#------------------------------------------------------------------------------
#$Date: 2019-12-11 10:40:18 +0200 (Wed, 11 Dec 2019) $
#$Revision: 244975 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/08/93/4089320.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4089320
loop_
_publ_author_name
'Nishihara, Yasushi'
'Takemura, Miwa'
'Osakada, Kohtaro'
_publ_section_title
;
 Structure and Properties of Halogeno(hydrido)(triorganosilyl)rhodium(III)
 Complexes, RhX(H)(SiR1nR23-n)(PPh3)2(X = Cl, I; R1= OSiMe3, OEt, R2= Me).
 Influence of the Alkoxy Groups and Halo Ligand on Stability and
 Reactivity of the Complexes
;
_journal_issue                   5
_journal_name_full               Organometallics
_journal_page_first              825
_journal_paper_doi               10.1021/om010862o
_journal_volume                  21
_journal_year                    2002
_chemical_formula_sum            'C49 H54 Cl O3 P2 Rh Si'
_chemical_formula_weight         919.36
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                101.35(2)
_cell_angle_beta                 92.20(2)
_cell_angle_gamma                103.58(2)
_cell_formula_units_Z            2
_cell_length_a                   13.053(3)
_cell_length_b                   18.541(4)
_cell_length_c                   10.173(3)
_cell_measurement_reflns_used    0
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      0.0
_cell_measurement_theta_min      0.0
_cell_volume                     2337.1(10)
_diffrn_ambient_temperature      296.2
_diffrn_measurement_device       'Rigaku AFC5R'
_diffrn_orient_matrix_UB_11      75001536.00000
_diffrn_orient_matrix_UB_12      0.00000
_diffrn_orient_matrix_UB_13      0.01518
_diffrn_orient_matrix_UB_21      0.02340
_diffrn_orient_matrix_UB_22      0.04891
_diffrn_orient_matrix_UB_23      0.00000
_diffrn_orient_matrix_UB_31      0.00289
_diffrn_orient_matrix_UB_32      0.02878
_diffrn_orient_matrix_UB_33      0.09471
_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rigaku rotating anode'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.05553
_diffrn_reflns_av_sigmaI/netI    0.170
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            11184
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.56
_diffrn_standards_decay_%        -4.40
_diffrn_standards_interval_count 0
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.555
_exptl_absorpt_correction_T_max  0.999
_exptl_absorpt_correction_T_min  0.885
_exptl_absorpt_correction_type
;
\y scans (North,Phillips & Matthews, 1968)
;
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.306
_exptl_crystal_density_meas      ?
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             956.00
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.45
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.84
_refine_diff_density_min         -4.41
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.631
_refine_ls_goodness_of_fit_ref   1.630
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     483
_refine_ls_number_reflns         5229
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0579
_refine_ls_R_factor_gt           0.0580
_refine_ls_shift/su_max          1.2800
_refine_ls_shift/su_mean         0.0385
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[σ²(Fo) + 0.00003|Fo|²]'
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_all         0.0570
_refine_ls_wR_factor_ref         0.0570
_reflns_number_gt                5229
_reflns_number_total             10709
_reflns_threshold_expression     I>3.00σ(I)
_cod_data_source_file            om010862o.cif
_cod_data_source_block           form3
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_crystal_density_meas' value 'not measured' was
changed to '?' -- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 

 Corrected the values of the '_diffrn_radiation_type',
 '_exptl_absorpt_correction_type', '_reflns_threshold_expression'
 and '_refine_ls_weighting_details' data items by replacing a
 sequence of malformed symbols with the backslash symbol ('\')
 after consulting the original publication.

