#------------------------------------------------------------------------------
#$Date: 2016-03-22 12:19:30 +0200 (Tue, 22 Mar 2016) $
#$Revision: 178945 $
#$URL: svn://www.crystallography.net/cod/cif/4/11/74/4117488.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4117488
loop_
_publ_author_name
'Ann Christin Jahnke'
'Kevin Pröpper'
'Catherine Bronner'
'Jörg Teichgräber'
'Sebastian Dechert'
'Michael John'
'Oliver S. Wenger'
'Franc Meyer'
_publ_contact_author_address
; Institut für Anorganische Chemie
  Georg August Universität Göttingen
  Tammannstraße 4
  D-37077 Göttingen
  Germany
;
_publ_contact_author_email       franc.meyer@chemie.uni-goettingen.de
_publ_contact_author_fax         49(551)393063
_publ_contact_author_name        'Prof. Dr. Franc Meyer'
_publ_contact_author_phone       49(551)393012
_publ_section_title
;
 A New Dimension in Cyclic Coinage Metal Pyrazolates: Decoration with a
 Second Ring of Coinage Metals Supported by Inter-ring Metallophilic
 Interactions
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              2938
_journal_page_last               2941
_journal_paper_doi               10.1021/ja211549e
_journal_volume                  134
_journal_year                    2012
_chemical_formula_moiety
'C92 H76 Ag4 Au4 N8 S8 4+, 4(C H2 Cl2), 4(B F4 -)'
_chemical_formula_sum            'C96 H84 Ag4 Au4 B4 Cl8 F16 N8 S8'
_chemical_formula_weight         3456.38
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 118.0780(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   31.0857(5)
_cell_length_b                   13.3190(3)
_cell_length_c                   29.7191(5)
_cell_measurement_reflns_used    62231
_cell_measurement_temperature    133(2)
_cell_measurement_theta_max      25.66
_cell_measurement_theta_min      1.48
_cell_volume                     10856.5(4)
_computing_cell_refinement       'X-AREA (Stoe & Cie, 2002)'
_computing_data_collection       'X-AREA (Stoe & Cie, 2002)'
_computing_data_reduction        'X-AREA (Stoe & Cie, 2002)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 2001)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      133(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Stoe IPDS II'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0574
_diffrn_reflns_av_sigmaI/netI    0.0279
_diffrn_reflns_limit_h_max       37
_diffrn_reflns_limit_h_min       -37
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_number            62231
_diffrn_reflns_theta_full        25.66
_diffrn_reflns_theta_max         25.66
_diffrn_reflns_theta_min         1.48
_exptl_absorpt_coefficient_mu    6.517
_exptl_absorpt_correction_T_max  0.4344
_exptl_absorpt_correction_T_min  0.1558
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'X-RED (Stoe & Cie, 2002)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.115
_exptl_crystal_description       block
_exptl_crystal_F_000             6592
_exptl_crystal_size_max          0.37
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.036
_refine_diff_density_min         -1.621
_refine_diff_density_rms         0.140
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.168
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     667
_refine_ls_number_reflns         10229
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.168
_refine_ls_R_factor_all          0.0381
_refine_ls_R_factor_gt           0.0356
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0263P)²+156.2967P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0889
_refine_ls_wR_factor_ref         0.0901
_reflns_number_gt                9634
_reflns_number_total             10229
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja211549e_si_002_4.cif
_cod_data_source_block           aj13-3c
_cod_original_cell_volume        10856.4(4)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4117488
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Au1 Au 0.497601(9) 0.604341(16) 0.673226(8) 0.02270(7) Uani 1 1 d .
Au2 Au 0.577267(9) 0.610182(16) 0.782888(9) 0.02335(7) Uani 1 1 d .
Ag1 Ag 0.46859(2) 0.59873(3) 0.566647(19) 0.03320(12) Uani 1 1 d .
Ag2 Ag 0.681090(19) 0.62099(4) 0.83841(2) 0.03456(12) Uani 1 1 d .
S1 S 0.49538(6) 0.42498(11) 0.57076(6) 0.0293(3) Uani 1 1 d .
S2 S 0.69748(6) 0.44646(13) 0.82875(6) 0.0318(3) Uani 1 1 d .
S11 S 0.44732(6) 0.77575(11) 0.54539(6) 0.0264(3) Uani 1 1 d .
