#------------------------------------------------------------------------------
#$Date: 2016-03-22 11:58:54 +0200 (Tue, 22 Mar 2016) $
#$Revision: 178927 $
#$URL: svn://www.crystallography.net/cod/cif/4/11/56/4115644.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4115644
loop_
_publ_author_name
'Quan-Ming Wang'
'Thomas C. W. Mak'
_publ_section_title
;
 Argentophilicity and Solvent-Induced Structural Diversity in Double Salts
 of Silver Acetylide with Silver Perfluoroalkyl Carboxylates
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              7594
_journal_page_last               7600
_journal_paper_doi               10.1021/ja0043441
_journal_volume                  123
_journal_year                    2001
_chemical_formula_sum            'C26 H10 Ag8 F30 N2 O12'
_chemical_formula_weight         1975.32
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.486(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.685(3)
_cell_length_b                   16.439(4)
_cell_length_c                   25.220(6)
_cell_measurement_temperature    293(2)
_cell_volume                     4836(2)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0724
_diffrn_reflns_av_sigmaI/netI    0.1048
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            32153
_diffrn_reflns_theta_full        28.12
_diffrn_reflns_theta_max         28.12
_diffrn_reflns_theta_min         1.62
_exptl_absorpt_coefficient_mu    3.339
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.458
_exptl_absorpt_correction_type   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.713
_exptl_crystal_description       block
_exptl_crystal_F_000             3688
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.892
_refine_diff_density_min         -0.910
_refine_diff_density_rms         0.150
_refine_ls_extinction_coef       0.00013(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.864
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     704
_refine_ls_number_reflns         11707
_refine_ls_number_restraints     63
_refine_ls_restrained_S_all      0.867
_refine_ls_R_factor_all          0.1365
_refine_ls_R_factor_gt           0.0504
_refine_ls_shift/su_max          0.016
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0666P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1160
_refine_ls_wR_factor_ref         0.1442
_reflns_number_gt                5001
_reflns_number_total             11707
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja0043441_6.cif
_cod_data_source_block           compound6
_cod_original_cell_volume        4835.6(19)
_cod_database_code               4115644
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag -0.04402(5) 0.42657(4) 0.47753(3) 0.0605(2) Uani 1 1 d .
Ag2 Ag 0.12568(6) 0.30563(4) 0.48914(3) 0.0625(2) Uani 1 1 d .
Ag3 Ag 0.34514(6) 0.37125(5) 0.53408(3) 0.0645(2) Uani 1 1 d .
Ag4 Ag 0.26854(6) 0.55585(5) 0.59151(3) 0.0628(2) Uani 1 1 d .
Ag5 Ag 0.19147(6) 0.50414(6) 0.41473(3) 0.0699(3) Uani 1 1 d .
Ag6 Ag 0.11404(7) 0.39801(6) 0.58942(3) 0.0760(3) Uani 1 1 d .
Ag7 Ag 0.37173(6) 0.55222(5) 0.49429(3) 0.0639(2) Uani 1 1 d .
Ag8 Ag 0.03322(8) 0.11123(5) 0.52416(4) 0.0902(3) Uani 1 1 d .
C1 C 0.1491(7) 0.4379(6) 0.5005(4) 0.054(2) Uani 1 1 d .
C2 C 0.2234(7) 0.4828(6) 0.5157(4) 0.060(3) Uani 1 1 d .
O11 O 0.5222(5) 0.4241(4) 0.5769(3) 0.0668(18) Uani 1 1 d .
O12 O 0.6604(5) 0.4661(5) 0.6352(3) 0.076(2) Uani 1 1 d .
