#------------------------------------------------------------------------------
#$Date: 2019-11-24 12:11:00 +0200 (Sun, 24 Nov 2019) $
#$Revision: 237879 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/08/89/4088915.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4088915
loop_
_publ_author_name
'Santschi, Nico'
'Thiehoff, Christian'
'Holland, Mareike C.'
'Daniliuc, Constantin G.'
'Houk, K. N.'
'Gilmour, Ryan'
_publ_section_title
;
 The Sulfur--Fluorine Gauche Effect in Coinage-Metal Complexes: Augmenting
 Conformational Equilibria by Complexation
;
_journal_issue                   17
_journal_name_full               Organometallics
_journal_page_first              3040
_journal_paper_doi               10.1021/acs.organomet.6b00564
_journal_volume                  35
_journal_year                    2016
_chemical_absolute_configuration ad
_chemical_formula_sum            'C34 H34 Ag2 F14 S2 Sb2'
_chemical_formula_weight         1231.97
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_Hall           'P 2ac 2ab'
_space_group_name_H-M_alt        'P 21 21 21'
_atom_sites_solution_hydrogens   geom
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   17.4030(7)
_cell_length_b                   14.0758(6)
_cell_length_c                   15.9506(6)
_cell_measurement_reflns_used    9626
_cell_measurement_temperature    100.(2)
_cell_measurement_theta_max      27.5710
_cell_measurement_theta_min      2.6664
_cell_volume                     3907.3(3)
_computing_cell_refinement       'SAINT V8.34A (Bruker AXS Inc., 2013)'
_computing_data_collection
;
APEX2 v.2014.1-1 (Bruker AXS Inc., 2014)

;
_computing_data_reduction        'SAINT V8.34A (Bruker AXS Inc., 2013)'
_computing_molecular_graphics    'XP (Sheldrick, 2014)'
_computing_publication_material  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXL-2014 (Sheldrick, 2014)'
_diffrn_ambient_temperature      100.(2)
_diffrn_detector_area_resol_mean 10.4167
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker D8 Venture PHOTON 100 CMOS'
_diffrn_measurement_method       'omega and phi scans'
_diffrn_radiation_monochromator  'MX mirror'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0391
_diffrn_reflns_av_unetI/netI     0.0122
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            168450
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         2.26
_diffrn_source                   'Mo ImS'
_diffrn_source_type              'micro focus tube'
_exptl_absorpt_coefficient_mu    2.555
