#------------------------------------------------------------------------------
#$Date: 2016-03-22 12:20:51 +0200 (Tue, 22 Mar 2016) $
#$Revision: 178946 $
#$URL: svn://www.crystallography.net/cod/cif/4/11/75/4117579.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4117579
loop_
_publ_author_name
'Yuanjing Cui'
'Hui Xu'
'Yanfeng Yue'
'Zhiyong Guo'
'Jiancan Yu'
'Zhenxia Chen'
'Junkuo Gao'
'Yu Yang'
'Guodong Qian'
'Banglin Chen'
_publ_section_title
;
 A Luminescent Mixed-Lanthanide Metal-Organic Framework Thermometer
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              3979
_journal_page_last               3982
_journal_paper_doi               10.1021/ja2108036
_journal_volume                  134
_journal_year                    2012
_chemical_formula_sum            'C33 H41 Eu2 N O24'
_chemical_formula_weight         1139.59
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2011-11-09 # Formatted by publCIF
;
_cell_angle_alpha                90.00
_cell_angle_beta                 104.2560(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.9484(8)
_cell_length_b                   20.9541(17)
_cell_length_c                   19.5857(16)
_cell_measurement_reflns_used    9978
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.39
_cell_measurement_theta_min      2.33
_cell_volume                     3957.1(6)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0171
_diffrn_reflns_av_sigmaI/netI    0.0178
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            23481
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.45
_exptl_absorpt_coefficient_mu    3.235
_exptl_absorpt_correction_T_max  0.7819
_exptl_absorpt_correction_T_min  0.6425
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.913
_exptl_crystal_description       block
_exptl_crystal_F_000             2256
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.246
_refine_diff_density_min         -2.545
_refine_diff_density_rms         0.176
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.123
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     546
_refine_ls_number_reflns         6924
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.123
_refine_ls_R_factor_all          0.0443
_refine_ls_R_factor_gt           0.0362
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0589P)²+22.4445P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1025
_refine_ls_wR_factor_ref         0.1264
_reflns_number_gt                6041
_reflns_number_total             6924
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja2108036_si_002.cif
_cod_data_source_block           Eu-DMBDC-New
_cod_database_code               4117579
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.68789(3) 0.877989(11) 0.770225(12) 0.01963(11) Uani 1 1 d . . .
Eu2 Eu 0.19686(3) 0.875402(18) 0.765289(17) 0.04015(13) Uani 1 1 d . . .
C1 C 0.7510(7) 0.8330(3) 0.9125(3) 0.0399(15) Uani 1 1 d . . .
C2 C 0.7831(8) 0.8037(3) 0.9843(3) 0.0408(15) Uani 1 1 d . . .
C3 C 0.9207(8) 0.7944(4) 1.0174(4) 0.0522(19) Uani 1 1 d . . .
H3A H 0.9885 0.8081 0.9955 0.063 Uiso 1 1 calc R . .
C4 C 0.9608(8) 0.7649(4) 1.0832(4) 0.0496(18) Uani 1 1 d . . .
C5 C 0.8612(7) 0.7417(3) 1.1148(3) 0.0378(15) Uani 1 1 d . . .
C6 C 0.7236(8) 0.7517(3) 1.0823(3) 0.0454(17) Uani 1 1 d . . .
H6A H 0.6560 0.7371 1.1039 0.054 Uiso 1 1 calc R . .
C7 C 0.6825(8) 0.7834(3) 1.0170(3) 0.0444(16) Uani 1 1 d . . .
C8 C 0.8914(8) 0.7029(3) 1.1811(3) 0.0413(16) Uani 1 1 d . . .
C9 C 0.4473(12) 0.7639(8) 1.0052(10) 0.174(10) Uani 1 1 d . . .
H9A H 0.3589 0.7768 0.9763 0.261 Uiso 1 1 calc R . .
H9B H 0.4522 0.7743 1.0535 0.261 Uiso 1 1 calc R . .
H9C H 0.4582 0.7187 1.0008 0.261 Uiso 1 1 calc R . .
C10 C 1.1912(11) 0.7885(6) 1.0909(5) 0.093(4) Uani 1 1 d . . .
H10A H 1.2823 0.7773 1.1179 0.139 Uiso 1 1 calc R . .
