#------------------------------------------------------------------------------
#$Date: 2019-11-24 07:31:22 +0200 (Sun, 24 Nov 2019) $
#$Revision: 237131 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/08/79/4087930.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4087930
loop_
_publ_author_name
'Wang, Lin'
'Sun, Hongjian'
'Li, Xiaoyan'
_publ_section_title
;
 Imine Nitrogen Bridged Binuclear Nickel Complexes via N--H Bond
 Activation: Synthesis, Characterization, Unexpected C,N-Coupling
 Reaction, and Their Catalytic Application in Hydrosilylation of Aldehydes
;
_journal_issue                   20
_journal_name_full               Organometallics
_journal_page_first              5175
_journal_paper_doi               10.1021/acs.organomet.5b00734
_journal_volume                  34
_journal_year                    2015
_chemical_formula_sum            'C36 H44 F4 N2 Ni2 P2'
_chemical_formula_weight         760.09
_space_group_IT_number           13
_space_group_name_Hall           '-P 2yc'
_space_group_name_H-M_alt        'P 1 2/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 106.919(8)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   21.281(10)
_cell_length_b                   9.058(4)
_cell_length_c                   19.919(9)
_cell_measurement_reflns_used    1698
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      21.189
_cell_measurement_theta_min      2.461
_cell_volume                     3673(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0776
_diffrn_reflns_av_unetI/netI     0.1008
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            17486
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.00
_exptl_absorpt_coefficient_mu    1.159
_exptl_absorpt_correction_T_max  0.8929
_exptl_absorpt_correction_T_min  0.8453
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.374
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1584
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.327
_refine_diff_density_min         -0.542
_refine_diff_density_rms         0.109
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     423
_refine_ls_number_reflns         6425
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.056
_refine_ls_R_factor_all          0.1256
_refine_ls_R_factor_gt           0.0717
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0706P)²+10.6200P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1664
_refine_ls_wR_factor_ref         0.1927
_reflns_number_gt                3839
_reflns_number_total             6425
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om5b00734_si_002.cif
_cod_data_source_block           complex11
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_H-M      'P2/c  '
_cod_database_code               4087930
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ni1 Ni 0.50285(4) 0.72751(9) 0.18645(4) 0.0270(3) Uani 1 1 d .
Ni2 Ni 0.00774(4) 0.75447(9) 0.31642(4) 0.0277(3) Uani 1 1 d .
P1 P 0.43410(10) 0.8633(2) 0.11402(10) 0.0340(5) Uani 1 1 d .
P2 P -0.05772(10) 0.6178(2) 0.35120(10) 0.0334(5) Uani 1 1 d .
F1 F 0.2973(2) 0.6667(5) 0.2550(2) 0.0482(11) Uani 1 1 d .
F2 F 0.4306(2) 0.2538(4) 0.2607(2) 0.0507(12) Uani 1 1 d .
F3 F 0.2108(2) 0.8156(5) 0.3667(2) 0.0543(13) Uani 1 1 d .
F4 F 0.0729(2) 1.2281(5) 0.2983(2) 0.0529(13) Uani 1 1 d .
C1 C 0.4540(5) 1.0558(9) 0.1212(5) 0.079(3) Uani 1 1 d .
H1A H 0.4548 1.0913 0.1679 0.118 Uiso 1 1 calc R
H1B H 0.4209 1.1108 0.0854 0.118 Uiso 1 1 calc R
H1C H 0.4973 1.0707 0.1142 0.118 Uiso 1 1 calc R
C2 C 0.3517(4) 0.8652(12) 0.1245(5) 0.080(3) Uani 1 1 d .
H2A H 0.3319 0.7670 0.1140 0.119 Uiso 1 1 calc R
H2B H 0.3245 0.9376 0.0923 0.119 Uiso 1 1 calc R
H2C H 0.3543 0.8920 0.1729 0.119 Uiso 1 1 calc R
C3 C 0.4190(5) 0.8256(11) 0.0218(4) 0.076(3) Uani 1 1 d .
H3A H 0.4605 0.8307 0.0098 0.115 Uiso 1 1 calc R
H3B H 0.3883 0.8990 -0.0057 0.115 Uiso 1 1 calc R
H3C H 0.4001 0.7267 0.0111 0.115 Uiso 1 1 calc R
C4 C 0.5714(4) 0.8078(9) 0.1500(4) 0.049(2) Uani 1 1 d .
