#------------------------------------------------------------------------------
#$Date: 2016-03-22 11:25:03 +0200 (Tue, 22 Mar 2016) $
#$Revision: 178898 $
#$URL: svn://www.crystallography.net/cod/cif/4/11/27/4112716.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4112716
loop_
_publ_author_name
'Olivier Tardif'
'Daisuke Hashizume'
'Zhaomin Hou'
_publ_section_title
;
 Hydrogenation of Carbon Dioxide and Aryl Isocyanates by a Tetranuclear
 Tetrahydrido Yttrium Complex. Isolation, Structures, and CO2 Insertion
 Reactions of Methylene Diolate and μ3-Oxo Yttrium Complexes
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              8080
_journal_page_last               8081
_journal_paper_doi               10.1021/ja047889u
_journal_volume                  126
_journal_year                    2004
_chemical_formula_sum            'C60 H106 O5 Si6 Y4'
_chemical_formula_weight         1431.63
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 111.150(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   26.150(2)
_cell_length_b                   12.1801(11)
_cell_length_c                   23.553(2)
_cell_measurement_temperature    203(2)
_cell_volume                     6996.5(10)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      203(2)
_diffrn_measured_fraction_theta_full 0.943
_diffrn_measured_fraction_theta_max 0.943
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0388
_diffrn_reflns_av_sigmaI/netI    0.1257
_diffrn_reflns_limit_h_max       34
_diffrn_reflns_limit_h_min       -34
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            20469
_diffrn_reflns_theta_full        27.99
_diffrn_reflns_theta_max         27.99
_diffrn_reflns_theta_min         1.67
_exptl_absorpt_coefficient_mu    3.429
_exptl_absorpt_correction_T_max  0.93
_exptl_absorpt_correction_T_min  0.53
_exptl_absorpt_correction_type   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.359
_exptl_crystal_description       hexagonal
_exptl_crystal_F_000             2984
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.2
_refine_diff_density_max         0.556
_refine_diff_density_min         -0.815
_refine_diff_density_rms         0.175
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.768
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     374
_refine_ls_number_reflns         7961
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.768
_refine_ls_R_factor_all          0.0730
_refine_ls_R_factor_gt           0.0366
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0180P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0651
_refine_ls_wR_factor_ref         0.0699
_reflns_number_gt                4653
_reflns_number_total             7961
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja047889urom20040413_031904.cif
_cod_data_source_block           3
_cod_original_cell_volume        6996.6(11)
_cod_database_code               4112716
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Y1 Y 0.425398(14) 0.39984(3) 0.252023(16) 0.02615(10) Uani 1 1 d . .
Y2 Y 0.531236(15) 0.21013(3) 0.348792(16) 0.02756(10) Uani 1 1 d . .
Si1 Si 0.55959(4) 0.45154(9) 0.40313(5) 0.0333(3) Uani 1 1 d . .
Si2 Si 0.26808(4) 0.31944(10) 0.22867(6) 0.0433(3) Uani 1 1 d . .
Si3 Si 0.66055(5) 0.00690(10) 0.44297(6) 0.0438(3) Uani 1 1 d . .
O1 O 0.56120(9) 0.22754(18) 0.19924(10) 0.0250(6) Uani 1 1 d . .
O2 O 0.59452(9) 0.22573(19) 0.30212(10) 0.0270(6) Uani 1 1 d . .
O3 O 0.51925(16) 0.1384(4) 0.2515(2) 0.0277(13) Uani 0.50 1 d P .
C1 C 0.52484(13) 0.4184(3) 0.32173(15) 0.0244(8) Uani 1 1 d . .
C2 C 0.51091(14) 0.5148(3) 0.28237(15) 0.0229(8) Uani 1 1 d . .
H2 H 0.5183(12) 0.582(2) 0.2993(12) 0.020(9) Uiso 1 1 d . .
C3 C 0.51750(15) 0.4034(3) 0.44846(16) 0.0460(11) Uani 1 1 d . .
H3A H 0.4838 0.4440 0.4363 0.069 Uiso 1 1 calc R .
H3B H 0.5376 0.4152 0.4910 0.069 Uiso 1 1 calc R .
H3C H 0.5096 0.3266 0.4412 0.069 Uiso 1 1 calc R .
C4 C 0.57879(16) 0.5981(3) 0.42466(16) 0.0521(12) Uani 1 1 d . .
H4A H 0.6014 0.6246 0.4033 0.078 Uiso 1 1 calc R .
H4B H 0.5987 0.6029 0.4677 0.078 Uiso 1 1 calc R .
H4C H 0.5462 0.6420 0.4140 0.078 Uiso 1 1 calc R .
C5 C 0.62536(14) 0.3696(3) 0.43466(16) 0.0466(12) Uani 1 1 d . .
H5A H 0.6170 0.2926 0.4308 0.070 Uiso 1 1 calc R .
H5B H 0.6439 0.3875 0.4768 0.070 Uiso 1 1 calc R .
H5C H 0.6486 0.3872 0.4124 0.070 Uiso 1 1 calc R .
C6 C 0.32332(14) 0.4243(3) 0.24869(17) 0.0297(9) Uani 1 1 d . .
C7 C 0.32970(14) 0.5059(3) 0.20807(16) 0.0306(9) Uani 1 1 d . .
C8 C 0.36694(15) 0.5861(3) 0.24154(18) 0.0326(10) Uani 1 1 d . .
C9 C 0.38434(15) 0.5578(3) 0.30354(17) 0.0320(10) Uani 1 1 d . .
C10 C 0.35750(15) 0.4607(3) 0.30838(16) 0.0306(9) Uani 1 1 d . .
C11 C 0.29479(15) 0.5160(3) 0.14133(16) 0.0489(12) Uani 1 1 d . .
H11A H 0.2609 0.5516 0.1371 0.073 Uiso 1 1 calc R .
H11B H 0.2874 0.4442 0.1234 0.073 Uiso 1 1 calc R .
H11C H 0.3140 0.5586 0.1211 0.073 Uiso 1 1 calc R .
C12 C 0.38116(17) 0.6927(3) 0.21738(19) 0.0528(13) Uani 1 1 d . .
H12A H 0.3730 0.6861 0.1744 0.079 Uiso 1 1 calc R .
H12B H 0.4195 0.7079 0.2376 0.079 Uiso 1 1 calc R .
H12C H 0.3600 0.7515 0.2249 0.079 Uiso 1 1 calc R .
C13 C 0.41841(16) 0.6317(3) 0.35492(17) 0.0501(12) Uani 1 1 d . .
H13A H 0.4482 0.6619 0.3453 0.075 Uiso 1 1 calc R .
H13B H 0.4327 0.5899 0.3919 0.075 Uiso 1 1 calc R .
H13C H 0.3959 0.6902 0.3602 0.075 Uiso 1 1 calc R .
C14 C 0.36150(16) 0.4084(3) 0.36854(16) 0.0531(13) Uani 1 1 d . .
H14A H 0.3869 0.4492 0.4016 0.080 Uiso 1 1 calc R .
H14B H 0.3741 0.3341 0.3699 0.080 Uiso 1 1 calc R .
H14C H 0.3260 0.4088 0.3720 0.080 Uiso 1 1 calc R .
C15 C 0.20164(15) 0.3919(4) 0.2138(2) 0.0731(16) Uani 1 1 d . .
H15A H 0.2032 0.4317 0.2496 0.110 Uiso 1 1 calc R .
H15B H 0.1724 0.3392 0.2037 0.110 Uiso 1 1 calc R .
H15C H 0.1951 0.4422 0.1806 0.110 Uiso 1 1 calc R .
C16 C 0.27675(18) 0.2156(4) 0.2890(2) 0.0773(16) Uani 1 1 d . .
H16A H 0.3126 0.1835 0.3007 0.116 Uiso 1 1 calc R .
H16B H 0.2495 0.1593 0.2739 0.116 Uiso 1 1 calc R .
H16C H 0.2726 0.2502 0.3237 0.116 Uiso 1 1 calc R .
C17 C 0.26071(18) 0.2399(4) 0.15875(19) 0.0739(16) Uani 1 1 d . .
H17A H 0.2430 0.2846 0.1235 0.111 Uiso 1 1 calc R .
H17B H 0.2390 0.1756 0.1570 0.111 Uiso 1 1 calc R .
H17C H 0.2963 0.2185 0.1596 0.111 Uiso 1 1 calc R .
C18 C 0.58733(14) 0.0487(3) 0.42165(15) 0.0270(9) Uani 1 1 d . .
C19 C 0.54220(16) -0.0036(3) 0.37672(16) 0.0323(9) Uani 1 1 d . .
C20 C 0.49366(15) 0.0266(3) 0.38390(18) 0.0374(10) Uani 1 1 d . .
C21 C 0.50656(16) 0.0966(3) 0.43444(18) 0.0377(10) Uani 1 1 d . .
C22 C 0.56413(16) 0.1102(3) 0.45819(16) 0.0334(9) Uani 1 1 d . .
C23 C 0.54571(15) -0.0901(3) 0.33143(16) 0.0473(11) Uani 1 1 d . .
H23A H 0.5095 -0.1065 0.3033 0.071 Uiso 1 1 calc R .
H23B H 0.5622 -0.1556 0.3530 0.071 Uiso 1 1 calc R .
H23C H 0.5677 -0.0626 0.3095 0.071 Uiso 1 1 calc R .
C24 C 0.43719(16) -0.0188(4) 0.3492(2) 0.0635(14) Uani 1 1 d . .
H24A H 0.4321 -0.0858 0.3680 0.095 Uiso 1 1 calc R .
H24B H 0.4336 -0.0333 0.3079 0.095 Uiso 1 1 calc R .
H24C H 0.4100 0.0337 0.3497 0.095 Uiso 1 1 calc R .
