#------------------------------------------------------------------------------
#$Date: 2016-03-21 19:10:27 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178838 $
#$URL: svn://www.crystallography.net/cod/cif/4/10/92/4109251.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4109251
loop_
_publ_author_name
'Theodore Lazarides'
'Timothy L. Easun'
'Claire Veyne-Marti'
'Wassim Z. Alsindi'
'Michael W. George'
'Nina Deppermann'
'Christopher A. Hunter'
'Harry Adams'
'Michael D. Ward'
_publ_contact_author
; 
        Prof. Mike Ward
        Department of Chemistry
        University of Sheffield
        SHEFFIELD
        S3 7HF
;
_publ_contact_author_email       m.d.ward@sheffield.ac.uk
_publ_contact_author_fax         '0114 2229346'
_publ_section_title
;
 Structural and Photophysical Properties of Adducts of [Ru(bipy)(CN)4]2-
 with Different Metal Cations: Metallochromism and Its Use in Switching
 Photoinduced Energy Transfer
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              4014
_journal_page_last               4027
_journal_paper_doi               10.1021/ja068436n
_journal_volume                  129
_journal_year                    2007
_chemical_formula_sum            'C14 H16 K Li N6 O4 Ru'
_chemical_formula_weight         479.44
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                111.702(6)
_cell_angle_beta                 100.355(6)
_cell_angle_gamma                96.102(4)
_cell_formula_units_Z            4
_cell_length_a                   7.8843(9)
_cell_length_b                   14.8087(17)
_cell_length_c                   18.078(3)
_cell_measurement_reflns_used    9824
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      54.745
_cell_measurement_theta_min      5.534
_cell_volume                     1894.4(5)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      103(2)
_diffrn_measured_fraction_theta_full 0.970
_diffrn_measured_fraction_theta_max 0.970
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0235
_diffrn_reflns_av_sigmaI/netI    0.0181
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            37119
_diffrn_reflns_theta_full        27.41
_diffrn_reflns_theta_max         27.41
_diffrn_reflns_theta_min         1.25
_exptl_absorpt_coefficient_mu    1.079
_exptl_absorpt_correction_T_max  0.8998
_exptl_absorpt_correction_T_min  0.8131
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.681
_exptl_crystal_description       block
_exptl_crystal_F_000             960
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         2.518
_refine_diff_density_min         -0.876
_refine_diff_density_rms         0.079
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     489
_refine_ls_number_reflns         8385
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.033
_refine_ls_R_factor_all          0.0259
_refine_ls_R_factor_gt           0.0247
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0309P)²+2.6428P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0653
_refine_ls_wR_factor_ref         0.0665
_reflns_number_gt                8005
_reflns_number_total             8385
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja068436nsi20070122_062933_5.cif
_cod_data_source_block           imw764m
_cod_original_cell_volume        1894.4(4)
_cod_database_code               4109251
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ru1 Ru 0.122290(19) 0.484428(10) 0.227990(9) 0.01166(5) Uani 1 1 d .
Ru2 Ru -0.131082(19) -0.003903(11) 0.261994(9) 0.01244(5) Uani 1 1 d .
K1 K -0.38750(6) 0.35982(4) 0.25706(3) 0.02950(11) Uani 1 1 d .
K2 K 0.11346(6) 0.17149(4) 0.18312(3) 0.02504(10) Uani 1 1 d .
Li1 Li 0.3191(5) 0.3200(3) 0.4205(2) 0.0197(7) Uani 1 1 d .
Li2 Li -0.3261(5) 0.1602(2) 0.0680(2) 0.0178(7) Uani 1 1 d .
O1 O 0.5236(2) 0.26597(13) 0.43837(11) 0.0318(4) Uani 1 1 d .
H1WA H 0.5382 0.1984 0.4156 0.038 Uiso 1 1 d R
H1WB H 0.6379 0.3077 0.4604 0.038 Uiso 1 1 d R
O2 O 0.2949(3) 0.42334(13) 0.51799(11) 0.0389(5) Uani 1 1 d .
H2WA H 0.2489 0.4281 0.5647 0.047 Uiso 1 1 d R
H2WB H 0.2571 0.4756 0.5039 0.047 Uiso 1 1 d R
O3 O -0.33612(19) 0.05635(11) -0.03833(9) 0.0202(3) Uani 1 1 d .
H3WB H -0.4489 0.0170 -0.0705 0.024 Uiso 1 1 d R
H3WA H -0.2784 0.0591 -0.0801 0.024 Uiso 1 1 d R
O4 O -0.5322(2) 0.21737(11) 0.06657(10) 0.0267(3) Uani 1 1 d .
H4WA H -0.5457 0.2847 0.0792 0.032 Uiso 1 1 d R
H4WB H -0.6492 0.1790 0.0460 0.032 Uiso 1 1 d R
N1 N 0.0138(2) 0.55181(12) 0.15093(10) 0.0138(3) Uani 1 1 d .
N2 N 0.2720(2) 0.63041(12) 0.28437(10) 0.0142(3) Uani 1 1 d .
N3 N 0.4135(2) 0.41176(13) 0.12896(11) 0.0205(4) Uani 1 1 d .
N4 N -0.1308(2) 0.27827(13) 0.12778(11) 0.0215(4) Uani 1 1 d .
N5 N 0.3126(3) 0.39105(15) 0.34227(12) 0.0270(4) Uani 1 1 d .
N6 N -0.1441(3) 0.55002(13) 0.34321(12) 0.0227(4) Uani 1 1 d .
N7 N -0.0176(2) -0.06565(12) 0.34289(10) 0.0148(3) Uani 1 1 d .
N8 N -0.2750(2) -0.15070(12) 0.20948(10) 0.0139(3) Uani 1 1 d .
N9 N 0.1204(3) -0.06371(14) 0.13947(12) 0.0251(4) Uani 1 1 d .
N10 N -0.3174(2) 0.07386(13) 0.13562(11) 0.0190(3) Uani 1 1 d .
N11 N 0.1167(3) 0.20290(14) 0.36137(12) 0.0262(4) Uani 1 1 d .
N12 N -0.4131(3) 0.07300(14) 0.36643(12) 0.0253(4) Uani 1 1 d .
C1 C -0.1202(3) 0.50757(15) 0.08391(12) 0.0192(4) Uani 1 1 d .
H1 H -0.1786 0.4425 0.0717 0.023 Uiso 1 1 calc R
C2 C -0.1756(3) 0.55345(17) 0.03240(13) 0.0237(4) Uani 1 1 d .
H2 H -0.2713 0.5206 -0.0140 0.028 Uiso 1 1 calc R
C3 C -0.0903(3) 0.64765(17) 0.04899(14) 0.0237(4) Uani 1 1 d .
H3 H -0.1239 0.6796 0.0132 0.028 Uiso 1 1 calc R
C4 C 0.0451(3) 0.69484(15) 0.11857(13) 0.0204(4) Uani 1 1 d .
H4 H 0.1046 0.7600 0.1316 0.024 Uiso 1 1 calc R
C5 C 0.0930(2) 0.64563(14) 0.16924(12) 0.0146(4) Uani 1 1 d .
C6 C 0.2319(2) 0.69110(14) 0.24569(12) 0.0145(4) Uani 1 1 d .
C7 C 0.3153(3) 0.79002(15) 0.27755(13) 0.0192(4) Uani 1 1 d .
H7 H 0.2844 0.8315 0.2499 0.023 Uiso 1 1 calc R
C8 C 0.4434(3) 0.82687(16) 0.34994(14) 0.0235(4) Uani 1 1 d .
H8 H 0.5020 0.8940 0.3725 0.028 Uiso 1 1 calc R
C9 C 0.4853(3) 0.76479(16) 0.38913(13) 0.0235(4) Uani 1 1 d .
H9 H 0.5733 0.7886 0.4388 0.028 Uiso 1 1 calc R
C10 C 0.3966(3) 0.66727(15) 0.35473(12) 0.0190(4) Uani 1 1 d .
H10 H 0.4251 0.6250 0.3820 0.023 Uiso 1 1 calc R
C11 C 0.3048(3) 0.43915(14) 0.16157(12) 0.0149(4) Uani 1 1 d .
C12 C -0.0360(3) 0.35406(14) 0.16488(12) 0.0162(4) Uani 1 1 d .
C13 C 0.2432(3) 0.42862(15) 0.30244(12) 0.0176(4) Uani 1 1 d .
C14 C -0.0500(3) 0.52756(14) 0.30029(12) 0.0162(4) Uani 1 1 d .
C15 C -0.3989(3) -0.19121(15) 0.13888(12) 0.0183(4) Uani 1 1 d .
H15 H -0.4290 -0.1512 0.1097 0.022 Uiso 1 1 calc R
C16 C -0.4845(3) -0.28871(16) 0.10691(13) 0.0218(4) Uani 1 1 d .
H16 H -0.5718 -0.3149 0.0569 0.026 Uiso 1 1 calc R
C17 C -0.4408(3) -0.34760(15) 0.14912(13) 0.0217(4) Uani 1 1 d .
H17 H -0.4974 -0.4149 0.1284 0.026 Uiso 1 1 calc R
C18 C -0.3133(3) -0.30677(15) 0.22199(13) 0.0178(4) Uani 1 1 d .
H18 H -0.2810 -0.3459 0.2517 0.021 Uiso 1 1 calc R
C19 C -0.2331(2) -0.20796(14) 0.25124(12) 0.0147(4) Uani 1 1 d .
C20 C -0.0946(2) -0.15871(14) 0.32781(12) 0.0147(4) Uani 1 1 d .
C21 C -0.0451(3) -0.20382(15) 0.38155(13) 0.0200(4) Uani 1 1 d .
H21 H -0.1031 -0.2686 0.3707 0.024 Uiso 1 1 calc R
C22 C 0.0893(3) -0.15331(17) 0.45091(13) 0.0233(4) Uani 1 1 d .
