#------------------------------------------------------------------------------
#$Date: 2017-02-04 03:17:14 +0200 (Sat, 04 Feb 2017) $
#$Revision: 191288 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/08/69/4086987.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4086987
loop_
_publ_author_name
'Chen, Yi-Ting'
'Krytchankou, Ilya S.'
'Karttunen, Antti J.'
'Grachova, Elena V.'
'Tunik, Sergey P.'
'Chou, Pi-Tai'
'Koshevoy, Igor O.'
_publ_section_title
;
 Silver Alkynyl-Phosphine Clusters: An Electronic Effect of the Alkynes
 Defines Structural Diversity
;
_journal_issue                   2
_journal_name_full               Organometallics
_journal_page_first              480
_journal_paper_doi               10.1021/acs.organomet.6b00866
_journal_volume                  36
_journal_year                    2017
_chemical_formula_moiety         'C104 H74 Ag6 F18 O9 P6 S3'
_chemical_formula_sum            'C104 H74 Ag6 F18 O9 P6 S3'
_chemical_formula_weight         2738.85
_space_group_crystal_system      trigonal
_space_group_IT_number           147
_space_group_name_Hall           '-P 3'
_space_group_name_H-M_alt        'P -3'
_symmetry_space_group_name_Hall  '-P 3'
_symmetry_space_group_name_H-M   'P -3'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            2
_cell_length_a                   18.4199(10)
_cell_length_b                   18.4199(10)
_cell_length_c                   21.9233(11)
_cell_measurement_reflns_used    9627
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      37.64
_cell_measurement_theta_min      2.21
_cell_volume                     6441.9(6)
_computing_cell_refinement       'SAINT (Bruker AXS, 2009)'
_computing_data_collection       'APEX2 (Bruker AXS, 2010)'
_computing_data_reduction        'SAINT (Bruker AXS, 2009)'
_computing_molecular_graphics    'Diamond v.4.03 (Brandenburg, 2014)'
_computing_publication_material  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-2014 (Sheldrick, 2014)'
_diffrn_ambient_temperature      120(2)
_diffrn_detector_area_resol_mean 16
_diffrn_measured_fraction_theta_full 0.890
_diffrn_measured_fraction_theta_max 0.908
_diffrn_measurement_device       '62mm x 62mm CCD camera on κ-goniostat'
_diffrn_measurement_device_type  'Bruker KAPPA APEX II DUO CCD'
_diffrn_measurement_method       'φ scans and ω scans with κ offset'
_diffrn_radiation_monochromator  'curved graphite crystal'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0409
_diffrn_reflns_av_unetI/netI     0.0279
_diffrn_reflns_Laue_measured_fraction_full 0.890
_diffrn_reflns_Laue_measured_fraction_max 0.908
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            88413
_diffrn_reflns_point_group_measured_fraction_full 0.890
_diffrn_reflns_point_group_measured_fraction_max 0.908
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.992
_diffrn_reflns_theta_min         1.858
_exptl_absorpt_coefficient_mu    1.089
_exptl_absorpt_correction_T_max  0.860
_exptl_absorpt_correction_T_min  0.793
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2008)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.412
_exptl_crystal_description       block
_exptl_crystal_F_000             2704
_exptl_crystal_size_max          0.223
_exptl_crystal_size_mid          0.203
_exptl_crystal_size_min          0.143
_refine_diff_density_max         1.324
_refine_diff_density_min         -1.396
_refine_diff_density_rms         0.103
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     426
_refine_ls_number_reflns         8550
_refine_ls_number_restraints     126
_refine_ls_restrained_S_all      1.097
_refine_ls_R_factor_all          0.0536
_refine_ls_R_factor_gt           0.0483
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0389P)²+27.9563P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1113
_refine_ls_wR_factor_ref         0.1139
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7724
_reflns_number_total             8550
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            1_2.cif
_cod_data_source_block           2
_cod_original_cell_volume        6441.9(8)
_cod_database_code               4086987
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.793
_shelx_estimated_absorpt_t_max   0.860
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.6813(2) 0.4679(2) 0.27071(18) 0.0204(7) Uani 1 1 d . . . . .