S12 S 0.31081(6) 0.80008(12) 0.65077(7) 0.0342(4) Uani 1 1 d .
N1 N 0.54015(19) 0.4819(4) 0.69589(18) 0.0241(10) Uani 1 1 d .
N2 N 0.5774(2) 0.4870(4) 0.74461(19) 0.0260(11) Uani 1 1 d .
N11 N 0.45686(19) 0.7284(4) 0.6587(2) 0.0251(11) Uani 1 1 d .
N12 N 0.4271(2) 0.7334(4) 0.68093(19) 0.0245(11) Uani 1 1 d .
C1 C 0.5782(3) 0.3346(4) 0.7149(2) 0.0272(13) Uani 1 1 d .
C2 C 0.5399(2) 0.3900(4) 0.6771(2) 0.0244(12) Uani 1 1 d .
C3 C 0.6004(2) 0.3983(4) 0.7565(2) 0.0258(13) Uani 1 1 d .
C4 C 0.5905(3) 0.2270(5) 0.7120(2) 0.0343(16) Uani 1 1 d .
C5 C 0.5555(4) 0.1522(5) 0.7009(3) 0.047(2) Uani 1 1 d .
H5 H 0.5238 0.1683 0.6938 0.080 Uiso 1 1 calc R
C6 C 0.5694(5) 0.0516(6) 0.7006(3) 0.066(3) Uani 1 1 d .
H6 H 0.5466 0.0008 0.6932 0.080 Uiso 1 1 calc R
C7 C 0.6155(5) 0.0273(7) 0.7109(3) 0.075(4) Uani 1 1 d .
H7 H 0.6240 -0.0395 0.7105 0.080 Uiso 1 1 calc R
C8 C 0.6489(5) 0.1005(7) 0.7218(4) 0.074(3) Uani 1 1 d .
H8 H 0.6806 0.0829 0.7294 0.080 Uiso 1 1 calc R
C9 C 0.6376(4) 0.2016(6) 0.7222(3) 0.055(2) Uani 1 1 d .
H9 H 0.6610 0.2510 0.7290 0.080 Uiso 1 1 calc R
C10 C 0.5022(3) 0.3557(5) 0.6265(2) 0.0292(13) Uani 1 1 d .
H10A H 0.4711 0.3566 0.6266 0.080 Uiso 1 1 calc R
H10B H 0.5092 0.2863 0.6224 0.080 Uiso 1 1 calc R
C11 C 0.5534(3) 0.4215(5) 0.5732(2) 0.0297(13) Uani 1 1 d .
C12 C 0.5672(3) 0.5014(5) 0.5536(3) 0.0391(16) Uani 1 1 d .
H12 H 0.5487 0.5600 0.5447 0.080 Uiso 1 1 calc R
C13 C 0.6081(3) 0.4956(7) 0.5468(3) 0.0474(19) Uani 1 1 d .
H13 H 0.6164 0.5488 0.5321 0.080 Uiso 1 1 calc R
C14 C 0.6366(3) 0.4108(7) 0.5620(3) 0.050(2) Uani 1 1 d .
H14 H 0.6643 0.4066 0.5576 0.080 Uiso 1 1 calc R
C15 C 0.6243(3) 0.3317(6) 0.5839(3) 0.050(2) Uani 1 1 d .
H15 H 0.6444 0.2756 0.5953 0.080 Uiso 1 1 calc R
C16 C 0.5823(3) 0.3353(5) 0.5888(3) 0.0414(17) Uani 1 1 d .
H16 H 0.5735 0.2811 0.6024 0.080 Uiso 1 1 calc R
C17 C 0.6411(3) 0.3760(5) 0.8088(2) 0.0311(14) Uani 1 1 d .
H17A H 0.6487 0.3050 0.8104 0.080 Uiso 1 1 calc R
H17B H 0.6293 0.3885 0.8333 0.080 Uiso 1 1 calc R
C18 C 0.7084(3) 0.4390(5) 0.7755(3) 0.0332(15) Uani 1 1 d .
C19 C 0.6852(3) 0.5032(6) 0.7340(3) 0.0431(18) Uani 1 1 d .
H19 H 0.6630 0.5506 0.7333 0.080 Uiso 1 1 calc R
C20 C 0.6956(3) 0.4959(7) 0.6936(3) 0.051(2) Uani 1 1 d .
