#------------------------------------------------------------------------------
#$Date: 2016-03-21 19:19:44 +0200 (Mon, 21 Mar 2016) $
#$Revision: 178845 $
#$URL: svn://www.crystallography.net/cod/cif/4/10/99/4109918.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4109918
loop_
_publ_author_name
'Takashi Kawashima'
'Toshiro Takao'
'Hiroharu Suzuki'
_publ_section_title
;
 Dehydrogenative Coupling of 4-Substituted Pyridines Catalyzed by
 Diruthenium Complexes
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              11006
_journal_page_last               11007
_journal_paper_doi               10.1021/ja074224u
_journal_volume                  129
_journal_year                    2007
_chemical_formula_sum            'C37 H56 N2 O2 Ru2'
_chemical_formula_weight         762.98
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           11
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yb'
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.5110(11)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   10.1058(4)
_cell_length_b                   13.1552(6)
_cell_length_c                   13.5335(5)
_cell_measurement_reflns_used    17165
_cell_measurement_temperature    153(2)
_cell_measurement_theta_max      27.46
_cell_measurement_theta_min      3.02
_cell_volume                     1795.82(13)
_computing_cell_refinement       'PROCESS-AUTO (T.Higashi, 1998)'
_computing_data_collection       'PROCESS-AUTO (T.Higashi, 1998)'
_computing_data_reduction        'PROCESS-AUTO (T.Higashi, 1998)'
_computing_molecular_graphics    'ORTEX (P.McArdle, 1995)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      153(2)
_diffrn_detector_area_resol_mean 100
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID Imaging Plate'
_diffrn_measurement_method       'oscillation photograph'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rigaku Rotating Anode ultraX18'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0295
_diffrn_reflns_av_sigmaI/netI    0.0256
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            17165
_diffrn_reflns_theta_full        27.46
_diffrn_reflns_theta_max         27.46
_diffrn_reflns_theta_min         3.02
_exptl_absorpt_coefficient_mu    0.874
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.6159
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'ABSCOR (T.Higashi, 2001)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.411
_exptl_crystal_description       prism
_exptl_crystal_F_000             792
_exptl_crystal_size_max          0.290
_exptl_crystal_size_mid          0.180
_exptl_crystal_size_min          0.090
_refine_diff_density_max         0.893
_refine_diff_density_min         -0.406
_refine_diff_density_rms         0.096
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.111
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     349
_refine_ls_number_reflns         4264
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.111
_refine_ls_R_factor_all          0.0652
_refine_ls_R_factor_gt           0.0501
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0599P)²+2.4607P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1251
_refine_ls_wR_factor_ref         0.1386
_reflns_number_gt                3304
_reflns_number_total             4283
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja074224usi20070610_095731_1.cif
_cod_data_source_block           3
_cod_database_code               4109918
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru2 Ru 0.29464(7) 0.33505(6) 0.28993(5) 0.02975(18) Uani 0.50 1 d P . 1
O1 O 0.8213(4) 0.3289(4) 0.4083(4) 0.0460(12) Uani 0.50 1 d P . 1
O2 O 0.2730(6) 0.3396(5) 0.6920(4) 0.0591(16) Uani 0.50 1 d P . 1
C1 C 0.4787(7) 0.2756(5) 0.3274(5) 0.029(3) Uani 0.50 1 d P . 1
C2 C 0.5957(7) 0.3252(7) 0.3592(5) 0.0341(14) Uani 0.50 1 d P . 1
H2A H 0.5952 0.3970 0.3665 0.041 Uiso 0.50 1 calc PR . 1
C3 C 0.7127(6) 0.2722(6) 0.3805(5) 0.033(3) Uani 0.50 1 d P . 1
C6 C 0.9433(6) 0.2727(7) 0.4345(7) 0.055(3) Uani 0.50 1 d P . 1
H6A H 1.016(14) 0.2500 0.404(10) 0.20(6) Uiso 1 2 d S A 1
C7 C 0.2744(8) 0.2777(5) 0.4301(6) 0.026(2) Uani 0.50 1 d P . 1
C8 C 0.2789(11) 0.3311(7) 0.5208(9) 0.038(2) Uani 0.50 1 d P . 1
H8A H 0.2894 0.4029 0.5214 0.046 Uiso 0.50 1 calc PR . 1
C9 C 0.2682(16) 0.2796(8) 0.6081(12) 0.045(7) Uani 0.50 1 d P . 1
C12 C 0.2791(12) 0.2852(9) 0.7855(5) 0.080(4) Uani 0.50 1 d P . 1
H12A H 0.352(10) 0.2500 0.801(7) 0.10(4) Uiso 1 2 d S B 1
C23 C 0.3125(4) 0.5075(3) 0.3019(3) 0.0432(19) Uani 0.50 1 d PG . 1
