#------------------------------------------------------------------------------
#$Date: 2016-03-21 18:20:39 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178809 $
#$URL: svn://www.crystallography.net/cod/cif/4/10/63/4106362.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4106362
loop_
_publ_author_name
'William D. Woodul'
'Emma Carter'
'Robert Müller'
'Anne F. Richards'
'Andreas Stasch'
'Martin Kaupp'
'Damien M. Murphy'
'Matthias Driess'
'Cameron Jones'
_publ_section_title
;
 A Neutral, Monomeric Germanium(I) Radical
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              10074
_journal_page_last               10077
_journal_paper_doi               10.1021/ja204344e
_journal_volume                  133
_journal_year                    2011
_chemical_formula_sum            'C72 H94 Cl Ge Mg2 N6'
_chemical_formula_weight         1200.19
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.09(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.924(3)
_cell_length_b                   20.046(4)
_cell_length_c                   24.386(5)
_cell_measurement_temperature    123(2)
_cell_volume                     6807(2)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      123(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0593
_diffrn_reflns_av_sigmaI/netI    0.1330
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            18775
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.93
_exptl_absorpt_coefficient_mu    0.552
_exptl_absorpt_correction_T_max  0.960
_exptl_absorpt_correction_T_min  0.911
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Sortav (Blessing, 1995)'
_exptl_crystal_colour            'dichroic red-yellow'
_exptl_crystal_density_diffrn    1.171
_exptl_crystal_description       plate
_exptl_crystal_F_000             2564
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.07
_refine_diff_density_max         0.649
_refine_diff_density_min         -0.459
_refine_diff_density_rms         0.073
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     749
_refine_ls_number_reflns         11947
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.014
_refine_ls_R_factor_all          0.1395
_refine_ls_R_factor_gt           0.0617
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0545P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1104
_refine_ls_wR_factor_ref         0.1329
_reflns_number_gt                6847
_reflns_number_total             11947
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja204344e_si_005.cif
_cod_data_source_block           compound2S
_cod_database_code               4106362
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ge1 Ge 0.41791(3) 0.28082(2) 0.757052(15) 0.02378(13) Uani 1 1 d .
Cl1 Cl 0.44960(7) 0.46556(5) 0.75362(3) 0.0292(3) Uani 1 1 d .
Mg1 Mg 0.45061(8) 0.38682(7) 0.82600(4) 0.0234(3) Uani 1 1 d .
N1 N 0.3402(2) 0.19884(17) 0.78515(11) 0.0242(8) Uani 1 1 d .
C1 C 0.6091(3) 0.2216(2) 0.71424(14) 0.0312(10) Uani 1 1 d .
H1A H 0.6452 0.1796 0.7129 0.047 Uiso 1 1 calc R
H1B H 0.6444 0.2541 0.7365 0.047 Uiso 1 1 calc R
H1C H 0.6010 0.2390 0.6770 0.047 Uiso 1 1 calc R
Mg2 Mg 0.39829(9) 0.40759(7) 0.66991(4) 0.0249(3) Uani 1 1 d .
N2 N 0.3612(2) 0.31620(16) 0.69607(11) 0.0251(8) Uani 1 1 d .
C2 C 0.5132(3) 0.2095(2) 0.73905(13) 0.0244(10) Uani 1 1 d .
N3 N 0.5684(2) 0.37912(16) 0.87587(11) 0.0240(8) Uani 1 1 d .
C3 C 0.4854(3) 0.1498(2) 0.75673(14) 0.0286(10) Uani 1 1 d .
H3 H 0.5260 0.1119 0.7531 0.034 Uiso 1 1 calc R
N4 N 0.3690(2) 0.42668(15) 0.88732(11) 0.0230(8) Uani 1 1 d .
C4 C 0.3912(3) 0.1444(2) 0.78174(14) 0.0263(10) Uani 1 1 d .
N5 N 0.5124(2) 0.42134(17) 0.61674(11) 0.0247(8) Uani 1 1 d .
C5 C 0.3581(3) 0.0783(2) 0.80287(15) 0.0348(11) Uani 1 1 d .
H5A H 0.3077 0.0851 0.8303 0.052 Uiso 1 1 calc R
H5B H 0.4124 0.0547 0.8197 0.052 Uiso 1 1 calc R
H5C H 0.3325 0.0517 0.7724 0.052 Uiso 1 1 calc R
N6 N 0.3121(2) 0.47610(17) 0.62902(11) 0.0262(8) Uani 1 1 d .