C25 C 0.46548(17) 0.1357(3) 0.46179(19) 0.0643(15) Uani 1 1 d . .
H25A H 0.4334 0.1631 0.4301 0.097 Uiso 1 1 calc R .
H25B H 0.4816 0.1933 0.4906 0.097 Uiso 1 1 calc R .
H25C H 0.4555 0.0757 0.4821 0.097 Uiso 1 1 calc R .
C26 C 0.59549(17) 0.1620(3) 0.51925(16) 0.0506(12) Uani 1 1 d . .
H26A H 0.5711 0.2068 0.5316 0.076 Uiso 1 1 calc R .
H26B H 0.6245 0.2068 0.5159 0.076 Uiso 1 1 calc R .
H26C H 0.6107 0.1055 0.5489 0.076 Uiso 1 1 calc R .
C27 C 0.67154(17) -0.1139(4) 0.4950(2) 0.0881(18) Uani 1 1 d . .
H27A H 0.7091 -0.1368 0.5079 0.132 Uiso 1 1 calc R .
H27B H 0.6482 -0.1731 0.4739 0.132 Uiso 1 1 calc R .
H27C H 0.6630 -0.0938 0.5300 0.132 Uiso 1 1 calc R .
C28 C 0.71095(15) 0.1141(4) 0.48251(19) 0.0637(14) Uani 1 1 d . .
H28A H 0.7053 0.1778 0.4569 0.096 Uiso 1 1 calc R .
H28B H 0.7474 0.0866 0.4913 0.096 Uiso 1 1 calc R .
H28C H 0.7063 0.1337 0.5198 0.096 Uiso 1 1 calc R .
C29 C 0.67871(17) -0.0347(4) 0.3764(2) 0.0840(18) Uani 1 1 d . .
H29A H 0.6654 0.0194 0.3448 0.126 Uiso 1 1 calc R .
H29B H 0.6622 -0.1044 0.3613 0.126 Uiso 1 1 calc R .
H29C H 0.7178 -0.0407 0.3887 0.126 Uiso 1 1 calc R .
C30A C 0.5919(3) 0.1663(7) 0.2503(4) 0.032(2) Uani 0.50 1 d P 1
H30A H 0.6286 0.1539 0.2503 0.038 Uiso 0.50 1 calc PR 1
H30B H 0.5747 0.0956 0.2499 0.038 Uiso 0.50 1 calc PR 1
C30B C 0.5620(3) 0.1917(6) 0.2507(4) 0.0230(18) Uani 0.50 1 d P 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Y Y -2.7962 3.5667 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Y1 O2 56.29(7) 2_655 2_655
O1 Y1 C2 113.37(10) 2_655 .
O2 Y1 C2 129.42(9) 2_655 .
O1 Y1 C2 130.63(10) 2_655 2_655
O2 Y1 C2 110.90(9) 2_655 2_655
C2 Y1 C2 32.81(15) . 2_655
O1 Y1 C1 113.05(9) 2_655 2_655
O2 Y1 C1 77.52(9) 2_655 2_655
C2 Y1 C1 61.31(11) . 2_655
C2 Y1 C1 33.54(10) 2_655 2_655
O1 Y1 C1 80.02(10) 2_655 .
O2 Y1 C1 113.14(9) 2_655 .
C2 Y1 C1 33.56(10) . .
C2 Y1 C1 61.09(11) 2_655 .
C1 Y1 C1 77.00(12) 2_655 .
O1 Y1 C30B 29.85(18) 2_655 2_655
O2 Y1 C30B 29.37(18) 2_655 2_655
C2 Y1 C30B 116.71(18) . 2_655
C2 Y1 C30B 115.83(18) 2_655 2_655
C1 Y1 C30B 88.22(19) 2_655 2_655
C1 Y1 C30B 89.64(18) . 2_655
O1 Y1 C6 94.91(10) 2_655 .
O2 Y1 C6 93.41(10) 2_655 .
C2 Y1 C6 136.61(11) . .
C2 Y1 C6 134.47(11) 2_655 .
C1 Y1 C6 136.86(11) 2_655 .
C1 Y1 C6 142.50(11) . .
C30B Y1 C6 104.30(18) 2_655 .
O1 Y1 C7 124.99(10) 2_655 .
O2 Y1 C7 103.01(10) 2_655 .
C2 Y1 C7 116.99(12) . .
C2 Y1 C7 104.00(11) 2_655 .
C1 Y1 C7 109.44(11) 2_655 .
C1 Y1 C7 143.74(12) . .
C30B Y1 C7 125.46(19) 2_655 .
C6 Y1 C7 31.14(10) . .
O1 Y1 C10 90.80(10) 2_655 .
O2 Y1 C10 116.53(10) 2_655 .
C2 Y1 C10 112.70(12) . .
C2 Y1 C10 129.68(12) 2_655 .
C1 Y1 C10 156.02(11) 2_655 .
C1 Y1 C10 111.28(11) . .
C30B Y1 C10 113.65(19) 2_655 .
C6 Y1 C10 31.25(10) . .
C7 Y1 C10 50.34(10) . .
O1 Y1 C9 115.45(10) 2_655 .
O2 Y1 C9 144.45(10) 2_655 .
C2 Y1 C9 86.13(11) . .
C2 Y1 C9 99.49(12) 2_655 .
C1 Y1 C9 129.24(11) 2_655 .
C1 Y1 C9 97.28(11) . .
C30B Y1 C9 142.53(19) 2_655 .
C6 Y1 C9 51.29(11) . .
C7 Y1 C9 50.18(11) . .
C10 Y1 C9 30.21(10) . .
O1 Y1 C8 140.67(9) 2_655 .
O2 Y1 C8 132.73(10) 2_655 .
C2 Y1 C8 88.52(12) . .
C2 Y1 C8 85.52(11) 2_655 .
C1 Y1 C8 106.07(11) 2_655 .
C1 Y1 C8 113.52(12) . .
C30B Y1 C8 154.76(18) 2_655 .
C6 Y1 C8 51.18(11) . .
C7 Y1 C8 30.31(11) . .
C10 Y1 C8 49.97(11) . .
C9 Y1 C8 30.25(10) . .
O1 Y2 O2 124.88(8) 2_655 .
O1 Y2 O3 78.89(11) 2_655 .
O2 Y2 O3 55.56(11) . .
O1 Y2 O3 56.00(11) 2_655 2_655
O2 Y2 O3 78.23(11) . 2_655
O3 Y2 O3 23.70(18) . 2_655
O1 Y2 C1 79.93(9) 2_655 .
O2 Y2 C1 78.26(9) . .
O3 Y2 C1 98.53(13) . .
O3 Y2 C1 98.55(13) 2_655 .
O1 Y2 C18 128.69(9) 2_655 .
O2 Y2 C18 92.57(9) . .
O3 Y2 C18 101.56(13) . .
O3 Y2 C18 109.96(13) 2_655 .
C1 Y2 C18 147.66(10) . .
O1 Y2 C19 102.30(10) 2_655 .
O2 Y2 C19 99.56(10) . .
O3 Y2 C19 81.00(13) . .
O3 Y2 C19 82.00(13) 2_655 .
C1 Y2 C19 177.56(11) . .
C18 Y2 C19 30.80(10) . .
O1 Y2 C20 77.89(10) 2_655 .
O2 Y2 C20 128.39(11) . .
O3 Y2 C20 93.17(14) . .
O3 Y2 C20 82.46(14) 2_655 .
C1 Y2 C20 152.36(11) . .
C18 Y2 C20 50.80(11) . .
C19 Y2 C20 30.02(10) . .
O1 Y2 C22 115.60(10) 2_655 .
O2 Y2 C22 117.23(10) . .
O3 Y2 C22 130.12(14) . .
O3 Y2 C22 130.16(14) 2_655 .
C1 Y2 C22 130.07(11) . .
C18 Y2 C22 30.91(10) . .
C19 Y2 C22 49.93(11) . .
C20 Y2 C22 49.94(11) . .
O1 Y2 C21 85.54(10) 2_655 .
O2 Y2 C21 143.46(10) . .
O3 Y2 C21 123.28(14) . .
O3 Y2 C21 110.52(14) 2_655 .
C1 Y2 C21 131.88(11) . .
C18 Y2 C21 50.90(10) . .
C19 Y2 C21 49.69(11) . .
C20 Y2 C21 30.11(11) . .
C22 Y2 C21 30.33(10) . .
O1 Y2 C30B 28.04(16) 2_655 2_655
O2 Y2 C30B 99.87(16) . 2_655
O3 Y2 C30B 50.9(2) . 2_655
O3 Y2 C30B 28.60(17) 2_655 2_655
C1 Y2 C30B 84.88(17) . 2_655
C18 Y2 C30B 127.41(18) . 2_655
C19 Y2 C30B 96.62(18) . 2_655
C20 Y2 C30B 83.27(18) . 2_655
C22 Y2 C30B 131.74(18) . 2_655
C21 Y2 C30B 102.68(19) . 2_655
O1 Y2 C30B 99.92(16) 2_655 .
O2 Y2 C30B 27.82(15) . .
O3 Y2 C30B 28.59(16) . .
O3 Y2 C30B 50.47(19) 2_655 .
C1 Y2 C30B 83.39(18) . .
C18 Y2 C30B 102.88(18) . .
C19 Y2 C30B 95.19(18) . .
C20 Y2 C30B 116.51(18) . .
C22 Y2 C30B 133.29(18) . .
C21 Y2 C30B 144.55(18) . .
C30B Y2 C30B 73.1(2) 2_655 .
C1 Si1 C4 118.20(17) . .
C1 Si1 C3 110.59(16) . .
C4 Si1 C3 107.31(17) . .
C1 Si1 C5 109.23(16) . .
