#------------------------------------------------------------------------------
#$Date: 2015-09-05 20:44:13 +0300 (Sat, 05 Sep 2015) $
#$Revision: 154498 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/62/4086218.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4086218
loop_
_publ_author_name
'Karwasara, Surendar'
'Siwatch, Rahul Kumar'
'Jha, Chandan Kumar'
'Nagendran, Selvarajan'
_publ_section_title
;
 Aminotroponiminatosilathio- and Siloxygermylenes: Reactivity Comparison
;
_journal_issue                   13
_journal_name_full               Organometallics
_journal_page_first              3246
_journal_paper_doi               10.1021/acs.organomet.5b00286
_journal_volume                  34
_journal_year                    2015
_chemical_formula_moiety         'C66 H76 Ge2 N4 O4 Si2'
_chemical_formula_sum            'C66 H76 Ge2 N4 O4 Si2'
_chemical_formula_weight         1190.71
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                112.293(6)
_cell_angle_beta                 102.656(7)
_cell_angle_gamma                101.348(7)
_cell_formula_units_Z            1
_cell_length_a                   11.603(3)
_cell_length_b                   12.094(4)
_cell_length_c                   12.526(4)
_cell_measurement_reflns_used    3234
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      28.20
_cell_measurement_theta_min      2.18
_cell_volume                     1508.7(8)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0635
_diffrn_reflns_av_sigmaI/netI    0.1131
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            9942
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.18
_exptl_absorpt_coefficient_mu    1.087
_exptl_absorpt_correction_T_max  0.667
_exptl_absorpt_correction_T_min  0.643
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2000)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.311
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             624.0
_exptl_crystal_size_max          0.416
_exptl_crystal_size_mid          0.398
_exptl_crystal_size_min          0.373
_refine_diff_density_max         0.976
_refine_diff_density_min         -0.681
_refine_diff_density_rms         0.104
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.986
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     356
_refine_ls_number_reflns         5306
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.986
_refine_ls_R_factor_all          0.0966
_refine_ls_R_factor_gt           0.0584
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0648P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1237
_refine_ls_wR_factor_ref         0.1355
_reflns_number_gt                3693
_reflns_number_total             5306
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om5b00286_si_001.cif
_cod_data_source_block           20sepb_0m
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/current/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 
;
_cod_database_code               4086218
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ge1 Ge 0.51908(4) 0.60424(4) 0.59978(4) 0.01762(17) Uani 1 1 d .
Si1 Si 0.32094(11) 0.58852(12) 0.75420(10) 0.0191(3) Uani 1 1 d .
O1 O 0.4579(2) 0.5511(3) 0.4388(2) 0.0188(7) Uani 1 1 d .
O2 O 0.4025(3) 0.5792(3) 0.6657(2) 0.0246(8) Uani 1 1 d .
N1 N 0.5135(3) 0.7768(3) 0.6377(3) 0.0191(9) Uani 1 1 d .
N2 N 0.6876(3) 0.6969(3) 0.7022(3) 0.0204(9) Uani 1 1 d .
C7 C 0.7193(4) 0.8218(4) 0.7507(3) 0.0205(11) Uani 1 1 d .
C16 C 0.4246(4) 0.6795(4) 0.9164(4) 0.0220(11) Uani 1 1 d .
C22 C 0.2345(4) 0.4252(4) 0.7187(3) 0.0217(11) Uani 1 1 d .
C1 C 0.6143(4) 0.8689(4) 0.7186(3) 0.0185(10) Uani 1 1 d .
C23 C 0.2510(4) 0.3224(4) 0.6283(4) 0.0283(12) Uani 1 1 d .
H23 H 0.3084 0.3366 0.5898 0.034 Uiso 1 1 calc R
C28 C 0.2089(4) 0.6741(4) 0.7224(4) 0.0203(10) Uani 1 1 d .
C2 C 0.6161(4) 0.9946(4) 0.7735(4) 0.0232(11) Uani 1 1 d .
H2 H 0.5383 1.0055 0.7555 0.028 Uiso 1 1 calc R
C10 C 0.4029(4) 0.8627(4) 0.5045(4) 0.0223(11) Uani 1 1 d .
