#------------------------------------------------------------------------------
#$Date: 2016-03-21 18:09:44 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178803 $
#$URL: svn://www.crystallography.net/cod/cif/4/10/57/4105784.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4105784
loop_
_publ_author_name
'Yun-Peng Xie'
'Thomas C. W. Mak'
_publ_section_title
;
 Silver(I)-Ethynide Clusters Constructed with Phosphonate-Functionized
 Polyoxovanadates
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              3760
_journal_page_last               3763
_journal_paper_doi               10.1021/ja1112035
_journal_volume                  133
_journal_year                    2011
_chemical_formula_sum            'C84 H134 Ag16 N11 O60 P8 V8'
_chemical_formula_weight         4639.22
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 130.765(11)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   17.396(4)
_cell_length_b                   25.696(6)
_cell_length_c                   22.829(4)
_cell_measurement_reflns_used    9599
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.22
_cell_measurement_theta_min      2.61
_cell_volume                     7729(3)
_computing_cell_refinement       SAINT(Bruker,2001)
_computing_data_collection       APEX2(Bruker,2003)
_computing_data_reduction        APEX2(Bruker,2003)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0680
_diffrn_reflns_av_sigmaI/netI    0.0483
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_k_min       -33
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            120189
_diffrn_reflns_theta_full        27.93
_diffrn_reflns_theta_max         27.93
_diffrn_reflns_theta_min         1.58
_exptl_absorpt_coefficient_mu    2.594
_exptl_absorpt_correction_T_max  0.816
_exptl_absorpt_correction_T_min  0.745
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            orang-red
_exptl_crystal_density_diffrn    1.993
_exptl_crystal_description       block
_exptl_crystal_F_000             4502
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_refine_diff_density_max         4.248
_refine_diff_density_min         -2.538
_refine_diff_density_rms         0.164
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     802
_refine_ls_number_reflns         18362
_refine_ls_number_restraints     10
_refine_ls_restrained_S_all      1.032
_refine_ls_R_factor_all          0.1280
_refine_ls_R_factor_gt           0.0675
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1039P)²+45.0117P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1773
_refine_ls_wR_factor_ref         0.2292
_reflns_number_gt                10503
_reflns_number_total             18362
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja1112035_si_002_1.cif
_cod_data_source_block           1
_cod_database_code               4105784
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.66577(6) -0.07690(3) 0.90528(5) 0.0675(2) Uani 1 1 d .
Ag2 Ag 0.42698(6) -0.05776(3) 0.83974(5) 0.0679(2) Uani 1 1 d .
Ag3 Ag 0.28403(7) 0.01205(3) 0.70862(5) 0.0684(2) Uani 1 1 d .
Ag4 Ag 0.22968(7) -0.03786(3) 0.78932(5) 0.0674(2) Uani 1 1 d .
Ag5 Ag 0.10759(7) 0.01521(4) 0.84825(5) 0.0751(3) Uani 1 1 d .
Ag6 Ag 0.27541(7) -0.14669(3) 0.78385(5) 0.0713(2) Uani 1 1 d .
Ag7 Ag 0.68526(8) -0.07227(4) 1.04474(5) 0.0844(3) Uani 1 1 d .
Ag8 Ag 0.73188(10) 0.01933(3) 0.99813(6) 0.1037(4) Uani 1 1 d .
V1 V 0.35537(12) -0.14478(6) 1.07899(9) 0.0487(3) Uani 1 1 d .
V2 V 0.38822(12) -0.20409(6) 0.96296(9) 0.0512(4) Uani 1 1 d .
V3 V 0.64638(12) -0.19305(5) 1.10393(9) 0.0498(3) Uani 1 1 d .
V4 V 0.38601(11) 0.13653(5) 0.77662(8) 0.0462(3) Uani 1 1 d .
P1 P 0.20297(18) -0.12087(9) 0.89249(13) 0.0496(5) Uani 1 1 d .
P2 P 0.53374(18) -0.17593(8) 0.92341(13) 0.0466(5) Uani 1 1 d .
P3 P 0.53689(18) 0.04161(8) 0.81257(14) 0.0487(5) Uani 1 1 d .
P4 P 0.20929(17) 0.09795(9) 0.77890(13) 0.0480(5) Uani 1 1 d .
O1 O 0.1762(6) -0.0712(2) 0.8488(4) 0.0639(17) Uani 1 1 d .
O2 O 0.2527(5) -0.1100(2) 0.9770(3) 0.0530(14) Uani 1 1 d .
O3 O 0.2735(5) -0.1553(2) 0.8897(4) 0.0533(14) Uani 1 1 d .
O4 O 0.4306(5) -0.1797(2) 0.9052(3) 0.0507(14) Uani 1 1 d .
O5 O 0.5322(5) -0.1309(2) 0.8810(4) 0.0610(16) Uani 1 1 d .
O6 O 0.6222(5) -0.1704(2) 1.0118(4) 0.0543(15) Uani 1 1 d .
O7 O 0.5393(5) -0.0140(2) 0.8339(5) 0.0686(19) Uani 1 1 d .
O8 O 0.4342(5) 0.0670(2) 0.7756(4) 0.0515(14) Uani 1 1 d .
O9 O 0.6242(5) 0.0723(2) 0.8847(3) 0.0522(14) Uani 1 1 d .
O10 O 0.2782(4) 0.0930(2) 0.7586(3) 0.0498(13) Uani 1 1 d .
O11 O 0.1900(5) 0.0457(2) 0.7964(4) 0.0639(17) Uani 1 1 d .
O13 O 0.2877(5) -0.1701(3) 1.0943(4) 0.0637(17) Uani 1 1 d .
O14 O 0.3594(5) -0.1950(2) 1.0251(4) 0.0536(14) Uani 1 1 d .
O15 O 0.3379(5) -0.2595(2) 0.9247(4) 0.0624(17) Uani 1 1 d .
O16 O 0.5203(5) -0.2209(2) 1.0403(3) 0.0552(15) Uani 1 1 d .
O17 O 0.2604(5) 0.1334(2) 0.8500(4) 0.0557(15) Uani 1 1 d .
O18 O 0.7190(5) -0.2420(2) 1.1333(4) 0.0651(17) Uani 1 1 d .
O19 O 0.3598(5) 0.1831(2) 0.8202(3) 0.0512(14) Uani 1 1 d .
O20 O 0.3322(5) 0.1593(3) 0.6935(4) 0.0630(17) Uani 1 1 d .
O21 O 0.5167(5) 0.1568(2) 0.8329(3) 0.0535(15) Uani 1 1 d .
O22 O 0.1987(11) 0.0365(5) 0.5842(6) 0.125(4) Uani 1 1 d .
O23 O 0.1982(8) -0.2239(4) 0.7242(6) 0.100(3) Uani 1 1 d .
O24 O 0.6706(8) -0.1137(3) 0.8166(6) 0.090(3) Uani 1 1 d .
O25 O 0.5153(8) -0.0590(4) 0.9772(6) 0.114(3) Uani 1 1 d .
O26 O 0.4965(10) -0.1036(6) 1.0504(7) 0.138(4) Uani 1 1 d .
O27 O 0.3861(11) -0.0445(5) 0.9641(9) 0.140(4) Uani 1 1 d .
O28 O -0.0383(16) -0.0094(9) 0.7157(12) 0.225(9) Uiso 1 1 d D
O30 O -0.176(2) 0.0161(15) 0.6478(16) 0.41(2) Uiso 1 1 d D
O29 O -0.0770(19) 0.0279(9) 0.7733(14) 0.260(11) Uiso 1 1 d D
N1 N 0.4717(12) -0.0660(6) 1.0065(11) 0.126(6) Uani 1 1 d .
N2 N 0.6044(9) -0.1788(4) 0.7299(6) 0.084(3) Uani 1 1 d .
N3 N 0.119(2) 0.0873(10) 0.4847(16) 0.196(8) Uiso 1 1 d D
N4 N 0.1922(9) -0.3126(5) 0.7340(8) 0.096(3) Uani 1 1 d .
N5 N -0.0949(19) 0.0154(8) 0.7161(14) 0.204(9) Uiso 1 1 d D
C1 C 0.2671(8) -0.0725(3) 0.7246(5) 0.056(2) Uani 1 1 d .
C2 C 0.2576(8) -0.0956(4) 0.6739(6) 0.062(2) Uani 1 1 d .
C3 C 0.2490(8) -0.1201(4) 0.6132(6) 0.068(3) Uani 1 1 d .
C4 C 0.2547(10) -0.0922(5) 0.5656(7) 0.084(3) Uani 1 1 d .
H4 H 0.2612 -0.0563 0.5717 0.101 Uiso 1 1 calc R
C5 C 0.2514(10) -0.1138(6) 0.5091(8) 0.092(4) Uani 1 1 d .
H5 H 0.2545 -0.0937 0.4768 0.111 Uiso 1 1 calc R
C6 C 0.2432(12) -0.1674(7) 0.5035(8) 0.105(5) Uani 1 1 d .
H6 H 0.2386 -0.1837 0.4649 0.126 Uiso 1 1 calc R
C7 C 0.2416(13) -0.1964(6) 0.5499(8) 0.110(5) Uani 1 1 d .
H7 H 0.2398 -0.2325 0.5458 0.131 Uiso 1 1 calc R
C8 C 0.2427(11) -0.1734(5) 0.6044(7) 0.092(4) Uani 1 1 d .
H8 H 0.2391 -0.1940 0.6360 0.110 Uiso 1 1 calc R
C9 C 0.8030(8) -0.0554(4) 1.0346(6) 0.064(2) Uani 1 1 d .
C10 C 0.8387(9) -0.0952(5) 1.0295(7) 0.077(3) Uani 1 1 d .
C11 C 0.8862(12) -0.1422(6) 1.0326(9) 0.106(5) Uani 1 1 d .
C12 C 0.9089(14) -0.1477(7) 0.9851(11) 0.129(6) Uani 1 1 d .
H12 H 0.8908 -0.1209 0.9508 0.155 Uiso 1 1 calc R
C13 C 0.956(2) -0.1897(10) 0.9856(17) 0.180(11) Uani 1 1 d .
H13 H 0.9764 -0.1906 0.9569 0.215 Uiso 1 1 calc R
C14 C 0.972(2) -0.2316(13) 1.0309(16) 0.194(14) Uani 1 1 d .
H14 H 0.9990 -0.2620 1.0289 0.232 Uiso 1 1 calc R
C15 C 0.9496(16) -0.2304(8) 1.0780(13) 0.154(9) Uani 1 1 d .
H15 H 0.9629 -0.2589 1.1086 0.185 Uiso 1 1 calc R
C16 C 0.9043(12) -0.1833(6) 1.0790(9) 0.116(5) Uani 1 1 d .
H16 H 0.8879 -0.1809 1.1103 0.139 Uiso 1 1 calc R
C17 C 0.0864(7) -0.1564(4) 0.8481(6) 0.061(2) Uani 1 1 d .
C18 C 0.0290(10) -0.1617(7) 0.7605(7) 0.103(5) Uani 1 1 d .
H18A H 0.0170 -0.1278 0.7384 0.155 Uiso 1 1 calc R
H18B H -0.0348 -0.1789 0.7352 0.155 Uiso 1 1 calc R
H18C H 0.0692 -0.1818 0.7536 0.155 Uiso 1 1 calc R
C19 C 0.0193(10) -0.1242(6) 0.8565(9) 0.098(4) Uani 1 1 d .
H19A H 0.0078 -0.0904 0.8344 0.147 Uiso 1 1 calc R
H19B H 0.0528 -0.1207 0.9103 0.147 Uiso 1 1 calc R
H19C H -0.0446 -0.1416 0.8302 0.147 Uiso 1 1 calc R
C20 C 0.1056(9) -0.2094(5) 0.8828(7) 0.082(3) Uani 1 1 d .
H20A H 0.1475 -0.2290 0.8772 0.123 Uiso 1 1 calc R
H20B H 0.0422 -0.2271 0.8568 0.123 Uiso 1 1 calc R
H20C H 0.1396 -0.2061 0.9367 0.123 Uiso 1 1 calc R
C21 C 0.5514(9) -0.2358(4) 0.8907(6) 0.066(3) Uani 1 1 d .
