#------------------------------------------------------------------------------
#$Date: 2016-03-22 11:16:28 +0200 (Tue, 22 Mar 2016) $
#$Revision: 178892 $
#$URL: svn://www.crystallography.net/cod/cif/4/11/21/4112151.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4112151
loop_
_publ_author_name
'Adam J. Clarke'
'Michael J. Ingleson'
'Gabriele Kociok-Köhn'
'Mary F. Mahon'
'Nathan J. Patmore'
'Jonathan P. Rourke'
'Giuseppe D. Ruggiero'
'Andrew S. Weller'
_publ_section_title
;
 Silver-Phosphine Complexes of the Highly Methylated Carborane Monoanion
 [closo-1-H-CB11Me11]-
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              1503
_journal_page_last               1517
_journal_paper_doi               10.1021/ja038173m
_journal_volume                  126
_journal_year                    2004
_chemical_formula_sum            'C30 H49 Ag B11 P'
_chemical_formula_weight         667.44
_chemical_name_common            'compound 2'
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                111.6370(10)
_cell_angle_beta                 95.0050(10)
_cell_angle_gamma                100.3360(10)
_cell_formula_units_Z            2
_cell_length_a                   9.18400(10)
_cell_length_b                   13.6170(2)
_cell_length_c                   15.1520(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      18
_cell_measurement_theta_min      12
_cell_volume                     1708.23(5)
_computing_data_reduction
'Denzo and Scalepack (otwinowski & Minor, 1997)'
_computing_molecular_graphics    'ORTEX (P.McArdle, 1995)'
_computing_publication_material  'SHELXL-97/2 (Sheldrick,1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       KappaCCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0417
_diffrn_reflns_av_sigmaI/netI    0.0475
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            38763
_diffrn_reflns_theta_full        30.06
_diffrn_reflns_theta_max         30.06
_diffrn_reflns_theta_min         3.57
_exptl_absorpt_coefficient_mu    0.658
_exptl_absorpt_correction_T_max  0.92
_exptl_absorpt_correction_T_min  0.95
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            Red
_exptl_crystal_density_diffrn    1.298
_exptl_crystal_description       Plate
_exptl_crystal_F_000             692
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.503
_refine_diff_density_min         -0.859
_refine_diff_density_rms         0.126
_refine_ls_extinction_coef       0.0074(11)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.017
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     433
_refine_ls_number_reflns         9965
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.017
_refine_ls_R_factor_all          0.0627
_refine_ls_R_factor_gt           0.0378
_refine_ls_shift/su_max          0.061
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
; calc
 [1.00000+0.00000exp(0.00(sinθ/λ)²)]/
   [σ²(Fo²)+0.0000+0.4216*P+(0.0516P)²+0.0000sinθ/λ]
 where P = 0.00000Fo² + 1.00000Fc²
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0941
_refine_ls_wR_factor_ref         0.1043
_reflns_number_gt                7255
_reflns_number_total             9965
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja038173msi20030828_055709.cif
_cod_data_source_block           c:\backup\helix\h02asw2\h02asw2
_cod_database_code               4112151
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.836147(18) 0.183668(12) 0.162217(14) 0.04894(8) Uani 1 1 d .
P1 P 0.97307(5) 0.36606(4) 0.20695(3) 0.02621(10) Uani 1 1 d .
C1 C 0.41379(18) -0.01430(15) 0.36470(12) 0.0267(3) Uani 1 1 d .
H1 H 0.4608 -0.0168 0.4344 0.032 Uiso 1 1 calc R
C2 C 0.6513(2) -0.10793(17) 0.27888(17) 0.0387(5) Uani 1 1 d .
H2A H 0.7386 -0.0589 0.2730 0.058 Uiso 1 1 calc R
H2B H 0.6375 -0.1801 0.2277 0.058 Uiso 1 1 calc R
H2C H 0.6675 -0.1129 0.3418 0.058 Uiso 1 1 calc R
C3 C 0.6666(2) 0.16032(17) 0.39266(15) 0.0391(5) Uani 1 1 d .