C24 C 0.3582(5) 0.4762(3) 0.2083(3) 0.043(2) Uani 0.50 1 d PG . 1
C25 C 0.2483(6) 0.4318(4) 0.1516(4) 0.0293(15) Uani 0.50 1 d PG . 1
C26 C 0.1347(6) 0.4357(4) 0.2101(4) 0.0293(16) Uani 0.50 1 d PG . 1
C27 C 0.1744(5) 0.4825(4) 0.3031(3) 0.0374(18) Uani 0.50 1 d PG . 1
C28 C 0.3961(6) 0.5585(5) 0.3856(5) 0.055(2) Uani 0.50 1 d PG . 1
H28A H 0.3779 0.5265 0.4487 0.083 Uiso 0.50 1 calc PR . 1
H28B H 0.3738 0.6309 0.3879 0.083 Uiso 0.50 1 calc PR . 1
H28C H 0.4903 0.5508 0.3738 0.083 Uiso 0.50 1 calc PR . 1
C29 C 0.4988(7) 0.4881(5) 0.1749(5) 0.063(3) Uani 0.50 1 d PG . 1
H29A H 0.4976 0.5318 0.1163 0.095 Uiso 0.50 1 calc PR . 1
H29B H 0.5342 0.4211 0.1587 0.095 Uiso 0.50 1 calc PR . 1
H29C H 0.5552 0.5188 0.2284 0.095 Uiso 0.50 1 calc PR . 1
C30 C 0.2516(9) 0.3882(6) 0.0473(6) 0.089(6) Uani 0.50 1 d PG . 1
H30A H 0.3337 0.3495 0.0417 0.134 Uiso 0.50 1 calc PR . 1
H30B H 0.2480 0.4438 -0.0010 0.134 Uiso 0.50 1 calc PR . 1
H30C H 0.1752 0.3432 0.0342 0.134 Uiso 0.50 1 calc PR . 1
C31 C -0.0039(8) 0.3969(7) 0.1790(6) 0.116(8) Uani 0.50 1 d PG . 1
H31A H 0.0013 0.3494 0.1236 0.175 Uiso 0.50 1 calc PR . 1
H31B H -0.0609 0.4544 0.1585 0.175 Uiso 0.50 1 calc PR . 1
H31C H -0.0412 0.3620 0.2350 0.175 Uiso 0.50 1 calc PR . 1
C32 C 0.0854(7) 0.5021(6) 0.3881(5) 0.061(3) Uani 0.50 1 d PG . 1
H32A H 0.1328 0.5445 0.4382 0.091 Uiso 0.50 1 calc PR . 1
H32B H 0.0616 0.4372 0.4178 0.091 Uiso 0.50 1 calc PR . 1
H32C H 0.0047 0.5372 0.3629 0.091 Uiso 0.50 1 calc PR . 1
Ru1 Ru 0.28704(7) 0.11724(6) 0.28683(6) 0.03198(18) Uani 0.50 1 d P C 2
N1 N 0.4811(7) 0.1701(5) 0.3239(5) 0.0355(18) Uani 0.50 1 d P C 2
N2 N 0.2728(7) 0.1737(5) 0.4319(5) 0.0306(19) Uani 0.50 1 d P C 2
C4 C 0.7134(7) 0.1645(7) 0.3748(6) 0.0384(18) Uani 0.50 1 d P C 2
C5 C 0.5930(8) 0.1202(7) 0.3470(6) 0.0357(15) Uani 0.50 1 d P C 2
H5A H 0.5900 0.0480 0.3443 0.043 Uiso 0.50 1 calc PR C 2
C10 C 0.2651(17) 0.1719(11) 0.6100(15) 0.050(4) Uani 0.50 1 d P C 2
C11 C 0.2647(11) 0.1246(8) 0.5182(9) 0.039(2) Uani 0.50 1 d P C 2
H11A H 0.2582 0.0526 0.5164 0.047 Uiso 0.50 1 calc PR C 2
C13 C 0.2865(4) -0.0494(3) 0.2811(3) 0.049(2) Uani 0.50 1 d PG C 2
C14 C 0.3344(5) -0.0137(3) 0.1918(3) 0.052(2) Uani 0.50 1 d PG C 2
C15 C 0.2320(5) 0.0417(4) 0.1411(3) 0.059(3) Uani 0.50 1 d PG C 2
C16 C 0.1207(5) 0.0403(4) 0.1990(4) 0.057(3) Uani 0.50 1 d PG C 2
C17 C 0.1544(5) -0.0160(3) 0.2856(3) 0.047(2) Uani 0.50 1 d PG C 2
C18 C 0.3626(6) -0.1118(5) 0.3579(5) 0.068(3) Uani 0.50 1 d PG C 2
H18A H 0.4578 -0.1026 0.3512 0.102 Uiso 0.50 1 calc PR C 2
H18B H 0.3397 -0.1838 0.3486 0.102 Uiso 0.50 1 calc PR C 2
H18C H 0.3399 -0.0900 0.4240 0.102 Uiso 0.50 1 calc PR C 2
C19 C 0.4704(6) -0.0316(5) 0.1569(5) 0.054(2) Uani 0.50 1 d PG C 2
H19A H 0.5351 -0.0322 0.2139 0.082 Uiso 0.50 1 calc PR C 2
H19B H 0.4927 0.0229 0.1114 0.082 Uiso 0.50 1 calc PR C 2
H19C H 0.4724 -0.0972 0.1226 0.082 Uiso 0.50 1 calc PR C 2
C20 C 0.2399(8) 0.0931(6) 0.0428(5) 0.043(3) Uani 0.50 1 d PG C 2
H20A H 0.1801 0.1518 0.0391 0.065 Uiso 0.50 1 calc PR C 2
H20B H 0.2139 0.0451 -0.0103 0.065 Uiso 0.50 1 calc PR C 2
H20C H 0.3310 0.1160 0.0352 0.065 Uiso 0.50 1 calc PR C 2
C21 C -0.0104(7) 0.0900(5) 0.1732(5) 0.037(2) Uani 0.50 1 d PG C 2
H21A H 0.0035 0.1521 0.1353 0.056 Uiso 0.50 1 calc PR C 2
H21B H -0.0532 0.1071 0.2341 0.056 Uiso 0.50 1 calc PR C 2
H21C H -0.0671 0.0432 0.1333 0.056 Uiso 0.50 1 calc PR C 2
C22 C 0.0654(6) -0.0367(5) 0.3679(5) 0.042(2) Uani 0.50 1 d PG C 2
H22A H 0.0026 0.0195 0.3728 0.064 Uiso 0.50 1 calc PR C 2
H22B H 0.1190 -0.0432 0.4305 0.064 Uiso 0.50 1 calc PR C 2
H22C H 0.0166 -0.1000 0.3544 0.064 Uiso 0.50 1 calc PR C 2
C33 C 0.9265(12) 0.2500 0.8172(9) 0.130(4) Uani 1 2 d S . .
C34 C 0.804(3) 0.2877(17) 0.8680(17) 0.221(16) Uani 0.50 1 d P . .
C35 C 0.7761(9) 0.2500 0.9558(7) 0.088(2) Uani 1 2 d S . .
C36 C 0.658(2) 0.2801(9) 1.0100(11) 0.141(7) Uani 0.50 1 d P . .
C37 C 0.6265(16) 0.2500 1.0960(11) 0.170(6) Uani 1 2 d S . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ru2 C7 76.9(3) . .
C1 Ru2 Ru2 67.6(2) . 4_565
C7 Ru2 Ru2 68.5(2) . 4_565
C1 Ru2 C24 98.8(2) . .
C7 Ru2 C24 142.4(2) . .
Ru2 Ru2 C24 144.78(12) 4_565 .
C1 Ru2 C23 107.1(2) . .
C7 Ru2 C23 108.1(2) . .
Ru2 Ru2 C23 174.07(10) 4_565 .
C24 Ru2 C23 36.73(9) . .
C1 Ru2 C25 123.4(3) . .
C7 Ru2 C25 158.2(3) . .
Ru2 Ru2 C25 123.80(14) 4_565 .
C24 Ru2 C25 36.67(9) . .
C23 Ru2 C25 61.08(14) . .
C1 Ru2 C27 141.0(2) . .
C7 Ru2 C27 98.9(3) . .
Ru2 Ru2 C27 147.44(12) 4_565 .
C24 Ru2 C27 61.00(14) . .
C23 Ru2 C27 36.50(9) . .