C11 C 0.5649(7) 0.4388(6) 0.6244(4) 0.060(3) Uani 1 1 d D
C12 C 0.4932(6) 0.4307(8) 0.6726(3) 0.109(5) Uani 1 1 d D
F11 F 0.5154(10) 0.4832(7) 0.7131(4) 0.188(5) Uani 1 1 d D
F12 F 0.3828(5) 0.4303(5) 0.6562(3) 0.122(3) Uani 1 1 d D
C13 C 0.5143(9) 0.3496(8) 0.7013(4) 0.189(11) Uani 1 1 d D
F13 F 0.4473(9) 0.3518(8) 0.7419(4) 0.202(6) Uani 1 1 d D
F14 F 0.6210(8) 0.3534(8) 0.7221(4) 0.201(6) Uani 1 1 d D
F15 F 0.4879(10) 0.2997(7) 0.6610(4) 0.174(5) Uani 1 1 d D
O21 O 0.2070(5) 0.1835(4) 0.5128(3) 0.072(2) Uani 1 1 d .
O22 O 0.3669(6) 0.2383(4) 0.5502(3) 0.089(2) Uani 1 1 d .
C21 C 0.3026(9) 0.1806(5) 0.5381(5) 0.070(3) Uani 1 1 d D
C22 C 0.3385(10) 0.0939(5) 0.5511(5) 0.123(6) Uani 1 1 d D
F21 F 0.3313(11) 0.0424(6) 0.5102(5) 0.198(6) Uani 1 1 d D
F22 F 0.2716(10) 0.0643(6) 0.5874(5) 0.194(5) Uani 1 1 d D
C23 C 0.4598(11) 0.0816(6) 0.5761(5) 0.220(14) Uani 1 1 d D
F23 F 0.4718(10) 0.0019(6) 0.5822(6) 0.222(6) Uani 1 1 d D
F24 F 0.5169(13) 0.1067(8) 0.5356(8) 0.270(10) Uani 1 1 d D
F25 F 0.4528(18) 0.1240(8) 0.6204(5) 0.282(11) Uani 1 1 d D
O31 O 0.5666(5) 0.3755(5) 0.3846(3) 0.073(2) Uani 1 1 d .
O32 O 0.4837(5) 0.3753(4) 0.4610(3) 0.0683(19) Uani 1 1 d .
C31 C 0.4926(7) 0.3547(6) 0.4143(5) 0.059(3) Uani 1 1 d D
C32 C 0.3969(5) 0.2999(5) 0.3922(4) 0.077(3) Uani 1 1 d D
F31 F 0.4047(7) 0.2272(5) 0.4151(3) 0.135(3) Uani 1 1 d D
F32 F 0.2938(5) 0.3287(5) 0.4010(3) 0.117(3) Uani 1 1 d D
C33 C 0.3896(7) 0.2818(5) 0.3328(4) 0.110(5) Uani 1 1 d D
F33 F 0.4819(7) 0.2412(5) 0.3201(4) 0.144(3) Uani 1 1 d D
F34 F 0.2999(6) 0.2357(5) 0.3186(3) 0.130(3) Uani 1 1 d D
F35 F 0.3829(7) 0.3510(6) 0.3060(3) 0.129(3) Uani 1 1 d D
O41 O -0.0161(7) 0.2441(4) 0.5587(4) 0.097(3) Uani 1 1 d .
O42 O -0.0970(7) 0.3588(4) 0.5747(4) 0.096(3) Uani 1 1 d .
C41 C -0.0974(9) 0.2835(7) 0.5726(4) 0.070(3) Uani 1 1 d D
C42 C -0.2034(7) 0.2387(5) 0.5879(4) 0.100(4) Uani 1 1 d D
F41 F -0.2962(6) 0.2849(5) 0.5813(4) 0.141(3) Uani 1 1 d D
F42 F -0.2206(6) 0.1703(5) 0.5605(4) 0.127(3) Uani 1 1 d D
C43 C -0.1911(8) 0.2168(7) 0.6468(4) 0.121(5) Uani 1 1 d D
F43 F -0.1714(11) 0.2843(7) 0.6740(4) 0.200(6) Uani 1 1 d D
F44 F -0.2865(9) 0.1820(7) 0.6604(5) 0.207(6) Uani 1 1 d D
F45 F -0.1041(9) 0.1666(7) 0.6555(4) 0.176(5) Uani 1 1 d D
O51 O 0.0012(6) 0.5202(5) 0.6207(3) 0.079(2) Uani 1 1 d .
