#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/11/68/4116811.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4116811
loop_
_publ_author_name
'Ken Sakai'
'Yuko Tanaka'
'Yuriko Tsuchiya'
'Kentaro Hirata'
'Taro Tsubomura'
'Seiichiro Iijima'
'Ashis Bhattacharjee'
_publ_contact_author
;
    Dr Ken Sakai
    Department of Industrial Chemistry
    Faculty of Engineering
    Seikei University
    Kichijoji-Kitamachi
    Musashino, Tokyo 180
    Japan
;
_publ_contact_author_email       ksakai@ch.seikei.ac.jp
_publ_contact_author_fax         '+81 422 37 3871'
_publ_contact_author_phone       '+81 422 37 3759'
_publ_section_title
;
 New Structural Aspects of α-Pyrrolidinonate- and α-Pyridonate-Bridged,
 Homo- and Mixed-Valence, Di- and Tetranuclear cis-Diammineplatinum
 Complexes: Eight New Crystal Structures, Stoichiometric 1:1 Mixture of
 Pt(2.25+)4 and Pt(2.5+)4, New Quasi-One-Dimensional Halide-Bridged
 [Pt(2.5+)4-Cl...]∞ System, and Consideration of Solution Properties
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              8366
_journal_page_last               8379
_journal_paper_doi               10.1021/ja980019q
_journal_volume                  120
_journal_year                    1998
_chemical_formula_moiety         'C16 H48 N12 O4 Pt4, (N O3)2, (P F6)3'
_chemical_formula_sum            'C16 H48 F18 N14 O10 P3 Pt4'
_chemical_formula_weight         1811.90
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_audit_creation_date             1997-10-28
_audit_creation_method           'teXsan (modified by Ken Sakai)'
_audit_update_record
;
1997-10-28    text and data added by Ken Sakai
;
_cell_angle_alpha                90
_cell_angle_beta                 95.18(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4.00
_cell_length_a                   18.277(7)
_cell_length_b                   9.801(9)
_cell_length_c                   26.03(1)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.0
_cell_measurement_theta_max      59.28
_cell_measurement_theta_min      50.87
_cell_volume                     4644(5)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan: PROCESS (MSC)'
_computing_publication_material  'teXsan: FINISH (MSC)'
_computing_structure_refinement  'teXsan: LS (MSC)'
_computing_structure_solution    SAPI91
_diffrn_ambient_temperature      296.0
_diffrn_measurement_device       'Rigaku AFC5S'
_diffrn_measurement_method       θ/2θ
_diffrn_orient_matrix_UB_11      -0.01944
_diffrn_orient_matrix_UB_12      0.01103
_diffrn_orient_matrix_UB_13      -0.03693
_diffrn_orient_matrix_UB_21      -0.05130
_diffrn_orient_matrix_UB_22      0.00161
_diffrn_orient_matrix_UB_23      0.01049
_diffrn_orient_matrix_UB_31      0.00293
_diffrn_orient_matrix_UB_32      0.10142
_diffrn_orient_matrix_UB_33      0.00385
_diffrn_radiation_detector       'scintillation,NaI,Rigaku SC-30'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0964
_diffrn_reflns_av_sigmaI/netI    0.1000
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            3845
_diffrn_reflns_theta_max         60.00
_diffrn_reflns_theta_min         1.71
_diffrn_standards_decay_%        -0.79
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    24.216
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.8979
_exptl_absorpt_correction_type   refdelf
_exptl_absorpt_process_details   'DIFABS (Walker & Stuart, 1983)'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    2.5916
_exptl_crystal_description       plate
_exptl_crystal_F_000             3364.00
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.01
_refine_diff_density_max         2.05
_refine_diff_density_min         -3.07
_refine_ls_abs_structure_details
;
none
;
_refine_ls_extinction_coef       0.10(9)
_refine_ls_extinction_method     Zachariasen_type_2_gaussian_isotropic
_refine_ls_goodness_of_fit_obs   2.910
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     180
_refine_ls_number_reflns         2428
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1300
_refine_ls_R_factor_obs          0.0914
_refine_ls_shift/esd_max         0.0360
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma_w=1/\s^2^(F)+0.000400F^2^
_refine_ls_wR_factor_all         0.0932
_refine_ls_wR_factor_obs         0.0901
_reflns_number_observed          2428
_reflns_number_total             3698
_reflns_observed_criterion       I_>_2.0_sigma(I)
_cod_data_source_file            ja980019q_3.cif
_cod_data_source_block           complex5
_cod_original_formula_sum        'C16 F18 H48 N14 O10 P3 Pt4'
_cod_database_code               4116811
loop_
_symmetry_equiv_pos_as_xyz
'   +x,   +y,   +z'
'   -x,   +y,1/2-z'
'1/2+x,1/2+y,   +z'
1/2-x,1/2+y,1/2-z
'   -x,   -y,   -z'
'   +x,   -y,1/2+z'
'1/2-x,1/2-y,   -z'
1/2+x,1/2-y,1/2+z
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_calc_flag
_atom_site_calc_attached_atom
_atom_site_occupancy
_atom_site_refinement_flags
Pt(1) 0.79539(7) 0.1745(2) 0.53782(6) 0.0477(4) Uani d . 1.0 .