C22 C 0.4677(10) -0.2392(5) 0.8027(7) 0.086(4) Uani 1 1 d .
H22A H 0.4712 -0.2092 0.7793 0.130 Uiso 1 1 calc R
H22B H 0.4027 -0.2402 0.7893 0.130 Uiso 1 1 calc R
H22C H 0.4768 -0.2701 0.7843 0.130 Uiso 1 1 calc R
C23 C 0.5463(11) -0.2830(4) 0.9279(8) 0.082(3) Uani 1 1 d .
H23A H 0.4810 -0.2843 0.9140 0.123 Uiso 1 1 calc R
H23B H 0.5983 -0.2805 0.9831 0.123 Uiso 1 1 calc R
H23C H 0.5564 -0.3140 0.9101 0.123 Uiso 1 1 calc R
C24 C 0.6566(9) -0.2331(5) 0.9127(8) 0.083(3) Uani 1 1 d .
H24A H 0.6593 -0.2029 0.8892 0.125 Uiso 1 1 calc R
H24B H 0.6669 -0.2638 0.8946 0.125 Uiso 1 1 calc R
H24C H 0.7089 -0.2307 0.9679 0.125 Uiso 1 1 calc R
C25 C 0.5516(8) 0.0441(4) 0.7403(6) 0.060(2) Uani 1 1 d .
C26 C 0.4729(12) 0.0071(6) 0.6747(8) 0.102(4) Uani 1 1 d .
H26A H 0.4848 -0.0275 0.6948 0.152 Uiso 1 1 calc R
H26B H 0.4786 0.0075 0.6356 0.152 Uiso 1 1 calc R
H26C H 0.4061 0.0182 0.6527 0.152 Uiso 1 1 calc R
C27 C 0.5341(10) 0.0993(4) 0.7099(7) 0.075(3) Uani 1 1 d .
H27A H 0.5842 0.1220 0.7515 0.113 Uiso 1 1 calc R
H27B H 0.4676 0.1107 0.6883 0.113 Uiso 1 1 calc R
H27C H 0.5394 0.1001 0.6706 0.113 Uiso 1 1 calc R
C28 C 0.6600(10) 0.0255(5) 0.7798(8) 0.084(3) Uani 1 1 d .
C29 C 0.0896(7) 0.1271(4) 0.6963(6) 0.063(3) Uani 1 1 d .
C30 C 0.0343(10) 0.0878(6) 0.6308(8) 0.100(4) Uani 1 1 d .
H30A H 0.0738 0.0807 0.6160 0.151 Uiso 1 1 calc R
H30B H -0.0305 0.1017 0.5873 0.151 Uiso 1 1 calc R
H30C H 0.0245 0.0562 0.6476 0.151 Uiso 1 1 calc R
C31 C 0.0273(10) 0.1387(6) 0.7197(8) 0.094(4) Uani 1 1 d .
H31A H 0.0622 0.1639 0.7607 0.140 Uiso 1 1 calc R
H31B H 0.0179 0.1073 0.7371 0.140 Uiso 1 1 calc R
H31C H -0.0376 0.1523 0.6760 0.140 Uiso 1 1 calc R
C32 C 0.1087(10) 0.1778(5) 0.6708(8) 0.095(4) Uani 1 1 d .
H32A H 0.1475 0.1699 0.6556 0.142 Uiso 1 1 calc R
H32B H 0.1457 0.2019 0.7132 0.142 Uiso 1 1 calc R
H32C H 0.0449 0.1928 0.6280 0.142 Uiso 1 1 calc R
C33 C 0.1928(14) -0.2626(8) 0.7497(10) 0.125(6) Uani 1 1 d .
H33 H 0.1880 -0.2570 0.7874 0.150 Uiso 1 1 calc R
C34 C 0.2084(19) -0.3265(11) 0.6818(14) 0.193(11) Uani 1 1 d .
H34A H 0.2055 -0.3636 0.6763 0.289 Uiso 1 1 calc R
H34B H 0.2739 -0.3142 0.7020 0.289 Uiso 1 1 calc R
H34C H 0.1567 -0.3108 0.6323 0.289 Uiso 1 1 calc R
C35 C 0.181(2) -0.3479(10) 0.7745(13) 0.183(10) Uani 1 1 d .
H35A H 0.1806 -0.3828 0.7594 0.275 Uiso 1 1 calc R
H35B H 0.1174 -0.3413 0.7627 0.275 Uiso 1 1 calc R
H35C H 0.2355 -0.3438 0.8290 0.275 Uiso 1 1 calc R
C36 C 0.1890(18) 0.0701(10) 0.5562(11) 0.154(9) Uani 1 1 d .
H36 H 0.2412 0.0939 0.5880 0.184 Uiso 1 1 calc R
C37 C 0.013(3) 0.0764(18) 0.428(3) 0.36(3) Uiso 1 1 d D
H37A H -0.0158 0.0959 0.3819 0.547 Uiso 1 1 calc R
H37B H -0.0198 0.0859 0.4476 0.547 Uiso 1 1 calc R
H37C H 0.0034 0.0399 0.4161 0.547 Uiso 1 1 calc R
C38 C 0.160(5) 0.124(2) 0.463(4) 0.50(5) Uiso 1 1 d D
H38A H 0.1065 0.1359 0.4106 0.757 Uiso 1 1 calc R
H38B H 0.2121 0.1080 0.4661 0.757 Uiso 1 1 calc R
H38C H 0.1876 0.1538 0.4970 0.757 Uiso 1 1 calc R
C39 C 0.5993(12) -0.1375(5) 0.7603(8) 0.085(4) Uani 1 1 d .
H39 H 0.5348 -0.1249 0.7367 0.102 Uiso 1 1 calc R
C40 C 0.5207(14) -0.2054(7) 0.6640(10) 0.135(7) Uani 1 1 d .
H40A H 0.5445 -0.2346 0.6533 0.203 Uiso 1 1 calc R
H40B H 0.4833 -0.1823 0.6204 0.203 Uiso 1 1 calc R
H40C H 0.4775 -0.2176 0.6734 0.203 Uiso 1 1 calc R
C41 C 0.7069(12) -0.2020(7) 0.7697(10) 0.120(6) Uani 1 1 d .
H41A H 0.6999 -0.2320 0.7414 0.180 Uiso 1 1 calc R
H41B H 0.7370 -0.2122 0.8212 0.180 Uiso 1 1 calc R
H41C H 0.7495 -0.1768 0.7720 0.180 Uiso 1 1 calc R
O31 O 0.873(3) 0.0383(14) 0.977(2) 0.173(12) Uiso 0.50 1 d P
N6 N 1.0000 0.0000 1.0000 0.164(9) Uiso 1 2 d SD
C42 C 0.920(3) 0.0324(16) 0.978(3) 0.142(15) Uiso 0.50 1 d PD
C43 C 1.052(3) 0.0034(18) 1.0829(12) 0.148(14) Uiso 0.50 1 d PD
OW1 O -0.406(3) -0.0913(17) 0.568(2) 0.223(16) Uiso 0.50 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
V V 0.3005 0.5294 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O24 Ag1 O7 103.4(3) . .
O24 Ag1 C9 128.0(4) . .
O7 Ag1 C9 115.9(3) . .
O24 Ag1 O5 98.3(3) . .
O7 Ag1 O5 84.9(2) . .
C9 Ag1 O5 117.0(3) . .
O24 Ag1 C10 102.4(4) . .
O7 Ag1 C10 144.8(3) . .
C9 Ag1 C10 29.6(4) . .
O5 Ag1 C10 114.5(3) . .
O24 Ag1 Ag8 139.4(2) . .
O7 Ag1 Ag8 70.68(19) . .
C9 Ag1 Ag8 45.7(2) . .
O5 Ag1 Ag8 120.34(17) . .
C10 Ag1 Ag8 74.1(3) . .
O24 Ag1 Ag7 156.9(2) . .
O7 Ag1 Ag7 96.7(2) . .
C9 Ag1 Ag7 48.2(3) . .
O5 Ag1 Ag7 72.04(16) . .
C10 Ag1 Ag7 65.1(3) . .
Ag8 Ag1 Ag7 58.69(4) . .
C1 Ag2 O7 116.7(3) . .
C1 Ag2 O5 111.9(3) . .
O7 Ag2 O5 86.9(2) . .
C1 Ag2 O25 138.5(4) . .
O7 Ag2 O25 103.5(3) . .
O5 Ag2 O25 78.5(3) . .
C1 Ag2 Ag4 47.9(2) . .
O7 Ag2 Ag4 136.03(16) . .
O5 Ag2 Ag4 135.96(16) . .
O25 Ag2 Ag4 95.9(2) . .
C1 Ag2 Ag3 49.2(2) . .
O7 Ag2 Ag3 80.27(17) . .
O5 Ag2 Ag3 144.73(17) . .
O25 Ag2 Ag3 136.4(2) . .
Ag4 Ag2 Ag3 59.13(3) . .
C1 Ag2 Ag6 47.9(2) . .
O7 Ag2 Ag6 149.30(19) . .
O5 Ag2 Ag6 78.66(17) . .
O25 Ag2 Ag6 100.0(3) . .
Ag4 Ag2 Ag6 59.13(3) . .
Ag3 Ag2 Ag6 96.04(4) . .
C1 Ag3 O22 114.9(4) . .
C1 Ag3 O10 134.9(3) . .
O22 Ag3 O10 99.1(3) . .
C1 Ag3 O8 131.0(3) . .
O22 Ag3 O8 100.5(4) . .
O10 Ag3 O8 64.00(19) . .
C1 Ag3 Ag4 48.0(2) . .
O22 Ag3 Ag4 135.0(4) . .
O10 Ag3 Ag4 87.03(14) . .
O8 Ag3 Ag4 121.64(15) . .
C1 Ag3 Ag2 50.2(2) . .
O22 Ag3 Ag2 150.4(3) . .
O10 Ag3 Ag2 108.32(14) . .
O8 Ag3 Ag2 82.37(14) . .
Ag4 Ag3 Ag2 59.14(3) . .
C1 Ag4 O1 133.1(3) . .
C1 Ag4 O11 132.4(3) . .
O1 Ag4 O11 92.9(2) . .
C1 Ag4 Ag3 51.0(2) . .
O1 Ag4 Ag3 174.64(17) . .
O11 Ag4 Ag3 82.38(17) . .
C1 Ag4 Ag2 51.9(3) . .
O1 Ag4 Ag2 123.17(18) . .
O11 Ag4 Ag2 118.42(17) . .
Ag3 Ag4 Ag2 61.73(3) . .
C1 Ag4 Ag6 50.6(2) . .
O1 Ag4 Ag6 83.92(16) . .
O11 Ag4 Ag6 176.82(17) . .
Ag3 Ag4 Ag6 100.77(3) . .
Ag2 Ag4 Ag6 63.88(3) . .
C9 Ag5 O28 158.6(6) 3_657 .
C9 Ag5 O29 109.5(6) 3_657 .
O28 Ag5 O29 49.5(7) . .
C9 Ag5 O11 104.5(3) 3_657 .
O28 Ag5 O11 87.0(5) . .
O29 Ag5 O11 121.0(6) . .
C9 Ag5 O1 115.8(3) 3_657 .
O28 Ag5 O1 83.3(6) . .
O29 Ag5 O1 121.0(6) . .
O11 Ag5 O1 82.1(2) . .
C9 Ag5 Ag8 47.7(3) 3_657 3_657
O28 Ag5 Ag8 146.7(5) . 3_657
O29 Ag5 Ag8 132.6(6) . 3_657
O11 Ag5 Ag8 106.01(18) . 3_657
O1 Ag5 Ag8 68.78(17) . 3_657
C9 Ag5 Ag7 46.4(3) 3_657 3_657
O28 Ag5 Ag7 146.3(5) . 3_657
O29 Ag5 Ag7 142.7(6) . 3_657
O11 Ag5 Ag7 59.71(17) . 3_657
O1 Ag5 Ag7 96.30(18) . 3_657
Ag8 Ag5 Ag7 58.39(4) 3_657 3_657
O23 Ag6 C1 125.9(4) . .