_exptl_absorpt_correction_T_max  0.73
_exptl_absorpt_correction_T_min  0.66
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
Bruker AXS (2014). SADABS, Version 2014/2, Bruker AXS Inc., Madison, Wisconsin,
USA.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.094
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2368
_exptl_crystal_size_max          0.285
_exptl_crystal_size_mid          0.226
_exptl_crystal_size_min          0.132
_refine_diff_density_max         1.556
_refine_diff_density_min         -0.981
_refine_ls_abs_structure_details
;
Flack x determined using 3474 quotients [(I+)-(I-)]/[(I+)+(I-)]
(Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.024(4)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.210
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     487
_refine_ls_number_reflns         7980
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.210
_refine_ls_R_factor_all          0.0305
_refine_ls_R_factor_gt           0.0302
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0205P)²+22.2010P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0755
_refine_ls_wR_factor_ref         0.0756
_reflns_number_gt                7915
_reflns_number_total             7980
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            om6b00564_si_003.cif
_cod_data_source_block           gil8183
_cod_database_code               4088915
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_posn
_atom_site_occupancy
Ag Ag1 0.37814(3) 0.48661(4) 0.51150(3) 0.01730(12) Uani d . . 1
Ag Ag2 0.25022(4) 0.47859(6) 0.26965(4) 0.02897(17) Uani d . . 1
S S1 0.33325(10) 0.44385(12) 0.66061(11) 0.0112(3) Uani d . . 1
S S2 0.35619(9) 0.42990(13) 0.36781(11) 0.0099(3) Uani d . . 1
F F1 0.4879(3) 0.5216(4) 0.5957(3) 0.0260(10) Uani d . . 1
F F2 0.3728(3) 0.5308(4) 0.1984(3) 0.0303(11) Uani d . . 1
C C1 0.4273(4) 0.4436(5) 0.7150(4) 0.0110(13) Uani d . . 1
H H1 0.4175 0.451 0.7764 0.013 Uiso calc U R 1
C C2 0.4630(4) 0.3441(5) 0.7005(5) 0.0152(15) Uani d . . 1
H H2A 0.5157 0.3511 0.6781 0.018 Uiso calc U R 1
H H2B 0.4661 0.3096 0.7544 0.018 Uiso calc U R 1
C C3 0.4140(5) 0.2877(6) 0.6386(5) 0.0170(16) Uani d . . 1
H H3A 0.4216 0.2187 0.6472 0.02 Uiso calc U R 1
H H3B 0.4287 0.3036 0.5803 0.02 Uiso calc U R 1
C C4 0.3297(4) 0.3143(5) 0.6542(5) 0.0164(15) Uani d . . 1
H H4A 0.3106 0.2862 0.7072 0.02 Uiso calc U R 1
H H4B 0.2964 0.2931 0.6074 0.02 Uiso calc U R 1
C C5 0.4726(4) 0.5308(5) 0.6851(4) 0.0114(13) Uani d . . 1