H20 H 0.6803 0.5386 0.6657 0.080 Uiso 1 1 calc R
C21 C 0.7284(3) 0.4258(7) 0.6946(3) 0.051(2) Uani 1 1 d .
H21 H 0.7350 0.4214 0.6672 0.080 Uiso 1 1 calc R
C22 C 0.7518(3) 0.3617(6) 0.7356(3) 0.048(2) Uani 1 1 d .
H22 H 0.7740 0.3146 0.7359 0.080 Uiso 1 1 calc R
C23 C 0.7419(3) 0.3686(6) 0.7764(3) 0.0417(17) Uani 1 1 d .
H23 H 0.7576 0.3261 0.8043 0.080 Uiso 1 1 calc R
C31 C 0.4254(2) 0.8823(4) 0.6468(2) 0.0225(12) Uani 1 1 d .
C32 C 0.4559(2) 0.8182(4) 0.6377(2) 0.0232(12) Uani 1 1 d .
C33 C 0.4082(2) 0.8260(4) 0.6743(2) 0.0245(12) Uani 1 1 d .
C34 C 0.4134(2) 0.9894(4) 0.6312(2) 0.0255(13) Uani 1 1 d .
C35 C 0.4270(3) 1.0641(5) 0.6688(3) 0.0401(17) Uani 1 1 d .
H35 H 0.4443 1.0477 0.7032 0.080 Uiso 1 1 calc R
C36 C 0.4140(4) 1.1640(5) 0.6535(4) 0.053(2) Uani 1 1 d .
H36 H 0.4228 1.2139 0.6781 0.080 Uiso 1 1 calc R
C37 C 0.3890(3) 1.1891(5) 0.6034(4) 0.047(2) Uani 1 1 d .
H37 H 0.3807 1.2558 0.5942 0.080 Uiso 1 1 calc R
C38 C 0.3756(3) 1.1162(5) 0.5661(3) 0.0449(19) Uani 1 1 d .
H38 H 0.3582 1.1336 0.5318 0.080 Uiso 1 1 calc R
C39 C 0.3884(3) 1.0159(5) 0.5803(3) 0.0325(14) Uani 1 1 d .
H39 H 0.3802 0.9668 0.5553 0.080 Uiso 1 1 calc R
C40 C 0.4823(2) 0.8363(5) 0.6079(2) 0.0260(13) Uani 1 1 d .
H40A H 0.5149 0.8080 0.6255 0.080 Uiso 1 1 calc R
H40B H 0.4851 0.9078 0.6037 0.080 Uiso 1 1 calc R
C41 C 0.4761(2) 0.8229(5) 0.5103(2) 0.0269(13) Uani 1 1 d .
C42 C 0.4499(3) 0.8937(5) 0.4720(3) 0.0366(16) Uani 1 1 d .
H42 H 0.4203 0.9183 0.4680 0.080 Uiso 1 1 calc R
C43 C 0.4684(3) 0.9267(6) 0.4402(3) 0.0430(18) Uani 1 1 d .
H43 H 0.4510 0.9726 0.4143 0.080 Uiso 1 1 calc R
C44 C 0.5135(3) 0.8900(5) 0.4477(3) 0.0394(17) Uani 1 1 d .
H44 H 0.5260 0.9108 0.4262 0.080 Uiso 1 1 calc R
C45 C 0.5393(3) 0.8237(5) 0.4862(3) 0.0372(16) Uani 1 1 d .
H45 H 0.5697 0.8014 0.4914 0.080 Uiso 1 1 calc R
C46 C 0.5207(3) 0.7895(5) 0.5177(3) 0.0312(14) Uani 1 1 d .
H46 H 0.5384 0.7441 0.5436 0.080 Uiso 1 1 calc R
C47 C 0.3720(3) 0.8527(5) 0.6915(3) 0.0315(14) Uani 1 1 d .
H47A H 0.3695 0.9252 0.6921 0.080 Uiso 1 1 calc R
H47B H 0.3836 0.8286 0.7261 0.080 Uiso 1 1 calc R
C48 C 0.3005(3) 0.8301(5) 0.5886(3) 0.0334(15) Uani 1 1 d .
C49 C 0.2730(3) 0.9161(6) 0.5656(3) 0.0455(19) Uani 1 1 d .