C6 C 0.2488(3) 0.19667(19) 0.81332(14) 0.0248(10) Uani 1 1 d .
C7 C 0.2457(3) 0.2088(2) 0.86989(14) 0.0278(10) Uani 1 1 d .
C8 C 0.1582(3) 0.2038(2) 0.89658(16) 0.0371(11) Uani 1 1 d .
H8 H 0.1556 0.2112 0.9350 0.044 Uiso 1 1 calc R
C9 C 0.0736(3) 0.1882(2) 0.86854(17) 0.0363(11) Uani 1 1 d .
C10 C 0.0803(3) 0.1756(2) 0.81280(17) 0.0345(11) Uani 1 1 d .
H10 H 0.0234 0.1651 0.7931 0.041 Uiso 1 1 calc R
C11 C 0.1665(3) 0.1778(2) 0.78460(14) 0.0270(10) Uani 1 1 d .
C12 C 0.3361(3) 0.2249(2) 0.90180(14) 0.0371(11) Uani 1 1 d .
H12A H 0.3847 0.1906 0.8947 0.056 Uiso 1 1 calc R
H12B H 0.3214 0.2261 0.9411 0.056 Uiso 1 1 calc R
H12C H 0.3607 0.2685 0.8902 0.056 Uiso 1 1 calc R
C13 C -0.0211(3) 0.1833(3) 0.89901(19) 0.0578(14) Uani 1 1 d .
H13A H -0.0604 0.2226 0.8908 0.087 Uiso 1 1 calc R
H13B H -0.0087 0.1812 0.9385 0.087 Uiso 1 1 calc R
H13C H -0.0552 0.1430 0.8874 0.087 Uiso 1 1 calc R
C14 C 0.1704(3) 0.1556(2) 0.72561(14) 0.0381(11) Uani 1 1 d .
H14A H 0.1724 0.1068 0.7240 0.057 Uiso 1 1 calc R
H14B H 0.2281 0.1739 0.7082 0.057 Uiso 1 1 calc R
H14C H 0.1133 0.1717 0.7062 0.057 Uiso 1 1 calc R
C15 C 0.2961(3) 0.2842(2) 0.65928(13) 0.0245(9) Uani 1 1 d .
C16 C 0.1974(3) 0.3016(2) 0.66271(14) 0.0280(10) Uani 1 1 d .
C17 C 0.1335(3) 0.2766(2) 0.62346(15) 0.0323(10) Uani 1 1 d .
H17 H 0.0678 0.2891 0.6257 0.039 Uiso 1 1 calc R
C18 C 0.1614(3) 0.2347(2) 0.58163(14) 0.0315(11) Uani 1 1 d .
C19 C 0.2572(3) 0.2171(2) 0.57963(14) 0.0319(10) Uani 1 1 d .
H19 H 0.2778 0.1879 0.5513 0.038 Uiso 1 1 calc R
C20 C 0.3253(3) 0.2402(2) 0.61700(14) 0.0271(10) Uani 1 1 d .
C21 C 0.1603(3) 0.3435(2) 0.70919(14) 0.0338(11) Uani 1 1 d .
H21A H 0.0988 0.3636 0.6987 0.051 Uiso 1 1 calc R
H21B H 0.2068 0.3789 0.7175 0.051 Uiso 1 1 calc R
H21C H 0.1513 0.3155 0.7417 0.051 Uiso 1 1 calc R
C22 C 0.0897(3) 0.2099(2) 0.53969(16) 0.0454(12) Uani 1 1 d .
H22A H 0.1235 0.1858 0.5106 0.068 Uiso 1 1 calc R
H22B H 0.0552 0.2479 0.5238 0.068 Uiso 1 1 calc R
H22C H 0.0437 0.1799 0.5575 0.068 Uiso 1 1 calc R
C23 C 0.4274(3) 0.2168(2) 0.61254(14) 0.0335(11) Uani 1 1 d .
H23A H 0.4383 0.1802 0.6385 0.050 Uiso 1 1 calc R
H23B H 0.4709 0.2538 0.6211 0.050 Uiso 1 1 calc R
H23C H 0.4396 0.2011 0.5751 0.050 Uiso 1 1 calc R
C24 C 0.6523(3) 0.3692(2) 0.96387(14) 0.0337(11) Uani 1 1 d .
