#------------------------------------------------------------------------------
#$Date: 2016-02-13 14:50:18 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176428 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/63/4086347.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4086347
loop_
_publ_author_name
'O, Wylie W. N.'
'Kang, Xiaohui'
'Luo, Yi'
'Hou, Zhaomin'
_publ_section_title
;
 PNP-Ligated Heterometallic Rare-Earth/Ruthenium Hydride Complexes Bearing
 Phosphinophenyl and Phosphinomethyl Bridging Ligands
;
_journal_issue                   4
_journal_name_full               Organometallics
_journal_page_first              1030
_journal_page_last               1043
_journal_paper_doi               10.1021/om401216v
_journal_volume                  33
_journal_year                    2014
_chemical_formula_sum            'C52 H76 Dy N P3 Ru'
_chemical_formula_weight         1071.62
_chemical_name_common            PNP(iPr)Dy(H)2Ru(C5Me5)PPh2(CH2)
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                99.641(3)
_cell_angle_beta                 102.993(2)
_cell_angle_gamma                113.592(2)
_cell_formula_units_Z            2
_cell_length_a                   12.5336(8)
_cell_length_b                   13.2381(8)
_cell_length_c                   18.2036(12)
_cell_measurement_reflns_used    57163
_cell_measurement_temperature    163(2)
_cell_measurement_theta_max      25.06
_cell_measurement_theta_min      1.75
_cell_volume                     2582.5(3)
_computing_cell_refinement       'APEX2 (Bruker, 2013); SAINT (Bruker, 2012)'
_computing_data_collection       'GIS (Bruker)'
_computing_data_reduction
'SAINT (Bruker, 2012); XPREP (Sheldrick, 2013)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      163(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type
'Bruker D8 QUEST diffractometer with a CMOS area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  'doubly curved silicon crystal'
_diffrn_radiation_source         'microfocus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0656
_diffrn_reflns_av_sigmaI/netI    0.0430
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            57163
_diffrn_reflns_theta_full        25.06
_diffrn_reflns_theta_max         25.06
_diffrn_reflns_theta_min         1.75
_exptl_absorpt_coefficient_mu    1.854
_exptl_absorpt_correction_T_max  0.9130
_exptl_absorpt_correction_T_min  0.5099
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'Sheldrick, G. M. (2012) SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.378
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1100
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.38
_exptl_crystal_size_min          0.05
_refine_diff_density_max         3.695
_refine_diff_density_min         -0.587
_refine_diff_density_rms         0.122
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.079
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     523
_refine_ls_number_reflns         9127
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.079
_refine_ls_R_factor_all          0.0514
_refine_ls_R_factor_gt           0.0378
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0383P)²+6.9495P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0862
_refine_ls_wR_factor_ref         0.0914
_reflns_number_gt                7660
_reflns_number_total             9127
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om401216v_si_002.cif
_cod_data_source_block           2b-Dy
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 4093 2015-10-18 17:28:56Z antanas 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4086347
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.8283(4) 0.4322(4) 0.3729(3) 0.0217(10) Uani 1 1 d . . .
H1A H 0.9056 0.4750 0.4180 0.026 Uiso 1 1 calc R . .
H1B H 0.7559 0.4147 0.3911 0.026 Uiso 1 1 calc R . .
C2 C 0.7439(4) 0.1855(4) 0.3454(3) 0.0208(10) Uani 1 1 d . . .
C3 C 0.6292(5) 0.1618(4) 0.3521(3) 0.0308(12) Uani 1 1 d . . .
H3 H 0.5925 0.2095 0.3388 0.037 Uiso 1 1 calc R . .
C4 C 0.5666(5) 0.0691(5) 0.3780(4) 0.0388(14) Uani 1 1 d . . .
H4 H 0.4880 0.0543 0.3825 0.047 Uiso 1 1 calc R . .