H49 H 0.2608 0.9555 0.5828 0.080 Uiso 1 1 calc R
C50 C 0.2641(3) 0.9420(7) 0.5166(4) 0.056(2) Uani 1 1 d .
H50 H 0.2466 0.9998 0.5012 0.080 Uiso 1 1 calc R
C51 C 0.2814(3) 0.8817(7) 0.4910(3) 0.056(2) Uani 1 1 d .
H51 H 0.2744 0.8984 0.4579 0.080 Uiso 1 1 calc R
C52 C 0.3086(3) 0.7979(7) 0.5131(3) 0.048(2) Uani 1 1 d .
H52 H 0.3206 0.7592 0.4955 0.080 Uiso 1 1 calc R
C53 C 0.3183(3) 0.7706(5) 0.5628(3) 0.0352(15) Uani 1 1 d .
H53 H 0.3365 0.7133 0.5781 0.080 Uiso 1 1 calc R
B1 B 0.3648(3) 0.4876(6) 0.5712(3) 0.0372(18) Uani 1 1 d .
F11 F 0.33080(16) 0.5133(3) 0.58740(16) 0.0404(10) Uani 1 1 d .
F12 F 0.38049(17) 0.5760(3) 0.55743(18) 0.0460(11) Uani 1 1 d .
F13 F 0.40389(18) 0.4422(3) 0.6118(2) 0.0570(13) Uani 1 1 d .
F14 F 0.3440(2) 0.4236(4) 0.5304(2) 0.0658(15) Uani 1 1 d .
B2 B 0.6176(4) 0.7467(8) 0.6607(4) 0.050(2) Uani 1 1 d .
F21 F 0.5822(2) 0.6750(4) 0.6358(2) 0.0611(13) Uani 1 1 d .
F22 F 0.6330(3) 0.7447(6) 0.7120(2) 0.094(2) Uani 1 1 d .
F23 F 0.5986(2) 0.8410(4) 0.6400(2) 0.0691(15) Uani 1 1 d .
F24 F 0.6568(2) 0.7286(5) 0.6524(3) 0.0833(19) Uani 1 1 d .
C61 C 0.6673(5) 0.9985(12) 0.1239(5) 0.104(5) Uani 1 1 d .
H61A H 0.6350 0.9818 0.1190 0.080 Uiso 1 1 calc R
H61B H 0.6814 1.0472 0.1513 0.080 Uiso 1 1 calc R
Cl1 Cl 0.70365(14) 0.8892(3) 0.14179(19) 0.1120(13) Uani 1 1 d .
Cl2 Cl 0.66250(15) 1.0504(3) 0.07013(17) 0.1148(12) Uani 1 1 d .
C62 C 0.7752(7) 0.1969(14) 0.9134(6) 0.133(6) Uani 1 1 d .
H62A H 0.7966 0.2363 0.9049 0.080 Uiso 1 1 calc R
H62B H 0.7943 0.1436 0.9364 0.080 Uiso 1 1 calc R
Cl4 Cl 0.7494(3) 0.2751(5) 0.94370(19) 0.170(2) Uani 1 1 d .
Cl5 Cl 0.72840(17) 0.1459(3) 0.85844(15) 0.1082(12) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N11 Au1 N1 173.7(2) . .
N11 Au1 Ag1 86.84(15) . .
N1 Au1 Ag1 99.51(14) . .
N11 Au1 Au2 108.97(15) . .
N1 Au1 Au2 65.37(14) . .
Ag1 Au1 Au2 149.959(15) . .
N11 Au1 Au2 63.54(15) . 2_656
N1 Au1 Au2 112.27(14) . 2_656
Ag1 Au1 Au2 123.288(15) . 2_656
Au2 Au1 Au2 86.749(9) . 2_656
N2 Au2 N12 176.7(2) . 2_656
N2 Au2 Ag2 93.75(16) . .
N12 Au2 Ag2 89.59(16) 2_656 .
N2 Au2 Au1 65.53(15) . .
N12 Au2 Au1 111.79(15) 2_656 .
Ag2 Au2 Au1 138.867(14) . .
N2 Au2 Au1 114.49(15) . 2_656
N12 Au2 Au1 63.17(14) 2_656 2_656
Ag2 Au2 Au1 127.942(14) . 2_656
Au1 Au2 Au1 93.180(9) . 2_656
S1 Ag1 S11 165.66(6) . .