Pt(2) 0.87805(8) 0.0733(2) 0.62739(6) 0.0501(5) Uani d . 1.0 .
P(1) 0.8163(6) 0.155(1) 0.8694(5) 0.1183 Uiso d . 1.0 .
P(2) 1.0000 -0.144(2) 0.7500 0.066(5) Uani d . 0.5 S
F(1) 0.767(1) 0.198(3) 0.9107(9) 0.2456 Uiso d . 1.0 .
F(2) 0.866(1) 0.111(3) 0.8280(8) 0.2323 Uiso d . 1.0 .
F(3) 0.871(1) 0.266(2) 0.887(1) 0.3084 Uiso d . 1.0 .
F(4) 0.761(1) 0.043(2) 0.851(1) 0.2806 Uiso d . 1.0 .
F(5) 0.777(1) 0.255(3) 0.8313(10) 0.2425 Uiso d . 1.0 .
F(6) 0.856(1) 0.054(2) 0.9074(9) 0.2030 Uiso d . 1.0 .
F(7) 1.0000 -0.007(5) 0.7500 0.32(5) Uani d . 0.5 S
F(8) 1.0000 -0.290(5) 0.7500 0.23(3) Uani d . 0.5 S
F(9) 1.010(1) -0.146(3) 0.6908(9) 0.12(1) Uani d . 1.0 .
F(10) 1.083(1) -0.162(5) 0.763(1) 0.18(2) Uani d . 1.0 .
O(1) 0.841(1) 0.344(3) 0.5587(9) 0.064(8) Uani d . 1.0 .
O(2) 0.715(1) 0.205(4) 0.587(1) 0.13(1) Uani d . 1.0 .
O(3) 0.874(1) -0.262(3) 0.517(1) 0.1550 Uiso d . 1.0 .
O(4) 0.972(2) -0.318(4) 0.486(2) 0.2764 Uiso d . 1.0 .
O(5) 0.956(2) -0.115(3) 0.510(1) 0.1677 Uiso d . 1.0 .
N(1) 0.902(1) 0.265(4) 0.634(1) 0.07(1) Uani d . 1.0 .
N(2) 0.782(1) 0.110(4) 0.6537(10) 0.08(1) Uani d . 1.0 .
N(3) 0.861(1) -0.121(3) 0.623(1) 0.061(10) Uani d . 1.0 .
N(4) 0.980(1) 0.037(4) 0.605(1) 0.08(1) Uani d . 1.0 .
N(5) 0.751(1) -0.003(4) 0.514(1) 0.09(1) Uani d . 1.0 .
N(6) 0.874(1) 0.151(4) 0.483(1) 0.11(1) Uani d . 1.0 .
N(7) 0.934(1) -0.231(3) 0.5042(8) 0.1572 Uiso d . 1.0 .
C(1) 0.882(2) 0.363(5) 0.597(2) 0.08(1) Uiso d . 1.0 .
C(2) 0.912(3) 0.494(6) 0.619(2) 0.11(2) Uiso d . 1.0 .
C(3) 0.959(3) 0.469(7) 0.664(3) 0.16(2) Uiso d . 1.0 .
C(4) 0.950(2) 0.320(5) 0.678(2) 0.10(2) Uiso d . 1.0 .
C(5) 0.725(2) 0.165(4) 0.631(2) 0.06(1) Uiso d . 1.0 .
C(6) 0.661(2) 0.183(5) 0.662(2) 0.09(1) Uiso d . 1.0 .
C(7) 0.691(3) 0.097(5) 0.718(2) 0.13(2) Uiso d . 1.0 .
C(8) 0.774(2) 0.074(4) 0.711(1) 0.062(10) Uiso d . 1.0 .
H(1) 0.9388 0.5381 0.5936 0.2124 Uiso calc C(2) 1.0 .
H(2) 0.8728 0.5517 0.6268 0.2124 Uiso calc C(2) 1.0 .