O52 O 0.1612(6) 0.5629(5) 0.6645(3) 0.091(3) Uani 1 1 d .
C51 C 0.0575(9) 0.5498(7) 0.6596(4) 0.070(3) Uani 1 1 d D
C52 C -0.0122(8) 0.5856(9) 0.7022(5) 0.154(8) Uani 1 1 d D
F51 F -0.1191(9) 0.6018(11) 0.6854(5) 0.274(10) Uani 1 1 d D
F52 F 0.0309(10) 0.6488(7) 0.7288(5) 0.208(6) Uani 1 1 d D
C53 C -0.0280(14) 0.5195(11) 0.7436(6) 0.271(14) Uani 1 1 d DU
F53 F -0.0889(13) 0.5473(14) 0.7819(5) 0.383(13) Uani 1 1 d DU
F54 F -0.0819(19) 0.4584(12) 0.7194(6) 0.324(11) Uani 1 1 d DU
F55 F 0.0743(15) 0.5003(14) 0.7647(6) 0.317(11) Uani 1 1 d DU
O61 O -0.0041(6) 0.2209(5) 0.4416(3) 0.094(3) Uani 1 1 d .
O62 O -0.1389(6) 0.3160(4) 0.4412(4) 0.096(3) Uani 1 1 d .
C61 C -0.1065(10) 0.2446(7) 0.4328(6) 0.101(4) Uani 1 1 d D
C62 C -0.2020(8) 0.1821(6) 0.4232(7) 0.229(16) Uani 1 1 d D
F61 F -0.3090(7) 0.2003(6) 0.4344(4) 0.143(3) Uani 1 1 d D
F62 F -0.1860(8) 0.1093(5) 0.4456(4) 0.144(4) Uani 1 1 d D
C63 C -0.2206(10) 0.1674(6) 0.3635(7) 0.37(3) Uani 1 1 d D
F63 F -0.1160(9) 0.1425(9) 0.3550(4) 0.203(5) Uani 1 1 d D
F64 F -0.2347(11) 0.2428(6) 0.3455(4) 0.176(4) Uani 1 1 d D
F65 F -0.3051(12) 0.1133(7) 0.3608(6) 0.256(8) Uani 1 1 d D
N1 N -0.0516(9) 0.0101(7) 0.5607(5) 0.106(4) Uani 1 1 d .
C3 C -0.1055(12) -0.0299(9) 0.5854(6) 0.111(5) Uani 1 1 d D
C4 C -0.1735(15) -0.0855(9) 0.6167(7) 0.146(7) Uani 1 1 d D
C5 C -0.232(2) -0.0370(11) 0.6559(9) 0.217(11) Uani 1 1 d D
N2 N 0.1613(10) 0.3146(8) 0.6562(6) 0.120(4) Uani 1 1 d .
C6 C 0.1852(13) 0.2599(12) 0.6856(6) 0.128(6) Uani 1 1 d D
C7 C 0.208(2) 0.2008(12) 0.7270(7) 0.182(9) Uani 1 1 d D
C8 C 0.1493(17) 0.1228(13) 0.7159(9) 0.193(10) Uani 1 1 d D
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O62 Ag1 C1 127.4(3) . .
O62 Ag1 C2 96.3(3) . 3_566
C1 Ag1 C2 136.3(3) . 3_566
O62 Ag1 C1 122.5(3) . 3_566
C1 Ag1 C1 110.0(2) . 3_566
C2 Ag1 C1 26.3(2) 3_566 3_566
O62 Ag1 Ag2 78.55(19) . .
C1 Ag1 Ag2 50.0(2) . .
C2 Ag1 Ag2 166.0(2) 3_566 .
C1 Ag1 Ag2 156.4(2) 3_566 .