C C11 0.4437(4) 0.4379(5) 0.3011(4) 0.0091(13) Uani d . . 1
H H11 0.4896 0.4413 0.3386 0.011 Uiso calc U R 1
C C12 0.4472(4) 0.3433(5) 0.2518(4) 0.0118(14) Uani d . . 1
H H12A 0.4459 0.3568 0.1909 0.014 Uiso calc U R 1
H H12B 0.4961 0.3104 0.2645 0.014 Uiso calc U R 1
C C13 0.3802(5) 0.2788(5) 0.2746(5) 0.0200(15) Uani d . . 1
H H13A 0.3953 0.2114 0.2685 0.024 Uiso calc U R 1
H H13B 0.336 0.2914 0.2371 0.024 Uiso calc U R 1
C C14 0.3586(5) 0.2998(5) 0.3651(5) 0.0190(16) Uani d . . 1
H H14A 0.3975 0.2744 0.4044 0.023 Uiso calc U R 1
H H14B 0.3077 0.2725 0.3792 0.023 Uiso calc U R 1
C C15 0.4406(4) 0.5297(5) 0.2482(4) 0.0124(14) Uani d . . 1
C C21 0.5491(4) 0.5419(5) 0.7308(5) 0.0144(15) Uani d . . 1
C C22 0.5650(5) 0.5007(6) 0.8078(5) 0.0183(16) Uani d . . 1
H H22 0.5273 0.463 0.8351 0.022 Uiso calc U R 1
C C23 0.6368(5) 0.5149(6) 0.8452(6) 0.0277(19) Uani d . . 1
H H23 0.6479 0.4871 0.8981 0.033 Uiso calc U R 1
C C24 0.6921(5) 0.5699(6) 0.8046(6) 0.027(2) Uani d . . 1
H H24 0.7413 0.5777 0.8294 0.032 Uiso calc U R 1
C C25 0.6764(5) 0.6125(6) 0.7296(6) 0.0270(19) Uani d . . 1
H H25 0.7142 0.6511 0.7034 0.032 Uiso calc U R 1
C C26 0.6053(4) 0.5997(6) 0.6917(6) 0.0201(17) Uani d . . 1
H H26 0.5943 0.6296 0.6397 0.024 Uiso calc U R 1
C C31 0.4228(4) 0.6188(5) 0.6971(5) 0.0120(14) Uani d . . 1
C C32 0.3929(4) 0.6395(5) 0.7766(5) 0.0130(14) Uani d . . 1
H H32 0.4069 0.6018 0.8237 0.016 Uiso calc U R 1
C C33 0.3423(5) 0.7161(6) 0.7863(6) 0.0233(18) Uani d . . 1
H H33 0.3213 0.729 0.8401 0.028 Uiso calc U R 1
C C34 0.3222(5) 0.7734(6) 0.7194(6) 0.0250(18) Uani d . . 1
H H34 0.2884 0.8257 0.7268 0.03 Uiso calc U R 1
C C35 0.3523(5) 0.7530(6) 0.6422(6) 0.0265(19) Uani d . . 1
H H35 0.3387 0.7917 0.5957 0.032 Uiso calc U R 1
C C36 0.4019(5) 0.6777(5) 0.6300(5) 0.0169(16) Uani d . . 1
H H36 0.4221 0.6657 0.5757 0.02 Uiso calc U R 1
C C41 0.5120(5) 0.5375(5) 0.1912(4) 0.0148(15) Uani d . . 1
C C42 0.5839(4) 0.5064(5) 0.2162(5) 0.0158(15) Uani d . . 1
H H42 0.5906 0.4777 0.2697 0.019 Uiso calc U R 1
C C43 0.6467(4) 0.5175(6) 0.1620(5) 0.0197(16) Uani d . . 1
H H43 0.6963 0.4969 0.1793 0.024 Uiso calc U R 1
C C44 0.6374(5) 0.5580(6) 0.0838(5) 0.0226(18) Uani d . . 1
H H44 0.6802 0.566 0.0477 0.027 Uiso calc U R 1
C C45 0.5649(5) 0.5869(6) 0.0587(5) 0.0224(17) Uani d . . 1
H H45 0.5581 0.6132 0.0044 0.027 Uiso calc U R 1
C C46 0.5025(5) 0.5781(5) 0.1111(5) 0.0174(15) Uani d . . 1
H H46 0.4533 0.5993 0.0934 0.021 Uiso calc U R 1
C C51 0.4366(4) 0.6160(5) 0.3078(5) 0.0131(14) Uani d . . 1