H4A H 0.6137 0.7631 0.1750 0.074 Uiso 1 1 calc R
H4B H 0.5739 0.9150 0.1569 0.074 Uiso 1 1 calc R
H4C H 0.5610 0.7856 0.0998 0.074 Uiso 1 1 calc R
C5 C 0.2614(4) 0.4659(11) 0.1122(5) 0.063(3) Uani 1 1 d .
H5A H 0.2580 0.3874 0.1448 0.095 Uiso 1 1 calc R
H5B H 0.2230 0.4623 0.0706 0.095 Uiso 1 1 calc R
H5C H 0.2631 0.5620 0.1352 0.095 Uiso 1 1 calc R
C6 C 0.3223(4) 0.4444(9) 0.0907(4) 0.052(2) Uani 1 1 d .
C7 C 0.3150(5) 0.3897(9) 0.0223(4) 0.058(2) Uani 1 1 d .
H7 H 0.2728 0.3646 -0.0076 0.069 Uiso 1 1 calc R
C8 C 0.3686(6) 0.3738(10) 0.0000(5) 0.065(3) Uani 1 1 d .
H8 H 0.3629 0.3410 -0.0467 0.077 Uiso 1 1 calc R
C9 C 0.4315(5) 0.4029(9) 0.0420(5) 0.059(3) Uani 1 1 d .
H9 H 0.4683 0.3886 0.0249 0.071 Uiso 1 1 calc R
C10 C 0.4395(5) 0.4526(8) 0.1085(4) 0.045(2) Uani 1 1 d .
H10 H 0.4825 0.4712 0.1382 0.054 Uiso 1 1 calc R
C11 C 0.3844(4) 0.4772(8) 0.1345(4) 0.0359(18) Uani 1 1 d .
C12 C 0.3993(3) 0.5389(7) 0.2080(3) 0.0261(16) Uani 1 1 d .
C13 C 0.3671(3) 0.4652(8) 0.2571(3) 0.0311(17) Uani 1 1 d .
C14 C 0.3188(3) 0.5328(8) 0.2812(4) 0.0349(18) Uani 1 1 d .
C15 C 0.2912(4) 0.4670(10) 0.3280(4) 0.049(2) Uani 1 1 d .
H15 H 0.2580 0.5166 0.3424 0.058 Uiso 1 1 calc R
C16 C 0.3116(4) 0.3312(11) 0.3533(4) 0.057(2) Uani 1 1 d .
H16 H 0.2935 0.2868 0.3867 0.069 Uiso 1 1 calc R
C17 C 0.3590(4) 0.2557(10) 0.3310(5) 0.054(2) Uani 1 1 d .
H17 H 0.3731 0.1596 0.3479 0.065 Uiso 1 1 calc R
C18 C 0.3844(4) 0.3250(9) 0.2839(4) 0.0388(19) Uani 1 1 d .
C19 C -0.0347(4) 0.4246(8) 0.3599(5) 0.063(3) Uani 1 1 d .
H19A H -0.0263 0.3905 0.3166 0.095 Uiso 1 1 calc R
H19B H -0.0704 0.3665 0.3685 0.095 Uiso 1 1 calc R
H19C H 0.0052 0.4123 0.3993 0.095 Uiso 1 1 calc R
C20 C -0.1398(4) 0.6060(10) 0.2923(5) 0.059(3) Uani 1 1 d .
H20A H -0.1587 0.7052 0.2832 0.089 Uiso 1 1 calc R
H20B H -0.1670 0.5451 0.3136 0.089 Uiso 1 1 calc R
H20C H -0.1384 0.5612 0.2480 0.089 Uiso 1 1 calc R
C21 C -0.0710(5) 0.6605(10) 0.4347(5) 0.069(3) Uani 1 1 d .
H21A H -0.0287 0.6627 0.4713 0.103 Uiso 1 1 calc R
H21B H -0.0992 0.5848 0.4461 0.103 Uiso 1 1 calc R
H21C H -0.0923 0.7571 0.4320 0.103 Uiso 1 1 calc R
C22 C 0.0810(4) 0.6741(10) 0.3906(4) 0.052(2) Uani 1 1 d .
