 C4 C9 C10 39.3(4) . .
C7 C8 C12 C14 87.3(4) . .
C3 C8 C12 C14 -90.6(3) . .
C7 C8 C12 C13 -33.6(4) . .
C3 C8 C12 C13 148.5(3) . .
N2 C15 C16 C17 179.3(2) . .
C20 C15 C16 C17 -0.3(4) . .
N2 C15 C16 C21 -3.4(4) . .
C20 C15 C16 C21 177.0(2) . .
C15 C16 C17 C18 0.3(4) . .
C21 C16 C17 C18 -177.0(3) . .
C16 C17 C18 C19 0.0(4) . .
C17 C18 C19 C20 -0.2(4) . .
C18 C19 C20 C15 0.2(4) . .
C18 C19 C20 C24 178.0(3) . .
N2 C15 C20 C19 -179.5(2) . .
C16 C15 C20 C19 0.1(4) . .
N2 C15 C20 C24 2.7(4) . .
C16 C15 C20 C24 -177.7(2) . .
C17 C16 C21 C22 97.5(3) . .
C15 C16 C21 C22 -79.8(3) . .
C17 C16 C21 C23 -27.2(4) . .
C15 C16 C21 C23 155.5(2) . .
C19 C20 C24 C26 -94.7(3) . .
C15 C20 C24 C26 83.1(3) . .
C19 C20 C24 C25 29.6(4) . .
C15 C20 C24 C25 -152.6(3) . .
N1 C1 N1 C2 -0.01(12) 2_755 .
Co1 C1 N1 C2 179.99(12) . .
N1 C1 N1 C3 -177.3(2) 2_755 .
Co1 C1 N1 C3 2.7(2) . .
C2 C2 N1 C1 0.0(3) 2_755 .
C2 C2 N1 C3 177.5(2) 2_755 .
C4 C3 N1 C1 89.2(3) . .
C8 C3 N1 C1 -96.4(2) . .
C4 C3 N1 C2 -87.9(3) . .
C8 C3 N1 C2 86.6(3) . .
C20 C15 N2 Co1 14.9(4) . .
C16 C15 N2 Co1 -164.7(2) . .
C15 N2 Co1 N2 -93.7(3) . 2_755
C15 N2 Co1 C1 86.3(3) . .