 Antanas Vaitkus,
 2019-12-11
;
_cod_original_cell_volume        2337(1)
_cod_original_sg_symbol_H-M      'P -1       '
_cod_original_formula_sum        'C49 H54 Cl O3 P2 Rh Si '
_cod_database_code               4089320
loop_
_symmetry_equiv_pos_as_xyz
'   +x,   +y,   +z'
'   -x,   -y,   -z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_occupancy
_atom_site_adp_type
_atom_site_calc_flag
Rh(1) 0.23539(4) 0.17786(3) 0.32561(5) 0.0387(1) 1.000 Uani d
Cl(1) 0.1477(1) 0.1727(1) 0.5280(1) 0.0593(5) 1.000 Uani d
P(1) 0.0934(1) 0.21005(9) 0.2285(1) 0.0425(4) 1.000 Uani d
P(2) 0.3538(1) 0.11580(9) 0.4001(1) 0.0430(4) 1.000 Uani d
Si(0) 0.3540(1) 0.2878(1) 0.3266(2) 0.0542(6) 1.000 Uani d
O(1) 0.3541(5) 0.3213(3) 0.1949(6) 0.141(3) 1.000 Uani d
O(2) 0.4696(4) 0.2818(3) 0.3642(7) 0.132(3) 1.000 Uani d
O(3) 0.3319(6) 0.3565(3) 0.4374(7) 0.141(3) 1.000 Uani d
C(1) 0.3599(9) 0.3953(7) 0.176(1) 0.153(5) 1.000 Uani d
C(2) 0.415(1) 0.4130(7) 0.070(1) 0.227(8) 1.000 Uani d
C(3) 0.5688(8) 0.3257(8) 0.349(1) 0.185(6) 1.000 Uani d
C(4) 0.635(1) 0.356(1) 0.446(2) 0.34(1) 1.000 Uani d
C(5) 0.3186(9) 0.3684(6) 0.569(1) 0.126(4) 1.000 Uani d
C(6) 0.356(1) 0.4326(8) 0.653(1) 0.282(8) 1.000 Uani d
C(7) -0.0082(4) 0.1205(3) 0.1724(5) 0.043(2) 1.000 Uani d
C(8) -0.0567(5) 0.0985(4) 0.0420(6) 0.055(2) 1.000 Uani d
C(9) -0.1292(5) 0.0286(4) -0.0012(6) 0.064(2) 1.000 Uani d
C(10) -0.1535(5) -0.0191(4) 0.0850(7) 0.066(2) 1.000 Uani d
C(11) -0.1070(5) 0.0015(4) 0.2138(7) 0.063(2) 1.000 Uani d
C(12) -0.0340(4) 0.0710(4) 0.2580(6) 0.053(2) 1.000 Uani d
C(13) 0.0301(5) 0.2725(3) 0.3405(6) 0.048(2) 1.000 Uani d
C(14) 0.0787(5) 0.3496(4) 0.3740(7) 0.074(3) 1.000 Uani d
C(15) 0.0373(7) 0.3979(4) 0.4622(9) 0.091(3) 1.000 Uani d
C(16) -0.0506(8) 0.3719(5) 0.5229(8) 0.094(3) 1.000 Uani d
C(17) -0.0998(7) 0.2965(5) 0.4926(9) 0.098(3) 1.000 Uani d
C(18) -0.0590(5) 0.2470(4) 0.4008(7) 0.074(3) 1.000 Uani d
C(19) 0.1016(4) 0.2490(3) 0.0770(6) 0.047(2) 1.000 Uani d
C(20) 0.1733(5) 0.2322(4) -0.0139(6) 0.056(2) 1.000 Uani d
C(21) 0.1730(5) 0.2519(4) -0.1390(6) 0.066(2) 1.000 Uani d
C(22) 0.1006(6) 0.2914(4) -0.1691(6) 0.069(2) 1.000 Uani d
C(23) 0.0311(6) 0.3103(4) -0.0803(7) 0.073(3) 1.000 Uani d
C(24) 0.0314(5) 0.2895(4) 0.0435(6) 0.064(2) 1.000 Uani d
C(25) 0.2880(4) 0.0145(3) 0.3606(5) 0.044(2) 1.000 Uani d
C(26) 0.1830(5) -0.0092(4) 0.3903(6) 0.058(2) 1.000 Uani d
C(27) 0.1300(5) -0.0853(5) 0.3557(8) 0.074(3) 1.000 Uani d