S1 Ag1 Au1 92.69(4) . .
S11 Ag1 Au1 99.60(4) . .
S12 Ag2 S2 162.19(6) 2_656 .
S12 Ag2 Au2 98.40(5) 2_656 .
S2 Ag2 Au2 97.27(5) . .
C11 S1 C10 105.5(3) . .
C11 S1 Ag1 110.1(2) . .
C10 S1 Ag1 114.7(2) . .
C18 S2 C17 103.8(3) . .
C18 S2 Ag2 107.4(2) . .
C17 S2 Ag2 108.0(2) . .
C41 S11 C40 102.4(3) . .
C41 S11 Ag1 110.0(2) . .
C40 S11 Ag1 101.6(2) . .
C48 S12 C47 103.0(3) . .
C48 S12 Ag2 108.7(2) . 2_656
C47 S12 Ag2 106.2(2) . 2_656
C2 N1 N2 108.8(5) . .
C2 N1 Au1 136.6(4) . .
N2 N1 Au1 114.4(4) . .
C3 N2 N1 108.6(5) . .
C3 N2 Au2 135.9(4) . .
N1 N2 Au2 114.6(4) . .
C32 N11 N12 108.0(5) . .
C32 N11 Au1 135.1(4) . .
N12 N11 Au1 116.1(4) . .
C33 N12 N11 108.9(5) . .
C33 N12 Au2 134.2(4) . 2_656
N11 N12 Au2 116.9(4) . 2_656
C3 C1 C2 105.8(5) . .
C3 C1 C4 127.1(6) . .
C2 C1 C4 127.0(6) . .
N1 C2 C1 107.9(5) . .
N1 C2 C10 123.6(6) . .
C1 C2 C10 128.3(5) . .
N2 C3 C1 108.8(6) . .
N2 C3 C17 122.2(5) . .
C1 C3 C17 128.8(6) . .
C9 C4 C5 120.1(7) . .
C9 C4 C1 119.5(7) . .
C5 C4 C1 120.4(7) . .
C4 C5 C6 118.2(9) . .
C7 C6 C5 121.4(10) . .
C8 C7 C6 119.7(8) . .
C7 C8 C9 122.0(11) . .
C4 C9 C8 118.6(10) . .
C2 C10 S1 117.8(5) . .
C12 C11 C16 119.7(7) . .
C12 C11 S1 118.5(5) . .
C16 C11 S1 121.4(5) . .
C11 C12 C13 120.7(7) . .
C14 C13 C12 119.6(8) . .
C13 C14 C15 120.1(8) . .
C16 C15 C14 120.5(8) . .
C15 C16 C11 119.2(7) . .
C3 C17 S2 116.6(5) . .
C19 C18 C23 119.9(7) . .
C19 C18 S2 121.5(5) . .
C23 C18 S2 118.6(6) . .
C20 C19 C18 119.5(7) . .
C21 C20 C19 120.2(8) . .
C20 C21 C22 121.1(7) . .
C21 C22 C23 119.2(7) . .
C22 C23 C18 120.1(7) . .
C33 C31 C32 105.6(5) . .
C33 C31 C34 126.2(5) . .
C32 C31 C34 128.2(5) . .
N11 C32 C31 108.8(5) . .
N11 C32 C40 121.6(5) . .
C31 C32 C40 129.4(5) . .
N12 C33 C31 108.6(5) . .
N12 C33 C47 121.5(5) . .
C31 C33 C47 129.7(6) . .
C39 C34 C35 119.6(6) . .
C39 C34 C31 120.9(6) . .
C35 C34 C31 119.5(6) . .
C36 C35 C34 118.8(7) . .
C37 C36 C35 121.2(8) . .
C36 C37 C38 120.5(7) . .
C37 C38 C39 119.4(8) . .
C34 C39 C38 120.5(7) . .
C32 C40 S11 107.5(4) . .
C46 C41 C42 120.3(6) . .
C46 C41 S11 122.8(5) . .
C42 C41 S11 116.8(5) . .
C43 C42 C41 119.7(7) . .
C42 C43 C44 119.0(7) . .
C45 C44 C43 120.5(7) . .
C44 C45 C46 120.7(7) . .
