#------------------------------------------------------------------------------
#$Date: 2016-03-21 18:01:52 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178799 $
#$URL: svn://www.crystallography.net/cod/cif/4/10/53/4105355.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4105355
loop_
_publ_author_name
'Paul J. Lusby'
'Peter Müller'
'Sarah J. Pike'
'Alexandra M. Z. Slawin'
_publ_section_title
;
 Stimuli-Responsive Reversible Assembly of 2D and 3D Metallosupramolecular
 Architectures
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              16398
_journal_page_last               16400
_journal_paper_doi               10.1021/ja907297z
_journal_volume                  131
_journal_year                    2009
_chemical_formula_moiety         'C108 H80 F24 N12 P4 Pt4,5(C H3 N O2)'
_chemical_formula_sum            'C113 H95 F24 N17 O10 P4 Pt4'
_chemical_formula_weight         3211.30
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                97.384(7)
_cell_angle_beta                 100.261(7)
_cell_angle_gamma                116.076(7)
_cell_formula_units_Z            1
_cell_length_a                   13.5137(17)
_cell_length_b                   13.8563(18)
_cell_length_c                   21.010(2)
_cell_measurement_reflns_used    8615
_cell_measurement_temperature    93(2)
_cell_measurement_theta_max      27.8505
_cell_measurement_theta_min      2.6328
_cell_volume                     3380.6(7)
_computing_cell_refinement       'CrystalClear (Rigaku Corp., 2004)'
_computing_data_collection       'CrystalClear (Rigaku Corp., 2004)'
_computing_data_reduction        'CrystalClear (Rigaku Corp., 2004)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      93(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  CCD
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  confocal
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0521
_diffrn_reflns_av_sigmaI/netI    0.0492
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            33698
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.30
_diffrn_reflns_theta_min         2.63
_exptl_absorpt_coefficient_mu    4.262
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.8007
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.577
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1560
_exptl_crystal_size_max          0.1800
_exptl_crystal_size_mid          0.1800
_exptl_crystal_size_min          0.1200
_refine_diff_density_max         3.011
_refine_diff_density_min         -1.804
_refine_diff_density_rms         0.189
_refine_ls_extinction_coef       0.0033(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     905
_refine_ls_number_reflns         12098
_refine_ls_number_restraints     18
_refine_ls_restrained_S_all      1.045
_refine_ls_R_factor_all          0.0729
_refine_ls_R_factor_gt           0.0673
_refine_ls_shift/su_max          0.146
_refine_ls_shift/su_mean         0.005
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1196P)²+13.6452P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1857
_refine_ls_wR_factor_ref         0.1944
_reflns_number_gt                10719
_reflns_number_total             12098
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja907297z_si_003.cif
_cod_data_source_block           square
_cod_database_code               4105355
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt 0.084637(18) 0.023667(16) 0.783384(10) 0.05171(6) Uani 1 1 d .
C1 C 0.1313(5) -0.0912(5) 0.8049(3) 0.0604(16) Uani 1 1 d .
C2 C 0.0992(5) -0.1770(5) 0.7485(3) 0.0561(14) Uani 1 1 d .
C3 C 0.1156(5) -0.2677(5) 0.7544(3) 0.0664(17) Uani 1 1 d .
H3A H 0.0945 -0.3245 0.7162 0.080 Uiso 1 1 calc R
C4 C 0.1634(6) -0.2748(5) 0.8168(4) 0.081(2) Uani 1 1 d .
H4A H 0.1772 -0.3355 0.8212 0.097 Uiso 1 1 calc R
C5 C 0.1911(7) -0.1928(6) 0.8728(4) 0.089(2) Uani 1 1 d .
H5A H 0.2212 -0.1993 0.9156 0.106 Uiso 1 1 calc R
C6 C 0.1751(6) -0.1023(6) 0.8667(3) 0.0797(19) Uani 1 1 d .
H6A H 0.1944 -0.0471 0.9054 0.096 Uiso 1 1 calc R
C7 C 0.0480(5) -0.1620(4) 0.6838(3) 0.0530(14) Uani 1 1 d .
N8 N 0.0482(4) -0.0619(3) 0.6871(2) 0.0486(11) Uani 1 1 d .
C9 C 0.0162(4) -0.0367(4) 0.6297(3) 0.0516(14) Uani 1 1 d .
C10 C -0.0310(5) -0.1145(5) 0.5694(3) 0.0567(16) Uani 1 1 d .
H10A H -0.0572 -0.0959 0.5302 0.068 Uiso 1 1 calc R
C11 C -0.0401(5) -0.2173(5) 0.5659(3) 0.0595(16) Uani 1 1 d .
H11A H -0.0760 -0.2718 0.5252 0.071 Uiso 1 1 calc R
C12 C 0.0046(5) -0.2402(5) 0.6237(3) 0.0565(15) Uani 1 1 d .
H12A H 0.0054 -0.3087 0.6220 0.068 Uiso 1 1 calc R
C13 C 0.0467(5) 0.0806(4) 0.6294(3) 0.0512(14) Uani 1 1 d .
C14 C 0.1611(5) 0.1611(5) 0.6546(3) 0.0568(15) Uani 1 1 d .
H14A H 0.2163 0.1425 0.6758 0.068 Uiso 1 1 calc R
C15 C 0.1938(5) 0.2714(5) 0.6481(3) 0.0632(17) Uani 1 1 d .
H15A H 0.2715 0.3266 0.6634 0.076 Uiso 1 1 calc R
C16 C 0.1101(5) 0.2975(5) 0.6189(3) 0.0615(15) Uani 1 1 d .
H16A H 0.1310 0.3717 0.6163 0.074 Uiso 1 1 calc R
C17 C -0.0029(5) 0.2167(5) 0.5936(3) 0.0644(16) Uani 1 1 d .