H10 H 0.4660 0.9455 0.5514 0.027 Uiso 1 1 calc R
C29 C 0.1321(4) 0.6326(4) 0.6036(4) 0.0242(11) Uani 1 1 d .
H29 H 0.1312 0.5581 0.5429 0.029 Uiso 1 1 calc R
C4 C 0.8369(4) 1.1220(5) 0.8922(4) 0.0302(12) Uani 1 1 d .
H4 H 0.8888 1.2046 0.9364 0.036 Uiso 1 1 calc R
C6 C 0.8407(4) 0.8997(4) 0.8180(4) 0.0268(12) Uani 1 1 d .
H6 H 0.8979 0.8566 0.8249 0.032 Uiso 1 1 calc R
C31 C 0.0572(4) 0.6993(5) 0.5735(4) 0.0284(12) Uani 1 1 d .
H31 H 0.0070 0.6692 0.4932 0.034 Uiso 1 1 calc R
C9 C 0.7791(4) 0.6316(4) 0.7207(4) 0.0244(11) Uani 1 1 d .
H9A H 0.8525 0.6683 0.7059 0.029 Uiso 1 1 calc R
H9B H 0.7445 0.5443 0.6607 0.029 Uiso 1 1 calc R
C8 C 0.3981(4) 0.7989(4) 0.5882(4) 0.0209(10) Uani 1 1 d .
H8A H 0.3751 0.8502 0.6559 0.025 Uiso 1 1 calc R
H8B H 0.3329 0.7187 0.5434 0.025 Uiso 1 1 calc R
C32 C 0.1301(4) 0.8519(5) 0.7806(4) 0.0298(12) Uani 1 1 d .
H32 H 0.1299 0.9262 0.8410 0.036 Uiso 1 1 calc R
C3 C 0.7111(4) 1.1045(4) 0.8486(4) 0.0264(11) Uani 1 1 d .
H3 H 0.6876 1.1770 0.8737 0.032 Uiso 1 1 calc R
C30 C 0.2042(4) 0.7844(4) 0.8105(4) 0.0244(11) Uani 1 1 d .
H30 H 0.2520 0.8133 0.8913 0.029 Uiso 1 1 calc R
C20 C 0.5264(5) 0.6991(5) 1.1166(4) 0.0375(14) Uani 1 1 d .
H20 H 0.5354 0.6650 1.1720 0.045 Uiso 1 1 calc R
C11 C 0.8187(5) 0.6366(5) 0.8486(4) 0.0382(14) Uani 1 1 d .
H11 H 0.8626 0.7243 0.9080 0.046 Uiso 1 1 calc R
C18 C 0.4390(4) 0.6283(5) 0.9989(4) 0.0287(12) Uani 1 1 d .
H18 H 0.3906 0.5470 0.9763 0.034 Uiso 1 1 calc R
C17 C 0.4990(4) 0.8016(4) 0.9542(4) 0.0291(12) Uani 1 1 d .
H17 H 0.4901 0.8378 0.9005 0.035 Uiso 1 1 calc R
C33 C 0.0562(4) 0.8092(5) 0.6610(4) 0.0286(12) Uani 1 1 d .
H33 H 0.0066 0.8546 0.6405 0.034 Uiso 1 1 calc R
C24 C 0.1476(4) 0.3975(5) 0.7736(4) 0.0314(12) Uani 1 1 d .
H24 H 0.1347 0.4631 0.8340 0.038 Uiso 1 1 calc R
C13 C 0.4384(5) 0.7892(5) 0.3957(4) 0.0358(13) Uani 1 1 d .
H13A H 0.3736 0.7110 0.3440 0.054 Uiso 1 1 calc R
H13B H 0.5143 0.7728 0.4233 0.054 Uiso 1 1 calc R
H13C H 0.4499 0.8371 0.3507 0.054 Uiso 1 1 calc R
C5 C 0.8925(4) 1.0293(5) 0.8765(4) 0.0324(13) Uani 1 1 d .
H5 H 0.9786 1.0581 0.9107 0.039 Uiso 1 1 calc R
C27 C 0.0978(5) 0.1777(5) 0.6526(5) 0.0435(15) Uani 1 1 d .