C2 C 0.7113(2) 0.5431(3) 0.27766(19) 0.0224(8) Uani 1 1 d . . . . .
C3 C 0.7425(3) 0.6311(2) 0.2880(2) 0.0268(9) Uani 1 1 d . . . . .
C4 C 0.6872(3) 0.6579(3) 0.3050(3) 0.0464(14) Uani 1 1 d . . . . .
H4 H 0.6290 0.6186 0.3083 0.056 Uiso 1 1 calc R U . . .
C5 C 0.7170(3) 0.7422(3) 0.3171(3) 0.0518(17) Uani 1 1 d . . . . .
H5 H 0.6792 0.7607 0.3289 0.062 Uiso 1 1 calc R U . . .
C6 C 0.8013(3) 0.7988(3) 0.3120(3) 0.0444(13) Uani 1 1 d . . . . .
C7 C 0.8566(3) 0.7728(3) 0.2935(3) 0.0413(12) Uani 1 1 d . . . . .
H7 H 0.9144 0.8128 0.2888 0.050 Uiso 1 1 calc R U . . .
C8 C 0.8282(3) 0.6892(3) 0.2818(2) 0.0318(10) Uani 1 1 d . . . . .
H8 H 0.8662 0.6712 0.2698 0.038 Uiso 1 1 calc R U . . .
C9 C 0.8327(4) 0.8885(4) 0.3239(3) 0.0621(18) Uani 1 1 d D U . . .
C10 C 0.6667 0.3333 0.4619(3) 0.0175(12) Uani 1 3 d S T P A .
H10 H 0.6667 0.3333 0.5075 0.021 Uiso 1 3 calc R U P . .
C11 C 0.5928(4) 0.4443(4) 0.4648(3) 0.0187(14) Uani 0.81(3) 1 d . . P A 1
C12 C 0.6180(5) 0.5145(4) 0.4281(4) 0.0260(15) Uani 0.81(3) 1 d . . P A 1
H12 H 0.6271 0.5115 0.3857 0.031 Uiso 0.81(3) 1 calc R U P A 1
C13 C 0.6301(5) 0.5894(4) 0.4533(5) 0.034(2) Uani 0.81(3) 1 d . . P A 1
H13 H 0.6482 0.6377 0.4285 0.041 Uiso 0.81(3) 1 calc R U P A 1
C14 C 0.6155(4) 0.5923(6) 0.5146(6) 0.039(3) Uani 0.81(3) 1 d . . P A 1
H14 H 0.6243 0.6433 0.5319 0.047 Uiso 0.81(3) 1 calc R U P A 1
C15 C 0.5884(4) 0.5229(6) 0.5515(4) 0.035(2) Uani 0.81(3) 1 d . . P A 1
H15 H 0.5773 0.5258 0.5935 0.042 Uiso 0.81(3) 1 calc R U P A 1
C16 C 0.5775(4) 0.4484(5) 0.5268(4) 0.0322(18) Uani 0.81(3) 1 d . . P A 1
H16 H 0.5598 0.4005 0.5520 0.039 Uiso 0.81(3) 1 calc R U P A 1
C11A C 0.5968(18) 0.4359(14) 0.4763(11) 0.021(4) Uani 0.19(3) 1 d G U P A 2
C12A C 0.6095(17) 0.5072(16) 0.4453(10) 0.021(4) Uani 0.19(3) 1 d G U P A 2
H12A H 0.6151 0.5100 0.4022 0.025 Uiso 0.19(3) 1 calc R U P A 2
C13A C 0.6140(14) 0.5744(14) 0.4775(14) 0.021(4) Uani 0.19(3) 1 d G U P A 2
H13A H 0.6227 0.6231 0.4564 0.025 Uiso 0.19(3) 1 calc R U P A 2
C14A C 0.6058(12) 0.5702(14) 0.5406(14) 0.021(4) Uani 0.19(3) 1 d G U P A 2
H14A H 0.6089 0.6161 0.5626 0.025 Uiso 0.19(3) 1 calc R U P A 2
C15A C 0.5931(12) 0.4989(15) 0.5716(11) 0.021(4) Uani 0.19(3) 1 d G U P A 2
H15A H 0.5876 0.4961 0.6147 0.025 Uiso 0.19(3) 1 calc R U P A 2
C16A C 0.5886(16) 0.4318(12) 0.5394(11) 0.021(4) Uani 0.19(3) 1 d G U P A 2
H16A H 0.5799 0.3831 0.5605 0.025 Uiso 0.19(3) 1 calc R U P A 2
C17 C 0.4788(2) 0.2698(2) 0.4611(2) 0.0229(8) Uani 1 1 d . . . . .
