#------------------------------------------------------------------------------
#$Date: 2016-03-21 18:31:43 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178815 $
#$URL: svn://www.crystallography.net/cod/cif/4/10/69/4106996.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4106996
loop_
_publ_author_name
'Ruwei Shen'
'Tieqiao Chen'
'Yalei Zhao'
'Renhua Qiu'
'Yongbo Zhou'
'Shuangfeng Yin'
'Xiangbo Wang'
'Midori Goto'
'Li-Biao Han'
_publ_section_title
;
 Facile Regio- and Stereoselective Hydrometalation of Alkynes with a
 Combination of Carboxylic Acids and Group 10 Transition Metal Complexes:
 Selective Hydrogenation of Alkynes with Formic Acid
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              17037
_journal_page_last               17044
_journal_paper_doi               10.1021/ja2069246
_journal_volume                  133
_journal_year                    2011
_chemical_formula_sum            'C28 H44 O2 P2 Pd'
_chemical_formula_weight         580.97
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                76.1030(10)
_cell_angle_beta                 71.0080(10)
_cell_angle_gamma                82.1290(10)
_cell_formula_units_Z            2
_cell_length_a                   10.1647(4)
_cell_length_b                   10.5937(4)
_cell_length_c                   14.4332(6)
_cell_measurement_reflns_used    9969
_cell_measurement_temperature    183(2)
_cell_measurement_theta_max      28.38
_cell_measurement_theta_min      2.21
_cell_volume                     1423.64(10)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      183(2)
_diffrn_detector_area_resol_mean 8.333
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.890
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'rotating unit'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0130
_diffrn_reflns_av_sigmaI/netI    0.0163
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            14506
_diffrn_reflns_theta_full        27.00
_diffrn_reflns_theta_max         28.58
_diffrn_reflns_theta_min         1.98
_diffrn_standards_decay_%        0.0
_exptl_absorpt_coefficient_mu    0.786
_exptl_absorpt_correction_T_max  0.9618
_exptl_absorpt_correction_T_min  0.7440
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.355
_exptl_crystal_description       rectangular
_exptl_crystal_F_000             608
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.441
_refine_diff_density_min         -0.391
_refine_diff_density_rms         0.048
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.708
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     306
_refine_ls_number_reflns         6469
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.708
_refine_ls_R_factor_all          0.0205
_refine_ls_R_factor_gt           0.0189
_refine_ls_shift/su_max          0.016
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0737P)²+2.7862P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0553
_refine_ls_wR_factor_ref         0.0586
_reflns_number_gt                6093
_reflns_number_total             6469
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja2069246_si_002_1.cif
_cod_data_source_block           2a
_cod_database_code               4106996
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.93627(14) 0.29896(14) 0.28928(10) 0.0220(3) Uani 1 1 d .
C2 C 0.83914(14) 0.22497(13) 0.38133(10) 0.0222(3) Uani 1 1 d .
C3 C 0.88327(16) 0.16158(15) 0.46412(11) 0.0272(3) Uani 1 1 d .
H3 H 0.9762 0.1688 0.4624 0.033 Uiso 1 1 calc R
C4 C 0.79423(18) 0.08846(16) 0.54863(12) 0.0332(3) Uani 1 1 d .
H4 H 0.8261 0.0477 0.6043 0.040 Uiso 1 1 calc R
C5 C 0.65938(18) 0.07470(16) 0.55203(13) 0.0359(4) Uani 1 1 d .
H5 H 0.5980 0.0255 0.6101 0.043 Uiso 1 1 calc R
C6 C 0.61444(16) 0.13358(16) 0.46970(14) 0.0357(4) Uani 1 1 d .
H6 H 0.5225 0.1228 0.4710 0.043 Uiso 1 1 calc R
C7 C 0.70265(15) 0.20799(15) 0.38556(12) 0.0293(3) Uani 1 1 d .
H7 H 0.6702 0.2480 0.3300 0.035 Uiso 1 1 calc R
C8 C 0.89868(15) 0.41180(14) 0.23490(11) 0.0254(3) Uani 1 1 d .
H8 H 0.9658 0.4405 0.1720 0.030 Uiso 1 1 calc R
C9 C 0.77019(14) 0.49886(13) 0.25659(11) 0.0246(3) Uani 1 1 d .