H22 H 0.1236 -0.1824 0.4888 0.028 Uiso 1 1 calc R
C23 C 0.1726(3) -0.06003(17) 0.46414(13) 0.0239(4) Uani 1 1 d .
H23 H 0.2680 -0.0250 0.5103 0.029 Uiso 1 1 calc R
C24 C 0.1162(3) -0.01805(16) 0.40970(13) 0.0202(4) Uani 1 1 d .
H24 H 0.1734 0.0465 0.4196 0.024 Uiso 1 1 calc R
C25 C 0.0367(3) -0.04472(14) 0.18728(13) 0.0173(4) Uani 1 1 d .
C26 C -0.2508(3) 0.04391(14) 0.18237(12) 0.0153(4) Uani 1 1 d .
C27 C 0.0226(3) 0.12701(15) 0.32399(13) 0.0190(4) Uani 1 1 d .
C28 C -0.3113(3) 0.04295(14) 0.33034(12) 0.0169(4) Uani 1 1 d .
O7 O -0.8550(2) 0.09469(11) 0.01938(10) 0.0258(3) Uani 1 1 d .
H7WA H -0.8092 0.0349 0.0099 0.061(10) Uiso 1 1 d R
H7WB H -0.9279 0.0885 -0.0315 0.038(8) Uiso 1 1 d R
O6 O 0.4529(2) 0.17749(13) 0.24145(10) 0.0288(4) Uani 1 1 d .
H6WA H 0.5213 0.1343 0.2111 0.035 Uiso 1 1 d R
H6WB H 0.4600 0.1558 0.2856 0.035 Uiso 1 1 d R
O5 O -0.1009(3) 0.34370(14) 0.35652(13) 0.0422(5) Uani 1 1 d .
H5WA H -0.0534 0.2866 0.3563 0.051 Uiso 1 1 d R
H5WB H -0.0126 0.3930 0.3557 0.051 Uiso 1 1 d R
O8 O 0.8252(3) 0.40748(16) 0.50681(13) 0.0476(5) Uani 1 1 d .
H8WA H 0.9159 0.4259 0.5558 0.057 Uiso 1 1 d R
H8WB H 0.8808 0.3865 0.4618 0.057 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C13 Ru1 C12 89.05(8) . .
C13 Ru1 C14 90.87(8) . .
C12 Ru1 C14 90.09(8) . .
C13 Ru1 C11 85.35(8) . .
C12 Ru1 C11 90.56(8) . .
C14 Ru1 C11 176.16(7) . .
C13 Ru1 N1 175.19(7) . .
C12 Ru1 N1 95.13(7) . .
C14 Ru1 N1 91.50(7) . .
C11 Ru1 N1 92.22(7) . .
C13 Ru1 N2 98.60(7) . .
C12 Ru1 N2 172.35(7) . .
C14 Ru1 N2 89.64(7) . .
C11 Ru1 N2 90.22(7) . .
N1 Ru1 N2 77.24(6) . .
C26 Ru2 C27 90.57(8) . .
C26 Ru2 C25 86.39(8) . .
C27 Ru2 C25 90.45(8) . .
C26 Ru2 C28 88.33(8) . .
C27 Ru2 C28 89.21(8) . .
C25 Ru2 C28 174.70(7) . .
C26 Ru2 N7 175.48(7) . .
C27 Ru2 N7 93.91(7) . .
C25 Ru2 N7 94.18(7) . .
C28 Ru2 N7 91.13(7) . .
C26 Ru2 N8 98.25(7) . .
C27 Ru2 N8 171.18(7) . .
C25 Ru2 N8 90.26(7) . .
C28 Ru2 N8 90.88(7) . .
N7 Ru2 N8 77.27(6) . .
C26 Ru2 K2 56.75(6) . .
C27 Ru2 K2 50.25(6) . .
C25 Ru2 K2 55.86(5) . .
C28 Ru2 K2 120.47(5) . .
N7 Ru2 K2 127.05(5) . .
N8 Ru2 K2 135.92(4) . .
O5 K1 O6 88.45(6) . 1_455
O5 K1 N6 69.00(6) . .
O6 K1 N6 154.11(5) 1_455 .
O5 K1 N3 157.41(6) . 1_455
O6 K1 N3 108.99(5) 1_455 1_455
N6 K1 N3 96.19(5) . 1_455
O5 K1 N5 110.54(6) . 1_455
O6 K1 N5 72.60(5) 1_455 1_455
N6 K1 N5 102.77(6) . 1_455
N3 K1 N5 88.87(5) 1_455 1_455
O5 K1 C14 66.01(6) . .
O6 K1 C14 152.80(5) 1_455 .
N6 K1 C14 21.07(5) . .
N3 K1 C14 93.91(5) 1_455 .
N5 K1 C14 123.75(6) 1_455 .
O5 K1 O4 124.38(5) . .
O6 K1 O4 70.13(5) 1_455 .
N6 K1 O4 132.99(5) . .
N3 K1 O4 53.64(5) 1_455 .
N5 K1 O4 110.53(5) 1_455 .
C14 K1 O4 115.85(5) . .
O5 K1 C11 165.60(6) . 1_455
O6 K1 C11 104.65(5) 1_455 1_455
N6 K1 C11 96.86(5) . 1_455
N3 K1 C11 20.30(5) 1_455 1_455
N5 K1 C11 68.88(5) 1_455 1_455
C14 K1 C11 101.84(5) . 1_455
O4 K1 C11 67.04(4) . 1_455
O5 K1 C13 128.86(6) . 1_455
O6 K1 C13 84.07(5) 1_455 1_455
N6 K1 C13 99.97(5) . 1_455
N3 K1 C13 68.96(5) 1_455 1_455
N5 K1 C13 20.37(5) 1_455 1_455
C14 K1 C13 118.75(5) . 1_455
O4 K1 C13 100.14(5) . 1_455
C11 K1 C13 48.77(5) 1_455 1_455
O5 K1 N4 77.95(6) . .
O6 K1 N4 96.84(5) 1_455 .
N6 K1 N4 90.86(5) . .
N3 K1 N4 85.59(5) 1_455 .
N5 K1 N4 165.77(5) 1_455 .
C14 K1 N4 69.80(5) . .
O4 K1 N4 55.92(4) . .
C11 K1 N4 105.85(5) 1_455 .
C13 K1 N4 153.16(5) 1_455 .
O5 K1 C12 71.02(6) . .
O6 K1 C12 114.20(5) 1_455 .
N6 K1 C12 71.34(5) . .
N3 K1 C12 88.37(5) 1_455 .
N5 K1 C12 173.18(5) 1_455 .
C14 K1 C12 50.28(5) . .
O4 K1 C12 72.61(5) . .
C11 K1 C12 107.87(5) 1_455 .
C13 K1 C12 155.06(5) 1_455 .
N4 K1 C12 19.53(5) . .
O5 K1 Li2 94.10(7) . .
O6 K1 Li2 69.48(6) 1_455 .
N6 K1 Li2 122.82(7) . .
N3 K1 Li2 79.43(6) 1_455 .
N5 K1 Li2 133.71(7) 1_455 .
C14 K1 Li2 101.78(7) . .
O4 K1 Li2 30.61(6) . .
C11 K1 Li2 96.09(6) 1_455 .
C13 K1 Li2 129.09(7) 1_455 .
N4 K1 Li2 32.21(6) . .
C12 K1 Li2 51.68(6) . .
O5 K1 H4WA 137.7 . .
O6 K1 H4WA 83.9 1_455 .
N6 K1 H4WA 121.2 . .
N3 K1 H4WA 36.6 1_455 .
N5 K1 H4WA 106.7 1_455 .
C14 K1 H4WA 108.2 . .
O4 K1 H4WA 17.3 . .
C11 K1 H4WA 51.7 1_455 .
C13 K1 H4WA 91.7 1_455 .
N4 K1 H4WA 61.8 . .
C12 K1 H4WA 74.5 . .
Li2 K1 H4WA 44.4 . .
O5 K1 H5WB 18.0 . .
O6 K1 H5WB 105.6 1_455 .
N6 K1 H5WB 53.9 . .
N3 K1 H5WB 140.1 1_455 .
N5 K1 H5WB 120.4 1_455 .
C14 K1 H5WB 48.2 . .
O4 K1 H5WB 125.0 . .
C11 K1 H5WB 149.8 1_455 .
C13 K1 H5WB 134.7 1_455 .
N4 K1 H5WB 71.0 . .
C12 K1 H5WB 59.3 . .
Li2 K1 H5WB 94.9 . .
H4WA K1 H5WB 132.8 . .
O6 K2 O7 92.42(5) . 1_655
O6 K2 N4 143.91(5) . .
O7 K2 N4 84.79(5) 1_655 .
O6 K2 C27 90.09(5) . .
O7 K2 C27 146.96(5) 1_655 .
N4 K2 C27 111.43(6) . .
O6 K2 N11 79.26(5) . .
O7 K2 N11 163.98(5) 1_655 .
N4 K2 N11 110.01(5) . .
C27 K2 N11 21.91(5) . .
O6 K2 C12 123.61(5) . .
O7 K2 C12 92.55(5) 1_655 .
N4 K2 C12 21.55(5) . .
C27 K2 C12 113.18(5) . .
N11 K2 C12 103.47(5) . .
O6 K2 C25 87.24(5) . .
O7 K2 C25 93.27(5) 1_655 .
N4 K2 C25 128.81(5) . .
C27 K2 C25 53.94(5) . .
N11 K2 C25 72.83(5) . .
C12 K2 C25 148.29(5) . .
O6 K2 C26 133.64(5) . .
O7 K2 C26 105.29(5) 1_655 .
N4 K2 C26 81.19(5) . .
C27 K2 C26 52.64(5) . .
N11 K2 C26 72.19(5) . .
C12 K2 C26 98.48(5) . .