H3A H 0.6836 0.1526 0.4543 0.059 Uiso 1 1 calc R
H3B H 0.6607 0.2352 0.4045 0.059 Uiso 1 1 calc R
H3C H 0.7497 0.1428 0.3579 0.059 Uiso 1 1 calc R
C4 C 0.3358(3) 0.18714(19) 0.47237(16) 0.0490(6) Uani 1 1 d .
H4A H 0.2387 0.1716 0.4925 0.073 Uiso 1 1 calc R
H4B H 0.3506 0.2572 0.4661 0.073 Uiso 1 1 calc R
H4C H 0.4164 0.1899 0.5207 0.073 Uiso 1 1 calc R
C5 C 0.1170(2) -0.0646(2) 0.40724(15) 0.0449(5) Uani 1 1 d .
H5A H 0.1162 -0.1377 0.4046 0.067 Uiso 1 1 calc R
H5B H 0.0148 -0.0604 0.3870 0.067 Uiso 1 1 calc R
H5C H 0.1547 -0.0115 0.4733 0.067 Uiso 1 1 calc R
C6 C 0.3116(2) -0.24700(17) 0.28758(18) 0.0426(5) Uani 1 1 d .
H6A H 0.3766 -0.2350 0.3472 0.064 Uiso 1 1 calc R
H6B H 0.3422 -0.2998 0.2327 0.064 Uiso 1 1 calc R
H6C H 0.2072 -0.2749 0.2912 0.064 Uiso 1 1 calc R
C7 C 0.5973(2) 0.0433(2) 0.14023(17) 0.0371(4) Uani 1 1 d .
C8 C 0.4008(2) 0.23184(17) 0.26215(19) 0.0461(5) Uani 1 1 d .
H8A H 0.3233 0.2682 0.2907 0.069 Uiso 1 1 calc R
H8B H 0.3956 0.2251 0.1952 0.069 Uiso 1 1 calc R
H8C H 0.5000 0.2746 0.2988 0.069 Uiso 1 1 calc R
C9 C 0.0466(2) 0.0874(2) 0.26819(19) 0.0417(5) Uani 1 1 d .
C10 C 0.0318(2) -0.18729(17) 0.15504(14) 0.0374(4) Uani 1 1 d .
H10A H 0.0510 -0.2601 0.1263 0.056 Uiso 1 1 calc R
H10B H -0.0129 -0.1681 0.1043 0.056 Uiso 1 1 calc R
H10C H -0.0375 -0.1863 0.2009 0.056 Uiso 1 1 calc R
C11 C 0.3682(2) -0.21441(17) 0.07031(15) 0.0412(5) Uani 1 1 d .
H11A H 0.4120 -0.2674 0.0865 0.062 Uiso 1 1 calc R
H11B H 0.4309 -0.1866 0.0317 0.062 Uiso 1 1 calc R
H11C H 0.2669 -0.2494 0.0333 0.062 Uiso 1 1 calc R
C12 C 0.2066(3) -0.0062(2) 0.06486(16) 0.0417(5) Uani 1 1 d .
C13 C 1.0991(2) 0.41801(14) 0.32154(13) 0.0296(4) Uani 1 1 d .
C14 C 1.0549(3) 0.38368(18) 0.39304(15) 0.0418(5) Uani 1 1 d .
H14 H 0.9627 0.3326 0.3810 0.050 Uiso 1 1 calc R
C15 C 1.1476(4) 0.4252(2) 0.48233(17) 0.0594(7) Uani 1 1 d .
H15 H 1.1175 0.4023 0.5314 0.071 Uiso 1 1 calc R
C16 C 1.2801(3) 0.4976(2) 0.50054(18) 0.0625(8) Uani 1 1 d .