H10B H 1.1764 0.8334 1.0957 0.139 Uiso 1 1 calc R . .
H10C H 1.1827 0.7785 1.0422 0.139 Uiso 1 1 calc R . .
C11 C 0.4339(7) 0.9932(3) 0.7695(3) 0.0392(15) Uani 1 1 d . . .
C12 C 0.4650(7) 1.0633(3) 0.7651(4) 0.0488(19) Uani 1 1 d . A .
C13 C 0.5921(7) 1.0795(3) 0.7522(4) 0.0509(19) Uani 1 1 d . . .
H13A H 0.6552 1.0471 0.7506 0.061 Uiso 1 1 calc R A .
C14 C 0.6288(8) 1.1421(3) 0.7417(5) 0.059(2) Uani 1 1 d . A .
C15 C 0.5372(9) 1.1917(3) 0.7461(5) 0.065(3) Uani 1 1 d . . .
C16 C 0.4099(9) 1.1751(4) 0.7597(5) 0.068(3) Uani 1 1 d . A .
H16A H 0.3477 1.2076 0.7623 0.082 Uiso 1 1 calc R . .
C17 C 0.3722(8) 1.1132(4) 0.7693(5) 0.059(2) Uani 1 1 d . . .
C18 C 0.5641(10) 1.2616(4) 0.7376(5) 0.069(3) Uani 1 1 d . A .
C19 C 0.8617(10) 1.1116(4) 0.7434(6) 0.075(3) Uani 1 1 d . A .
H19A H 0.9409 1.1281 0.7295 0.113 Uiso 1 1 calc R . .
H19B H 0.8331 1.0722 0.7192 0.113 Uiso 1 1 calc R . .
H19C H 0.8855 1.1043 0.7933 0.113 Uiso 1 1 calc R . .
C20 C 0.2365(12) 1.0798(6) 0.8503(7) 0.096(4) Uani 1 1 d . . .
H20A H 0.1412 1.0754 0.8518 0.144 Uiso 1 1 calc R A .
H20B H 0.2823 1.1092 0.8860 0.144 Uiso 1 1 calc R . .
H20C H 0.2814 1.0390 0.8584 0.144 Uiso 1 1 calc R . .
C21 C 0.3646(8) 0.9522(5) 1.0389(4) 0.072(3) Uani 1 1 d . . .
H21A H 0.4413 0.9314 1.0266 0.107 Uiso 1 1 calc R . .
H21B H 0.3485 0.9328 1.0807 0.107 Uiso 1 1 calc R . .
H21C H 0.3853 0.9966 1.0475 0.107 Uiso 1 1 calc R . .
C22 C 0.1245(7) 0.9726(4) 0.9916(3) 0.0437(17) Uani 1 1 d . . .
C23 C 0.0031(6) 0.9712(4) 0.9352(3) 0.0417(16) Uani 1 1 d . A .
C24 C -0.1172(7) 0.9988(4) 0.9454(3) 0.0432(16) Uani 1 1 d . . .
C25 C -0.0037(7) 0.9424(4) 0.8643(3) 0.0477(18) Uani 1 1 d . . .
C26 C 0.5973(6) 0.9289(3) 0.6312(3) 0.0290(12) Uani 1 1 d . . .
C27 C 0.5425(6) 0.9639(3) 0.5621(3) 0.0303(12) Uani 1 1 d . . .
C28 C 0.6173(7) 1.0170(3) 0.5502(3) 0.0350(13) Uani 1 1 d . . .
C29 C 0.4228(7) 0.9464(3) 0.5110(3) 0.0354(14) Uani 1 1 d . . .
C30 C 0.2273(11) 0.8777(5) 0.4682(6) 0.092(4) Uani 1 1 d . . .
H30A H 0.1869 0.8396 0.4819 0.139 Uiso 1 1 calc R . .
H30B H 0.2508 0.8705 0.4242 0.139 Uiso 1 1 calc R . .
H30C H 0.1619 0.9121 0.4632 0.139 Uiso 1 1 calc R . .
C31 C 0.898(2) 0.9045(10) 0.5210(10) 0.194(11) Uani 1 1 d . . .
H31A H 0.9742 0.9334 0.5261 0.291 Uiso 1 1 calc R . .