C41 C46 C45 119.7(6) . .
C33 C47 S12 113.4(5) . .
C53 C48 C49 120.7(7) . .
C53 C48 S12 121.7(5) . .
C49 C48 S12 117.6(6) . .
C50 C49 C48 119.2(8) . .
C51 C50 C49 119.8(8) . .
C52 C51 C50 121.5(8) . .
C51 C52 C53 119.7(8) . .
C48 C53 C52 119.1(7) . .
F14 B1 F13 110.8(7) . .
F14 B1 F11 109.8(7) . .
F13 B1 F11 107.6(6) . .
F14 B1 F12 110.4(7) . .
F13 B1 F12 109.7(7) . .
F11 B1 F12 108.5(6) . .
F22 B2 F24 108.8(8) . .
F22 B2 F21 111.0(9) . .
F24 B2 F21 109.4(7) . .
F22 B2 F23 111.2(7) . .
F24 B2 F23 107.7(9) . .
F21 B2 F23 108.6(8) . .
Cl2 C61 Cl1 112.6(9) . .
Cl5 C62 Cl4 108.9(11) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 N11 2.001(5) .
Au1 N1 2.006(5) .
Au1 Ag1 2.8571(5) .
Au1 Au2 3.0270(3) .
Au1 Au2 3.1592(3) 2_656
Au2 N2 1.998(5) .
Au2 N12 2.002(5) 2_656
Au2 Ag2 2.8542(6) .
Au2 Au1 3.1593(3) 2_656
Ag1 S1 2.4429(16) .
Ag1 S11 2.4499(16) .
Ag2 S12 2.4042(17) 2_656
Ag2 S2 2.4255(17) .
S1 C11 1.770(7) .
S1 C10 1.819(6) .
S2 C18 1.769(7) .
S2 C17 1.823(7) .
S11 C41 1.779(6) .
S11 C40 1.839(6) .
S12 C48 1.767(7) .
S12 C47 1.846(7) .
S12 Ag2 2.4043(17) 2_656
N1 C2 1.344(7) .
N1 N2 1.365(7) .
N2 C3 1.340(8) .
N11 C32 1.344(7) .
N11 N12 1.367(7) .
N12 C33 1.340(8) .
N12 Au2 2.002(5) 2_656
C1 C3 1.386(9) .
C1 C2 1.402(9) .
C1 C4 1.496(8) .
C2 C10 1.477(9) .
C3 C17 1.499(9) .
C4 C9 1.391(12) .
C4 C5 1.395(11) .
C5 C6 1.410(11) .
C6 C7 1.355(17) .
C7 C8 1.348(17) .
C8 C9 1.393(11) .
C11 C12 1.378(10) .
C11 C16 1.396(10) .
C12 C13 1.381(11) .
C13 C14 1.374(12) .
C14 C15 1.385(12) .
C15 C16 1.380(12) .
C18 C19 1.393(10) .
C18 C23 1.393(10) .
C19 C20 1.384(11) .
C20 C21 1.373(11) .
C21 C22 1.382(12) .
C22 C23 1.386(11) .
C31 C33 1.389(8) .
C31 C32 1.394(8) .
C31 C34 1.492(8) .
C32 C40 1.483(8) .
C33 C47 1.482(9) .
C34 C39 1.382(9) .
C34 C35 1.405(9) .
C35 C36 1.402(10) .
C36 C37 1.357(12) .
C37 C38 1.384(12) .
C38 C39 1.401(9) .
C41 C46 1.371(10) .
C41 C42 1.405(9) .
C42 C43 1.388(10) .
C43 C44 1.402(12) .
C44 C45 1.367(11) .
C45 C46 1.387(9) .
C48 C53 1.387(10) .
C48 C49 1.400(10) .
C49 C50 1.392(13) .
C50 C51 1.376(14) .
C51 C52 1.367(13) .
C52 C53 1.407(10) .
B1 F14 1.369(9) .
B1 F13 1.385(10) .
B1 F11 1.395(9) .
B1 F12 1.408(9) .
B2 F22 1.364(12) .
B2 F24 1.374(12) .
B2 F21 1.381(11) .
B2 F23 1.401(12) .
C61 Cl2 1.682(15) .
C61 Cl1 1.764(16) .
C62 Cl5 1.735(18) .
C62 Cl4 1.794(19) .