C25 K2 C26 49.99(5) . .
O6 K2 N9 78.51(5) . .
O7 K2 N9 75.43(5) 1_655 .
N4 K2 N9 134.43(5) . .
C27 K2 N9 72.83(5) . .
N11 K2 N9 89.42(5) . .
C12 K2 N9 155.80(5) . .
C25 K2 N9 20.36(5) . .
C26 K2 N9 65.70(5) . .
O6 K2 N10 153.08(5) . .
O7 K2 N10 94.49(5) 1_655 .
N4 K2 N10 62.78(5) . .
C27 K2 N10 70.32(5) . .
N11 K2 N10 87.31(5) . .
C12 K2 N10 82.06(5) . .
C25 K2 N10 66.43(5) . .
C26 K2 N10 20.13(5) . .
N9 K2 N10 78.13(5) . .
O6 K2 N5 67.20(5) . .
O7 K2 N5 130.36(5) 1_655 .
N4 K2 N5 87.45(5) . .
C27 K2 N5 80.53(5) . .
N11 K2 N5 58.81(5) . .
C12 K2 N5 67.32(5) . .
C25 K2 N5 128.02(5) . .
C26 K2 N5 121.77(5) . .
N9 K2 N5 136.17(5) . .
N10 K2 N5 124.47(5) . .
O6 K2 C13 81.05(5) . .
O7 K2 C13 119.53(5) 1_655 .
N4 K2 C13 69.48(5) . .
C27 K2 C13 93.40(5) . .
N11 K2 C13 73.02(5) . .
C12 K2 C13 48.67(5) . .
C25 K2 C13 145.38(5) . .
C26 K2 C13 122.25(5) . .
N9 K2 C13 155.20(5) . .
N10 K2 C13 117.29(5) . .
N5 K2 C13 19.11(5) . .
O1 Li1 O2 112.6(2) . .
O1 Li1 N11 106.17(18) . .
O2 Li1 N11 117.6(2) . .
O1 Li1 N5 115.80(19) . .
O2 Li1 N5 101.17(17) . .
N11 Li1 N5 103.46(18) . .
O1 Li1 K2 102.82(14) . .
O2 Li1 K2 144.51(16) . .
N11 Li1 K2 50.08(10) . .
N5 Li1 K2 59.79(11) . .
O1 Li1 K1 74.31(12) . 1_655
O2 Li1 K1 125.07(15) . 1_655
N11 Li1 K1 111.11(14) . 1_655
N5 Li1 K1 41.93(9) . 1_655
K2 Li1 K1 62.47(5) . 1_655
O4 Li2 O3 111.35(18) . .
O4 Li2 N4 103.37(17) . .
O3 Li2 N4 124.50(19) . .
O4 Li2 N10 112.17(18) . .
O3 Li2 N10 97.98(16) . .
N4 Li2 N10 107.45(17) . .
O4 Li2 K2 146.84(16) . .
O3 Li2 K2 101.58(13) . .
N4 Li2 K2 51.78(9) . .
N10 Li2 K2 65.34(10) . .
O4 Li2 K1 58.87(10) . .
O3 Li2 K1 170.12(16) . .
N4 Li2 K1 62.50(10) . .
N10 Li2 K1 85.42(12) . .
K2 Li2 K1 88.28(8) . .
Li1 O1 H1WA 128.8 . .
Li1 O1 H1WB 120.7 . .
H1WA O1 H1WB 108.4 . .
Li1 O2 H2WA 137.0 . .
Li1 O2 H2WB 108.4 . .
H2WA O2 H2WB 104.3 . .
Li2 O3 H3WB 117.8 . .
Li2 O3 H3WA 128.9 . .
H3WB O3 H3WA 101.5 . .
Li2 O4 K1 90.53(12) . .
Li2 O4 H4WA 130.8 . .
K1 O4 H4WA 66.2 . .
Li2 O4 H4WB 123.4 . .
K1 O4 H4WB 121.1 . .
H4WA O4 H4WB 105.5 . .
C1 N1 C5 118.47(17) . .
C1 N1 Ru1 125.43(13) . .
C5 N1 Ru1 116.02(13) . .
C10 N2 C6 118.55(17) . .
C10 N2 Ru1 125.86(13) . .
C6 N2 Ru1 115.56(13) . .
C11 N3 K1 97.07(14) . 1_655
C12 N4 Li2 170.5(2) . .
C12 N4 K2 92.69(14) . .
Li2 N4 K2 95.12(12) . .
C12 N4 K1 86.81(14) . .
Li2 N4 K1 85.29(12) . .
K2 N4 K1 111.81(6) . .
C13 N5 Li1 153.2(2) . .
C13 N5 K1 94.25(14) . 1_655
Li1 N5 K1 111.23(12) . 1_655
C13 N5 K2 86.16(15) . .
Li1 N5 K2 89.02(12) . .
K1 N5 K2 82.20(5) 1_655 .
C14 N6 K1 93.12(14) . .
C24 N7 C20 118.51(17) . .
C24 N7 Ru2 125.50(14) . .
C20 N7 Ru2 115.87(13) . .
C15 N8 C19 118.47(17) . .
C15 N8 Ru2 125.82(13) . .
C19 N8 Ru2 115.70(13) . .
C25 N9 K2 77.00(13) . .
C26 N10 Li2 155.20(19) . .
C26 N10 K2 74.61(13) . .
Li2 N10 K2 80.76(11) . .
C27 N11 Li1 168.6(2) . .
C27 N11 K2 77.22(14) . .
Li1 N11 K2 99.49(12) . .
N1 C1 C2 122.40(19) . .
N1 C1 H1 118.8 . .
C2 C1 H1 118.8 . .
C1 C2 C3 119.3(2) . .
C1 C2 H2 120.4 . .
C3 C2 H2 120.4 . .
C2 C3 C4 118.94(19) . .
C2 C3 H3 120.5 . .
C4 C3 H3 120.5 . .
C3 C4 C5 119.22(19) . .
C3 C4 H4 120.4 . .
C5 C4 H4 120.4 . .
N1 C5 C4 121.60(18) . .
N1 C5 C6 115.46(16) . .
C4 C5 C6 122.94(18) . .
N2 C6 C7 121.69(18) . .
N2 C6 C5 115.42(16) . .
C7 C6 C5 122.88(18) . .
C8 C7 C6 119.11(19) . .
C8 C7 H7 120.4 . .
C6 C7 H7 120.4 . .
C7 C8 C9 119.21(19) . .
C7 C8 H8 120.4 . .
C9 C8 H8 120.4 . .
C8 C9 C10 119.0(2) . .
C8 C9 H9 120.5 . .
C10 C9 H9 120.5 . .
N2 C10 C9 122.44(19) . .
N2 C10 H10 118.8 . .
C9 C10 H10 118.8 . .
N3 C11 Ru1 174.77(17) . .
N3 C11 K1 62.63(12) . 1_655
Ru1 C11 K1 112.14(7) . 1_655
N4 C12 Ru1 179.04(18) . .
N4 C12 K2 65.75(12) . .
Ru1 C12 K2 115.15(8) . .
N4 C12 K1 73.66(13) . .
Ru1 C12 K1 105.72(7) . .
K2 C12 K1 102.01(5) . .
N5 C13 Ru1 176.20(19) . .
N5 C13 K1 65.39(13) . 1_655
Ru1 C13 K1 112.90(8) . 1_655
N5 C13 K2 74.72(14) . .
Ru1 C13 K2 101.66(8) . .
K1 C13 K2 76.49(4) 1_655 .
N6 C14 Ru1 177.10(18) . .
N6 C14 K1 65.81(13) . .
Ru1 C14 K1 113.87(8) . .
N8 C15 C16 122.75(19) . .
N8 C15 H15 118.6 . .
C16 C15 H15 118.6 . .
C15 C16 C17 118.9(2) . .
C15 C16 H16 120.6 . .
C17 C16 H16 120.6 . .
C18 C17 C16 118.98(19) . .
C18 C17 H17 120.5 . .
C16 C17 H17 120.5 . .
C17 C18 C19 119.36(18) . .
C17 C18 H18 120.3 . .
C19 C18 H18 120.3 . .
N8 C19 C18 121.56(18) . .
N8 C19 C20 115.42(17) . .
C18 C19 C20 123.00(17) . .
N7 C20 C21 121.57(18) . .
N7 C20 C19 115.36(16) . .
C21 C20 C19 123.08(18) . .
C22 C21 C20 119.32(19) . .
C22 C21 H21 120.3 . .
C20 C21 H21 120.3 . .
C23 C22 C21 118.85(19) . .
C23 C22 H22 120.6 . .
C21 C22 H22 120.6 . .
C22 C23 C24 119.4(2) . .
C22 C23 H23 120.3 . .
C24 C23 H23 120.3 . .
N7 C24 C23 122.2(2) . .
N7 C24 H24 118.9 . .
C23 C24 H24 118.9 . .
N9 C25 Ru2 172.30(18) . .
N9 C25 K2 82.63(13) . .
Ru2 C25 K2 92.64(7) . .
N10 C26 Ru2 178.18(17) . .
N10 C26 K2 85.26(13) . .
Ru2 C26 K2 92.93(7) . .
N11 C27 Ru2 178.06(19) . .
N11 C27 K2 80.87(14) . .
Ru2 C27 K2 99.81(8) . .
N12 C28 Ru2 176.01(18) . .
K2 O7 H7WA 107.8 1_455 .
K2 O7 H7WB 133.6 1_455 .
H7WA O7 H7WB 108.0 . .
K2 O6 K1 103.30(6) . 1_655
K2 O6 H6WA 123.4 . .
K1 O6 H6WA 102.3 1_655 .
K2 O6 H6WB 107.2 . .
K1 O6 H6WB 124.5 1_655 .
H6WA O6 H6WB 98.0 . .
K1 O5 H5WA 130.6 . .
K1 O5 H5WB 101.2 . .