C C52 0.4943(4) 0.6272(6) 0.3693(5) 0.0159(14) Uani d . . 1
H H52 0.5347 0.582 0.3734 0.019 Uiso calc U R 1
C C53 0.4921(5) 0.7044(5) 0.4238(5) 0.0203(16) Uani d . . 1
H H53 0.531 0.7115 0.4652 0.024 Uiso calc U R 1
C C54 0.4342(5) 0.7706(6) 0.4182(5) 0.0194(16) Uani d . . 1
H H54 0.4335 0.8238 0.4548 0.023 Uiso calc U R 1
C C55 0.3768(5) 0.7590(5) 0.3589(5) 0.0215(17) Uani d . . 1
H H55 0.3359 0.8035 0.3561 0.026 Uiso calc U R 1
C C56 0.3787(5) 0.6823(5) 0.3029(5) 0.0174(15) Uani d . . 1
H H56 0.3398 0.6761 0.2614 0.021 Uiso calc U R 1
Sb Sb1 0.62194(3) 0.33444(4) 0.47642(3) 0.01746(11) Uani d . . 1
F F3 0.5922(4) 0.2214(4) 0.5274(4) 0.0399(14) Uani d . . 1
F F4 0.6176(3) 0.3976(3) 0.5798(3) 0.0243(10) Uani d . . 1
F F5 0.6469(4) 0.4488(5) 0.4256(4) 0.0476(17) Uani d . . 1
F F6 0.6245(4) 0.2766(5) 0.3711(3) 0.0479(16) Uani d . . 1
F F7 0.7253(3) 0.3038(4) 0.4957(3) 0.0325(13) Uani d . . 1
F F8 0.5165(3) 0.3628(5) 0.4633(3) 0.0420(15) Uani d . . 1
Sb Sb2 0.17197(3) 0.62710(4) 0.46197(3) 0.01883(12) Uani d . . 1
F F9 0.2767(3) 0.6201(4) 0.4910(3) 0.0323(12) Uani d . . 1
F F10 0.1988(3) 0.6458(5) 0.3493(3) 0.0396(15) Uani d . . 1
F F11 0.0684(3) 0.6318(6) 0.4307(4) 0.055(2) Uani d . . 1
F F12 0.1441(4) 0.6048(5) 0.5735(3) 0.0460(17) Uani d . . 1
F F13 0.1738(5) 0.4967(4) 0.4404(5) 0.062(2) Uani d . . 1
F F14 0.1724(3) 0.7566(3) 0.4810(4) 0.0360(13) Uani d . . 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
F1 Ag1 S2 . . 135.79(12)
F1 Ag1 S1 . . 76.77(12)
S2 Ag1 S1 . . 137.61(6)
S2 Ag2 S1 . 2_564 166.52(7)
S2 Ag2 F2 . . 74.92(12)
S1 Ag2 F2 2_564 . 92.90(12)
C4 S1 C1 . . 93.1(3)
C4 S1 Ag2 . 2_565 116.9(3)
C1 S1 Ag2 . 2_565 100.8(2)
C4 S1 Ag1 . . 101.1(3)
C1 S1 Ag1 . . 99.5(2)
Ag2 S1 Ag1 2_565 . 135.44(8)
C14 S2 C11 . . 91.6(3)
C14 S2 Ag1 . . 110.1(3)
C11 S2 Ag1 . . 112.7(2)
C14 S2 Ag2 . . 105.9(3)
C11 S2 Ag2 . . 103.2(2)
Ag1 S2 Ag2 . . 127.33(7)
C5 F1 Ag1 . . 115.0(4)
C15 F2 Ag2 . . 116.5(4)
C5 C1 C2 . . 118.1(6)
C5 C1 S1 . . 107.9(5)
C2 C1 S1 . . 106.6(5)
C5 C1 H1 . . 108.0
C2 C1 H1 . . 108.0
S1 C1 H1 . . 108.0
C3 C2 C1 . . 110.0(6)
C3 C2 H2A . . 109.7
C1 C2 H2A . . 109.7
C3 C2 H2B . . 109.7
C1 C2 H2B . . 109.7
H2A C2 H2B . . 108.2
C2 C3 C4 . . 107.6(6)
C2 C3 H3A . . 110.2
C4 C3 H3A . . 110.2
C2 C3 H3B . . 110.2
C4 C3 H3B . . 110.2
H3A C3 H3B . . 108.5
C3 C4 S1 . . 102.7(5)
C3 C4 H4A . . 111.2
S1 C4 H4A . . 111.2
C3 C4 H4B . . 111.2
S1 C4 H4B . . 111.2
H4A C4 H4B . . 109.1
F1 C5 C31 . . 107.4(6)
F1 C5 C21 . . 108.5(5)
C31 C5 C21 . . 110.7(6)