C5 C 0.6179(5) -0.0011(5) 0.3971(4) 0.0429(15) Uani 1 1 d . . .
H5 H 0.5752 -0.0644 0.4148 0.051 Uiso 1 1 calc R . .
C6 C 0.7311(5) 0.0208(5) 0.3905(4) 0.0390(14) Uani 1 1 d . . .
H6 H 0.7665 -0.0280 0.4034 0.047 Uiso 1 1 calc R . .
C7 C 0.7950(5) 0.1136(4) 0.3651(3) 0.0300(12) Uani 1 1 d . . .
H7 H 0.8739 0.1281 0.3612 0.036 Uiso 1 1 calc R . .
C8 C 0.9823(4) 0.3351(4) 0.3442(3) 0.0193(10) Uani 1 1 d . . .
C9 C 1.0462(4) 0.3639(4) 0.4242(3) 0.0266(11) Uani 1 1 d . . .
H9 H 1.0040 0.3646 0.4614 0.032 Uiso 1 1 calc R . .
C10 C 1.1693(5) 0.3914(5) 0.4501(3) 0.0328(12) Uani 1 1 d . . .
H10 H 1.2114 0.4111 0.5047 0.039 Uiso 1 1 calc R . .
C11 C 1.2306(5) 0.3902(5) 0.3965(3) 0.0345(13) Uani 1 1 d . . .
H11 H 1.3156 0.4096 0.4141 0.041 Uiso 1 1 calc R . .
C12 C 1.1694(5) 0.3610(5) 0.3173(3) 0.0340(13) Uani 1 1 d . . .
H12 H 1.2116 0.3588 0.2802 0.041 Uiso 1 1 calc R . .
C13 C 1.0463(4) 0.3348(4) 0.2920(3) 0.0248(11) Uani 1 1 d . . .
H13 H 1.0051 0.3162 0.2373 0.030 Uiso 1 1 calc R . .
C14 C 0.6790(5) 0.2189(5) 0.0486(3) 0.0342(6) Uani 1 1 d . . .
C15 C 0.5773(5) 0.1651(5) 0.0739(3) 0.0342(6) Uani 1 1 d . . .
C16 C 0.6028(5) 0.0980(5) 0.1225(3) 0.0342(6) Uani 1 1 d . . .
C17 C 0.7228(5) 0.1108(5) 0.1255(3) 0.0342(6) Uani 1 1 d . . .
C18 C 0.7695(5) 0.1853(5) 0.0812(3) 0.0342(6) Uani 1 1 d . . .
C19 C 0.6876(8) 0.2921(6) -0.0074(4) 0.065(2) Uani 1 1 d . . .
H19A H 0.6649 0.2441 -0.0611 0.098 Uiso 1 1 calc R . .
H19B H 0.7721 0.3535 0.0082 0.098 Uiso 1 1 calc R . .
H19C H 0.6315 0.3263 -0.0057 0.098 Uiso 1 1 calc R . .
C20 C 0.4559(6) 0.1664(7) 0.0489(4) 0.066(2) Uani 1 1 d . . .
H20A H 0.4675 0.2385 0.0365 0.100 Uiso 1 1 calc R . .
H20B H 0.4203 0.1601 0.0917 0.100 Uiso 1 1 calc R . .
H20C H 0.4002 0.1012 0.0022 0.100 Uiso 1 1 calc R . .
C21 C 0.5152(7) 0.0149(6) 0.1530(4) 0.066(2) Uani 1 1 d . . .
H21A H 0.4685 -0.0602 0.1129 0.099 Uiso 1 1 calc R . .
H21B H 0.4584 0.0436 0.1651 0.099 Uiso 1 1 calc R . .
H21C H 0.5614 0.0067 0.2008 0.099 Uiso 1 1 calc R . .
C22 C 0.7859(7) 0.0472(6) 0.1632(4) 0.059(2) Uani 1 1 d . . .
