#------------------------------------------------------------------------------
#$Date: 2016-03-21 17:38:18 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178788 $
#$URL: svn://www.crystallography.net/cod/cif/4/10/42/4104222.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4104222
loop_
_publ_author_name
'Marc-Etienne Moret'
'Peter Chen'
_publ_section_title
;
 Interaction of Organoplatinum(II) Complexes with Monovalent Coinage Metal
 Triflates
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              5675
_journal_page_last               5690
_journal_paper_doi               10.1021/ja900449y
_journal_volume                  131
_journal_year                    2009
_chemical_formula_moiety         'C38 H36 Ag2 Cl8 F6 N4 O6 Pt2 S2, 2(C6 H6)'
_chemical_formula_sum            'C50 H48 Ag2 Cl8 F6 N4 O6 Pt2 S2'
_chemical_formula_weight         1868.56
_chemical_name_systematic
;                                                                              
 ?                                                                             
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                110.231(12)
_cell_angle_beta                 105.478(11)
_cell_angle_gamma                90.209(10)
_cell_formula_units_Z            1
_cell_length_a                   10.6556(12)
_cell_length_b                   12.1622(13)
_cell_length_c                   12.6936(13)
_cell_measurement_reflns_used    6590
_cell_measurement_temperature    220(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      2.61
_cell_volume                     1479.2(3)
_computing_cell_refinement       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_collection       'COLLECT (Nonius, 2000)'
_computing_data_reduction        'Denzo + Scalepak (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'ORTEP (Johnson,1976)'
_computing_publication_material  SHELXL97
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR97 (Altomare et Al., 1997)'
_diffrn_ambient_temperature      220(2)
_diffrn_measured_fraction_theta_full .997
_diffrn_measured_fraction_theta_max .997
_diffrn_measurement_device_type
'Nonius Kappa CCD area-detector diffractometer'
_diffrn_measurement_method       'φ and ω scans with κ offsets'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0378
_diffrn_reflns_av_sigmaI/netI    0.0441
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            12197
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         2.61
_exptl_absorpt_coefficient_mu    5.868
_exptl_absorpt_correction_T_max  .46
_exptl_absorpt_correction_T_min  .39
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Blessing (1995)'
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    2.098
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'Cut fragment'
_exptl_crystal_F_000             896
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.13
_refine_diff_density_max         1.135
_refine_diff_density_min         -1.962
_refine_diff_density_rms         .138
_refine_ls_extinction_coef       0.0048(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL97
_refine_ls_goodness_of_fit_ref   1.026
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     366
_refine_ls_number_reflns         6777
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.026
_refine_ls_R_factor_all          0.0321
_refine_ls_R_factor_gt           0.0302
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0489P)²+0.8782P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0786
_refine_ls_wR_factor_ref         0.0801
_reflns_number_gt                6425
_reflns_number_total             6777
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja900449y_si_003.cif
_cod_data_source_block           moret24_ch_08
_cod_database_code               4104222
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt 0.535028(11) 0.195178(11) 0.168865(10) 0.02381(6) Uani 1 d .
Ag1 Ag 0.42541(3) 0.05182(3) -0.06939(2) 0.03527(8) Uani 1 d .
Cl1 Cl 0.81183(12) 0.44751(10) 0.41212(10) 0.0460(2) Uani 1 d .
Cl2 Cl 0.84405(11) 0.03977(10) 0.07440(11) 0.0479(3) Uani 1 d .
Cl3 Cl 0.40210(12) -0.12523(10) 0.19636(12) 0.0525(3) Uani 1 d .
Cl4 Cl 0.41775(12) 0.33938(10) 0.43830(11) 0.0505(3) Uani 1 d .
S1 S 0.17930(10) 0.16324(10) -0.24897(10) 0.0384(2) Uani 1 d .
F1 F 0.3232(5) 0.2538(4) -0.3414(4) 0.0914(13) Uani 1 d .
F2 F 0.1778(5) 0.3604(4) -0.2854(5) 0.1134(17) Uani 1 d .
F3 F 0.3516(5) 0.3484(4) -0.1601(4) 0.0918(13) Uani 1 d .
O1 O 0.2845(3) 0.0910(3) -0.2268(3) 0.0397(6) Uani 1 d .