C25 Ru2 C27 60.78(14) . .
C1 Ru2 C26 158.9(3) . .
C7 Ru2 C26 122.3(3) . .
Ru2 Ru2 C26 125.04(14) 4_565 .
C24 Ru2 C26 60.93(14) . .
C23 Ru2 C26 60.82(14) . .
C25 Ru2 C26 36.40(9) . .
C27 Ru2 C26 36.30(9) . .
C1 Ru2 C1 15.1(3) . 4_565
C7 Ru2 C1 72.7(3) . 4_565
Ru2 Ru2 C1 52.50(17) 4_565 4_565
C24 Ru2 C1 111.2(2) . 4_565
C23 Ru2 C1 122.2(2) . 4_565
C25 Ru2 C1 129.0(2) . 4_565
C27 Ru2 C1 154.7(2) . 4_565
C26 Ru2 C1 164.2(2) . 4_565
C1 Ru2 C7 72.1(3) . 4_565
C7 Ru2 C7 16.2(3) . 4_565
Ru2 Ru2 C7 52.32(19) 4_565 4_565
C24 Ru2 C7 156.8(2) . 4_565
C23 Ru2 C7 124.2(2) . 4_565
C25 Ru2 C7 163.1(3) . 4_565
C27 Ru2 C7 112.6(2) . 4_565
C26 Ru2 C7 128.8(2) . 4_565
C1 Ru2 C7 64.2(2) 4_565 4_565
C3 O1 C6 116.4(6) . .
C3 O1 C3 16.2(4) . 4_565
C6 O1 C3 100.1(5) . 4_565
C3 O1 C6 100.1(5) . 4_565
C6 O1 C6 16.3(5) . 4_565
C3 O1 C6 83.9(4) 4_565 4_565
C9 O2 C12 115.5(9) . .
C1 C1 C2 117.9(5) 4_565 .
C1 C1 C2 42.9(3) 4_565 4_565
C2 C1 C2 75.0(7) . 4_565
C1 C1 Ru2 112.4(2) 4_565 .
C2 C1 Ru2 129.5(6) . .
C2 C1 Ru2 155.0(5) 4_565 .
C1 C1 Ru2 52.50(18) 4_565 4_565
C2 C1 Ru2 169.5(6) . 4_565
C2 C1 Ru2 95.3(4) 4_565 4_565
Ru2 C1 Ru2 59.9(2) . 4_565
C3 C2 C1 121.6(7) . .
C3 C2 C3 16.7(5) . 4_565
C1 C2 C3 105.0(6) . 4_565
C3 C2 C1 102.5(6) . 4_565
C1 C2 C1 19.2(4) . 4_565
C3 C2 C1 85.8(5) 4_565 4_565
C3 C2 C2 59.9(5) . 4_565
C1 C2 C2 62.1(5) . 4_565
C3 C2 C2 43.1(3) 4_565 4_565
C1 C2 C2 42.9(3) 4_565 4_565
C3 C3 O1 123.2(4) 4_565 .
C3 C3 C2 120.1(5) 4_565 .
O1 C3 C2 116.4(7) . .
C3 C3 O1 40.5(3) 4_565 4_565
O1 C3 O1 82.7(5) . 4_565
C2 C3 O1 160.3(7) . 4_565
C3 C3 C2 43.1(4) 4_565 4_565
O1 C3 C2 165.7(6) . 4_565
C2 C3 C2 77.0(7) . 4_565
O1 C3 C2 83.5(4) 4_565 4_565
C6 C6 O1 120.4(4) 4_565 .
C6 C6 O1 43.4(3) 4_565 4_565
O1 C6 O1 77.0(5) . 4_565
C7 C7 C8 119.8(5) 4_565 .
C7 C7 C8 40.6(4) 4_565 4_565
C8 C7 C8 79.2(9) . 4_565
C7 C7 Ru2 111.5(2) 4_565 .
C8 C7 Ru2 128.1(6) . .
C8 C7 Ru2 151.3(6) 4_565 .
C7 C7 Ru2 52.32(19) 4_565 4_565
C8 C7 Ru2 169.6(7) . 4_565
C8 C7 Ru2 92.6(5) 4_565 4_565
Ru2 C7 Ru2 59.1(2) . 4_565
C9 C8 C7 120.2(8) . .
C9 C8 C9 21.1(7) . 4_565
C7 C8 C9 99.2(7) . 4_565
C9 C8 C7 100.7(7) . 4_565
C7 C8 C7 19.6(4) . 4_565
C9 C8 C7 79.7(6) 4_565 4_565
C9 C9 C8 119.6(6) 4_565 .
C9 C9 O2 124.9(7) 4_565 .
C8 C9 O2 115.1(10) . .
C9 C9 C8 39.3(6) 4_565 4_565
C8 C9 C8 80.3(10) . 4_565
O2 C9 C8 163.3(12) . 4_565
C12 C12 O2 119.6(5) 4_565 .
C27 C23 C24 108.0 . .
C27 C23 C28 126.0 . .
C24 C23 C28 126.0 . .
C27 C23 Ru2 72.51(16) . .
C24 C23 Ru2 71.35(16) . .
C28 C23 Ru2 121.85(16) . .
C25 C24 C23 108.0 . .
C25 C24 C29 126.0 . .
C23 C24 C29 126.0 . .
C25 C24 Ru2 72.25(16) . .
C23 C24 Ru2 71.92(16) . .
C29 C24 Ru2 121.55(16) . .
C24 C25 C26 108.0 . .
C24 C25 C30 126.0 . .
C26 C25 C30 126.0 . .
C24 C25 Ru2 71.08(16) . .
C26 C25 Ru2 72.45(16) . .
C30 C25 Ru2 122.17(16) . .
C27 C26 C25 108.0 . .
C27 C26 C31 126.0 . .
C25 C26 C31 126.0 . .
C27 C26 Ru2 71.67(16) . .
C25 C26 Ru2 71.15(15) . .
C31 C26 Ru2 122.84(15) . .
C23 C27 C26 108.0 . .
C23 C27 C32 126.0 . .
C26 C27 C32 126.0 . .
C23 C27 Ru2 70.99(16) . .
C26 C27 Ru2 72.04(16) . .
C32 C27 Ru2 122.64(15) . .
N1 Ru1 N2 77.2(3) . .
N1 Ru1 C13 109.7(2) . .
N2 Ru1 C13 112.6(2) . .
N1 Ru1 C17 144.9(2) . .
N2 Ru1 C17 102.1(2) . .
C13 Ru1 C17 37.39(8) . .
N1 Ru1 C14 99.4(2) . .
N2 Ru1 C14 147.2(2) . .