H24A H 0.6870 0.3298 0.9506 0.051 Uiso 1 1 calc R
H24B H 0.6349 0.3628 1.0024 0.051 Uiso 1 1 calc R
H24C H 0.6934 0.4086 0.9604 0.051 Uiso 1 1 calc R
C25 C 0.5625(3) 0.37885(19) 0.93023(14) 0.0260(10) Uani 1 1 d .
C26 C 0.4775(3) 0.3912(2) 0.95925(14) 0.0263(10) Uani 1 1 d .
H26 H 0.4788 0.3793 0.9969 0.032 Uiso 1 1 calc R
C27 C 0.3907(3) 0.41871(19) 0.94052(14) 0.0242(10) Uani 1 1 d .
C28 C 0.3208(3) 0.4422(2) 0.98377(13) 0.0321(11) Uani 1 1 d .
H28A H 0.3187 0.4911 0.9839 0.048 Uiso 1 1 calc R
H28B H 0.3417 0.4262 1.0198 0.048 Uiso 1 1 calc R
H28C H 0.2567 0.4246 0.9756 0.048 Uiso 1 1 calc R
C29 C 0.6620(3) 0.3732(2) 0.85121(13) 0.0262(10) Uani 1 1 d .
C30 C 0.7134(3) 0.4310(2) 0.83773(14) 0.0286(10) Uani 1 1 d .
C31 C 0.8015(3) 0.4233(3) 0.81198(14) 0.0374(12) Uani 1 1 d .
H31 H 0.8373 0.4622 0.8032 0.045 Uiso 1 1 calc R
C32 C 0.8397(3) 0.3617(3) 0.79840(15) 0.0397(12) Uani 1 1 d .
C33 C 0.7884(3) 0.3058(2) 0.81266(14) 0.0366(12) Uani 1 1 d .
H33 H 0.8138 0.2631 0.8041 0.044 Uiso 1 1 calc R
C34 C 0.6991(3) 0.3100(2) 0.83955(14) 0.0315(11) Uani 1 1 d .
C35 C 0.6741(3) 0.4992(2) 0.85111(16) 0.0398(12) Uani 1 1 d .
H35A H 0.7240 0.5328 0.8450 0.060 Uiso 1 1 calc R
H35B H 0.6539 0.5003 0.8896 0.060 Uiso 1 1 calc R
H35C H 0.6188 0.5086 0.8274 0.060 Uiso 1 1 calc R
C36 C 0.9334(3) 0.3551(3) 0.76807(16) 0.0587(15) Uani 1 1 d .
H36A H 0.9712 0.3187 0.7841 0.088 Uiso 1 1 calc R
H36B H 0.9695 0.3970 0.7710 0.088 Uiso 1 1 calc R
H36C H 0.9206 0.3454 0.7294 0.088 Uiso 1 1 calc R
C37 C 0.6471(3) 0.2475(2) 0.85642(15) 0.0401(12) Uani 1 1 d .
H37A H 0.6523 0.2418 0.8962 0.060 Uiso 1 1 calc R
H37B H 0.6758 0.2090 0.8379 0.060 Uiso 1 1 calc R
H37C H 0.5792 0.2510 0.8461 0.060 Uiso 1 1 calc R
C38 C 0.2887(3) 0.4699(2) 0.87525(13) 0.0228(9) Uani 1 1 d .
C39 C 0.3039(3) 0.5391(2) 0.87530(13) 0.0277(10) Uani 1 1 d .
C40 C 0.2244(3) 0.5802(2) 0.86428(14) 0.0332(11) Uani 1 1 d .
H40 H 0.2331 0.6272 0.8641 0.040 Uiso 1 1 calc R
C41 C 0.1338(3) 0.5547(3) 0.85363(15) 0.0368(11) Uani 1 1 d .
C42 C 0.1231(3) 0.4863(2) 0.85275(15) 0.0350(11) Uani 1 1 d .
H42 H 0.0618 0.4681 0.8446 0.042 Uiso 1 1 calc R
C43 C 0.1989(3) 0.4429(2) 0.86338(14) 0.0300(10) Uani 1 1 d .
C44 C 0.4015(3) 0.5688(2) 0.88576(15) 0.0341(11) Uani 1 1 d .