C4 Si1 C5 106.21(18) . .
C3 Si1 C5 104.35(17) . .
C1 Si1 Y2 54.91(11) . .
C4 Si1 Y2 171.37(12) . .
C3 Si1 Y2 80.88(13) . .
C5 Si1 Y2 73.61(12) . .
C16 Si2 C6 113.94(19) . .
C16 Si2 C17 105.6(2) . .
C6 Si2 C17 113.93(18) . .
C16 Si2 C15 108.3(2) . .
C6 Si2 C15 107.96(18) . .
C17 Si2 C15 106.8(2) . .
C28 Si3 C29 105.30(19) . .
C28 Si3 C18 114.72(18) . .
C29 Si3 C18 113.30(19) . .
C28 Si3 C27 108.2(2) . .
C29 Si3 C27 108.2(2) . .
C18 Si3 C27 106.92(18) . .
C30B O1 C30A 36.5(4) . .
C30B O1 Y2 95.2(4) . 2_655
C30A O1 Y2 123.7(4) . 2_655
C30B O1 Y1 83.9(4) . 2_655
C30A O1 Y1 96.8(4) . 2_655
Y2 O1 Y1 105.63(9) 2_655 2_655
C30B O2 C30A 36.5(4) . .
C30B O2 Y2 94.6(4) . .
C30A O2 Y2 123.9(4) . .
C30B O2 Y1 80.9(4) . 2_655
C30A O2 Y1 93.4(4) . 2_655
Y2 O2 Y1 105.52(9) . 2_655
O3 O3 C30B 149.7(4) 2_655 .
O3 O3 Y2 81.1(5) 2_655 .
C30B O3 Y2 90.9(4) . .
O3 O3 Y2 75.2(5) 2_655 2_655
C30B O3 Y2 88.5(4) . 2_655
Y2 O3 Y2 130.42(18) . 2_655
C2 C1 Si1 113.7(2) . .
C2 C1 Y1 73.00(18) . 2_655
Si1 C1 Y1 123.42(16) . 2_655
C2 C1 Y1 72.39(19) . .
Si1 C1 Y1 134.24(16) . .
Y1 C1 Y1 102.06(11) 2_655 .
C2 C1 Y2 156.7(2) . .
Si1 C1 Y2 89.68(13) . .
Y1 C1 Y2 94.43(11) 2_655 .
Y1 C1 Y2 91.81(11) . .
C2 C2 C1 126.40(19) 2_655 .
C2 C2 Y1 74.0(2) 2_655 .
C1 C2 Y1 74.05(19) . .
C2 C2 Y1 73.2(2) 2_655 2_655
C1 C2 Y1 73.45(19) . 2_655
Y1 C2 Y1 102.85(13) . 2_655
C2 C2 H2 114.5(19) 2_655 .
C1 C2 H2 119.0(19) . .
Y1 C2 H2 131.2(19) . .
Y1 C2 H2 125.9(19) 2_655 .
Si1 C3 H3A 109.5 . .
Si1 C3 H3B 109.5 . .
H3A C3 H3B 109.5 . .
Si1 C3 H3C 109.5 . .
H3A C3 H3C 109.5 . .
H3B C3 H3C 109.5 . .
Si1 C4 H4A 109.5 . .
Si1 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
Si1 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
Si1 C5 H5A 109.5 . .
Si1 C5 H5B 109.5 . .
H5A C5 H5B 109.5 . .
Si1 C5 H5C 109.5 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
C7 C6 C10 105.0(3) . .
C7 C6 Si2 125.2(3) . .
C10 C6 Si2 127.8(3) . .
C7 C6 Y1 74.91(19) . .
C10 C6 Y1 75.07(19) . .
Si2 C6 Y1 127.67(17) . .
C8 C7 C6 109.4(3) . .
C8 C7 C11 124.3(4) . .
C6 C7 C11 125.4(4) . .
C8 C7 Y1 75.9(2) . .
C6 C7 Y1 74.0(2) . .
C11 C7 Y1 124.9(2) . .
C7 C8 C9 108.1(3) . .
C7 C8 C12 126.8(4) . .
C9 C8 C12 124.6(4) . .
C7 C8 Y1 73.8(2) . .
C9 C8 Y1 74.8(2) . .
C12 C8 Y1 123.2(2) . .
C10 C9 C8 107.9(3) . .
C10 C9 C13 127.2(4) . .
C8 C9 C13 124.1(4) . .
C10 C9 Y1 74.2(2) . .
C8 C9 Y1 74.9(2) . .
C13 C9 Y1 124.7(2) . .
C9 C10 C6 109.5(3) . .
C9 C10 C14 124.1(4) . .
C6 C10 C14 126.2(4) . .
C9 C10 Y1 75.63(19) . .
C6 C10 Y1 73.68(18) . .
C14 C10 Y1 120.7(2) . .
C7 C11 H11A 109.5 . .
C7 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C7 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C8 C12 H12A 109.5 . .
C8 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C8 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C9 C13 H13A 109.5 . .
C9 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C9 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
C10 C14 H14A 109.5 . .
C10 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C10 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
Si2 C15 H15A 109.5 . .
Si2 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
Si2 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
Si2 C16 H16A 109.5 . .
Si2 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
Si2 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
Si2 C17 H17A 109.5 . .
Si2 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
Si2 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C19 C18 C22 105.3(3) . .
C19 C18 Si3 125.1(3) . .
C22 C18 Si3 126.7(3) . .
C19 C18 Y2 74.6(2) . .
C22 C18 Y2 75.4(2) . .
Si3 C18 Y2 130.19(16) . .
C20 C19 C18 109.9(3) . .
C20 C19 C23 123.8(4) . .
C18 C19 C23 126.0(3) . .
C20 C19 Y2 75.6(2) . .
C18 C19 Y2 74.6(2) . .
C23 C19 Y2 121.9(2) . .
C19 C20 C21 108.3(3) . .
C19 C20 C24 126.5(4) . .
C21 C20 C24 124.7(4) . .
C19 C20 Y2 74.4(2) . .
C21 C20 Y2 75.7(2) . .
C24 C20 Y2 122.2(3) . .
C20 C21 C22 107.6(3) . .
C20 C21 C25 124.2(4) . .
C22 C21 C25 127.7(4) . .
C20 C21 Y2 74.2(2) . .
C22 C21 Y2 74.3(2) . .
C25 C21 Y2 123.5(3) . .
C21 C22 C18 108.8(3) . .
C21 C22 C26 124.0(4) . .
C18 C22 C26 126.0(3) . .
C21 C22 Y2 75.4(2) . .
C18 C22 Y2 73.72(19) . .
C26 C22 Y2 126.6(3) . .
C19 C23 H23A 109.5 . .
C19 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C19 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C20 C24 H24A 109.5 . .
C20 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C20 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C21 C25 H25A 109.5 . .
C21 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
C21 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
C22 C26 H26A 109.5 . .
C22 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C22 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
Si3 C27 H27A 109.5 . .
Si3 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
Si3 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
Si3 C28 H28A 109.5 . .
Si3 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
Si3 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
Si3 C29 H29A 109.5 . .
Si3 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
Si3 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
O1 C30A O2 107.8(6) . .
O1 C30A Y1 54.4(3) . 2_655
O2 C30A Y1 57.5(3) . 2_655
O1 C30A H30A 110.1 . .
O2 C30A H30A 110.1 . .
Y1 C30A H30A 107.6 2_655 .
O1 C30A H30B 110.1 . .
O2 C30A H30B 110.1 . .
Y1 C30A H30B 143.9 2_655 .
O2 C30B O1 124.6(6) . .
O2 C30B O3 115.6(7) . .
O1 C30B O3 117.6(6) . .
O2 C30B Y1 69.7(3) . 2_655
O1 C30B Y1 66.3(3) . 2_655
O3 C30B Y1 127.9(5) . 2_655
O2 C30B Y2 151.5(5) . 2_655
O1 C30B Y2 56.7(3) . 2_655
O3 C30B Y2 62.9(4) . 2_655
Y1 C30B Y2 88.9(2) 2_655 2_655
O2 C30B Y2 57.6(3) . .
O1 C30B Y2 150.2(5) . .
O3 C30B Y2 60.5(4) . .
Y1 C30B Y2 91.1(2) 2_655 .
Y2 C30B Y2 106.1(2) 2_655 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Y1 O1 2.357(2) 2_655
Y1 O2 2.432(2) 2_655
Y1 C2 2.513(4) .
Y1 C2 2.523(3) 2_655
Y1 C1 2.529(3) 2_655
Y1 C1 2.535(3) .
Y1 C30B 2.560(8) 2_655
Y1 C6 2.659(3) .
Y1 C7 2.671(3) .
Y1 C10 2.677(3) .
Y1 C9 2.696(3) .
Y1 C8 2.697(4) .
Y2 O1 2.279(2) 2_655
Y2 O2 2.301(2) .
Y2 O3 2.365(5) .
Y2 O3 2.416(5) 2_655
Y2 C1 2.607(4) .
Y2 C18 2.673(3) .
Y2 C19 2.675(4) .
Y2 C20 2.690(4) .
Y2 C22 2.695(3) .
Y2 C21 2.709(3) .
Y2 C30B 2.714(8) 2_655
Y2 C30B 2.716(8) .
Si1 C1 1.846(3) .
Si1 C4 1.874(4) .
Si1 C3 1.882(3) .
Si1 C5 1.893(4) .
Si2 C16 1.855(4) .
Si2 C6 1.857(4) .
Si2 C17 1.860(4) .
Si2 C15 1.866(4) .
Si3 C28 1.850(4) .
Si3 C29 1.866(4) .
Si3 C18 1.866(4) .
Si3 C27 1.870(4) .
O1 C30B 1.281(8) .
O1 C30A 1.397(8) .