C18 C 0.4106(3) 0.2426(3) 0.4215(2) 0.0271(9) Uani 1 1 d . . . . .
H18 H 0.4196 0.2598 0.3800 0.033 Uiso 1 1 calc R U . . .
C19 C 0.3293(3) 0.1901(3) 0.4429(3) 0.0399(12) Uani 1 1 d . . . . .
H19 H 0.2830 0.1722 0.4161 0.048 Uiso 1 1 calc R U . . .
C20 C 0.3163(3) 0.1642(3) 0.5029(3) 0.0456(14) Uani 1 1 d . . . . .
H20 H 0.2608 0.1287 0.5173 0.055 Uiso 1 1 calc R U . . .
C21 C 0.3836(3) 0.1897(3) 0.5421(3) 0.0404(12) Uani 1 1 d . . . . .
H21 H 0.3742 0.1710 0.5833 0.049 Uiso 1 1 calc R U . . .
C22 C 0.4647(3) 0.2426(3) 0.5217(2) 0.0322(10) Uani 1 1 d . . . . .
H22 H 0.5107 0.2602 0.5488 0.039 Uiso 1 1 calc R U . . .
C23 C 0.6667 0.3333 0.0509(3) 0.0339(18) Uani 1 3 d S T P . .
H23 H 0.6667 0.3333 0.0053 0.041 Uiso 1 3 calc R U P . .
C24 C 0.6055(4) 0.4515(5) 0.0315(3) 0.0663(8) Uani 1 1 d . U . . .
C25 C 0.6035(4) 0.5195(5) 0.0584(3) 0.0663(8) Uani 1 1 d . U . . .
H25 H 0.6001 0.5229 0.1015 0.080 Uiso 1 1 calc R U . . .
C26 C 0.6066(4) 0.5819(5) 0.0208(3) 0.0663(8) Uani 1 1 d . U . . .
H26 H 0.6039 0.6278 0.0381 0.080 Uiso 1 1 calc R U . . .
C27 C 0.6134(4) 0.5773(5) -0.0413(3) 0.0663(8) Uani 1 1 d . U . . .
H27 H 0.6168 0.6211 -0.0662 0.080 Uiso 1 1 calc R U . . .
C28 C 0.6154(4) 0.5131(5) -0.0674(3) 0.0663(8) Uani 1 1 d . U . . .
H28 H 0.6194 0.5114 -0.1106 0.080 Uiso 1 1 calc R U . . .
C29 C 0.6116(4) 0.4472(5) -0.0317(3) 0.0663(8) Uani 1 1 d . U . . .
H29 H 0.6131 0.4013 -0.0502 0.080 Uiso 1 1 calc R U . . .
C30 C 0.4874(3) 0.2847(3) 0.0707(2) 0.0337(10) Uani 1 1 d . . . . .
C31 C 0.4531(4) 0.2574(4) 0.0128(2) 0.0467(13) Uani 1 1 d . . . . .
H31 H 0.4865 0.2825 -0.0224 0.056 Uiso 1 1 calc R U . . .
C32 C 0.3710(4) 0.1943(4) 0.0064(3) 0.0560(16) Uani 1 1 d . . . . .
H32 H 0.3482 0.1756 -0.0332 0.067 Uiso 1 1 calc R U . . .
C33 C 0.3219(4) 0.1583(4) 0.0571(3) 0.0574(16) Uani 1 1 d . . . . .
