#------------------------------------------------------------------------------
#$Date: 2019-11-24 06:13:25 +0200 (Sun, 24 Nov 2019) $
#$Revision: 236917 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/08/76/4087683.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4087683
loop_
_publ_author_name
'Ibad, Muhammad Farooq'
'Schulz, Axel'
'Villinger, Alexander'
_publ_section_title
;
 Pentafluorophenyl Silver: Structure and Bonding of Arene Solvates
;
_journal_issue                   15
_journal_name_full               Organometallics
_journal_page_first              3893
_journal_paper_doi               10.1021/acs.organomet.5b00492
_journal_volume                  34
_journal_year                    2015
_chemical_formula_moiety         'C24 Ag4 F20, 2(C10 H14)'
_chemical_formula_sum            'C44 H28 Ag4 F20'
_chemical_formula_weight         1368.14
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.1380(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   11.7064(2)
_cell_length_b                   20.1576(4)
_cell_length_c                   9.1518(2)
_cell_measurement_reflns_used    9988
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      65.055
_cell_measurement_theta_min      5.995
_cell_volume                     2159.57(7)
_computing_cell_refinement       'Bruker Apex V7.51A'
_computing_data_collection       'Bruker Apex V7.51A'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'ORTEP-3v2.01 (Farrugia, 1997)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker-Nonius Apex X8-CCD-diffractometer'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0198
_diffrn_reflns_av_sigmaI/netI    0.0180
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            38665
_diffrn_reflns_theta_full        32.50
_diffrn_reflns_theta_max         32.50
_diffrn_reflns_theta_min         3.00
_exptl_absorpt_coefficient_mu    1.907
_exptl_absorpt_correction_T_max  0.7501
_exptl_absorpt_correction_T_min  0.6790
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2004)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.104
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1320
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.16
_refine_diff_density_max         0.627
_refine_diff_density_min         -0.481
_refine_diff_density_rms         0.074
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     315
_refine_ls_number_reflns         7800
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.053
_refine_ls_R_factor_all          0.0294
_refine_ls_R_factor_gt           0.0219
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0247P)²+0.8218P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0502
_refine_ls_wR_factor_ref         0.0532
_reflns_number_gt                6727
_reflns_number_total             7800
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            om5b00492_si_002.cif
_cod_data_source_block           av_fi134b_AgC6F5_1235MeC6H2
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4087683
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.147898(10) 0.514366(5) 0.171648(13) 0.02441(3) Uani 1 1 d .
Ag2 Ag 0.015016(10) 0.426391(5) 0.010116(13) 0.02688(4) Uani 1 1 d .
C1 C 0.16622(13) 0.40686(7) 0.15480(17) 0.0243(3) Uani 1 1 d .
C2 C 0.25784(14) 0.38500(8) 0.07172(18) 0.0278(3) Uani 1 1 d .
C3 C 0.31251(15) 0.32525(9) 0.09423(19) 0.0325(4) Uani 1 1 d .
C4 C 0.27233(16) 0.28359(8) 0.2030(2) 0.0350(4) Uani 1 1 d .
C5 C 0.18313(15) 0.30298(8) 0.28939(19) 0.0318(3) Uani 1 1 d .
C6 C 0.13249(14) 0.36401(8) 0.26514(17) 0.0271(3) Uani 1 1 d .
C7 C 0.12205(13) 0.62035(7) 0.12471(18) 0.0261(3) Uani 1 1 d .
C8 C 0.07332(15) 0.66369(8) 0.2246(2) 0.0322(3) Uani 1 1 d .
C9 C 0.10508(17) 0.72961(9) 0.2359(2) 0.0426(5) Uani 1 1 d .
C10 C 0.1890(2) 0.75424(9) 0.1471(3) 0.0492(6) Uani 1 1 d .
C11 C 0.24048(17) 0.71354(10) 0.0473(2) 0.0446(5) Uani 1 1 d .
C12 C 0.20569(14) 0.64814(8) 0.03675(19) 0.0319(3) Uani 1 1 d .