O23 Ag6 O4 99.2(3) . .
C1 Ag6 O4 124.0(3) . .
O23 Ag6 O3 97.4(3) . .
C1 Ag6 O3 128.5(3) . .
O4 Ag6 O3 64.2(2) . .
O23 Ag6 C2 101.8(3) . .
C1 Ag6 C2 27.0(3) . .
O4 Ag6 C2 127.2(3) . .
O3 Ag6 C2 154.9(3) . .
O23 Ag6 Ag4 141.7(3) . .
C1 Ag6 Ag4 46.8(2) . .
O4 Ag6 Ag4 114.44(14) . .
O3 Ag6 Ag4 82.26(15) . .
C2 Ag6 Ag4 72.7(2) . .
O23 Ag6 Ag2 155.1(3) . .
C1 Ag6 Ag2 47.9(3) . .
O4 Ag6 Ag2 76.84(14) . .
O3 Ag6 Ag2 102.64(15) . .
C2 Ag6 Ag2 64.2(2) . .
Ag4 Ag6 Ag2 56.99(3) . .
C9 Ag7 O25 139.6(4) . .
C9 Ag7 O17 115.1(3) . 3_657
O25 Ag7 O17 104.6(4) . 3_657
C9 Ag7 Ag8 46.8(3) . .
O25 Ag7 Ag8 100.3(3) . .
O17 Ag7 Ag8 147.68(15) 3_657 .
C9 Ag7 Ag1 51.2(3) . .
O25 Ag7 Ag1 95.2(3) . .
O17 Ag7 Ag1 135.66(15) 3_657 .
Ag8 Ag7 Ag1 60.34(3) . .
C9 Ag7 Ag5 47.3(3) . 3_657
O25 Ag7 Ag5 141.6(3) . 3_657
O17 Ag7 Ag5 91.41(15) 3_657 3_657
Ag8 Ag7 Ag5 56.43(3) . 3_657
Ag1 Ag7 Ag5 97.11(4) . 3_657
C9 Ag8 O2 147.5(3) . 3_657
C9 Ag8 O9 141.0(3) . .
O2 Ag8 O9 65.6(2) 3_657 .
C9 Ag8 Ag5 52.2(3) . 3_657
O2 Ag8 Ag5 98.33(15) 3_657 3_657
O9 Ag8 Ag5 162.83(15) . 3_657
C9 Ag8 Ag7 50.1(3) . .
O2 Ag8 Ag7 136.27(15) 3_657 .
O9 Ag8 Ag7 130.38(16) . .
Ag5 Ag8 Ag7 65.18(4) 3_657 .
C9 Ag8 Ag1 51.9(3) . .
O2 Ag8 Ag1 157.41(15) 3_657 .
O9 Ag8 Ag1 92.10(14) . .
Ag5 Ag8 Ag1 103.41(4) 3_657 .
Ag7 Ag8 Ag1 60.97(4) . .
O13 V1 O21 103.8(3) . 3_657
O13 V1 O14 102.8(3) . .
O21 V1 O14 93.9(3) 3_657 .
O13 V1 O9 104.7(3) . 3_657
O21 V1 O9 86.6(3) 3_657 3_657
O14 V1 O9 151.5(3) . 3_657
O13 V1 O2 102.4(3) . .
O21 V1 O2 153.1(3) 3_657 .
O14 V1 O2 85.9(3) . .
O9 V1 O2 81.1(2) 3_657 .
O15 V2 O14 102.2(3) . .
O15 V2 O16 102.3(3) . .
O14 V2 O16 95.2(3) . .
O15 V2 O4 103.1(3) . .
O14 V2 O4 153.7(3) . .
O16 V2 O4 86.4(3) . .
O15 V2 O3 102.1(3) . .
O14 V2 O3 86.5(3) . .
O16 V2 O3 154.5(3) . .
O4 V2 O3 81.2(2) . .
O18 V3 O16 103.9(3) . .
O18 V3 O19 103.5(3) . 3_657
O16 V3 O19 91.5(3) . 3_657
O18 V3 O6 104.1(3) . .
O16 V3 O6 87.6(3) . .
O19 V3 O6 151.7(3) 3_657 .
O18 V3 O17 103.9(3) . 3_657
O16 V3 O17 152.0(3) . 3_657
O19 V3 O17 85.5(3) 3_657 3_657
O6 V3 O17 82.3(3) . 3_657
O20 V4 O19 104.6(3) . .
O20 V4 O21 103.3(3) . .
O19 V4 O21 94.1(3) . .
O20 V4 O8 104.1(3) . .
O19 V4 O8 150.5(3) . .
O21 V4 O8 85.6(3) . .
O20 V4 O10 102.8(3) . .
O19 V4 O10 86.7(3) . .
O21 V4 O10 152.8(3) . .
O8 V4 O10 80.7(2) . .
O1 P1 O2 110.9(4) . .
O1 P1 O3 111.8(4) . .
O2 P1 O3 110.1(4) . .
O1 P1 C17 108.1(5) . .
O2 P1 C17 107.4(4) . .
O3 P1 C17 108.4(4) . .
O5 P2 O6 110.7(4) . .
O5 P2 O4 110.1(4) . .
O6 P2 O4 110.1(3) . .
O5 P2 C21 108.9(4) . .
O6 P2 C21 108.7(4) . .
O4 P2 C21 108.2(4) . .
O7 P3 O8 111.0(4) . .
O7 P3 O9 110.0(4) . .
O8 P3 O9 110.6(3) . .
O7 P3 C25 109.6(5) . .
O8 P3 C25 106.7(4) . .
O9 P3 C25 108.9(4) . .
O11 P4 O17 108.9(4) . .
O11 P4 O10 111.0(4) . .
O17 P4 O10 109.7(4) . .
O11 P4 C29 109.9(5) . .
O17 P4 C29 109.3(4) . .
O10 P4 C29 108.0(4) . .
P1 O1 Ag4 130.8(4) . .
P1 O1 Ag5 134.2(4) . .
Ag4 O1 Ag5 92.5(2) . .
P1 O2 V1 136.3(4) . .
P1 O2 Ag8 111.2(3) . 3_657
V1 O2 Ag8 106.6(3) . 3_657
P1 O3 V2 135.2(4) . .
P1 O3 Ag6 120.8(3) . .
V2 O3 Ag6 103.5(2) . .
P2 O4 V2 134.8(4) . .
P2 O4 Ag6 120.7(3) . .
V2 O4 Ag6 104.4(3) . .
P2 O5 Ag2 124.0(4) . .
P2 O5 Ag1 132.9(4) . .
Ag2 O5 Ag1 90.7(2) . .
P2 O6 V3 135.2(4) . .
P3 O7 Ag1 134.5(4) . .
P3 O7 Ag2 129.0(4) . .
Ag1 O7 Ag2 94.0(2) . .
P3 O8 V4 136.5(4) . .
P3 O8 Ag3 119.0(3) . .
V4 O8 Ag3 104.0(3) . .
P3 O9 V1 135.5(4) . 3_657
P3 O9 Ag8 113.2(3) . .
V1 O9 Ag8 106.4(3) 3_657 .
P4 O10 V4 134.8(4) . .
P4 O10 Ag3 119.6(3) . .
V4 O10 Ag3 105.0(2) . .
P4 O11 Ag4 133.6(4) . .
P4 O11 Ag5 134.5(4) . .
Ag4 O11 Ag5 91.9(2) . .
V2 O14 V1 141.2(3) . .
V3 O16 V2 142.1(4) . .
P4 O17 V3 137.1(4) . 3_657
P4 O17 Ag7 103.8(3) . 3_657
V3 O17 Ag7 108.4(3) 3_657 3_657
V4 O19 V3 144.6(3) . 3_657
V1 O21 V4 143.7(4) 3_657 .
C36 O22 Ag3 136.3(16) . .
C33 O23 Ag6 129.8(11) . .
C39 O24 Ag1 122.8(8) . .
N1 O25 Ag7 123.8(11) . .
N1 O25 Ag2 124.9(10) . .
Ag7 O25 Ag2 108.7(4) . .
N5 O28 Ag5 92.7(17) . .
N5 O29 Ag5 90.8(19) . .
O26 N1 O27 124.9(13) . .
O26 N1 O25 120.2(13) . .
O27 N1 O25 109.7(15) . .
C39 N2 C40 125.6(13) . .
C39 N2 C41 118.0(12) . .
C40 N2 C41 116.3(11) . .
C36 N3 C37 131(3) . .
C36 N3 C38 112(4) . .
C37 N3 C38 117(4) . .
C33 N4 C35 115.2(18) . .
C33 N4 C34 119.4(18) . .
C35 N4 C34 125.3(18) . .
O29 N5 O28 123(3) . .
O29 N5 O30 130(3) . .
O28 N5 O30 106(2) . .
C2 C1 Ag4 160.3(9) . .
C2 C1 Ag3 105.5(7) . .
Ag4 C1 Ag3 80.9(3) . .
C2 C1 Ag6 94.2(7) . .
Ag4 C1 Ag6 82.5(3) . .
Ag3 C1 Ag6 159.2(5) . .
C2 C1 Ag2 118.9(8) . .
Ag4 C1 Ag2 80.2(3) . .
Ag3 C1 Ag2 80.6(3) . .
Ag6 C1 Ag2 84.2(3) . .
C1 C2 C3 176.3(12) . .
C1 C2 Ag6 58.8(6) . .
C3 C2 Ag6 124.5(7) . .
C4 C3 C8 116.5(11) . .
C4 C3 C2 121.6(10) . .
C8 C3 C2 121.7(11) . .
C3 C4 C5 124.0(13) . .
C3 C4 H4 118.0 . .
C5 C4 H4 118.0 . .
C4 C5 C6 115.4(14) . .
C4 C5 H5 122.3 . .
C6 C5 H5 122.3 . .
C7 C6 C5 123.2(12) . .
C7 C6 H6 118.4 . .
C5 C6 H6 118.4 . .
C6 C7 C8 119.6(14) . .
C6 C7 H7 120.2 . .
C8 C7 H7 120.2 . .
C7 C8 C3 121.2(14) . .
C7 C8 H8 119.4 . .
C3 C8 H8 119.4 . .
C10 C9 Ag8 154.4(10) . .
C10 C9 Ag7 113.3(9) . .
Ag8 C9 Ag7 83.0(4) . .
C10 C9 Ag5 118.9(9) . 3_657
Ag8 C9 Ag5 80.1(3) . 3_657
Ag7 C9 Ag5 86.4(4) . 3_657
C10 C9 Ag1 81.2(8) . .
Ag8 C9 Ag1 82.3(4) . .
Ag7 C9 Ag1 80.6(3) . .
Ag5 C9 Ag1 159.3(5) 3_657 .
C9 C10 C11 173.6(13) . .
C9 C10 Ag1 69.2(7) . .
C11 C10 Ag1 116.4(9) . .
C16 C11 C12 118.9(15) . .
C16 C11 C10 121.1(16) . .
C12 C11 C10 119.9(15) . .
C13 C12 C11 124(2) . .
C13 C12 H12 118.1 . .
C11 C12 H12 118.1 . .
C12 C13 C14 117(2) . .
C12 C13 H13 121.5 . .
C14 C13 H13 121.5 . .
C15 C14 C13 123(2) . .
C15 C14 H14 118.4 . .
C13 C14 H14 118.4 . .
C14 C15 C16 118(2) . .
C14 C15 H15 121.1 . .
C16 C15 H15 121.1 . .
C11 C16 C15 119(2) . .
C11 C16 H16 120.6 . .
C15 C16 H16 120.6 . .
C20 C17 C19 110.4(10) . .
C20 C17 C18 109.6(10) . .
C19 C17 C18 107.8(11) . .
C20 C17 P1 112.3(7) . .
C19 C17 P1 108.8(8) . .
C18 C17 P1 107.9(8) . .
C17 C18 H18A 109.5 . .
C17 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C17 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C17 C19 H19A 109.5 . .