H17A H -0.0581 0.2357 0.5728 0.077 Uiso 1 1 calc R
C18 C -0.0363(5) 0.1084(4) 0.5983(3) 0.0577(15) Uani 1 1 d .
H18A H -0.1139 0.0535 0.5808 0.069 Uiso 1 1 calc R
N19 N 0.0159(4) 0.1340(3) 0.7650(2) 0.0478(11) Uani 1 1 d .
C20 C -0.0961(5) 0.0957(4) 0.7496(3) 0.0569(15) Uani 1 1 d .
H20A H -0.1435 0.0190 0.7449 0.068 Uiso 1 1 calc R
C21 C -0.1482(5) 0.1612(5) 0.7399(3) 0.0592(16) Uani 1 1 d .
H21A H -0.2291 0.1300 0.7289 0.071 Uiso 1 1 calc R
C22 C -0.0787(5) 0.2748(4) 0.7468(3) 0.0535(14) Uani 1 1 d .
C23 C 0.0408(5) 0.3148(5) 0.7663(3) 0.0571(15) Uani 1 1 d .
H23A H 0.0912 0.3915 0.7733 0.068 Uiso 1 1 calc R
C24 C 0.0841(5) 0.2431(5) 0.7751(3) 0.0558(15) Uani 1 1 d .
H24A H 0.1646 0.2714 0.7887 0.067 Uiso 1 1 calc R
C25 C -0.1293(5) 0.3474(4) 0.7328(3) 0.0534(14) Uani 1 1 d .
C26 C -0.0887(5) 0.4221(4) 0.6930(3) 0.0546(14) Uani 1 1 d .
H26A H -0.0254 0.4292 0.6765 0.065 Uiso 1 1 calc R
C27 C -0.1402(5) 0.4847(4) 0.6779(3) 0.0558(14) Uani 1 1 d .
H27A H -0.1126 0.5337 0.6500 0.067 Uiso 1 1 calc R
N28 N -0.2295(4) 0.4799(4) 0.7013(2) 0.0499(11) Uani 1 1 d .
C29 C -0.2684(5) 0.4082(5) 0.7399(3) 0.0573(14) Uani 1 1 d .
H29A H -0.3312 0.4029 0.7563 0.069 Uiso 1 1 calc R
C30 C -0.2212(5) 0.3437(5) 0.7559(3) 0.0642(16) Uani 1 1 d .
H30A H -0.2511 0.2949 0.7836 0.077 Uiso 1 1 calc R
Pt31 Pt -0.298615(16) 0.589038(16) 0.678021(10) 0.04896(6) Uani 1 1 d .
C31 C -0.3364(5) 0.7070(5) 0.6556(3) 0.0549(15) Uani 1 1 d .
C32 C -0.3347(5) 0.7183(4) 0.5904(3) 0.0532(14) Uani 1 1 d .
C33 C -0.3480(5) 0.8031(4) 0.5677(3) 0.0614(17) Uani 1 1 d .
H33A H -0.3451 0.8108 0.5237 0.074 Uiso 1 1 calc R
C34 C -0.3657(6) 0.8767(5) 0.6102(4) 0.075(2) Uani 1 1 d .
H34A H -0.3754 0.9347 0.5953 0.090 Uiso 1 1 calc R
C35 C -0.3691(5) 0.8647(5) 0.6732(4) 0.071(2) Uani 1 1 d .
H35A H -0.3844 0.9132 0.7011 0.085 Uiso 1 1 calc R
C36 C -0.3511(5) 0.7851(5) 0.6978(4) 0.0647(17) Uani 1 1 d .
H36A H -0.3484 0.7823 0.7430 0.078 Uiso 1 1 calc R
C37 C -0.3327(5) 0.6256(4) 0.5464(3) 0.0520(14) Uani 1 1 d .
N38 N -0.3399(3) 0.5409(3) 0.5765(2) 0.0462(11) Uani 1 1 d .
C39 C -0.3638(4) 0.4437(4) 0.5383(3) 0.0513(14) Uani 1 1 d .
C40 C -0.3698(5) 0.4308(5) 0.4690(3) 0.0561(16) Uani 1 1 d .
H40A H -0.3866 0.3618 0.4425 0.067 Uiso 1 1 calc R
C41 C -0.3509(5) 0.5201(5) 0.4412(3) 0.0559(15) Uani 1 1 d .
H41A H -0.3496 0.5148 0.3959 0.067 Uiso 1 1 calc R
C42 C -0.3336(5) 0.6179(5) 0.4802(3) 0.0552(15) Uani 1 1 d .
H42A H -0.3225 0.6794 0.4612 0.066 Uiso 1 1 calc R
C43 C -0.3927(5) 0.3444(4) 0.5657(3) 0.0545(15) Uani 1 1 d .
C44 C -0.4704(5) 0.3177(5) 0.6059(3) 0.0569(16) Uani 1 1 d .
H44A H -0.4980 0.3670 0.6198 0.068 Uiso 1 1 calc R
C45 C -0.5052(5) 0.2174(6) 0.6243(3) 0.0692(19) Uani 1 1 d .
H45A H -0.5589 0.1970 0.6502 0.083 Uiso 1 1 calc R
C46 C -0.4635(7) 0.1478(5) 0.6057(4) 0.082(2) Uani 1 1 d .
H46A H -0.4902 0.0789 0.6181 0.098 Uiso 1 1 calc R
C47 C -0.3834(7) 0.1750(6) 0.5694(4) 0.087(2) Uani 1 1 d .
H47A H -0.3522 0.1274 0.5589 0.105 Uiso 1 1 calc R
C48 C -0.3492(5) 0.2729(5) 0.5486(4) 0.0657(18) Uani 1 1 d .
H48A H -0.2958 0.2915 0.5225 0.079 Uiso 1 1 calc R
N49 N -0.2574(4) 0.6513(4) 0.7779(2) 0.0537(12) Uani 1 1 d .
C50 C -0.3384(6) 0.6198(8) 0.8120(4) 0.100(3) Uani 1 1 d .