F1 F 0.29798(10) 0.42337(6) -0.03709(13) 0.0440(3) Uani 1 1 d .
F2 F 0.40267(11) 0.30705(7) 0.01428(14) 0.0533(3) Uani 1 1 d .
F3 F 0.32254(12) 0.22482(6) 0.22463(15) 0.0558(3) Uani 1 1 d .
F4 F 0.14556(12) 0.26284(6) 0.39620(14) 0.0518(3) Uani 1 1 d .
F5 F 0.04505(9) 0.38064(6) 0.35273(12) 0.0415(3) Uani 1 1 d .
F6 F -0.00903(11) 0.64219(7) 0.31484(14) 0.0504(3) Uani 1 1 d .
F7 F 0.05246(13) 0.76960(7) 0.33261(16) 0.0653(4) Uani 1 1 d .
F8 F 0.21892(15) 0.81790(6) 0.1559(2) 0.0792(5) Uani 1 1 d .
F9 F 0.32242(13) 0.73747(8) -0.04123(18) 0.0735(5) Uani 1 1 d .
F10 F 0.25650(10) 0.61024(7) -0.06503(13) 0.0474(3) Uani 1 1 d .
C13 C 0.28918(14) 0.54133(8) 0.40891(18) 0.0289(3) Uani 1 1 d .
C14 C 0.38375(14) 0.53256(8) 0.31718(17) 0.0279(3) Uani 1 1 d .
C15 C 0.44029(13) 0.47133(8) 0.31535(17) 0.0268(3) Uani 1 1 d .
C16 C 0.40412(13) 0.42081(8) 0.40998(17) 0.0259(3) Uani 1 1 d .
C17 C 0.31063(14) 0.43147(8) 0.50144(18) 0.0286(3) Uani 1 1 d .
H17 H 0.2867 0.3968 0.5647 0.034 Uiso 1 1 calc R
C18 C 0.25166(14) 0.49104(8) 0.50277(19) 0.0292(3) Uani 1 1 d .
C19 C 0.42771(17) 0.59066(10) 0.2291(2) 0.0409(4) Uani 1 1 d .
H19A H 0.3819 0.6301 0.2507 0.061 Uiso 1 1 calc R
H19B H 0.4220 0.5803 0.1246 0.061 Uiso 1 1 calc R
H19C H 0.5077 0.5991 0.2547 0.061 Uiso 1 1 calc R
C20 C 0.54031(16) 0.45961(11) 0.2166(2) 0.0418(4) Uani 1 1 d .
H20A H 0.5527 0.4989 0.1555 0.063 Uiso 1 1 calc R
H20B H 0.5249 0.4211 0.1542 0.063 Uiso 1 1 calc R
H20C H 0.6087 0.4512 0.2757 0.063 Uiso 1 1 calc R
C21 C 0.46817(16) 0.35595(9) 0.4190(2) 0.0371(4) Uani 1 1 d .
H21A H 0.5461 0.3642 0.4539 0.056 Uiso 1 1 calc R
H21B H 0.4710 0.3354 0.3220 0.056 Uiso 1 1 calc R
H21C H 0.4290 0.3261 0.4870 0.056 Uiso 1 1 calc R
C22 C 0.15424(17) 0.50288(11) 0.6072(3) 0.0466(5) Uani 1 1 d .
H22A H 0.0988 0.4667 0.5986 0.070 Uiso 1 1 calc R
H22B H 0.1169 0.5451 0.5833 0.070 Uiso 1 1 calc R
H22C H 0.1837 0.5046 0.7074 0.070 Uiso 1 1 calc R
H13 H 0.2486(18) 0.5855(11) 0.413(2) 0.039(6) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ag1 C7 164.51(6) . .
C1 Ag1 Ag2 52.02(4) . .
C7 Ag1 Ag2 116.03(4) . .
C1 Ag1 Ag2 116.68(4) . 3_565
C7 Ag1 Ag2 51.37(4) . 3_565
Ag2 Ag1 Ag2 64.932(5) . 3_565
C7 Ag2 C1 144.90(5) 3_565 .