H16 H 1.3422 0.5245 0.5618 0.075 Uiso 1 1 calc R
C17 C 1.3249(3) 0.5324(2) 0.42995(19) 0.0567(7) Uani 1 1 d .
H17 H 1.4175 0.5834 0.4428 0.068 Uiso 1 1 calc R
C18 C 1.2345(2) 0.49258(16) 0.34054(15) 0.0391(4) Uani 1 1 d .
H18 H 1.2652 0.5164 0.2921 0.047 Uiso 1 1 calc R
C19 C 0.85011(19) 0.46014(14) 0.22407(12) 0.0267(3) Uani 1 1 d .
C20 C 0.9045(2) 0.57176(15) 0.27400(14) 0.0331(4) Uani 1 1 d .
H20 H 1.0091 0.6005 0.2965 0.040 Uiso 1 1 calc R
C21 C 0.8070(2) 0.64096(16) 0.29103(15) 0.0385(4) Uani 1 1 d .
H21 H 0.8448 0.7170 0.3242 0.046 Uiso 1 1 calc R
C22 C 0.6546(2) 0.59882(19) 0.25952(16) 0.0442(5) Uani 1 1 d .
H22 H 0.5874 0.6460 0.2720 0.053 Uiso 1 1 calc R
C23 C 0.5996(2) 0.48891(19) 0.21023(17) 0.0446(5) Uani 1 1 d .
H23 H 0.4947 0.4605 0.1888 0.054 Uiso 1 1 calc R
C24 C 0.6967(2) 0.41942(17) 0.19172(14) 0.0349(4) Uani 1 1 d .
H24 H 0.6582 0.3437 0.1568 0.042 Uiso 1 1 calc R
C25 C 1.09272(19) 0.38264(15) 0.12184(13) 0.0295(4) Uani 1 1 d .
C26 C 1.1087(2) 0.46821(17) 0.09195(15) 0.0393(4) Uani 1 1 d .
H26 H 1.0518 0.5217 0.1143 0.047 Uiso 1 1 calc R
C27 C 1.2084(3) 0.4758(2) 0.02902(16) 0.0493(6) Uani 1 1 d .
H27 H 1.2195 0.5346 0.0087 0.059 Uiso 1 1 calc R
C28 C 1.2907(2) 0.3983(2) -0.00376(16) 0.0519(6) Uani 1 1 d .
H28 H 1.3585 0.4038 -0.0465 0.062 Uiso 1 1 calc R
C29 C 1.2752(2) 0.3122(2) 0.02540(16) 0.0478(6) Uani 1 1 d .
H29 H 1.3325 0.2591 0.0030 0.057 Uiso 1 1 calc R
C30 C 1.1758(2) 0.30401(18) 0.08722(14) 0.0375(4) Uani 1 1 d .
H30 H 1.1639 0.2444 0.1063 0.045 Uiso 1 1 calc R
B2 B 0.5054(2) -0.06224(16) 0.26940(15) 0.0250(4) Uani 1 1 d .
B3 B 0.5133(2) 0.07964(16) 0.32985(14) 0.0262(4) Uani 1 1 d .
B4 B 0.3386(2) 0.09404(17) 0.37124(15) 0.0290(4) Uani 1 1 d .
B5 B 0.2229(2) -0.03893(18) 0.33727(14) 0.0279(4) Uani 1 1 d .
B6 B 0.3257(2) -0.13534(16) 0.27396(15) 0.0268(4) Uani 1 1 d .
B7 B 0.4753(2) 0.01686(16) 0.20286(14) 0.0245(4) Uani 1 1 d .
B8 B 0.3737(2) 0.11420(16) 0.26494(15) 0.0276(4) Uani 1 1 d .
B9 B 0.1938(2) 0.03999(16) 0.26920(14) 0.0256(4) Uani 1 1 d .
B10 B 0.1853(2) -0.10200(16) 0.20966(14) 0.0242(4) Uani 1 1 d .