C17 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
C17 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
C17 C20 H20A 109.5 . .
C17 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C17 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C23 C21 C22 109.7(10) . .
C23 C21 C24 110.1(10) . .
C22 C21 C24 109.8(10) . .
C23 C21 P2 111.0(7) . .
C22 C21 P2 108.3(8) . .
C24 C21 P2 107.9(7) . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C21 C23 H23A 109.5 . .
C21 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C21 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C21 C24 H24A 109.5 . .
C21 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C21 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C27 C25 C26 110.4(10) . .
C27 C25 C28 111.1(9) . .
C26 C25 C28 110.5(10) . .
C27 C25 P3 109.9(7) . .
C26 C25 P3 107.3(8) . .
C28 C25 P3 107.5(7) . .
C25 C26 H26A 109.5 . .
C25 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C25 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
C25 C27 H27A 109.5 . .
C25 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
C25 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
C30 C29 C31 109.8(10) . .
C30 C29 C32 110.1(11) . .
C31 C29 C32 110.1(10) . .
C30 C29 P4 107.9(8) . .
C31 C29 P4 108.2(8) . .
C32 C29 P4 110.7(7) . .
C29 C30 H30A 109.5 . .
C29 C30 H30B 109.5 . .
H30A C30 H30B 109.5 . .
C29 C30 H30C 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
C29 C31 H31A 109.5 . .
C29 C31 H31B 109.5 . .
H31A C31 H31B 109.5 . .
C29 C31 H31C 109.5 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
C29 C32 H32A 109.5 . .
C29 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
C29 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
O23 C33 N4 131.7(19) . .
O23 C33 H33 114.1 . .
N4 C33 H33 114.1 . .
N4 C34 H34A 109.5 . .
N4 C34 H34B 109.5 . .
H34A C34 H34B 109.5 . .
N4 C34 H34C 109.5 . .
H34A C34 H34C 109.5 . .
H34B C34 H34C 109.5 . .
N4 C35 H35A 109.5 . .
N4 C35 H35B 109.5 . .
H35A C35 H35B 109.5 . .
N4 C35 H35C 109.5 . .
H35A C35 H35C 109.5 . .
H35B C35 H35C 109.5 . .
O22 C36 N3 134(3) . .
O22 C36 H36 112.9 . .
N3 C36 H36 112.9 . .
N3 C37 H37A 109.5 . .
N3 C37 H37B 109.5 . .
H37A C37 H37B 109.5 . .
N3 C37 H37C 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
N3 C38 H38A 109.5 . .
N3 C38 H38B 109.5 . .
H38A C38 H38B 109.5 . .
N3 C38 H38C 109.5 . .
H38A C38 H38C 109.5 . .
H38B C38 H38C 109.5 . .
O24 C39 N2 126.5(14) . .
O24 C39 H39 116.8 . .
N2 C39 H39 116.8 . .
N2 C40 H40A 109.5 . .
N2 C40 H40B 109.5 . .
H40A C40 H40B 109.5 . .
N2 C40 H40C 109.5 . .
H40A C40 H40C 109.5 . .
H40B C40 H40C 109.5 . .
N2 C41 H41A 109.5 . .
N2 C41 H41B 109.5 . .
H41A C41 H41B 109.5 . .
N2 C41 H41C 109.5 . .
H41A C41 H41C 109.5 . .
H41B C41 H41C 109.5 . .
C42 N6 C42 180(5) . 3_757
C42 N6 C43 87(3) . 3_757
C42 N6 C43 93(3) 3_757 3_757
C42 N6 C43 93(3) . .
C42 N6 C43 87(3) 3_757 .
C43 N6 C43 180.000(15) 3_757 .
O31 C42 N6 149(6) . .
O31 C42 C43 141(6) . 3_757
N6 C42 C43 48.1(15) . 3_757
N6 C43 C42 45.2(13) . 3_757
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 O24 2.287(8) .
Ag1 O7 2.329(7) .
Ag1 C9 2.349(11) .
Ag1 O5 2.440(7) .
Ag1 C10 2.484(12) .
Ag1 Ag8 2.9576(13) .
Ag1 Ag7 2.9760(14) .
Ag2 C1 2.289(10) .
Ag2 O7 2.333(7) .
Ag2 O5 2.349(7) .
Ag2 O25 2.431(11) .
Ag2 Ag4 2.8650(14) .
Ag2 Ag3 2.9395(13) .
Ag2 Ag6 3.0675(13) .
Ag3 C1 2.255(9) .
Ag3 O22 2.272(11) .
Ag3 O10 2.406(6) .
Ag3 O8 2.436(6) .
Ag3 Ag4 2.8648(12) .
Ag4 C1 2.157(10) .
Ag4 O1 2.257(6) .
Ag4 O11 2.292(6) .
Ag4 Ag6 2.9325(13) .
Ag5 C9 2.281(11) 3_657
Ag5 O28 2.44(2) .
Ag5 O29 2.48(2) .
Ag5 O11 2.506(7) .
Ag5 O1 2.516(6) .
Ag5 Ag8 2.8452(14) 3_657
Ag5 Ag7 3.0995(15) 3_657
Ag6 O23 2.282(9) .
Ag6 C1 2.286(9) .
Ag6 O4 2.432(6) .
Ag6 O3 2.448(6) .
Ag6 C2 2.665(11) .
Ag7 C9 2.248(11) .
Ag7 O25 2.299(10) .
Ag7 O17 2.484(6) 3_657
Ag7 Ag8 2.9081(16) .
Ag7 Ag5 3.0995(15) 3_657
Ag8 C9 2.137(10) .
Ag8 O2 2.371(6) 3_657
Ag8 O9 2.394(6) .
Ag8 Ag5 2.8452(15) 3_657
V1 O13 1.572(6) .
V1 O21 1.803(6) 3_657
V1 O14 1.815(6) .
V1 O9 1.974(6) 3_657
V1 O2 1.995(6) .
V2 O15 1.600(6) .
V2 O14 1.802(6) .
V2 O16 1.812(7) .
V2 O4 1.985(6) .
V2 O3 1.998(6) .
V3 O18 1.587(6) .
V3 O16 1.809(7) .
V3 O19 1.823(6) 3_657
V3 O6 1.946(6) .
V3 O17 1.964(6) 3_657
V4 O20 1.582(6) .
V4 O19 1.794(6) .
V4 O21 1.810(7) .
V4 O8 1.980(6) .
V4 O10 1.983(6) .
P1 O1 1.496(7) .
P1 O2 1.539(6) .
P1 O3 1.548(6) .
P1 C17 1.815(10) .
P2 O5 1.496(6) .
P2 O6 1.551(7) .
P2 O4 1.558(7) .
P2 C21 1.822(9) .
P3 O7 1.502(6) .
P3 O8 1.537(6) .
P3 O9 1.541(6) .
P3 C25 1.829(10) .
P4 O11 1.501(7) .
P4 O17 1.540(6) .
P4 O10 1.547(6) .
P4 C29 1.823(9) .
O2 Ag8 2.371(6) 3_657
O9 V1 1.974(6) 3_657
O17 V3 1.964(6) 3_657
O17 Ag7 2.484(6) 3_657
O19 V3 1.823(6) 3_657
O21 V1 1.803(6) 3_657
O22 C36 1.02(2) .
O23 C33 1.19(2) .
O24 C39 1.217(15) .
O25 N1 1.310(15) .
O26 N1 1.249(17) .
O27 N1 1.256(18) .
O28 N5 1.18(3) .
O30 N5 1.247(18) .
O29 N5 1.173(17) .
N2 C39 1.302(15) .
N2 C40 1.412(17) .
N2 C41 1.498(17) .
N3 C36 1.32(3) .
N3 C37 1.424(19) .
N3 C38 1.46(2) .
N4 C33 1.33(2) .
N4 C35 1.40(2) .
N4 C34 1.44(2) .
C1 C2 1.213(13) .
C2 C3 1.437(14) .
C3 C4 1.360(17) .
C3 C8 1.377(16) .
C4 C5 1.371(17) .
C4 H4 0.9300 .
C5 C6 1.38(2) .
C5 H5 0.9300 .
C6 C7 1.31(2) .
C6 H6 0.9300 .
C7 C8 1.367(17) .
C7 H7 0.9300 .
C8 H8 0.9300 .
C9 C10 1.242(15) .
C9 Ag5 2.281(11) 3_657
C10 C11 1.438(18) .
C11 C16 1.38(2) .
C11 C12 1.38(2) .
C12 C13 1.35(2) .
C12 H12 0.9300 .
C13 C14 1.39(4) .
C13 H13 0.9300 .
C14 C15 1.36(3) .
C14 H14 0.9300 .
C15 C16 1.45(3) .
C15 H15 0.9300 .
C16 H16 0.9300 .
C17 C20 1.499(16) .
C17 C19 1.542(16) .
C17 C18 1.553(15) .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C21 C23 1.515(15) .
C21 C22 1.531(16) .
C21 C24 1.551(16) .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
C25 C27 1.520(15) .
C25 C26 1.530(16) .
C25 C28 1.541(15) .
C26 H26A 0.9600 .
C26 H26B 0.9600 .
C26 H26C 0.9600 .
C27 H27A 0.9600 .
C27 H27B 0.9600 .
C27 H27C 0.9600 .
C29 C30 1.516(16) .
C29 C31 1.518(16) .
C29 C32 1.548(17) .
C30 H30A 0.9600 .
C30 H30B 0.9600 .
C30 H30C 0.9600 .
C31 H31A 0.9600 .
C31 H31B 0.9600 .
C31 H31C 0.9600 .
C32 H32A 0.9600 .
C32 H32B 0.9600 .
C32 H32C 0.9600 .
C33 H33 0.9300 .
C34 H34A 0.9600 .
C34 H34B 0.9600 .
C34 H34C 0.9600 .
C35 H35A 0.9600 .
C35 H35B 0.9600 .
C35 H35C 0.9600 .
C36 H36 0.9300 .
C37 H37A 0.9600 .
C37 H37B 0.9600 .
C37 H37C 0.9600 .
C38 H38A 0.9600 .
C38 H38B 0.9600 .
C38 H38C 0.9600 .
C39 H39 0.9300 .
C40 H40A 0.9600 .
C40 H40B 0.9600 .
C40 H40C 0.9600 .
C41 H41A 0.9600 .
C41 H41B 0.9600 .
C41 H41C 0.9600 .
O31 C42 0.81(4) .
N6 C42 1.406(19) .
N6 C42 1.406(19) 3_757
N6 C43 1.474(19) 3_757
N6 C43 1.474(19) .
C42 C43 1.98(5) 3_757
C43 C42 1.98(5) 3_757
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O7 Ag2 Ag3 C1 138.6(4) . .
O5 Ag2 Ag3 C1 68.3(4) . .
O25 Ag2 Ag3 C1 -121.9(5) . .
Ag4 Ag2 Ag3 C1 -58.9(3) . .
Ag6 Ag2 Ag3 C1 -10.6(3) . .
C1 Ag2 Ag3 O22 -69.1(8) . .
O7 Ag2 Ag3 O22 69.5(8) . .
O5 Ag2 Ag3 O22 -0.8(8) . .
O25 Ag2 Ag3 O22 169.0(8) . .
Ag4 Ag2 Ag3 O22 -128.0(7) . .
Ag6 Ag2 Ag3 O22 -79.7(7) . .
C1 Ag2 Ag3 O10 133.8(4) . .
O7 Ag2 Ag3 O10 -87.6(2) . .
O5 Ag2 Ag3 O10 -157.9(3) . .
O25 Ag2 Ag3 O10 11.9(4) . .
Ag4 Ag2 Ag3 O10 74.85(15) . .
Ag6 Ag2 Ag3 O10 123.22(15) . .
C1 Ag2 Ag3 O8 -166.9(4) . .
O7 Ag2 Ag3 O8 -28.2(2) . .
O5 Ag2 Ag3 O8 -98.6(3) . .
O25 Ag2 Ag3 O8 71.2(4) . .
Ag4 Ag2 Ag3 O8 134.16(15) . .
Ag6 Ag2 Ag3 O8 -177.46(14) . .