C7 Ag2 Ag1 164.54(4) 3_565 .
C1 Ag2 Ag1 50.11(4) . .
C7 Ag2 Ag1 50.39(4) 3_565 3_565
C1 Ag2 Ag1 164.28(4) . 3_565
Ag1 Ag2 Ag1 115.068(5) . 3_565
C7 Ag2 Ag2 107.47(4) 3_565 3_565
C1 Ag2 Ag2 107.63(4) . 3_565
Ag1 Ag2 Ag2 57.754(4) . 3_565
Ag1 Ag2 Ag2 57.313(4) 3_565 3_565
C6 C1 C2 115.02(14) . .
C6 C1 Ag1 122.59(12) . .
C2 C1 Ag1 115.47(11) . .
C6 C1 Ag2 108.27(10) . .
C2 C1 Ag2 110.00(10) . .
Ag1 C1 Ag2 77.87(5) . .
F1 C2 C3 116.71(15) . .
F1 C2 C1 119.62(14) . .
C3 C2 C1 123.66(16) . .
F2 C3 C2 121.64(17) . .
F2 C3 C4 119.78(15) . .
C2 C3 C4 118.58(16) . .
F3 C4 C5 120.24(17) . .
F3 C4 C3 119.56(18) . .
C5 C4 C3 120.19(14) . .
F4 C5 C4 119.98(15) . .
F4 C5 C6 120.76(17) . .
C4 C5 C6 119.26(16) . .
F5 C6 C5 116.92(15) . .
F5 C6 C1 119.84(14) . .
C5 C6 C1 123.23(16) . .
C12 C7 C8 114.82(15) . .
C12 C7 Ag1 114.11(12) . .
C8 C7 Ag1 122.63(12) . .
C12 C7 Ag2 110.94(11) . 3_565
C8 C7 Ag2 109.50(11) . 3_565
Ag1 C7 Ag2 78.24(5) . 3_565
F6 C8 C9 117.21(17) . .
F6 C8 C7 119.91(15) . .
C9 C8 C7 122.87(18) . .
F7 C9 C10 120.18(18) . .
F7 C9 C8 120.0(2) . .
C10 C9 C8 119.80(19) . .
F8 C10 C11 120.1(2) . .
F8 C10 C9 120.1(2) . .
C11 C10 C9 119.74(17) . .
F9 C11 C10 120.13(19) . .
F9 C11 C12 120.6(2) . .
C10 C11 C12 119.22(19) . .
F10 C12 C11 117.34(17) . .
F10 C12 C7 119.12(15) . .
C11 C12 C7 123.54(18) . .
C18 C13 C14 121.69(15) . .
C18 C13 H13 117.8(12) . .
C14 C13 H13 120.4(12) . .
C15 C14 C13 119.47(15) . .
C15 C14 C19 120.96(17) . .
C13 C14 C19 119.46(16) . .
C14 C15 C16 119.27(15) . .
C14 C15 C20 121.05(16) . .
C16 C15 C20 119.67(16) . .
C17 C16 C15 119.77(14) . .
C17 C16 C21 119.38(16) . .
C15 C16 C21 120.80(16) . .
C18 C17 C16 122.02(16) . .
C18 C17 H17 119.0 . .
C16 C17 H17 119.0 . .
C17 C18 C13 117.73(16) . .
C17 C18 C22 121.35(17) . .
C13 C18 C22 120.84(16) . .
C14 C19 H19A 109.5 . .
C14 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
C14 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
C15 C20 H20A 109.5 . .
C15 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C15 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C16 C21 H21A 109.5 . .
C16 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C16 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
C18 C22 H22A 109.5 . .
C18 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C18 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C1 2.1831(15) .
Ag1 C7 2.1999(15) .
Ag1 Ag2 2.78190(15) .
Ag1 Ag2 2.79556(15) 3_565
Ag2 C7 2.2305(14) 3_565
Ag2 C1 2.2428(14) .
Ag2 Ag1 2.79556(15) 3_565
Ag2 Ag2 2.9940(2) 3_565
C1 C6 1.387(2) .