C10 C 0.69492(16) 0.51891(15) 0.35247(12) 0.0288(3) Uani 1 1 d .
H10 H 0.7212 0.4692 0.4086 0.035 Uiso 1 1 calc R
C11 C 0.58229(17) 0.61036(16) 0.36692(14) 0.0350(3) Uani 1 1 d .
H11 H 0.5320 0.6223 0.4327 0.042 Uiso 1 1 calc R
C12 C 0.54292(17) 0.68433(16) 0.28582(15) 0.0383(4) Uani 1 1 d .
H12 H 0.4668 0.7478 0.2959 0.046 Uiso 1 1 calc R
C13 C 0.61466(18) 0.66555(17) 0.19032(15) 0.0386(4) Uani 1 1 d .
H13 H 0.5873 0.7151 0.1346 0.046 Uiso 1 1 calc R
C14 C 0.72694(17) 0.57386(15) 0.17628(12) 0.0315(3) Uani 1 1 d .
H14 H 0.7758 0.5617 0.1104 0.038 Uiso 1 1 calc R
C15 C 0.93632(18) 0.14917(18) 0.11083(13) 0.0365(4) Uani 1 1 d .
H15A H 0.9056 0.0829 0.0856 0.044 Uiso 1 1 calc R
H15B H 0.8522 0.1912 0.1525 0.044 Uiso 1 1 calc R
C16 C 1.0121(3) 0.2514(2) 0.02242(14) 0.0512(5) Uani 1 1 d .
H16A H 1.0488 0.3135 0.0469 0.077 Uiso 1 1 calc R
H16B H 0.9470 0.2979 -0.0135 0.077 Uiso 1 1 calc R
H16C H 1.0893 0.2087 -0.0230 0.077 Uiso 1 1 calc R
C17 C 0.94324(19) -0.05866(16) 0.28102(13) 0.0363(4) Uani 1 1 d .
H17A H 1.0009 -0.1102 0.3223 0.044 Uiso 1 1 calc R
H17B H 0.8630 -0.0166 0.3260 0.044 Uiso 1 1 calc R
C18 C 0.8874(2) -0.1525(2) 0.23904(16) 0.0498(5) Uani 1 1 d .
H18A H 0.8250 -0.1039 0.2016 0.075 Uiso 1 1 calc R
H18B H 0.8360 -0.2186 0.2944 0.075 Uiso 1 1 calc R
H18C H 0.9656 -0.1953 0.1943 0.075 Uiso 1 1 calc R
C19 C 1.18323(18) -0.01792(17) 0.10289(13) 0.0351(3) Uani 1 1 d .
H19A H 1.1391 -0.0564 0.0651 0.042 Uiso 1 1 calc R
H19B H 1.2486 0.0454 0.0539 0.042 Uiso 1 1 calc R
C20 C 1.2662(2) -0.12626(19) 0.15551(16) 0.0473(4) Uani 1 1 d .
H20A H 1.2987 -0.0921 0.2010 0.071 Uiso 1 1 calc R
H20B H 1.3466 -0.1580 0.1054 0.071 Uiso 1 1 calc R
H20C H 1.2064 -0.1981 0.1938 0.071 Uiso 1 1 calc R
C21 C 1.32535(16) 0.31601(16) 0.37472(12) 0.0307(3) Uani 1 1 d .
H21A H 1.3950 0.2484 0.3479 0.037 Uiso 1 1 calc R
H21B H 1.3767 0.3880 0.3763 0.037 Uiso 1 1 calc R
C22 C 1.23991(18) 0.25781(18) 0.48152(13) 0.0357(3) Uani 1 1 d .
H22A H 1.1700 0.3238 0.5085 0.054 Uiso 1 1 calc R
H22B H 1.3018 0.2292 0.5234 0.054 Uiso 1 1 calc R
H22C H 1.1931 0.1831 0.4812 0.054 Uiso 1 1 calc R
C23 C 1.34603(17) 0.46773(17) 0.17975(13) 0.0351(3) Uani 1 1 d .
H23A H 1.3779 0.5389 0.1992 0.042 Uiso 1 1 calc R
H23B H 1.4283 0.4081 0.1574 0.042 Uiso 1 1 calc R
C24 C 1.2892(2) 0.5259(2) 0.09223(15) 0.0512(5) Uani 1 1 d .