C(28) 0.1799(7) -0.1380(4) 0.2942(8) 0.080(3) 1.000 Uani d
C(29) 0.2841(7) -0.1155(5) 0.2663(8) 0.084(3) 1.000 Uani d
C(30) 0.3378(5) -0.0396(4) 0.2995(7) 0.063(2) 1.000 Uani d
C(31) 0.4794(4) 0.1175(3) 0.3267(6) 0.049(2) 1.000 Uani d
C(32) 0.4829(5) 0.1105(4) 0.1882(6) 0.066(2) 1.000 Uani d
C(33) 0.5760(6) 0.1078(5) 0.1296(7) 0.080(3) 1.000 Uani d
C(34) 0.6675(6) 0.1120(4) 0.2080(9) 0.083(3) 1.000 Uani d
C(35) 0.6644(5) 0.1182(4) 0.3429(8) 0.075(3) 1.000 Uani d
C(36) 0.5716(5) 0.1201(4) 0.4023(6) 0.058(2) 1.000 Uani d
C(37) 0.3899(4) 0.1381(4) 0.5832(6) 0.049(2) 1.000 Uani d
C(38) 0.4312(6) 0.2124(4) 0.6465(6) 0.072(2) 1.000 Uani d
C(39) 0.4567(6) 0.2316(4) 0.7844(7) 0.082(3) 1.000 Uani d
C(40) 0.4414(6) 0.1771(5) 0.8590(6) 0.076(3) 1.000 Uani d
C(41) 0.4036(5) 0.1026(5) 0.7954(7) 0.075(3) 1.000 Uani d
C(42) 0.3770(5) 0.0823(4) 0.6583(6) 0.059(2) 1.000 Uani d
C(43) 0.831(2) 0.448(1) 0.051(2) 0.253(9) 1.000 Uiso d
C(44) 0.830(1) 0.472(1) -0.059(2) 0.242(8) 1.000 Uiso d
C(45) 0.761(1) 0.420(1) -0.178(2) 0.249(8) 1.000 Uiso d
C(46) 0.739(1) 0.3524(9) -0.119(2) 0.190(6) 1.000 Uiso d
C(47) 0.745(1) 0.3218(9) -0.004(2) 0.219(7) 1.000 Uiso d
C(48) 0.796(1) 0.364(1) 0.117(2) 0.245(7) 1.000 Uiso d
C(49) 0.869(2) 0.460(1) 0.164(2) 0.31(1) 1.000 Uiso d
H(1) 0.306(7) 0.176(5) 0.23(1) 0.224(8) 1.000 Uiso d
H(2) 0.3955 0.4305 0.2562 0.185 1.000 Uiso c
H(3) 0.2908 0.4016 0.1633 0.185 1.000 Uiso c
H(4) 0.4087 0.3664 0.0047 0.272 1.000 Uiso c
H(5) 0.3856 0.4461 0.0308 0.272 1.000 Uiso c
H(6) 0.4870 0.4345 0.0993 0.272 1.000 Uiso c
H(7) 0.5562 0.3669 0.3134 0.223 1.000 Uiso c
H(8) 0.6004 0.2951 0.2873 0.223 1.000 Uiso c
H(9) 0.6078 0.3422 0.5263 0.408 1.000 Uiso c
H(10) 0.6970 0.3367 0.4311 0.408 1.000 Uiso c
H(11) 0.6533 0.4087 0.4568 0.408 1.000 Uiso c
H(12) 0.3481 0.3327 0.6039 0.154 1.000 Uiso c
H(13) 0.2441 0.3559 0.5758 0.154 1.000 Uiso c
H(14) 0.3144 0.4675 0.6382 0.340 1.000 Uiso c
H(15) 0.3531 0.4266 0.7424 0.340 1.000 Uiso c
H(16) 0.4270 0.4534 0.6364 0.340 1.000 Uiso c
H(17) -0.0399 0.1318 -0.0187 0.067 1.000 Uiso c
H(18) -0.1611 0.0146 -0.0910 0.076 1.000 Uiso c
H(19) -0.2031 -0.0668 0.0552 0.080 1.000 Uiso c
H(20) -0.1248 -0.0319 0.2738 0.076 1.000 Uiso c
H(21) -0.0015 0.0845 0.3472 0.064 1.000 Uiso c
H(22) 0.1417 0.3685 0.3356 0.088 1.000 Uiso c
H(23) 0.0699 0.4507 0.4812 0.110 1.000 Uiso c
H(24) -0.0781 0.4055 0.5862 0.111 1.000 Uiso c
H(25) -0.1621 0.2776 0.5339 0.117 1.000 Uiso c
H(26) -0.0934 0.1941 0.3802 0.088 1.000 Uiso c