F1 C5 C1 . . 109.1(6)
C31 C5 C1 . . 108.6(5)
C21 C5 C1 . . 112.4(6)
C15 C11 C12 . . 116.4(6)
C15 C11 S2 . . 109.5(5)
C12 C11 S2 . . 105.7(5)
C15 C11 H11 . . 108.3
C12 C11 H11 . . 108.3
S2 C11 H11 . . 108.3
C13 C12 C11 . . 111.2(6)
C13 C12 H12A . . 109.4
C11 C12 H12A . . 109.4
C13 C12 H12B . . 109.4
C11 C12 H12B . . 109.4
H12A C12 H12B . . 108.0
C12 C13 C14 . . 107.5(6)
C12 C13 H13A . . 110.2
C14 C13 H13A . . 110.2
C12 C13 H13B . . 110.2
C14 C13 H13B . . 110.2
H13A C13 H13B . . 108.5
C13 C14 S2 . . 102.8(5)
C13 C14 H14A . . 111.2
S2 C14 H14A . . 111.2
C13 C14 H14B . . 111.2
S2 C14 H14B . . 111.2
H14A C14 H14B . . 109.1
F2 C15 C41 . . 109.8(6)
F2 C15 C11 . . 110.1(6)
C41 C15 C11 . . 110.7(6)
F2 C15 C51 . . 107.3(6)
C41 C15 C51 . . 110.0(6)
C11 C15 C51 . . 108.9(5)
C22 C21 C26 . . 119.5(7)
C22 C21 C5 . . 123.7(7)
C26 C21 C5 . . 116.8(7)
C21 C22 C23 . . 119.7(8)
C21 C22 H22 . . 120.1
C23 C22 H22 . . 120.1
C24 C23 C22 . . 119.8(8)
C24 C23 H23 . . 120.1
C22 C23 H23 . . 120.1
C25 C24 C23 . . 120.9(8)
C25 C24 H24 . . 119.5
C23 C24 H24 . . 119.5
C24 C25 C26 . . 120.1(8)
C24 C25 H25 . . 120.0
C26 C25 H25 . . 120.0
C25 C26 C21 . . 119.9(8)
C25 C26 H26 . . 120.1
C21 C26 H26 . . 120.1
C32 C31 C36 . . 118.1(7)
C32 C31 C5 . . 119.6(7)
C36 C31 C5 . . 122.2(7)
C33 C32 C31 . . 119.5(7)
C33 C32 H32 . . 120.2
C31 C32 H32 . . 120.2
C34 C33 C32 . . 121.5(8)
C34 C33 H33 . . 119.3
C32 C33 H33 . . 119.3
C35 C34 C33 . . 118.4(8)
C35 C34 H34 . . 120.8
C33 C34 H34 . . 120.8
C34 C35 C36 . . 121.7(8)
C34 C35 H35 . . 119.1
C36 C35 H35 . . 119.1
C35 C36 C31 . . 120.6(8)
C35 C36 H36 . . 119.7
C31 C36 H36 . . 119.7
C42 C41 C46 . . 119.7(7)
C42 C41 C15 . . 122.4(6)
C46 C41 C15 . . 118.0(7)
C41 C42 C43 . . 119.5(7)
C41 C42 H42 . . 120.3
C43 C42 H42 . . 120.3
C44 C43 C42 . . 120.7(7)
C44 C43 H43 . . 119.7
C42 C43 H43 . . 119.7
C43 C44 C45 . . 119.4(7)
C43 C44 H44 . . 120.3
C45 C44 H44 . . 120.3
C46 C45 C44 . . 121.1(7)
C46 C45 H45 . . 119.5
C44 C45 H45 . . 119.5
C45 C46 C41 . . 119.7(8)
C45 C46 H46 . . 120.1
C41 C46 H46 . . 120.1
C56 C51 C52 . . 119.0(7)
C56 C51 C15 . . 122.1(7)
C52 C51 C15 . . 118.9(7)
C53 C52 C51 . . 120.1(7)
C53 C52 H52 . . 120.0
C51 C52 H52 . . 120.0
C54 C53 C52 . . 120.5(8)
C54 C53 H53 . . 119.7
C52 C53 H53 . . 119.7
C53 C54 C55 . . 119.5(7)
C53 C54 H54 . . 120.2
C55 C54 H54 . . 120.2
C54 C55 C56 . . 120.7(8)
C54 C55 H55 . . 119.7
C56 C55 H55 . . 119.7
C51 C56 C55 . . 120.2(8)
C51 C56 H56 . . 119.9
C55 C56 H56 . . 119.9
F5 Sb1 F3 . . 177.4(3)
F5 Sb1 F6 . . 88.8(3)