O1 Y2 2.279(2) 2_655
O1 Y1 2.357(2) 2_655
O2 C30B 1.272(8) .
O2 C30A 1.400(8) .
O2 Y1 2.432(2) 2_655
O3 O3 0.983(8) 2_655
O3 C30B 1.300(7) .
O3 Y2 2.416(5) 2_655
C1 C2 1.458(5) .
C1 Y1 2.529(3) 2_655
C2 C2 1.422(6) 2_655
C2 Y1 2.523(3) 2_655
C2 H2 0.90(3) .
C3 H3A 0.9600 .
C3 H3B 0.9600 .
C3 H3C 0.9600 .
C4 H4A 0.9600 .
C4 H4B 0.9600 .
C4 H4C 0.9600 .
C5 H5A 0.9600 .
C5 H5B 0.9600 .
C5 H5C 0.9600 .
C6 C7 1.431(5) .
C6 C10 1.437(5) .
C7 C8 1.404(5) .
C7 C11 1.511(4) .
C8 C9 1.407(5) .
C8 C12 1.516(5) .
C9 C10 1.400(5) .
C9 C13 1.514(5) .
C10 C14 1.523(5) .
C11 H11A 0.9600 .
C11 H11B 0.9600 .
C11 H11C 0.9600 .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C13 H13A 0.9600 .
C13 H13B 0.9600 .
C13 H13C 0.9600 .
C14 H14A 0.9600 .
C14 H14B 0.9600 .
C14 H14C 0.9600 .
C15 H15A 0.9600 .
C15 H15B 0.9600 .
C15 H15C 0.9600 .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C17 H17A 0.9600 .
C17 H17B 0.9600 .
C17 H17C 0.9600 .
C18 C19 1.420(4) .
C18 C22 1.431(5) .
C19 C20 1.389(5) .
C19 C23 1.526(5) .
C20 C21 1.402(5) .
C20 C24 1.511(5) .
C21 C22 1.414(5) .
C21 C25 1.515(4) .
C22 C26 1.513(5) .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
C25 H25A 0.9600 .
C25 H25B 0.9600 .
C25 H25C 0.9600 .
C26 H26A 0.9600 .
C26 H26B 0.9600 .
C26 H26C 0.9600 .
C27 H27A 0.9600 .
C27 H27B 0.9600 .
C27 H27C 0.9600 .
C28 H28A 0.9600 .
C28 H28B 0.9600 .
C28 H28C 0.9600 .
C29 H29A 0.9600 .
C29 H29B 0.9600 .
C29 H29C 0.9600 .
C30A Y1 2.878(8) 2_655
C30A H30A 0.9700 .
C30A H30B 0.9700 .
C30B Y1 2.560(8) 2_655
C30B Y2 2.714(8) 2_655
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 Y2 Si1 C1 -57.22(14) 2_655 .
O2 Y2 Si1 C1 68.36(14) . .
O3 Y2 Si1 C1 26.29(18) . .
O3 Y2 Si1 C1 -5.93(18) 2_655 .
C18 Y2 Si1 C1 161.54(15) . .
C19 Y2 Si1 C1 175.88(19) . .
C20 Y2 Si1 C1 -139.53(17) . .
C22 Y2 Si1 C1 -174.22(15) . .
C21 Y2 Si1 C1 -145.08(15) . .
C30B Y2 Si1 C1 -32.9(2) 2_655 .
C30B Y2 Si1 C1 46.7(2) . .
O1 Y2 Si1 C4 -95.9(9) 2_655 .
O2 Y2 Si1 C4 29.7(9) . .
O3 Y2 Si1 C4 -12.4(9) . .
O3 Y2 Si1 C4 -44.6(9) 2_655 .
C1 Y2 Si1 C4 -38.7(9) . .
C18 Y2 Si1 C4 122.9(9) . .
C19 Y2 Si1 C4 137.2(9) . .
C20 Y2 Si1 C4 -178.2(9) . .
C22 Y2 Si1 C4 147.1(9) . .
C21 Y2 Si1 C4 176.3(9) . .
C30B Y2 Si1 C4 -71.6(9) 2_655 .
C30B Y2 Si1 C4 8.1(9) . .
O1 Y2 Si1 C3 66.02(13) 2_655 .
O2 Y2 Si1 C3 -168.40(13) . .
O3 Y2 Si1 C3 149.53(17) . .
O3 Y2 Si1 C3 117.31(17) 2_655 .
C1 Y2 Si1 C3 123.24(17) . .
C18 Y2 Si1 C3 -75.22(14) . .
C19 Y2 Si1 C3 -60.88(19) . .
C20 Y2 Si1 C3 -16.30(17) . .
C22 Y2 Si1 C3 -50.99(14) . .
C21 Y2 Si1 C3 -21.84(15) . .
C30B Y2 Si1 C3 90.3(2) 2_655 .
C30B Y2 Si1 C3 170.0(2) . .
O1 Y2 Si1 C5 174.01(13) 2_655 .
O2 Y2 Si1 C5 -60.40(13) . .
O3 Y2 Si1 C5 -102.48(17) . .
O3 Y2 Si1 C5 -134.70(17) 2_655 .
C1 Y2 Si1 C5 -128.77(17) . .
C18 Y2 Si1 C5 32.77(14) . .
C19 Y2 Si1 C5 47.11(19) . .
C20 Y2 Si1 C5 91.70(16) . .
C22 Y2 Si1 C5 57.01(14) . .
C21 Y2 Si1 C5 86.15(14) . .
C30B Y2 Si1 C5 -161.7(2) 2_655 .
C30B Y2 Si1 C5 -82.0(2) . .
O1 Y2 O2 C30B -29.4(4) 2_655 .
O3 Y2 O2 C30B 10.9(4) . .
O3 Y2 O2 C30B 3.3(4) 2_655 .
C1 Y2 O2 C30B -98.1(4) . .
C18 Y2 O2 C30B 113.2(4) . .
C19 Y2 O2 C30B 83.0(4) . .
C20 Y2 O2 C30B 73.7(4) . .
C22 Y2 O2 C30B 132.6(4) . .
C21 Y2 O2 C30B 112.0(4) . .
C30B Y2 O2 C30B -15.5(3) 2_655 .
O1 Y2 O2 C30A -52.8(4) 2_655 .
O3 Y2 O2 C30A -12.5(4) . .
O3 Y2 O2 C30A -20.1(4) 2_655 .
C1 Y2 O2 C30A -121.5(4) . .
C18 Y2 O2 C30A 89.8(4) . .
C19 Y2 O2 C30A 59.6(4) . .
C20 Y2 O2 C30A 50.3(5) . .
C22 Y2 O2 C30A 109.2(4) . .
C21 Y2 O2 C30A 88.6(5) . .
C30B Y2 O2 C30A -38.9(5) 2_655 .
C30B Y2 O2 C30A -23.4(6) . .
O1 Y2 O2 Y1 52.37(13) 2_655 2_655
O3 Y2 O2 Y1 92.67(15) . 2_655
O3 Y2 O2 Y1 85.08(13) 2_655 2_655
C1 Y2 O2 Y1 -16.36(9) . 2_655
C18 Y2 O2 Y1 -165.06(10) . 2_655
C19 Y2 O2 Y1 164.75(10) . 2_655
C20 Y2 O2 Y1 155.44(11) . 2_655
C22 Y2 O2 Y1 -145.60(11) . 2_655
C21 Y2 O2 Y1 -166.24(16) . 2_655
C30B Y2 O2 Y1 66.25(18) 2_655 2_655
C30B Y2 O2 Y1 81.8(4) . 2_655
O1 Y2 O3 O3 -14.0(2) 2_655 2_655
O2 Y2 O3 O3 -161.2(3) . 2_655
C1 Y2 O3 O3 -91.8(2) . 2_655
C18 Y2 O3 O3 113.6(2) . 2_655
C19 Y2 O3 O3 90.6(2) . 2_655
C20 Y2 O3 O3 63.0(2) . 2_655
C22 Y2 O3 O3 100.3(3) . 2_655
C21 Y2 O3 O3 63.1(3) . 2_655
C30B Y2 O3 O3 -15.6(3) 2_655 2_655
C30B Y2 O3 O3 -150.6(5) . 2_655
O1 Y2 O3 C30B 136.7(4) 2_655 .
O2 Y2 O3 C30B -10.6(4) . .
O3 Y2 O3 C30B 150.6(5) 2_655 .
C1 Y2 O3 C30B 58.8(4) . .
C18 Y2 O3 C30B -95.8(4) . .
C19 Y2 O3 C30B -118.8(4) . .
C20 Y2 O3 C30B -146.3(4) . .
C22 Y2 O3 C30B -109.1(4) . .
C21 Y2 O3 C30B -146.3(4) . .
C30B Y2 O3 C30B 135.0(6) 2_655 .
O1 Y2 O3 Y2 47.8(2) 2_655 2_655
O2 Y2 O3 Y2 -99.4(2) . 2_655
O3 Y2 O3 Y2 61.8(3) 2_655 2_655
C1 Y2 O3 Y2 -30.1(2) . 2_655
C18 Y2 O3 Y2 175.4(2) . 2_655
C19 Y2 O3 Y2 152.4(2) . 2_655
C20 Y2 O3 Y2 124.8(2) . 2_655
C22 Y2 O3 Y2 162.05(17) . 2_655
C21 Y2 O3 Y2 124.9(2) . 2_655
C30B Y2 O3 Y2 46.1(3) 2_655 2_655
C30B Y2 O3 Y2 -88.8(5) . 2_655
C4 Si1 C1 C2 -5.9(3) . .
C3 Si1 C1 C2 118.3(3) . .
C5 Si1 C1 C2 -127.4(3) . .
Y2 Si1 C1 C2 -179.7(3) . .