H22A H 0.7644 -0.0248 0.1245 0.089 Uiso 1 1 calc R . .
H22B H 0.7591 0.0299 0.2081 0.089 Uiso 1 1 calc R . .
H22C H 0.8752 0.0953 0.1813 0.089 Uiso 1 1 calc R . .
C23 C 0.8853(6) 0.2127(7) 0.0603(4) 0.063(2) Uani 1 1 d . . .
H23A H 0.9412 0.1957 0.0973 0.094 Uiso 1 1 calc R . .
H23B H 0.9253 0.2945 0.0631 0.094 Uiso 1 1 calc R . .
H23C H 0.8650 0.1658 0.0067 0.094 Uiso 1 1 calc R . .
C24 C 0.8316(4) 0.7464(4) 0.3679(3) 0.0177(10) Uani 1 1 d . . .
C25 C 0.8983(5) 0.8291(4) 0.4421(3) 0.0244(11) Uani 1 1 d . . .
H25 H 0.9849 0.8724 0.4558 0.029 Uiso 1 1 calc R . .
C26 C 0.8409(5) 0.8486(4) 0.4949(3) 0.0281(12) Uani 1 1 d . . .
H26 H 0.8889 0.9046 0.5445 0.034 Uiso 1 1 calc R . .
C27 C 0.7133(5) 0.7875(4) 0.4772(3) 0.0267(11) Uani 1 1 d . . .
C28 C 0.6467(5) 0.7067(4) 0.4057(3) 0.0242(11) Uani 1 1 d . . .
H28 H 0.5601 0.6642 0.3930 0.029 Uiso 1 1 calc R . .
C29 C 0.7031(4) 0.6844(4) 0.3501(3) 0.0200(10) Uani 1 1 d . . .
C30 C 0.6528(6) 0.8112(6) 0.5362(3) 0.0418(14) Uani 1 1 d . . .
H30A H 0.6742 0.8933 0.5509 0.063 Uiso 1 1 calc R . .
H30B H 0.6815 0.7902 0.5832 0.063 Uiso 1 1 calc R . .
H30C H 0.5633 0.7656 0.5129 0.063 Uiso 1 1 calc R . .
C31 C 0.9771(4) 0.8119(4) 0.2993(3) 0.0193(10) Uani 1 1 d . . .
C32 C 1.0705(4) 0.7976(4) 0.2739(3) 0.0212(10) Uani 1 1 d . . .
C33 C 1.1552(5) 0.8879(4) 0.2552(3) 0.0281(11) Uani 1 1 d . . .
H33 H 1.2170 0.8771 0.2380 0.034 Uiso 1 1 calc R . .
C34 C 1.1525(5) 0.9928(4) 0.2606(3) 0.0295(12) Uani 1 1 d . . .
C35 C 1.0604(5) 1.0048(4) 0.2851(3) 0.0281(12) Uani 1 1 d . . .
H35 H 1.0555 1.0751 0.2887 0.034 Uiso 1 1 calc R . .
C36 C 0.9754(5) 0.9186(4) 0.3046(3) 0.0256(11) Uani 1 1 d . . .
H36 H 0.9146 0.9313 0.3219 0.031 Uiso 1 1 calc R . .
C37 C 1.2448(6) 1.0873(5) 0.2387(4) 0.0430(15) Uani 1 1 d . . .
H37A H 1.2278 1.1538 0.2451 0.065 Uiso 1 1 calc R . .
H37B H 1.2385 1.0593 0.1838 0.065 Uiso 1 1 calc R . .
H37C H 1.3279 1.1101 0.2730 0.065 Uiso 1 1 calc R . .
C38 C 0.3871(5) 0.3987(5) 0.1765(3) 0.0412(14) Uani 1 1 d . . .
H38A H 0.4304 0.3623 0.1526 0.062 Uiso 1 1 calc R . .
H38B H 0.3636 0.4424 0.1433 0.062 Uiso 1 1 calc R . .