H31B H 0.9316 0.8615 0.5284 0.291 Uiso 1 1 calc R . .
H31C H 0.8460 0.9147 0.5550 0.291 Uiso 1 1 calc R . .
C32 C 0.688(2) 0.8716(8) 0.4332(8) 0.135(6) Uani 1 1 d . . .
H32A H 0.6370 0.8790 0.3855 0.203 Uiso 1 1 calc R . .
H32B H 0.6313 0.8813 0.4648 0.203 Uiso 1 1 calc R . .
H32C H 0.7164 0.8277 0.4386 0.203 Uiso 1 1 calc R . .
C33 C 0.829(2) 0.9503(8) 0.4044(9) 0.164(9) Uani 1 1 d . . .
H33A H 0.7717 0.9480 0.3591 0.197 Uiso 1 1 calc R . .
O1 O 0.8238(6) 0.8154(3) 0.8708(2) 0.0617(16) Uani 1 1 d . . .
O2 O 0.6574(5) 0.8745(2) 0.8942(2) 0.0373(10) Uani 1 1 d . . .
O3 O 1.0091(7) 0.6799(3) 1.2025(3) 0.0714(18) Uani 1 1 d . . .
O4 O 0.7973(6) 0.6944(2) 1.2118(3) 0.0517(13) Uani 1 1 d . . .
O5 O 1.0974(7) 0.7560(4) 1.1143(4) 0.106(3) Uani 1 1 d . . .
O6 O 0.5481(6) 0.7943(3) 0.9843(3) 0.0769(19) Uani 1 1 d . . .
O7 O 0.3122(5) 0.9747(2) 0.7583(3) 0.0570(14) Uani 1 1 d . A .
O8 O 0.5386(5) 0.9575(2) 0.7827(3) 0.0451(11) Uani 1 1 d . A .
O9 O 0.4643(8) 1.2974(3) 0.7296(3) 0.086(2) Uani 1 1 d . . .
O10 O 0.6795(8) 1.2797(3) 0.7395(6) 0.144(5) Uani 1 1 d . . .
O11 O 0.7505(6) 1.1568(2) 0.7259(4) 0.083(2) Uani 1 1 d . . .
O12 O 0.2432(6) 1.1032(3) 0.7826(5) 0.087(2) Uani 1 1 d . A .
O13 O -0.1203(4) 0.9416(2) 0.8204(2) 0.0392(10) Uani 1 1 d . . .
O14 O 0.1032(5) 0.9201(4) 0.8523(3) 0.088(3) Uani 1 1 d . A .
O15 O 0.2445(5) 0.9457(3) 0.9830(3) 0.0588(15) Uani 1 1 d . . .
O16 O 0.7127(4) 0.9457(2) 0.6698(2) 0.0355(10) Uani 1 1 d . . .
O17 O 0.5273(5) 0.8856(2) 0.6505(2) 0.0402(11) Uani 1 1 d . . .
O18 O 0.3504(6) 0.8937(3) 0.5213(3) 0.0627(16) Uani 1 1 d . . .
O19" O 0.1166(13) 0.8056(6) 0.8560(7) 0.029(3) Uiso 0.33 1 d P A 3
O19' O 0.1698(17) 0.7667(8) 0.8303(9) 0.037(3) Uiso 0.33 1 d P A 2
O19 O 0.142(4) 0.7777(19) 0.845(2) 0.124(15) Uiso 0.33 1 d P A 1
O20 O 0.0271(5) 0.9541(3) 0.6998(3) 0.0529(13) Uani 1 1 d . A .
O21 O 0.2459(5) 0.8770(2) 0.6509(3) 0.0486(12) Uani 1 1 d . A .
O22 O 0.3702(5) 0.8839(4) 0.8766(3) 0.077(2) Uani 1 1 d . A .
O23 O 0.914(3) 0.9890(9) 0.4139(8) 0.317(15) Uani 1 1 d . . .
O24 O 0.9381(15) 0.6978(6) 0.8518(10) 0.210(7) Uani 1 1 d . . .
N1 N 0.8054(15) 0.9104(6) 0.4486(7) 0.118(4) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O9 Eu1 O8 95.2(3) 2_646 .