H33 H 0.2658 0.1139 0.0524 0.069 Uiso 1 1 calc R U . . .
C34 C 0.3537(4) 0.1863(4) 0.1152(3) 0.0480(13) Uani 1 1 d . . . . .
H34 H 0.3192 0.1626 0.1501 0.058 Uiso 1 1 calc R U . . .
C35 C 0.4366(3) 0.2493(3) 0.1216(2) 0.0353(10) Uani 1 1 d . . . . .
H35 H 0.4589 0.2685 0.1612 0.042 Uiso 1 1 calc R U . . .
C36 C 0.3469(3) 0.3874(3) 0.2453(3) 0.0412(12) Uani 1 1 d . . . . .
O1 O 0.4569(2) 0.3504(2) 0.2778(2) 0.0480(10) Uani 1 1 d . . . . .
O2 O 0.4914(2) 0.4458(3) 0.19372(17) 0.0469(9) Uani 1 1 d . . . . .
O3 O 0.4864(2) 0.4926(2) 0.29592(17) 0.0400(8) Uani 1 1 d . . . . .
F1 F 0.3064(2) 0.3630(3) 0.29798(19) 0.0634(10) Uani 1 1 d . . . . .
F2 F 0.3112(2) 0.3234(3) 0.2074(2) 0.0786(14) Uani 1 1 d . . . . .
F3 F 0.3342(2) 0.4472(3) 0.2228(2) 0.0699(12) Uani 1 1 d . . . . .
F4 F 0.7764(4) 0.9100(4) 0.3303(4) 0.101(2) Uani 0.765(10) 1 d D . P B 1
F5 F 0.8767(4) 0.9110(3) 0.3786(4) 0.101(2) Uani 0.765(10) 1 d D . P B 1
F6 F 0.8913(4) 0.9401(3) 0.2856(4) 0.101(2) Uani 0.765(10) 1 d D . P B 1
F6A F 0.9112(7) 0.9453(10) 0.3269(9) 0.074(4) Uani 0.235(10) 1 d D U P B 2
F4A F 0.8119(10) 0.9201(10) 0.2693(6) 0.074(4) Uani 0.235(10) 1 d D U P B 2
F5A F 0.7889(11) 0.9081(13) 0.3615(7) 0.074(4) Uani 0.235(10) 1 d D U P B 2
P1 P 0.58009(6) 0.34832(6) 0.42995(4) 0.01652(19) Uani 1 1 d . . . . .
P2 P 0.59500(8) 0.36875(8) 0.08210(5) 0.0287(2) Uani 1 1 d . . . . .
S1 S 0.45878(6) 0.42488(6) 0.25427(5) 0.0236(2) Uani 1 1 d . . . . .
Ag1 Ag 0.58228(2) 0.34811(2) 0.31708(2) 0.01673(8) Uani 1 1 d . . . . .
Ag2 Ag 0.62700(2) 0.40584(2) 0.18685(2) 0.02253(9) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 C1 Ag2 122.8(3) . .
C2 C1 Ag1 137.2(3) . .
Ag2 C1 Ag1 86.11(14) . .
C2 C1 Ag1 111.9(3) . 3_665
Ag2 C1 Ag1 112.33(16) . 3_665
Ag1 C1 Ag1 78.32(12) . 3_665
C1 C2 C3 176.6(5) . .
C4 C3 C8 120.2(4) . .
C4 C3 C2 119.4(4) . .
C8 C3 C2 120.5(4) . .
C3 C4 C5 119.9(4) . .
C3 C4 H4 120.0 . .
C5 C4 H4 120.0 . .
C6 C5 C4 119.8(5) . .
C6 C5 H5 120.1 . .
C4 C5 H5 120.1 . .
C5 C6 C7 120.6(5) . .
C5 C6 C9 119.7(5) . .
C7 C6 C9 119.6(5) . .
C8 C7 C6 120.3(4) . .
C8 C7 H7 119.8 . .
C6 C7 H7 119.8 . .
C7 C8 C3 119.2(4) . .