H24A H 1.2672 0.4556 0.0674 0.077 Uiso 1 1 calc R
H24B H 1.3593 0.5783 0.0385 0.077 Uiso 1 1 calc R
H24C H 1.2045 0.5812 0.1145 0.077 Uiso 1 1 calc R
C25 C 1.09987(16) 0.50443(15) 0.34543(13) 0.0304(3) Uani 1 1 d .
H25A H 1.0569 0.5570 0.2948 0.037 Uiso 1 1 calc R
H25B H 1.0242 0.4612 0.4023 0.037 Uiso 1 1 calc R
C26 C 1.16388(19) 0.59678(17) 0.38297(14) 0.0385(4) Uani 1 1 d .
H26A H 1.1963 0.5479 0.4392 0.058 Uiso 1 1 calc R
H26B H 1.0936 0.6653 0.4052 0.058 Uiso 1 1 calc R
H26C H 1.2429 0.6364 0.3286 0.058 Uiso 1 1 calc R
C27 C 1.42426(18) 0.15059(18) 0.13434(14) 0.0375(4) Uani 1 1 d .
C28 C 1.5701(2) 0.0895(3) 0.1310(2) 0.0742(8) Uani 1 1 d .
H28A H 1.5852 0.0090 0.1056 0.111 Uiso 1 1 calc R
H28B H 1.5794 0.0694 0.1985 0.111 Uiso 1 1 calc R
H28C H 1.6396 0.1506 0.0865 0.111 Uiso 1 1 calc R
O1 O 1.33775(11) 0.13067(11) 0.21986(9) 0.0318(2) Uani 1 1 d .
O2 O 1.40269(15) 0.21257(16) 0.05612(10) 0.0519(3) Uani 1 1 d .
P1 P 1.04757(4) 0.06946(4) 0.18780(3) 0.02406(8) Uani 1 1 d .
P2 P 1.22021(4) 0.37822(4) 0.28994(3) 0.02328(8) Uani 1 1 d .
Pd1 Pd 1.131479(9) 0.216781(9) 0.247703(7) 0.01957(4) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C8 C1 C2 123.58(12)
C8 C1 Pd1 121.05(10)
C2 C1 Pd1 115.36(10)
C3 C2 C7 117.39(13)
C3 C2 C1 121.38(12)
C7 C2 C1 121.06(13)
C2 C3 C4 121.46(14)
C2 C3 H3 119.3
C4 C3 H3 119.3
C5 C4 C3 120.25(15)
C5 C4 H4 119.9
C3 C4 H4 119.9
C4 C5 C6 119.35(15)
C4 C5 H5 120.3
C6 C5 H5 120.3
C7 C6 C5 120.55(15)
C7 C6 H6 119.7
C5 C6 H6 119.7
C2 C7 C6 120.96(14)
C2 C7 H7 119.5
C6 C7 H7 119.5
C1 C8 C9 130.85(13)
C1 C8 H8 114.6
C9 C8 H8 114.6
C14 C9 C10 117.36(13)
C14 C9 C8 118.71(13)
C10 C9 C8 123.72(13)
C11 C10 C9 121.02(15)
C11 C10 H10 119.5
C9 C10 H10 119.5
C12 C11 C10 120.33(16)
C12 C11 H11 119.8
C10 C11 H11 119.8
C11 C12 C13 119.84(15)
C11 C12 H12 120.1
C13 C12 H12 120.1
C12 C13 C14 119.61(16)
C12 C13 H13 120.2
C14 C13 H13 120.2
C9 C14 C13 121.84(16)
C9 C14 H14 119.1
C13 C14 H14 119.1
C16 C15 P1 111.64(13)
C16 C15 H15A 109.3
P1 C15 H15A 109.3
C16 C15 H15B 109.3
P1 C15 H15B 109.3
H15A C15 H15B 108.0
C15 C16 H16A 109.5
C15 C16 H16B 109.5
H16A C16 H16B 109.5
C15 C16 H16C 109.5
H16A C16 H16C 109.5
H16B C16 H16C 109.5
C18 C17 P1 115.80(13)
C18 C17 H17A 108.3
P1 C17 H17A 108.3