C13 Ru1 C14 37.26(8) . .
C17 Ru1 C14 62.07(13) . .
N1 Ru1 C16 158.5(2) . .
N2 Ru1 C16 124.1(2) . .
C13 Ru1 C16 61.94(12) . .
C17 Ru1 C16 36.98(8) . .
C14 Ru1 C16 61.55(12) . .
N1 Ru1 C15 122.0(2) . .
N2 Ru1 C15 160.7(2) . .
C13 Ru1 C15 61.81(12) . .
C17 Ru1 C15 61.62(12) . .
C14 Ru1 C15 36.79(8) . .
C16 Ru1 C15 36.63(8) . .
C5 N1 Ru1 131.1(6) . .
C11 N2 Ru1 130.6(6) . .
N1 C5 C4 125.4(9) . .
N2 C11 C10 124.4(10) . .
C17 C13 C14 108.0 . .
C17 C13 C18 126.0 . .
C14 C13 C18 126.0 . .
C17 C13 Ru1 71.79(14) . .
C14 C13 Ru1 72.37(15) . .
C18 C13 Ru1 121.55(15) . .
C13 C14 C15 108.0 . .
C13 C14 C19 126.0 . .
C15 C14 C19 126.0 . .
C13 C14 Ru1 70.36(15) . .
C15 C14 Ru1 72.70(16) . .
C19 C14 Ru1 122.61(13) . .
C16 C15 C14 108.0 . .
C16 C15 C20 126.0 . .
C14 C15 C20 126.0 . .
C16 C15 Ru1 71.37(14) . .
C14 C15 Ru1 70.51(15) . .
C20 C15 Ru1 123.75(14) . .
C15 C16 C17 108.0 . .
C15 C16 C21 126.0 . .
C17 C16 C21 126.0 . .
C15 C16 Ru1 72.00(14) . .
C17 C16 Ru1 70.21(15) . .
C21 C16 Ru1 123.42(15) . .
C13 C17 C16 108.0 . .
C13 C17 C22 126.0 . .
C16 C17 C22 126.0 . .
C13 C17 Ru1 70.82(15) . .
C16 C17 Ru1 72.81(16) . .
C22 C17 Ru1 122.06(14) . .
C34 C33 C34 37.7(18) . 4_565
C34 C34 C35 68.2(10) 4_565 .
C34 C34 C33 71.2(9) 4_565 .
C35 C34 C33 119.9(16) . .
C34 C35 C34 44(2) 4_565 .
C34 C35 C36 139.1(17) 4_565 .
C34 C35 C36 123.9(12) . .
C34 C35 C36 123.9(13) 4_565 4_565
C34 C35 C36 139.1(17) . 4_565
C36 C35 C36 30.8(10) . 4_565
C36 C36 C37 72.1(6) 4_565 .
C36 C36 C35 74.6(5) 4_565 .
C37 C36 C35 127.7(15) . .
C36 C37 C36 35.8(11) 4_565 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ru2 C1 2.052(7) .
Ru2 C7 2.063(8) .
Ru2 Ru2 2.2377(15) 4_565
Ru2 C24 2.274(4) .
Ru2 C23 2.281(4) .
Ru2 C25 2.289(5) .
Ru2 C27 2.301(5) .
Ru2 C26 2.306(5) .
Ru2 C1 2.392(7) 4_565
Ru2 C7 2.426(8) 4_565
O1 C3 1.360(8) .
O1 C6 1.462(9) .
O1 C3 1.751(9) 4_565
O1 C6 1.838(9) 4_565
O2 C9 1.381(14) .
O2 C12 1.452(11) .
C1 C1 0.675(14) 4_565
C1 C2 1.395(11) .
C1 C2 1.812(12) 4_565
C1 Ru2 2.392(7) 4_565
C2 C3 1.388(10) .
C2 C3 1.756(11) 4_565
C2 C1 1.812(12) 4_565
C2 C2 1.979(18) 4_565
C3 C3 0.585(15) 4_565
C3 O1 1.751(9) 4_565
C3 C2 1.756(11) 4_565
C6 C6 0.597(18) 4_565
C6 O1 1.838(9) 4_565
C7 C7 0.728(14) 4_565
C7 C8 1.413(14) .
C7 C8 1.884(14) 4_565
C7 Ru2 2.426(8) 4_565
C8 C9 1.37(2) .
C8 C9 1.883(18) 4_565
C8 C7 1.884(14) 4_565
C9 C9 0.78(2) 4_565
C9 C8 1.883(18) 4_565
C12 C12 0.93(2) 4_565
C23 C27 1.435(3) .
C23 C24 1.435(3) .
C23 C28 1.526(3) .
C24 C25 1.435(3) .
C24 C29 1.526(3) .
C25 C26 1.435(3) .
C25 C30 1.526(3) .
C26 C27 1.435(3) .
C26 C31 1.526(3) .
C27 C32 1.526(3) .
Ru1 N1 2.112(7) .
Ru1 N2 2.113(7) .
Ru1 C13 2.193(4) .
Ru1 C17 2.206(4) .
Ru1 C14 2.220(4) .
Ru1 C16 2.240(5) .
Ru1 C15 2.248(5) .
N1 C5 1.329(10) .
N2 C11 1.342(13) .
C4 C5 1.380(11) .
C10 C11 1.39(2) .
C13 C17 1.410(2) .
C13 C14 1.410(2) .
C13 C18 1.499(2) .
C14 C15 1.410(2) .
C14 C19 1.499(2) .
C15 C16 1.410(2) .
C15 C20 1.499(2) .
C16 C17 1.410(2) .
C16 C21 1.499(2) .
C17 C22 1.499(2) .
C33 C34 1.53(2) .
C33 C34 1.53(2) 4_565
C34 C34 0.99(5) 4_565
C34 C35 1.33(2) .
C35 C34 1.33(2) 4_565
C35 C36 1.492(16) .
C35 C36 1.492(16) 4_565
C36 C36 0.79(2) 4_565
C36 C37 1.289(16) .
C37 C36 1.289(16) 4_565
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C7 Ru2 C1 C1 71.9(2) . 4_565
Ru2 Ru2 C1 C1 0.0 4_565 4_565
C24 Ru2 C1 C1 -146.14(13) . 4_565
C23 Ru2 C1 C1 177.09(11) . 4_565
C25 Ru2 C1 C1 -116.7(2) . 4_565
C27 Ru2 C1 C1 159.9(3) . 4_565
C26 Ru2 C1 C1 -131.1(6) . 4_565
C7 Ru2 C1 C1 55.8(2) 4_565 4_565
C7 Ru2 C1 C2 -102.4(7) . .