C1 C2 1.388(2) .
C2 F1 1.346(2) .
C2 C3 1.379(2) .
C3 F2 1.337(2) .
C3 C4 1.386(3) .
C4 F3 1.3368(18) .
C4 C5 1.368(3) .
C5 F4 1.344(2) .
C5 C6 1.383(2) .
C6 F5 1.344(2) .
C7 C12 1.387(2) .
C7 C8 1.388(2) .
C7 Ag2 2.2305(14) 3_565
C8 F6 1.343(2) .
C8 C9 1.384(2) .
C9 F7 1.348(2) .
C9 C10 1.370(3) .
C10 F8 1.332(2) .
C10 C11 1.368(3) .
C11 F9 1.347(2) .
C11 C12 1.383(3) .
C12 F10 1.344(2) .
C13 C18 1.400(3) .
C13 C14 1.402(2) .
C13 H13 1.01(2) .
C14 C15 1.401(2) .
C14 C19 1.513(2) .
C15 C16 1.403(2) .
C15 C20 1.499(2) .
C16 C17 1.396(2) .
C16 C21 1.509(2) .
C17 C18 1.385(2) .
C17 H17 0.9500 .
C18 C22 1.509(3) .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9800 .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C21 H21A 0.9800 .
C21 H21B 0.9800 .
C21 H21C 0.9800 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C1 Ag1 Ag2 C7 167.88(17) . 3_565
C7 Ag1 Ag2 C7 -23.8(2) . 3_565
Ag2 Ag1 Ag2 C7 -18.36(17) 3_565 3_565
C7 Ag1 Ag2 C1 168.32(8) . .
Ag2 Ag1 Ag2 C1 173.76(6) 3_565 .
C1 Ag1 Ag2 Ag1 -173.76(6) . 3_565
C7 Ag1 Ag2 Ag1 -5.44(5) . 3_565
Ag2 Ag1 Ag2 Ag1 0.0 3_565 3_565
C1 Ag1 Ag2 Ag2 -173.76(6) . 3_565
C7 Ag1 Ag2 Ag2 -5.44(5) . 3_565
C7 Ag1 C1 C6 -147.0(2) . .
Ag2 Ag1 C1 C6 -104.07(13) . .
Ag2 Ag1 C1 C6 -110.40(11) 3_565 .
C7 Ag1 C1 C2 63.7(3) . .
Ag2 Ag1 C1 C2 106.57(12) . .
Ag2 Ag1 C1 C2 100.25(10) 3_565 .
C7 Ag1 C1 Ag2 -42.9(2) . .
Ag2 Ag1 C1 Ag2 -6.32(6) 3_565 .
C7 Ag2 C1 C6 -53.80(16) 3_565 .
Ag1 Ag2 C1 C6 120.61(13) . .
Ag1 Ag2 C1 C6 141.91(12) 3_565 .
Ag2 Ag2 C1 C6 126.14(10) 3_565 .
C7 Ag2 C1 C2 72.64(15) 3_565 .
Ag1 Ag2 C1 C2 -112.95(12) . .
Ag1 Ag2 C1 C2 -91.65(18) 3_565 .
Ag2 Ag2 C1 C2 -107.41(10) 3_565 .
C7 Ag2 C1 Ag1 -174.41(8) 3_565 .
Ag1 Ag2 C1 Ag1 21.30(18) 3_565 .
Ag2 Ag2 C1 Ag1 5.53(5) 3_565 .
C6 C1 C2 F1 -179.23(14) . .
Ag1 C1 C2 F1 -27.52(18) . .
Ag2 C1 C2 F1 58.22(16) . .
C6 C1 C2 C3 0.3(2) . .
Ag1 C1 C2 C3 152.03(13) . .
Ag2 C1 C2 C3 -122.23(14) . .
F1 C2 C3 F2 1.6(2) . .
C1 C2 C3 F2 -177.98(15) . .
F1 C2 C3 C4 -178.61(14) . .