H(3) 1.0088 0.4864 0.6572 0.1700 Uiso calc C(3) 1.0 .
H(4) 0.9463 0.5263 0.6909 0.1700 Uiso calc C(3) 1.0 .
H(5) 0.9270 0.3119 0.7091 0.1181 Uiso calc C(4) 1.0 .
H(6) 0.9958 0.2744 0.6813 0.1181 Uiso calc C(4) 1.0 .
H(7) 0.6521 0.2771 0.6688 0.0829 Uiso calc C(6) 1.0 .
H(8) 0.6174 0.1438 0.6454 0.0829 Uiso calc C(6) 1.0 .
H(9) 0.6842 0.1500 0.7472 0.0829 Uiso calc C(7) 1.0 .
H(10) 0.6655 0.0125 0.7196 0.0829 Uiso calc C(7) 1.0 .
H(11) 0.7871 -0.0183 0.7176 0.0829 Uiso calc C(8) 1.0 .
H(12) 0.8034 0.1323 0.7331 0.0829 Uiso calc C(8) 1.0 .
H(13) 0.8178 -0.1396 0.6325 0.0638 Uiso calc N(3) 1.0 .
H(14) 0.8646 -0.1488 0.5919 0.0638 Uiso calc N(3) 1.0 .
H(15) 0.8942 -0.1630 0.6440 0.0638 Uiso calc N(3) 1.0 .
H(16) 1.0045 -0.0169 0.6268 0.0754 Uiso calc N(4) 1.0 .
H(17) 0.9765 -0.0018 0.5744 0.0754 Uiso calc N(4) 1.0 .
H(18) 1.0041 0.1135 0.6030 0.0754 Uiso calc N(4) 1.0 .
H(19) 0.7124 -0.0196 0.5302 0.0697 Uiso calc N(5) 1.0 .
H(20) 0.7373 0.0022 0.4807 0.0697 Uiso calc N(5) 1.0 .
H(21) 0.7827 -0.0678 0.5193 0.0697 Uiso calc N(5) 1.0 .
H(22) 0.8975 0.0747 0.4886 0.0928 Uiso calc N(6) 1.0 .
H(23) 0.8509 0.1487 0.4519 0.0928 Uiso calc N(6) 1.0 .
H(24) 0.9042 0.2188 0.4852 0.0744 Uiso calc N(6) 1.0 .
loop_
_atom_type_symbol
_atom_type_oxidation_number
_atom_type_number_in_cell
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Pt 0 16 -4.593 6.926
;
'International Tables for X-ray Crystallography (1974, Vol. IV)'
;
P 0 12 0.295 0.434
;
'International Tables for X-ray Crystallography (1974, Vol. IV)'
;
F 0 72 0.073 0.053
;
'International Tables for X-ray Crystallography (1974, Vol. IV)'
;
O 0 40 0.049 0.032
;
'International Tables for X-ray Crystallography (1974, Vol. IV)'
;
N 0 56 0.031 0.018
;
'International Tables for X-ray Crystallography (1974, Vol. IV)'
;
C 0 64 0.018 0.009
;
'International Tables for X-ray Crystallography (1974, Vol. IV)'
;
H 0 192 0.000 0.000
;
'International Tables for X-ray Crystallography (1974, Vol. IV)'
;
loop_
_diffrn_standard_refln_index_h
_diffrn_standard_refln_index_k
_diffrn_standard_refln_index_l
-2 2 -1
-1 1 -1
-1 1 -2
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Pt(1) Pt(1) Pt(2) 167.27(10) 7_656 1_555 1_555 yes
Pt(1) Pt(1) O(1) 87.7(7) 7_656 1_555 1_555 yes
Pt(1) Pt(1) O(2) 87.0(9) 7_656 1_555 1_555 yes
Pt(1) Pt(1) N(5) 92.1(9) 7_656 1_555 1_555 yes
Pt(1) Pt(1) N(6) 88.6(9) 7_656 1_555 1_555 yes
Pt(2) Pt(1) O(1) 83.3(7) 1_555 1_555 1_555 yes
Pt(2) Pt(1) O(2) 84.2(8) 1_555 1_555 1_555 yes