H5WA O5 H5WB 110.7 . .
H8WA O8 H8WB 106.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ru1 C13 1.983(2) .
Ru1 C12 1.983(2) .
Ru1 C14 2.041(2) .
Ru1 C11 2.048(2) .
Ru1 N1 2.1093(16) .
Ru1 N2 2.1217(16) .
Ru2 C26 1.968(2) .
Ru2 C27 1.972(2) .
Ru2 C25 2.036(2) .
Ru2 C28 2.058(2) .
Ru2 N7 2.1136(16) .
Ru2 N8 2.1159(16) .
Ru2 K2 3.8934(6) .
K1 O5 2.7143(19) .
K1 O6 2.7457(18) 1_455
K1 N6 2.928(2) .
K1 N3 2.9468(19) 1_455
K1 N5 3.032(2) 1_455
K1 C14 3.205(2) .
K1 O4 3.2116(18) .
K1 C11 3.2931(19) 1_455
K1 C13 3.325(2) 1_455
K1 N4 3.339(2) .
K1 C12 3.474(2) .
K1 Li2 3.752(3) .
K1 H4WA 2.9574 .
K1 H5WB 3.0503 .
K2 O6 2.6738(17) .
K2 O7 2.8200(18) 1_655
K2 N4 2.8872(18) .
K2 C27 3.038(2) .
K2 N11 3.076(2) .
K2 C12 3.1630(19) .
K2 C25 3.226(2) .
K2 C26 3.260(2) .
K2 N9 3.283(2) .
K2 N10 3.3701(19) .
K2 N5 3.419(2) .
K2 C13 3.536(2) .
Li1 O1 1.903(4) .
Li1 O2 1.916(4) .
Li1 N11 2.031(4) .
Li1 N5 2.049(4) .
Li1 K1 4.229(4) 1_655
Li2 O4 1.910(4) .
Li2 O3 1.950(4) .
Li2 N4 2.006(4) .
Li2 N10 2.068(4) .
O1 H1WA 0.9599 .
O1 H1WB 0.9600 .
O2 H2WA 0.9600 .
O2 H2WB 0.9599 .
O3 H3WB 0.9600 .
O3 H3WA 0.9600 .
O4 H4WA 0.9601 .
O4 H4WB 0.9600 .
N1 C1 1.349(3) .
N1 C5 1.353(2) .
N2 C10 1.343(3) .
N2 C6 1.357(2) .
N3 C11 1.151(3) .
N3 K1 2.9468(19) 1_655
N4 C12 1.163(3) .
N5 C13 1.160(3) .
N5 K1 3.032(2) 1_655
N6 C14 1.154(3) .
N7 C24 1.350(3) .
N7 C20 1.352(2) .
N8 C15 1.343(3) .
N8 C19 1.357(2) .
N9 C25 1.152(3) .
N10 C26 1.164(3) .
N11 C27 1.162(3) .
N12 C28 1.147(3) .
C1 C2 1.380(3) .
C1 H1 0.9500 .
C2 C3 1.381(3) .
C2 H2 0.9500 .
C3 C4 1.385(3) .
C3 H3 0.9500 .
C4 C5 1.393(3) .
C4 H4 0.9500 .
C5 C6 1.474(3) .
C6 C7 1.395(3) .
C7 C8 1.382(3) .
C7 H7 0.9500 .
C8 C9 1.385(3) .
C8 H8 0.9500 .
C9 C10 1.388(3) .
C9 H9 0.9500 .
C10 H10 0.9500 .
C11 K1 3.2931(19) 1_655
C13 K1 3.325(2) 1_655
C15 C16 1.382(3) .
C15 H15 0.9500 .
C16 C17 1.387(3) .
C16 H16 0.9500 .
C17 C18 1.384(3) .
C17 H17 0.9500 .
C18 C19 1.390(3) .
C18 H18 0.9500 .
C19 C20 1.477(3) .
C20 C21 1.393(3) .
C21 C22 1.384(3) .
C21 H21 0.9500 .
C22 C23 1.380(3) .
C22 H22 0.9500 .
C23 C24 1.381(3) .
C23 H23 0.9500 .
C24 H24 0.9500 .
O7 K2 2.8200(18) 1_455
O7 H7WA 0.9600 .
O7 H7WB 0.9601 .
O6 K1 2.7457(18) 1_655
O6 H6WA 0.9600 .
O6 H6WB 0.9601 .
O5 H5WA 0.9600 .
O5 H5WB 0.9599 .
O8 H8WA 0.9599 .
O8 H8WB 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O6 K2 Li1 O1 -19.94(12) . .
O7 K2 Li1 O1 -46.9(2) 1_655 .
N4 K2 Li1 O1 -161.80(12) . .
C27 K2 Li1 O1 95.26(15) . .
N11 K2 Li1 O1 100.49(18) . .
C12 K2 Li1 O1 -147.17(13) . .
C25 K2 Li1 O1 63.09(14) . .
C26 K2 Li1 O1 113.59(13) . .
N9 K2 Li1 O1 45.55(15) . .
N10 K2 Li1 O1 130.33(12) . .
N5 K2 Li1 O1 -112.58(19) . .
C13 K2 Li1 O1 -123.71(16) . .
O6 K2 Li1 O2 157.1(3) . .
O7 K2 Li1 O2 130.2(2) 1_655 .
N4 K2 Li1 O2 15.3(3) . .
C27 K2 Li1 O2 -87.7(3) . .
N11 K2 Li1 O2 -82.4(3) . .
C12 K2 Li1 O2 29.9(3) . .
C25 K2 Li1 O2 -119.8(3) . .
C26 K2 Li1 O2 -69.3(3) . .
N9 K2 Li1 O2 -137.4(3) . .
N10 K2 Li1 O2 -52.6(3) . .
N5 K2 Li1 O2 64.5(3) . .
C13 K2 Li1 O2 53.4(2) . .
O6 K2 Li1 N11 -120.42(13) . .
O7 K2 Li1 N11 -147.37(12) 1_655 .
N4 K2 Li1 N11 97.71(12) . .
C27 K2 Li1 N11 -5.23(10) . .
C12 K2 Li1 N11 112.34(12) . .
C25 K2 Li1 N11 -37.39(12) . .
C26 K2 Li1 N11 13.10(13) . .
N9 K2 Li1 N11 -54.94(13) . .
N10 K2 Li1 N11 29.84(13) . .
N5 K2 Li1 N11 146.94(19) . .
C13 K2 Li1 N11 135.81(15) . .
O6 K2 Li1 N5 92.64(12) . .
O7 K2 Li1 N5 65.69(17) 1_655 .
N4 K2 Li1 N5 -49.23(12) . .
C27 K2 Li1 N5 -152.17(14) . .
N11 K2 Li1 N5 -146.94(19) . .
C12 K2 Li1 N5 -34.59(11) . .
C25 K2 Li1 N5 175.67(11) . .
C26 K2 Li1 N5 -133.84(11) . .
N9 K2 Li1 N5 158.12(10) . .
N10 K2 Li1 N5 -117.10(10) . .
C13 K2 Li1 N5 -11.13(9) . .
O6 K2 Li1 K1 44.50(5) . 1_655
O7 K2 Li1 K1 17.55(14) 1_655 1_655
N4 K2 Li1 K1 -97.36(5) . 1_655
C27 K2 Li1 K1 159.69(8) . 1_655
N11 K2 Li1 K1 164.92(13) . 1_655
C12 K2 Li1 K1 -82.73(5) . 1_655
C25 K2 Li1 K1 127.53(4) . 1_655
C26 K2 Li1 K1 178.02(4) . 1_655
N9 K2 Li1 K1 109.99(5) . 1_655
N10 K2 Li1 K1 -165.24(4) . 1_655
N5 K2 Li1 K1 -48.14(9) . 1_655
C13 K2 Li1 K1 -59.27(6) . 1_655
O6 K2 Li2 O4 -129.8(3) . .
O7 K2 Li2 O4 -148.2(3) 1_655 .
N4 K2 Li2 O4 -48.2(2) . .
C27 K2 Li2 O4 65.5(3) . .
N11 K2 Li2 O4 45.8(3) . .
C12 K2 Li2 O4 -45.7(3) . .
C25 K2 Li2 O4 119.9(3) . .
C26 K2 Li2 O4 92.0(3) . .
N9 K2 Li2 O4 139.9(3) . .
N10 K2 Li2 O4 93.2(3) . .
N5 K2 Li2 O4 -19.1(3) . .
C13 K2 Li2 O4 -30.1(3) . .
O6 K2 Li2 O3 43.4(4) . .
O7 K2 Li2 O3 25.03(12) 1_655 .
N4 K2 Li2 O3 125.06(19) . .
C27 K2 Li2 O3 -121.32(12) . .
N11 K2 Li2 O3 -140.96(11) . .
C12 K2 Li2 O3 127.49(15) . .
C25 K2 Li2 O3 -66.86(13) . .
C26 K2 Li2 O3 -94.78(13) . .
N9 K2 Li2 O3 -46.90(13) . .
N10 K2 Li2 O3 -93.54(16) . .
N5 K2 Li2 O3 154.12(10) . .
C13 K2 Li2 O3 143.13(12) . .
O6 K2 Li2 N4 -81.6(4) . .
O7 K2 Li2 N4 -100.03(11) 1_655 .
C27 K2 Li2 N4 113.62(11) . .
N11 K2 Li2 N4 93.97(12) . .
C12 K2 Li2 N4 2.43(9) . .
C25 K2 Li2 N4 168.08(11) . .
C26 K2 Li2 N4 140.16(14) . .
N9 K2 Li2 N4 -171.96(11) . .
N10 K2 Li2 N4 141.39(18) . .
N5 K2 Li2 N4 29.06(13) . .
C13 K2 Li2 N4 18.07(12) . .
O6 K2 Li2 N10 137.0(3) . .