B11 B 0.3599(2) -0.11613(16) 0.16729(14) 0.0259(4) Uani 1 1 d .
B12 B 0.2780(2) -0.00747(16) 0.16430(14) 0.0252(4) Uani 1 1 d .
H7A H 0.596(3) 0.111(3) 0.139(2) 0.065(8) Uiso 1 1 d .
H9A H -0.028(4) 0.045(3) 0.214(3) 0.102(12) Uiso 1 1 d .
H12A H 0.204(3) -0.069(3) 0.010(2) 0.071(9) Uiso 1 1 d .
H7B H 0.691(3) 0.039(2) 0.1655(18) 0.054(7) Uiso 1 1 d .
H9B H 0.051(4) 0.153(3) 0.258(3) 0.108(13) Uiso 1 1 d .
H12B H 0.258(3) 0.043(2) 0.0485(18) 0.051(7) Uiso 1 1 d .
H7C H 0.587(4) -0.013(3) 0.081(3) 0.086(11) Uiso 1 1 d .
H9C H -0.017(4) 0.086(3) 0.313(3) 0.100(12) Uiso 1 1 d .
H12C H 0.116(4) 0.005(3) 0.063(3) 0.101(12) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
H7A Ag1 H7B 41.6(10) . .
H7A Ag1 P1 132.4(8) . .
H7B Ag1 P1 162.0(7) . .
H7A Ag1 H12A 80.1(10) . 2_655
H7B Ag1 H12A 81.7(10) . 2_655
P1 Ag1 H12A 115.5(7) . 2_655
H7A Ag1 H9B 128.5(12) . 1_655
H7B Ag1 H9B 89.1(12) . 1_655
P1 Ag1 H9B 88.7(10) . 1_655
H12A Ag1 H9B 112.6(11) 2_655 1_655
H7A Ag1 C7 21.1(8) . .
H7B Ag1 C7 21.0(7) . .
P1 Ag1 C7 152.21(6) . .
H12A Ag1 C7 77.2(7) 2_655 .
H9B Ag1 C7 109.9(9) 1_655 .
H7A Ag1 H9A 104.1(12) . 1_655
H7B Ag1 H9A 62.5(11) . 1_655
P1 Ag1 H9A 118.5(9) . 1_655
H12A Ag1 H9A 93.2(11) 2_655 1_655
H9B Ag1 H9A 30.3(11) 1_655 1_655
C7 Ag1 H9A 83.4(8) . 1_655
C25 P1 C13 104.72(8) . .
C25 P1 C19 108.67(8) . .
C13 P1 C19 104.29(8) . .
C25 P1 Ag1 113.52(6) . .
C13 P1 Ag1 112.89(6) . .
C19 P1 Ag1 112.08(6) . .
B3 C1 B5 115.84(14) . .
B3 C1 B6 115.73(14) . .
B5 C1 B6 63.25(11) . .
B3 C1 B4 63.12(11) . .
B5 C1 B4 63.06(12) . .
B6 C1 B4 115.67(13) . .
B3 C1 B2 63.20(11) . .
B5 C1 B2 115.93(13) . .
B6 C1 B2 63.06(11) . .
B4 C1 B2 115.78(14) . .
H7C C7 H7B 97(2) . .
H7C C7 H7A 116(3) . .
H7B C7 H7A 114(2) . .
H7C C7 B7 112(2) . .
H7B C7 B7 109.2(16) . .
H7A C7 B7 108.8(17) . .
H7C C7 Ag1 108(2) . .
H7B C7 Ag1 58.0(16) . .
H7A C7 Ag1 57.3(17) . .
B7 C7 Ag1 138.88(15) . .
H9A C9 H9C 95(3) . .
H9A C9 H9B 94(3) . .
H9C C9 H9B 109(3) . .
H9A C9 B9 114(2) . .
H9C C9 B9 120(2) . .
H9B C9 B9 120(2) . .