Pt(2) Pt(1) N(5) 97.4(9) 1_555 1_555 1_555 yes
Pt(2) Pt(1) N(6) 100.1(9) 1_555 1_555 1_555 yes
O(1) Pt(1) O(2) 91(1) 1_555 1_555 1_555 yes
O(1) Pt(1) N(5) 177(1) 1_555 1_555 1_555 yes
O(1) Pt(1) N(6) 88(1) 1_555 1_555 1_555 yes
O(2) Pt(1) N(5) 91(1) 1_555 1_555 1_555 yes
O(2) Pt(1) N(6) 175(1) 1_555 1_555 1_555 yes
N(5) Pt(1) N(6) 88(1) 1_555 1_555 1_555 yes
Pt(1) Pt(2) N(1) 80.4(9) 1_555 1_555 1_555 yes
Pt(1) Pt(2) N(2) 78.2(8) 1_555 1_555 1_555 yes
Pt(1) Pt(2) N(3) 103.3(8) 1_555 1_555 1_555 yes
Pt(1) Pt(2) N(4) 104.8(9) 1_555 1_555 1_555 yes
N(1) Pt(2) N(2) 89(1) 1_555 1_555 1_555 yes
N(1) Pt(2) N(3) 175(1) 1_555 1_555 1_555 yes
N(1) Pt(2) N(4) 89(1) 1_555 1_555 1_555 yes
N(2) Pt(2) N(3) 93(1) 1_555 1_555 1_555 yes
N(2) Pt(2) N(4) 176(1) 1_555 1_555 1_555 yes
N(3) Pt(2) N(4) 87(1) 1_555 1_555 1_555 yes
F(7) P(2) F(8) 180(1) 1_555 1_555 1_555 yes
F(7) P(2) F(9) 90(1) 1_555 1_555 1_555 yes
F(7) P(2) F(9) 90(1) 1_555 1_555 2_756 yes
F(7) P(2) F(10) 96(2) 1_555 1_555 1_555 yes
F(7) P(2) F(10) 96(2) 1_555 1_555 2_756 yes
F(8) P(2) F(9) 89(1) 1_555 1_555 1_555 yes
F(8) P(2) F(9) 89(1) 1_555 1_555 2_756 yes
F(8) P(2) F(10) 83(2) 1_555 1_555 1_555 yes
F(8) P(2) F(10) 83(2) 1_555 1_555 2_756 yes
F(9) P(2) F(9) 178(2) 1_555 1_555 2_756 yes
F(9) P(2) F(10) 91(1) 1_555 1_555 1_555 yes
F(9) P(2) F(10) 88(1) 1_555 1_555 2_756 yes
F(9) P(2) F(10) 88(1) 2_756 1_555 1_555 yes
F(9) P(2) F(10) 91(1) 2_756 1_555 2_756 yes
F(10) P(2) F(10) 166(4) 1_555 1_555 2_756 yes
Pt(1) O(1) C(1) 125(2) 1_555 1_555 1_555 yes
Pt(1) O(2) C(5) 119(2) 1_555 1_555 1_555 yes
Pt(2) N(1) C(1) 124(2) 1_555 1_555 1_555 yes
Pt(2) N(1) C(4) 122(2) 1_555 1_555 1_555 yes
C(1) N(1) C(4) 112(3) 1_555 1_555 1_555 yes
Pt(2) N(2) C(5) 129(2) 1_555 1_555 1_555 yes
Pt(2) N(2) C(8) 116(1) 1_555 1_555 1_555 yes
C(5) N(2) C(8) 113(2) 1_555 1_555 1_555 yes
O(1) C(1) N(1) 125(4) 1_555 1_555 1_555 yes
O(1) C(1) C(2) 128(4) 1_555 1_555 1_555 yes
N(1) C(1) C(2) 106(3) 1_555 1_555 1_555 yes
C(1) C(2) C(3) 109(4) 1_555 1_555 1_555 yes
C(2) C(3) C(4) 107(4) 1_555 1_555 1_555 yes
N(1) C(4) C(3) 103(4) 1_555 1_555 1_555 yes
O(2) C(5) N(2) 128(3) 1_555 1_555 1_555 yes
O(2) C(5) C(6) 114(3) 1_555 1_555 1_555 yes
N(2) C(5) C(6) 116(3) 1_555 1_555 1_555 yes
C(5) C(6) C(7) 100(3) 1_555 1_555 1_555 yes
C(6) C(7) C(8) 102(3) 1_555 1_555 1_555 yes
N(2) C(8) C(7) 104(2) 1_555 1_555 1_555 yes
O(3) N(7) O(4) 119(3) 1_555 1_555 1_555 yes
O(3) N(7) O(5) 119(2) 1_555 1_555 1_555 yes
O(4) N(7) O(5) 120(2) 1_555 1_555 1_555 yes