C1 Ag2 Ag3 Ag4 58.9(3) . .
O7 Ag2 Ag3 Ag4 -162.41(19) . .
O5 Ag2 Ag3 Ag4 127.3(3) . .
O25 Ag2 Ag3 Ag4 -63.0(4) . .
Ag6 Ag2 Ag3 Ag4 48.37(3) . .
O22 Ag3 Ag4 C1 84.4(6) . .
O10 Ag3 Ag4 C1 -175.7(4) . .
O8 Ag3 Ag4 C1 -118.9(4) . .
Ag2 Ag3 Ag4 C1 -62.3(3) . .
C1 Ag3 Ag4 O1 -141(2) . .
O22 Ag3 Ag4 O1 -57(2) . .
O10 Ag3 Ag4 O1 43(2) . .
O8 Ag3 Ag4 O1 100(2) . .
Ag2 Ag3 Ag4 O1 157(2) . .
C1 Ag3 Ag4 O11 -169.6(4) . .
O22 Ag3 Ag4 O11 -85.3(5) . .
O10 Ag3 Ag4 O11 14.7(2) . .
O8 Ag3 Ag4 O11 71.5(2) . .
Ag2 Ag3 Ag4 O11 128.10(19) . .
C1 Ag3 Ag4 Ag2 62.3(3) . .
O22 Ag3 Ag4 Ag2 146.6(4) . .
O10 Ag3 Ag4 Ag2 -113.43(14) . .
O8 Ag3 Ag4 Ag2 -56.63(16) . .
C1 Ag3 Ag4 Ag6 9.9(3) . .
O22 Ag3 Ag4 Ag6 94.3(4) . .
O10 Ag3 Ag4 Ag6 -165.75(14) . .
O8 Ag3 Ag4 Ag6 -108.95(16) . .
Ag2 Ag3 Ag4 Ag6 -52.32(4) . .
O7 Ag2 Ag4 C1 86.3(4) . .
O5 Ag2 Ag4 C1 -77.7(4) . .
O25 Ag2 Ag4 C1 -157.3(4) . .
Ag3 Ag2 Ag4 C1 60.9(3) . .
Ag6 Ag2 Ag4 C1 -59.1(3) . .
C1 Ag2 Ag4 O1 121.6(4) . .
O7 Ag2 Ag4 O1 -152.1(4) . .
O5 Ag2 Ag4 O1 43.9(3) . .
O25 Ag2 Ag4 O1 -35.6(4) . .
Ag3 Ag2 Ag4 O1 -177.5(2) . .
Ag6 Ag2 Ag4 O1 62.5(2) . .
C1 Ag2 Ag4 O11 -123.4(4) . .
O7 Ag2 Ag4 O11 -37.1(4) . .
O5 Ag2 Ag4 O11 158.9(3) . .
O25 Ag2 Ag4 O11 79.4(3) . .
Ag3 Ag2 Ag4 O11 -62.5(2) . .
Ag6 Ag2 Ag4 O11 177.5(2) . .
C1 Ag2 Ag4 Ag3 -60.9(3) . .
O7 Ag2 Ag4 Ag3 25.4(3) . .
O5 Ag2 Ag4 Ag3 -138.6(2) . .
O25 Ag2 Ag4 Ag3 141.8(3) . .
Ag6 Ag2 Ag4 Ag3 -120.00(4) . .
C1 Ag2 Ag4 Ag6 59.1(3) . .
O7 Ag2 Ag4 Ag6 145.4(3) . .
O5 Ag2 Ag4 Ag6 -18.6(2) . .
O25 Ag2 Ag4 Ag6 -98.2(3) . .
Ag3 Ag2 Ag4 Ag6 120.00(4) . .
C1 Ag4 Ag6 O23 -96.4(5) . .
O1 Ag4 Ag6 O23 71.0(5) . .
O11 Ag4 Ag6 O23 66(4) . .
Ag3 Ag4 Ag6 O23 -106.3(4) . .
Ag2 Ag4 Ag6 O23 -157.3(4) . .
O1 Ag4 Ag6 C1 167.4(4) . .
O11 Ag4 Ag6 C1 162(4) . .
Ag3 Ag4 Ag6 C1 -10.0(3) . .
Ag2 Ag4 Ag6 C1 -60.9(3) . .
C1 Ag4 Ag6 O4 114.5(4) . .
O1 Ag4 Ag6 O4 -78.1(2) . .
O11 Ag4 Ag6 O4 -83(4) . .
Ag3 Ag4 Ag6 O4 104.53(16) . .
Ag2 Ag4 Ag6 O4 53.60(16) . .
C1 Ag4 Ag6 O3 171.5(4) . .
O1 Ag4 Ag6 O3 -21.1(2) . .
O11 Ag4 Ag6 O3 -26(4) . .
Ag3 Ag4 Ag6 O3 161.52(15) . .
Ag2 Ag4 Ag6 O3 110.59(15) . .
C1 Ag4 Ag6 C2 -9.1(4) . .
O1 Ag4 Ag6 C2 158.3(3) . .
O11 Ag4 Ag6 C2 153(4) . .
Ag3 Ag4 Ag6 C2 -19.1(2) . .
Ag2 Ag4 Ag6 C2 -70.0(2) . .
C1 Ag4 Ag6 Ag2 60.9(3) . .
O1 Ag4 Ag6 Ag2 -131.69(19) . .
O11 Ag4 Ag6 Ag2 -137(4) . .
Ag3 Ag4 Ag6 Ag2 50.93(4) . .
C1 Ag2 Ag6 O23 86.1(8) . .
O7 Ag2 Ag6 O23 15.8(8) . .
O5 Ag2 Ag6 O23 -47.8(7) . .
O25 Ag2 Ag6 O23 -123.8(7) . .
Ag4 Ag2 Ag6 O23 145.3(7) . .
Ag3 Ag2 Ag6 O23 96.9(7) . .
O7 Ag2 Ag6 C1 -70.3(5) . .
O5 Ag2 Ag6 C1 -133.9(4) . .
O25 Ag2 Ag6 C1 150.1(4) . .
Ag4 Ag2 Ag6 C1 59.2(3) . .
Ag3 Ag2 Ag6 C1 10.8(3) . .
C1 Ag2 Ag6 O4 169.6(4) . .
O7 Ag2 Ag6 O4 99.3(4) . .
O5 Ag2 Ag6 O4 35.7(2) . .
O25 Ag2 Ag6 O4 -40.3(3) . .
Ag4 Ag2 Ag6 O4 -131.19(15) . .
Ag3 Ag2 Ag6 O4 -179.56(14) . .
C1 Ag2 Ag6 O3 -131.1(4) . .
O7 Ag2 Ag6 O3 158.6(4) . .
O5 Ag2 Ag6 O3 95.0(2) . .
O25 Ag2 Ag6 O3 19.0(3) . .
Ag4 Ag2 Ag6 O3 -71.92(15) . .
Ag3 Ag2 Ag6 O3 -120.29(15) . .
C1 Ag2 Ag6 C2 26.2(4) . .
O7 Ag2 Ag6 C2 -44.1(4) . .
O5 Ag2 Ag6 C2 -107.7(3) . .
O25 Ag2 Ag6 C2 176.3(3) . .
Ag4 Ag2 Ag6 C2 85.4(2) . .
Ag3 Ag2 Ag6 C2 37.0(2) . .
C1 Ag2 Ag6 Ag4 -59.2(3) . .
O7 Ag2 Ag6 Ag4 -129.5(3) . .
O5 Ag2 Ag6 Ag4 166.93(17) . .
O25 Ag2 Ag6 Ag4 90.9(2) . .
Ag3 Ag2 Ag6 Ag4 -48.37(3) . .
O24 Ag1 Ag7 C9 90.5(7) . .
O7 Ag1 Ag7 C9 -119.0(4) . .
O5 Ag1 Ag7 C9 158.6(4) . .
C10 Ag1 Ag7 C9 29.4(5) . .
Ag8 Ag1 Ag7 C9 -56.5(3) . .
O24 Ag1 Ag7 O25 -114.1(7) . .
O7 Ag1 Ag7 O25 36.4(3) . .
C9 Ag1 Ag7 O25 155.4(4) . .
O5 Ag1 Ag7 O25 -46.0(3) . .
C10 Ag1 Ag7 O25 -175.2(4) . .
Ag8 Ag1 Ag7 O25 98.9(3) . .
O24 Ag1 Ag7 O17 3.1(7) . 3_657
O7 Ag1 Ag7 O17 153.5(3) . 3_657
C9 Ag1 Ag7 O17 -87.5(4) . 3_657
O5 Ag1 Ag7 O17 71.1(3) . 3_657
C10 Ag1 Ag7 O17 -58.0(4) . 3_657
Ag8 Ag1 Ag7 O17 -144.0(2) . 3_657
O24 Ag1 Ag7 Ag8 147.0(6) . .
O7 Ag1 Ag7 Ag8 -62.52(17) . .
C9 Ag1 Ag7 Ag8 56.5(3) . .
O5 Ag1 Ag7 Ag8 -144.95(16) . .
C10 Ag1 Ag7 Ag8 85.9(3) . .
O24 Ag1 Ag7 Ag5 102.4(6) . 3_657
O7 Ag1 Ag7 Ag5 -107.09(17) . 3_657
C9 Ag1 Ag7 Ag5 11.9(3) . 3_657
O5 Ag1 Ag7 Ag5 170.48(16) . 3_657
C10 Ag1 Ag7 Ag5 41.3(3) . 3_657
Ag8 Ag1 Ag7 Ag5 -44.57(4) . 3_657
O25 Ag7 Ag8 C9 -153.0(5) . .
O17 Ag7 Ag8 C9 66.8(5) 3_657 .
Ag1 Ag7 Ag8 C9 -62.9(4) . .
Ag5 Ag7 Ag8 C9 60.4(4) 3_657 .
C9 Ag7 Ag8 O2 -135.8(4) . 3_657
O25 Ag7 Ag8 O2 71.2(3) . 3_657
O17 Ag7 Ag8 O2 -68.9(4) 3_657 3_657
Ag1 Ag7 Ag8 O2 161.3(2) . 3_657
Ag5 Ag7 Ag8 O2 -75.4(2) 3_657 3_657
C9 Ag7 Ag8 O9 128.3(4) . .
O25 Ag7 Ag8 O9 -24.7(3) . .
O17 Ag7 Ag8 O9 -164.9(3) 3_657 .
Ag1 Ag7 Ag8 O9 65.4(2) . .
Ag5 Ag7 Ag8 O9 -171.4(2) 3_657 .
C9 Ag7 Ag8 Ag5 -60.4(4) . 3_657
O25 Ag7 Ag8 Ag5 146.6(3) . 3_657
O17 Ag7 Ag8 Ag5 6.4(3) 3_657 3_657
Ag1 Ag7 Ag8 Ag5 -123.29(5) . 3_657
C9 Ag7 Ag8 Ag1 62.9(4) . .
O25 Ag7 Ag8 Ag1 -90.1(3) . .
O17 Ag7 Ag8 Ag1 129.7(3) 3_657 .
Ag5 Ag7 Ag8 Ag1 123.29(5) 3_657 .
O24 Ag1 Ag8 C9 -100.6(5) . .
O7 Ag1 Ag8 C9 171.2(4) . .
O5 Ag1 Ag8 C9 99.5(4) . .
C10 Ag1 Ag8 C9 -10.0(5) . .
Ag7 Ag1 Ag8 C9 60.2(4) . .
O24 Ag1 Ag8 O2 54.3(6) . 3_657
O7 Ag1 Ag8 O2 -33.8(5) . 3_657
C9 Ag1 Ag8 O2 154.9(6) . 3_657
O5 Ag1 Ag8 O2 -105.6(5) . 3_657
C10 Ag1 Ag8 O2 145.0(5) . 3_657
Ag7 Ag1 Ag8 O2 -144.8(4) . 3_657
O24 Ag1 Ag8 O9 63.0(4) . .
O7 Ag1 Ag8 O9 -25.2(2) . .
C9 Ag1 Ag8 O9 163.6(4) . .