O62 Ag1 Ag1 172.3(2) . 3_566
C1 Ag1 Ag1 60.3(2) . 3_566
C2 Ag1 Ag1 76.0(2) 3_566 3_566
C1 Ag1 Ag1 49.77(19) 3_566 3_566
Ag2 Ag1 Ag1 108.92(4) . 3_566
O62 Ag1 Ag4 58.16(19) . 3_566
C1 Ag1 Ag4 157.6(2) . 3_566
C2 Ag1 Ag4 46.8(2) 3_566 3_566
C1 Ag1 Ag4 69.2(2) 3_566 3_566
Ag2 Ag1 Ag4 134.28(4) . 3_566
Ag1 Ag1 Ag4 115.04(4) 3_566 3_566
O62 Ag1 Ag6 117.4(2) . .
C1 Ag1 Ag6 46.4(2) . .
C2 Ag1 Ag6 116.0(2) 3_566 .
C1 Ag1 Ag6 100.6(2) 3_566 .
Ag2 Ag1 Ag6 57.14(3) . .
Ag1 Ag1 Ag6 67.03(3) 3_566 .
Ag4 Ag1 Ag6 155.38(3) 3_566 .
C1 Ag2 O21 141.7(3) . .
C1 Ag2 O61 136.5(3) . .
O21 Ag2 O61 81.8(3) . .
C1 Ag2 Ag1 53.0(2) . .
O21 Ag2 Ag1 158.15(16) . .
O61 Ag2 Ag1 86.34(19) . .
C1 Ag2 Ag3 59.4(2) . .
O21 Ag2 Ag3 83.26(17) . .
O61 Ag2 Ag3 159.90(19) . .
Ag1 Ag2 Ag3 111.92(3) . .
C1 Ag2 Ag6 52.8(2) . .
O21 Ag2 Ag6 105.49(19) . .
O61 Ag2 Ag6 133.0(2) . .
Ag1 Ag2 Ag6 69.96(3) . .
Ag3 Ag2 Ag6 64.37(3) . .
O22 Ag3 C2 149.3(3) . .
O22 Ag3 O11 100.6(2) . .
C2 Ag3 O11 107.3(3) . .
O22 Ag3 O32 95.0(3) . .
C2 Ag3 O32 104.0(3) . .
O11 Ag3 O32 75.5(2) . .
O22 Ag3 C1 123.6(3) . .
C2 Ag3 C1 26.7(3) . .
O11 Ag3 C1 133.9(3) . .
O32 Ag3 C1 109.7(2) . .
O22 Ag3 Ag2 78.38(18) . .
C2 Ag3 Ag2 73.0(2) . .
O11 Ag3 Ag2 176.33(16) . .
O32 Ag3 Ag2 108.09(15) . .
C1 Ag3 Ag2 46.2(2) . .
O22 Ag3 Ag6 98.5(2) . .
C2 Ag3 Ag6 56.8(2) . .
O11 Ag3 Ag6 118.87(16) . .
O32 Ag3 Ag6 157.73(16) . .
C1 Ag3 Ag6 47.99(19) . .
Ag2 Ag3 Ag6 58.06(3) . .
O22 Ag3 Ag7 165.0(2) . .
C2 Ag3 Ag7 43.4(2) . .
O11 Ag3 Ag7 73.01(16) . .
O32 Ag3 Ag7 70.35(16) . .
C1 Ag3 Ag7 66.82(19) . .
Ag2 Ag3 Ag7 108.82(3) . .
Ag6 Ag3 Ag7 96.48(3) . .
O31 Ag4 O52 104.9(2) 3_666 .
O31 Ag4 C2 128.9(3) 3_666 .
O52 Ag4 C2 125.9(3) . .
O31 Ag4 Ag7 80.82(17) 3_666 .
O52 Ag4 Ag7 172.16(18) . .
C2 Ag4 Ag7 49.3(2) . .
O31 Ag4 Ag1 141.39(19) 3_666 3_566
O52 Ag4 Ag1 87.72(18) . 3_566
C2 Ag4 Ag1 55.4(2) . 3_566
Ag7 Ag4 Ag1 84.49(3) . 3_566
O31 Ag4 Ag6 151.97(19) 3_666 .
O52 Ag4 Ag6 73.4(2) . .
C2 Ag4 Ag6 56.9(2) . .
Ag7 Ag4 Ag6 104.13(3) . .
Ag1 Ag4 Ag6 66.45(3) 3_566 .