H(27) 0.2237 0.2064 0.0103 0.067 1.000 Uiso c
H(28) 0.2216 0.2388 -0.2016 0.079 1.000 Uiso c
H(29) 0.0988 0.3050 -0.2540 0.083 1.000 Uiso c
H(30) -0.0169 0.3382 -0.1027 0.089 1.000 Uiso c
H(31) -0.0172 0.3026 0.1055 0.077 1.000 Uiso c
H(32) 0.1482 0.0270 0.4346 0.070 1.000 Uiso c
H(33) 0.0584 -0.1008 0.3736 0.089 1.000 Uiso c
H(34) 0.1433 -0.1901 0.2714 0.096 1.000 Uiso c
H(35) 0.3189 -0.1524 0.2241 0.101 1.000 Uiso c
H(36) 0.4094 -0.0244 0.2796 0.076 1.000 Uiso c
H(37) 0.4207 0.1082 0.1341 0.081 1.000 Uiso c
H(38) 0.5767 0.1020 0.0342 0.097 1.000 Uiso c
H(39) 0.7322 0.1115 0.1687 0.101 1.000 Uiso c
H(40) 0.7264 0.1204 0.3972 0.090 1.000 Uiso c
H(41) 0.5710 0.1241 0.4969 0.070 1.000 Uiso c
H(42) 0.4418 0.2510 0.5955 0.085 1.000 Uiso c
H(43) 0.4855 0.2833 0.8275 0.100 1.000 Uiso c
H(44) 0.4565 0.1904 0.9538 0.093 1.000 Uiso c
H(45) 0.3962 0.0643 0.8464 0.090 1.000 Uiso c
H(46) 0.3496 0.0305 0.6155 0.071 1.000 Uiso c
loop_
_atom_type_symbol
_atom_type_oxidation_number
_atom_type_number_in_cell
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C 0 98 0.002 0.002
;International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.2)
;
H 0 108 0.000 0.000
;International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.2)
;
O 0 6 0.008 0.006
;International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.2)
;
Cl 0 2 0.132 0.159
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
P 0 4 0.090 0.095
;International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.2)
;
Si 0 2 0.072 0.071
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
Rh 0 2 -1.287 0.919
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
Cl(1) Rh(1) P(1) 90.10(7) ?
Cl(1) Rh(1) P(2) 89.81(7) ?
Cl(1) Rh(1) Si 115.35(9) ?
Cl(1) Rh(1) H(1) 165(5) no
P(1) Rh(1) P(2) 166.02(7) ?
P(1) Rh(1) Si 95.90(8) ?
P(1) Rh(1) H(1) 105(5) no
P(2) Rh(1) Si 96.77(8) ?
P(2) Rh(1) H(1) 76(5) no
Si Rh(1) H(1) 64(5) no
Rh(1) P(1) C(7) 105.7(2) ?
Rh(1) P(1) C(13) 116.1(2) ?
Rh(1) P(1) C(19) 122.5(2) ?
C(7) P(1) C(13) 105.5(3) ?
C(7) P(1) C(19) 101.9(3) ?
C(13) P(1) C(19) 103.3(3) ?
Rh(1) P(2) C(25) 106.7(2) ?
Rh(1) P(2) C(31) 121.2(2) ?
Rh(1) P(2) C(37) 116.1(3) ?
C(25) P(2) C(31) 102.3(3) ?
C(25) P(2) C(37) 104.5(3) ?
C(31) P(2) C(37) 104.1(3) ?
Rh(1) Si O(1) 117.5(3) ?
Rh(1) Si O(2) 110.6(3) ?
Rh(1) Si O(3) 111.2(3) ?
O(1) Si O(2) 108.7(5) ?
O(1) Si O(3) 101.2(5) ?
O(2) Si O(3) 106.8(5) ?
Si O(1) C(1) 131.8(9) ?
Si O(2) C(3) 132.3(9) ?