C7 C8 H8 120.4 . .
C3 C8 H8 120.4 . .
F6A C9 F5A 109.6(11) . .
F4 C9 F6 110.0(6) . .
F4 C9 F5 104.8(6) . .
F6 C9 F5 101.0(6) . .
F6A C9 F4A 97.4(10) . .
F5A C9 F4A 94.8(9) . .
F4 C9 C6 116.0(5) . .
F6A C9 C6 124.6(9) . .
F5A C9 C6 117.7(10) . .
F6 C9 C6 114.4(6) . .
F5 C9 C6 109.3(5) . .
F4A C9 C6 105.4(8) . .
P1 C10 P1 107.06(19) 2_655 3_665
P1 C10 P1 107.06(19) 2_655 .
P1 C10 P1 107.05(19) 3_665 .
P1 C10 H10 111.8 2_655 .
P1 C10 H10 111.8 3_665 .
P1 C10 H10 111.8 . .
C12 C11 C16 119.7(5) . .
C12 C11 P1 118.6(4) . .
C16 C11 P1 121.7(5) . .
C11 C12 C13 120.2(5) . .
C11 C12 H12 119.9 . .
C13 C12 H12 119.9 . .
C14 C13 C12 119.1(6) . .
C14 C13 H13 120.5 . .
C12 C13 H13 120.5 . .
C13 C14 C15 121.7(5) . .
C13 C14 H14 119.2 . .
C15 C14 H14 119.2 . .
C14 C15 C16 119.5(6) . .
C14 C15 H15 120.3 . .
C16 C15 H15 120.3 . .
C15 C16 C11 119.8(6) . .
C15 C16 H16 120.1 . .
C11 C16 H16 120.1 . .
C12A C11A C16A 120.0 . .
C12A C11A P1 116.4(12) . .
C16A C11A P1 123.2(13) . .
C13A C12A C11A 120.0 . .
C13A C12A H12A 120.0 . .
C11A C12A H12A 120.0 . .
C12A C13A C14A 120.0 . .
C12A C13A H13A 120.0 . .
C14A C13A H13A 120.0 . .
C15A C14A C13A 120.0 . .
C15A C14A H14A 120.0 . .
C13A C14A H14A 120.0 . .
C14A C15A C16A 120.0 . .
C14A C15A H15A 120.0 . .
C16A C15A H15A 120.0 . .
C15A C16A C11A 120.0 . .
C15A C16A H16A 120.0 . .
C11A C16A H16A 120.0 . .
C18 C17 C22 119.3(4) . .
C18 C17 P1 115.5(3) . .
C22 C17 P1 124.9(3) . .
C19 C18 C17 120.0(5) . .
C19 C18 H18 120.0 . .
C17 C18 H18 120.0 . .
C20 C19 C18 120.1(5) . .
C20 C19 H19 119.9 . .
C18 C19 H19 119.9 . .
C19 C20 C21 120.3(4) . .
C19 C20 H20 119.9 . .
C21 C20 H20 119.9 . .
C20 C21 C22 120.3(5) . .
C20 C21 H21 119.9 . .
C22 C21 H21 119.9 . .
C21 C22 C17 120.0(5) . .
C21 C22 H22 120.0 . .
C17 C22 H22 120.0 . .
P2 C23 P2 107.4(2) 2_655 3_665
P2 C23 P2 107.4(2) 2_655 .
P2 C23 P2 107.4(2) 3_665 .
P2 C23 H23 111.4 2_655 .
P2 C23 H23 111.4 3_665 .
P2 C23 H23 111.4 . .
C29 C24 C25 120.5(6) . .
C29 C24 P2 122.4(7) . .
C25 C24 P2 117.0(5) . .
C26 C25 C24 118.7(7) . .
C26 C25 H25 120.7 . .
C24 C25 H25 120.7 . .
C27 C26 C25 120.2(8) . .
C27 C26 H26 119.9 . .
C25 C26 H26 119.9 . .
C28 C27 C26 121.8(6) . .
C28 C27 H27 119.1 . .