H50A H -0.4139 0.5642 0.7895 0.120 Uiso 1 1 calc R
C51 C -0.3135(7) 0.6665(8) 0.8784(4) 0.100(3) Uani 1 1 d .
H51A H -0.3730 0.6459 0.9003 0.120 Uiso 1 1 calc R
C52 C -0.2032(5) 0.7431(5) 0.9139(3) 0.0562(15) Uani 1 1 d .
C53 C -0.1196(7) 0.7720(7) 0.8793(3) 0.089(3) Uani 1 1 d .
H53A H -0.0422 0.8226 0.9015 0.106 Uiso 1 1 calc R
C54 C -0.1522(6) 0.7246(6) 0.8103(3) 0.077(2) Uani 1 1 d .
H54A H -0.0956 0.7467 0.7864 0.093 Uiso 1 1 calc R
C55 C -0.1760(5) 0.7963(5) 0.9861(3) 0.0580(16) Uani 1 1 d .
C56 C -0.2607(6) 0.7833(6) 1.0180(3) 0.074(2) Uani 1 1 d .
H56A H -0.3389 0.7382 0.9947 0.089 Uiso 1 1 calc R
C57 C -0.2303(6) 0.8363(6) 1.0838(3) 0.073(2) Uani 1 1 d .
H57A H -0.2893 0.8258 1.1053 0.088 Uiso 1 1 calc R
N58 N -0.1230(4) 0.9014(4) 1.1189(2) 0.0555(13) Uani 1 1 d .
C59 C -0.0384(6) 0.9153(5) 1.0886(3) 0.0675(18) Uani 1 1 d .
H59A H 0.0389 0.9615 1.1133 0.081 Uiso 1 1 calc R
C60 C -0.0619(6) 0.8640(5) 1.0233(3) 0.0659(18) Uani 1 1 d .
H60A H -0.0014 0.8741 1.0033 0.079 Uiso 1 1 calc R
P1 P 0.7118(4) 0.0093(4) 0.9008(2) 0.1808(17) Uani 1 1 d .
F1 F 0.7631(9) -0.0546(8) 0.8612(7) 0.238(6) Uani 1 1 d .
F2 F 0.6670(12) 0.0851(13) 0.9339(9) 0.340(8) Uani 1 1 d .
F3 F 0.7916(8) 0.0337(9) 0.9635(4) 0.218(5) Uani 1 1 d .
F4 F 0.6176(13) -0.0908(12) 0.9179(10) 0.431(12) Uani 1 1 d .
F5 F 0.8267(14) 0.1239(10) 0.8876(6) 0.295(7) Uani 1 1 d .
F6 F 0.6074(15) -0.0299(19) 0.8407(10) 0.460(12) Uani 1 1 d .
P2 P 0.0000 0.5000 0.5000 0.0489(5) Uani 1 2 d S
F7 F 0.0728(3) 0.6235(3) 0.4950(2) 0.0768(12) Uani 1 1 d .
F8 F 0.0582(4) 0.5372(3) 0.57858(19) 0.0788(12) Uani 1 1 d .
F9 F 0.0992(3) 0.4734(3) 0.4872(2) 0.0815(12) Uani 1 1 d .
P3 P 0.32949(4) 0.53213(4) 0.92711(3) 0.151(3) Uani 0.50 1 d PD
F10 F 0.23481(4) 0.54687(5) 0.88273(3) 0.197(8) Uani 0.50 1 d PD
F11 F 0.42417(4) 0.51737(5) 0.97150(3) 0.66(4) Uani 0.50 1 d PD
F12 F 0.35888(6) 0.49234(6) 0.86417(3) 0.64(4) Uani 0.50 1 d PD
F13 F 0.41721(6) 0.65299(4) 0.93094(4) 0.65(4) Uani 0.50 1 d PD
F14 F 0.30011(6) 0.57191(6) 0.99006(3) 0.322(19) Uani 0.50 1 d PD
F15 F 0.24178(6) 0.41126(5) 0.92329(4) 0.46(2) Uani 0.50 1 d PD
N71 N 0.4995(11) 0.0691(11) 0.7772(6) 0.085(4) Uani 0.50 1 d P
O71 O 0.5186(8) 0.0278(10) 0.7323(6) 0.107(3) Uani 0.50 1 d P
O72 O 0.4110(10) 0.0224(13) 0.8049(8) 0.125(6) Uani 0.50 1 d P
C71 C 0.5536(10) 0.1731(12) 0.7920(10) 0.099(5) Uani 0.50 1 d P
H71A H 0.5858 0.1991 0.7554 0.149 Uiso 0.50 1 calc PR
H71B H 0.6155 0.1984 0.8325 0.149 Uiso 0.50 1 calc PR
H71C H 0.5017 0.2026 0.7994 0.149 Uiso 0.50 1 calc PR
N73 N 0.7294(7) 0.0877(8) 0.4060(5) 0.054(3) Uani 0.50 1 d P
O73 O 0.7271(6) 0.0200(6) 0.3608(5) 0.067(2) Uani 0.50 1 d P
C73 C 0.7043(11) 0.1744(9) 0.3815(7) 0.065(4) Uani 0.50 1 d P
H73A H 0.6442 0.1792 0.3996 0.098 Uiso 0.50 1 calc PR
H73B H 0.6788 0.1542 0.3328 0.098 Uiso 0.50 1 calc PR
H73C H 0.7736 0.2462 0.3962 0.098 Uiso 0.50 1 calc PR
O74 O 0.7470(7) 0.0894(9) 0.4622(6) 0.084(3) Uani 0.50 1 d P
N75 N 0.4502(7) 0.3252(9) 0.8121(6) 0.068(3) Uani 0.50 1 d P
O75 O 0.4736(6) 0.3674(7) 0.7656(4) 0.063(2) Uani 0.50 1 d P
O76 O 0.3543(8) 0.2424(9) 0.7995(5) 0.078(3) Uani 0.50 1 d P