H12C C12 H12B 104(3) . .
H12C C12 H12A 106(3) . .
H12B C12 H12A 100(2) . .
H12C C12 B12 115(2) . .
H12B C12 B12 114.3(17) . .
H12A C12 B12 115.3(19) . .
C18 C13 C14 119.50(19) . .
C18 C13 P1 122.21(15) . .
C14 C13 P1 118.26(16) . .
C15 C14 C13 119.2(2) . .
C16 C15 C14 121.2(2) . .
C15 C16 C17 120.1(2) . .
C18 C17 C16 119.9(3) . .
C17 C18 C13 120.2(2) . .
C24 C19 C20 118.98(17) . .
C24 C19 P1 119.20(14) . .
C20 C19 P1 121.70(13) . .
C21 C20 C19 120.50(18) . .
C22 C21 C20 119.69(19) . .
C23 C22 C21 120.32(19) . .
C22 C23 C24 120.28(19) . .
C23 C24 C19 120.21(19) . .
C26 C25 C30 119.21(18) . .
C26 C25 P1 124.46(15) . .
C30 C25 P1 116.30(15) . .
C25 C26 C27 120.0(2) . .
C28 C27 C26 120.2(2) . .
C27 C28 C29 120.3(2) . .
C30 C29 C28 119.7(2) . .
C29 C30 C25 120.6(2) . .
C2 B2 C1 121.84(16) . .
C2 B2 B7 125.78(15) . .
C1 B2 B7 103.31(13) . .
C2 B2 B11 125.54(16) . .
C1 B2 B11 103.78(12) . .
B7 B2 B11 60.47(11) . .
C2 B2 B6 120.50(15) . .
C1 B2 B6 58.35(10) . .
B7 B2 B6 107.66(13) . .
B11 B2 B6 59.66(11) . .
C2 B2 B3 120.09(15) . .
C1 B2 B3 58.24(11) . .
B7 B2 B3 59.54(11) . .
B11 B2 B3 108.13(13) . .
B6 B2 B3 107.72(13) . .
C3 B3 C1 122.00(16) . .
C3 B3 B7 125.48(16) . .
C1 B3 B7 103.48(13) . .
C3 B3 B8 125.08(16) . .
C1 B3 B8 104.15(13) . .
B7 B3 B8 60.48(11) . .
C3 B3 B4 120.50(15) . .
C1 B3 B4 58.60(11) . .
B7 B3 B4 107.74(13) . .
B8 B3 B4 59.72(11) . .
C3 B3 B2 120.00(15) . .
C1 B3 B2 58.56(11) . .
B7 B3 B2 59.45(11) . .
B8 B3 B2 108.35(13) . .
B4 B3 B2 108.21(13) . .
C4 B4 C1 121.25(17) . .
C4 B4 B9 125.79(16) . .
C1 B4 B9 103.83(13) . .
C4 B4 B8 125.60(18) . .
C1 B4 B8 104.03(13) . .
B9 B4 B8 60.72(11) . .
C4 B4 B5 119.84(17) . .
C1 B4 B5 58.35(11) . .
B9 B4 B5 59.86(11) . .
B8 B4 B5 108.55(14) . .
C4 B4 B3 120.05(16) . .
C1 B4 B3 58.29(11) . .
B9 B4 B3 108.21(13) . .
B8 B4 B3 59.87(11) . .
B5 B4 B3 107.92(13) . .
C5 B5 C1 121.50(16) . .
C5 B5 B10 125.36(16) . .
C1 B5 B10 103.89(13) . .
C5 B5 B9 125.82(16) . .
C1 B5 B9 103.89(13) . .
B10 B5 B9 60.53(11) . .
C5 B5 B4 120.30(16) . .
C1 B5 B4 58.59(11) . .
B10 B5 B4 108.23(14) . .
B9 B5 B4 59.70(11) . .
C5 B5 B6 120.07(17) . .