H22A H 0.1221 0.7197 0.3882 0.077 Uiso 1 1 calc R
H22B H 0.0834 0.5670 0.3845 0.077 Uiso 1 1 calc R
H22C H 0.0745 0.6951 0.4364 0.077 Uiso 1 1 calc R
C23 C 0.2301(6) 1.0106(12) 0.2360(6) 0.083(3) Uani 1 1 d .
H23A H 0.2362 1.0871 0.2721 0.124 Uiso 1 1 calc R
H23B H 0.2651 1.0180 0.2133 0.124 Uiso 1 1 calc R
H23C H 0.2316 0.9130 0.2577 0.124 Uiso 1 1 calc R
C24 C 0.1684(6) 1.0302(10) 0.1852(6) 0.066(3) Uani 1 1 d .
C25 C 0.1712(7) 1.0805(10) 0.1142(7) 0.089(4) Uani 1 1 d .
H25 H 0.2111 1.0965 0.1031 0.107 Uiso 1 1 calc R
C26 C 0.1100(7) 1.1012(11) 0.0667(7) 0.079(3) Uani 1 1 d U
H26 H 0.1095 1.1375 0.0218 0.095 Uiso 1 1 calc R
C27 C 0.0492(7) 1.0751(11) 0.0770(6) 0.092(4) Uani 1 1 d U
H27 H 0.0098 1.0882 0.0400 0.110 Uiso 1 1 calc R
C28 C 0.0478(6) 1.0309(8) 0.1404(4) 0.068(3) Uani 1 1 d U
H28 H 0.0070 1.0186 0.1501 0.081 Uiso 1 1 calc R
C29 C 0.1109(4) 1.0009(7) 0.1965(4) 0.040(2) Uani 1 1 d U
C30 C 0.1008(3) 0.9416(7) 0.2623(3) 0.0285(16) Uani 1 1 d .
C31 C 0.1383(3) 1.0142(7) 0.3301(3) 0.0269(16) Uani 1 1 d .
C32 C 0.1901(4) 0.9512(8) 0.3809(4) 0.0378(18) Uani 1 1 d .
C33 C 0.2211(4) 1.0148(9) 0.4455(4) 0.049(2) Uani 1 1 d .
H33 H 0.2546 0.9636 0.4796 0.059 Uiso 1 1 calc R
C34 C 0.2019(4) 1.1527(10) 0.4584(4) 0.052(2) Uani 1 1 d .
H34 H 0.2234 1.2000 0.5016 0.062 Uiso 1 1 calc R
C35 C 0.1513(4) 1.2254(9) 0.4093(4) 0.047(2) Uani 1 1 d .
H35 H 0.1375 1.3211 0.4185 0.057 Uiso 1 1 calc R
C36 C 0.1219(4) 1.1545(8) 0.3470(4) 0.0397(19) Uani 1 1 d .
N1 N 0.4413(3) 0.6403(6) 0.2295(3) 0.0286(13) Uani 1 1 d .
N2 N 0.0586(3) 0.8429(6) 0.2615(3) 0.0289(13) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ni1 N1 76.8(3) 2_655 .
N1 Ni1 C4 98.0(3) 2_655 .
N1 Ni1 C4 174.7(3) . .
N1 Ni1 P1 163.92(18) 2_655 .
N1 Ni1 P1 96.68(17) . .
C4 Ni1 P1 88.5(2) . .
N1 Ni1 Ni1 48.30(17) 2_655 2_655
N1 Ni1 Ni1 47.94(16) . 2_655
C4 Ni1 Ni1 128.5(3) . 2_655
P1 Ni1 Ni1 116.66(7) . 2_655
N2 Ni2 N2 76.8(3) . 2
N2 Ni2 C22 97.4(3) . .
N2 Ni2 C22 174.2(3) 2 .
N2 Ni2 P2 163.53(17) . .
N2 Ni2 P2 96.20(17) 2 .
C22 Ni2 P2 89.5(3) . .
N2 Ni2 Ni2 48.62(16) . 2
N2 Ni2 Ni2 48.01(17) 2 2
C22 Ni2 Ni2 127.9(3) . 2
P2 Ni2 Ni2 115.85(7) . 2
C1 P1 C3 103.5(5) . .
C1 P1 C2 101.2(5) . .
C3 P1 C2 103.1(5) . .
C1 P1 Ni1 114.2(3) . .