O12 Ag5 O51 124.2(2) 3_666 3_566
O12 Ag5 C1 141.0(3) 3_666 .
O51 Ag5 C1 91.1(3) 3_566 .
O12 Ag5 O42 102.7(3) 3_666 3_566
O51 Ag5 O42 77.5(3) 3_566 3_566
C1 Ag5 O42 100.7(3) . 3_566
O12 Ag5 C2 120.8(3) 3_666 .
O51 Ag5 C2 114.9(2) 3_566 .
C1 Ag5 C2 27.0(3) . .
O42 Ag5 C2 93.2(3) 3_566 .
O12 Ag5 Ag7 77.24(17) 3_666 .
O51 Ag5 Ag7 156.62(16) 3_566 .
C1 Ag5 Ag7 72.3(2) . .
O42 Ag5 Ag7 89.3(2) 3_566 .
C2 Ag5 Ag7 45.91(19) . .
N2 Ag6 C1 146.4(4) . .
N2 Ag6 O42 98.5(4) . .
C1 Ag6 O42 98.7(3) . .
N2 Ag6 O51 111.2(4) . .
C1 Ag6 O51 101.2(3) . .
O42 Ag6 O51 74.4(2) . .
N2 Ag6 C2 137.3(4) . .
C1 Ag6 C2 26.0(3) . .
O42 Ag6 C2 121.5(3) . .
O51 Ag6 C2 94.7(3) . .
N2 Ag6 Ag2 108.1(4) . .
C1 Ag6 Ag2 47.3(2) . .
O42 Ag6 Ag2 80.85(19) . .
O51 Ag6 Ag2 135.97(16) . .
C2 Ag6 Ag2 68.2(2) . .
N2 Ag6 Ag3 94.0(3) . .
C1 Ag6 Ag3 54.7(2) . .
O42 Ag6 Ag3 138.42(19) . .
O51 Ag6 Ag3 136.08(16) . .
C2 Ag6 Ag3 46.60(19) . .
Ag2 Ag6 Ag3 57.58(3) . .
N2 Ag6 Ag4 112.3(3) . .
C1 Ag6 Ag4 70.2(2) . .
O42 Ag6 Ag4 139.04(17) . .
O51 Ag6 Ag4 69.76(16) . .
C2 Ag6 Ag4 45.2(2) . .
Ag2 Ag6 Ag4 112.31(3) . .
Ag3 Ag6 Ag4 67.49(3) . .
N2 Ag6 Ag1 146.7(3) . .
C1 Ag6 Ag1 44.1(2) . .
O42 Ag6 Ag1 55.15(19) . .
O51 Ag6 Ag1 83.12(16) . .
C2 Ag6 Ag1 66.64(19) . .
Ag2 Ag6 Ag1 52.90(3) . .
Ag3 Ag6 Ag1 95.23(3) . .
Ag4 Ag6 Ag1 100.74(3) . .
C2 Ag7 O11 140.1(3) . 3_666
C2 Ag7 O32 136.3(3) . 3_666
O11 Ag7 O32 83.1(3) 3_666 3_666
C2 Ag7 Ag4 53.1(3) . .
O11 Ag7 Ag4 166.36(18) 3_666 .
O32 Ag7 Ag4 84.39(18) 3_666 .
C2 Ag7 Ag5 58.4(3) . .
O11 Ag7 Ag5 84.79(18) 3_666 .
O32 Ag7 Ag5 161.82(18) 3_666 .
Ag4 Ag7 Ag5 106.01(3) . .
C2 Ag7 Ag3 48.0(2) . .
O11 Ag7 Ag3 118.70(17) 3_666 .
O32 Ag7 Ag3 114.47(18) 3_666 .
Ag4 Ag7 Ag3 71.70(3) . .
Ag5 Ag7 Ag3 83.28(3) . .
N1 Ag8 O21 147.9(4) . .
N1 Ag8 O41 114.3(3) . .
O21 Ag8 O41 79.5(2) . .
C2 C1 Ag2 137.5(8) . .
C2 C1 Ag1 145.1(8) . .