C1 B5 B6 58.38(10) . .
B10 B5 B6 59.54(11) . .
B9 B5 B6 107.84(13) . .
B4 B5 B6 107.97(13) . .
C6 B6 C1 121.51(16) . .
C6 B6 B10 125.40(15) . .
C1 B6 B10 104.04(13) . .
C6 B6 B11 125.22(16) . .
C1 B6 B11 104.16(13) . .
B10 B6 B11 60.81(11) . .
C6 B6 B2 119.75(15) . .
C1 B6 B2 58.59(10) . .
B10 B6 B2 108.61(13) . .
B11 B6 B2 59.91(11) . .
C6 B6 B5 120.24(16) . .
C1 B6 B5 58.37(10) . .
B10 B6 B5 59.75(11) . .
B11 B6 B5 108.39(14) . .
B2 B6 B5 108.18(14) . .
C7 B7 B2 120.16(15) . .
C7 B7 B3 120.47(15) . .
B2 B7 B3 61.01(11) . .
C7 B7 B11 121.39(16) . .
B2 B7 B11 60.19(11) . .
B3 B7 B11 109.07(14) . .
C7 B7 B8 121.47(16) . .
B2 B7 B8 109.33(14) . .
B3 B7 B8 60.15(11) . .
B11 B7 B8 108.96(13) . .
C7 B7 B12 122.53(15) . .
B2 B7 B12 108.54(13) . .
B3 B7 B12 108.46(13) . .
B11 B7 B12 60.13(11) . .
B8 B7 B12 60.34(11) . .
C8 B8 B4 121.38(17) . .
C8 B8 B3 120.26(15) . .
B4 B8 B3 60.40(11) . .
C8 B8 B7 121.87(16) . .
B4 B8 B7 107.39(14) . .
B3 B8 B7 59.36(11) . .
C8 B8 B12 123.45(17) . .
B4 B8 B12 107.26(14) . .
B3 B8 B12 107.45(13) . .
B7 B8 B12 59.85(10) . .
C8 B8 B9 123.36(15) . .
B4 B8 B9 59.59(11) . .
B3 B8 B9 107.74(14) . .
B7 B8 B9 107.17(13) . .
B12 B8 B9 59.54(10) . .
C9 B9 B4 121.91(16) . .
C9 B9 B5 121.66(16) . .
B4 B9 B5 60.44(12) . .
C9 B9 B12 121.62(16) . .
B4 B9 B12 107.89(12) . .
B5 B9 B12 107.89(13) . .
C9 B9 B10 121.40(15) . .
B4 B9 B10 108.09(13) . .
B5 B9 B10 59.62(11) . .
B12 B9 B10 60.24(11) . .
C9 B9 B8 121.71(16) . .
B4 B9 B8 59.69(11) . .
B5 B9 B8 108.19(13) . .
B12 B9 B8 60.22(11) . .
B10 B9 B8 108.43(12) . .
C10 B10 B6 121.09(16) . .
C10 B10 B5 120.79(15) . .
B6 B10 B5 60.71(11) . .
C10 B10 B9 121.91(15) . .
B6 B10 B9 108.22(13) . .
B5 B10 B9 59.85(11) . .
C10 B10 B12 122.93(15) . .
B6 B10 B12 107.56(12) . .
B5 B10 B12 107.63(13) . .
B9 B10 B12 59.68(11) . .
C10 B10 B11 122.19(15) . .
B6 B10 B11 59.72(11) . .
B5 B10 B11 108.28(13) . .
B9 B10 B11 107.77(13) . .
B12 B10 B11 59.83(10) . .
C11 B11 B6 122.25(16) . .
C11 B11 B2 122.28(15) . .
B6 B11 B2 60.43(11) . .
C11 B11 B7 122.28(15) . .
B6 B11 B7 107.37(13) . .
B2 B11 B7 59.33(11) . .
C11 B11 B12 121.32(16) . .