F3 Sb1 F6 . . 91.5(3)
F5 Sb1 F7 . . 92.7(3)
F3 Sb1 F7 . . 89.9(3)
F6 Sb1 F7 . . 91.4(3)
F5 Sb1 F4 . . 89.0(3)
F3 Sb1 F4 . . 90.6(2)
F6 Sb1 F4 . . 177.4(3)
F7 Sb1 F4 . . 90.2(2)
F5 Sb1 F8 . . 89.8(3)
F3 Sb1 F8 . . 87.6(3)
F6 Sb1 F8 . . 90.9(3)
F7 Sb1 F8 . . 176.7(2)
F4 Sb1 F8 . . 87.6(2)
F14 Sb2 F13 . . 178.3(3)
F14 Sb2 F12 . . 90.6(3)
F13 Sb2 F12 . . 90.8(3)
F14 Sb2 F11 . . 90.7(3)
F13 Sb2 F11 . . 90.1(4)
F12 Sb2 F11 . . 90.6(3)
F14 Sb2 F10 . . 91.0(3)
F13 Sb2 F10 . . 87.5(3)
F12 Sb2 F10 . . 178.3(3)
F11 Sb2 F10 . . 88.8(3)
F14 Sb2 F9 . . 90.4(3)
F13 Sb2 F9 . . 88.7(3)
F12 Sb2 F9 . . 90.5(3)
F11 Sb2 F9 . . 178.4(3)
F10 Sb2 F9 . . 90.1(2)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Ag1 F1 . 2.387(5)
Ag1 S2 . 2.4568(18)
Ag1 S1 . 2.5748(18)
Ag2 S2 . 2.5144(18)
Ag2 S1 2_564 2.5153(18)
Ag2 F2 . 2.527(6)
S1 C4 . 1.828(8)
S1 C1 . 1.852(7)
S1 Ag2 2_565 2.5154(18)
S2 C14 . 1.832(8)
S2 C11 . 1.862(7)
F1 C5 . 1.456(8)
F2 C15 . 1.422(9)
C1 C5 . 1.535(10)
C1 C2 . 1.549(10)
C1 H1 . 1.0
C2 C3 . 1.528(11)
C2 H2A . 0.99
C2 H2B . 0.99
C3 C4 . 1.535(10)
C3 H3A . 0.99
C3 H3B . 0.99
C4 H4A . 0.99
C4 H4B . 0.99
C5 C31 . 1.524(10)
C5 C21 . 1.526(10)
C11 C15 . 1.544(9)
C11 C12 . 1.547(9)
C11 H11 . 1.0
C12 C13 . 1.521(11)
C12 H12A . 0.99
C12 H12B . 0.99
C13 C14 . 1.521(11)
C13 H13A . 0.99
C13 H13B . 0.99
C14 H14A . 0.99
C14 H14B . 0.99
C15 C41 . 1.542(10)
C15 C51 . 1.545(10)
C21 C22 . 1.386(11)
C21 C26 . 1.416(11)
C22 C23 . 1.399(12)
C22 H22 . 0.95
C23 C24 . 1.394(14)
C23 H23 . 0.95
C24 C25 . 1.365(14)
C24 H24 . 0.95
C25 C26 . 1.390(12)
C25 H25 . 0.95
C26 H26 . 0.95
C31 C32 . 1.402(10)
C31 C36 . 1.402(11)
C32 C33 . 1.401(11)
C32 H32 . 0.95
C33 C34 . 1.382(13)
C33 H33 . 0.95
C34 C35 . 1.369(14)
C34 H34 . 0.95
C35 C36 . 1.380(12)
C35 H35 . 0.95
C36 H36 . 0.95
C41 C42 . 1.385(11)
C41 C46 . 1.410(10)
C42 C43 . 1.403(11)
C42 H42 . 0.95
C43 C44 . 1.381(12)
C43 H43 . 0.95
C44 C45 . 1.384(12)
C44 H44 . 0.95
C45 C46 . 1.375(11)
C45 H45 . 0.95
C46 H46 . 0.95
C51 C56 . 1.376(11)
C51 C52 . 1.412(11)
C52 C53 . 1.393(11)
C52 H52 . 0.95
C53 C54 . 1.376(12)
C53 H53 . 0.95
C54 C55 . 1.386(13)
C54 H54 . 0.95
C55 C56 . 1.401(11)
C55 H55 . 0.95
C56 H56 . 0.95
Sb1 F5 . 1.854(6)
Sb1 F3 . 1.860(6)
Sb1 F6 . 1.867(5)
Sb1 F7 . 1.875(5)
Sb1 F4 . 1.875(4)
Sb1 F8 . 1.889(5)
Sb2 F14 . 1.848(5)
Sb2 F13 . 1.869(6)
Sb2 F12 . 1.870(5)
Sb2 F11 . 1.871(6)
Sb2 F10 . 1.875(5)
Sb2 F9 . 1.883(5)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion
C4 S1 C1 C5 . 145.3(5)
Ag2 S1 C1 C5 2_565 -96.6(4)
Ag1 S1 C1 C5 . 43.5(5)