H38C H 0.3131 0.3392 0.1811 0.062 Uiso 1 1 calc R . .
C39 C 0.4929(5) 0.4114(5) 0.3147(4) 0.0360(13) Uani 1 1 d . . .
H39A H 0.4144 0.3620 0.3204 0.054 Uiso 1 1 calc R . .
H39B H 0.5499 0.4646 0.3662 0.054 Uiso 1 1 calc R . .
H39C H 0.5282 0.3636 0.2937 0.054 Uiso 1 1 calc R . .
C40 C 0.4715(4) 0.4799(4) 0.2583(3) 0.0281(12) Uani 1 1 d . . .
H40 H 0.4325 0.5262 0.2788 0.034 Uiso 1 1 calc R . .
C41 C 0.5721(8) 0.6074(7) 0.1032(4) 0.075(2) Uani 1 1 d . . .
H41A H 0.4893 0.5424 0.0830 0.112 Uiso 1 1 calc R . .
H41B H 0.6324 0.5791 0.0990 0.112 Uiso 1 1 calc R . .
H41C H 0.5770 0.6621 0.0723 0.112 Uiso 1 1 calc R . .
C42 C 0.5172(6) 0.7190(6) 0.2057(4) 0.0565(18) Uani 1 1 d . . .
H42A H 0.5176 0.7725 0.1744 0.085 Uiso 1 1 calc R . .
H42B H 0.5477 0.7606 0.2618 0.085 Uiso 1 1 calc R . .
H42C H 0.4331 0.6578 0.1922 0.085 Uiso 1 1 calc R . .
C43 C 0.5993(6) 0.6667(5) 0.1885(3) 0.0421(15) Uani 1 1 d . . .
H43 H 0.6822 0.7342 0.2033 0.051 Uiso 1 1 calc R . .
C44 C 1.0257(6) 0.6198(6) 0.1053(3) 0.0466(16) Uani 1 1 d . . .
H44A H 1.0527 0.6061 0.0597 0.070 Uiso 1 1 calc R . .
H44B H 1.0148 0.6897 0.1099 0.070 Uiso 1 1 calc R . .
H44C H 0.9475 0.5541 0.0984 0.070 Uiso 1 1 calc R . .
C45 C 1.1462(6) 0.5302(5) 0.1727(4) 0.0450(15) Uani 1 1 d . . .
H45A H 1.0706 0.4623 0.1671 0.068 Uiso 1 1 calc R . .
H45B H 1.2113 0.5430 0.2200 0.068 Uiso 1 1 calc R . .
H45C H 1.1720 0.5179 0.1264 0.068 Uiso 1 1 calc R . .
C46 C 1.1227(5) 0.6350(5) 0.1800(3) 0.0320(12) Uani 1 1 d . . .
H46 H 1.2011 0.7044 0.1879 0.038 Uiso 1 1 calc R . .
C47 C 1.3185(5) 0.7674(6) 0.3628(4) 0.0559(19) Uani 1 1 d . . .
H47A H 1.3198 0.8429 0.3685 0.084 Uiso 1 1 calc R . .
H47B H 1.3406 0.7470 0.3162 0.084 Uiso 1 1 calc R . .
H47C H 1.3777 0.7704 0.4097 0.084 Uiso 1 1 calc R . .
C48 C 1.1541(5) 0.7025(6) 0.4258(3) 0.0467(16) Uani 1 1 d . . .
H48A H 1.2132 0.7037 0.4720 0.070 Uiso 1 1 calc R . .
H48B H 1.0717 0.6424 0.4183 0.070 Uiso 1 1 calc R . .
H48C H 1.1538 0.7774 0.4340 0.070 Uiso 1 1 calc R . .
C49 C 1.1905(5) 0.6777(5) 0.3536(3) 0.0332(13) Uani 1 1 d . . .