Si O(3) C(5) 135.7(9) ?
O(1) C(1) C(2) 114(2) ?
O(1) C(1) H(2) 108.1 no
O(1) C(1) H(3) 109.2 no
C(2) C(1) H(2) 107.6 no
C(2) C(1) H(3) 108.7 no
H(2) C(1) H(3) 109.1 no
C(1) C(2) H(4) 108.0 no
C(1) C(2) H(5) 110.2 no
C(1) C(2) H(6) 110.0 no
H(4) C(2) H(5) 109.3 no
H(4) C(2) H(6) 108.3 no
H(5) C(2) H(6) 111.0 no
O(2) C(3) C(4) 122(2) ?
O(2) C(3) H(7) 105.8 no
O(2) C(3) H(8) 106.9 no
C(4) C(3) H(7) 104.8 no
C(4) C(3) H(8) 107.0 no
H(7) C(3) H(8) 110.2 no
C(3) C(4) H(9) 110.1 no
C(3) C(4) H(10) 108.7 no
C(3) C(4) H(11) 111.2 no
H(9) C(4) H(10) 107.8 no
H(9) C(4) H(11) 109.9 no
H(10) C(4) H(11) 109.1 no
O(3) C(5) C(6) 124(2) ?
O(3) C(5) H(12) 106.2 no
O(3) C(5) H(13) 106.4 no
C(6) C(5) H(12) 105.1 no
C(6) C(5) H(13) 105.7 no
H(12) C(5) H(13) 108.5 no
C(5) C(6) H(14) 109.2 no
C(5) C(6) H(15) 111.2 no
C(5) C(6) H(16) 109.4 no
H(14) C(6) H(15) 109.3 no
H(14) C(6) H(16) 108.1 no
H(15) C(6) H(16) 109.7 no
P(1) C(7) C(8) 121.7(6) ?
P(1) C(7) C(12) 120.1(5) ?
C(8) C(7) C(12) 118.1(7) ?
C(7) C(8) C(9) 121.0(7) ?
C(7) C(8) H(17) 119.4 no
C(9) C(8) H(17) 119.6 no
C(8) C(9) C(10) 119.9(8) ?
C(8) C(9) H(18) 119.6 no
C(10) C(9) H(18) 120.5 no
C(9) C(10) C(11) 120.0(8) ?
C(9) C(10) H(19) 119.7 no
C(11) C(10) H(19) 120.3 no
C(10) C(11) C(12) 120.7(8) ?
C(10) C(11) H(20) 119.6 no
C(12) C(11) H(20) 119.7 no
C(7) C(12) C(11) 120.3(7) ?
C(7) C(12) H(21) 119.7 no
C(11) C(12) H(21) 120.0 no
P(1) C(13) C(14) 118.5(6) ?
P(1) C(13) C(18) 123.5(6) ?
C(14) C(13) C(18) 117.8(7) ?
C(13) C(14) C(15) 120.8(9) ?
C(13) C(14) H(22) 119.5 no
C(15) C(14) H(22) 119.7 no
C(14) C(15) C(16) 121(1) ?
C(14) C(15) H(23) 119.6 no
C(16) C(15) H(23) 119.4 no
C(15) C(16) C(17) 119.6(9) ?
C(15) C(16) H(24) 120.8 no
C(17) C(16) H(24) 119.6 no
C(16) C(17) C(18) 119.7(9) ?
C(16) C(17) H(25) 120.4 no
C(18) C(17) H(25) 119.9 no
C(13) C(18) C(17) 121.1(9) ?
C(13) C(18) H(26) 119.4 no
C(17) C(18) H(26) 119.5 no
P(1) C(19) C(20) 119.6(6) ?
P(1) C(19) C(24) 121.8(6) ?
C(20) C(19) C(24) 118.4(7) ?
C(19) C(20) C(21) 121.7(7) ?
C(19) C(20) H(27) 118.7 no
C(21) C(20) H(27) 119.5 no
C(20) C(21) C(22) 117.9(8) ?
C(20) C(21) H(28) 120.9 no
C(22) C(21) H(28) 121.2 no
C(21) C(22) C(23) 121.5(8) ?