Ag2 C1 Ag1 77.0(3) . .
C2 C1 Ag6 91.8(7) . .
Ag2 C1 Ag6 79.9(3) . .
Ag1 C1 Ag6 89.6(3) . .
C2 C1 Ag5 80.2(7) . .
Ag2 C1 Ag5 110.3(4) . .
Ag1 C1 Ag5 93.5(3) . .
Ag6 C1 Ag5 169.8(4) . .
C2 C1 Ag1 75.3(6) . 3_566
Ag2 C1 Ag1 144.0(4) . 3_566
Ag1 C1 Ag1 70.0(2) . 3_566
Ag6 C1 Ag1 85.8(3) . 3_566
Ag5 C1 Ag1 86.2(3) . 3_566
C2 C1 Ag3 63.2(6) . .
Ag2 C1 Ag3 74.3(3) . .
Ag1 C1 Ag3 150.1(4) . .
Ag6 C1 Ag3 77.3(3) . .
Ag5 C1 Ag3 104.2(3) . .
Ag1 C1 Ag3 134.1(4) 3_566 .
C1 C2 Ag7 145.8(9) . .
C1 C2 Ag4 136.3(8) . .
Ag7 C2 Ag4 77.6(3) . .
C1 C2 Ag3 90.1(7) . .
Ag7 C2 Ag3 88.7(3) . .
Ag4 C2 Ag3 98.0(3) . .
C1 C2 Ag5 72.9(7) . .
Ag7 C2 Ag5 75.7(3) . .
Ag4 C2 Ag5 139.9(4) . .
Ag3 C2 Ag5 110.6(4) . .
C1 C2 Ag1 78.4(6) . 3_566
Ag7 C2 Ag1 112.1(4) . 3_566
Ag4 C2 Ag1 77.8(3) . 3_566
Ag3 C2 Ag1 156.9(4) . 3_566
Ag5 C2 Ag1 85.3(3) . 3_566
C1 C2 Ag6 62.3(6) . .
Ag7 C2 Ag6 149.2(4) . .
Ag4 C2 Ag6 77.9(3) . .
Ag3 C2 Ag6 76.6(3) . .
Ag5 C2 Ag6 134.7(3) . .
Ag1 C2 Ag6 80.4(3) 3_566 .
C11 O11 Ag7 120.1(5) . 3_666
C11 O11 Ag3 138.4(5) . .
Ag7 O11 Ag3 101.5(3) 3_666 .
C11 O12 Ag5 132.8(6) . 3_666
O12 C11 O11 124.9(8) . .
O12 C11 C12 113.3(8) . .
O11 C11 C12 121.6(8) . .
F12 C12 F11 112.0(11) . .
F12 C12 C11 108.8(7) . .
F11 C12 C11 117.3(8) . .
F12 C12 C13 105.5(9) . .
F11 C12 C13 100.5(9) . .
C11 C12 C13 111.9(8) . .
F14 C13 F15 120.1(12) . .
F14 C13 F13 106.1(9) . .
F15 C13 F13 119.1(11) . .
F14 C13 C12 105.5(9) . .
F15 C13 C12 98.9(10) . .
F13 C13 C12 104.8(9) . .
C21 O21 Ag2 120.7(6) . .
C21 O21 Ag8 131.3(6) . .
Ag2 O21 Ag8 97.2(2) . .
C21 O22 Ag3 130.1(6) . .
O22 C21 O21 127.2(8) . .
O22 C21 C22 120.8(9) . .
O21 C21 C22 111.9(9) . .
F21 C22 F22 106.7(12) . .
F21 C22 C21 115.2(10) . .
F22 C22 C21 109.0(8) . .
F21 C22 C23 104.4(10) . .
F22 C22 C23 103.6(11) . .
C21 C22 C23 116.8(9) . .
F24 C23 F25 123.3(16) . .
F24 C23 F23 110.1(12) . .
F25 C23 F23 115.7(13) . .
F24 C23 C22 97.9(11) . .
F25 C23 C22 100.1(11) . .
F23 C23 C22 105.5(9) . .