H27 H 0.0521 0.0955 0.6305 0.052 Uiso 1 1 calc R
C25 C 0.1827(5) 0.2008(5) 0.5963(4) 0.0399(14) Uani 1 1 d .
H25 H 0.1943 0.1339 0.5362 0.048 Uiso 1 1 calc R
C21 C 0.5981(5) 0.8180(5) 1.1490(4) 0.0418(15) Uani 1 1 d .
H21 H 0.6563 0.8643 1.2266 0.050 Uiso 1 1 calc R
C14 C 0.9100(5) 0.5612(6) 0.8499(5) 0.0504(16) Uani 1 1 d .
H14A H 0.9444 0.5712 0.9313 0.076 Uiso 1 1 calc R
H14B H 0.9756 0.5911 0.8230 0.076 Uiso 1 1 calc R
H14C H 0.8672 0.4739 0.7963 0.076 Uiso 1 1 calc R
C19 C 0.5855(4) 0.8704(5) 1.0692(4) 0.0369(14) Uani 1 1 d .
H19 H 0.6348 0.9515 1.0923 0.044 Uiso 1 1 calc R
C12 C 0.2785(5) 0.8822(5) 0.4646(4) 0.0417(14) Uani 1 1 d .
H12A H 0.2145 0.8024 0.4223 0.063 Uiso 1 1 calc R
H12B H 0.2808 0.9218 0.4113 0.063 Uiso 1 1 calc R
H12C H 0.2614 0.9348 0.5350 0.063 Uiso 1 1 calc R
C15 C 0.7115(5) 0.5892(5) 0.8838(5) 0.0466(15) Uani 1 1 d .
H15A H 0.6586 0.6415 0.8870 0.070 Uiso 1 1 calc R
H15B H 0.7415 0.5911 0.9624 0.070 Uiso 1 1 calc R
H15C H 0.6652 0.5044 0.8245 0.070 Uiso 1 1 calc R
C26 C 0.0806(5) 0.2757(5) 0.7410(5) 0.0422(14) Uani 1 1 d .
H26 H 0.0234 0.2601 0.7792 0.051 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 Ge1 O1 112.80(13) . .
O2 Ge1 O1 95.87(13) . 2_666
O1 Ge1 O1 85.63(14) . 2_666
O2 Ge1 N2 119.92(13) . .
O1 Ge1 N2 126.91(13) . .
O1 Ge1 N2 94.67(14) 2_666 .
O2 Ge1 N1 90.79(14) . .
O1 Ge1 N1 93.44(13) . .
O1 Ge1 N1 173.10(13) 2_666 .
N2 Ge1 N1 80.41(15) . .
O2 Ge1 Ge1 109.32(9) . 2_666
O1 Ge1 Ge1 43.64(10) . 2_666
O1 Ge1 Ge1 41.99(8) 2_666 2_666
N2 Ge1 Ge1 117.34(10) . 2_666
N1 Ge1 Ge1 136.67(10) . 2_666
O2 Si1 C22 107.42(18) . .
O2 Si1 C16 109.51(17) . .
C22 Si1 C16 112.4(2) . .
O2 Si1 C28 108.30(18) . .
C22 Si1 C28 110.10(19) . .
C16 Si1 C28 109.00(19) . .
Ge1 O1 Ge1 94.37(14) . 2_666
Si1 O2 Ge1 165.37(19) . .
C1 N1 C8 122.7(4) . .
C1 N1 Ge1 116.2(3) . .
C8 N1 Ge1 120.6(3) . .
C7 N2 C9 121.7(3) . .
C7 N2 Ge1 117.4(3) . .
C9 N2 Ge1 120.8(3) . .
N2 C7 C6 123.1(4) . .
N2 C7 C1 113.3(4) . .
C6 C7 C1 123.5(4) . .
C18 C16 C17 117.9(4) . .
C18 C16 Si1 123.4(3) . .
C17 C16 Si1 118.6(4) . .
C24 C22 C23 116.8(4) . .
C24 C22 Si1 123.2(3) . .
C23 C22 Si1 119.9(3) . .
N1 C1 C2 122.8(4) . .
N1 C1 C7 112.1(4) . .
C2 C1 C7 124.9(4) . .
C25 C23 C22 120.6(4) . .