C26 C27 H27 119.1 . .
C27 C28 C29 120.7(7) . .
C27 C28 H28 119.6 . .
C29 C28 H28 119.6 . .
C24 C29 C28 118.1(8) . .
C24 C29 H29 121.0 . .
C28 C29 H29 121.0 . .
C35 C30 C31 118.8(5) . .
C35 C30 P2 118.7(3) . .
C31 C30 P2 122.4(4) . .
C32 C31 C30 120.4(6) . .
C32 C31 H31 119.8 . .
C30 C31 H31 119.8 . .
C33 C32 C31 120.1(5) . .
C33 C32 H32 119.9 . .
C31 C32 H32 119.9 . .
C32 C33 C34 120.6(6) . .
C32 C33 H33 119.7 . .
C34 C33 H33 119.7 . .
C35 C34 C33 119.1(6) . .
C35 C34 H34 120.4 . .
C33 C34 H34 120.4 . .
C34 C35 C30 120.8(5) . .
C34 C35 H35 119.6 . .
C30 C35 H35 119.6 . .
F2 C36 F1 107.5(5) . .
F2 C36 F3 106.9(5) . .
F1 C36 F3 107.6(5) . .
F2 C36 S1 111.7(4) . .
F1 C36 S1 111.8(4) . .
F3 C36 S1 111.1(4) . .
S1 O1 Ag1 123.8(2) . .
C11A P1 C17 98.5(9) . .
C17 P1 C11 101.3(2) . .
C11A P1 C10 98.3(10) . .
C17 P1 C10 110.47(18) . .
C11 P1 C10 106.1(2) . .
C11A P1 Ag1 124.8(9) . .
C17 P1 Ag1 112.52(14) . .
C11 P1 Ag1 115.1(2) . .
C10 P1 Ag1 110.81(18) . .
C24 P2 C30 104.1(3) . .
C24 P2 C23 105.8(3) . .
C30 P2 C23 108.14(18) . .
C24 P2 Ag2 116.1(3) . .
C30 P2 Ag2 112.55(16) . .
C23 P2 Ag2 109.6(2) . .
O3 S1 O2 116.3(2) . .
O3 S1 O1 115.6(3) . .
O2 S1 O1 113.1(3) . .
O3 S1 C36 104.0(2) . .
O2 S1 C36 104.2(2) . .
O1 S1 C36 101.1(2) . .
C1 Ag1 C1 121.32(19) . 2_655
C1 Ag1 P1 116.74(10) . .
C1 Ag1 P1 115.30(10) 2_655 .
C1 Ag1 O1 97.43(13) . .
C1 Ag1 O1 89.42(13) 2_655 .
P1 Ag1 O1 109.31(11) . .
C1 Ag1 Ag1 105.42(10) . 2_655
C1 Ag1 Ag1 49.07(9) 2_655 2_655
P1 Ag1 Ag1 90.82(2) . 2_655
O1 Ag1 Ag1 138.46(9) . 2_655
C1 Ag1 Ag1 52.61(9) . 3_665
C1 Ag1 Ag1 102.36(9) 2_655 3_665
P1 Ag1 Ag1 90.88(2) . 3_665
O1 Ag1 Ag1 149.74(9) . 3_665
Ag1 Ag1 Ag1 60.0 2_655 3_665
C1 Ag1 Ag2 44.87(10) . .
C1 Ag1 Ag2 81.92(10) 2_655 .
P1 Ag1 Ag2 161.50(3) . .
O1 Ag1 Ag2 75.99(11) . .
Ag1 Ag1 Ag2 96.399(7) 2_655 .
Ag1 Ag1 Ag2 78.197(9) 3_665 .
C1 Ag2 P2 165.21(11) . .
C1 Ag2 Ag1 49.02(10) . .
P2 Ag2 Ag1 145.73(3) . .
C1 Ag2 Ag2 83.07(10) . 3_665
P2 Ag2 Ag2 93.50(3) . 3_665
Ag1 Ag2 Ag2 92.557(7) . 3_665
C1 Ag2 Ag2 111.42(10) . 2_655
P2 Ag2 Ag2 78.68(3) . 2_655
Ag1 Ag2 Ag2 75.369(9) . 2_655
Ag2 Ag2 Ag2 60.0 3_665 2_655
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.218(6) .