C4 Si1 C1 Y1 78.8(2) . 2_655
C3 Si1 C1 Y1 -157.01(18) . 2_655
C5 Si1 C1 Y1 -42.7(2) . 2_655
Y2 Si1 C1 Y1 -95.10(19) . 2_655
C4 Si1 C1 Y1 -93.9(3) . .
C3 Si1 C1 Y1 30.3(3) . .
C5 Si1 C1 Y1 144.6(2) . .
Y2 Si1 C1 Y1 92.2(2) . .
C4 Si1 C1 Y2 173.89(15) . .
C3 Si1 C1 Y2 -61.91(17) . .
C5 Si1 C1 Y2 52.39(16) . .
O1 Y1 C1 C2 173.7(2) 2_655 .
O2 Y1 C1 C2 127.21(18) 2_655 .
C2 Y1 C1 C2 25.26(18) 2_655 .
C1 Y1 C1 C2 57.1(2) 2_655 .
C30B Y1 C1 C2 145.3(3) 2_655 .
C6 Y1 C1 C2 -101.2(2) . .
C7 Y1 C1 C2 -48.1(3) . .
C10 Y1 C1 C2 -99.3(2) . .
C9 Y1 C1 C2 -71.6(2) . .
C8 Y1 C1 C2 -45.0(2) . .
O1 Y1 C1 Si1 -80.1(2) 2_655 .
O2 Y1 C1 Si1 -126.6(2) 2_655 .
C2 Y1 C1 Si1 106.2(3) . .
C2 Y1 C1 Si1 131.4(3) 2_655 .
C1 Y1 C1 Si1 163.26(17) 2_655 .
C30B Y1 C1 Si1 -108.5(3) 2_655 .
C6 Y1 C1 Si1 4.9(4) . .
C7 Y1 C1 Si1 58.0(3) . .
C10 Y1 C1 Si1 6.9(3) . .
C9 Y1 C1 Si1 34.6(3) . .
C8 Y1 C1 Si1 61.2(3) . .
O1 Y1 C1 Y1 106.16(12) 2_655 2_655
O2 Y1 C1 Y1 59.63(13) 2_655 2_655
C2 Y1 C1 Y1 -67.58(18) . 2_655
C2 Y1 C1 Y1 -42.32(12) 2_655 2_655
C1 Y1 C1 Y1 -10.49(16) 2_655 2_655
C30B Y1 C1 Y1 77.8(2) 2_655 2_655
C6 Y1 C1 Y1 -168.81(13) . 2_655
C7 Y1 C1 Y1 -115.72(16) . 2_655
C10 Y1 C1 Y1 -166.90(11) . 2_655
C9 Y1 C1 Y1 -139.17(12) . 2_655
C8 Y1 C1 Y1 -112.58(12) . 2_655
O1 Y1 C1 Y2 11.24(8) 2_655 .
O2 Y1 C1 Y2 -35.29(12) 2_655 .
C2 Y1 C1 Y2 -162.5(2) . .
C2 Y1 C1 Y2 -137.24(14) 2_655 .
C1 Y1 C1 Y2 -105.41(9) 2_655 .
C30B Y1 C1 Y2 -17.16(19) 2_655 .
C6 Y1 C1 Y2 96.27(18) . .
C7 Y1 C1 Y2 149.36(14) . .
C10 Y1 C1 Y2 98.18(12) . .
C9 Y1 C1 Y2 125.91(11) . .
C8 Y1 C1 Y2 152.50(10) . .
O1 Y2 C1 C2 -58.0(6) 2_655 .
O2 Y2 C1 C2 71.1(6) . .
O3 Y2 C1 C2 19.1(6) . .
O3 Y2 C1 C2 -4.9(6) 2_655 .
C18 Y2 C1 C2 147.1(5) . .
C19 Y2 C1 C2 98(3) . .
C20 Y2 C1 C2 -95.0(6) . .
C22 Y2 C1 C2 -173.1(6) . .
C21 Y2 C1 C2 -132.6(6) . .
C30B Y2 C1 C2 -30.1(6) 2_655 .
C30B Y2 C1 C2 43.4(6) . .
O1 Y2 C1 Si1 122.62(12) 2_655 .
O2 Y2 C1 Si1 -108.32(12) . .
O3 Y2 C1 Si1 -160.35(14) . .
O3 Y2 C1 Si1 175.68(13) 2_655 .
C18 Y2 C1 Si1 -32.4(2) . .
C19 Y2 C1 Si1 -81(3) . .
C20 Y2 C1 Si1 85.6(3) . .
C22 Y2 C1 Si1 7.53(19) . .
C21 Y2 C1 Si1 48.02(19) . .
C30B Y2 C1 Si1 150.5(2) 2_655 .
C30B Y2 C1 Si1 -136.03(19) . .
O1 Y2 C1 Y1 -113.88(10) 2_655 2_655
O2 Y2 C1 Y1 15.18(9) . 2_655
O3 Y2 C1 Y1 -36.85(13) . 2_655
O3 Y2 C1 Y1 -60.82(13) 2_655 2_655
C18 Y2 C1 Y1 91.14(19) . 2_655
C19 Y2 C1 Y1 42(3) . 2_655
C20 Y2 C1 Y1 -150.9(2) . 2_655
C22 Y2 C1 Y1 131.03(12) . 2_655
C21 Y2 C1 Y1 171.52(12) . 2_655
C30B Y2 C1 Y1 -86.02(18) 2_655 2_655
C30B Y2 C1 Y1 -12.53(17) . 2_655
O1 Y2 C1 Y1 -11.63(8) 2_655 .
O2 Y2 C1 Y1 117.43(10) . .
O3 Y2 C1 Y1 65.40(12) . .
O3 Y2 C1 Y1 41.42(12) 2_655 .
C18 Y2 C1 Y1 -166.61(14) . .
C19 Y2 C1 Y1 144(2) . .
C20 Y2 C1 Y1 -48.6(3) . .
C22 Y2 C1 Y1 -126.72(12) . .
C21 Y2 C1 Y1 -86.24(15) . .
C30B Y2 C1 Y1 16.23(17) 2_655 .
C30B Y2 C1 Y1 89.72(17) . .
Si1 C1 C2 C2 173.3(4) . 2_655
Y1 C1 C2 C2 53.6(4) 2_655 2_655
Y1 C1 C2 C2 -55.4(4) . 2_655
Y2 C1 C2 C2 -6.1(10) . 2_655
Si1 C1 C2 Y1 -131.3(2) . .
Y1 C1 C2 Y1 109.04(9) 2_655 .
Y2 C1 C2 Y1 49.3(6) . .
Si1 C1 C2 Y1 119.7(2) . 2_655
Y1 C1 C2 Y1 -109.04(9) . 2_655
Y2 C1 C2 Y1 -59.7(6) . 2_655
O1 Y1 C2 C2 129.70(15) 2_655 2_655
O2 Y1 C2 C2 65.00(19) 2_655 2_655
C1 Y1 C2 C2 25.24(17) 2_655 2_655
C1 Y1 C2 C2 136.4(3) . 2_655
C30B Y1 C2 C2 96.9(3) 2_655 2_655
C6 Y1 C2 C2 -103.9(2) . 2_655
C7 Y1 C2 C2 -73.21(19) . 2_655
C10 Y1 C2 C2 -128.93(17) . 2_655
C9 Y1 C2 C2 -114.20(17) . 2_655
C8 Y1 C2 C2 -84.02(17) . 2_655
O1 Y1 C2 C1 -6.7(2) 2_655 .
O2 Y1 C2 C1 -71.4(2) 2_655 .
C2 Y1 C2 C1 -136.4(3) 2_655 .
C1 Y1 C2 C1 -111.2(2) 2_655 .
C30B Y1 C2 C1 -39.5(3) 2_655 .
C6 Y1 C2 C1 119.6(2) . .
C7 Y1 C2 C1 150.37(18) . .
C10 Y1 C2 C1 94.7(2) . .
C9 Y1 C2 C1 109.4(2) . .
C8 Y1 C2 C1 139.6(2) . .
O1 Y1 C2 Y1 61.63(13) 2_655 2_655
O2 Y1 C2 Y1 -3.07(18) 2_655 2_655
C2 Y1 C2 Y1 -68.07(18) 2_655 2_655
C1 Y1 C2 Y1 -42.83(11) 2_655 2_655
C1 Y1 C2 Y1 68.35(19) . 2_655
C30B Y1 C2 Y1 28.8(2) 2_655 2_655
C6 Y1 C2 Y1 -172.02(12) . 2_655
C7 Y1 C2 Y1 -141.28(11) . 2_655
C10 Y1 C2 Y1 163.00(11) . 2_655
C9 Y1 C2 Y1 177.72(13) . 2_655
C8 Y1 C2 Y1 -152.09(13) . 2_655
C16 Si2 C6 C7 172.8(3) . .
C17 Si2 C6 C7 51.6(4) . .
C15 Si2 C6 C7 -66.8(3) . .
C16 Si2 C6 C10 -26.1(4) . .
C17 Si2 C6 C10 -147.3(3) . .
C15 Si2 C6 C10 94.3(3) . .
C16 Si2 C6 Y1 74.7(3) . .
C17 Si2 C6 Y1 -46.5(3) . .
C15 Si2 C6 Y1 -164.9(2) . .
O1 Y1 C6 C7 -166.2(2) 2_655 .
O2 Y1 C6 C7 -109.7(2) 2_655 .
C2 Y1 C6 C7 61.7(3) . .
C2 Y1 C6 C7 14.3(3) 2_655 .
C1 Y1 C6 C7 -34.4(3) 2_655 .
C1 Y1 C6 C7 113.9(2) . .
C30B Y1 C6 C7 -137.4(3) 2_655 .
C10 Y1 C6 C7 110.4(3) . .