C3 P1 Ni1 117.8(3) . .
C2 P1 Ni1 115.0(3) . .
C20 P2 C21 103.3(5) . .
C20 P2 C19 100.9(4) . .
C21 P2 C19 103.2(5) . .
C20 P2 Ni2 115.2(3) . .
C21 P2 Ni2 117.9(3) . .
C19 P2 Ni2 114.1(3) . .
P1 C1 H1A 109.5 . .
P1 C1 H1B 109.5 . .
H1A C1 H1B 109.5 . .
P1 C1 H1C 109.5 . .
H1A C1 H1C 109.5 . .
H1B C1 H1C 109.5 . .
P1 C2 H2A 109.5 . .
P1 C2 H2B 109.5 . .
H2A C2 H2B 109.5 . .
P1 C2 H2C 109.5 . .
H2A C2 H2C 109.5 . .
H2B C2 H2C 109.5 . .
P1 C3 H3A 109.5 . .
P1 C3 H3B 109.5 . .
H3A C3 H3B 109.5 . .
P1 C3 H3C 109.5 . .
H3A C3 H3C 109.5 . .
H3B C3 H3C 109.5 . .
Ni1 C4 H4A 109.5 . .
Ni1 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
Ni1 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
C6 C5 H5A 109.5 . .
C6 C5 H5B 109.5 . .
H5A C5 H5B 109.5 . .
C6 C5 H5C 109.5 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
C11 C6 C7 119.8(9) . .
C11 C6 C5 122.7(8) . .
C7 C6 C5 117.5(8) . .
C8 C7 C6 119.3(9) . .
C8 C7 H7 120.3 . .
C6 C7 H7 120.3 . .
C7 C8 C9 123.0(9) . .
C7 C8 H8 118.5 . .
C9 C8 H8 118.5 . .
C10 C9 C8 118.5(9) . .
C10 C9 H9 120.8 . .
C8 C9 H9 120.8 . .
C9 C10 C11 121.4(9) . .
C9 C10 H10 119.3 . .
C11 C10 H10 119.3 . .
C6 C11 C10 118.0(7) . .
C6 C11 C12 125.5(7) . .
C10 C11 C12 116.5(7) . .
N1 C12 C13 120.9(6) . .
N1 C12 C11 121.5(6) . .
C13 C12 C11 117.3(6) . .
C18 C13 C14 114.0(7) . .
C18 C13 C12 122.6(7) . .
C14 C13 C12 123.4(6) . .
F1 C14 C15 119.3(7) . .
F1 C14 C13 117.5(7) . .
C15 C14 C13 123.1(7) . .
C16 C15 C14 119.6(8) . .
C16 C15 H15 120.2 . .
C14 C15 H15 120.2 . .
C15 C16 C17 120.7(8) . .
C15 C16 H16 119.6 . .
C17 C16 H16 119.6 . .
C18 C17 C16 117.5(8) . .
C18 C17 H17 121.3 . .
C16 C17 H17 121.3 . .
C17 C18 F2 118.9(7) . .
C17 C18 C13 125.0(8) . .
F2 C18 C13 116.0(7) . .
P2 C19 H19A 109.5 . .
P2 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
P2 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
P2 C20 H20A 109.5 . .
P2 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
P2 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
P2 C21 H21A 109.5 . .
P2 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
P2 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
Ni2 C22 H22A 109.5 . .
Ni2 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
Ni2 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C24 C23 H23A 109.5 . .
C24 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C24 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C29 C24 C23 124.0(10) . .
C29 C24 C25 120.5(11) . .
C23 C24 C25 115.4(10) . .
C26 C25 C24 113.5(11) . .
C26 C25 H25 123.2 . .
C24 C25 H25 123.2 . .
C25 C26 C27 127.4(12) . .
C25 C26 H26 116.3 . .
C27 C26 H26 116.3 . .
C28 C27 C26 118.1(12) . .
C28 C27 H27 120.9 . .
C26 C27 H27 120.9 . .
C27 C28 C29 119.8(11) . .
C27 C28 H28 120.1 . .
C29 C28 H28 120.1 . .
C24 C29 C30 126.5(9) . .
C24 C29 C28 120.4(8) . .
C30 C29 C28 113.1(7) . .
N2 C30 C29 121.9(6) . .