H49 H 1.1931 0.6024 0.3485 0.040 Uiso 1 1 calc R . .
N1 N 0.8878(3) 0.7194(3) 0.3145(2) 0.0209(9) Uani 1 1 d . . .
P1 P 0.82107(10) 0.30874(10) 0.30949(7) 0.0165(2) Uani 1 1 d . . .
P2 P 0.62225(11) 0.57826(10) 0.25349(7) 0.0203(3) Uani 1 1 d . . .
P3 P 1.06826(11) 0.65821(11) 0.26474(7) 0.0213(3) Uani 1 1 d . . .
Ru1 Ru 0.73815(3) 0.28390(3) 0.17788(2) 0.01731(10) Uani 1 1 d . . .
Dy1 Dy 0.82378(2) 0.520991(18) 0.269486(13) 0.01814(8) Uani 1 1 d . . .
H2RU H 0.846(4) 0.400(4) 0.183(3) 0.031(14) Uiso 1 1 d . . .
H1RU H 0.671(5) 0.355(5) 0.203(3) 0.038(15) Uiso 1 1 d . . .
C50 C 0.1608(8) 0.2191(10) 0.9521(7) 0.107(4) Uani 1 1 d . . .
H50A H 0.1653 0.2772 0.9954 0.161 Uiso 1 1 calc R . .
H50B H 0.1520 0.2435 0.9040 0.161 Uiso 1 1 calc R . .
H50C H 0.2363 0.2103 0.9654 0.161 Uiso 1 1 calc R . .
C51 C 0.0511(8) 0.1052(8) 0.9387(5) 0.078(3) Uani 1 1 d . . .
H51A H -0.0242 0.1156 0.9263 0.093 Uiso 1 1 calc R . .
H51B H 0.0439 0.0489 0.8922 0.093 Uiso 1 1 calc R . .
C52 C 0.0565(6) 0.0564(7) 1.0061(4) 0.066(2) Uani 1 1 d . . .
H52A H 0.0670 0.1140 1.0531 0.079 Uiso 1 1 calc R . .
H52B H 0.1301 0.0432 1.0172 0.079 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 C1 Dy1 91.05(19) . .
C3 C2 C7 118.2(4) . .
C3 C2 P1 118.8(4) . .
C7 C2 P1 123.1(4) . .
C2 C3 C4 121.0(5) . .
C5 C4 C3 120.2(5) . .
C6 C5 C4 119.5(5) . .
C5 C6 C7 120.8(5) . .
C6 C7 C2 120.3(5) . .
C13 C8 C9 117.7(4) . .
C13 C8 P1 120.4(3) . .
C9 C8 P1 121.7(4) . .
C10 C9 C8 121.3(5) . .
C11 C10 C9 119.6(5) . .
C10 C11 C12 120.2(5) . .
C11 C12 C13 119.7(5) . .
C8 C13 C12 121.4(5) . .
C15 C14 C18 107.4(5) . .
C15 C14 C19 126.6(6) . .
C18 C14 C19 125.8(6) . .
C15 C14 Ru1 71.4(3) . .
C18 C14 Ru1 71.7(3) . .
C19 C14 Ru1 125.4(4) . .
C14 C15 C16 109.3(5) . .
C14 C15 C20 126.9(6) . .
C16 C15 C20 123.6(6) . .
C14 C15 Ru1 71.2(3) . .
C16 C15 Ru1 72.5(3) . .
C20 C15 Ru1 127.1(4) . .
C15 C16 C17 106.2(5) . .
C15 C16 C21 127.3(6) . .
C17 C16 C21 125.7(6) . .
C15 C16 Ru1 70.1(3) . .
C17 C16 Ru1 71.5(3) . .
C21 C16 Ru1 130.9(4) . .
C18 C17 C16 108.9(5) . .
C18 C17 C22 124.5(6) . .
C16 C17 C22 126.4(6) . .
C18 C17 Ru1 70.6(3) . .