H44A H 0.4277 0.5508 0.9200 0.051 Uiso 1 1 calc R
H44B H 0.3959 0.6174 0.8887 0.051 Uiso 1 1 calc R
H44C H 0.4445 0.5575 0.8554 0.051 Uiso 1 1 calc R
C45 C 0.0499(3) 0.6002(3) 0.84138(17) 0.0528(14) Uani 1 1 d .
H45A H 0.0307 0.5950 0.8029 0.079 Uiso 1 1 calc R
H45B H 0.0688 0.6466 0.8480 0.079 Uiso 1 1 calc R
H45C H -0.0041 0.5886 0.8652 0.079 Uiso 1 1 calc R
C46 C 0.1842(3) 0.3688(2) 0.86350(15) 0.0352(11) Uani 1 1 d .
H46A H 0.1180 0.3586 0.8526 0.053 Uiso 1 1 calc R
H46B H 0.1962 0.3513 0.9004 0.053 Uiso 1 1 calc R
H46C H 0.2288 0.3480 0.8376 0.053 Uiso 1 1 calc R
C47 C 0.6166(3) 0.4979(2) 0.56442(15) 0.0338(11) Uani 1 1 d .
H47A H 0.6712 0.4807 0.5855 0.051 Uiso 1 1 calc R
H47B H 0.6223 0.5464 0.5607 0.051 Uiso 1 1 calc R
H47C H 0.6160 0.4774 0.5279 0.051 Uiso 1 1 calc R
C48 C 0.5239(3) 0.4811(2) 0.59405(13) 0.0257(10) Uani 1 1 d .
C49 C 0.4529(3) 0.5307(2) 0.59310(14) 0.0277(10) Uani 1 1 d .
H49 H 0.4754 0.5741 0.5844 0.033 Uiso 1 1 calc R
C50 C 0.3538(3) 0.5262(2) 0.60304(13) 0.0243(10) Uani 1 1 d .
C51 C 0.2928(3) 0.5825(2) 0.58010(15) 0.0331(11) Uani 1 1 d .
H51A H 0.2495 0.5649 0.5519 0.050 Uiso 1 1 calc R
H51B H 0.3346 0.6166 0.5639 0.050 Uiso 1 1 calc R
H51C H 0.2549 0.6024 0.6097 0.050 Uiso 1 1 calc R
C52 C 0.5848(3) 0.3729(2) 0.60300(14) 0.0266(10) Uani 1 1 d .
C53 C 0.6653(3) 0.3631(2) 0.63609(14) 0.0254(10) Uani 1 1 d .
C54 C 0.7379(3) 0.3197(2) 0.61816(15) 0.0339(11) Uani 1 1 d .
H54 H 0.7928 0.3133 0.6407 0.041 Uiso 1 1 calc R
C55 C 0.7320(3) 0.2863(2) 0.56905(15) 0.0354(11) Uani 1 1 d .
C56 C 0.6476(3) 0.2935(2) 0.53832(15) 0.0357(11) Uani 1 1 d .
H56 H 0.6404 0.2685 0.5055 0.043 Uiso 1 1 calc R
C57 C 0.5743(3) 0.3362(2) 0.55423(14) 0.0279(10) Uani 1 1 d .
C58 C 0.6758(3) 0.3997(2) 0.68954(14) 0.0374(11) Uani 1 1 d .
H58A H 0.6911 0.4466 0.6823 0.056 Uiso 1 1 calc R
H58B H 0.7276 0.3795 0.7111 0.056 Uiso 1 1 calc R
H58C H 0.6155 0.3970 0.7101 0.056 Uiso 1 1 calc R
C59 C 0.8128(3) 0.2430(2) 0.54916(17) 0.0462(12) Uani 1 1 d .
H59A H 0.7910 0.1966 0.5470 0.069 Uiso 1 1 calc R
H59B H 0.8669 0.2461 0.5748 0.069 Uiso 1 1 calc R
H59C H 0.8332 0.2580 0.5128 0.069 Uiso 1 1 calc R
C60 C 0.4849(3) 0.3429(2) 0.51976(14) 0.0397(12) Uani 1 1 d .