C75 C 0.5295(15) 0.3599(17) 0.8752(9) 0.108(6) Uani 0.50 1 d P
H75A H 0.6068 0.3859 0.8695 0.162 Uiso 0.50 1 calc PR
H75B H 0.5105 0.2977 0.8968 0.162 Uiso 0.50 1 calc PR
H75C H 0.5258 0.4201 0.9031 0.162 Uiso 0.50 1 calc PR
N77 N 0.3528(8) 0.6118(9) 0.7420(6) 0.081(4) Uani 0.50 1 d P
O77 O 0.3941(7) 0.5558(8) 0.7279(4) 0.071(3) Uani 0.50 1 d P
O78 O 0.2554(11) 0.5835(10) 0.7134(8) 0.193(5) Uani 0.50 1 d P
C77 C 0.4148(11) 0.7164(12) 0.7851(9) 0.090(5) Uani 0.50 1 d P
H77A H 0.4934 0.7311 0.8032 0.135 Uiso 0.50 1 calc PR
H77B H 0.3793 0.7193 0.8216 0.135 Uiso 0.50 1 calc PR
H77C H 0.4154 0.7723 0.7607 0.135 Uiso 0.50 1 calc PR
N79 N 1.0326(18) 0.5557(14) 1.0053(12) 0.144(7) Uani 0.50 1 d P
O79 O 1.041(2) 0.6401(18) 1.0629(15) 0.255(12) Uani 0.50 1 d P
O80 O 0.985(3) 0.595(2) 0.9535(19) 0.363(16) Uani 0.50 1 d P
C79 C 1.1552(19) 0.558(2) 1.0077(12) 0.136(8) Uani 0.50 1 d P
H79A H 1.1743 0.5269 1.0445 0.203 Uiso 0.50 1 calc PR
H79B H 1.2147 0.6343 1.0145 0.203 Uiso 0.50 1 calc PR
H79C H 1.1500 0.5138 0.9657 0.203 Uiso 0.50 1 calc PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Pt1 N58 93.3(2) . 2_567
C1 Pt1 N8 82.2(2) . .
N58 Pt1 N8 175.4(2) 2_567 .
C1 Pt1 N19 172.5(2) . .
N58 Pt1 N19 84.60(19) 2_567 .
N8 Pt1 N19 99.83(18) . .
C6 C1 C2 118.4(6) . .
C6 C1 Pt1 128.5(5) . .
C2 C1 Pt1 112.6(5) . .
C3 C2 C1 121.0(6) . .
C3 C2 C7 123.4(5) . .
C1 C2 C7 115.7(6) . .
C2 C3 C4 119.3(6) . .
C2 C3 H3A 120.3 . .
C4 C3 H3A 120.3 . .
C3 C4 C5 120.0(7) . .
C3 C4 H4A 120.0 . .
C5 C4 H4A 120.0 . .
C6 C5 C4 120.5(7) . .
C6 C5 H5A 119.7 . .
C4 C5 H5A 119.7 . .
C5 C6 C1 120.8(7) . .
C5 C6 H6A 119.6 . .
C1 C6 H6A 119.6 . .
N8 C7 C12 121.1(5) . .
N8 C7 C2 114.7(5) . .
C12 C7 C2 124.2(5) . .
C9 N8 C7 118.2(4) . .
C9 N8 Pt1 128.6(4) . .
C7 N8 Pt1 112.9(4) . .
N8 C9 C10 121.4(5) . .
N8 C9 C13 119.2(4) . .
C10 C9 C13 118.8(5) . .
C11 C10 C9 120.8(6) . .
C11 C10 H10A 119.6 . .
C9 C10 H10A 119.6 . .
C10 C11 C12 118.3(5) . .
C10 C11 H11A 120.9 . .
C12 C11 H11A 120.9 . .
C11 C12 C7 119.5(6) . .
C11 C12 H12A 120.2 . .
C7 C12 H12A 120.2 . .
C14 C13 C18 120.5(5) . .
C14 C13 C9 118.4(5) . .
C18 C13 C9 120.8(4) . .
C13 C14 C15 119.1(6) . .
C13 C14 H14A 120.4 . .
C15 C14 H14A 120.4 . .
C16 C15 C14 119.3(5) . .
C16 C15 H15A 120.3 . .
C14 C15 H15A 120.3 . .
C17 C16 C15 120.9(6) . .
C17 C16 H16A 119.6 . .
C15 C16 H16A 119.6 . .
C16 C17 C18 120.8(6) . .
C16 C17 H17A 119.6 . .
C18 C17 H17A 119.6 . .
C17 C18 C13 119.3(5) . .
C17 C18 H18A 120.4 . .
C13 C18 H18A 120.4 . .
C20 N19 C24 118.8(5) . .
C20 N19 Pt1 119.5(4) . .
C24 N19 Pt1 121.4(4) . .
N19 C20 C21 123.8(5) . .
N19 C20 H20A 118.1 . .
C21 C20 H20A 118.1 . .
C20 C21 C22 118.4(5) . .
C20 C21 H21A 120.8 . .
C22 C21 H21A 120.8 . .
C21 C22 C23 116.9(6) . .
C21 C22 C25 120.9(5) . .
C23 C22 C25 122.2(5) . .
C24 C23 C22 120.2(5) . .
C24 C23 H23A 119.9 . .
C22 C23 H23A 119.9 . .
N19 C24 C23 121.8(5) . .
N19 C24 H24A 119.1 . .
C23 C24 H24A 119.1 . .
C30 C25 C26 116.4(6) . .
C30 C25 C22 122.9(6) . .
C26 C25 C22 120.7(6) . .
C27 C26 C25 119.9(6) . .
C27 C26 H26A 120.1 . .
C25 C26 H26A 120.1 . .
N28 C27 C26 122.6(6) . .
N28 C27 H27A 118.7 . .