C(21) C(22) H(29) 119.2 no
C(23) C(22) H(29) 119.4 no
C(22) C(23) C(24) 120.0(8) ?
C(22) C(23) H(30) 119.8 no
C(24) C(23) H(30) 120.2 no
C(19) C(24) C(23) 120.5(8) ?
C(19) C(24) H(31) 119.6 no
C(23) C(24) H(31) 119.9 no
P(2) C(25) C(26) 119.3(6) ?
P(2) C(25) C(30) 122.0(6) ?
C(26) C(25) C(30) 118.7(7) ?
C(25) C(26) C(27) 120.3(8) ?
C(25) C(26) H(32) 119.8 no
C(27) C(26) H(32) 119.9 no
C(26) C(27) C(28) 120.4(9) ?
C(26) C(27) H(33) 119.9 no
C(28) C(27) H(33) 119.7 no
C(27) C(28) C(29) 119.9(9) ?
C(27) C(28) H(34) 119.9 no
C(29) C(28) H(34) 120.1 no
C(28) C(29) C(30) 120(1) ?
C(28) C(29) H(35) 119.7 no
C(30) C(29) H(35) 119.9 no
C(25) C(30) C(29) 120.4(8) ?
C(25) C(30) H(36) 119.7 no
C(29) C(30) H(36) 120.0 no
P(2) C(31) C(32) 119.5(6) ?
P(2) C(31) C(36) 122.5(6) ?
C(32) C(31) C(36) 117.8(7) ?
C(31) C(32) C(33) 120.6(7) ?
C(31) C(32) H(37) 119.5 no
C(33) C(32) H(37) 120.0 no
C(32) C(33) C(34) 120.5(8) ?
C(32) C(33) H(38) 119.5 no
C(34) C(33) H(38) 120.0 no
C(33) C(34) C(35) 119.3(8) ?
C(33) C(34) H(39) 120.9 no
C(35) C(34) H(39) 119.8 no
C(34) C(35) C(36) 120.7(8) ?
C(34) C(35) H(40) 120.0 no
C(36) C(35) H(40) 119.3 no
C(31) C(36) C(35) 121.2(8) ?
C(31) C(36) H(41) 119.4 no
C(35) C(36) H(41) 119.4 no
P(2) C(37) C(38) 118.6(6) ?
P(2) C(37) C(42) 122.2(6) ?
C(38) C(37) C(42) 119.2(7) ?
C(37) C(38) C(39) 120.2(8) ?
C(37) C(38) H(42) 119.8 no
C(39) C(38) H(42) 119.9 no
C(38) C(39) C(40) 120.7(9) ?
C(38) C(39) H(43) 119.7 no
C(40) C(39) H(43) 119.6 no
C(39) C(40) C(41) 119.1(8) ?
C(39) C(40) H(44) 120.7 no
C(41) C(40) H(44) 120.2 no
C(40) C(41) C(42) 121.1(8) ?
C(40) C(41) H(45) 119.4 no
C(42) C(41) H(45) 119.5 no
C(37) C(42) C(41) 119.6(8) ?
C(37) C(42) H(46) 120.0 no
C(41) C(42) H(46) 120.4 no
C(44) C(43) C(48) 142(3) ?
C(44) C(43) C(49) 147(4) ?
C(48) C(43) C(49) 69(2) ?
C(43) C(44) C(45) 117(3) ?
C(44) C(45) C(46) 96(2) ?
C(45) C(46) C(47) 148(2) ?
C(46) C(47) C(48) 123(2) ?
C(43) C(48) C(47) 92(2) ?
C(43) C(48) C(49) 39(1) ?
C(47) C(48) C(49) 132(2) ?
C(43) C(49) C(48) 71(2) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Rh(1) Cl(1) 2.401(2) ?
Rh(1) P(1) 2.319(2) ?
Rh(1) P(2) 2.319(2) ?
Rh(1) Si 2.251(2) ?
Rh(1) H(1) 1.4(1) no
P(1) C(7) 1.837(7) ?
P(1) C(13) 1.823(7) ?
P(1) C(19) 1.823(7) ?
P(2) C(25) 1.830(7) ?