N2 C30 C31 120.6(6) . .
C29 C30 C31 117.3(6) . .
C36 C31 C32 113.8(6) . .
C36 C31 C30 120.9(6) . .
C32 C31 C30 125.2(6) . .
F3 C32 C31 117.1(6) . .
F3 C32 C33 118.2(7) . .
C31 C32 C33 124.6(7) . .
C34 C33 C32 118.0(8) . .
C34 C33 H33 121.0 . .
C32 C33 H33 121.0 . .
C33 C34 C35 120.9(8) . .
C33 C34 H34 119.6 . .
C35 C34 H34 119.6 . .
C36 C35 C34 118.0(7) . .
C36 C35 H35 121.0 . .
C34 C35 H35 121.0 . .
F4 C36 C35 117.6(7) . .
F4 C36 C31 117.8(6) . .
C35 C36 C31 124.5(7) . .
C12 N1 Ni1 142.2(5) . 2_655
C12 N1 Ni1 130.6(5) . .
Ni1 N1 Ni1 83.8(2) 2_655 .
C30 N2 Ni2 143.4(5) . .
C30 N2 Ni2 130.6(5) . 2
Ni2 N2 Ni2 83.4(2) . 2
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ni1 N1 1.919(5) 2_655
Ni1 N1 1.930(6) .
Ni1 C4 1.949(7) .
Ni1 P1 2.123(2) .
Ni1 Ni1 2.570(2) 2_655
Ni2 N2 1.923(6) .
Ni2 N2 1.941(5) 2
Ni2 C22 1.951(7) .
Ni2 P2 2.125(2) .
Ni2 Ni2 2.570(2) 2
P1 C1 1.791(8) .
P1 C3 1.803(8) .
P1 C2 1.826(9) .
P2 C20 1.802(8) .
P2 C21 1.809(9) .
P2 C19 1.812(8) .
F1 C14 1.347(8) .
F2 C18 1.365(8) .
F3 C32 1.362(8) .
F4 C36 1.373(8) .
C1 H1A 0.9800 .
C1 H1B 0.9800 .
C1 H1C 0.9800 .
C2 H2A 0.9800 .
C2 H2B 0.9800 .
C2 H2C 0.9800 .
C3 H3A 0.9800 .
C3 H3B 0.9800 .
C3 H3C 0.9800 .
C4 H4A 0.9800 .
C4 H4B 0.9800 .
C4 H4C 0.9800 .
C5 C6 1.491(12) .
C5 H5A 0.9800 .
C5 H5B 0.9800 .
C5 H5C 0.9800 .
C6 C11 1.389(11) .
C6 C7 1.415(11) .
C7 C8 1.346(13) .
C7 H7 0.9500 .
C8 C9 1.382(13) .
C8 H8 0.9500 .
C9 C10 1.362(11) .
C9 H9 0.9500 .
C10 C11 1.430(11) .
C10 H10 0.9500 .
C11 C12 1.512(9) .
C12 N1 1.266(8) .
C12 C13 1.503(10) .
C13 C18 1.385(10) .
C13 C14 1.397(10) .
C14 C15 1.372(11) .
C15 C16 1.352(12) .
C15 H15 0.9500 .
C16 C17 1.394(12) .
C16 H16 0.9500 .
C17 C18 1.364(11) .
C17 H17 0.9500 .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9800 .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C21 H21A 0.9800 .
C21 H21B 0.9800 .
C21 H21C 0.9800 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 C24 1.415(14) .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
C24 C29 1.334(12) .
C24 C25 1.503(14) .
C25 C26 1.383(15) .
C25 H25 0.9500 .
C26 C27 1.387(16) .
C26 H26 0.9500 .
C27 C28 1.334(13) .
C27 H27 0.9500 .
C28 C29 1.501(13) .
C28 H28 0.9500 .
C29 C30 1.490(10) .
C30 N2 1.265(8) .
C30 C31 1.505(9) .
C31 C36 1.385(10) .
C31 C32 1.385(9) .
C32 C33 1.388(10) .
C33 C34 1.362(11) .
C33 H33 0.9500 .
C34 C35 1.392(11) .
C34 H34 0.9500 .
C35 C36 1.375(10) .
C35 H35 0.9500 .
N1 Ni1 1.919(5) 2_655
N2 Ni2 1.941(5) 2
