#------------------------------------------------------------------------------
#$Date: 2019-11-24 05:46:02 +0200 (Sun, 24 Nov 2019) $
#$Revision: 236859 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/08/75/4087576.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4087576
loop_
_publ_author_name
'Karthik, Vedhagiri'
'Gupta, Vivek'
'Anantharaman, Ganapathi'
_publ_section_title
;
 Synthesis, Structure, and Coordination Chemistry of
 Phosphine-Functionalized Imidazole/Imidazolium Salts and Cleavage of a
 C--P Bond in an NHC--Phosphenium Salt using a Pd(0) Precursor
;
_journal_issue                   15
_journal_name_full               Organometallics
_journal_page_first              3713
_journal_paper_doi               10.1021/acs.organomet.5b00336
_journal_volume                  34
_journal_year                    2015
_chemical_formula_moiety         'C33 H33 B2 Cu F8 N4 P2'
_chemical_formula_sum            'C33 H33 B2 Cu F8 N4 P2'
_chemical_formula_weight         784.73
_chemical_name_common            'Copper-phosphine complex'
_space_group_IT_number           11
_space_group_name_Hall           '-P 2yb'
_space_group_name_H-M_alt        'P 1 21/m 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yb'
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 116.335(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   11.1242(11)
_cell_length_b                   15.2340(16)
_cell_length_c                   11.7171(12)
_cell_measurement_reflns_used    2843
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      25.96
_cell_measurement_theta_min      2.36
_cell_volume                     1779.6(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'ORTEP 3v2'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0353
_diffrn_reflns_av_sigmaI/netI    0.0418
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            10019
_diffrn_reflns_theta_full        25.99
_diffrn_reflns_theta_max         25.99
_diffrn_reflns_theta_min         1.94
_exptl_absorpt_coefficient_mu    0.776
_exptl_absorpt_correction_T_max  0.8991
_exptl_absorpt_correction_T_min  0.8478
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.464
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             800
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.14
_refine_diff_density_max         0.794
_refine_diff_density_min         -0.859
_refine_diff_density_rms         0.086
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.067
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     262
_refine_ls_number_reflns         3605
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.067
_refine_ls_R_factor_all          0.0651
_refine_ls_R_factor_gt           0.0509
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0582P)²+2.7566P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1207
_refine_ls_wR_factor_ref         0.1348
_reflns_number_gt                2904
_reflns_number_total             3605
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om5b00336_si_002.cif
_cod_data_source_block           28aprbm
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_refine_ls_hydrogen_treatment' value 'Constr' was changed
to 'constr' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_Hall     ' -P 2yb '
_cod_original_sg_symbol_H-M      'P2(1)/m  '
_cod_database_code               4087576
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
B1 B 0.3565(7) 0.7145(6) 0.0443(9) 0.038(2) Uani 0.50 1 d P
B2 B 0.6440(5) 0.7500 0.7284(5) 0.0281(11) Uani 1 2 d S
C1 C 0.6109(5) 0.7500 -0.0093(5) 0.0441(14) Uani 1 2 d S
H1 H 0.5380 0.7500 -0.0922 0.053 Uiso 1 2 calc SR
C2 C 0.7709(3) 0.7053(2) 0.1733(3) 0.0267(7) Uani 1 1 d .
C3 C 0.6283(5) 0.5879(3) 0.0148(4) 0.0710(17) Uani 1 1 d .
H3A H 0.5793 0.5640 0.0596 0.107 Uiso 1 1 calc R
H3B H 0.7082 0.5522 0.0340 0.107 Uiso 1 1 calc R
H3C H 0.5703 0.5871 -0.0772 0.107 Uiso 1 1 calc R
C4 C 0.9895(3) 0.5835(2) 0.2487(3) 0.0304(7) Uani 1 1 d .
C5 C 1.0757(3) 0.5182(3) 0.3228(3) 0.0402(9) Uani 1 1 d .