H60A H 0.4911 0.3153 0.4868 0.060 Uiso 1 1 calc R
H60B H 0.4764 0.3897 0.5091 0.060 Uiso 1 1 calc R
H60C H 0.4291 0.3282 0.5410 0.060 Uiso 1 1 calc R
C61 C 0.2086(3) 0.4773(2) 0.62989(15) 0.0287(10) Uani 1 1 d .
C62 C 0.1606(3) 0.5108(2) 0.67212(16) 0.0356(11) Uani 1 1 d .
C63 C 0.0611(3) 0.5120(2) 0.6720(2) 0.0494(13) Uani 1 1 d .
H63 H 0.0286 0.5341 0.7010 0.059 Uiso 1 1 calc R
C64 C 0.0072(3) 0.4822(2) 0.6310(2) 0.0516(13) Uani 1 1 d .
C65 C 0.0560(3) 0.4493(2) 0.5899(2) 0.0488(13) Uani 1 1 d .
H65 H 0.0200 0.4283 0.5616 0.059 Uiso 1 1 calc R
C66 C 0.1567(3) 0.4457(2) 0.58805(16) 0.0357(11) Uani 1 1 d .
C67 C 0.2157(3) 0.5455(2) 0.71741(16) 0.0455(12) Uani 1 1 d .
H67A H 0.1731 0.5766 0.7365 0.068 Uiso 1 1 calc R
H67B H 0.2698 0.5700 0.7016 0.068 Uiso 1 1 calc R
H67C H 0.2399 0.5122 0.7434 0.068 Uiso 1 1 calc R
C68 C -0.1017(3) 0.4866(3) 0.6303(3) 0.087(2) Uani 1 1 d .
H68A H -0.1267 0.4755 0.6667 0.130 Uiso 1 1 calc R
H68B H -0.1274 0.4551 0.6033 0.130 Uiso 1 1 calc R
H68C H -0.1212 0.5320 0.6205 0.130 Uiso 1 1 calc R
C69 C 0.2081(3) 0.4102(2) 0.54196(15) 0.0423(12) Uani 1 1 d .
H69A H 0.2524 0.4412 0.5240 0.063 Uiso 1 1 calc R
H69B H 0.1609 0.3941 0.5152 0.063 Uiso 1 1 calc R
H69C H 0.2442 0.3723 0.5568 0.063 Uiso 1 1 calc R
C70 C 1.0010(3) 0.4652(2) 0.99201(19) 0.0563(14) Uiso 1 1 d .
H70A H 1.0040 0.4375 1.0256 0.068 Uiso 1 1 calc R
H70B H 1.0605 0.4569 0.9709 0.068 Uiso 1 1 calc R
C71 C 0.9147(3) 0.4423(3) 0.95746(19) 0.0573(14) Uiso 1 1 d .
H71A H 0.8553 0.4480 0.9791 0.069 Uiso 1 1 calc R
H71B H 0.9096 0.4710 0.9246 0.069 Uiso 1 1 calc R
C72 C 0.9226(3) 0.3721(2) 0.94004(17) 0.0504(13) Uiso 1 1 d .
H72A H 0.9794 0.3667 0.9167 0.076 Uiso 1 1 calc R
H72B H 0.8650 0.3595 0.9194 0.076 Uiso 1 1 calc R
H72C H 0.9288 0.3435 0.9724 0.076 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mg Mg 0.0486 0.0363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
N2 Ge1 C2 112.66(13) .
N2 Ge1 N1 110.49(12) .
C2 Ge1 N1 81.54(15) .
N2 Ge1 Mg1 105.61(10) .
C2 Ge1 Mg1 125.32(11) .
N1 Ge1 Mg1 119.63(8) .
Mg1 Cl1 Mg2 107.80(6) .
N4 Mg1 N3 92.33(12) .
N4 Mg1 Cl1 106.39(10) .
N3 Mg1 Cl1 119.82(11) .
N4 Mg1 Ge1 131.20(10) .
N3 Mg1 Ge1 115.94(10) .
Cl1 Mg1 Ge1 93.36(5) .
C4 N1 C6 118.9(3) .
C4 N1 Ge1 110.9(3) .
C6 N1 Ge1 129.5(3) .
N2 Mg2 N5 121.23(14) .
N2 Mg2 N6 127.38(14) .
N5 Mg2 N6 93.11(13) .
N2 Mg2 Cl1 104.04(9) .
N5 Mg2 Cl1 103.60(10) .