O7 K2 Li2 N10 118.57(11) 1_655 .
N4 K2 Li2 N10 -141.39(18) . .
C27 K2 Li2 N10 -27.78(11) . .
N11 K2 Li2 N10 -47.42(12) . .
C12 K2 Li2 N10 -138.97(13) . .
C25 K2 Li2 N10 26.68(11) . .
C26 K2 Li2 N10 -1.24(8) . .
N9 K2 Li2 N10 46.64(11) . .
N5 K2 Li2 N10 -112.34(10) . .
C13 K2 Li2 N10 -123.32(10) . .
O6 K2 Li2 K1 -137.3(3) . .
O7 K2 Li2 K1 -155.67(7) 1_655 .
N4 K2 Li2 K1 -55.64(10) . .
C27 K2 Li2 K1 57.97(7) . .
N11 K2 Li2 K1 38.33(8) . .
C12 K2 Li2 K1 -53.21(6) . .
C25 K2 Li2 K1 112.44(6) . .
C26 K2 Li2 K1 84.51(7) . .
N9 K2 Li2 K1 132.39(6) . .
N10 K2 Li2 K1 85.75(11) . .
N5 K2 Li2 K1 -26.59(8) . .
C13 K2 Li2 K1 -37.57(7) . .
O5 K1 Li2 O4 172.19(11) . .
O6 K1 Li2 O4 85.39(11) 1_455 .
N6 K1 Li2 O4 -120.23(11) . .
N3 K1 Li2 O4 -29.64(10) 1_455 .
N5 K1 Li2 O4 48.47(14) 1_455 .
C14 K1 Li2 O4 -121.47(11) . .
C11 K1 Li2 O4 -18.00(11) 1_455 .
C13 K1 Li2 O4 21.89(14) 1_455 .
N4 K1 Li2 O4 -128.24(17) . .
C12 K1 Li2 O4 -125.99(13) . .
O5 K1 Li2 O3 163.4(9) . .
O6 K1 Li2 O3 76.6(9) 1_455 .
N6 K1 Li2 O3 -129.0(9) . .
N3 K1 Li2 O3 -38.4(9) 1_455 .
N5 K1 Li2 O3 39.7(9) 1_455 .
C14 K1 Li2 O3 -130.3(9) . .
O4 K1 Li2 O3 -8.8(8) . .
C11 K1 Li2 O3 -26.8(9) 1_455 .
C13 K1 Li2 O3 13.1(9) 1_455 .
N4 K1 Li2 O3 -137.0(10) . .
C12 K1 Li2 O3 -134.8(9) . .
O5 K1 Li2 N4 -59.57(11) . .
O6 K1 Li2 N4 -146.37(12) 1_455 .
N6 K1 Li2 N4 8.01(14) . .
N3 K1 Li2 N4 98.59(11) 1_455 .
N5 K1 Li2 N4 176.70(8) 1_455 .
C14 K1 Li2 N4 6.77(11) . .
O4 K1 Li2 N4 128.24(17) . .
C11 K1 Li2 N4 110.24(10) 1_455 .
C13 K1 Li2 N4 150.13(9) 1_455 .
C12 K1 Li2 N4 2.24(8) . .
O5 K1 Li2 N10 52.82(11) . .
O6 K1 Li2 N10 -33.98(10) 1_455 .
N6 K1 Li2 N10 120.40(10) . .
N3 K1 Li2 N10 -149.02(12) 1_455 .
N5 K1 Li2 N10 -70.91(14) 1_455 .
C14 K1 Li2 N10 119.15(11) . .
O4 K1 Li2 N10 -119.37(17) . .
C11 K1 Li2 N10 -137.37(11) 1_455 .
C13 K1 Li2 N10 -97.48(12) 1_455 .
N4 K1 Li2 N10 112.39(16) . .
C12 K1 Li2 N10 114.63(13) . .
O5 K1 Li2 K2 -12.58(7) . .
O6 K1 Li2 K2 -99.38(7) 1_455 .
N6 K1 Li2 K2 55.00(9) . .
N3 K1 Li2 K2 145.58(7) 1_455 .
N5 K1 Li2 K2 -136.31(6) 1_455 .
C14 K1 Li2 K2 53.75(7) . .
O4 K1 Li2 K2 175.23(15) . .
C11 K1 Li2 K2 157.23(6) 1_455 .
C13 K1 Li2 K2 -162.88(5) 1_455 .
N4 K1 Li2 K2 46.99(8) . .
C12 K1 Li2 K2 49.23(6) . .
O3 Li2 O4 K1 178.38(15) . .
N4 Li2 O4 K1 -45.73(14) . .
N10 Li2 O4 K1 69.71(16) . .
K2 Li2 O4 K1 -8.7(3) . .
O5 K1 O4 Li2 -9.45(13) . .
O6 K1 O4 Li2 -83.06(12) 1_455 .
N6 K1 O4 Li2 83.08(13) . .
N3 K1 O4 Li2 142.86(13) 1_455 .
N5 K1 O4 Li2 -144.71(12) 1_455 .
C14 K1 O4 Li2 68.08(12) . .
C11 K1 O4 Li2 160.51(12) 1_455 .
C13 K1 O4 Li2 -162.90(11) 1_455 .
N4 K1 O4 Li2 30.36(11) . .
C12 K1 O4 Li2 41.70(11) . .
C13 Ru1 N1 C1 150.7(8) . .
C12 Ru1 N1 C1 0.40(16) . .
C14 Ru1 N1 C1 -89.82(16) . .
C11 Ru1 N1 C1 91.17(16) . .
N2 Ru1 N1 C1 -179.11(16) . .
C13 Ru1 N1 C5 -26.0(9) . .
C12 Ru1 N1 C5 -176.24(14) . .
C14 Ru1 N1 C5 93.54(14) . .
C11 Ru1 N1 C5 -85.47(14) . .
N2 Ru1 N1 C5 4.25(13) . .
C13 Ru1 N2 C10 -5.86(17) . .
C12 Ru1 N2 C10 172.9(5) . .
C14 Ru1 N2 C10 84.97(16) . .
C11 Ru1 N2 C10 -91.19(16) . .
N1 Ru1 N2 C10 176.58(17) . .
C13 Ru1 N2 C6 176.15(13) . .
C12 Ru1 N2 C6 -5.0(6) . .
C14 Ru1 N2 C6 -93.02(14) . .
C11 Ru1 N2 C6 90.83(14) . .
N1 Ru1 N2 C6 -1.40(12) . .
O4 Li2 N4 C12 9.9(13) . .
O3 Li2 N4 C12 138.0(11) . .
N10 Li2 N4 C12 -108.8(12) . .
K2 Li2 N4 C12 -145.3(12) . .
K1 Li2 N4 C12 -33.8(12) . .
O4 Li2 N4 K2 155.24(14) . .
O3 Li2 N4 K2 -76.6(2) . .
N10 Li2 N4 K2 36.47(16) . .
K1 Li2 N4 K2 111.52(6) . .
O4 Li2 N4 K1 43.71(14) . .
O3 Li2 N4 K1 171.8(2) . .
N10 Li2 N4 K1 -75.05(14) . .
K2 Li2 N4 K1 -111.52(6) . .
O6 K2 N4 C12 -23.71(19) . .
O7 K2 N4 C12 -110.65(14) 1_655 .
C27 K2 N4 C12 99.06(14) . .
N11 K2 N4 C12 75.67(14) . .
C25 K2 N4 C12 159.34(13) . .
C26 K2 N4 C12 142.97(14) . .
N9 K2 N4 C12 -174.34(12) . .
N10 K2 N4 C12 151.57(15) . .
N5 K2 N4 C12 20.27(14) . .
C13 K2 N4 C12 13.58(13) . .
O6 K2 N4 Li2 161.68(12) . .
O7 K2 N4 Li2 74.74(12) 1_655 .
C27 K2 N4 Li2 -75.55(13) . .
N11 K2 N4 Li2 -98.94(12) . .
C12 K2 N4 Li2 -174.6(2) . .
C25 K2 N4 Li2 -15.27(14) . .
C26 K2 N4 Li2 -31.64(12) . .
N9 K2 N4 Li2 11.05(15) . .
N10 K2 N4 Li2 -23.04(11) . .
N5 K2 N4 Li2 -154.34(12) . .
C13 K2 N4 Li2 -161.02(13) . .
O6 K2 N4 K1 -111.35(9) . .
O7 K2 N4 K1 161.71(6) 1_655 .
C27 K2 N4 K1 11.42(8) . .
N11 K2 N4 K1 -11.98(7) . .
C12 K2 N4 K1 -87.64(14) . .
C25 K2 N4 K1 71.70(8) . .
C26 K2 N4 K1 55.33(6) . .
N9 K2 N4 K1 98.02(8) . .
N10 K2 N4 K1 63.93(6) . .
N5 K2 N4 K1 -67.37(6) . .
C13 K2 N4 K1 -74.06(6) . .
O5 K1 N4 C12 -66.84(13) . .
O6 K1 N4 C12 -153.77(13) 1_455 .
N6 K1 N4 C12 1.46(13) . .
N3 K1 N4 C12 97.60(13) 1_455 .
N5 K1 N4 C12 164.99(19) 1_455 .
C14 K1 N4 C12 1.79(13) . .
O4 K1 N4 C12 145.86(14) . .
C11 K1 N4 C12 98.84(13) 1_455 .
C13 K1 N4 C12 115.86(15) 1_455 .
Li2 K1 N4 C12 174.73(19) . .
O5 K1 N4 Li2 118.43(12) . .
O6 K1 N4 Li2 31.50(11) 1_455 .
N6 K1 N4 Li2 -173.27(11) . .
N3 K1 N4 Li2 -77.13(11) 1_455 .
N5 K1 N4 Li2 -9.7(2) 1_455 .
C14 K1 N4 Li2 -172.94(12) . .
O4 K1 N4 Li2 -28.87(11) . .