C26 C27 H27A 118.7 . .
C29 N28 C27 117.5(5) . .
C29 N28 Pt31 123.2(4) . .
C27 N28 Pt31 119.3(4) . .
C30 C29 N28 122.3(6) . .
C30 C29 H29A 118.9 . .
N28 C29 H29A 118.9 . .
C29 C30 C25 121.3(6) . .
C29 C30 H30A 119.4 . .
C25 C30 H30A 119.4 . .
C31 Pt31 N49 93.1(2) . .
C31 Pt31 N38 81.3(2) . .
N49 Pt31 N38 174.3(2) . .
C31 Pt31 N28 170.4(2) . .
N49 Pt31 N28 87.2(2) . .
N38 Pt31 N28 98.09(18) . .
C32 C31 C36 117.9(6) . .
C32 C31 Pt31 112.8(5) . .
C36 C31 Pt31 128.9(5) . .
C33 C32 C31 121.1(6) . .
C33 C32 C37 123.7(6) . .
C31 C32 C37 114.7(5) . .
C32 C33 C34 119.4(7) . .
C32 C33 H33A 120.3 . .
C34 C33 H33A 120.3 . .
C35 C34 C33 119.5(7) . .
C35 C34 H34A 120.3 . .
C33 C34 H34A 120.3 . .
C34 C35 C36 122.3(7) . .
C34 C35 H35A 118.8 . .
C36 C35 H35A 118.8 . .
C35 C36 C31 119.6(7) . .
C35 C36 H36A 120.2 . .
C31 C36 H36A 120.2 . .
N38 C37 C42 121.4(5) . .
N38 C37 C32 113.6(5) . .
C42 C37 C32 124.8(6) . .
C39 N38 C37 118.7(5) . .
C39 N38 Pt31 128.8(4) . .
C37 N38 Pt31 112.3(3) . .
N38 C39 C40 121.3(5) . .
N38 C39 C43 121.0(5) . .
C40 C39 C43 117.6(5) . .
C41 C40 C39 118.8(6) . .
C41 C40 H40A 120.6 . .
C39 C40 H40A 120.6 . .
C40 C41 C42 119.4(6) . .
C40 C41 H41A 120.3 . .
C42 C41 H41A 120.3 . .
C37 C42 C41 119.9(6) . .
C37 C42 H42A 120.1 . .
C41 C42 H42A 120.1 . .
C48 C43 C44 119.7(6) . .
C48 C43 C39 120.1(6) . .
C44 C43 C39 120.1(6) . .
C45 C44 C43 118.2(6) . .
C45 C44 H44A 120.9 . .
C43 C44 H44A 120.9 . .
C46 C45 C44 121.0(7) . .
C46 C45 H45A 119.5 . .
C44 C45 H45A 119.5 . .
C45 C46 C47 121.5(7) . .
C45 C46 H46A 119.2 . .
C47 C46 H46A 119.2 . .
C46 C47 C48 119.0(8) . .
C46 C47 H47A 120.5 . .
C48 C47 H47A 120.5 . .
C47 C48 C43 120.5(7) . .
C47 C48 H48A 119.8 . .
C43 C48 H48A 119.8 . .
C54 N49 C50 118.6(6) . .
C54 N49 Pt31 120.6(5) . .
C50 N49 Pt31 120.8(4) . .
N49 C50 C51 121.5(7) . .
N49 C50 H50A 119.3 . .
C51 C50 H50A 119.3 . .
C50 C51 C52 121.0(7) . .
C50 C51 H51A 119.5 . .
C52 C51 H51A 119.5 . .
C51 C52 C53 117.2(6) . .
C51 C52 C55 121.2(6) . .
C53 C52 C55 121.5(5) . .
C52 C53 C54 118.7(6) . .
C52 C53 H53A 120.6 . .
C54 C53 H53A 120.6 . .
N49 C54 C53 122.8(7) . .
N49 C54 H54A 118.6 . .
C53 C54 H54A 118.6 . .
C56 C55 C60 117.6(6) . .
C56 C55 C52 122.0(5) . .
C60 C55 C52 120.3(6) . .
C57 C56 C55 119.2(6) . .
C57 C56 H56A 120.4 . .
C55 C56 H56A 120.4 . .
N58 C57 C56 123.4(7) . .
N58 C57 H57A 118.3 . .
C56 C57 H57A 118.3 . .
C57 N58 C59 118.5(5) . .
C57 N58 Pt1 121.1(5) . 2_567
C59 N58 Pt1 120.4(4) . 2_567
N58 C59 C60 121.5(6) . .
N58 C59 H59A 119.3 . .
C60 C59 H59A 119.3 . .
C59 C60 C55 119.8(7) . .
C59 C60 H60A 120.1 . .
C55 C60 H60A 120.1 . .
F3 P1 F6 168.2(11) . .
F3 P1 F4 91.9(8) . .
F6 P1 F4 77.1(11) . .
F3 P1 F2 89.7(8) . .
F6 P1 F2 86.0(10) . .
F4 P1 F2 88.7(11) . .
F3 P1 F1 93.7(8) . .
F6 P1 F1 92.0(10) . .
F4 P1 F1 98.5(10) . .
F2 P1 F1 171.9(10) . .
F3 P1 F5 83.3(6) . .
F6 P1 F5 107.7(11) . .
F4 P1 F5 175.2(9) . .
F2 P1 F5 91.8(9) . .
F1 P1 F5 81.3(7) . .
F7 P2 F7 179.997(2) . 2_566
F7 P2 F9 89.9(2) . 2_566
F7 P2 F9 90.1(2) 2_566 2_566
F7 P2 F9 90.1(2) . .
F7 P2 F9 89.9(2) 2_566 .
F9 P2 F9 180.000(2) 2_566 .
F7 P2 F8 90.9(2) . 2_566
F7 P2 F8 89.1(2) 2_566 2_566
F9 P2 F8 90.4(2) 2_566 2_566
F9 P2 F8 89.6(2) . 2_566
F7 P2 F8 89.1(2) . .