C18 C17 H17B 108.3
P1 C17 H17B 108.3
H17A C17 H17B 107.4
C17 C18 H18A 109.5
C17 C18 H18B 109.5
H18A C18 H18B 109.5
C17 C18 H18C 109.5
H18A C18 H18C 109.5
H18B C18 H18C 109.5
C20 C19 P1 114.11(12)
C20 C19 H19A 108.7
P1 C19 H19A 108.7
C20 C19 H19B 108.7
P1 C19 H19B 108.7
H19A C19 H19B 107.6
C19 C20 H20A 109.5
C19 C20 H20B 109.5
H20A C20 H20B 109.5
C19 C20 H20C 109.5
H20A C20 H20C 109.5
H20B C20 H20C 109.5
C22 C21 P2 113.60(11)
C22 C21 H21A 108.8
P2 C21 H21A 108.8
C22 C21 H21B 108.8
P2 C21 H21B 108.8
H21A C21 H21B 107.7
C21 C22 H22A 109.5
C21 C22 H22B 109.5
H22A C22 H22B 109.5
C21 C22 H22C 109.5
H22A C22 H22C 109.5
H22B C22 H22C 109.5
C24 C23 P2 114.14(13)
C24 C23 H23A 108.7
P2 C23 H23A 108.7
C24 C23 H23B 108.7
P2 C23 H23B 108.7
H23A C23 H23B 107.6
C23 C24 H24A 109.5
C23 C24 H24B 109.5
H24A C24 H24B 109.5
C23 C24 H24C 109.5
H24A C24 H24C 109.5
H24B C24 H24C 109.5
C26 C25 P2 115.80(11)
C26 C25 H25A 108.3
P2 C25 H25A 108.3
C26 C25 H25B 108.3
P2 C25 H25B 108.3
H25A C25 H25B 107.4
C25 C26 H26A 109.5
C25 C26 H26B 109.5
H26A C26 H26B 109.5
C25 C26 H26C 109.5
H26A C26 H26C 109.5
H26B C26 H26C 109.5
O2 C27 O1 126.93(16)
O2 C27 C28 119.16(18)
O1 C27 C28 113.91(17)
C27 C28 H28A 109.5
C27 C28 H28B 109.5
H28A C28 H28B 109.5
C27 C28 H28C 109.5
H28A C28 H28C 109.5
H28B C28 H28C 109.5
C27 O1 Pd1 121.68(11)
C19 P1 C15 102.53(8)
C19 P1 C17 104.64(8)
C15 P1 C17 104.37(9)
C19 P1 Pd1 114.20(6)
C15 P1 Pd1 112.42(6)
C17 P1 Pd1 117.17(6)
C21 P2 C25 104.61(7)
C21 P2 C23 101.98(8)
C25 P2 C23 104.81(8)
C21 P2 Pd1 114.03(6)
C25 P2 Pd1 119.09(5)
C23 P2 Pd1 110.60(6)
C1 Pd1 O1 173.69(5)
C1 Pd1 P2 91.66(4)
O1 Pd1 P2 84.59(3)
C1 Pd1 P1 88.49(4)
O1 Pd1 P1 95.79(3)
P2 Pd1 P1 173.695(13)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
C1 C8 1.345(2)
C1 C2 1.4873(19)
C1 Pd1 2.0145(13)
C2 C3 1.400(2)
C2 C7 1.4032(19)
C3 C4 1.388(2)
C3 H3 0.9500
C4 C5 1.382(2)
C4 H4 0.9500
C5 C6 1.389(3)
C5 H5 0.9500
C6 C7 1.387(2)
C6 H6 0.9500
C7 H7 0.9500
C8 C9 1.4823(19)
C8 H8 0.9500
C9 C14 1.401(2)
C9 C10 1.397(2)
C10 C11 1.390(2)
C10 H10 0.9500
C11 C12 1.387(3)
C11 H11 0.9500
C12 C13 1.382(3)
C12 H12 0.9500
C13 C14 1.388(2)
C13 H13 0.9500
C14 H14 0.9500
C15 C16 1.523(3)
C15 P1 1.8253(17)
C15 H15A 0.9900
C15 H15B 0.9900