C11 K1 N4 Li2 -75.89(11) 1_455 .
C13 K1 N4 Li2 -58.87(16) 1_455 .
C12 K1 N4 Li2 -174.73(19) . .
O5 K1 N4 K2 24.78(6) . .
O6 K1 N4 K2 -62.15(6) 1_455 .
N6 K1 N4 K2 93.08(6) . .
N3 K1 N4 K2 -170.77(6) 1_455 .
N5 K1 N4 K2 -103.4(2) 1_455 .
C14 K1 N4 K2 93.42(7) . .
O4 K1 N4 K2 -122.51(7) . .
C11 K1 N4 K2 -169.54(6) 1_455 .
C13 K1 N4 K2 -152.52(9) 1_455 .
C12 K1 N4 K2 91.63(14) . .
Li2 K1 N4 K2 -93.64(12) . .
O1 Li1 N5 C13 169.7(4) . .
O2 Li1 N5 C13 -68.2(5) . .
N11 Li1 N5 C13 54.0(5) . .
K2 Li1 N5 C13 79.5(5) . .
K1 Li1 N5 C13 160.7(5) 1_655 .
O1 Li1 N5 K1 9.0(2) . 1_655
O2 Li1 N5 K1 131.04(14) . 1_655
N11 Li1 N5 K1 -106.72(15) . 1_655
K2 Li1 N5 K1 -81.24(8) . 1_655
O1 Li1 N5 K2 90.22(18) . .
O2 Li1 N5 K2 -147.71(15) . .
N11 Li1 N5 K2 -25.48(14) . .
K1 Li1 N5 K2 81.24(8) 1_655 .
O6 K2 N5 C13 134.21(14) . .
O7 K2 N5 C13 61.51(15) 1_655 .
N4 K2 N5 C13 -19.45(14) . .
C27 K2 N5 C13 -131.67(14) . .
N11 K2 N5 C13 -134.75(15) . .
C12 K2 N5 C13 -11.52(13) . .
C25 K2 N5 C13 -159.05(13) . .
C26 K2 N5 C13 -97.45(14) . .
N9 K2 N5 C13 175.63(12) . .
N10 K2 N5 C13 -73.58(14) . .
O6 K2 N5 Li1 -72.19(12) . .
O7 K2 N5 Li1 -144.90(11) 1_655 .
N4 K2 N5 Li1 134.14(12) . .
C27 K2 N5 Li1 21.93(12) . .
N11 K2 N5 Li1 18.84(11) . .
C12 K2 N5 Li1 142.07(12) . .
C25 K2 N5 Li1 -5.46(13) . .
C26 K2 N5 Li1 56.14(13) . .
N9 K2 N5 Li1 -30.78(14) . .
N10 K2 N5 Li1 80.01(12) . .
C13 K2 N5 Li1 153.6(2) . .
O6 K2 N5 K1 39.39(5) . 1_655
O7 K2 N5 K1 -33.32(7) 1_655 1_655
N4 K2 N5 K1 -114.27(5) . 1_655
C27 K2 N5 K1 133.51(5) . 1_655
N11 K2 N5 K1 130.42(6) . 1_655
C12 K2 N5 K1 -106.34(5) . 1_655
C25 K2 N5 K1 106.12(6) . 1_655
C26 K2 N5 K1 167.72(5) . 1_655
N9 K2 N5 K1 80.80(7) . 1_655
N10 K2 N5 K1 -168.41(4) . 1_655
C13 K2 N5 K1 -94.82(14) . 1_655
O5 K1 N6 C14 77.60(14) . .
O6 K1 N6 C14 108.55(17) 1_455 .
N3 K1 N6 C14 -84.79(14) 1_455 .
N5 K1 N6 C14 -175.04(14) 1_455 .
O4 K1 N6 C14 -40.37(16) . .
C11 K1 N6 C14 -105.21(14) 1_455 .
C13 K1 N6 C14 -154.46(14) 1_455 .
N4 K1 N6 C14 0.87(14) . .
C12 K1 N6 C14 1.38(13) . .
Li2 K1 N6 C14 -3.40(17) . .
C26 Ru2 N7 C24 -173.4(8) . .
C27 Ru2 N7 C24 -1.09(17) . .
C25 Ru2 N7 C24 89.65(17) . .
C28 Ru2 N7 C24 -90.37(17) . .
N8 Ru2 N7 C24 178.98(17) . .
K2 Ru2 N7 C24 40.20(18) . .
C26 Ru2 N7 C20 2.5(9) . .
C27 Ru2 N7 C20 174.81(14) . .
C25 Ru2 N7 C20 -94.45(14) . .
C28 Ru2 N7 C20 85.52(14) . .
N8 Ru2 N7 C20 -5.12(13) . .
K2 Ru2 N7 C20 -143.91(11) . .
C26 Ru2 N8 C15 4.29(17) . .
C27 Ru2 N8 C15 -176.8(4) . .
C25 Ru2 N8 C15 -82.10(16) . .
C28 Ru2 N8 C15 92.73(16) . .
N7 Ru2 N8 C15 -176.32(16) . .
K2 Ru2 N8 C15 -45.42(18) . .
C26 Ru2 N8 C19 -177.21(13) . .
C27 Ru2 N8 C19 1.7(5) . .
C25 Ru2 N8 C19 96.41(14) . .
C28 Ru2 N8 C19 -88.77(14) . .
N7 Ru2 N8 C19 2.18(13) . .
K2 Ru2 N8 C19 133.08(11) . .
O6 K2 N9 C25 113.98(15) . .
O7 K2 N9 C25 -150.44(15) 1_655 .
N4 K2 N9 C25 -83.16(16) . .
C27 K2 N9 C25 20.28(14) . .
N11 K2 N9 C25 34.83(15) . .
C12 K2 N9 C25 -88.24(19) . .
C26 K2 N9 C25 -35.84(14) . .
N10 K2 N9 C25 -52.55(14) . .
N5 K2 N9 C25 75.49(16) . .
C13 K2 N9 C25 78.91(18) . .
O4 Li2 N10 C26 -137.2(4) . .
O3 Li2 N10 C26 105.8(4) . .
N4 Li2 N10 C26 -24.2(5) . .
K2 Li2 N10 C26 6.7(4) . .
K1 Li2 N10 C26 -83.5(4) . .
O4 Li2 N10 K2 -143.86(17) . .
O3 Li2 N10 K2 99.13(13) . .
N4 Li2 N10 K2 -30.92(14) . .
K1 Li2 N10 K2 -90.21(5) . .
O6 K2 N10 C26 19.29(19) . .
O7 K2 N10 C26 123.65(13) 1_655 .
N4 K2 N10 C26 -154.56(14) . .
C27 K2 N10 C26 -26.23(13) . .
N11 K2 N10 C26 -40.39(13) . .
C12 K2 N10 C26 -144.39(13) . .
C25 K2 N10 C26 32.04(13) . .
N9 K2 N10 C26 49.58(13) . .
N5 K2 N10 C26 -89.00(13) . .
C13 K2 N10 C26 -109.70(13) . .
O6 K2 N10 Li2 -163.62(13) . .
O7 K2 N10 Li2 -59.26(11) 1_655 .
N4 K2 N10 Li2 22.53(11) . .
C27 K2 N10 Li2 150.86(12) . .
N11 K2 N10 Li2 136.70(11) . .
C12 K2 N10 Li2 32.70(11) . .
C25 K2 N10 Li2 -150.87(12) . .
C26 K2 N10 Li2 177.09(18) . .
N9 K2 N10 Li2 -133.33(11) . .
N5 K2 N10 Li2 88.08(11) . .
C13 K2 N10 Li2 67.39(12) . .
O1 Li1 N11 C27 -21.2(11) . .
O2 Li1 N11 C27 -148.3(10) . .
N5 Li1 N11 C27 101.2(10) . .
K2 Li1 N11 C27 72.2(10) . .
K1 Li1 N11 C27 57.9(11) 1_655 .
O1 Li1 N11 K2 -93.37(16) . .
O2 Li1 N11 K2 139.49(17) . .
N5 Li1 N11 K2 29.00(16) . .
K1 Li1 N11 K2 -14.31(12) 1_655 .
O6 K2 N11 C27 -118.43(15) . .
O7 K2 N11 C27 -58.8(3) 1_655 .
N4 K2 N11 C27 97.83(14) . .
C12 K2 N11 C27 119.30(14) . .
C25 K2 N11 C27 -28.01(14) . .
C26 K2 N11 C27 24.58(14) . .
N9 K2 N11 C27 -40.02(14) . .
N10 K2 N11 C27 38.13(14) . .
N5 K2 N11 C27 171.82(16) . .
C13 K2 N11 C27 157.75(15) . .
O6 K2 N11 Li1 50.46(12) . .
O7 K2 N11 Li1 110.1(2) 1_655 .
N4 K2 N11 Li1 -93.27(12) . .
C27 K2 N11 Li1 168.9(2) . .
C12 K2 N11 Li1 -71.81(13) . .
C25 K2 N11 Li1 140.88(13) . .
C26 K2 N11 Li1 -166.53(13) . .
N9 K2 N11 Li1 128.88(12) . .
N10 K2 N11 Li1 -152.98(12) . .
N5 K2 N11 Li1 -19.28(11) . .
C13 K2 N11 Li1 -33.36(12) . .
C5 N1 C1 C2 1.9(3) . .
Ru1 N1 C1 C2 -174.63(15) . .
N1 C1 C2 C3 0.7(3) . .
C1 C2 C3 C4 -2.1(3) . .
C2 C3 C4 C5 0.8(3) . .
C1 N1 C5 C4 -3.3(3) . .
Ru1 N1 C5 C4 173.63(14) . .
C1 N1 C5 C6 176.82(16) . .
Ru1 N1 C5 C6 -6.3(2) . .
C3 C4 C5 N1 1.9(3) . .