C1 C2 C3 C4 1.8(2) . .
F2 C3 C4 F3 -1.6(2) . .
C2 C3 C4 F3 178.58(15) . .
F2 C3 C4 C5 177.29(15) . .
C2 C3 C4 C5 -2.5(2) . .
F3 C4 C5 F4 -0.1(2) . .
C3 C4 C5 F4 -179.00(15) . .
F3 C4 C5 C6 179.97(15) . .
C3 C4 C5 C6 1.1(2) . .
F4 C5 C6 F5 -0.1(2) . .
C4 C5 C6 F5 179.85(14) . .
F4 C5 C6 C1 -178.70(15) . .
C4 C5 C6 C1 1.2(2) . .
C2 C1 C6 F5 179.53(13) . .
Ag1 C1 C6 F5 30.05(19) . .
Ag2 C1 C6 F5 -57.00(16) . .
C2 C1 C6 C5 -1.9(2) . .
Ag1 C1 C6 C5 -151.35(13) . .
Ag2 C1 C6 C5 121.61(14) . .
C1 Ag1 C7 C12 -64.9(3) . .
Ag2 Ag1 C7 C12 -101.56(11) . .
Ag2 Ag1 C7 C12 -107.87(12) 3_565 .
C1 Ag1 C7 C8 148.7(2) . .
Ag2 Ag1 C7 C8 112.07(12) . .
Ag2 Ag1 C7 C8 105.76(14) 3_565 .
C1 Ag1 C7 Ag2 43.0(2) . 3_565
Ag2 Ag1 C7 Ag2 6.31(6) . 3_565
C12 C7 C8 F6 179.66(14) . .
Ag1 C7 C8 F6 -34.2(2) . .
Ag2 C7 C8 F6 54.10(17) 3_565 .
C12 C7 C8 C9 0.2(2) . .
Ag1 C7 C8 C9 146.32(14) . .
Ag2 C7 C8 C9 -125.39(15) 3_565 .
F6 C8 C9 F7 -1.2(2) . .
C7 C8 C9 F7 178.32(15) . .
F6 C8 C9 C10 179.69(16) . .
C7 C8 C9 C10 -0.8(3) . .
F7 C9 C10 F8 -0.1(3) . .
C8 C9 C10 F8 179.05(16) . .
F7 C9 C10 C11 -178.80(16) . .
C8 C9 C10 C11 0.3(3) . .
F8 C10 C11 F9 0.7(3) . .
C9 C10 C11 F9 179.47(17) . .
F8 C10 C11 C12 -177.98(17) . .
C9 C10 C11 C12 0.7(3) . .
F9 C11 C12 F10 -0.3(3) . .
C10 C11 C12 F10 178.44(16) . .
F9 C11 C12 C7 179.84(16) . .
C10 C11 C12 C7 -1.4(3) . .
C8 C7 C12 F10 -178.92(14) . .
Ag1 C7 C12 F10 32.00(18) . .
Ag2 C7 C12 F10 -54.11(17) 3_565 .
C8 C7 C12 C11 1.0(2) . .
Ag1 C7 C12 C11 -148.12(14) . .
Ag2 C7 C12 C11 125.77(15) 3_565 .
C18 C13 C14 C15 2.1(2) . .
C18 C13 C14 C19 -173.99(14) . .
C13 C14 C15 C16 -2.7(2) . .
C19 C14 C15 C16 173.37(14) . .
C13 C14 C15 C20 178.81(14) . .
C19 C14 C15 C20 -5.1(2) . .
C14 C15 C16 C17 1.8(2) . .
C20 C15 C16 C17 -179.66(15) . .
C14 C15 C16 C21 -175.53(14) . .
C20 C15 C16 C21 3.0(2) . .
C15 C16 C17 C18 -0.3(2) . .
C21 C16 C17 C18 177.07(15) . .
C16 C17 C18 C13 -0.3(2) . .
C16 C17 C18 C22 -177.14(16) . .
C14 C13 C18 C17 -0.6(2) . .
C14 C13 C18 C22 176.24(16) . .