Ru2 Ru2 C1 C2 -174.3(8) 4_565 .
C24 Ru2 C1 C2 39.5(7) . .
C23 Ru2 C1 C2 2.8(8) . .
C25 Ru2 C1 C2 69.0(8) . .
C27 Ru2 C1 C2 -14.4(9) . .
C26 Ru2 C1 C2 54.6(11) . .
C1 Ru2 C1 C2 -174.3(8) 4_565 .
C7 Ru2 C1 C2 -118.5(8) 4_565 .
C7 Ru2 C1 C2 63.9(12) . 4_565
Ru2 Ru2 C1 C2 -8.0(11) 4_565 4_565
C24 Ru2 C1 C2 -154.1(11) . 4_565
C23 Ru2 C1 C2 169.1(11) . 4_565
C25 Ru2 C1 C2 -124.7(11) . 4_565
C27 Ru2 C1 C2 151.9(10) . 4_565
C26 Ru2 C1 C2 -139.1(10) . 4_565
C1 Ru2 C1 C2 -8.0(11) 4_565 4_565
C7 Ru2 C1 C2 47.8(11) 4_565 4_565
C7 Ru2 C1 Ru2 71.9(2) . 4_565
C24 Ru2 C1 Ru2 -146.14(13) . 4_565
C23 Ru2 C1 Ru2 177.09(11) . 4_565
C25 Ru2 C1 Ru2 -116.7(2) . 4_565
C27 Ru2 C1 Ru2 159.9(3) . 4_565
C26 Ru2 C1 Ru2 -131.1(6) . 4_565
C1 Ru2 C1 Ru2 0.0 4_565 4_565
C7 Ru2 C1 Ru2 55.8(2) 4_565 4_565
C1 C1 C2 C3 6.6(9) 4_565 .
C2 C1 C2 C3 6.6(9) 4_565 .
Ru2 C1 C2 C3 -179.3(5) . .
Ru2 C1 C2 C3 29(4) 4_565 .
C1 C1 C2 C3 4.6(6) 4_565 4_565
C2 C1 C2 C3 4.6(6) 4_565 4_565
Ru2 C1 C2 C3 178.7(5) . 4_565
Ru2 C1 C2 C3 27(3) 4_565 4_565
C2 C1 C2 C1 0.000(2) 4_565 4_565
Ru2 C1 C2 C1 174.0(8) . 4_565
Ru2 C1 C2 C1 22(3) 4_565 4_565
C1 C1 C2 C2 0.000(1) 4_565 4_565
Ru2 C1 C2 C2 174.0(8) . 4_565
Ru2 C1 C2 C2 22(3) 4_565 4_565
C6 O1 C3 C3 2.9(7) . 4_565
C6 O1 C3 C3 2.1(5) 4_565 4_565
C6 O1 C3 C2 177.6(7) . .
C3 O1 C3 C2 174.8(8) 4_565 .
C6 O1 C3 C2 176.9(6) 4_565 .
C6 O1 C3 O1 2.9(7) . 4_565
C3 O1 C3 O1 0.000(2) 4_565 4_565
C6 O1 C3 O1 2.1(5) 4_565 4_565
C6 O1 C3 C2 18(3) . 4_565
C3 O1 C3 C2 15(2) 4_565 4_565
C6 O1 C3 C2 17(3) 4_565 4_565
C1 C2 C3 C3 -6.8(9) . 4_565
C1 C2 C3 C3 -4.6(6) 4_565 4_565
C2 C2 C3 C3 0.000(1) 4_565 4_565
C1 C2 C3 O1 178.2(7) . .
C3 C2 C3 O1 -175.0(7) 4_565 .
C1 C2 C3 O1 -179.5(5) 4_565 .
C2 C2 C3 O1 -175.0(7) 4_565 .
C1 C2 C3 O1 -17(2) . 4_565
C3 C2 C3 O1 -10.4(15) 4_565 4_565
C1 C2 C3 O1 -15(2) 4_565 4_565
C2 C2 C3 O1 -10.4(15) 4_565 4_565
C1 C2 C3 C2 -6.8(9) . 4_565
C3 C2 C3 C2 0.000(2) 4_565 4_565
C1 C2 C3 C2 -4.6(6) 4_565 4_565
C3 O1 C6 C6 -2.8(7) . 4_565
C3 O1 C6 C6 -2.0(5) 4_565 4_565
C3 O1 C6 O1 -2.8(7) . 4_565
C3 O1 C6 O1 -2.0(5) 4_565 4_565
C6 O1 C6 O1 0.000(2) 4_565 4_565
C1 Ru2 C7 C7 -70.8(2) . 4_565
Ru2 Ru2 C7 C7 0.000(3) 4_565 4_565
C24 Ru2 C7 C7 -158.2(3) . 4_565
C23 Ru2 C7 C7 -174.83(11) . 4_565
C25 Ru2 C7 C7 128.8(6) . 4_565
C27 Ru2 C7 C7 148.76(14) . 4_565
C26 Ru2 C7 C7 118.8(2) . 4_565
C1 Ru2 C7 C7 -55.8(2) 4_565 4_565
C1 Ru2 C7 C8 100.1(9) . .
Ru2 Ru2 C7 C8 170.9(9) 4_565 .
C24 Ru2 C7 C8 12.7(11) . .
C23 Ru2 C7 C8 -3.9(9) . .
C25 Ru2 C7 C8 -60.3(12) . .
C27 Ru2 C7 C8 -40.3(9) . .
C26 Ru2 C7 C8 -70.3(9) . .
C1 Ru2 C7 C8 115.1(9) 4_565 .
C7 Ru2 C7 C8 170.9(9) 4_565 .
C1 Ru2 C7 C8 -59.6(12) . 4_565
Ru2 Ru2 C7 C8 11.2(11) 4_565 4_565
C24 Ru2 C7 C8 -147.0(10) . 4_565
C23 Ru2 C7 C8 -163.6(11) . 4_565
C25 Ru2 C7 C8 140.1(11) . 4_565
C27 Ru2 C7 C8 160.0(12) . 4_565
C26 Ru2 C7 C8 130.0(11) . 4_565
C1 Ru2 C7 C8 -44.6(12) 4_565 4_565
C7 Ru2 C7 C8 11.2(11) 4_565 4_565
C1 Ru2 C7 Ru2 -70.8(2) . 4_565
C24 Ru2 C7 Ru2 -158.2(3) . 4_565
C23 Ru2 C7 Ru2 -174.83(11) . 4_565
C25 Ru2 C7 Ru2 128.8(6) . 4_565
C27 Ru2 C7 Ru2 148.76(14) . 4_565
C26 Ru2 C7 Ru2 118.8(2) . 4_565
C1 Ru2 C7 Ru2 -55.8(2) 4_565 4_565
C7 Ru2 C7 Ru2 0.000(4) 4_565 4_565
C7 C7 C8 C9 -7.4(14) 4_565 .