C9 Y1 C6 C7 74.9(2) . .
C8 Y1 C6 C7 35.8(2) . .
O1 Y1 C6 C10 83.4(2) 2_655 .
O2 Y1 C6 C10 139.9(2) 2_655 .
C2 Y1 C6 C10 -48.7(3) . .
C2 Y1 C6 C10 -96.1(2) 2_655 .
C1 Y1 C6 C10 -144.8(2) 2_655 .
C1 Y1 C6 C10 3.4(3) . .
C30B Y1 C6 C10 112.2(3) 2_655 .
C7 Y1 C6 C10 -110.4(3) . .
C9 Y1 C6 C10 -35.5(2) . .
C8 Y1 C6 C10 -74.6(2) . .
O1 Y1 C6 Si2 -43.1(2) 2_655 .
O2 Y1 C6 Si2 13.3(2) 2_655 .
C2 Y1 C6 Si2 -175.21(17) . .
C2 Y1 C6 Si2 137.32(19) 2_655 .
C1 Y1 C6 Si2 88.7(3) 2_655 .
C1 Y1 C6 Si2 -123.1(2) . .
C30B Y1 C6 Si2 -14.3(3) 2_655 .
C7 Y1 C6 Si2 123.0(3) . .
C10 Y1 C6 Si2 -126.5(3) . .
C9 Y1 C6 Si2 -162.1(3) . .
C8 Y1 C6 Si2 158.8(3) . .
C10 C6 C7 C8 1.4(4) . .
Si2 C6 C7 C8 166.0(3) . .
Y1 C6 C7 C8 -68.2(2) . .
C10 C6 C7 C11 -168.6(3) . .
Si2 C6 C7 C11 -4.0(5) . .
Y1 C6 C7 C11 121.7(3) . .
C10 C6 C7 Y1 69.6(2) . .
Si2 C6 C7 Y1 -125.7(3) . .
O1 Y1 C7 C8 132.3(2) 2_655 .
O2 Y1 C7 C8 -169.9(2) 2_655 .
C2 Y1 C7 C8 -21.8(3) . .
C2 Y1 C7 C8 -54.1(2) 2_655 .
C1 Y1 C7 C8 -88.7(2) 2_655 .
C1 Y1 C7 C8 5.7(3) . .
C30B Y1 C7 C8 169.1(3) 2_655 .
C6 Y1 C7 C8 115.4(3) . .
C10 Y1 C7 C8 76.3(2) . .
C9 Y1 C7 C8 36.6(2) . .
O1 Y1 C7 C6 16.9(3) 2_655 .
O2 Y1 C7 C6 74.7(2) 2_655 .
C2 Y1 C7 C6 -137.2(2) . .
C2 Y1 C7 C6 -169.5(2) 2_655 .
C1 Y1 C7 C6 155.8(2) 2_655 .
C1 Y1 C7 C6 -109.7(3) . .
C30B Y1 C7 C6 53.7(3) 2_655 .
C10 Y1 C7 C6 -39.2(2) . .
C9 Y1 C7 C6 -78.8(2) . .
C8 Y1 C7 C6 -115.4(3) . .
O1 Y1 C7 C11 -105.4(3) 2_655 .
O2 Y1 C7 C11 -47.7(3) 2_655 .
C2 Y1 C7 C11 100.4(3) . .
C2 Y1 C7 C11 68.1(3) 2_655 .
C1 Y1 C7 C11 33.5(3) 2_655 .
C1 Y1 C7 C11 128.0(3) . .
C30B Y1 C7 C11 -68.7(4) 2_655 .
C6 Y1 C7 C11 -122.3(4) . .
C10 Y1 C7 C11 -161.5(4) . .
C9 Y1 C7 C11 158.9(4) . .
C8 Y1 C7 C11 122.2(4) . .
C6 C7 C8 C9 -0.6(4) . .
C11 C7 C8 C9 169.6(3) . .
Y1 C7 C8 C9 -67.5(3) . .
C6 C7 C8 C12 -173.4(3) . .
C11 C7 C8 C12 -3.3(6) . .
Y1 C7 C8 C12 119.6(3) . .
C6 C7 C8 Y1 67.0(2) . .
C11 C7 C8 Y1 -122.9(3) . .
O1 Y1 C8 C7 -72.8(3) 2_655 .
O2 Y1 C8 C7 13.4(3) 2_655 .
C2 Y1 C8 C7 160.7(2) . .
C2 Y1 C8 C7 127.9(2) 2_655 .
C1 Y1 C8 C7 101.2(2) 2_655 .
C1 Y1 C8 C7 -176.3(2) . .
C30B Y1 C8 C7 -21.2(5) 2_655 .
C6 Y1 C8 C7 -36.8(2) . .
C10 Y1 C8 C7 -77.6(2) . .
C9 Y1 C8 C7 -114.5(3) . .
O1 Y1 C8 C9 41.6(3) 2_655 .
O2 Y1 C8 C9 127.9(2) 2_655 .
C2 Y1 C8 C9 -84.9(2) . .
C2 Y1 C8 C9 -117.6(2) 2_655 .
C1 Y1 C8 C9 -144.4(2) 2_655 .
C1 Y1 C8 C9 -61.8(2) . .
C30B Y1 C8 C9 93.3(5) 2_655 .
C6 Y1 C8 C9 77.7(2) . .
C7 Y1 C8 C9 114.5(3) . .
C10 Y1 C8 C9 36.9(2) . .
O1 Y1 C8 C12 163.4(3) 2_655 .
O2 Y1 C8 C12 -110.3(3) 2_655 .
C2 Y1 C8 C12 36.9(3) . .
C2 Y1 C8 C12 4.2(3) 2_655 .
C1 Y1 C8 C12 -22.6(3) 2_655 .
C1 Y1 C8 C12 59.9(3) . .
C30B Y1 C8 C12 -145.0(5) 2_655 .
C6 Y1 C8 C12 -160.6(4) . .
C7 Y1 C8 C12 -123.8(4) . .
C10 Y1 C8 C12 158.6(4) . .
C9 Y1 C8 C12 121.8(4) . .
C7 C8 C9 C10 -0.5(4) . .
C12 C8 C9 C10 172.5(3) . .
Y1 C8 C9 C10 -67.4(2) . .
C7 C8 C9 C13 -171.1(3) . .
C12 C8 C9 C13 1.9(6) . .
Y1 C8 C9 C13 122.0(3) . .
C7 C8 C9 Y1 66.9(3) . .
C12 C8 C9 Y1 -120.1(3) . .
O1 Y1 C9 C10 -38.1(2) 2_655 .
O2 Y1 C9 C10 28.8(3) 2_655 .
C2 Y1 C9 C10 -152.2(2) . .
C2 Y1 C9 C10 177.7(2) 2_655 .
C1 Y1 C9 C10 160.3(2) 2_655 .
C1 Y1 C9 C10 -120.5(2) . .
C30B Y1 C9 C10 -21.5(4) 2_655 .
C6 Y1 C9 C10 36.8(2) . .
C7 Y1 C9 C10 77.3(2) . .
C8 Y1 C9 C10 114.1(3) . .
O1 Y1 C9 C8 -152.2(2) 2_655 .
O2 Y1 C9 C8 -85.2(3) 2_655 .
C2 Y1 C9 C8 93.7(2) . .
C2 Y1 C9 C8 63.6(2) 2_655 .
C1 Y1 C9 C8 46.3(3) 2_655 .
C1 Y1 C9 C8 125.4(2) . .
C30B Y1 C9 C8 -135.6(3) 2_655 .
C6 Y1 C9 C8 -77.3(2) . .
C7 Y1 C9 C8 -36.7(2) . .
C10 Y1 C9 C8 -114.1(3) . .
O1 Y1 C9 C13 86.5(3) 2_655 .
O2 Y1 C9 C13 153.5(3) 2_655 .
C2 Y1 C9 C13 -27.6(3) . .
C2 Y1 C9 C13 -57.7(3) 2_655 .
C1 Y1 C9 C13 -75.0(3) 2_655 .
C1 Y1 C9 C13 4.1(3) . .
C30B Y1 C9 C13 103.1(4) 2_655 .
C6 Y1 C9 C13 161.4(4) . .
C7 Y1 C9 C13 -158.0(4) . .
C10 Y1 C9 C13 124.6(4) . .
C8 Y1 C9 C13 -121.3(4) . .
C8 C9 C10 C6 1.4(4) . .
C13 C9 C10 C6 171.6(3) . .
Y1 C9 C10 C6 -66.5(2) . .
C8 C9 C10 C14 -174.5(3) . .
C13 C9 C10 C14 -4.3(6) . .
Y1 C9 C10 C14 117.6(3) . .
C8 C9 C10 Y1 67.9(2) . .
C13 C9 C10 Y1 -121.8(4) . .
C7 C6 C10 C9 -1.7(4) . .
Si2 C6 C10 C9 -165.8(3) . .
Y1 C6 C10 C9 67.8(2) . .
C7 C6 C10 C14 174.1(3) . .
Si2 C6 C10 C14 10.0(5) . .
Y1 C6 C10 C14 -116.4(4) . .
C7 C6 C10 Y1 -69.5(2) . .
Si2 C6 C10 Y1 126.4(3) . .
O1 Y1 C10 C9 146.1(2) 2_655 .
O2 Y1 C10 C9 -161.7(2) 2_655 .
C2 Y1 C10 C9 30.3(2) . .
C2 Y1 C10 C9 -2.9(3) 2_655 .
C1 Y1 C10 C9 -39.9(4) 2_655 .
C1 Y1 C10 C9 66.5(2) . .
C30B Y1 C10 C9 165.9(3) 2_655 .
C6 Y1 C10 C9 -115.7(3) . .