O2 O 0.1264(4) 0.2147(4) -0.1527(4) 0.0694(11) Uani 1 d .
O3 O 0.0872(4) 0.1121(4) -0.3614(4) 0.0731(13) Uani 1 d .
N1 N 0.7318(3) 0.1941(3) 0.2622(3) 0.0240(6) Uani 1 d .
N2 N 0.5205(3) 0.1286(3) 0.2992(3) 0.0248(6) Uani 1 d .
C1 C 0.2613(6) 0.2876(5) -0.2601(5) 0.0557(13) Uani 1 d .
C2 C 0.8391(3) 0.2479(3) 0.2426(3) 0.0267(7) Uani 1 d .
C3 C 0.8824(4) 0.3663(3) 0.3049(3) 0.0320(8) Uani 1 d .
C4 C 0.9806(4) 0.4228(4) 0.2817(4) 0.0374(9) Uani 1 d .
H4 H 1.0097 0.5028 0.3253 0.045 Uiso 1 calc R
C5 C 1.0346(4) 0.3597(4) 0.1938(4) 0.0404(9) Uani 1 d .
H5 H 1.1007 0.3970 0.1776 0.048 Uiso 1 calc R
C6 C 0.9919(4) 0.2426(4) 0.1302(4) 0.0379(9) Uani 1 d .
H6 H 1.0285 0.2000 0.0705 0.046 Uiso 1 calc R
C7 C 0.8940(4) 0.1872(3) 0.1546(4) 0.0323(8) Uani 1 d .
C8 C 0.7500(3) 0.1648(3) 0.3536(3) 0.0254(7) Uani 1 d .
C9 C 0.6285(3) 0.1216(3) 0.3707(3) 0.0267(7) Uani 1 d .
C10 C 0.3964(3) 0.1054(3) 0.3150(3) 0.0288(7) Uani 1 d .
C11 C 0.3277(4) -0.0063(3) 0.2646(3) 0.0310(8) Uani 1 d .
C12 C 0.2018(4) -0.0264(4) 0.2707(4) 0.0388(9) Uani 1 d .
H12 H 0.1567 -0.1025 0.2355 0.047 Uiso 1 calc R
C13 C 0.1443(4) 0.0681(5) 0.3297(4) 0.0464(11) Uani 1 d .
H13 H 0.0592 0.0559 0.3346 0.056 Uiso 1 calc R
C14 C 0.2100(4) 0.1802(4) 0.3815(4) 0.0449(10) Uani 1 d .
H14 H 0.1702 0.2436 0.4220 0.054 Uiso 1 calc R
C15 C 0.3348(4) 0.1988(4) 0.3734(4) 0.0356(8) Uani 1 d .
C16 C 0.6372(4) 0.0779(4) 0.4695(4) 0.0369(9) Uani 1 d .
H16A H 0.6719 0.1424 0.5438 0.055 Uiso 1 calc R
H16B H 0.6948 0.0158 0.4642 0.055 Uiso 1 calc R
H16C H 0.5507 0.0473 0.4643 0.055 Uiso 1 calc R
C17 C 0.8766(4) 0.1771(4) 0.4434(3) 0.0339(8) Uani 1 d .
H17A H 0.9463 0.2064 0.4210 0.051 Uiso 1 calc R
H17B H 0.8939 0.1010 0.4495 0.051 Uiso 1 calc R
H17C H 0.8723 0.2322 0.5185 0.051 Uiso 1 calc R
C18 C 0.5762(4) 0.2863(4) 0.0716(4) 0.0367(9) Uani 1 d .
H18A H 0.4998 0.2782 0.0065 0.055 Uiso 1 calc R
H18B H 0.6486 0.2549 0.0418 0.055 Uiso 1 calc R
H18C H 0.5999 0.3689 0.1203 0.055 Uiso 1 calc R
C19 C 0.3417(4) 0.2154(4) 0.1121(4) 0.0351(8) Uani 1 d .
H19A H 0.3243 0.2920 0.1600 0.053 Uiso 1 calc R
H19B H 0.2887 0.1542 0.1184 0.053 Uiso 1 calc R
H19C H 0.3200 0.2097 0.0311 0.053 Uiso 1 calc R
C20 C 0.1260(5) 0.6228(4) 0.1159(4) 0.0480(11) Uani 1 d .