C8 C7 C8 C9 -7.4(14) 4_565 .
Ru2 C7 C8 C9 -177.6(10) . .
Ru2 C7 C8 C9 -46(4) 4_565 .
C7 C7 C8 C9 -4.7(9) 4_565 4_565
C8 C7 C8 C9 -4.7(9) 4_565 4_565
Ru2 C7 C8 C9 -174.9(7) . 4_565
Ru2 C7 C8 C9 -44(4) 4_565 4_565
C8 C7 C8 C7 0.000(7) 4_565 4_565
Ru2 C7 C8 C7 -170.2(10) . 4_565
Ru2 C7 C8 C7 -39(3) 4_565 4_565
C7 C8 C9 C9 7.4(14) . 4_565
C7 C8 C9 C9 4.9(9) 4_565 4_565
C7 C8 C9 O2 -179.5(10) . .
C9 C8 C9 O2 173.1(16) 4_565 .
C7 C8 C9 O2 177.9(10) 4_565 .
C7 C8 C9 C8 7.4(14) . 4_565
C9 C8 C9 C8 0.000(11) 4_565 4_565
C7 C8 C9 C8 4.9(9) 4_565 4_565
C12 O2 C9 C9 0.4(11) . 4_565
C12 O2 C9 C8 -172.3(11) . .
C12 O2 C9 C8 -17(5) . 4_565
C9 O2 C12 C12 -0.3(11) . 4_565
C1 Ru2 C23 C27 -161.8(3) . .
C7 Ru2 C23 C27 -80.4(3) . .
Ru2 Ru2 C23 C27 -134.7(10) 4_565 .
C24 Ru2 C23 C27 116.63(9) . .
C25 Ru2 C23 C27 78.99(10) . .
C26 Ru2 C23 C27 37.13(6) . .
C1 Ru2 C23 C27 -160.9(3) 4_565 .
C7 Ru2 C23 C27 -82.1(3) 4_565 .
C1 Ru2 C23 C24 81.6(3) . .
C7 Ru2 C23 C24 163.0(3) . .
Ru2 Ru2 C23 C24 108.7(10) 4_565 .
C25 Ru2 C23 C24 -37.64(6) . .
C27 Ru2 C23 C24 -116.63(9) . .
C26 Ru2 C23 C24 -79.50(9) . .
C1 Ru2 C23 C24 82.5(3) 4_565 .
C7 Ru2 C23 C24 161.3(3) 4_565 .
C1 Ru2 C23 C28 -39.8(3) . .
C7 Ru2 C23 C28 41.6(3) . .
Ru2 Ru2 C23 C28 -12.7(11) 4_565 .
C24 Ru2 C23 C28 -121.38(8) . .
C25 Ru2 C23 C28 -159.0 . .
C27 Ru2 C23 C28 121.99(8) . .
C26 Ru2 C23 C28 159.1 . .
C1 Ru2 C23 C28 -38.9(3) 4_565 .
C7 Ru2 C23 C28 39.9(3) 4_565 .
C27 C23 C24 C25 0.0 . .
C28 C23 C24 C25 180.0 . .
Ru2 C23 C24 C25 63.69(17) . .
C27 C23 C24 C29 180.0 . .
C28 C23 C24 C29 0.0 . .
Ru2 C23 C24 C29 -116.30(17) . .
C27 C23 C24 Ru2 -63.70(17) . .
C28 C23 C24 Ru2 116.31(17) . .
C1 Ru2 C24 C25 136.6(2) . .
C7 Ru2 C24 C25 -143.6(5) . .
Ru2 Ru2 C24 C25 73.29(16) 4_565 .
C23 Ru2 C24 C25 -116.47(9) . .
C27 Ru2 C24 C25 -79.03(10) . .
C26 Ru2 C24 C25 -37.29(6) . .
C1 Ru2 C24 C25 127.6(2) 4_565 .
C7 Ru2 C24 C25 -158.8(6) 4_565 .
C1 Ru2 C24 C23 -107.0(2) . .
C7 Ru2 C24 C23 -27.1(5) . .
Ru2 Ru2 C24 C23 -170.23(18) 4_565 .
C25 Ru2 C24 C23 116.47(9) . .
C27 Ru2 C24 C23 37.44(6) . .
C26 Ru2 C24 C23 79.18(10) . .
C1 Ru2 C24 C23 -115.9(2) 4_565 .
C7 Ru2 C24 C23 -42.4(5) 4_565 .
C1 Ru2 C24 C29 14.7(2) . .
C7 Ru2 C24 C29 94.6(5) . .
Ru2 Ru2 C24 C29 -48.56(19) 4_565 .
C23 Ru2 C24 C29 121.67(8) . .
C25 Ru2 C24 C29 -121.85(8) . .
C27 Ru2 C24 C29 159.1 . .
C26 Ru2 C24 C29 -159.1 . .
C1 Ru2 C24 C29 5.7(2) 4_565 .
C7 Ru2 C24 C29 79.3(6) 4_565 .
C23 C24 C25 C26 0.0 . .
C29 C24 C25 C26 180.0 . .
Ru2 C24 C25 C26 63.48(17) . .
C23 C24 C25 C30 180.0 . .
C29 C24 C25 C30 0.0 . .
Ru2 C24 C25 C30 -116.52(17) . .
C23 C24 C25 Ru2 -63.47(17) . .
C29 C24 C25 Ru2 116.52(17) . .
C1 Ru2 C25 C24 -54.5(3) . .
C7 Ru2 C25 C24 102.4(7) . .
Ru2 Ru2 C25 C24 -138.34(12) 4_565 .
C23 Ru2 C25 C24 37.71(6) . .
C27 Ru2 C25 C24 79.70(10) . .
C26 Ru2 C25 C24 116.81(9) . .
C1 Ru2 C25 C24 -72.0(3) 4_565 .
C7 Ru2 C25 C24 150.7(8) 4_565 .
C1 Ru2 C25 C26 -171.3(3) . .
C7 Ru2 C25 C26 -14.4(6) . .
Ru2 Ru2 C25 C26 104.85(12) 4_565 .
C24 Ru2 C25 C26 -116.81(9) . .
C23 Ru2 C25 C26 -79.10(10) . .
C27 Ru2 C25 C26 -37.11(6) . .
C1 Ru2 C25 C26 171.2(3) 4_565 .
C7 Ru2 C25 C26 33.9(7) 4_565 .