C4 S1 C1 C2 . 17.6(5)
Ag2 S1 C1 C2 2_565 135.7(4)
Ag1 S1 C1 C2 . -84.2(4)
C5 C1 C2 C3 . -114.3(7)
S1 C1 C2 C3 . 7.2(7)
C1 C2 C3 C4 . -35.3(8)
C2 C3 C4 S1 . 46.5(7)
C1 S1 C4 C3 . -36.7(5)
Ag2 S1 C4 C3 2_565 -140.5(4)
Ag1 S1 C4 C3 . 63.6(5)
Ag1 F1 C5 C31 . -66.6(6)
Ag1 F1 C5 C21 . 173.7(4)
Ag1 F1 C5 C1 . 50.9(6)
C2 C1 C5 F1 . 57.0(8)
S1 C1 C5 F1 . -63.8(6)
C2 C1 C5 C31 . 173.8(6)
S1 C1 C5 C31 . 53.0(6)
C2 C1 C5 C21 . -63.3(8)
S1 C1 C5 C21 . 175.8(5)
C14 S2 C11 C15 . 149.9(5)
Ag1 S2 C11 C15 . -97.5(5)
Ag2 S2 C11 C15 . 43.1(5)
C14 S2 C11 C12 . 23.8(5)
Ag1 S2 C11 C12 . 136.4(4)
Ag2 S2 C11 C12 . -83.0(4)
C15 C11 C12 C13 . -122.0(7)
S2 C11 C12 C13 . -0.2(7)
C11 C12 C13 C14 . -30.3(8)
C12 C13 C14 S2 . 46.5(7)
C11 S2 C14 C13 . -40.6(6)
Ag1 S2 C14 C13 . -155.6(5)
Ag2 S2 C14 C13 . 63.6(5)
Ag2 F2 C15 C41 . 165.3(4)
Ag2 F2 C15 C11 . 43.2(7)
Ag2 F2 C15 C51 . -75.1(6)
C12 C11 C15 F2 . 62.1(8)
S2 C11 C15 F2 . -57.7(6)
C12 C11 C15 C41 . -59.5(8)
S2 C11 C15 C41 . -179.2(5)
C12 C11 C15 C51 . 179.5(6)
S2 C11 C15 C51 . 59.7(6)
F1 C5 C21 C22 . -141.6(7)
C31 C5 C21 C22 . 100.8(8)
C1 C5 C21 C22 . -20.8(9)
F1 C5 C21 C26 . 40.0(8)
C31 C5 C21 C26 . -77.7(8)
C1 C5 C21 C26 . 160.7(6)
C26 C21 C22 C23 . -1.4(11)
C5 C21 C22 C23 . -179.9(7)
C21 C22 C23 C24 . -0.3(12)
C22 C23 C24 C25 . 1.9(13)
C23 C24 C25 C26 . -1.6(12)
C24 C25 C26 C21 . -0.2(12)
C22 C21 C26 C25 . 1.7(11)
C5 C21 C26 C25 . -179.7(7)
F1 C5 C31 C32 . 173.6(6)
C21 C5 C31 C32 . -68.1(8)
C1 C5 C31 C32 . 55.8(8)
F1 C5 C31 C36 . -2.6(9)
C21 C5 C31 C36 . 115.7(8)
C1 C5 C31 C36 . -120.5(7)
C36 C31 C32 C33 . 1.4(11)
C5 C31 C32 C33 . -175.0(7)
C31 C32 C33 C34 . -1.4(12)
C32 C33 C34 C35 . 0.8(12)
C33 C34 C35 C36 . -0.3(13)
C34 C35 C36 C31 . 0.4(13)
C32 C31 C36 C35 . -0.9(11)
C5 C31 C36 C35 . 175.4(7)
F2 C15 C41 C42 . -157.2(7)
C11 C15 C41 C42 . -35.5(9)
C51 C15 C41 C42 . 84.9(8)
F2 C15 C41 C46 . 22.8(9)
C11 C15 C41 C46 . 144.5(6)
C51 C15 C41 C46 . -95.1(8)
C46 C41 C42 C43 . 1.3(11)
C15 C41 C42 C43 . -178.7(7)
C41 C42 C43 C44 . -0.8(12)
C42 C43 C44 C45 . -0.7(12)
C43 C44 C45 C46 . 1.7(12)
C44 C45 C46 C41 . -1.1(12)
C42 C41 C46 C45 . -0.4(11)
C15 C41 C46 C45 . 179.6(7)
F2 C15 C51 C56 . -5.3(9)
C41 C15 C51 C56 . 114.1(8)
C11 C15 C51 C56 . -124.4(7)
F2 C15 C51 C52 . 174.8(6)
C41 C15 C51 C52 . -65.8(8)
C11 C15 C51 C52 . 55.7(8)
C56 C51 C52 C53 . 0.0(11)
C15 C51 C52 C53 . 179.9(7)
C51 C52 C53 C54 . -0.3(12)
C52 C53 C54 C55 . 1.2(12)
C53 C54 C55 C56 . -2.0(12)
C52 C51 C56 C55 . -0.8(11)
C15 C51 C56 C55 . 179.3(7)
C54 C55 C56 C51 . 1.8(12)