C7 Y1 C10 C9 -76.7(2) . .
C8 Y1 C10 C9 -36.9(2) . .
O1 Y1 C10 C6 -98.2(2) 2_655 .
O2 Y1 C10 C6 -46.0(2) 2_655 .
C2 Y1 C10 C6 146.0(2) . .
C2 Y1 C10 C6 112.8(2) 2_655 .
C1 Y1 C10 C6 75.9(4) 2_655 .
C1 Y1 C10 C6 -177.8(2) . .
C30B Y1 C10 C6 -78.4(3) 2_655 .
C7 Y1 C10 C6 39.0(2) . .
C9 Y1 C10 C6 115.7(3) . .
C8 Y1 C10 C6 78.8(2) . .
O1 Y1 C10 C14 24.7(3) 2_655 .
O2 Y1 C10 C14 76.8(3) 2_655 .
C2 Y1 C10 C14 -91.2(3) . .
C2 Y1 C10 C14 -124.4(3) 2_655 .
C1 Y1 C10 C14 -161.3(3) 2_655 .
C1 Y1 C10 C14 -54.9(3) . .
C30B Y1 C10 C14 44.5(4) 2_655 .
C6 Y1 C10 C14 122.8(4) . .
C7 Y1 C10 C14 161.8(4) . .
C9 Y1 C10 C14 -121.4(4) . .
C8 Y1 C10 C14 -158.4(4) . .
C28 Si3 C18 C19 160.4(3) . .
C29 Si3 C18 C19 39.5(4) . .
C27 Si3 C18 C19 -79.6(4) . .
C28 Si3 C18 C22 -41.9(4) . .
C29 Si3 C18 C22 -162.8(3) . .
C27 Si3 C18 C22 78.1(4) . .
C28 Si3 C18 Y2 60.7(3) . .
C29 Si3 C18 Y2 -60.3(3) . .
C27 Si3 C18 Y2 -179.3(2) . .
O1 Y2 C18 C19 35.8(3) 2_655 .
O2 Y2 C18 C19 -104.4(2) . .
O3 Y2 C18 C19 -49.1(2) . .
O3 Y2 C18 C19 -26.0(2) 2_655 .
C1 Y2 C18 C19 -176.4(2) . .
C20 Y2 C18 C19 35.5(2) . .
C22 Y2 C18 C19 110.8(3) . .
C21 Y2 C18 C19 74.7(2) . .
C30B Y2 C18 C19 0.0(3) 2_655 .
C30B Y2 C18 C19 -78.3(3) . .
O1 Y2 C18 C22 -74.9(2) 2_655 .
O2 Y2 C18 C22 144.8(2) . .
O3 Y2 C18 C22 -159.9(2) . .
O3 Y2 C18 C22 -136.8(2) 2_655 .
C1 Y2 C18 C22 72.8(3) . .
C19 Y2 C18 C22 -110.8(3) . .
C20 Y2 C18 C22 -75.3(2) . .
C21 Y2 C18 C22 -36.1(2) . .
C30B Y2 C18 C22 -110.7(3) 2_655 .
C30B Y2 C18 C22 170.9(3) . .
O1 Y2 C18 Si3 159.06(18) 2_655 .
O2 Y2 C18 Si3 18.8(2) . .
O3 Y2 C18 Si3 74.1(2) . .
O3 Y2 C18 Si3 97.2(2) 2_655 .
C1 Y2 C18 Si3 -53.2(3) . .
C19 Y2 C18 Si3 123.2(3) . .
C20 Y2 C18 Si3 158.7(3) . .
C22 Y2 C18 Si3 -126.0(3) . .
C21 Y2 C18 Si3 -162.1(3) . .
C30B Y2 C18 Si3 123.3(3) 2_655 .
C30B Y2 C18 Si3 44.9(3) . .
C22 C18 C19 C20 1.7(4) . .
Si3 C18 C19 C20 163.3(3) . .
Y2 C18 C19 C20 -68.0(3) . .
C22 C18 C19 C23 -171.8(3) . .
Si3 C18 C19 C23 -10.2(5) . .
Y2 C18 C19 C23 118.5(4) . .
C22 C18 C19 Y2 69.7(2) . .
Si3 C18 C19 Y2 -128.7(3) . .
O1 Y2 C19 C20 -36.2(2) 2_655 .
O2 Y2 C19 C20 -165.3(2) . .
O3 Y2 C19 C20 -112.7(2) . .
O3 Y2 C19 C20 -88.8(2) 2_655 .
C1 Y2 C19 C20 168(2) . .
C18 Y2 C19 C20 115.9(3) . .
C22 Y2 C19 C20 77.0(2) . .
C21 Y2 C19 C20 36.9(2) . .
C30B Y2 C19 C20 -64.1(3) 2_655 .
C30B Y2 C19 C20 -137.6(3) . .
O1 Y2 C19 C18 -152.1(2) 2_655 .
O2 Y2 C19 C18 78.8(2) . .
O3 Y2 C19 C18 131.4(2) . .
O3 Y2 C19 C18 155.4(2) 2_655 .
C1 Y2 C19 C18 52(3) . .
C20 Y2 C19 C18 -115.9(3) . .
C22 Y2 C19 C18 -38.87(19) . .
C21 Y2 C19 C18 -78.9(2) . .
C30B Y2 C19 C18 -180.0(3) 2_655 .
C30B Y2 C19 C18 106.5(3) . .
O1 Y2 C19 C23 84.8(3) 2_655 .
O2 Y2 C19 C23 -44.2(3) . .
O3 Y2 C19 C23 8.4(3) . .
O3 Y2 C19 C23 32.3(3) 2_655 .
C1 Y2 C19 C23 -71(3) . .
C18 Y2 C19 C23 -123.1(4) . .
C20 Y2 C19 C23 121.1(4) . .
C22 Y2 C19 C23 -161.9(4) . .
C21 Y2 C19 C23 158.0(4) . .
C30B Y2 C19 C23 57.0(3) 2_655 .
C30B Y2 C19 C23 -16.5(3) . .
C18 C19 C20 C21 -1.5(4) . .
C23 C19 C20 C21 172.2(3) . .
Y2 C19 C20 C21 -68.8(3) . .
C18 C19 C20 C24 -173.9(4) . .
C23 C19 C20 C24 -0.2(6) . .
Y2 C19 C20 C24 118.7(4) . .
C18 C19 C20 Y2 67.3(3) . .
C23 C19 C20 Y2 -119.0(3) . .
O1 Y2 C20 C19 143.8(2) 2_655 .
O2 Y2 C20 C19 18.6(3) . .
O3 Y2 C20 C19 65.9(2) . .
O3 Y2 C20 C19 87.0(2) 2_655 .
C1 Y2 C20 C19 -178.9(2) . .
C18 Y2 C20 C19 -36.5(2) . .
C22 Y2 C20 C19 -76.9(2) . .
C21 Y2 C20 C19 -114.0(3) . .
C30B Y2 C20 C19 115.9(3) 2_655 .
C30B Y2 C20 C19 48.6(3) . .
O1 Y2 C20 C21 -102.2(2) 2_655 .
O2 Y2 C20 C21 132.6(2) . .
O3 Y2 C20 C21 179.9(2) . .
O3 Y2 C20 C21 -158.9(3) 2_655 .
C1 Y2 C20 C21 -64.9(3) . .
C18 Y2 C20 C21 77.5(2) . .
C19 Y2 C20 C21 114.0(3) . .
C22 Y2 C20 C21 37.1(2) . .
C30B Y2 C20 C21 -130.1(3) 2_655 .
C30B Y2 C20 C21 162.6(3) . .
O1 Y2 C20 C24 20.1(3) 2_655 .
O2 Y2 C20 C24 -105.1(3) . .
O3 Y2 C20 C24 -57.8(3) . .
O3 Y2 C20 C24 -36.6(3) 2_655 .
C1 Y2 C20 C24 57.4(5) . .
C18 Y2 C20 C24 -160.1(4) . .
C19 Y2 C20 C24 -123.7(5) . .
C22 Y2 C20 C24 159.4(4) . .
C21 Y2 C20 C24 122.3(5) . .
C30B Y2 C20 C24 -7.8(4) 2_655 .
C30B Y2 C20 C24 -75.0(4) . .
C19 C20 C21 C22 0.6(4) . .
C24 C20 C21 C22 173.2(4) . .
Y2 C20 C21 C22 -67.3(3) . .
C19 C20 C21 C25 -172.1(3) . .
C24 C20 C21 C25 0.6(6) . .
Y2 C20 C21 C25 120.0(4) . .
C19 C20 C21 Y2 67.9(3) . .
C24 C20 C21 Y2 -119.5(4) . .
O1 Y2 C21 C20 73.5(2) 2_655 .
O2 Y2 C21 C20 -75.7(3) . .
O3 Y2 C21 C20 -0.1(3) . .
O3 Y2 C21 C20 22.4(3) 2_655 .
C1 Y2 C21 C20 145.7(2) . .
C18 Y2 C21 C20 -77.2(2) . .
C19 Y2 C21 C20 -36.8(2) . .
C22 Y2 C21 C20 -114.0(3) . .
C30B Y2 C21 C20 51.1(3) 2_655 .
C30B Y2 C21 C20 -27.4(4) . .
O1 Y2 C21 C22 -172.5(3) 2_655 .
O2 Y2 C21 C22 38.4(3) . .
O3 Y2 C21 C22 113.9(3) . .
O3 Y2 C21 C22 136.4(3) 2_655 .
C1 Y2 C21 C22 -100.3(3) . .
C18 Y2 C21 C22 36.8(2) . .
C19 Y2 C21 C22 77.2(2) . .
C20 Y2 C21 C22 114.0(3) . .
C30B Y2 C21 C22 165.1(3) 2_655 .