C25 C23 H23 119.7 . .
C22 C23 H23 119.7 . .
C30 C28 C29 116.8(5) . .
C30 C28 Si1 123.4(3) . .
C29 C28 Si1 119.6(3) . .
C3 C2 C1 132.3(4) . .
C3 C2 H2 113.9 . .
C1 C2 H2 113.9 . .
C13 C10 C12 111.2(4) . .
C13 C10 C8 112.2(4) . .
C12 C10 C8 109.2(4) . .
C13 C10 H10 108.1 . .
C12 C10 H10 108.1 . .
C8 C10 H10 108.1 . .
C31 C29 C28 121.8(4) . .
C31 C29 H29 119.1 . .
C28 C29 H29 119.1 . .
C5 C4 C3 126.4(4) . .
C5 C4 H4 116.8 . .
C3 C4 H4 116.8 . .
C5 C6 C7 132.2(5) . .
C5 C6 H6 113.9 . .
C7 C6 H6 113.9 . .
C33 C31 C29 120.5(4) . .
C33 C31 H31 119.8 . .
C29 C31 H31 119.8 . .
N2 C9 C11 114.8(3) . .
N2 C9 H9A 108.6 . .
C11 C9 H9A 108.6 . .
N2 C9 H9B 108.6 . .
C11 C9 H9B 108.6 . .
H9A C9 H9B 107.6 . .
N1 C8 C10 115.7(3) . .
N1 C8 H8A 108.4 . .
C10 C8 H8A 108.4 . .
N1 C8 H8B 108.4 . .
C10 C8 H8B 108.4 . .
H8A C8 H8B 107.4 . .
C30 C32 C33 120.2(4) . .
C30 C32 H32 119.9 . .
C33 C32 H32 119.9 . .
C2 C3 C4 128.8(5) . .
C2 C3 H3 115.6 . .
C4 C3 H3 115.6 . .
C32 C30 C28 121.6(4) . .
C32 C30 H30 119.2 . .
C28 C30 H30 119.2 . .
C21 C20 C18 119.7(5) . .
C21 C20 H20 120.2 . .
C18 C20 H20 120.2 . .
C15 C11 C14 111.4(5) . .
C15 C11 C9 113.0(4) . .
C14 C11 C9 107.5(4) . .
C15 C11 H11 108.3 . .
C14 C11 H11 108.3 . .
C9 C11 H11 108.3 . .
C16 C18 C20 120.3(5) . .
C16 C18 H18 119.9 . .
C20 C18 H18 119.9 . .
C19 C17 C16 121.8(5) . .
C19 C17 H17 119.1 . .
C16 C17 H17 119.1 . .
C31 C33 C32 119.1(5) . .
C31 C33 H33 120.4 . .
C32 C33 H33 120.4 . .
C26 C24 C22 121.8(5) . .
C26 C24 H24 119.1 . .
C22 C24 H24 119.1 . .
C10 C13 H13A 109.5 . .
C10 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C10 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
C4 C5 C6 130.2(4) . .
C4 C5 H5 114.9 . .
C6 C5 H5 114.9 . .
C26 C27 C25 119.9(5) . .
C26 C27 H27 120.1 . .
C25 C27 H27 120.1 . .
C27 C25 C23 120.6(5) . .
C27 C25 H25 119.7 . .
C23 C25 H25 119.7 . .
C20 C21 C19 121.1(5) . .
C20 C21 H21 119.5 . .
C19 C21 H21 119.5 . .
C11 C14 H14A 109.5 . .
C11 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C11 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C21 C19 C17 119.3(5) . .
C21 C19 H19 120.3 . .
C17 C19 H19 120.3 . .
C10 C12 H12A 109.5 . .
C10 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C10 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C11 C15 H15A 109.5 . .
C11 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C11 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
C27 C26 C24 120.2(5) . .
C27 C26 H26 119.9 . .
C24 C26 H26 119.9 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ge1 O2 1.767(3) .
Ge1 O1 1.787(3) .
Ge1 O1 1.844(3) 2_666
Ge1 N2 1.917(3) .
Ge1 N1 1.975(4) .
Ge1 Ge1 2.6639(10) 2_666
Si1 O2 1.595(3) .
Si1 C22 1.861(5) .