O5 Ag1 Ag8 O9 -96.9(2) . .
C10 Ag1 Ag8 O9 153.7(3) . .
Ag7 Ag1 Ag8 O9 -136.15(16) . .
O24 Ag1 Ag8 Ag5 -109.6(4) . 3_657
O7 Ag1 Ag8 Ag5 162.2(2) . 3_657
C9 Ag1 Ag8 Ag5 -9.0(4) . 3_657
O5 Ag1 Ag8 Ag5 90.53(19) . 3_657
C10 Ag1 Ag8 Ag5 -18.9(3) . 3_657
Ag7 Ag1 Ag8 Ag5 51.26(5) . 3_657
O24 Ag1 Ag8 Ag7 -160.9(4) . .
O7 Ag1 Ag8 Ag7 111.0(2) . .
C9 Ag1 Ag8 Ag7 -60.2(4) . .
O5 Ag1 Ag8 Ag7 39.27(18) . .
C10 Ag1 Ag8 Ag7 -70.2(3) . .
O2 P1 O1 Ag4 118.5(5) . .
O3 P1 O1 Ag4 -4.8(7) . .
C17 P1 O1 Ag4 -124.0(6) . .
O2 P1 O1 Ag5 -38.3(7) . .
O3 P1 O1 Ag5 -161.6(5) . .
C17 P1 O1 Ag5 79.2(7) . .
C1 Ag4 O1 P1 36.5(8) . .
O11 Ag4 O1 P1 -157.1(6) . .
Ag3 Ag4 O1 P1 174.3(16) . .
Ag2 Ag4 O1 P1 -30.1(7) . .
Ag6 Ag4 O1 P1 23.1(5) . .
C1 Ag4 O1 Ag5 -159.9(4) . .
O11 Ag4 O1 Ag5 6.5(3) . .
Ag3 Ag4 O1 Ag5 -22(2) . .
Ag2 Ag4 O1 Ag5 133.51(13) . .
Ag6 Ag4 O1 Ag5 -173.3(2) . .
C9 Ag5 O1 P1 54.4(7) 3_657 .
O28 Ag5 O1 P1 -115.4(8) . .
O29 Ag5 O1 P1 -81.8(9) . .
O11 Ag5 O1 P1 156.7(6) . .
Ag8 Ag5 O1 P1 46.1(6) 3_657 .
Ag7 Ag5 O1 P1 98.6(6) 3_657 .
C9 Ag5 O1 Ag4 -108.2(4) 3_657 .
O28 Ag5 O1 Ag4 82.0(5) . .
O29 Ag5 O1 Ag4 115.5(7) . .
O11 Ag5 O1 Ag4 -5.9(2) . .
Ag8 Ag5 O1 Ag4 -116.6(2) 3_657 .
Ag7 Ag5 O1 Ag4 -64.1(2) 3_657 .
O1 P1 O2 V1 -149.4(5) . .
O3 P1 O2 V1 -25.2(7) . .
C17 P1 O2 V1 92.7(6) . .
O1 P1 O2 Ag8 -1.1(5) . 3_657
O3 P1 O2 Ag8 123.1(3) . 3_657
C17 P1 O2 Ag8 -119.0(4) . 3_657
O13 V1 O2 P1 -103.5(6) . .
O21 V1 O2 P1 89.3(8) 3_657 .
O14 V1 O2 P1 -1.3(6) . .
O9 V1 O2 P1 153.3(6) 3_657 .
O13 V1 O2 Ag8 107.2(3) . 3_657
O21 V1 O2 Ag8 -59.9(6) 3_657 3_657
O14 V1 O2 Ag8 -150.6(3) . 3_657
O9 V1 O2 Ag8 4.0(3) 3_657 3_657
O1 P1 O3 V2 145.1(5) . .
O2 P1 O3 V2 21.4(6) . .
C17 P1 O3 V2 -95.9(6) . .
O1 P1 O3 Ag6 -24.5(5) . .
O2 P1 O3 Ag6 -148.2(3) . .
C17 P1 O3 Ag6 94.5(5) . .
O15 V2 O3 P1 108.4(6) . .
O14 V2 O3 P1 6.6(5) . .
O16 V2 O3 P1 -88.2(8) . .
O4 V2 O3 P1 -150.0(6) . .
O15 V2 O3 Ag6 -80.7(3) . .
O14 V2 O3 Ag6 177.5(3) . .
O16 V2 O3 Ag6 82.7(7) . .
O4 V2 O3 Ag6 20.8(2) . .
O23 Ag6 O3 P1 -109.4(5) . .
C1 Ag6 O3 P1 39.8(6) . .
O4 Ag6 O3 P1 153.9(5) . .
C2 Ag6 O3 P1 30.5(8) . .
Ag4 Ag6 O3 P1 31.9(4) . .
Ag2 Ag6 O3 P1 85.5(4) . .
O23 Ag6 O3 V2 78.1(4) . .
C1 Ag6 O3 V2 -132.7(4) . .
O4 Ag6 O3 V2 -18.6(2) . .
C2 Ag6 O3 V2 -142.0(6) . .
Ag4 Ag6 O3 V2 -140.6(2) . .
Ag2 Ag6 O3 V2 -87.0(2) . .
O5 P2 O4 V2 -149.3(5) . .
O6 P2 O4 V2 -27.0(6) . .
C21 P2 O4 V2 91.7(6) . .
O5 P2 O4 Ag6 27.1(5) . .
O6 P2 O4 Ag6 149.4(3) . .
C21 P2 O4 Ag6 -91.9(5) . .
O15 V2 O4 P2 -103.8(5) . .
O14 V2 O4 P2 92.7(8) . .
O16 V2 O4 P2 -1.9(5) . .
O3 V2 O4 P2 155.7(5) . .
O15 V2 O4 Ag6 79.4(3) . .
O14 V2 O4 Ag6 -84.1(7) . .
O16 V2 O4 Ag6 -178.7(3) . .
O3 V2 O4 Ag6 -21.1(2) . .
O23 Ag6 O4 P2 107.6(4) . .
C1 Ag6 O4 P2 -38.0(5) . .
O3 Ag6 O4 P2 -158.6(4) . .
C2 Ag6 O4 P2 -4.9(5) . .
Ag4 Ag6 O4 P2 -91.2(3) . .
Ag2 Ag6 O4 P2 -47.3(3) . .
O23 Ag6 O4 V2 -75.0(3) . .
C1 Ag6 O4 V2 139.3(3) . .
O3 Ag6 O4 V2 18.8(2) . .
C2 Ag6 O4 V2 172.4(3) . .
Ag4 Ag6 O4 V2 86.2(2) . .
Ag2 Ag6 O4 V2 130.1(2) . .
O6 P2 O5 Ag2 -97.6(5) . .
O4 P2 O5 Ag2 24.4(6) . .
C21 P2 O5 Ag2 142.9(5) . .
O6 P2 O5 Ag1 32.6(6) . .
O4 P2 O5 Ag1 154.7(4) . .
C21 P2 O5 Ag1 -86.8(6) . .
C1 Ag2 O5 P2 -82.7(5) . .
O7 Ag2 O5 P2 159.7(5) . .
O25 Ag2 O5 P2 55.3(5) . .
Ag4 Ag2 O5 P2 -31.3(6) . .
Ag3 Ag2 O5 P2 -131.9(3) . .
Ag6 Ag2 O5 P2 -47.5(4) . .
C1 Ag2 O5 Ag1 131.4(3) . .
O7 Ag2 O5 Ag1 13.8(3) . .
O25 Ag2 O5 Ag1 -90.7(3) . .
Ag4 Ag2 O5 Ag1 -177.29(6) . .
Ag3 Ag2 O5 Ag1 82.1(3) . .
Ag6 Ag2 O5 Ag1 166.5(2) . .
O24 Ag1 O5 P2 102.7(6) . .
O7 Ag1 O5 P2 -154.5(6) . .
C9 Ag1 O5 P2 -38.0(6) . .
C10 Ag1 O5 P2 -5.1(7) . .
Ag8 Ag1 O5 P2 -90.4(5) . .
Ag7 Ag1 O5 P2 -55.8(5) . .
O24 Ag1 O5 Ag2 -116.6(3) . .
O7 Ag1 O5 Ag2 -13.8(3) . .
C9 Ag1 O5 Ag2 102.7(3) . .
C10 Ag1 O5 Ag2 135.6(3) . .
Ag8 Ag1 O5 Ag2 50.3(2) . .
Ag7 Ag1 O5 Ag2 84.94(18) . .
O5 P2 O6 V3 151.4(5) . .
O4 P2 O6 V3 29.4(6) . .
C21 P2 O6 V3 -89.0(6) . .
O18 V3 O6 P2 102.2(6) . .
O16 V3 O6 P2 -1.5(5) . .
O19 V3 O6 P2 -90.1(7) 3_657 .
O17 V3 O6 P2 -155.3(6) 3_657 .
O8 P3 O7 Ag1 -170.1(5) . .
O9 P3 O7 Ag1 -47.3(7) . .
C25 P3 O7 Ag1 72.4(7) . .
O8 P3 O7 Ag2 -12.8(7) . .
O9 P3 O7 Ag2 109.9(5) . .
C25 P3 O7 Ag2 -130.4(6) . .
O24 Ag1 O7 P3 -86.3(7) . .
C9 Ag1 O7 P3 58.7(8) . .
O5 Ag1 O7 P3 176.4(7) . .
C10 Ag1 O7 P3 49.8(10) . .
Ag8 Ag1 O7 P3 51.8(6) . .
Ag7 Ag1 O7 P3 105.2(6) . .
O24 Ag1 O7 Ag2 111.3(3) . .
C9 Ag1 O7 Ag2 -103.7(4) . .
O5 Ag1 O7 Ag2 13.9(3) . .
C10 Ag1 O7 Ag2 -112.7(6) . .
Ag8 Ag1 O7 Ag2 -110.7(3) . .
Ag7 Ag1 O7 Ag2 -57.3(2) . .
C1 Ag2 O7 P3 68.6(7) . .
O5 Ag2 O7 P3 -178.4(6) . .
O25 Ag2 O7 P3 -101.0(6) . .
Ag4 Ag2 O7 P3 12.6(8) . .
Ag3 Ag2 O7 P3 34.6(5) . .
Ag6 Ag2 O7 P3 120.0(5) . .
C1 Ag2 O7 Ag1 -127.4(3) . .
O5 Ag2 O7 Ag1 -14.5(3) . .
O25 Ag2 O7 Ag1 63.0(3) . .
Ag4 Ag2 O7 Ag1 176.59(6) . .
Ag3 Ag2 O7 Ag1 -161.5(2) . .
Ag6 Ag2 O7 Ag1 -76.0(4) . .
O7 P3 O8 V4 143.7(6) . .
O9 P3 O8 V4 21.3(7) . .
C25 P3 O8 V4 -97.0(6) . .
O7 P3 O8 Ag3 -26.6(5) . .
O9 P3 O8 Ag3 -149.0(3) . .
C25 P3 O8 Ag3 92.7(4) . .
O20 V4 O8 P3 107.8(6) . .
O19 V4 O8 P3 -85.2(8) . .
O21 V4 O8 P3 5.2(6) . .
O10 V4 O8 P3 -151.1(6) . .
O20 V4 O8 Ag3 -80.9(3) . .
O19 V4 O8 Ag3 86.0(6) . .
O21 V4 O8 Ag3 176.5(3) . .
O10 V4 O8 Ag3 20.1(2) . .
C1 Ag3 O8 P3 26.9(6) . .
O22 Ag3 O8 P3 -109.9(5) . .
O10 Ag3 O8 P3 155.0(4) . .
Ag4 Ag3 O8 P3 86.6(4) . .
Ag2 Ag3 O8 P3 40.3(3) . .
C1 Ag3 O8 V4 -146.2(4) . .
O22 Ag3 O8 V4 77.0(4) . .
O10 Ag3 O8 V4 -18.1(2) . .
Ag4 Ag3 O8 V4 -86.5(2) . .
Ag2 Ag3 O8 V4 -132.8(2) . .