N6 Mg2 Cl1 104.68(10) .
C15 N2 Ge1 127.6(3) .
C15 N2 Mg2 112.0(2) .
Ge1 N2 Mg2 120.13(15) .
C3 C2 C1 122.8(4) .
C3 C2 Ge1 112.3(3) .
C1 C2 Ge1 124.6(3) .
C25 N3 C29 118.2(3) .
C25 N3 Mg1 122.9(2) .
C29 N3 Mg1 118.9(2) .
C2 C3 C4 117.8(4) .
C27 N4 C38 116.2(3) .
C27 N4 Mg1 122.4(2) .
C38 N4 Mg1 121.1(2) .
N1 C4 C3 117.1(4) .
N1 C4 C5 123.5(4) .
C3 C4 C5 119.3(4) .
C48 N5 C52 115.2(3) .
C48 N5 Mg2 118.3(3) .
C52 N5 Mg2 126.5(2) .
C50 N6 C61 115.7(3) .
C50 N6 Mg2 118.6(3) .
C61 N6 Mg2 125.5(3) .
C11 C6 C7 121.0(3) .
C11 C6 N1 119.5(3) .
C7 C6 N1 119.3(3) .
C8 C7 C6 118.6(3) .
C8 C7 C12 120.3(3) .
C6 C7 C12 121.1(3) .
C7 C8 C9 121.8(4) .
C10 C9 C8 117.6(4) .
C10 C9 C13 121.9(4) .
C8 C9 C13 120.5(4) .
C11 C10 C9 122.8(4) .
C10 C11 C6 118.1(3) .
C10 C11 C14 119.8(3) .
C6 C11 C14 121.9(3) .
C20 C15 C16 118.3(3) .
C20 C15 N2 123.7(3) .
C16 C15 N2 117.8(3) .
C17 C16 C15 119.1(3) .
C17 C16 C21 119.9(3) .
C15 C16 C21 121.0(3) .
C18 C17 C16 123.0(4) .
C17 C18 C19 117.1(4) .
C17 C18 C22 120.9(4) .
C19 C18 C22 122.0(4) .
C18 C19 C20 123.3(4) .
C19 C20 C15 119.1(3) .
C19 C20 C23 119.5(3) .
C15 C20 C23 121.3(3) .
N3 C25 C26 123.8(3) .
N3 C25 C24 119.4(3) .
C26 C25 C24 116.6(3) .
C25 C26 C27 129.2(3) .
N4 C27 C26 123.7(3) .
N4 C27 C28 119.6(3) .
C26 C27 C28 116.8(3) .
C34 C29 C30 120.9(4) .
C34 C29 N3 119.6(4) .
C30 C29 N3 119.4(4) .
C31 C30 C29 117.7(4) .
C31 C30 C35 121.4(4) .
C29 C30 C35 120.9(4) .
C32 C31 C30 123.2(4) .
C33 C32 C31 117.8(4) .
C33 C32 C36 120.3(5) .
C31 C32 C36 121.9(5) .
C32 C33 C34 121.9(4) .
C29 C34 C33 118.4(4) .
C29 C34 C37 121.4(4) .
C33 C34 C37 120.2(4) .
C43 C38 C39 121.3(4) .
C43 C38 N4 120.2(4) .
C39 C38 N4 118.4(3) .
C38 C39 C40 117.4(4) .
C38 C39 C44 121.8(4) .
C40 C39 C44 120.8(4) .
C41 C40 C39 122.5(4) .
C42 C41 C40 117.8(4) .
C42 C41 C45 120.9(4) .
C40 C41 C45 121.2(5) .
C41 C42 C43 122.5(4) .
C42 C43 C38 118.4(4) .
C42 C43 C46 121.1(4) .
C38 C43 C46 120.5(4) .
N5 C48 C49 124.1(4) .
N5 C48 C47 120.1(4) .
C49 C48 C47 115.8(4) .
C48 C49 C50 130.2(4) .
N6 C50 C49 124.3(4) .
N6 C50 C51 119.7(3) .
C49 C50 C51 116.0(3) .
C53 C52 C57 119.9(4) .
C53 C52 N5 121.6(3) .
C57 C52 N5 118.5(3) .
C52 C53 C54 119.1(3) .
C52 C53 C58 120.6(4) .
C54 C53 C58 120.3(3) .