H5 H 1.0709 0.4991 0.3978 0.048 Uiso 1 1 calc R
C6 C 1.1684(4) 0.4807(3) 0.2891(3) 0.0413(9) Uani 1 1 d .
H6 H 1.2246 0.4346 0.3389 0.050 Uiso 1 1 calc R
C7 C 1.1788(6) 0.5099(3) 0.1847(5) 0.0659(15) Uani 1 1 d .
H7 H 1.2439 0.4851 0.1625 0.079 Uiso 1 1 calc R
C8 C 1.0952(9) 0.5754(4) 0.1106(7) 0.122(3) Uani 1 1 d .
H8 H 1.1023 0.5952 0.0370 0.146 Uiso 1 1 calc R
C9 C 1.0013(7) 0.6123(3) 0.1429(5) 0.084(2) Uani 1 1 d .
H9 H 0.9445 0.6578 0.0919 0.100 Uiso 1 1 calc R
C10 C 0.7733(3) 0.5612(2) 0.3275(3) 0.0300(7) Uani 1 1 d .
C11 C 0.7717(3) 0.4715(2) 0.3022(3) 0.0327(8) Uani 1 1 d .
H11 H 0.8318 0.4482 0.2724 0.039 Uiso 1 1 calc R
C12 C 0.6826(3) 0.4165(2) 0.3206(3) 0.0359(8) Uani 1 1 d .
H12 H 0.6829 0.3553 0.3048 0.043 Uiso 1 1 calc R
C13 C 0.5931(4) 0.4504(2) 0.3618(3) 0.0372(8) Uani 1 1 d .
H13 H 0.5307 0.4128 0.3725 0.045 Uiso 1 1 calc R
C14 C 0.5948(4) 0.5385(3) 0.3872(4) 0.0423(9) Uani 1 1 d .
H14 H 0.5336 0.5616 0.4158 0.051 Uiso 1 1 calc R
C15 C 0.6846(4) 0.5941(2) 0.3714(4) 0.0402(9) Uani 1 1 d .
H15 H 0.6858 0.6548 0.3906 0.048 Uiso 1 1 calc R
C16 C 0.9962(4) 0.7500 0.7103(4) 0.0314(11) Uani 1 2 d S
C17 C 0.9889(5) 0.7500 0.8321(5) 0.0510(16) Uani 1 2 d S
H17A H 1.0770 0.7649 0.9008 0.076 Uiso 0.50 1 calc PR
H17B H 0.9621 0.6916 0.8475 0.076 Uiso 0.50 1 calc PR
H17C H 0.9228 0.7935 0.8293 0.076 Uiso 0.50 1 calc PR
C18 C 1.2587(5) 0.7500 0.4187(4) 0.0325(11) Uani 1 2 d S
C19 C 1.3639(5) 0.7500 0.3754(5) 0.0598(19) Uani 1 2 d S
H19A H 1.3680 0.8079 0.3409 0.090 Uiso 0.50 1 calc PR
H19B H 1.3434 0.7054 0.3091 0.090 Uiso 0.50 1 calc PR
H19C H 1.4506 0.7367 0.4474 0.090 Uiso 0.50 1 calc PR
Cu1 Cu 0.99461(5) 0.7500 0.44711(5) 0.02230(17) Uani 1 2 d S
F1 F 0.4758(3) 0.7500 0.1561(3) 0.0732(13) Uani 1 2 d S
F2 F 0.2516(4) 0.7192(3) 0.0804(4) 0.0435(12) Uani 0.50 1 d P
F3 F 0.3373(5) 0.7500 -0.0478(5) 0.175(5) Uani 1 2 d S
F4 F 0.3669(6) 0.6375(5) 0.0051(7) 0.0837(19) Uani 0.50 1 d P
F5 F 0.5060(2) 0.7500 0.6909(3) 0.0325(6) Uani 1 2 d S
F6 F 0.6994(2) 0.67602(14) 0.8024(2) 0.0471(6) Uani 1 1 d .