C3 C4 C5 C6 -178.19(18) . .
C10 N2 C6 C7 -0.6(3) . .
Ru1 N2 C6 C7 177.56(14) . .
C10 N2 C6 C5 -179.52(16) . .
Ru1 N2 C6 C5 -1.4(2) . .
N1 C5 C6 N2 5.1(2) . .
C4 C5 C6 N2 -174.85(17) . .
N1 C5 C6 C7 -173.87(17) . .
C4 C5 C6 C7 6.2(3) . .
N2 C6 C7 C8 0.7(3) . .
C5 C6 C7 C8 179.56(18) . .
C6 C7 C8 C9 -0.2(3) . .
C7 C8 C9 C10 -0.3(3) . .
C6 N2 C10 C9 0.0(3) . .
Ru1 N2 C10 C9 -177.91(15) . .
C8 C9 C10 N2 0.4(3) . .
K1 N3 C11 Ru1 -2(2) 1_655 .
C13 Ru1 C11 N3 -6.0(19) . .
C12 Ru1 C11 N3 -95(2) . .
C14 Ru1 C11 N3 5(3) . .
N1 Ru1 C11 N3 169.9(19) . .
N2 Ru1 C11 N3 93(2) . .
C13 Ru1 C11 K1 -8.04(8) . 1_655
C12 Ru1 C11 K1 -97.04(8) . 1_655
C14 Ru1 C11 K1 2.6(11) . 1_655
N1 Ru1 C11 K1 167.81(7) . 1_655
N2 Ru1 C11 K1 90.57(7) . 1_655
Li2 N4 C12 Ru1 -16(12) . .
K2 N4 C12 Ru1 -161(100) . .
K1 N4 C12 Ru1 -50(11) . .
Li2 N4 C12 K2 145.4(12) . .
K1 N4 C12 K2 111.71(6) . .
Li2 N4 C12 K1 33.7(12) . .
K2 N4 C12 K1 -111.71(6) . .
C13 Ru1 C12 N4 138(11) . .
C14 Ru1 C12 N4 48(11) . .
C11 Ru1 C12 N4 -136(11) . .
N1 Ru1 C12 N4 -44(11) . .
N2 Ru1 C12 N4 -40(11) . .
C13 Ru1 C12 K2 -22.62(9) . .
C14 Ru1 C12 K2 -113.50(9) . .
C11 Ru1 C12 K2 62.71(8) . .
N1 Ru1 C12 K2 154.99(7) . .
N2 Ru1 C12 K2 158.6(5) . .
C13 Ru1 C12 K1 89.15(7) . .
C14 Ru1 C12 K1 -1.72(7) . .
C11 Ru1 C12 K1 174.49(7) . .
N1 Ru1 C12 K1 -93.23(7) . .
N2 Ru1 C12 K1 -89.7(5) . .
O6 K2 C12 N4 163.48(13) . .
O7 K2 C12 N4 68.88(14) 1_655 .
C27 K2 C12 N4 -89.86(15) . .
N11 K2 C12 N4 -110.59(14) . .
C25 K2 C12 N4 -31.54(19) . .
C26 K2 C12 N4 -36.99(14) . .
N9 K2 C12 N4 9.9(2) . .
N10 K2 C12 N4 -25.31(14) . .
N5 K2 C12 N4 -157.97(15) . .
C13 K2 C12 N4 -162.97(16) . .
O6 K2 C12 Ru1 -16.86(11) . .
O7 K2 C12 Ru1 -111.46(8) 1_655 .
N4 K2 C12 Ru1 179.7(2) . .
C27 K2 C12 Ru1 89.80(9) . .
N11 K2 C12 Ru1 69.07(9) . .
C25 K2 C12 Ru1 148.12(9) . .
C26 K2 C12 Ru1 142.67(8) . .
N9 K2 C12 Ru1 -170.45(9) . .
N10 K2 C12 Ru1 154.35(9) . .
N5 K2 C12 Ru1 21.69(7) . .
C13 K2 C12 Ru1 16.69(7) . .
O6 K2 C12 K1 -130.80(6) . .
O7 K2 C12 K1 134.59(5) 1_655 .
N4 K2 C12 K1 65.72(13) . .
C27 K2 C12 K1 -24.15(7) . .
N11 K2 C12 K1 -44.88(6) . .
C25 K2 C12 K1 34.17(12) . .
C26 K2 C12 K1 28.72(6) . .
N9 K2 C12 K1 75.61(13) . .
N10 K2 C12 K1 40.41(5) . .
N5 K2 C12 K1 -92.25(6) . .
C13 K2 C12 K1 -97.25(7) . .
O5 K1 C12 N4 108.03(14) . .
O6 K1 C12 N4 28.75(14) 1_455 .
N6 K1 C12 N4 -178.46(14) . .
N3 K1 C12 N4 -81.37(13) 1_455 .
N5 K1 C12 N4 -147.6(4) 1_455 .
C14 K1 C12 N4 -177.82(15) . .
O4 K1 C12 N4 -29.15(13) . .
C11 K1 C12 N4 -87.11(13) 1_455 .
C13 K1 C12 N4 -105.49(16) 1_455 .
Li2 K1 C12 N4 -3.58(13) . .
O5 K1 C12 Ru1 -72.73(8) . .
O6 K1 C12 Ru1 -152.00(7) 1_455 .
N6 K1 C12 Ru1 0.78(7) . .
N3 K1 C12 Ru1 97.87(8) 1_455 .
N5 K1 C12 Ru1 31.6(5) 1_455 .
C14 K1 C12 Ru1 1.43(6) . .
O4 K1 C12 Ru1 150.09(8) . .
C11 K1 C12 Ru1 92.13(8) 1_455 .
C13 K1 C12 Ru1 73.75(15) 1_455 .
N4 K1 C12 Ru1 179.24(18) . .
Li2 K1 C12 Ru1 175.67(11) . .
O5 K1 C12 K2 48.02(6) . .
O6 K1 C12 K2 -31.25(7) 1_455 .
N6 K1 C12 K2 121.53(7) . .
N3 K1 C12 K2 -141.38(6) 1_455 .
N5 K1 C12 K2 152.4(4) 1_455 .
C14 K1 C12 K2 122.17(8) . .
O4 K1 C12 K2 -89.16(6) . .
C11 K1 C12 K2 -147.12(5) 1_455 .
C13 K1 C12 K2 -165.50(10) 1_455 .
N4 K1 C12 K2 -60.01(12) . .
Li2 K1 C12 K2 -63.59(8) . .
Li1 N5 C13 Ru1 -98(3) . .
K1 N5 C13 Ru1 64(3) 1_655 .
K2 N5 C13 Ru1 -18(3) . .
Li1 N5 C13 K1 -162.0(5) . 1_655
K2 N5 C13 K1 -81.87(5) . 1_655
Li1 N5 C13 K2 -80.2(4) . .
K1 N5 C13 K2 81.87(5) 1_655 .
C12 Ru1 C13 N5 36(3) . .
C14 Ru1 C13 N5 126(3) . .
C11 Ru1 C13 N5 -54(3) . .
N1 Ru1 C13 N5 -114(3) . .
N2 Ru1 C13 N5 -144(3) . .
C12 Ru1 C13 K1 98.65(9) . 1_655
C14 Ru1 C13 K1 -171.28(8) . 1_655
C11 Ru1 C13 K1 8.01(8) . 1_655
N1 Ru1 C13 K1 -51.7(9) . 1_655
N2 Ru1 C13 K1 -81.51(8) . 1_655
C12 Ru1 C13 K2 18.54(7) . .
C14 Ru1 C13 K2 108.62(7) . .
C11 Ru1 C13 K2 -72.10(7) . .
N1 Ru1 C13 K2 -131.8(8) . .
N2 Ru1 C13 K2 -161.62(6) . .
O6 K2 C13 N5 -41.98(13) . .
O7 K2 C13 N5 -129.68(13) 1_655 .
N4 K2 C13 N5 159.20(15) . .
C27 K2 C13 N5 47.57(14) . .
N11 K2 C13 N5 39.44(13) . .
C12 K2 C13 N5 165.79(16) . .
C25 K2 C13 N5 29.72(18) . .
C26 K2 C13 N5 94.62(14) . .
N9 K2 C13 N5 -7.2(2) . .
N10 K2 C13 N5 117.15(13) . .
O6 K2 C13 Ru1 136.82(8) . .
O7 K2 C13 Ru1 49.13(9) 1_655 .
N4 K2 C13 Ru1 -22.00(7) . .
C27 K2 C13 Ru1 -133.62(7) . .
N11 K2 C13 Ru1 -141.76(8) . .
C12 K2 C13 Ru1 -15.40(6) . .
C25 K2 C13 Ru1 -151.48(7) . .
C26 K2 C13 Ru1 -86.57(8) . .
N9 K2 C13 Ru1 171.58(8) . .
N10 K2 C13 Ru1 -64.05(8) . .
N5 K2 C13 Ru1 178.81(18) . .
O6 K2 C13 K1 25.78(4) . 1_655
O7 K2 C13 K1 -61.91(6) 1_655 1_655
N4 K2 C13 K1 -133.04(6) . 1_655
C27 K2 C13 K1 115.34(5) . 1_655
N11 K2 C13 K1 107.20(5) . 1_655
C12 K2 C13 K1 -126.44(7) . 1_655
C25 K2 C13 K1 97.48(8) . 1_655
C26 K2 C13 K1 162.39(5) . 1_655
N9 K2 C13 K1 60.54(12) . 1_655
N10 K2 C13 K1 -175.09(4) . 1_655
N5 K2 C13 K1 67.77(13) . 1_655
K1 N6 C14 Ru1 -84(4) . .
C13 Ru1 C14 N6 -4(4) . .
C12 Ru1 C14 N6 85(4) . .
C11 Ru1 C14 N6 -15(4) . .
N1 Ru1 C14 N6 -180(100) . .