C1 Ru2 C25 C30 66.7(3) . .
C7 Ru2 C25 C30 -136.4(6) . .
Ru2 Ru2 C25 C30 -17.10(14) 4_565 .
C24 Ru2 C25 C30 121.23(9) . .
C23 Ru2 C25 C30 158.9 . .
C27 Ru2 C25 C30 -159.1 . .
C26 Ru2 C25 C30 -121.96(8) . .
C1 Ru2 C25 C30 49.3(3) 4_565 .
C7 Ru2 C25 C30 -88.0(8) 4_565 .
C24 C25 C26 C27 0.0 . .
C30 C25 C26 C27 180.0 . .
Ru2 C25 C26 C27 62.59(17) . .
C24 C25 C26 C31 180.0 . .
C30 C25 C26 C31 0.0 . .
Ru2 C25 C26 C31 -117.40(17) . .
C24 C25 C26 Ru2 -62.59(17) . .
C30 C25 C26 Ru2 117.41(17) . .
C1 Ru2 C26 C27 -96.7(7) . .
C7 Ru2 C26 C27 56.5(3) . .
Ru2 Ru2 C26 C27 141.64(12) 4_565 .
C24 Ru2 C26 C27 -79.62(10) . .
C23 Ru2 C26 C27 -37.34(6) . .
C25 Ru2 C26 C27 -117.19(9) . .
C1 Ru2 C26 C27 -143.0(8) 4_565 .
C7 Ru2 C26 C27 74.8(3) 4_565 .
C1 Ru2 C26 C25 20.5(7) . .
C7 Ru2 C26 C25 173.7(3) . .
Ru2 Ru2 C26 C25 -101.17(11) 4_565 .
C24 Ru2 C26 C25 37.57(6) . .
C23 Ru2 C26 C25 79.86(10) . .
C27 Ru2 C26 C25 117.19(9) . .
C1 Ru2 C26 C25 -25.8(8) 4_565 .
C7 Ru2 C26 C25 -168.0(3) 4_565 .
C1 Ru2 C26 C31 141.8(7) . .
C7 Ru2 C26 C31 -65.0(3) . .
Ru2 Ru2 C26 C31 20.09(13) 4_565 .
C24 Ru2 C26 C31 158.8 . .
C23 Ru2 C26 C31 -158.9 . .
C25 Ru2 C26 C31 121.25(8) . .
C27 Ru2 C26 C31 -121.55(9) . .
C1 Ru2 C26 C31 95.4(8) 4_565 .
C7 Ru2 C26 C31 -46.7(3) 4_565 .
C24 C23 C27 C26 0.0 . .
C28 C23 C27 C26 180.0 . .
Ru2 C23 C27 C26 -62.93(16) . .
C24 C23 C27 C32 180.0 . .
C28 C23 C27 C32 0.0 . .
Ru2 C23 C27 C32 117.05(16) . .
C24 C23 C27 Ru2 62.94(16) . .
C28 C23 C27 Ru2 -117.06(16) . .
C25 C26 C27 C23 0.0 . .
C31 C26 C27 C23 180.0 . .
Ru2 C26 C27 C23 62.26(16) . .
C25 C26 C27 C32 -180.0 . .
C31 C26 C27 C32 0.0 . .
Ru2 C26 C27 C32 -117.73(16) . .
C25 C26 C27 Ru2 -62.26(16) . .
C31 C26 C27 Ru2 117.73(16) . .
C1 Ru2 C27 C23 28.3(4) . .
C7 Ru2 C27 C23 108.4(2) . .
Ru2 Ru2 C27 C23 172.16(19) 4_565 .
C24 Ru2 C27 C23 -37.68(6) . .
C25 Ru2 C27 C23 -79.88(10) . .
C26 Ru2 C27 C23 -117.09(8) . .
C1 Ru2 C27 C23 40.4(5) 4_565 .
C7 Ru2 C27 C23 117.5(3) 4_565 .
C1 Ru2 C27 C26 145.4(4) . .
C7 Ru2 C27 C26 -134.5(3) . .
Ru2 Ru2 C27 C26 -70.74(17) 4_565 .
C24 Ru2 C27 C26 79.41(10) . .
C23 Ru2 C27 C26 117.09(9) . .
C25 Ru2 C27 C26 37.21(6) . .
C1 Ru2 C27 C26 157.5(5) 4_565 .
C7 Ru2 C27 C26 -125.4(3) 4_565 .
C1 Ru2 C27 C32 -92.9(4) . .
C7 Ru2 C27 C32 -12.7(3) . .
Ru2 Ru2 C27 C32 51.0(2) 4_565 .
C24 Ru2 C27 C32 -158.8 . .
C23 Ru2 C27 C32 -121.16(9) . .
C25 Ru2 C27 C32 159.0 . .
C26 Ru2 C27 C32 121.74(9) . .
C1 Ru2 C27 C32 -80.8(5) 4_565 .
C7 Ru2 C27 C32 -3.7(3) 4_565 .
N2 Ru1 N1 C5 106.3(8) . .
C13 Ru1 N1 C5 -3.4(8) . .
C17 Ru1 N1 C5 13.3(9) . .
C14 Ru1 N1 C5 -40.5(7) . .
C16 Ru1 N1 C5 -66.5(10) . .
C15 Ru1 N1 C5 -71.8(8) . .
N1 Ru1 N2 C11 -105.8(9) . .
C13 Ru1 N2 C11 0.5(9) . .
C17 Ru1 N2 C11 38.3(9) . .
C14 Ru1 N2 C11 -18.3(11) . .
C16 Ru1 N2 C11 71.0(9) . .
C15 Ru1 N2 C11 69.4(12) . .
Ru1 N1 C5 C4 -176.6(6) . .
Ru1 N2 C11 C10 175.3(10) . .
N1 Ru1 C13 C17 164.2(2) . .
N2 Ru1 C13 C17 80.3(2) . .
C14 Ru1 C13 C17 -116.48(8) . .
C16 Ru1 C13 C17 -37.49(5) . .
C15 Ru1 C13 C17 -79.24(9) . .
N1 Ru1 C13 C14 -79.3(2) . .
N2 Ru1 C13 C14 -163.2(2) . .
C17 Ru1 C13 C14 116.48(8) . .
C16 Ru1 C13 C14 78.99(9) . .
C15 Ru1 C13 C14 37.24(5) . .
N1 Ru1 C13 C18 42.6(2) . .
N2 Ru1 C13 C18 -41.3(2) . .
C17 Ru1 C13 C18 -121.61(8) . .
C14 Ru1 C13 C18 121.91(8) . .
C16 Ru1 C13 C18 -159.1 . .