F7 F 0.6704(3) 0.7500 0.6241(3) 0.0497(8) Uani 1 2 d S
N1 N 0.6688(3) 0.6787(2) 0.0564(3) 0.0387(8) Uani 1 1 d .
N2 N 1.0026(4) 0.7500 0.6174(4) 0.0280(8) Uani 1 2 d S
N3 N 1.1768(4) 0.7500 0.4512(3) 0.0255(8) Uani 1 2 d S
P1 P 0.88474(8) 0.64074(5) 0.30736(7) 0.0246(2) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
B1 B1 F3 61.6(5) 4_575 .
B1 B1 F4 156.1(5) 4_575 .
F3 B1 F4 96.0(8) . .
B1 B1 F2 87.1(4) 4_575 .
F3 B1 F2 115.3(7) . .
F4 B1 F2 111.8(7) . .
B1 B1 F1 68.7(3) 4_575 .
F3 B1 F1 112.3(6) . .
F4 B1 F1 117.4(6) . .
F2 B1 F1 104.5(7) . .
B1 B1 F2 54.3(3) 4_575 4_575
F3 B1 F2 95.2(6) . 4_575
F4 B1 F2 142.9(6) . 4_575
F2 B1 F2 32.8(3) . 4_575
F1 B1 F2 90.4(5) . 4_575
F7 B2 F6 110.1(3) . .
F7 B2 F6 110.1(3) . 4_575
F6 B2 F6 108.5(4) . 4_575
F7 B2 F5 111.0(4) . .
F6 B2 F5 108.5(3) . .
F6 B2 F5 108.5(3) 4_575 .
N1 C1 N1 110.5(4) . 4_575
N1 C1 H1 124.8 . .
N1 C1 H1 124.8 4_575 .
C2 C2 N1 106.9(2) 4_575 .
C2 C2 P1 122.94(10) 4_575 .
N1 C2 P1 130.2(3) . .
N1 C3 H3A 109.5 . .
N1 C3 H3B 109.5 . .
H3A C3 H3B 109.5 . .
N1 C3 H3C 109.5 . .
H3A C3 H3C 109.5 . .
H3B C3 H3C 109.5 . .
C9 C4 C5 118.4(3) . .
C9 C4 P1 121.5(3) . .
C5 C4 P1 119.3(3) . .
C6 C5 C4 121.0(3) . .
C6 C5 H5 119.5 . .
C4 C5 H5 119.5 . .
C7 C6 C5 119.8(4) . .
C7 C6 H6 120.1 . .
C5 C6 H6 120.1 . .
C6 C7 C8 120.2(4) . .
C6 C7 H7 119.9 . .
C8 C7 H7 119.9 . .
C7 C8 C9 120.2(4) . .
C7 C8 H8 119.9 . .
C9 C8 H8 119.9 . .
C4 C9 C8 120.3(4) . .
C4 C9 H9 119.8 . .
C8 C9 H9 119.8 . .
C15 C10 C11 119.1(3) . .
C15 C10 P1 116.2(3) . .
C11 C10 P1 124.7(3) . .
C12 C11 C10 120.1(3) . .
C12 C11 H11 119.9 . .
C10 C11 H11 119.9 . .
C13 C12 C11 120.2(3) . .
C13 C12 H12 119.9 . .
C11 C12 H12 119.9 . .
C14 C13 C12 119.8(3) . .
C14 C13 H13 120.1 . .
C12 C13 H13 120.1 . .
C13 C14 C15 120.7(4) . .
C13 C14 H14 119.6 . .
C15 C14 H14 119.6 . .
C14 C15 C10 120.0(3) . .
C14 C15 H15 120.0 . .
C10 C15 H15 120.0 . .
N2 C16 C17 179.6(5) . .
C16 C17 H17A 109.5 . .