F7 P2 F8 90.9(2) 2_566 .
F9 P2 F8 89.6(2) 2_566 .
F9 P2 F8 90.4(2) . .
F8 P2 F8 180.000(2) 2_566 .
F10 P3 F12 90.01(4) . .
F10 P3 F13 90.01(4) . .
F12 P3 F13 90.01(5) . .
F10 P3 F14 90.00(5) . .
F12 P3 F14 179.99(7) . .
F13 P3 F14 90.00(4) . .
F10 P3 F11 179.99(7) . .
F12 P3 F11 90.00(5) . .
F13 P3 F11 90.00(4) . .
F14 P3 F11 89.99(4) . .
F10 P3 F15 90.00(4) . .
F12 P3 F15 90.00(4) . .
F13 P3 F15 179.99(8) . .
F14 P3 F15 90.00(5) . .
F11 P3 F15 89.99(5) . .
O71 N71 C71 114.2(14) . .
O71 N71 O72 128.0(13) . .
C71 N71 O72 116.0(15) . .
N71 C71 H71A 109.5 . .
N71 C71 H71B 109.5 . .
H71A C71 H71B 109.5 . .
N71 C71 H71C 109.5 . .
H71A C71 H71C 109.5 . .
H71B C71 H71C 109.5 . .
O74 N73 O73 127.1(13) . .
O74 N73 C73 119.8(11) . .
O73 N73 C73 113.1(10) . .
N73 C73 H73A 109.5 . .
N73 C73 H73B 109.5 . .
H73A C73 H73B 109.5 . .
N73 C73 H73C 109.5 . .
H73A C73 H73C 109.5 . .
H73B C73 H73C 109.5 . .
O75 N75 O76 115.8(10) . .
O75 N75 C75 123.1(11) . .
O76 N75 C75 120.8(14) . .
N75 C75 H75A 109.5 . .
N75 C75 H75B 109.5 . .
H75A C75 H75B 109.5 . .
N75 C75 H75C 109.5 . .
H75A C75 H75C 109.5 . .
H75B C75 H75C 109.5 . .
O77 N77 O78 119.1(11) . .
O77 N77 C77 123.1(11) . .
O78 N77 C77 117.4(13) . .
N77 C77 H77A 109.5 . .
N77 C77 H77B 109.5 . .
H77A C77 H77B 109.5 . .
N77 C77 H77C 109.5 . .
H77A C77 H77C 109.5 . .
H77B C77 H77C 109.5 . .
N79 N79 O80 110(2) 2_767 .
N79 N79 O79 125(3) 2_767 .
O80 N79 O79 95(2) . .
N79 N79 C79 98(2) 2_767 .
O80 N79 C79 119(2) . .
O79 N79 C79 112.1(17) . .
N79 C79 H79A 109.5 . .
N79 C79 H79B 109.5 . .
H79A C79 H79B 109.5 . .
N79 C79 H79C 109.5 . .
H79A C79 H79C 109.5 . .
H79B C79 H79C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C1 2.025(7) .
Pt1 N58 2.041(4) 2_567
Pt1 N8 2.063(4) .
Pt1 N19 2.149(5) .
C1 C6 1.385(9) .
C1 C2 1.417(8) .
C2 C3 1.387(9) .
C2 C7 1.494(8) .
C3 C4 1.389(10) .
C3 H3A 0.9500 .
C4 C5 1.394(11) .
C4 H4A 0.9500 .
C5 C6 1.380(11) .
C5 H5A 0.9500 .
C6 H6A 0.9500 .
C7 N8 1.379(7) .
C7 C12 1.392(8) .
N8 C9 1.348(7) .
C9 C10 1.389(8) .
C9 C13 1.492(8) .
C10 C11 1.366(9) .
C10 H10A 0.9500 .
C11 C12 1.395(9) .
C11 H11A 0.9500 .
C12 H12A 0.9500 .
C13 C14 1.398(7) .
C13 C18 1.421(9) .
C14 C15 1.426(9) .
C14 H14A 0.9500 .
C15 C16 1.398(10) .
C15 H15A 0.9500 .
C16 C17 1.387(8) .
C16 H16A 0.9500 .
C17 C18 1.386(9) .
C17 H17A 0.9500 .
C18 H18A 0.9500 .
N19 C20 1.324(7) .
N19 C24 1.343(7) .
C20 C21 1.385(10) .
C20 H20A 0.9500 .
C21 C22 1.406(8) .
C21 H21A 0.9500 .
C22 C23 1.415(8) .
C22 C25 1.476(9) .
C23 C24 1.373(9) .
C23 H23A 0.9500 .
C24 H24A 0.9500 .
C25 C30 1.395(9) .
C25 C26 1.399(8) .
C26 C27 1.363(9) .
C26 H26A 0.9500 .
C27 N28 1.360(8) .
C27 H27A 0.9500 .
N28 C29 1.349(8) .
N28 Pt31 2.161(5) .
C29 C30 1.349(10) .
C29 H29A 0.9500 .
C30 H30A 0.9500 .
Pt31 C31 2.000(7) .
Pt31 N49 2.037(5) .
Pt31 N38 2.046(4) .
C31 C32 1.402(9) .
C31 C36 1.415(9) .
C32 C33 1.392(9) .
C32 C37 1.496(8) .
C33 C34 1.399(10) .
C33 H33A 0.9500 .
C34 C35 1.361(12) .
C34 H34A 0.9500 .
C35 C36 1.373(10) .
C35 H35A 0.9500 .
C36 H36A 0.9500 .
C37 N38 1.377(8) .
C37 C42 1.379(9) .
N38 C39 1.345(7) .
C39 C40 1.428(8) .
C39 C43 1.479(8) .
C40 C41 1.377(9) .
C40 H40A 0.9500 .