C15 Ru1 C13 C18 159.2 . .
C17 C13 C14 C15 0.0 . .
C18 C13 C14 C15 180.0 . .
Ru1 C13 C14 C15 -63.39(15) . .
C17 C13 C14 C19 180.0 . .
C18 C13 C14 C19 0.0 . .
Ru1 C13 C14 C19 116.62(15) . .
C17 C13 C14 Ru1 63.39(15) . .
C18 C13 C14 Ru1 -116.61(15) . .
N1 Ru1 C14 C13 110.4(2) . .
N2 Ru1 C14 C13 29.5(4) . .
C17 Ru1 C14 C13 -37.96(6) . .
C16 Ru1 C14 C13 -80.13(9) . .
C15 Ru1 C14 C13 -117.05(8) . .
N1 Ru1 C14 C15 -132.6(2) . .
N2 Ru1 C14 C15 146.5(4) . .
C13 Ru1 C14 C15 117.05(8) . .
C17 Ru1 C14 C15 79.09(9) . .
C16 Ru1 C14 C15 36.91(6) . .
N1 Ru1 C14 C19 -10.5(2) . .
N2 Ru1 C14 C19 -91.4(4) . .
C13 Ru1 C14 C19 -120.83(8) . .
C17 Ru1 C14 C19 -158.8 . .
C16 Ru1 C14 C19 159.0 . .
C15 Ru1 C14 C19 122.12(8) . .
C13 C14 C15 C16 0.0 . .
C19 C14 C15 C16 180.0 . .
Ru1 C14 C15 C16 -61.88(15) . .
C13 C14 C15 C20 180.0 . .
C19 C14 C15 C20 0.0 . .
Ru1 C14 C15 C20 118.12(15) . .
C13 C14 C15 Ru1 61.88(15) . .
C19 C14 C15 Ru1 -118.13(15) . .
N1 Ru1 C15 C16 176.7(3) . .
N2 Ru1 C15 C16 2.3(7) . .
C13 Ru1 C15 C16 80.01(9) . .
C17 Ru1 C15 C16 37.32(6) . .
C14 Ru1 C15 C16 117.73(8) . .
N1 Ru1 C15 C14 59.0(3) . .
N2 Ru1 C15 C14 -115.5(7) . .
C13 Ru1 C15 C14 -37.72(6) . .
C17 Ru1 C15 C14 -80.41(10) . .
C16 Ru1 C15 C14 -117.73(8) . .
N1 Ru1 C15 C20 -61.9(3) . .
N2 Ru1 C15 C20 123.6(7) . .
C13 Ru1 C15 C20 -158.6 . .
C17 Ru1 C15 C20 158.7 . .
C14 Ru1 C15 C20 -120.89(9) . .
C16 Ru1 C15 C20 121.38(8) . .
C14 C15 C16 C17 0.0 . .
C20 C15 C16 C17 180.0 . .
Ru1 C15 C16 C17 -61.33(16) . .
C14 C15 C16 C21 180.0 . .
C20 C15 C16 C21 0.0 . .
Ru1 C15 C16 C21 118.68(16) . .
C14 C15 C16 Ru1 61.33(16) . .
C20 C15 C16 Ru1 -118.67(16) . .
N1 Ru1 C16 C15 -7.6(6) . .
N2 Ru1 C16 C15 -179.1(3) . .
C13 Ru1 C16 C15 -79.61(9) . .
C17 Ru1 C16 C15 -117.52(9) . .
C14 Ru1 C16 C15 -37.08(6) . .
N1 Ru1 C16 C17 109.9(6) . .
N2 Ru1 C16 C17 -61.6(3) . .
C13 Ru1 C16 C17 37.91(6) . .
C14 Ru1 C16 C17 80.44(10) . .
C15 Ru1 C16 C17 117.52(9) . .
N1 Ru1 C16 C21 -129.4(6) . .
N2 Ru1 C16 C21 59.2(3) . .
C13 Ru1 C16 C21 158.6 . .
C17 Ru1 C16 C21 120.73(9) . .
C14 Ru1 C16 C21 -158.8 . .
C15 Ru1 C16 C21 -121.74(8) . .
C14 C13 C17 C16 0.0 . .
C18 C13 C17 C16 180.0 . .
Ru1 C13 C17 C16 63.77(16) . .
C14 C13 C17 C22 180.0 . .
C18 C13 C17 C22 0.0 . .
Ru1 C13 C17 C22 -116.24(16) . .
C14 C13 C17 Ru1 -63.76(16) . .
C18 C13 C17 Ru1 116.23(16) . .
C15 C16 C17 C13 0.0 . .
C21 C16 C17 C13 180.0 . .
Ru1 C16 C17 C13 -62.48(15) . .
C15 C16 C17 C22 180.0 . .
C21 C16 C17 C22 0.0 . .
Ru1 C16 C17 C22 117.52(15) . .
C15 C16 C17 Ru1 62.48(15) . .
C21 C16 C17 Ru1 -117.53(15) . .
N1 Ru1 C17 C13 -26.5(4) . .
N2 Ru1 C17 C13 -111.4(2) . .
C14 Ru1 C17 C13 37.84(6) . .
C16 Ru1 C17 C13 116.75(8) . .
C15 Ru1 C17 C13 79.78(9) . .
N1 Ru1 C17 C16 -143.2(4) . .
N2 Ru1 C17 C16 131.8(2) . .
C13 Ru1 C17 C16 -116.75(8) . .
C14 Ru1 C17 C16 -78.91(9) . .
C15 Ru1 C17 C16 -36.97(6) . .
N1 Ru1 C17 C22 94.6(4) . .
N2 Ru1 C17 C22 9.7(2) . .
C13 Ru1 C17 C22 121.09(8) . .
C14 Ru1 C17 C22 158.9 . .
C16 Ru1 C17 C22 -122.16(8) . .
C15 Ru1 C17 C22 -159.1 . .
C34 C33 C34 C35 49(3) 4_565 .
C33 C34 C35 C34 -51(3) . 4_565
C34 C34 C35 C36 -127.9(17) 4_565 .
C33 C34 C35 C36 -178.7(15) . .
C34 C34 C35 C36 -91.4(17) 4_565 4_565
C33 C34 C35 C36 -142.2(15) . 4_565
C34 C35 C36 C36 74.3(17) 4_565 4_565
C34 C35 C36 C36 130.6(18) . 4_565
C34 C35 C36 C37 126(2) 4_565 .
C34 C35 C36 C37 -178(2) . .
C36 C35 C36 C37 51.9(18) 4_565 .
C35 C36 C37 C36 -52.9(19) . 4_565