O7 P3 O9 V1 -148.0(5) . 3_657
O8 P3 O9 V1 -25.1(7) . 3_657
C25 P3 O9 V1 91.9(6) . 3_657
O7 P3 O9 Ag8 2.9(5) . .
O8 P3 O9 Ag8 125.9(3) . .
C25 P3 O9 Ag8 -117.1(4) . .
C9 Ag8 O9 P3 41.4(7) . .
O2 Ag8 O9 P3 -162.9(4) 3_657 .
Ag5 Ag8 O9 P3 175.6(3) 3_657 .
Ag7 Ag8 O9 P3 -31.9(4) . .
Ag1 Ag8 O9 P3 20.8(3) . .
C9 Ag8 O9 V1 -159.3(5) . 3_657
O2 Ag8 O9 V1 -3.6(2) 3_657 3_657
Ag5 Ag8 O9 V1 -25.1(7) 3_657 3_657
Ag7 Ag8 O9 V1 127.34(19) . 3_657
Ag1 Ag8 O9 V1 -180.0(2) . 3_657
O11 P4 O10 V4 -145.1(5) . .
O17 P4 O10 V4 -24.6(6) . .
C29 P4 O10 V4 94.4(6) . .
O11 P4 O10 Ag3 24.6(5) . .
O17 P4 O10 Ag3 145.0(3) . .
C29 P4 O10 Ag3 -95.9(5) . .
O20 V4 O10 P4 -107.3(5) . .
O19 V4 O10 P4 -3.0(5) . .
O21 V4 O10 P4 89.4(7) . .
O8 V4 O10 P4 150.3(5) . .
O20 V4 O10 Ag3 82.0(3) . .
O19 V4 O10 Ag3 -173.7(3) . .
O21 V4 O10 Ag3 -81.3(6) . .
O8 V4 O10 Ag3 -20.5(3) . .
C1 Ag3 O10 P4 -31.2(6) . .
O22 Ag3 O10 P4 108.5(5) . .
O8 Ag3 O10 P4 -154.3(4) . .
Ag4 Ag3 O10 P4 -26.7(3) . .
Ag2 Ag3 O10 P4 -82.7(4) . .
C1 Ag3 O10 V4 141.2(4) . .
O22 Ag3 O10 V4 -79.1(4) . .
O8 Ag3 O10 V4 18.2(2) . .
Ag4 Ag3 O10 V4 145.8(2) . .
Ag2 Ag3 O10 V4 89.7(2) . .
O17 P4 O11 Ag4 -126.9(6) . .
O10 P4 O11 Ag4 -6.0(7) . .
C29 P4 O11 Ag4 113.4(6) . .
O17 P4 O11 Ag5 50.8(7) . .
O10 P4 O11 Ag5 171.7(5) . .
C29 P4 O11 Ag5 -69.0(7) . .
C1 Ag4 O11 P4 -21.6(8) . .
O1 Ag4 O11 P4 171.9(6) . .
Ag3 Ag4 O11 P4 -10.7(6) . .
Ag2 Ag4 O11 P4 41.3(7) . .
Ag6 Ag4 O11 P4 177(3) . .
C1 Ag4 O11 Ag5 160.0(4) . .
O1 Ag4 O11 Ag5 -6.5(3) . .
Ag3 Ag4 O11 Ag5 170.9(2) . .
Ag2 Ag4 O11 Ag5 -137.05(12) . .
Ag6 Ag4 O11 Ag5 -1(4) . .
C9 Ag5 O11 P4 -57.7(7) 3_657 .
O28 Ag5 O11 P4 103.9(8) . .
O29 Ag5 O11 P4 66.0(9) . .
O1 Ag5 O11 P4 -172.5(6) . .
Ag8 Ag5 O11 P4 -107.3(6) 3_657 .
Ag7 Ag5 O11 P4 -70.3(6) 3_657 .
C9 Ag5 O11 Ag4 120.6(3) 3_657 .
O28 Ag5 O11 Ag4 -77.8(6) . .
O29 Ag5 O11 Ag4 -115.7(7) . .
O1 Ag5 O11 Ag4 5.9(2) . .
Ag8 Ag5 O11 Ag4 71.0(2) 3_657 .
Ag7 Ag5 O11 Ag4 108.0(2) 3_657 .
O15 V2 O14 V1 -164.1(6) . .
O16 V2 O14 V1 92.1(6) . .
O4 V2 O14 V1 -0.5(11) . .
O3 V2 O14 V1 -62.4(6) . .
O13 V1 O14 V2 162.4(6) . .
O21 V1 O14 V2 -92.5(6) 3_657 .
O9 V1 O14 V2 -2.3(11) 3_657 .
O2 V1 O14 V2 60.5(6) . .
O18 V3 O16 V2 -161.1(6) . .
O19 V3 O16 V2 94.5(6) 3_657 .
O6 V3 O16 V2 -57.2(6) . .
O17 V3 O16 V2 11.3(10) 3_657 .
O15 V2 O16 V3 160.7(6) . .
O14 V2 O16 V3 -95.6(6) . .
O4 V2 O16 V3 58.0(6) . .
O3 V2 O16 V3 -2.8(11) . .
O11 P4 O17 V3 152.0(5) . 3_657
O10 P4 O17 V3 30.3(7) . 3_657
C29 P4 O17 V3 -87.9(7) . 3_657
O11 P4 O17 Ag7 14.0(4) . 3_657
O10 P4 O17 Ag7 -107.7(3) . 3_657
C29 P4 O17 Ag7 134.1(4) . 3_657
O20 V4 O19 V3 159.9(6) . 3_657
O21 V4 O19 V3 -95.3(6) . 3_657
O8 V4 O19 V3 -7.0(10) . 3_657
O10 V4 O19 V3 57.5(6) . 3_657
O20 V4 O21 V1 -162.5(6) . 3_657
O19 V4 O21 V1 91.4(6) . 3_657
O8 V4 O21 V1 -59.0(6) . 3_657
O10 V4 O21 V1 0.7(10) . 3_657
C1 Ag3 O22 C36 180(3) . .
O10 Ag3 O22 C36 30(3) . .
O8 Ag3 O22 C36 -35(3) . .
Ag4 Ag3 O22 C36 125(3) . .
Ag2 Ag3 O22 C36 -128(3) . .
C1 Ag6 O23 C33 -173.9(15) . .
O4 Ag6 O23 C33 41.4(17) . .
O3 Ag6 O23 C33 -23.5(17) . .
C2 Ag6 O23 C33 172.7(16) . .
Ag4 Ag6 O23 C33 -110.3(16) . .
Ag2 Ag6 O23 C33 120.0(15) . .
O7 Ag1 O24 C39 -63.7(10) . .
C9 Ag1 O24 C39 157.2(10) . .
O5 Ag1 O24 C39 23.0(10) . .
C10 Ag1 O24 C39 140.5(10) . .
Ag8 Ag1 O24 C39 -139.6(9) . .
Ag7 Ag1 O24 C39 86.1(12) . .
C9 Ag7 O25 N1 -166.9(11) . .
O17 Ag7 O25 N1 23.0(12) 3_657 .
Ag8 Ag7 O25 N1 -136.2(11) . .
Ag1 Ag7 O25 N1 163.0(11) . .
Ag5 Ag7 O25 N1 -88.7(13) 3_657 .
C9 Ag7 O25 Ag2 30.5(8) . .
O17 Ag7 O25 Ag2 -139.5(4) 3_657 .
Ag8 Ag7 O25 Ag2 61.3(4) . .
Ag1 Ag7 O25 Ag2 0.5(4) . .
Ag5 Ag7 O25 Ag2 108.8(4) 3_657 .
C1 Ag2 O25 N1 -6.4(14) . .
O7 Ag2 O25 N1 159.5(11) . .
O5 Ag2 O25 N1 -116.5(12) . .
Ag4 Ag2 O25 N1 19.3(12) . .
Ag3 Ag2 O25 N1 69.5(13) . .
Ag6 Ag2 O25 N1 -40.4(12) . .
C1 Ag2 O25 Ag7 155.9(4) . .
O7 Ag2 O25 Ag7 -38.2(5) . .
O5 Ag2 O25 Ag7 45.8(4) . .
Ag4 Ag2 O25 Ag7 -178.5(4) . .
Ag3 Ag2 O25 Ag7 -128.2(3) . .
Ag6 Ag2 O25 Ag7 121.9(4) . .
C9 Ag5 O28 N5 -2(3) 3_657 .
O29 Ag5 O28 N5 11.0(13) . .
O11 Ag5 O28 N5 -125.2(15) . .
O1 Ag5 O28 N5 152.5(15) . .
Ag8 Ag5 O28 N5 119.8(14) 3_657 .
Ag7 Ag5 O28 N5 -116.2(14) 3_657 .
C9 Ag5 O29 N5 164.1(15) 3_657 .
O28 Ag5 O29 N5 -11.1(14) . .
O11 Ag5 O29 N5 42.7(18) . .
O1 Ag5 O29 N5 -57.3(18) . .
Ag8 Ag5 O29 N5 -146.1(13) 3_657 .
Ag7 Ag5 O29 N5 122.1(14) 3_657 .
Ag7 O25 N1 O26 -40(2) . .
Ag2 O25 N1 O26 120.0(17) . .
Ag7 O25 N1 O27 164.4(11) . .
Ag2 O25 N1 O27 -35.9(19) . .
Ag5 O29 N5 O28 21(3) . .
Ag5 O29 N5 O30 -173(3) . .
Ag5 O28 N5 O29 -21(3) . .
Ag5 O28 N5 O30 170(2) . .
O1 Ag4 C1 C2 64(2) . .
O11 Ag4 C1 C2 -97(2) . .
Ag3 Ag4 C1 C2 -111(2) . .
Ag2 Ag4 C1 C2 167(3) . .
Ag6 Ag4 C1 C2 82(2) . .
O1 Ag4 C1 Ag3 175.4(3) . .
O11 Ag4 C1 Ag3 14.0(5) . .
Ag2 Ag4 C1 Ag3 -82.0(3) . .
Ag6 Ag4 C1 Ag3 -167.3(4) . .
O1 Ag4 C1 Ag6 -17.3(5) . .
O11 Ag4 C1 Ag6 -178.7(3) . .
Ag3 Ag4 C1 Ag6 167.3(4) . .
Ag2 Ag4 C1 Ag6 85.4(3) . .
O1 Ag4 C1 Ag2 -102.7(4) . .
O11 Ag4 C1 Ag2 95.9(4) . .
Ag3 Ag4 C1 Ag2 82.0(3) . .
Ag6 Ag4 C1 Ag2 -85.4(3) . .
O22 Ag3 C1 C2 31.9(9) . .
O10 Ag3 C1 C2 167.1(6) . .
O8 Ag3 C1 C2 -100.2(8) . .
Ag4 Ag3 C1 C2 161.0(9) . .
Ag2 Ag3 C1 C2 -117.6(9) . .
O22 Ag3 C1 Ag4 -129.1(4) . .
O10 Ag3 C1 Ag4 6.1(5) . .
O8 Ag3 C1 Ag4 98.8(4) . .
Ag2 Ag3 C1 Ag4 81.4(3) . .
O22 Ag3 C1 Ag6 -166.9(14) . .
O10 Ag3 C1 Ag6 -31.7(17) . .
O8 Ag3 C1 Ag6 61.0(16) . .
Ag4 Ag3 C1 Ag6 -37.8(12) . .
Ag2 Ag3 C1 Ag6 43.7(13) . .
O22 Ag3 C1 Ag2 149.4(4) . .
O10 Ag3 C1 Ag2 -75.3(4) . .
O8 Ag3 C1 Ag2 17.3(5) . .
Ag4 Ag3 C1 Ag2 -81.4(3) . .
O23 Ag6 C1 C2 -30.1(9) . .
O4 Ag6 C1 C2 106.5(7) . .
O3 Ag6 C1 C2 -171.3(6) . .
Ag4 Ag6 C1 C2 -160.5(9) . .
Ag2 Ag6 C1 C2 118.7(8) . .
O23 Ag6 C1 Ag4 130.4(4) . .