C1 Ag2 2.131(4) .
C1 Ag1 2.281(4) .
C1 Ag1 2.399(4) 3_665
C2 C3 1.441(5) .
C3 C4 1.386(6) .
C3 C8 1.402(6) .
C4 C5 1.390(7) .
C4 H4 0.9500 .
C5 C6 1.376(7) .
C5 H5 0.9500 .
C6 C7 1.386(7) .
C6 C9 1.476(7) .
C7 C8 1.381(6) .
C7 H7 0.9500 .
C8 H8 0.9500 .
C9 F4 1.289(8) .
C9 F6A 1.295(12) .
C9 F5A 1.322(12) .
C9 F6 1.322(8) .
C9 F5 1.390(9) .
C9 F4A 1.464(12) .
C10 P1 1.884(3) 2_655
C10 P1 1.884(3) 3_665
C10 P1 1.884(3) .
C10 H10 1.0000 .
C11 C12 1.391(8) .
C11 C16 1.398(7) .
C11 P1 1.831(5) .
C12 C13 1.396(7) .
C12 H12 0.9500 .
C13 C14 1.377(10) .
C13 H13 0.9500 .
C14 C15 1.378(10) .
C14 H14 0.9500 .
C15 C16 1.393(8) .
C15 H15 0.9500 .
C16 H16 0.9500 .
C11A C12A 1.3900 .
C11A C16A 1.3900 .
C11A P1 1.798(15) .
C12A C13A 1.3900 .
C12A H12A 0.9500 .
C13A C14A 1.3900 .
C13A H13A 0.9500 .
C14A C15A 1.3900 .
C14A H14A 0.9500 .
C15A C16A 1.3900 .
C15A H15A 0.9500 .
C16A H16A 0.9500 .
C17 C18 1.398(6) .
C17 C22 1.398(6) .
C17 P1 1.827(4) .
C18 C19 1.396(6) .
C18 H18 0.9500 .
C19 C20 1.378(8) .
C19 H19 0.9500 .
C20 C21 1.385(9) .
C20 H20 0.9500 .
C21 C22 1.388(6) .
C21 H21 0.9500 .
C22 H22 0.9500 .
C23 P2 1.870(3) 2_655
C23 P2 1.870(3) 3_665
C23 P2 1.870(3) .
C23 H23 1.0000 .
C24 C29 1.396(11) .
C24 C25 1.401(12) .
C24 P2 1.816(6) .
C25 C26 1.394(8) .
C25 H25 0.9500 .
C26 C27 1.373(11) .
C26 H26 0.9500 .
C27 C28 1.331(12) .
C27 H27 0.9500 .
C28 C29 1.417(8) .
C28 H28 0.9500 .
C29 H29 0.9500 .
C30 C35 1.391(7) .
C30 C31 1.395(7) .
C30 P2 1.821(5) .
C31 C32 1.379(9) .
C31 H31 0.9500 .
C32 C33 1.377(10) .
C32 H32 0.9500 .
C33 C34 1.388(8) .
C33 H33 0.9500 .
C34 C35 1.387(7) .
C34 H34 0.9500 .
C35 H35 0.9500 .
C36 F2 1.318(7) .
C36 F1 1.326(7) .
C36 F3 1.329(6) .
C36 S1 1.827(5) .
O1 S1 1.450(3) .
O1 Ag1 2.485(3) .
O2 S1 1.428(4) .
O3 S1 1.419(4) .
P1 Ag1 2.4748(10) .
P2 Ag2 2.3845(11) .
Ag1 C1 2.399(4) 2_655
Ag1 Ag1 2.9563(5) 2_655
Ag1 Ag1 2.9563(5) 3_665
Ag1 Ag2 3.0142(4) .
Ag2 Ag2 3.1434(5) 3_665
Ag2 Ag2 3.1434(5) 2_655