C41 C42 1.389(9) .
C41 H41A 0.9500 .
C42 H42A 0.9500 .
C43 C48 1.398(9) .
C43 C44 1.416(9) .
C44 C45 1.389(9) .
C44 H44A 0.9500 .
C45 C46 1.364(12) .
C45 H45A 0.9500 .
C46 C47 1.380(12) .
C46 H46A 0.9500 .
C47 C48 1.384(10) .
C47 H47A 0.9500 .
C48 H48A 0.9500 .
N49 C54 1.313(8) .
N49 C50 1.357(9) .
C50 C51 1.374(10) .
C50 H50A 0.9500 .
C51 C52 1.384(9) .
C51 H51A 0.9500 .
C52 C53 1.390(10) .
C52 C55 1.501(8) .
C53 C54 1.414(9) .
C53 H53A 0.9500 .
C54 H54A 0.9500 .
C55 C56 1.383(10) .
C55 C60 1.407(8) .
C56 C57 1.376(9) .
C56 H56A 0.9500 .
C57 N58 1.326(8) .
C57 H57A 0.9500 .
N58 C59 1.358(9) .
N58 Pt1 2.041(4) 2_567
C59 C60 1.374(9) .
C59 H59A 0.9500 .
C60 H60A 0.9500 .
P1 F3 1.439(9) .
P1 F6 1.548(16) .
P1 F4 1.554(16) .
P1 F2 1.573(16) .
P1 F1 1.586(13) .
P1 F5 1.762(14) .
P2 F7 1.584(3) .
P2 F7 1.584(3) 2_566
P2 F9 1.594(4) 2_566
P2 F9 1.594(4) .
P2 F8 1.604(4) 2_566
P2 F8 1.604(4) .
P3 F10 1.5498(7) .
P3 F12 1.5499(7) .
P3 F13 1.5500(7) .
P3 F14 1.5500(7) .
P3 F11 1.5500(7) .
P3 F15 1.5500(7) .
N71 O71 1.167(17) .
N71 C71 1.259(19) .
N71 O72 1.362(18) .
C71 H71A 0.9800 .
C71 H71B 0.9800 .
C71 H71C 0.9800 .
N73 O74 1.159(15) .
N73 O73 1.232(13) .
N73 C73 1.509(17) .
C73 H73A 0.9800 .
C73 H73B 0.9800 .
C73 H73C 0.9800 .
N75 O75 1.221(15) .
N75 O76 1.248(12) .
N75 C75 1.42(2) .
C75 H75A 0.9800 .
C75 H75B 0.9800 .
C75 H75C 0.9800 .
N77 O77 1.175(15) .
N77 O78 1.204(16) .
N77 C77 1.395(16) .
C77 H77A 0.9800 .
C77 H77B 0.9800 .
C77 H77C 0.9800 .
N79 N79 1.36(3) 2_767
N79 O80 1.45(3) .
N79 O79 1.52(3) .
N79 C79 1.64(3) .
C79 H79A 0.9800 .
C79 H79B 0.9800 .
C79 H79C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N58 Pt1 C1 C6 -1.4(6) 2_567 .
N8 Pt1 C1 C6 179.2(6) . .
N58 Pt1 C1 C2 169.7(5) 2_567 .
N8 Pt1 C1 C2 -9.7(4) . .
C6 C1 C2 C3 -2.7(9) . .
Pt1 C1 C2 C3 -174.8(5) . .
C6 C1 C2 C7 177.5(6) . .
Pt1 C1 C2 C7 5.4(7) . .
C1 C2 C3 C4 0.6(9) . .
C7 C2 C3 C4 -179.7(6) . .
C2 C3 C4 C5 1.9(11) . .
C3 C4 C5 C6 -2.2(12) . .
C4 C5 C6 C1 0.0(12) . .
C2 C1 C6 C5 2.4(11) . .
Pt1 C1 C6 C5 173.1(6) . .
C3 C2 C7 N8 -174.4(5) . .
C1 C2 C7 N8 5.4(8) . .
C3 C2 C7 C12 4.5(9) . .
C1 C2 C7 C12 -175.7(6) . .
C12 C7 N8 C9 -6.7(8) . .
C2 C7 N8 C9 172.2(5) . .
C12 C7 N8 Pt1 167.7(4) . .
C2 C7 N8 Pt1 -13.3(6) . .
C1 Pt1 N8 C9 -173.4(5) . .
N19 Pt1 N8 C9 13.9(5) . .
C1 Pt1 N8 C7 12.9(4) . .
N19 Pt1 N8 C7 -159.8(4) . .
C7 N8 C9 C10 8.9(8) . .
Pt1 N8 C9 C10 -164.6(4) . .
C7 N8 C9 C13 -162.5(5) . .
Pt1 N8 C9 C13 24.1(8) . .
N8 C9 C10 C11 -4.0(9) . .
C13 C9 C10 C11 167.5(6) . .
C9 C10 C11 C12 -3.3(9) . .
C10 C11 C12 C7 5.4(9) . .
N8 C7 C12 C11 -0.4(9) . .
C2 C7 C12 C11 -179.3(6) . .
N8 C9 C13 C14 53.5(8) . .
C10 C9 C13 C14 -118.1(6) . .
N8 C9 C13 C18 -132.7(6) . .
C10 C9 C13 C18 55.7(8) . .
C18 C13 C14 C15 -0.6(9) . .
C9 C13 C14 C15 173.2(5) . .
C13 C14 C15 C16 2.4(9) . .
C14 C15 C16 C17 -3.0(9) . .
C15 C16 C17 C18 1.8(10) . .
C16 C17 C18 C13 0.0(9) . .
C14 C13 C18 C17 -0.6(9) . .
C9 C13 C18 C17 -174.2(6) . .
N58 Pt1 N19 C20 -103.5(4) 2_567 .
N8 Pt1 N19 C20 75.3(4) . .
N58 Pt1 N19 C24 69.9(4) 2_567 .