O4 Ag6 C1 Ag4 -93.0(3) . .
O3 Ag6 C1 Ag4 -10.8(5) . .
C2 Ag6 C1 Ag4 160.5(9) . .
Ag2 Ag6 C1 Ag4 -80.8(3) . .
O23 Ag6 C1 Ag3 168.0(13) . .
O4 Ag6 C1 Ag3 -55.4(15) . .
O3 Ag6 C1 Ag3 26.8(16) . .
C2 Ag6 C1 Ag3 -162(2) . .
Ag4 Ag6 C1 Ag3 37.6(12) . .
Ag2 Ag6 C1 Ag3 -43.2(13) . .
O23 Ag6 C1 Ag2 -148.8(4) . .
O4 Ag6 C1 Ag2 -12.2(4) . .
O3 Ag6 C1 Ag2 70.0(4) . .
C2 Ag6 C1 Ag2 -118.7(8) . .
Ag4 Ag6 C1 Ag2 80.8(3) . .
O7 Ag2 C1 C2 55.8(9) . .
O5 Ag2 C1 C2 -42.1(9) . .
O25 Ag2 C1 C2 -139.5(8) . .
Ag4 Ag2 C1 C2 -175.0(10) . .
Ag3 Ag2 C1 C2 102.6(9) . .
Ag6 Ag2 C1 C2 -91.6(8) . .
O7 Ag2 C1 Ag4 -129.1(2) . .
O5 Ag2 C1 Ag4 133.0(2) . .
O25 Ag2 C1 Ag4 35.5(6) . .
Ag3 Ag2 C1 Ag4 -82.3(3) . .
Ag6 Ag2 C1 Ag4 83.4(3) . .
O7 Ag2 C1 Ag3 -46.8(4) . .
O5 Ag2 C1 Ag3 -144.7(2) . .
O25 Ag2 C1 Ag3 117.8(4) . .
Ag4 Ag2 C1 Ag3 82.3(3) . .
Ag6 Ag2 C1 Ag3 165.8(4) . .
O7 Ag2 C1 Ag6 147.4(2) . .
O5 Ag2 C1 Ag6 49.6(3) . .
O25 Ag2 C1 Ag6 -47.9(6) . .
Ag4 Ag2 C1 Ag6 -83.4(3) . .
Ag3 Ag2 C1 Ag6 -165.8(4) . .
Ag4 C1 C2 C3 126(17) . .
Ag3 C1 C2 C3 19(18) . .
Ag6 C1 C2 C3 -154(18) . .
Ag2 C1 C2 C3 -69(18) . .
Ag4 C1 C2 Ag6 -80(2) . .
Ag3 C1 C2 Ag6 173.4(7) . .
Ag2 C1 C2 Ag6 85.7(6) . .
O23 Ag6 C2 C1 155.5(8) . .
O4 Ag6 C2 C1 -93.1(8) . .
O3 Ag6 C2 C1 16.3(11) . .
Ag4 Ag6 C2 C1 14.8(7) . .
Ag2 Ag6 C2 C1 -46.3(7) . .
O23 Ag6 C2 C3 -26.4(9) . .
C1 Ag6 C2 C3 178.1(13) . .
O4 Ag6 C2 C3 85.0(9) . .
O3 Ag6 C2 C3 -165.6(7) . .
Ag4 Ag6 C2 C3 -167.1(9) . .
Ag2 Ag6 C2 C3 131.8(9) . .
C1 C2 C3 C4 -17(19) . .
Ag6 C2 C3 C4 -170.4(9) . .
C1 C2 C3 C8 158(18) . .
Ag6 C2 C3 C8 4.3(15) . .
C8 C3 C4 C5 2(2) . .
C2 C3 C4 C5 177.0(12) . .
C3 C4 C5 C6 -1(2) . .
C4 C5 C6 C7 -2(2) . .
C5 C6 C7 C8 4(3) . .
C6 C7 C8 C3 -2(2) . .
C4 C3 C8 C7 0(2) . .
C2 C3 C8 C7 -175.4(13) . .
O2 Ag8 C9 C10 -112(2) 3_657 .
O9 Ag8 C9 C10 24(3) . .
Ag5 Ag8 C9 C10 -141(2) 3_657 .
Ag7 Ag8 C9 C10 132(2) . .
Ag1 Ag8 C9 C10 50(2) . .
O2 Ag8 C9 Ag7 116.2(5) 3_657 .
O9 Ag8 C9 Ag7 -108.0(4) . .
Ag5 Ag8 C9 Ag7 87.5(3) 3_657 .
Ag1 Ag8 C9 Ag7 -81.4(3) . .
O2 Ag8 C9 Ag5 28.7(7) 3_657 3_657
O9 Ag8 C9 Ag5 164.5(3) . 3_657
Ag7 Ag8 C9 Ag5 -87.5(3) . 3_657
Ag1 Ag8 C9 Ag5 -168.9(4) . 3_657
O2 Ag8 C9 Ag1 -162.4(4) 3_657 .
O9 Ag8 C9 Ag1 -26.6(6) . .
Ag5 Ag8 C9 Ag1 168.9(4) 3_657 .
Ag7 Ag8 C9 Ag1 81.4(3) . .
O25 Ag7 C9 C10 -115.9(9) . .
O17 Ag7 C9 C10 53.4(10) 3_657 .
Ag8 Ag7 C9 C10 -159.5(11) . .
Ag1 Ag7 C9 C10 -76.2(9) . .
Ag5 Ag7 C9 C10 120.0(10) 3_657 .
O25 Ag7 C9 Ag8 43.6(7) . .
O17 Ag7 C9 Ag8 -147.1(2) 3_657 .
Ag1 Ag7 C9 Ag8 83.3(3) . .
Ag5 Ag7 C9 Ag8 -80.5(3) 3_657 .
O25 Ag7 C9 Ag5 124.0(5) . 3_657
O17 Ag7 C9 Ag5 -66.6(3) 3_657 3_657
Ag8 Ag7 C9 Ag5 80.5(3) . 3_657
Ag1 Ag7 C9 Ag5 163.8(4) . 3_657
O25 Ag7 C9 Ag1 -39.8(6) . .
O17 Ag7 C9 Ag1 129.5(2) 3_657 .
Ag8 Ag7 C9 Ag1 -83.3(3) . .
Ag5 Ag7 C9 Ag1 -163.8(4) 3_657 .
O24 Ag1 C9 C10 -34.6(10) . .
O7 Ag1 C9 C10 -169.6(7) . .
O5 Ag1 C9 C10 92.5(8) . .
Ag8 Ag1 C9 C10 -160.3(10) . .
Ag7 Ag1 C9 C10 115.5(9) . .
O24 Ag1 C9 Ag8 125.7(4) . .
O7 Ag1 C9 Ag8 -9.2(4) . .
O5 Ag1 C9 Ag8 -107.1(3) . .
C10 Ag1 C9 Ag8 160.3(10) . .
Ag7 Ag1 C9 Ag8 -84.2(3) . .
O24 Ag1 C9 Ag7 -150.1(3) . .
O7 Ag1 C9 Ag7 74.9(4) . .
O5 Ag1 C9 Ag7 -23.0(4) . .
C10 Ag1 C9 Ag7 -115.5(9) . .
Ag8 Ag1 C9 Ag7 84.2(3) . .
O24 Ag1 C9 Ag5 158.0(13) . 3_657
O7 Ag1 C9 Ag5 23.1(16) . 3_657
O5 Ag1 C9 Ag5 -74.8(15) . 3_657
C10 Ag1 C9 Ag5 -167(2) . 3_657
Ag8 Ag1 C9 Ag5 32.3(13) . 3_657
Ag7 Ag1 C9 Ag5 -51.8(14) . 3_657
Ag8 C9 C10 C11 158(12) . .
Ag7 C9 C10 C11 -75(13) . .
Ag5 C9 C10 C11 24(13) 3_657 .
Ag1 C9 C10 C11 -151(13) . .
Ag8 C9 C10 Ag1 -51(2) . .
Ag7 C9 C10 Ag1 75.8(6) . .
Ag5 C9 C10 Ag1 174.9(8) 3_657 .
O24 Ag1 C10 C9 152.7(8) . .
O7 Ag1 C10 C9 16.4(11) . .
O5 Ag1 C10 C9 -102.1(8) . .
Ag8 Ag1 C10 C9 14.5(7) . .
Ag7 Ag1 C10 C9 -47.9(7) . .
O24 Ag1 C10 C11 -30.7(12) . .
O7 Ag1 C10 C11 -167.0(10) . .
C9 Ag1 C10 C11 176.6(16) . .
O5 Ag1 C10 C11 74.5(12) . .
Ag8 Ag1 C10 C11 -168.9(12) . .
Ag7 Ag1 C10 C11 128.7(12) . .
C9 C10 C11 C16 37(14) . .
Ag1 C10 C11 C16 -112.4(14) . .
C9 C10 C11 C12 -147(12) . .
Ag1 C10 C11 C12 63.7(19) . .
C16 C11 C12 C13 -6(3) . .
C10 C11 C12 C13 178(2) . .
C11 C12 C13 C14 7(4) . .
C12 C13 C14 C15 -5(5) . .
C13 C14 C15 C16 2(4) . .
C12 C11 C16 C15 2(3) . .
C10 C11 C16 C15 178.0(15) . .
C14 C15 C16 C11 0(3) . .
O1 P1 C17 C20 174.4(8) . .
O2 P1 C17 C20 -66.0(9) . .
O3 P1 C17 C20 53.1(9) . .
O1 P1 C17 C19 -63.1(9) . .
O2 P1 C17 C19 56.5(9) . .
O3 P1 C17 C19 175.5(8) . .
O1 P1 C17 C18 53.5(10) . .
O2 P1 C17 C18 173.2(9) . .
O3 P1 C17 C18 -67.8(9) . .
O5 P2 C21 C23 -176.1(8) . .
O6 P2 C21 C23 63.2(9) . .
O4 P2 C21 C23 -56.4(9) . .
O5 P2 C21 C22 -55.6(9) . .
O6 P2 C21 C22 -176.3(8) . .
O4 P2 C21 C22 64.1(9) . .
O5 P2 C21 C24 63.2(9) . .
O6 P2 C21 C24 -57.6(9) . .
O4 P2 C21 C24 -177.1(7) . .
O7 P3 C25 C27 171.9(7) . .
O8 P3 C25 C27 51.6(8) . .
O9 P3 C25 C27 -67.8(8) . .
O7 P3 C25 C26 51.8(9) . .
O8 P3 C25 C26 -68.4(9) . .
O9 P3 C25 C26 172.2(8) . .
O7 P3 C25 C28 -67.1(8) . .
O8 P3 C25 C28 172.7(7) . .
O9 P3 C25 C28 53.3(8) . .
O11 P4 C29 C30 -52.4(10) . .
O17 P4 C29 C30 -171.9(8) . .
O10 P4 C29 C30 68.8(9) . .
O11 P4 C29 C31 66.3(9) . .
O17 P4 C29 C31 -53.2(9) . .
O10 P4 C29 C31 -172.5(8) . .
O11 P4 C29 C32 -172.9(8) . .
O17 P4 C29 C32 67.6(9) . .
O10 P4 C29 C32 -51.7(9) . .
Ag6 O23 C33 N4 -145.2(15) . .
C35 N4 C33 O23 -177(2) . .
C34 N4 C33 O23 6(3) . .
Ag3 O22 C36 N3 -157(2) . .
C37 N3 C36 O22 29(6) . .
C38 N3 C36 O22 -152(4) . .
Ag1 O24 C39 N2 -143.4(11) . .
C40 N2 C39 O24 -179.3(15) . .
C41 N2 C39 O24 4(2) . .
C42 N6 C42 O31 69(34) 3_757 .
C43 N6 C42 O31 122(13) 3_757 .
C43 N6 C42 O31 -58(13) . .
C42 N6 C42 C43 -53(32) 3_757 3_757
C43 N6 C42 C43 180.00(4) . 3_757
C42 N6 C43 C42 180.00(3) . 3_757
C43 N6 C43 C42 94(17) 3_757 3_757