C31 O31 Ag4 126.3(6) . 3_666
C31 O32 Ag7 120.4(5) . 3_666
C31 O32 Ag3 141.5(5) . .
Ag7 O32 Ag3 98.0(3) 3_666 .
O31 C31 O32 127.5(7) . .
O31 C31 C32 118.3(9) . .
O32 C31 C32 114.2(8) . .
F32 C32 F31 106.8(8) . .
F32 C32 C31 112.6(7) . .
F31 C32 C31 110.3(7) . .
F32 C32 C33 103.7(7) . .
F31 C32 C33 104.4(8) . .
C31 C32 C33 118.2(7) . .
F35 C33 F33 109.5(9) . .
F35 C33 F34 109.4(8) . .
F33 C33 F34 106.8(8) . .
F35 C33 C32 109.4(7) . .
F33 C33 C32 109.8(7) . .
F34 C33 C32 111.9(7) . .
C41 O41 Ag8 141.8(7) . .
C41 O42 Ag5 153.3(7) . 3_566
C41 O42 Ag6 105.0(7) . .
Ag5 O42 Ag6 100.6(3) 3_566 .
O41 C41 O42 122.8(8) . .
O41 C41 C42 118.7(9) . .
O42 C41 C42 118.5(9) . .
F41 C42 F42 108.8(8) . .
F41 C42 C41 111.5(8) . .
F42 C42 C41 112.4(8) . .
F41 C42 C43 106.5(8) . .
F42 C42 C43 107.9(8) . .
C41 C42 C43 109.4(8) . .
F43 C43 F44 110.7(11) . .
F43 C43 F45 109.3(12) . .
F44 C43 F45 109.9(11) . .
F43 C43 C42 108.2(9) . .
F44 C43 C42 109.0(9) . .
F45 C43 C42 109.6(9) . .
C51 O51 Ag5 142.6(6) . 3_566
C51 O51 Ag6 107.0(6) . .
Ag5 O51 Ag6 104.1(3) 3_566 .
C51 O52 Ag4 119.7(6) . .
O52 C51 O51 128.1(9) . .
O52 C51 C52 115.6(9) . .
O51 C51 C52 115.6(9) . .
F52 C52 F51 109.2(12) . .
F52 C52 C51 117.6(10) . .
F51 C52 C51 113.0(9) . .
F52 C52 C53 105.7(12) . .
F51 C52 C53 102.2(14) . .
C51 C52 C53 107.6(10) . .
F54 C53 F55 113.6(19) . .
F54 C53 F53 109.9(17) . .
F55 C53 F53 107.7(17) . .
F54 C53 C52 107.5(13) . .
F55 C53 C52 107.6(13) . .
F53 C53 C52 110.4(14) . .
C61 O61 Ag2 119.0(7) . .
C61 O62 Ag1 131.8(7) . .
O62 C61 O61 123.3(9) . .
O62 C61 C62 115.6(10) . .
O61 C61 C62 119.7(10) . .
F62 C62 F61 102.8(10) . .
F62 C62 C61 117.1(10) . .
F61 C62 C61 120.1(11) . .
F62 C62 C63 106.6(11) . .
F61 C62 C63 99.5(10) . .
C61 C62 C63 108.8(10) . .
F63 C63 F64 109.4(12) . .
F63 C63 F65 118.5(13) . .
F64 C63 F65 122.2(12) . .
F63 C63 C62 97.5(11) . .
F64 C63 C62 101.3(11) . .
F65 C63 C62 102.5(11) . .
C3 N1 Ag8 165.8(12) . .
N1 C3 C4 177.4(16) . .
C3 C4 C5 108.2(13) . .
C6 N2 Ag6 168.9(15) . .
N2 C6 C7 172(2) . .
C6 C7 C8 112.6(15) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 O62 2.291(7) .
Ag1 C1 2.303(8) .
Ag1 C2 2.586(9) 3_566
Ag1 C1 2.619(9) 3_566
Ag1 Ag2 2.8108(11) .
Ag1 Ag1 2.8335(15) 3_566
Ag1 Ag4 3.0729(11) 3_566
Ag1 Ag6 3.3107(13) .