C55 C54 C53 122.1(4) .
C54 C55 C56 117.7(4) .
C54 C55 C59 121.3(4) .
C56 C55 C59 121.0(4) .
C57 C56 C55 122.1(4) .
C56 C57 C52 118.9(3) .
C56 C57 C60 120.5(3) .
C52 C57 C60 120.7(4) .
C62 C61 C66 120.4(4) .
C62 C61 N6 119.8(3) .
C66 C61 N6 119.8(3) .
C63 C62 C61 119.0(4) .
C63 C62 C67 120.0(4) .
C61 C62 C67 121.0(4) .
C64 C63 C62 122.4(4) .
C65 C64 C63 117.6(4) .
C65 C64 C68 120.8(5) .
C63 C64 C68 121.5(5) .
C64 C65 C66 122.7(4) .
C61 C66 C65 117.8(4) .
C61 C66 C69 120.7(4) .
C65 C66 C69 121.5(4) .
C70 C70 C71 114.8(5) 3_767
C72 C71 C70 112.6(4) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ge1 N2 1.826(3) .
Ge1 C2 2.000(4) .
Ge1 N1 2.084(3) .
Ge1 Mg1 2.7472(14) .
Cl1 Mg1 2.3681(15) .
Cl1 Mg2 2.4542(15) .
Mg1 N4 2.043(3) .
Mg1 N3 2.046(3) .
N1 C4 1.304(5) .
N1 C6 1.448(4) .
C1 C2 1.487(5) .
Mg2 N2 2.008(3) .
Mg2 N5 2.071(3) .
Mg2 N6 2.078(3) .
N2 C15 1.427(4) .
C2 C3 1.328(5) .
N3 C25 1.328(4) .
N3 C29 1.442(5) .
C3 C4 1.453(5) .
N4 C27 1.341(4) .
N4 C38 1.445(5) .
C4 C5 1.495(5) .
N5 C48 1.330(5) .
N5 C52 1.439(5) .
N6 C50 1.322(5) .
N6 C61 1.442(5) .
C6 C11 1.394(5) .
C6 C7 1.402(5) .
C7 C8 1.386(5) .
C7 C12 1.514(5) .
C8 C9 1.396(5) .
C9 C10 1.386(5) .
C9 C13 1.517(5) .
C10 C11 1.384(5) .
C11 C14 1.507(5) .
C15 C20 1.417(5) .
C15 C16 1.421(5) .
C16 C17 1.398(5) .
C16 C21 1.503(5) .
C17 C18 1.378(5) .
C18 C19 1.381(5) .
C18 C22 1.513(5) .
C19 C20 1.392(5) .
C20 C23 1.501(5) .
C24 C25 1.507(5) .
C25 C26 1.401(5) .
C26 C27 1.404(5) .
C27 C28 1.512(5) .
C29 C34 1.397(5) .
C29 C30 1.401(5) .
C30 C31 1.387(5) .
C30 C35 1.507(6) .
C31 C32 1.385(6) .
C32 C33 1.375(6) .
C32 C36 1.507(5) .
C33 C34 1.409(5) .
C34 C37 1.506(6) .
C38 C43 1.392(5) .
C38 C39 1.403(5) .
C39 C40 1.404(5) .
C39 C44 1.505(5) .
C40 C41 1.385(6) .
C41 C42 1.380(6) .
C41 C45 1.511(6) .
C42 C43 1.391(5) .
C43 C46 1.500(6) .
C47 C48 1.518(5) .
C48 C49 1.401(5) .
C49 C50 1.404(5) .
C50 C51 1.519(5) .
C52 C53 1.394(5) .
C52 C57 1.406(5) .
C53 C54 1.403(5) .
C53 C58 1.503(5) .
C54 C55 1.375(5) .
C55 C56 1.400(5) .
C55 C59 1.502(5) .
C56 C57 1.388(5) .
C57 C60 1.507(5) .
C61 C62 1.401(5) .
C61 C66 1.401(5) .
C62 C63 1.386(6) .
C62 C67 1.513(6) .
C63 C64 1.383(6) .
C64 C65 1.380(6) .
C64 C68 1.519(6) .
C65 C66 1.404(6) .
C66 C69 1.511(6) .
C70 C70 1.449(9) 3_767
C70 C71 1.536(6) .
C71 C72 1.474(6) .