C30B Y2 C21 C22 86.6(4) . .
O1 Y2 C21 C25 -47.4(3) 2_655 .
O2 Y2 C21 C25 163.5(3) . .
O3 Y2 C21 C25 -121.0(3) . .
O3 Y2 C21 C25 -98.5(3) 2_655 .
C1 Y2 C21 C25 24.8(4) . .
C18 Y2 C21 C25 162.0(4) . .
C19 Y2 C21 C25 -157.7(4) . .
C20 Y2 C21 C25 -120.9(4) . .
C22 Y2 C21 C25 125.1(5) . .
C30B Y2 C21 C25 -69.7(4) 2_655 .
C30B Y2 C21 C25 -148.3(4) . .
C20 C21 C22 C18 0.5(4) . .
C25 C21 C22 C18 172.8(4) . .
Y2 C21 C22 C18 -66.7(3) . .
C20 C21 C22 C26 -168.1(3) . .
C25 C21 C22 C26 4.2(6) . .
Y2 C21 C22 C26 124.6(4) . .
C20 C21 C22 Y2 67.3(3) . .
C25 C21 C22 Y2 -120.4(4) . .
C19 C18 C22 C21 -1.4(4) . .
Si3 C18 C22 C21 -162.6(3) . .
Y2 C18 C22 C21 67.8(3) . .
C19 C18 C22 C26 167.0(4) . .
Si3 C18 C22 C26 5.8(6) . .
Y2 C18 C22 C26 -123.8(4) . .
C19 C18 C22 Y2 -69.2(2) . .
Si3 C18 C22 Y2 129.6(3) . .
O1 Y2 C22 C21 8.2(3) 2_655 .
O2 Y2 C22 C21 -155.5(2) . .
O3 Y2 C22 C21 -88.9(3) . .
O3 Y2 C22 C21 -57.7(3) 2_655 .
C1 Y2 C22 C21 106.9(3) . .
C18 Y2 C22 C21 -115.1(3) . .
C19 Y2 C22 C21 -76.3(3) . .
C20 Y2 C22 C21 -36.8(2) . .
C30B Y2 C22 C21 -19.6(4) 2_655 .
C30B Y2 C22 C21 -127.3(3) . .
O1 Y2 C22 C18 123.3(2) 2_655 .
O2 Y2 C22 C18 -40.4(2) . .
O3 Y2 C22 C18 26.2(3) . .
O3 Y2 C22 C18 57.3(3) 2_655 .
C1 Y2 C22 C18 -138.1(2) . .
C19 Y2 C22 C18 38.7(2) . .
C20 Y2 C22 C18 78.3(2) . .
C21 Y2 C22 C18 115.1(3) . .
C30B Y2 C22 C18 95.4(3) 2_655 .
C30B Y2 C22 C18 -12.2(3) . .
O1 Y2 C22 C26 -113.6(3) 2_655 .
O2 Y2 C22 C26 82.7(3) . .
O3 Y2 C22 C26 149.3(3) . .
O3 Y2 C22 C26 -179.5(3) 2_655 .
C1 Y2 C22 C26 -15.0(4) . .
C18 Y2 C22 C26 123.1(4) . .
C19 Y2 C22 C26 161.9(4) . .
C20 Y2 C22 C26 -158.6(4) . .
C21 Y2 C22 C26 -121.8(4) . .
C30B Y2 C22 C26 -141.4(4) 2_655 .
C30B Y2 C22 C26 110.9(4) . .
C30B O1 C30A O2 -47.5(7) . .
Y2 O1 C30A O2 -91.4(5) 2_655 .
Y1 O1 C30A O2 22.5(5) 2_655 .
C30B O1 C30A Y1 -70.0(8) . 2_655
Y2 O1 C30A Y1 -113.9(3) 2_655 2_655
C30B O2 C30A O1 48.0(7) . .
Y2 O2 C30A O1 89.6(5) . .
Y1 O2 C30A O1 -21.7(5) 2_655 .
C30B O2 C30A Y1 69.6(9) . 2_655
Y2 O2 C30A Y1 111.3(3) . 2_655
C30A O2 C30B O1 -69.5(9) . .
Y2 O2 C30B O1 144.2(7) . .
Y1 O2 C30B O1 39.2(7) 2_655 .
C30A O2 C30B O3 128.0(12) . .
Y2 O2 C30B O3 -18.3(6) . .
Y1 O2 C30B O3 -123.3(6) 2_655 .
C30A O2 C30B Y1 -108.6(9) . 2_655
Y2 O2 C30B Y1 105.02(10) . 2_655
C30A O2 C30B Y2 -152.2(17) . 2_655
Y2 O2 C30B Y2 61.4(10) . 2_655
Y1 O2 C30B Y2 -43.6(10) 2_655 2_655
C30A O2 C30B Y2 146.4(8) . .
Y1 O2 C30B Y2 -105.02(10) 2_655 .
C30A O1 C30B O2 69.9(9) . .
Y2 O1 C30B O2 -145.5(7) 2_655 .
Y1 O1 C30B O2 -40.3(7) 2_655 .
C30A O1 C30B O3 -128.0(12) . .
Y2 O1 C30B O3 16.6(7) 2_655 .
Y1 O1 C30B O3 121.8(6) 2_655 .
C30A O1 C30B Y1 110.2(8) . 2_655
Y2 O1 C30B Y1 -105.20(10) 2_655 2_655
C30A O1 C30B Y2 -144.6(8) . 2_655
Y1 O1 C30B Y2 105.20(10) 2_655 2_655
C30A O1 C30B Y2 153.8(15) . .
Y2 O1 C30B Y2 -61.5(9) 2_655 .
Y1 O1 C30B Y2 43.7(9) 2_655 .
O3 O3 C30B O2 91.5(18) 2_655 .
Y2 O3 C30B O2 17.7(6) . .
Y2 O3 C30B O2 148.2(6) 2_655 .
O3 O3 C30B O1 -72.3(19) 2_655 .
Y2 O3 C30B O1 -146.0(6) . .
Y2 O3 C30B O1 -15.6(6) 2_655 .
O3 O3 C30B Y1 8(2) 2_655 2_655
Y2 O3 C30B Y1 -65.7(6) . 2_655
Y2 O3 C30B Y1 64.7(6) 2_655 2_655
O3 O3 C30B Y2 -56.7(16) 2_655 2_655
Y2 O3 C30B Y2 -130.42(18) . 2_655
O3 O3 C30B Y2 73.7(16) 2_655 .
Y2 O3 C30B Y2 130.42(18) 2_655 .
O1 Y2 C30B O2 155.9(3) 2_655 .
O3 Y2 C30B O2 -161.0(7) . .
O3 Y2 C30B O2 -175.8(5) 2_655 .
C1 Y2 C30B O2 77.3(3) . .
C18 Y2 C30B O2 -70.4(4) . .
C19 Y2 C30B O2 -100.7(4) . .
C20 Y2 C30B O2 -122.8(3) . .
C22 Y2 C30B O2 -64.0(4) . .
C21 Y2 C30B O2 -107.9(4) . .
C30B Y2 C30B O2 164.0(3) 2_655 .
O1 Y2 C30B O1 51.7(10) 2_655 .
O2 Y2 C30B O1 -104.2(11) . .
O3 Y2 C30B O1 94.8(10) . .
O3 Y2 C30B O1 80.0(10) 2_655 .
C1 Y2 C30B O1 -26.9(9) . .
C18 Y2 C30B O1 -174.6(9) . .
C19 Y2 C30B O1 155.1(9) . .
C20 Y2 C30B O1 133.0(9) . .
C22 Y2 C30B O1 -168.2(8) . .
C21 Y2 C30B O1 147.9(8) . .
C30B Y2 C30B O1 59.8(10) 2_655 .
O1 Y2 C30B O3 -43.1(4) 2_655 .
O2 Y2 C30B O3 161.0(7) . .
O3 Y2 C30B O3 -14.8(3) 2_655 .
C1 Y2 C30B O3 -121.7(4) . .
C18 Y2 C30B O3 90.6(4) . .
C19 Y2 C30B O3 60.3(4) . .
C20 Y2 C30B O3 38.2(4) . .
C22 Y2 C30B O3 97.0(4) . .
C21 Y2 C30B O3 53.1(5) . .
C30B Y2 C30B O3 -35.0(5) 2_655 .
O1 Y2 C30B Y1 90.86(18) 2_655 2_655
O2 Y2 C30B Y1 -65.0(3) . 2_655
O3 Y2 C30B Y1 134.0(5) . 2_655
O3 Y2 C30B Y1 119.2(3) 2_655 2_655
C1 Y2 C30B Y1 12.34(17) . 2_655
C18 Y2 C30B Y1 -135.43(17) . 2_655
C19 Y2 C30B Y1 -165.66(18) . 2_655
C20 Y2 C30B Y1 172.19(13) . 2_655
C22 Y2 C30B Y1 -129.02(19) . 2_655
C21 Y2 C30B Y1 -172.86(16) . 2_655
C30B Y2 C30B Y1 99.0(2) 2_655 2_655
O1 Y2 C30B Y2 1.7(2) 2_655 2_655
O2 Y2 C30B Y2 -154.1(5) . 2_655
O3 Y2 C30B Y2 44.9(3) . 2_655
O3 Y2 C30B Y2 30.04(19) 2_655 2_655
C1 Y2 C30B Y2 -76.8(2) . 2_655
C18 Y2 C30B Y2 135.4(2) . 2_655
C19 Y2 C30B Y2 105.2(2) . 2_655
C20 Y2 C30B Y2 83.0(3) . 2_655
C22 Y2 C30B Y2 141.84(18) . 2_655
C21 Y2 C30B Y2 98.0(3) . 2_655
C30B Y2 C30B Y2 9.8(3) 2_655 2_655