N8 Pt1 N19 C24 -111.2(4) . .
C24 N19 C20 C21 3.3(9) . .
Pt1 N19 C20 C21 176.9(5) . .
N19 C20 C21 C22 0.0(10) . .
C20 C21 C22 C23 -2.8(9) . .
C20 C21 C22 C25 176.0(6) . .
C21 C22 C23 C24 2.5(9) . .
C25 C22 C23 C24 -176.3(6) . .
C20 N19 C24 C23 -3.6(8) . .
Pt1 N19 C24 C23 -177.1(4) . .
C22 C23 C24 N19 0.7(9) . .
C21 C22 C25 C30 45.5(8) . .
C23 C22 C25 C30 -135.8(6) . .
C21 C22 C25 C26 -132.4(6) . .
C23 C22 C25 C26 46.4(8) . .
C30 C25 C26 C27 -1.2(8) . .
C22 C25 C26 C27 176.8(5) . .
C25 C26 C27 N28 1.4(8) . .
C26 C27 N28 C29 -1.1(7) . .
C26 C27 N28 Pt31 177.0(4) . .
C27 N28 C29 C30 0.7(8) . .
Pt31 N28 C29 C30 -177.4(4) . .
N28 C29 C30 C25 -0.5(9) . .
C26 C25 C30 C29 0.7(8) . .
C22 C25 C30 C29 -177.2(5) . .
C29 N28 Pt31 N49 58.1(4) . .
C27 N28 Pt31 N49 -119.9(4) . .
C29 N28 Pt31 N38 -124.1(4) . .
C27 N28 Pt31 N38 58.0(4) . .
N49 Pt31 C31 C32 160.3(4) . .
N38 Pt31 C31 C32 -18.5(4) . .
N49 Pt31 C31 C36 -12.0(5) . .
N38 Pt31 C31 C36 169.2(5) . .
C36 C31 C32 C33 -0.6(8) . .
Pt31 C31 C32 C33 -173.8(4) . .
C36 C31 C32 C37 -173.2(5) . .
Pt31 C31 C32 C37 13.6(6) . .
C31 C32 C33 C34 -1.3(8) . .
C37 C32 C33 C34 170.6(5) . .
C32 C33 C34 C35 0.4(9) . .
C33 C34 C35 C36 2.7(9) . .
C34 C35 C36 C31 -4.6(9) . .
C32 C31 C36 C35 3.5(8) . .
Pt31 C31 C36 C35 175.4(4) . .
C33 C32 C37 N38 -168.6(5) . .
C31 C32 C37 N38 3.8(7) . .
C33 C32 C37 C42 5.9(9) . .
C31 C32 C37 C42 178.3(5) . .
C42 C37 N38 C39 -9.0(8) . .
C32 C37 N38 C39 165.7(5) . .
C42 C37 N38 Pt31 166.4(4) . .
C32 C37 N38 Pt31 -18.9(6) . .
C31 Pt31 N38 C39 -164.3(5) . .
N28 Pt31 N38 C39 25.3(5) . .
C31 Pt31 N38 C37 20.8(4) . .
N28 Pt31 N38 C37 -149.5(4) . .
C37 N38 C39 C40 6.5(8) . .
Pt31 N38 C39 C40 -168.0(4) . .
C37 N38 C39 C43 -169.1(5) . .
Pt31 N38 C39 C43 16.4(8) . .
N38 C39 C40 C41 -0.1(8) . .
C43 C39 C40 C41 175.7(5) . .
C39 C40 C41 C42 -4.0(8) . .
N38 C37 C42 C41 5.0(8) . .
C32 C37 C42 C41 -169.2(5) . .
C40 C41 C42 C37 1.7(8) . .
N38 C39 C43 C48 -139.1(6) . .
C40 C39 C43 C48 45.0(7) . .
N38 C39 C43 C44 45.0(7) . .
C40 C39 C43 C44 -130.8(6) . .
C48 C43 C44 C45 -3.1(8) . .
C39 C43 C44 C45 172.8(5) . .
C43 C44 C45 C46 1.7(9) . .
C44 C45 C46 C47 1.5(11) . .
C45 C46 C47 C48 -3.3(12) . .
C46 C47 C48 C43 1.8(11) . .
C44 C43 C48 C47 1.4(9) . .
C39 C43 C48 C47 -174.5(6) . .
C31 Pt31 N49 C54 -90.2(6) . .
N28 Pt31 N49 C54 80.2(6) . .
C31 Pt31 N49 C50 88.4(7) . .
N28 Pt31 N49 C50 -101.2(7) . .
C54 N49 C50 C51 3.1(15) . .
Pt31 N49 C50 C51 -175.6(8) . .
N49 C50 C51 C52 -3.8(17) . .
C50 C51 C52 C53 1.2(15) . .
C50 C51 C52 C55 178.6(9) . .
C51 C52 C53 C54 1.8(13) . .
C55 C52 C53 C54 -175.6(8) . .
C50 N49 C54 C53 0.0(13) . .
Pt31 N49 C54 C53 178.7(7) . .
C52 C53 C54 N49 -2.5(14) . .
C51 C52 C55 C56 -8.9(11) . .
C53 C52 C55 C56 168.4(8) . .
C51 C52 C55 C60 172.5(8) . .
C53 C52 C55 C60 -10.2(11) . .
C60 C55 C56 C57 0.1(11) . .
C52 C55 C56 C57 -178.5(7) . .
C55 C56 C57 N58 0.8(13) . .
C56 C57 N58 C59 -1.0(12) . .
C56 C57 N58 Pt1 -179.5(6) . 2_567
C57 N58 C59 C60 0.2(11) . .
Pt1 N58 C59 C60 178.7(6) 2_567 .
N58 C59 C60 C55 0.7(11) . .
C56 C55 C60 C59 -0.9(11) . .
C52 C55 C60 C59 177.7(7) . .