P(2) C(31) 1.823(7) ?
P(2) C(37) 1.844(7) ?
Si O(1) 1.583(7) ?
Si O(2) 1.577(7) ?
Si O(3) 1.615(8) ?
O(1) C(1) 1.41(1) ?
O(2) C(3) 1.39(1) ?
O(3) C(5) 1.34(1) ?
C(1) C(2) 1.37(2) ?
C(1) H(2) 0.96 no
C(1) H(3) 0.94 no
C(2) H(4) 0.97 no
C(2) H(5) 0.94 no
C(2) H(6) 0.95 no
C(3) C(4) 1.23(2) ?
C(3) H(7) 0.95 no
C(3) H(8) 0.94 no
C(4) H(9) 0.96 no
C(4) H(10) 0.96 no
C(4) H(11) 0.94 no
C(5) C(6) 1.29(2) ?
C(5) H(12) 0.96 no
C(5) H(13) 0.95 no
C(6) H(14) 0.96 no
C(6) H(15) 0.94 no
C(6) H(16) 0.96 no
C(7) C(8) 1.388(9) ?
C(7) C(12) 1.381(9) ?
C(8) C(9) 1.39(1) ?
C(8) H(17) 0.95 no
C(9) C(10) 1.36(1) ?
C(9) H(18) 0.95 no
C(10) C(11) 1.37(1) ?
C(10) H(19) 0.95 no
C(11) C(12) 1.39(1) ?
C(11) H(20) 0.95 no
C(12) H(21) 0.95 no
C(13) C(14) 1.39(1) ?
C(13) C(18) 1.36(1) ?
C(14) C(15) 1.36(1) ?
C(14) H(22) 0.95 no
C(15) C(16) 1.36(1) ?
C(15) H(23) 0.95 no
C(16) C(17) 1.36(1) ?
C(16) H(24) 0.95 no
C(17) C(18) 1.39(1) ?
C(17) H(25) 0.96 no
C(18) H(26) 0.96 no
C(19) C(20) 1.38(1) ?
C(19) C(24) 1.38(1) ?
C(20) C(21) 1.39(1) ?
C(20) H(27) 0.95 no
C(21) C(22) 1.39(1) ?
C(21) H(28) 0.95 no
C(22) C(23) 1.36(1) ?
C(22) H(29) 0.95 no
C(23) C(24) 1.39(1) ?
C(23) H(30) 0.95 no
C(24) H(31) 0.95 no
C(25) C(26) 1.401(9) ?
C(25) C(30) 1.38(1) ?
C(26) C(27) 1.39(1) ?
C(26) H(32) 0.95 no
C(27) C(28) 1.36(1) ?
C(27) H(33) 0.95 no
C(28) C(29) 1.38(1) ?
C(28) H(34) 0.95 no
C(29) C(30) 1.39(1) ?
C(29) H(35) 0.95 no
C(30) H(36) 0.95 no
C(31) C(32) 1.39(1) ?
C(31) C(36) 1.388(9) ?
C(32) C(33) 1.38(1) ?
C(32) H(37) 0.95 no
C(33) C(34) 1.39(1) ?
C(33) H(38) 0.96 no
C(34) C(35) 1.36(1) ?
C(34) H(39) 0.95 no
C(35) C(36) 1.38(1) ?
C(35) H(40) 0.95 no
C(36) H(41) 0.95 no
C(37) C(38) 1.37(1) ?
C(37) C(42) 1.39(1) ?
C(38) C(39) 1.38(1) ?
C(38) H(42) 0.95 no
C(39) C(40) 1.36(1) ?
C(39) H(43) 0.95 no
C(40) C(41) 1.37(1) ?
C(40) H(44) 0.95 no
C(41) C(42) 1.38(1) ?
C(41) H(45) 0.95 no
C(42) H(46) 0.95 no
C(43) C(44) 1.28(3) ?
C(43) C(48) 1.79(3) ?
C(43) C(49) 1.20(3) ?
C(44) C(45) 1.50(3) ?
C(45) C(46) 1.47(2) ?
C(46) C(47) 1.40(2) ?
C(47) C(48) 1.37(3) ?
C(48) C(49) 1.77(3) ?