F(3) P(1) F(6) 90(1) 1_555 1_555 1_555 yes
F(3) P(1) F(2) 89(1) 1_555 1_555 1_555 yes
F(3) P(1) F(1) 90(1) 1_555 1_555 1_555 yes
F(3) P(1) F(5) 90(1) 1_555 1_555 1_555 yes
F(3) P(1) F(4) 180(2) 1_555 1_555 1_555 yes
F(6) P(1) F(2) 89(1) 1_555 1_555 1_555 yes
F(6) P(1) F(1) 90(1) 1_555 1_555 1_555 yes
F(6) P(1) F(5) 180(2) 1_555 1_555 1_555 yes
F(6) P(1) F(4) 90(1) 1_555 1_555 1_555 yes
F(2) P(1) F(1) 180(2) 1_555 1_555 1_555 yes
F(2) P(1) F(5) 90(1) 1_555 1_555 1_555 yes
F(2) P(1) F(4) 90(1) 1_555 1_555 1_555 yes
F(1) P(1) F(5) 89(1) 1_555 1_555 1_555 yes
F(1) P(1) F(4) 89(1) 1_555 1_555 1_555 yes
F(5) P(1) F(4) 90(1) 1_555 1_555 1_555 yes
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt(1) Pt(1) 2.868(3) 1_555 7_656 yes
Pt(1) Pt(2) 2.840(2) 1_555 1_555 yes
Pt(1) O(1) 1.92(3) 1_555 1_555 yes
Pt(1) O(2) 2.05(3) 1_555 1_555 yes
Pt(1) N(5) 2.00(4) 1_555 1_555 yes
Pt(1) N(6) 2.13(3) 1_555 1_555 yes
Pt(2) N(1) 1.93(3) 1_555 1_555 yes
Pt(2) N(2) 1.98(3) 1_555 1_555 yes
Pt(2) N(3) 1.93(3) 1_555 1_555 yes
Pt(2) N(4) 2.05(3) 1_555 1_555 yes
P(2) F(7) 1.34(5) 1_555 1_555 yes
P(2) F(8) 1.43(5) 1_555 1_555 yes
P(2) F(9) 1.57(2) 1_555 1_555 yes
P(2) F(9) 1.57(2) 1_555 2_756 yes
P(2) F(10) 1.53(2) 1_555 1_555 yes
P(2) F(10) 1.53(2) 1_555 2_756 yes
O(1) C(1) 1.21(5) 1_555 1_555 yes
O(2) C(5) 1.22(5) 1_555 1_555 yes
N(1) C(1) 1.38(6) 1_555 1_555 yes
N(1) C(4) 1.48(6) 1_555 1_555 yes
N(2) C(5) 1.26(5) 1_555 1_555 yes
N(2) C(8) 1.55(5) 1_555 1_555 yes
C(1) C(2) 1.49(7) 1_555 1_555 yes
C(2) C(3) 1.41(8) 1_555 1_555 yes
C(3) C(4) 1.52(9) 1_555 1_555 yes
C(5) C(6) 1.50(6) 1_555 1_555 yes
C(6) C(7) 1.72(7) 1_555 1_555 yes
C(7) C(8) 1.56(6) 1_555 1_555 yes
N(7) O(3) 1.22(4) 1_555 1_555 yes
N(7) O(4) 1.22(5) 1_555 1_555 yes
N(7) O(5) 1.22(4) 1_555 1_555 yes
P(1) F(3) 1.53(3) 1_555 1_555 yes
P(1) F(6) 1.53(3) 1_555 1_555 yes
P(1) F(2) 1.53(3) 1_555 1_555 yes
P(1) F(1) 1.53(3) 1_555 1_555 yes
P(1) F(5) 1.53(3) 1_555 1_555 yes
P(1) F(4) 1.53(3) 1_555 1_555 yes
loop_
_geom_contact_atom_site_label_1
_geom_contact_atom_site_label_2
_geom_contact_distance
_geom_contact_site_symmetry_1
_geom_contact_site_symmetry_2
_geom_contact_publ_flag
O(1) N(5) 2.87(4) 1_555 7_656 no
O(2) N(6) 2.71(5) 1_555 7_656 no
F(9) N(4) 2.88(4) 1_555 1_555 no
F(9) N(3) 3.11(3) 1_555 1_555 no
F(10) N(3) 3.05(4) 1_555 2_756 no
N(3) F(1) 3.00(4) 1_555 6_646 no
N(3) F(5) 3.12(4) 1_555 6_646 no
N(4) F(6) 3.04(3) 1_555 2_756 no
N(6) F(6) 2.81(5) 1_555 4_554 no
N(6) O(5) 3.12(4) 1_555 3_756 no