B6 B11 B12 107.54(13) . .
B2 B11 B12 107.74(13) . .
B7 B11 B12 59.99(10) . .
C11 B11 B10 121.47(15) . .
B6 B11 B10 59.47(10) . .
B2 B11 B10 107.96(13) . .
B7 B11 B10 107.65(13) . .
B12 B11 B10 60.05(10) . .
C12 B12 B9 120.83(15) . .
C12 B12 B7 123.57(15) . .
B9 B12 B7 107.70(13) . .
C12 B12 B11 121.32(16) . .
B9 B12 B11 108.34(14) . .
B7 B12 B11 59.88(11) . .
C12 B12 B10 120.20(15) . .
B9 B12 B10 60.09(11) . .
B7 B12 B10 107.62(13) . .
B11 B12 B10 60.12(10) . .
C12 B12 B8 122.46(17) . .
B9 B12 B8 60.24(11) . .
B7 B12 B8 59.81(10) . .
B11 B12 B8 108.33(13) . .
B10 B12 B8 108.33(13) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 H7A 2.19(3) .
Ag1 H7B 2.20(3) .
Ag1 P1 2.3871(5) .
Ag1 H12A 2.45(3) 2_655
Ag1 H9B 2.54(4) 1_655
Ag1 C7 2.544(2) .
Ag1 H9A 2.73(4) 1_655
P1 C25 1.8151(18) .
P1 C13 1.8177(19) .
P1 C19 1.8190(18) .
C1 B3 1.707(3) .
C1 B5 1.708(2) .
C1 B6 1.708(3) .
C1 B4 1.712(3) .
C1 B2 1.713(3) .
C2 B2 1.592(2) .
C3 B3 1.592(3) .
C4 B4 1.594(3) .
C5 B5 1.589(3) .
C6 B6 1.593(3) .
C7 H7C 0.93(4) .
C7 H7B 0.93(3) .
C7 H7A 0.93(3) .
C7 B7 1.606(3) .
C8 B8 1.593(3) .
C9 H9A 0.94(4) .
C9 H9C 0.94(4) .
C9 H9B 0.95(4) .
C9 B9 1.600(3) .
C10 B10 1.588(3) .
C11 B11 1.601(3) .
C12 H12C 0.87(4) .
C12 H12B 0.88(3) .
C12 H12A 0.94(3) .
C12 B12 1.598(3) .
C13 C18 1.389(3) .
C13 C14 1.392(3) .
C14 C15 1.392(3) .
C15 C16 1.357(4) .
C16 C17 1.385(4) .
C17 C18 1.385(3) .
C19 C24 1.390(3) .
C19 C20 1.395(3) .
C20 C21 1.385(3) .
C21 C22 1.383(3) .
C22 C23 1.375(3) .
C23 C24 1.385(3) .
C25 C26 1.387(3) .
C25 C30 1.397(3) .
C26 C27 1.396(3) .
C27 C28 1.378(4) .
C28 C29 1.387(4) .
C29 C30 1.383(3) .
B2 B7 1.764(3) .
B2 B11 1.780(3) .
B2 B6 1.789(3) .
B2 B3 1.792(3) .
B3 B7 1.766(3) .
B3 B8 1.780(3) .
B3 B4 1.789(3) .
B4 B9 1.775(3) .
B4 B8 1.777(3) .
B4 B5 1.789(3) .
B5 B10 1.774(3) .
B5 B9 1.778(3) .
B5 B6 1.791(3) .
B6 B10 1.770(3) .
B6 B11 1.775(3) .
B7 B11 1.785(3) .
B7 B8 1.786(3) .
B7 B12 1.787(2) .
B8 B12 1.795(3) .
B8 B9 1.796(3) .
B9 B12 1.783(3) .
B9 B10 1.790(3) .
B10 B12 1.793(3) .
B10 B11 1.794(2) .
B11 B12 1.789(3) .