C16 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C16 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
N3 C18 C19 179.5(5) . .
C18 C19 H19A 109.5 . .
C18 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
C18 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
N2 Cu1 N3 112.78(15) . .
N2 Cu1 P1 120.06(7) . .
N3 Cu1 P1 103.40(7) . .
N2 Cu1 P1 120.06(6) . 4_575
N3 Cu1 P1 103.40(7) . 4_575
P1 Cu1 P1 94.11(5) . 4_575
B1 F1 B1 42.5(7) . 4_575
F2 F2 B1 92.9(4) 4_575 .
F2 F2 B1 54.3(3) 4_575 4_575
B1 F2 B1 38.6(6) . 4_575
B1 F3 B1 56.7(10) . 4_575
C1 N1 C2 107.9(3) . .
C1 N1 C3 125.5(3) . .
C2 N1 C3 126.5(3) . .
C16 N2 Cu1 174.4(4) . .
C18 N3 Cu1 161.3(4) . .
C2 P1 C4 104.60(15) . .
C2 P1 C10 102.70(15) . .
C4 P1 C10 108.46(15) . .
C2 P1 Cu1 99.94(11) . .
C4 P1 Cu1 113.19(11) . .
C10 P1 Cu1 124.95(11) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
B1 B1 1.082(18) 4_575
B1 F3 1.139(9) .
B1 F4 1.283(11) .
B1 F2 1.408(9) .
B1 F1 1.492(9) .
B1 F2 1.732(10) 4_575
B2 F7 1.377(6) .
B2 F6 1.388(4) .
B2 F6 1.388(4) 4_575
B2 F5 1.397(6) .
C1 N1 1.322(4) .
C1 N1 1.322(4) 4_575
C1 H1 0.9500 .
C2 C2 1.361(7) 4_575
C2 N1 1.396(4) .
C2 P1 1.810(3) .
C3 N1 1.469(5) .
C3 H3A 0.9800 .
C3 H3B 0.9800 .
C3 H3C 0.9800 .
C4 C9 1.375(5) .
C4 C5 1.387(5) .
C4 P1 1.816(3) .
C5 C6 1.381(5) .
C5 H5 0.9500 .
C6 C7 1.353(5) .
C6 H6 0.9500 .
C7 C8 1.378(7) .
C7 H7 0.9500 .
C8 C9 1.379(6) .
C8 H8 0.9500 .
C9 H9 0.9500 .
C10 C15 1.394(5) .
C10 C11 1.395(5) .
C10 P1 1.823(3) .
C11 C12 1.386(5) .
C11 H11 0.9500 .
C12 C13 1.385(5) .
C12 H12 0.9500 .
C13 C14 1.374(5) .
C13 H13 0.9500 .
C14 C15 1.383(5) .
C14 H14 0.9500 .
C15 H15 0.9500 .
C16 N2 1.123(6) .
C16 C17 1.464(7) .
C17 H17A 0.9800 .
C17 H17B 0.9800 .
C17 H17C 0.9800 .
C18 N3 1.133(6) .
C18 C19 1.468(7) .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9800 .
Cu1 N2 1.957(4) .
Cu1 N3 2.006(4) .
Cu1 P1 2.2738(9) .
Cu1 P1 2.2738(9) 4_575
F1 B1 1.492(9) 4_575
F2 F2 0.939(8) 4_575
F2 B1 1.732(10) 4_575
F3 B1 1.139(9) 4_575
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C9 C4 C5 C6 -2.2(6) . .
P1 C4 C5 C6 -172.0(3) . .
C4 C5 C6 C7 2.3(6) . .
C5 C6 C7 C8 -1.5(8) . .
C6 C7 C8 C9 0.6(11) . .
C5 C4 C9 C8 1.3(8) . .
P1 C4 C9 C8 170.9(6) . .
C7 C8 C9 C4 -0.6(11) . .