C16 H16A 0.9800
C16 H16B 0.9800
C16 H16C 0.9800
C17 C18 1.532(2)
C17 P1 1.8345(17)
C17 H17A 0.9900
C17 H17B 0.9900
C18 H18A 0.9800
C18 H18B 0.9800
C18 H18C 0.9800
C19 C20 1.529(3)
C19 P1 1.8320(16)
C19 H19A 0.9900
C19 H19B 0.9900
C20 H20A 0.9800
C20 H20B 0.9800
C20 H20C 0.9800
C21 C22 1.526(2)
C21 P2 1.8288(16)
C21 H21A 0.9900
C21 H21B 0.9900
C22 H22A 0.9800
C22 H22B 0.9800
C22 H22C 0.9800
C23 C24 1.521(3)
C23 P2 1.8298(16)
C23 H23A 0.9900
C23 H23B 0.9900
C24 H24A 0.9800
C24 H24B 0.9800
C24 H24C 0.9800
C25 C26 1.527(2)
C25 P2 1.8315(15)
C25 H25A 0.9900
C25 H25B 0.9900
C26 H26A 0.9800
C26 H26B 0.9800
C26 H26C 0.9800
C27 O2 1.233(2)
C27 O1 1.249(2)
C27 C28 1.525(3)
C28 H28A 0.9800
C28 H28B 0.9800
C28 H28C 0.9800
O1 Pd1 2.1198(11)
P1 Pd1 2.3245(4)
P2 Pd1 2.3219(4)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C8 C1 C2 C3 -141.88(15)
Pd1 C1 C2 C3 39.40(17)
C8 C1 C2 C7 42.9(2)
Pd1 C1 C2 C7 -135.79(12)
C7 C2 C3 C4 -2.2(2)
C1 C2 C3 C4 -177.57(14)
C2 C3 C4 C5 1.2(2)
C3 C4 C5 C6 0.7(2)
C4 C5 C6 C7 -1.4(3)
C3 C2 C7 C6 1.4(2)
C1 C2 C7 C6 176.81(14)
C5 C6 C7 C2 0.3(2)
C2 C1 C8 C9 10.6(2)
Pd1 C1 C8 C9 -170.75(12)
C1 C8 C9 C14 -151.20(16)
C1 C8 C9 C10 34.2(2)
C14 C9 C10 C11 -0.4(2)
C8 C9 C10 C11 174.28(14)
C9 C10 C11 C12 -0.4(2)
C10 C11 C12 C13 1.0(3)
C11 C12 C13 C14 -0.9(3)
C10 C9 C14 C13 0.5(2)
C8 C9 C14 C13 -174.41(15)
C12 C13 C14 C9 0.1(3)
O2 C27 O1 Pd1 -4.8(3)
C28 C27 O1 Pd1 175.19(16)
C20 C19 P1 C15 -162.20(14)
C20 C19 P1 C17 -53.49(16)
C20 C19 P1 Pd1 75.91(14)
C16 C15 P1 C19 -65.77(15)
C16 C15 P1 C17 -174.69(13)
C16 C15 P1 Pd1 57.32(14)
C18 C17 P1 C19 -53.44(17)
C18 C17 P1 C15 53.92(17)
C18 C17 P1 Pd1 178.95(13)
C22 C21 P2 C25 60.10(14)
C22 C21 P2 C23 169.09(12)
C22 C21 P2 Pd1 -71.68(12)
C26 C25 P2 C21 43.88(15)
C26 C25 P2 C23 -63.03(14)
C26 C25 P2 Pd1 172.67(11)
C24 C23 P2 C21 176.90(14)
C24 C23 P2 C25 -74.27(15)
C24 C23 P2 Pd1 55.27(15)
C8 C1 Pd1 P2 70.96(12)
C2 C1 Pd1 P2 -110.28(10)
C8 C1 Pd1 P1 -102.73(12)
C2 C1 Pd1 P1 76.03(10)
C27 O1 Pd1 P1 79.62(13)
C21 P2 Pd1 C1 127.14(7)
C23 P2 Pd1 C1 -118.64(7)
C21 P2 Pd1 O1 -47.77(6)
C25 P2 Pd1 O1 -172.10(7)
C19 P1 Pd1 C1 163.74(8)
C15 P1 Pd1 C1 47.47(8)
C17 P1 Pd1 C1 -73.43(8)
C19 P1 Pd1 O1 -20.91(7)
C15 P1 Pd1 O1 -137.19(7)
C17 P1 Pd1 O1 101.92(8)