C16 C17 Ru1 71.2(3) . .
C22 C17 Ru1 128.5(4) . .
C17 C18 C14 108.2(5) . .
C17 C18 C23 127.4(5) . .
C14 C18 C23 123.9(6) . .
C17 C18 Ru1 72.6(3) . .
C14 C18 Ru1 70.7(3) . .
C23 C18 Ru1 129.1(4) . .
N1 C24 C25 123.1(4) . .
N1 C24 C29 119.6(4) . .
C25 C24 C29 117.2(4) . .
C26 C25 C24 121.5(5) . .
C25 C26 C27 121.4(5) . .
C28 C27 C26 118.1(5) . .
C28 C27 C30 121.6(5) . .
C26 C27 C30 120.3(5) . .
C27 C28 C29 121.8(5) . .
C24 C29 C28 119.9(4) . .
C24 C29 P2 115.0(3) . .
C28 C29 P2 125.0(4) . .
N1 C31 C36 122.9(4) . .
N1 C31 C32 119.8(4) . .
C36 C31 C32 117.3(4) . .
C33 C32 C31 119.5(4) . .
C33 C32 P3 124.0(4) . .
C31 C32 P3 116.5(3) . .
C34 C33 C32 122.7(5) . .
C35 C34 C33 116.8(4) . .
C35 C34 C37 122.3(5) . .
C33 C34 C37 120.9(5) . .
C36 C35 C34 122.5(5) . .
C35 C36 C31 121.2(5) . .
C39 C40 C38 110.4(5) . .
C39 C40 P2 108.3(3) . .
C38 C40 P2 110.4(4) . .
C42 C43 C41 116.7(6) . .
C42 C43 P2 113.6(4) . .
C41 C43 P2 111.8(5) . .
C45 C46 C44 110.6(5) . .
C45 C46 P3 110.9(4) . .
C44 C46 P3 108.6(4) . .
C48 C49 C47 111.6(5) . .
C48 C49 P3 109.2(4) . .
C47 C49 P3 114.5(4) . .
C24 N1 C31 117.3(4) . .
C24 N1 Dy1 112.8(3) . .
C31 N1 Dy1 129.8(3) . .
C1 P1 C8 101.0(2) . .
C1 P1 C2 106.4(2) . .
C8 P1 C2 101.6(2) . .
C1 P1 Ru1 113.92(15) . .
C8 P1 Ru1 116.82(15) . .
C2 P1 Ru1 115.40(15) . .
C1 P1 Dy1 52.38(15) . .
C8 P1 Dy1 106.97(14) . .
C2 P1 Dy1 147.01(16) . .
Ru1 P1 Dy1 65.22(3) . .
C29 P2 C40 105.7(2) . .
C29 P2 C43 102.4(2) . .
C40 P2 C43 109.1(3) . .
C29 P2 Dy1 90.19(15) . .
C40 P2 Dy1 122.56(16) . .
C43 P2 Dy1 120.9(2) . .
C32 P3 C46 104.4(2) . .
C32 P3 C49 105.8(2) . .
C46 P3 C49 106.5(2) . .
C32 P3 Dy1 100.99(15) . .
C46 P3 Dy1 125.13(18) . .
C49 P3 Dy1 112.01(17) . .
C14 Ru1 C15 37.3(2) . .
C14 Ru1 C18 37.6(2) . .
C15 Ru1 C18 62.2(2) . .
C14 Ru1 C16 62.8(2) . .
C15 Ru1 C16 37.45(19) . .
C18 Ru1 C16 62.5(2) . .
C14 Ru1 C17 62.12(19) . .
C15 Ru1 C17 61.85(19) . .
C18 Ru1 C17 36.8(2) . .
C16 Ru1 C17 37.3(2) . .
C14 Ru1 P1 162.03(14) . .
C15 Ru1 P1 141.49(15) . .
C18 Ru1 P1 125.11(14) . .