H20 H 0.0472 0.6429 0.0758 0.058 Uiso 1 calc R
C21 C 0.1577(5) 0.6511(4) 0.2343(4) 0.0465(10) Uani 1 d .
H21 H 0.1004 0.6914 0.2757 0.056 Uiso 1 calc R
C22 C 0.2727(5) 0.6214(5) 0.2939(5) 0.0517(11) Uani 1 d .
H22 H 0.2935 0.6409 0.3754 0.062 Uiso 1 calc R
C23 C 0.3573(5) 0.5628(5) 0.2330(5) 0.0589(13) Uani 1 d .
H23 H 0.4362 0.5425 0.2730 0.071 Uiso 1 calc R
C24 C 0.3253(6) 0.5343(5) 0.1136(6) 0.0634(14) Uani 1 d .
H24 H 0.3822 0.4942 0.0717 0.076 Uiso 1 calc R
C25 C 0.2109(6) 0.5642(5) 0.0556(5) 0.0564(13) Uani 1 d .
H25 H 0.1898 0.5447 -0.0260 0.068 Uiso 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C .0033 .0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H .0000 .0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl .1484 .1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F .0171 .0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N .0061 .0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O .0106 .0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S .1246 .1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C19 Pt1 C18 89.28(17) . .
C19 Pt1 N2 97.19(14) . .
C18 Pt1 N2 167.97(15) . .
C19 Pt1 N1 168.23(14) . .
C18 Pt1 N1 96.28(14) . .
N2 Pt1 N1 75.59(11) . .
C19 Pt1 Ag1 68.88(12) . .
C18 Pt1 Ag1 73.10(12) . .
N2 Pt1 Ag1 118.69(8) . .
N1 Pt1 Ag1 122.67(8) . .
C19 Pt1 Ag1 109.46(12) . 2_655
C18 Pt1 Ag1 110.60(13) . 2_655
N2 Pt1 Ag1 76.83(8) . 2_655
N1 Pt1 Ag1 78.30(8) . 2_655
Ag1 Pt1 Ag1 56.047(15) . 2_655
O1 Ag1 Ag1 164.82(8) . 2_655
O1 Ag1 Pt1 131.57(8) . .
Ag1 Ag1 Pt1 63.489(15) 2_655 .
O1 Ag1 Pt1 104.45(8) . 2_655
Ag1 Ag1 Pt1 60.465(17) 2_655 2_655
Pt1 Ag1 Pt1 123.955(16) . 2_655
O3 S1 O2 116.4(3) . .
O3 S1 O1 113.6(2) . .
O2 S1 O1 114.3(2) . .
O3 S1 C1 103.0(3) . .
O2 S1 C1 104.1(3) . .
O1 S1 C1 103.3(2) . .
S1 O1 Ag1 139.75(19) . .
C8 N1 C2 120.2(3) . .
C8 N1 Pt1 116.6(2) . .
C2 N1 Pt1 121.7(2) . .
C9 N2 C10 121.6(3) . .
C9 N2 Pt1 116.8(2) . .
C10 N2 Pt1 121.2(2) . .
F2 C1 F1 108.1(5) . .
F2 C1 F3 107.6(5) . .
F1 C1 F3 106.3(5) . .
F2 C1 S1 111.3(4) . .
F1 C1 S1 111.7(4) . .
F3 C1 S1 111.5(4) . .
C7 C2 C3 118.1(3) . .
C7 C2 N1 121.4(3) . .
C3 C2 N1 120.2(3) . .
C2 C3 C4 121.3(4) . .
C2 C3 Cl1 119.8(3) . .
C4 C3 Cl1 118.9(3) . .
C5 C4 C3 119.3(4) . .
C6 C5 C4 120.2(4) . .
C5 C6 C7 119.9(4) . .
C2 C7 C6 121.2(4) . .
C2 C7 Cl2 120.1(3) . .
C6 C7 Cl2 118.7(3) . .
N1 C8 C17 126.2(3) . .
N1 C8 C9 114.9(3) . .
C17 C8 C9 118.7(3) . .
N2 C9 C8 115.7(3) . .
N2 C9 C16 124.2(3) . .
C8 C9 C16 120.1(3) . .
C11 C10 C15 117.7(3) . .
C11 C10 N2 122.3(3) . .
C15 C10 N2 119.7(3) . .