Si1 C16 1.870(4) .
Si1 C28 1.881(5) .
O1 Ge1 1.844(3) 2_666
N1 C1 1.321(5) .
N1 C8 1.467(5) .
N2 C7 1.331(6) .
N2 C9 1.471(6) .
C7 C6 1.392(6) .
C7 C1 1.485(6) .
C16 C18 1.390(7) .
C16 C17 1.392(6) .
C22 C24 1.396(6) .
C22 C23 1.409(6) .
C1 C2 1.404(6) .
C23 C25 1.381(7) .
C23 H23 0.9300 .
C28 C30 1.392(6) .
C28 C29 1.392(6) .
C2 C3 1.374(6) .
C2 H2 0.9300 .
C10 C13 1.514(5) .
C10 C12 1.515(6) .
C10 C8 1.523(6) .
C10 H10 0.9800 .
C29 C31 1.382(7) .
C29 H29 0.9300 .
C4 C5 1.373(7) .
C4 C3 1.384(6) .
C4 H4 0.9300 .
C6 C5 1.387(6) .
C6 H6 0.9300 .
C31 C33 1.369(6) .
C31 H31 0.9300 .
C9 C11 1.541(6) .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C8 H8A 0.9700 .
C8 H8B 0.9700 .
C32 C30 1.383(7) .
C32 C33 1.387(6) .
C32 H32 0.9300 .
C3 H3 0.9300 .
C30 H30 0.9300 .
C20 C21 1.365(8) .
C20 C18 1.407(6) .
C20 H20 0.9300 .
C11 C15 1.491(6) .
C11 C14 1.529(7) .
C11 H11 0.9800 .
C18 H18 0.9300 .
C17 C19 1.380(6) .
C17 H17 0.9300 .
C33 H33 0.9300 .
C24 C26 1.376(7) .
C24 H24 0.9300 .
C13 H13A 0.9600 .
C13 H13B 0.9600 .
C13 H13C 0.9600 .
C5 H5 0.9300 .
C27 C26 1.366(7) .
C27 C25 1.376(7) .
C27 H27 0.9300 .
C25 H25 0.9300 .
C21 C19 1.369(8) .
C21 H21 0.9300 .
C14 H14A 0.9600 .
C14 H14B 0.9600 .
C14 H14C 0.9600 .
C19 H19 0.9300 .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C15 H15A 0.9600 .
C15 H15B 0.9600 .
C15 H15C 0.9600 .
C26 H26 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O2 Ge1 O1 Ge1 -94.54(15) . 2_666
O1 Ge1 O1 Ge1 0.0 2_666 2_666
N2 Ge1 O1 Ge1 92.56(18) . 2_666
N1 Ge1 O1 Ge1 173.15(13) . 2_666
C22 Si1 O2 Ge1 -147.3(9) . .
C16 Si1 O2 Ge1 -25.0(10) . .
C28 Si1 O2 Ge1 93.8(9) . .
O1 Ge1 O2 Si1 -147.8(9) . .
O1 Ge1 O2 Si1 124.5(9) 2_666 .
N2 Ge1 O2 Si1 25.7(10) . .
N1 Ge1 O2 Si1 -53.7(9) . .
Ge1 Ge1 O2 Si1 165.4(9) 2_666 .
O2 Ge1 N1 C1 113.8(3) . .
O1 Ge1 N1 C1 -133.3(3) . .
O1 Ge1 N1 C1 -51.2(12) 2_666 .
N2 Ge1 N1 C1 -6.4(3) . .
Ge1 Ge1 N1 C1 -126.4(2) 2_666 .
O2 Ge1 N1 C8 -59.5(3) . .
O1 Ge1 N1 C8 53.4(3) . .
O1 Ge1 N1 C8 135.5(10) 2_666 .
N2 Ge1 N1 C8 -179.7(3) . .
Ge1 Ge1 N1 C8 60.3(3) 2_666 .
O2 Ge1 N2 C7 -83.0(3) . .
O1 Ge1 N2 C7 89.5(3) . .
O1 Ge1 N2 C7 177.5(3) 2_666 .
N1 Ge1 N2 C7 2.4(3) . .
Ge1 Ge1 N2 C7 140.4(3) 2_666 .