C15 C10 C11 C12 0.2(5) . .
P1 C10 C11 C12 -179.9(2) . .
C10 C11 C12 C13 1.2(5) . .
C11 C12 C13 C14 -1.4(5) . .
C12 C13 C14 C15 0.3(6) . .
C13 C14 C15 C10 1.0(6) . .
C11 C10 C15 C14 -1.2(5) . .
P1 C10 C15 C14 178.8(3) . .
F3 B1 F1 B1 44.7(8) . 4_575
F4 B1 F1 B1 154.5(6) . 4_575
F2 B1 F1 B1 -81.0(5) . 4_575
F2 B1 F1 B1 -51.0(4) 4_575 4_575
B1 B1 F2 F2 0.001(2) 4_575 4_575
F3 B1 F2 F2 -56.6(7) . 4_575
F4 B1 F2 F2 -164.9(7) . 4_575
F1 B1 F2 F2 67.2(4) . 4_575
F3 B1 F2 B1 -56.6(7) . 4_575
F4 B1 F2 B1 -164.9(7) . 4_575
F1 B1 F2 B1 67.2(4) . 4_575
F2 B1 F2 B1 -0.001(1) 4_575 4_575
F4 B1 F3 B1 -171.0(4) . 4_575
F2 B1 F3 B1 71.4(8) . 4_575
F1 B1 F3 B1 -48.2(7) . 4_575
F2 B1 F3 B1 44.4(5) 4_575 4_575
N1 C1 N1 C2 0.3(5) 4_575 .
N1 C1 N1 C3 178.1(3) 4_575 .
C2 C2 N1 C1 -0.2(3) 4_575 .
P1 C2 N1 C1 178.4(3) . .
C2 C2 N1 C3 -178.0(3) 4_575 .
P1 C2 N1 C3 0.6(5) . .
C17 C16 N2 Cu1 180.0(3) . .
N3 Cu1 N2 C16 180.000(15) . .
P1 Cu1 N2 C16 -57.76(7) . .
P1 Cu1 N2 C16 57.76(7) 4_575 .
C19 C18 N3 Cu1 0.00(15) . .
N2 Cu1 N3 C18 180.000(3) . .
P1 Cu1 N3 C18 48.81(3) . .
P1 Cu1 N3 C18 -48.81(3) 4_575 .
C2 C2 P1 C4 -114.99(12) 4_575 .
N1 C2 P1 C4 66.6(3) . .
C2 C2 P1 C10 131.80(12) 4_575 .
N1 C2 P1 C10 -46.6(3) . .
C2 C2 P1 Cu1 2.33(9) 4_575 .
N1 C2 P1 Cu1 -176.1(3) . .
C9 C4 P1 C2 19.7(4) . .
C5 C4 P1 C2 -170.8(3) . .
C9 C4 P1 C10 128.7(4) . .
C5 C4 P1 C10 -61.8(3) . .
C9 C4 P1 Cu1 -88.1(4) . .
C5 C4 P1 Cu1 81.4(3) . .
C15 C10 P1 C2 -69.3(3) . .
C11 C10 P1 C2 110.8(3) . .
C15 C10 P1 C4 -179.6(3) . .
C11 C10 P1 C4 0.5(3) . .
C15 C10 P1 Cu1 42.7(3) . .
C11 C10 P1 Cu1 -137.3(2) . .
N2 Cu1 P1 C2 125.59(15) . .
N3 Cu1 P1 C2 -107.70(13) . .
P1 Cu1 P1 C2 -2.87(11) 4_575 .
N2 Cu1 P1 C4 -123.71(16) . .
N3 Cu1 P1 C4 3.01(15) . .
P1 Cu1 P1 C4 107.84(12) 4_575 .
N2 Cu1 P1 C10 12.33(19) . .
N3 Cu1 P1 C10 139.05(16) . .
P1 Cu1 P1 C10 -116.12(14) 4_575 .