C12 C11 C10 122.1(4) . .
C12 C11 Cl3 118.5(3) . .
C10 C11 Cl3 119.4(3) . .
C13 C12 C11 118.5(4) . .
C14 C13 C12 121.0(4) . .
C13 C14 C15 119.7(4) . .
C14 C15 C10 121.0(4) . .
C14 C15 Cl4 119.8(3) . .
C10 C15 Cl4 119.1(3) . .
C21 C20 C25 119.3(5) . .
C20 C21 C22 120.8(5) . .
C21 C22 C23 119.6(5) . .
C24 C23 C22 119.5(5) . .
C25 C24 C23 120.2(5) . .
C24 C25 C20 120.5(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C19 2.039(4) .
Pt1 C18 2.043(4) .
Pt1 N2 2.117(3) .
Pt1 N1 2.118(3) .
Pt1 Ag1 2.8290(6) .
Pt1 Ag1 2.9097(5) 2_655
Ag1 O1 2.354(3) .
Ag1 Ag1 2.6972(7) 2_655
Ag1 Pt1 2.9097(5) 2_655
Cl1 C3 1.737(4) .
Cl2 C7 1.725(4) .
Cl3 C11 1.726(4) .
Cl4 C15 1.735(4) .
S1 O3 1.421(4) .
S1 O2 1.429(4) .
S1 O1 1.455(3) .
S1 C1 1.809(5) .
F1 C1 1.320(7) .
F2 C1 1.314(6) .
F3 C1 1.334(7) .
N1 C8 1.295(4) .
N1 C2 1.435(4) .
N2 C9 1.285(5) .
N2 C10 1.430(4) .
C2 C7 1.385(5) .
C2 C3 1.387(5) .
C3 C4 1.398(5) .
C4 C5 1.384(6) .
C5 C6 1.375(6) .
C6 C7 1.395(5) .
C8 C17 1.484(5) .
C8 C9 1.490(5) .
C9 C16 1.505(5) .
C10 C11 1.390(5) .
C10 C15 1.397(5) .
C11 C12 1.390(5) .
C12 C13 1.382(7) .
C13 C14 1.382(7) .
C14 C15 1.384(5) .
C20 C21 1.364(7) .
C20 C25 1.382(7) .
C21 C22 1.379(7) .
C22 C23 1.383(8) .
C23 C24 1.377(8) .
C24 C25 1.367(8) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C19 Pt1 Ag1 O1 44.00(17) . .
C18 Pt1 Ag1 O1 -51.93(17) . .
N2 Pt1 Ag1 O1 130.65(14) . .
N1 Pt1 Ag1 O1 -138.56(14) . .
Ag1 Pt1 Ag1 O1 177.68(11) 2_655 .
C19 Pt1 Ag1 Ag1 -133.68(13) . 2_655
C18 Pt1 Ag1 Ag1 130.39(13) . 2_655
N2 Pt1 Ag1 Ag1 -47.03(9) . 2_655
N1 Pt1 Ag1 Ag1 43.77(9) . 2_655
C19 Pt1 Ag1 Pt1 -133.68(13) . 2_655
C18 Pt1 Ag1 Pt1 130.39(13) . 2_655
N2 Pt1 Ag1 Pt1 -47.03(9) . 2_655
N1 Pt1 Ag1 Pt1 43.77(9) . 2_655
Ag1 Pt1 Ag1 Pt1 0.0 2_655 2_655
O3 S1 O1 Ag1 -150.0(3) . .
O2 S1 O1 Ag1 -13.2(4) . .
C1 S1 O1 Ag1 99.2(3) . .
Ag1 Ag1 O1 S1 140.9(2) 2_655 .
Pt1 Ag1 O1 S1 -31.2(4) . .
Pt1 Ag1 O1 S1 146.9(3) 2_655 .
C19 Pt1 N1 C8 48.1(8) . .
C18 Pt1 N1 C8 166.0(3) . .
N2 Pt1 N1 C8 -5.0(3) . .
Ag1 Pt1 N1 C8 -120.1(2) . .
Ag1 Pt1 N1 C8 -84.2(3) 2_655 .
C19 Pt1 N1 C2 -118.1(7) . .
C18 Pt1 N1 C2 -0.3(3) . .
N2 Pt1 N1 C2 -171.2(3) . .