Ag2 C1 2.209(9) .
Ag2 O21 2.285(6) .
Ag2 O61 2.336(7) .
Ag2 Ag3 2.9447(11) .
Ag2 Ag6 2.9603(13) .
Ag3 O22 2.234(7) .
Ag3 C2 2.349(9) .
Ag3 O11 2.435(7) .
Ag3 O32 2.527(7) .
Ag3 C1 2.633(9) .
Ag3 Ag6 3.1452(12) .
Ag3 Ag7 3.1610(13) .
Ag4 O31 2.282(6) 3_666
Ag4 O52 2.292(7) .
Ag4 C2 2.292(10) .
Ag4 Ag7 2.7978(12) .
Ag4 Ag1 3.0729(11) 3_566
Ag4 Ag6 3.1596(12) .
Ag5 O12 2.255(6) 3_666
Ag5 O51 2.405(7) 3_566
Ag5 C1 2.498(9) .
Ag5 O42 2.529(7) 3_566
Ag5 C2 2.575(10) .
Ag5 Ag7 2.9281(11) .
Ag6 N2 2.216(14) .
Ag6 C1 2.396(9) .
Ag6 O42 2.554(8) .
Ag6 O51 2.554(8) .
Ag6 C2 2.706(10) .
Ag7 C2 2.171(9) .
Ag7 O11 2.276(6) 3_666
Ag7 O32 2.305(6) 3_666
Ag8 N1 2.170(11) .
Ag8 O21 2.385(6) .
Ag8 O41 2.433(8) .
C1 C2 1.185(11) .
C1 Ag1 2.619(9) 3_566
C2 Ag1 2.586(9) 3_566
O11 C11 1.292(10) .
O11 Ag7 2.276(6) 3_666
O12 C11 1.218(10) .
O12 Ag5 2.255(6) 3_666
C11 C12 1.523(5) .
C12 F12 1.331(5) .
C12 F11 1.350(5) .
C12 C13 1.530(5) .
C13 F14 1.324(5) .
C13 F15 1.327(5) .
C13 F13 1.327(5) .
O21 C21 1.253(11) .
O22 C21 1.238(11) .
C21 C22 1.516(5) .
C22 F21 1.332(5) .
C22 F22 1.333(5) .
C22 C23 1.529(5) .
C23 F24 1.320(5) .
C23 F25 1.324(5) .
C23 F23 1.326(5) .
O31 C31 1.227(11) .
O31 Ag4 2.282(6) 3_666
O32 C31 1.237(11) .
O32 Ag7 2.305(6) 3_666
C31 C32 1.515(5) .
C32 F32 1.325(5) .
C32 F31 1.329(5) .
C32 C33 1.527(5) .
C33 F35 1.323(5) .
C33 F33 1.324(5) .
C33 F34 1.325(5) .
O41 C41 1.219(12) .
O42 C41 1.240(12) .
O42 Ag5 2.529(7) 3_566
C41 C42 1.510(5) .
C42 F41 1.326(5) .
C42 F42 1.329(5) .
C42 C43 1.526(5) .
C43 F43 1.316(5) .
C43 F44 1.317(5) .
C43 F45 1.318(5) .
O51 C51 1.246(11) .
O51 Ag5 2.405(7) 3_566
O52 C51 1.230(11) .
C51 C52 1.507(5) .
C52 F52 1.320(5) .
C52 F51 1.321(5) .
C52 C53 1.526(5) .
C53 F54 1.316(5) .
C53 F55 1.316(5) .
C53 F53 1.317(5) .
O61 C61 1.265(13) .
O62 C61 1.256(13) .
C61 C62 1.525(5) .
C62 F62 1.332(5) .
C62 F61 1.333(5) .
C62 C63 1.527(5) .
C63 F63 1.320(5) .
C63 F64 1.326(5) .
C63 F65 1.328(5) .
N1 C3 1.124(15) .
C3 C4 1.473(16) .
C4 C5 1.473(5) .
N2 C6 1.188(18) .
C6 C7 1.440(18) .
C7 C8 1.474(5) .