N2 Ru1 C14 N6 -103(4) . .
C13 Ru1 C14 K1 -87.08(9) . .
C12 Ru1 C14 K1 1.96(8) . .
C11 Ru1 C14 K1 -97.7(11) . .
N1 Ru1 C14 K1 97.10(8) . .
N2 Ru1 C14 K1 174.32(8) . .
O5 K1 C14 N6 -93.65(15) . .
O6 K1 C14 N6 -115.08(16) 1_455 .
N3 K1 C14 N6 97.08(14) 1_455 .
N5 K1 C14 N6 5.82(16) 1_455 .
O4 K1 C14 N6 148.24(13) . .
C11 K1 C14 N6 78.20(14) 1_455 .
C13 K1 C14 N6 28.97(16) 1_455 .
N4 K1 C14 N6 -179.08(15) . .
C12 K1 C14 N6 -178.30(16) . .
Li2 K1 C14 N6 177.09(14) . .
O5 K1 C14 Ru1 83.19(9) . .
O6 K1 C14 Ru1 61.76(15) 1_455 .
N6 K1 C14 Ru1 176.8(2) . .
N3 K1 C14 Ru1 -86.08(8) 1_455 .
N5 K1 C14 Ru1 -177.33(7) 1_455 .
O4 K1 C14 Ru1 -34.92(9) . .
C11 K1 C14 Ru1 -104.96(8) 1_455 .
C13 K1 C14 Ru1 -154.18(7) 1_455 .
N4 K1 C14 Ru1 -2.23(7) . .
C12 K1 C14 Ru1 -1.46(6) . .
Li2 K1 C14 Ru1 -6.07(10) . .
C19 N8 C15 C16 -0.4(3) . .
Ru2 N8 C15 C16 178.10(15) . .
N8 C15 C16 C17 -0.2(3) . .
C15 C16 C17 C18 0.2(3) . .
C16 C17 C18 C19 0.3(3) . .
C15 N8 C19 C18 0.9(3) . .
Ru2 N8 C19 C18 -177.71(14) . .
C15 N8 C19 C20 179.40(16) . .
Ru2 N8 C19 C20 0.8(2) . .
C17 C18 C19 N8 -0.9(3) . .
C17 C18 C19 C20 -179.27(18) . .
C24 N7 C20 C21 3.3(3) . .
Ru2 N7 C20 C21 -172.85(14) . .
C24 N7 C20 C19 -176.70(16) . .
Ru2 N7 C20 C19 7.1(2) . .
N8 C19 C20 N7 -5.2(2) . .
C18 C19 C20 N7 173.25(17) . .
N8 C19 C20 C21 174.74(17) . .
C18 C19 C20 C21 -6.8(3) . .
N7 C20 C21 C22 -1.8(3) . .
C19 C20 C21 C22 178.26(18) . .
C20 C21 C22 C23 -1.1(3) . .
C21 C22 C23 C24 2.3(3) . .
C20 N7 C24 C23 -2.1(3) . .
Ru2 N7 C24 C23 173.68(16) . .
C22 C23 C24 N7 -0.7(3) . .
K2 N9 C25 Ru2 52.5(14) . .
C26 Ru2 C25 N9 -0.3(14) . .
C27 Ru2 C25 N9 -90.9(14) . .
C28 Ru2 C25 N9 -5(2) . .
N7 Ru2 C25 N9 175.2(14) . .
N8 Ru2 C25 N9 97.9(14) . .
K2 Ru2 C25 N9 -52.0(14) . .
C26 Ru2 C25 K2 51.62(7) . .
C27 Ru2 C25 K2 -38.93(7) . .
C28 Ru2 C25 K2 47.4(9) . .
N7 Ru2 C25 K2 -132.88(6) . .
N8 Ru2 C25 K2 149.87(6) . .
O6 K2 C25 N9 -63.69(15) . .
O7 K2 C25 N9 28.57(15) 1_655 .
N4 K2 C25 N9 114.51(15) . .
C27 K2 C25 N9 -155.82(17) . .
N11 K2 C25 N9 -143.30(15) . .
C12 K2 C25 N9 128.79(15) . .
C26 K2 C25 N9 135.84(17) . .
N10 K2 C25 N9 122.05(15) . .
N5 K2 C25 N9 -121.67(14) . .
C13 K2 C25 N9 -133.57(14) . .
O6 K2 C25 Ru2 122.42(7) . .
O7 K2 C25 Ru2 -145.32(7) 1_655 .
N4 K2 C25 Ru2 -59.38(9) . .
C27 K2 C25 Ru2 30.29(6) . .
N11 K2 C25 Ru2 42.82(7) . .
C12 K2 C25 Ru2 -45.10(13) . .
C26 K2 C25 Ru2 -38.05(6) . .
N9 K2 C25 Ru2 -173.89(19) . .
N10 K2 C25 Ru2 -51.84(6) . .
N5 K2 C25 Ru2 64.44(9) . .
C13 K2 C25 Ru2 52.55(12) . .
Li2 N10 C26 Ru2 1(6) . .
K2 N10 C26 Ru2 8(6) . .
Li2 N10 C26 K2 -6.9(4) . .
C27 Ru2 C26 N10 32(6) . .
C25 Ru2 C26 N10 -59(6) . .
C28 Ru2 C26 N10 121(6) . .
N7 Ru2 C26 N10 -156(5) . .
N8 Ru2 C26 N10 -148(6) . .
K2 Ru2 C26 N10 -8(6) . .
C27 Ru2 C26 K2 39.54(7) . .
C25 Ru2 C26 K2 -50.87(7) . .
C28 Ru2 C26 K2 128.74(7) . .
N7 Ru2 C26 K2 -148.2(8) . .
N8 Ru2 C26 K2 -140.62(5) . .
O6 K2 C26 N10 -168.07(12) . .
O7 K2 C26 N10 -59.35(13) 1_655 .
N4 K2 C26 N10 22.74(13) . .
C27 K2 C26 N10 148.43(15) . .
N11 K2 C26 N10 137.17(14) . .
C12 K2 C26 N10 35.66(13) . .
C25 K2 C26 N10 -140.60(15) . .
N9 K2 C26 N10 -125.17(14) . .
N5 K2 C26 N10 104.18(13) . .
C13 K2 C26 N10 81.60(13) . .
O6 K2 C26 Ru2 12.17(10) . .
O7 K2 C26 Ru2 120.90(6) 1_655 .
N4 K2 C26 Ru2 -157.01(7) . .
C27 K2 C26 Ru2 -31.32(6) . .
N11 K2 C26 Ru2 -42.59(6) . .
C12 K2 C26 Ru2 -144.09(7) . .
C25 K2 C26 Ru2 39.65(6) . .
N9 K2 C26 Ru2 55.07(6) . .
N10 K2 C26 Ru2 -179.75(17) . .
N5 K2 C26 Ru2 -75.58(8) . .
C13 K2 C26 Ru2 -98.15(7) . .
Li1 N11 C27 Ru2 37(7) . .
K2 N11 C27 Ru2 111(6) . .
Li1 N11 C27 K2 -74.3(10) . .
C26 Ru2 C27 N11 -154(6) . .
C25 Ru2 C27 N11 -68(6) . .
C28 Ru2 C27 N11 117(6) . .
N7 Ru2 C27 N11 26(6) . .
N8 Ru2 C27 N11 27(6) . .
K2 Ru2 C27 N11 -111(6) . .
C26 Ru2 C27 K2 -43.83(7) . .
C25 Ru2 C27 K2 42.56(7) . .
C28 Ru2 C27 K2 -132.15(7) . .
N7 Ru2 C27 K2 136.78(6) . .
N8 Ru2 C27 K2 137.2(4) . .
O6 K2 C27 N11 59.77(14) . .
O7 K2 C27 N11 154.34(13) 1_655 .
N4 K2 C27 N11 -90.55(15) . .
C12 K2 C27 N11 -67.31(15) . .
C25 K2 C27 N11 146.28(16) . .
C26 K2 C27 N11 -150.11(16) . .
N9 K2 C27 N11 137.70(15) . .
N10 K2 C27 N11 -139.08(15) . .
N5 K2 C27 N11 -7.09(14) . .
C13 K2 C27 N11 -21.27(14) . .
O6 K2 C27 Ru2 -118.40(8) . .
O7 K2 C27 Ru2 -23.83(14) 1_655 .
N4 K2 C27 Ru2 91.29(8) . .
N11 K2 C27 Ru2 -178.17(19) . .
C12 K2 C27 Ru2 114.53(8) . .
C25 K2 C27 Ru2 -31.88(6) . .
C26 K2 C27 Ru2 31.72(6) . .
N9 K2 C27 Ru2 -40.46(7) . .
N10 K2 C27 Ru2 42.75(7) . .
N5 K2 C27 Ru2 174.75(8) . .
C13 K2 C27 Ru2 160.56(7) . .
C26 Ru2 C28 N12 -25(3) . .
C27 Ru2 C28 N12 65(3) . .
C25 Ru2 C28 N12 -21(3) . .
N7 Ru2 C28 N12 159(3) . .
N8 Ru2 C28 N12 -124(3) . .
K2 Ru2 C28 N12 24(3) . .
O7 K2 O6 K1 87.76(6) 1_655 1_655
N4 K2 O6 K1 3.30(12) . 1_655
C27 K2 O6 K1 -125.19(6) . 1_655
N11 K2 O6 K1 -106.03(6) . 1_655
C12 K2 O6 K1 -6.91(8) . 1_655
C25 K2 O6 K1 -179.07(6) . 1_655
C26 K2 O6 K1 -158.35(5) . 1_655
N9 K2 O6 K1 162.37(6) . 1_655
N10 K2 O6 K1 -167.39(8) . 1_655
N5 K2 O6 K1 -45.50(5) . 1_655
C13 K2 O6 K1 -31.76(5) . 1_655