C16 Ru1 P1 107.54(14) . .
C17 Ru1 P1 100.75(14) . .
C14 Ru1 Dy1 126.17(14) . .
C15 Ru1 Dy1 133.07(14) . .
C18 Ru1 Dy1 140.27(15) . .
C16 Ru1 Dy1 155.36(14) . .
C17 Ru1 Dy1 164.76(14) . .
P1 Ru1 Dy1 69.24(3) . .
N1 Dy1 C1 113.17(15) . .
N1 Dy1 P2 66.68(9) . .
C1 Dy1 P2 107.04(11) . .
N1 Dy1 P3 67.60(9) . .
C1 Dy1 P3 112.18(12) . .
P2 Dy1 P3 128.26(3) . .
N1 Dy1 Ru1 166.70(10) . .
C1 Dy1 Ru1 80.13(11) . .
P2 Dy1 Ru1 110.79(3) . .
P3 Dy1 Ru1 108.07(3) . .
N1 Dy1 P1 147.18(10) . .
C1 Dy1 P1 36.57(11) . .
P2 Dy1 P1 124.44(3) . .
P3 Dy1 P1 107.10(3) . .
Ru1 Dy1 P1 45.54(2) . .
C52 C51 C50 114.6(7) . .
C51 C52 C52 114.7(8) . 2_557
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 P1 1.792(5) .
C1 Dy1 2.383(4) .
C2 C3 1.383(7) .
C2 C7 1.394(7) .
C2 P1 1.844(5) .
C3 C4 1.391(7) .
C4 C5 1.373(8) .
C5 C6 1.368(8) .
C6 C7 1.391(7) .
C8 C13 1.376(7) .
C8 C9 1.397(7) .
C8 P1 1.842(4) .
C9 C10 1.379(7) .
C10 C11 1.373(8) .
C11 C12 1.376(8) .
C12 C13 1.383(7) .
C14 C15 1.411(8) .
C14 C18 1.424(8) .
C14 C19 1.513(8) .
C14 Ru1 2.204(5) .
C15 C16 1.427(8) .
C15 C20 1.495(8) .
C15 Ru1 2.206(5) .
C16 C17 1.431(8) .
C16 C21 1.495(8) .
C16 Ru1 2.238(5) .
C17 C18 1.408(8) .
C17 C22 1.513(8) .
C17 Ru1 2.242(5) .
C18 C23 1.502(8) .
C18 Ru1 2.216(5) .
C24 N1 1.402(6) .
C24 C25 1.409(7) .
C24 C29 1.411(6) .
C25 C26 1.372(7) .
C26 C27 1.401(7) .
C27 C28 1.366(7) .
C27 C30 1.507(7) .
C28 C29 1.415(6) .
C29 P2 1.823(5) .
C31 N1 1.409(6) .
C31 C36 1.408(6) .
C31 C32 1.418(7) .
C32 C33 1.398(7) .
C32 P3 1.813(5) .
C33 C34 1.391(7) .
C34 C35 1.383(7) .
C34 C37 1.508(7) .
C35 C36 1.376(7) .
C38 C40 1.528(7) .
C39 C40 1.528(7) .
C40 P2 1.848(5) .
C41 C43 1.511(9) .
C42 C43 1.509(9) .
C43 P2 1.854(5) .
C44 C46 1.528(8) .
C45 C46 1.521(7) .
C46 P3 1.850(5) .
C47 C49 1.516(8) .
C48 C49 1.514(8) .
C49 P3 1.860(5) .
N1 Dy1 2.347(4) .
P1 Ru1 2.2959(12) .
P1 Dy1 3.0078(11) .
P2 Dy1 2.8837(12) .
P3 Dy1 2.9004(12) .
Ru1 Dy1 2.9206(5) .
C50 C51 1.514(13) .
C51 C52 1.479(10) .
C52 C52 1.530(16) 2_557