Ag1 Pt1 N1 C2 73.7(3) . .
Ag1 Pt1 N1 C2 109.5(3) 2_655 .
C19 Pt1 N2 C9 -169.0(3) . .
C18 Pt1 N2 C9 -46.9(8) . .
N1 Pt1 N2 C9 1.5(3) . .
Ag1 Pt1 N2 C9 121.2(3) . .
Ag1 Pt1 N2 C9 82.6(3) 2_655 .
C19 Pt1 N2 C10 4.2(3) . .
C18 Pt1 N2 C10 126.3(7) . .
N1 Pt1 N2 C10 174.7(3) . .
Ag1 Pt1 N2 C10 -65.7(3) . .
Ag1 Pt1 N2 C10 -104.2(3) 2_655 .
O3 S1 C1 F2 58.8(5) . .
O2 S1 C1 F2 -63.0(5) . .
O1 S1 C1 F2 177.3(4) . .
O3 S1 C1 F1 -62.2(4) . .
O2 S1 C1 F1 176.0(4) . .
O1 S1 C1 F1 56.3(4) . .
O3 S1 C1 F3 179.0(4) . .
O2 S1 C1 F3 57.2(5) . .
O1 S1 C1 F3 -62.5(5) . .
C8 N1 C2 C7 108.2(4) . .
Pt1 N1 C2 C7 -86.1(4) . .
C8 N1 C2 C3 -77.7(5) . .
Pt1 N1 C2 C3 88.0(4) . .
C7 C2 C3 C4 -1.3(6) . .
N1 C2 C3 C4 -175.5(3) . .
C7 C2 C3 Cl1 177.5(3) . .
N1 C2 C3 Cl1 3.2(5) . .
C2 C3 C4 C5 0.7(6) . .
Cl1 C3 C4 C5 -178.0(3) . .
C3 C4 C5 C6 0.0(7) . .
C4 C5 C6 C7 -0.2(7) . .
C3 C2 C7 C6 1.1(6) . .
N1 C2 C7 C6 175.3(3) . .
C3 C2 C7 Cl2 179.9(3) . .
N1 C2 C7 Cl2 -5.9(5) . .
C5 C6 C7 C2 -0.4(6) . .
C5 C6 C7 Cl2 -179.2(3) . .
C2 N1 C8 C17 -2.4(6) . .
Pt1 N1 C8 C17 -168.8(3) . .
C2 N1 C8 C9 173.8(3) . .
Pt1 N1 C8 C9 7.3(4) . .
C10 N2 C9 C8 -171.5(3) . .
Pt1 N2 C9 C8 1.6(4) . .
C10 N2 C9 C16 6.1(6) . .
Pt1 N2 C9 C16 179.3(3) . .
N1 C8 C9 N2 -6.0(5) . .
C17 C8 C9 N2 170.5(3) . .
N1 C8 C9 C16 176.3(3) . .
C17 C8 C9 C16 -7.2(5) . .
C9 N2 C10 C11 -90.9(5) . .
Pt1 N2 C10 C11 96.3(4) . .
C9 N2 C10 C15 95.2(5) . .
Pt1 N2 C10 C15 -77.6(4) . .
C15 C10 C11 C12 0.3(6) . .
N2 C10 C11 C12 -173.7(4) . .
C15 C10 C11 Cl3 -177.5(3) . .
N2 C10 C11 Cl3 8.5(5) . .
C10 C11 C12 C13 -0.5(6) . .
Cl3 C11 C12 C13 177.3(3) . .
C11 C12 C13 C14 0.1(7) . .
C12 C13 C14 C15 0.7(8) . .
C13 C14 C15 C10 -0.9(7) . .
C13 C14 C15 Cl4 180.0(4) . .
C11 C10 C15 C14 0.4(6) . .
N2 C10 C15 C14 174.6(4) . .
C11 C10 C15 Cl4 179.5(3) . .
N2 C10 C15 Cl4 -6.3(5) . .
C25 C20 C21 C22 -0.3(8) . .
C20 C21 C22 C23 0.4(8) . .
C21 C22 C23 C24 -0.3(8) . .
C22 C23 C24 C25 0.2(9) . .
C23 C24 C25 C20 -0.2(9) . .
C21 C20 C25 C24 0.3(8) . .