O2 Ge1 N2 C9 100.0(3) . .
O1 Ge1 N2 C9 -87.6(3) . .
O1 Ge1 N2 C9 0.5(3) 2_666 .
N1 Ge1 N2 C9 -174.7(3) . .
Ge1 Ge1 N2 C9 -36.7(3) 2_666 .
C9 N2 C7 C6 2.7(6) . .
Ge1 N2 C7 C6 -174.3(3) . .
C9 N2 C7 C1 178.5(3) . .
Ge1 N2 C7 C1 1.5(4) . .
O2 Si1 C16 C18 -116.7(4) . .
C22 Si1 C16 C18 2.7(4) . .
C28 Si1 C16 C18 125.0(4) . .
O2 Si1 C16 C17 57.9(4) . .
C22 Si1 C16 C17 177.3(3) . .
C28 Si1 C16 C17 -60.4(4) . .
O2 Si1 C22 C24 -175.9(4) . .
C16 Si1 C22 C24 63.6(4) . .
C28 Si1 C22 C24 -58.1(4) . .
O2 Si1 C22 C23 1.0(4) . .
C16 Si1 C22 C23 -119.5(4) . .
C28 Si1 C22 C23 118.7(4) . .
C8 N1 C1 C2 6.5(6) . .
Ge1 N1 C1 C2 -166.6(3) . .
C8 N1 C1 C7 -178.2(3) . .
Ge1 N1 C1 C7 8.7(4) . .
N2 C7 C1 N1 -6.7(5) . .
C6 C7 C1 N1 169.2(4) . .
N2 C7 C1 C2 168.5(4) . .
C6 C7 C1 C2 -15.7(6) . .
C24 C22 C23 C25 0.5(7) . .
Si1 C22 C23 C25 -176.6(4) . .
O2 Si1 C28 C30 -121.7(3) . .
C22 Si1 C28 C30 121.1(4) . .
C16 Si1 C28 C30 -2.6(4) . .
O2 Si1 C28 C29 53.2(4) . .
C22 Si1 C28 C29 -64.0(4) . .
C16 Si1 C28 C29 172.2(3) . .
N1 C1 C2 C3 -172.5(4) . .
C7 C1 C2 C3 12.9(7) . .
C30 C28 C29 C31 1.7(6) . .
Si1 C28 C29 C31 -173.5(3) . .
N2 C7 C6 C5 -179.1(5) . .
C1 C7 C6 C5 5.4(7) . .
C28 C29 C31 C33 -0.2(7) . .
C7 N2 C9 C11 74.5(5) . .
Ge1 N2 C9 C11 -108.6(4) . .
C1 N1 C8 C10 69.0(5) . .
Ge1 N1 C8 C10 -118.2(3) . .
C13 C10 C8 N1 58.1(5) . .
C12 C10 C8 N1 -178.3(4) . .
C1 C2 C3 C4 0.5(8) . .
C5 C4 C3 C2 -5.8(8) . .
C33 C32 C30 C28 1.3(7) . .
C29 C28 C30 C32 -2.3(6) . .
Si1 C28 C30 C32 172.7(3) . .
N2 C9 C11 C15 54.9(6) . .
N2 C9 C11 C14 178.3(4) . .
C17 C16 C18 C20 0.0(7) . .
Si1 C16 C18 C20 174.6(3) . .
C21 C20 C18 C16 -0.6(7) . .
C18 C16 C17 C19 0.7(7) . .
Si1 C16 C17 C19 -174.2(4) . .
C29 C31 C33 C32 -0.9(7) . .
C30 C32 C33 C31 0.3(7) . .
C23 C22 C24 C26 -0.3(7) . .
Si1 C22 C24 C26 176.6(4) . .
C3 C4 C5 C6 -1.3(9) . .
C7 C6 C5 C4 4.5(9) . .
C26 C27 C25 C23 0.0(8) . .
C22 C23 C25 C27 -0.3(8) . .
C18 C20 C21 C19 0.6(8) . .
C20 C21 C19 C17 0.0(8) . .
C16 C17 C19 C21 -0.7(7) . .
C25 C27 C26 C24 0.2(8) . .
C22 C24 C26 C27 0.0(8) . .