O9 Eu1 O4 84.7(2) 2_646 4_575
O8 Eu1 O4 157.48(17) . 4_575
O9 Eu1 O13 154.2(2) 2_646 1_655
O8 Eu1 O13 91.37(18) . 1_655
O4 Eu1 O13 98.43(18) 4_575 1_655
O9 Eu1 O1 80.7(3) 2_646 .
O8 Eu1 O1 122.94(16) . .
O4 Eu1 O1 79.35(17) 4_575 .
O13 Eu1 O1 74.8(2) 1_655 .
O9 Eu1 O16 128.46(19) 2_646 .
O8 Eu1 O16 82.11(16) . .
O4 Eu1 O16 80.41(17) 4_575 .
O13 Eu1 O16 77.13(14) 1_655 .
O1 Eu1 O16 142.32(18) . .
O9 Eu1 O17 77.1(2) 2_646 .
O8 Eu1 O17 76.78(17) . .
O4 Eu1 O17 81.30(17) 4_575 .
O13 Eu1 O17 128.73(14) 1_655 .
O1 Eu1 O17 151.64(18) . .
O16 Eu1 O17 52.08(13) . .
O9 Eu1 O2 74.85(18) 2_646 .
O8 Eu1 O2 71.47(15) . .
O4 Eu1 O2 129.55(16) 4_575 .
O13 Eu1 O2 83.74(15) 1_655 .
O1 Eu1 O2 52.38(15) . .
O16 Eu1 O2 146.87(14) . .
O17 Eu1 O2 134.88(15) . .
O9 Eu1 C26 103.0(2) 2_646 .
O8 Eu1 C26 76.64(16) . .
O4 Eu1 C26 81.43(17) 4_575 .
O13 Eu1 C26 102.77(16) 1_655 .
O1 Eu1 C26 160.01(16) . .
O16 Eu1 C26 26.12(15) . .
O17 Eu1 C26 26.06(15) . .
O2 Eu1 C26 147.61(15) . .
O9 Eu1 C1 74.9(2) 2_646 .
O8 Eu1 C1 97.37(18) . .
O4 Eu1 C1 104.31(18) 4_575 .
O13 Eu1 C1 79.51(18) 1_655 .
O1 Eu1 C1 26.35(18) . .
O16 Eu1 C1 156.61(18) . .
O17 Eu1 C1 150.71(18) . .
O2 Eu1 C1 26.11(17) . .
C26 Eu1 C1 173.56(18) . .
O3 Eu2 O14 100.2(2) 4_475 .
O3 Eu2 O10 85.0(2) 4_475 2_646
O14 Eu2 O10 132.4(4) . 2_646
O3 Eu2 O7 138.5(2) 4_475 .
O14 Eu2 O7 88.6(3) . .
O10 Eu2 O7 118.2(3) 2_646 .
O3 Eu2 O21 80.31(19) 4_475 .
O14 Eu2 O21 152.2(2) . .
O10 Eu2 O21 75.4(3) 2_646 .
O7 Eu2 O21 74.07(18) . .
O3 Eu2 O22 145.7(2) 4_475 .
O14 Eu2 O22 68.75(19) . .
O10 Eu2 O22 80.6(3) 2_646 .
O7 Eu2 O22 75.1(2) . .
O21 Eu2 O22 124.90(18) . .
O3 Eu2 O20 72.3(2) 4_475 .
O14 Eu2 O20 76.6(2) . .
O10 Eu2 O20 146.9(3) 2_646 .
O7 Eu2 O20 70.56(17) . .
O21 Eu2 O20 77.16(17) . .
O22 Eu2 O20 131.1(2) . .
O3 Eu2 O19" 74.5(3) 4_475 .
O14 Eu2 O19" 58.4(4) . .
O10 Eu2 O19" 78.4(4) 2_646 .
O7 Eu2 O19" 140.0(3) . .
O21 Eu2 O19" 144.9(3) . .
O22 Eu2 O19" 72.2(3) . .
O20 Eu2 O19" 116.6(3) . .
O3 Eu2 O19' 69.9(4) 4_475 .
O14 Eu2 O19' 83.6(4) . .
O10 Eu2 O19' 53.6(5) 2_646 .
O7 Eu2 O19' 151.5(4) . .
O21 Eu2 O19' 121.7(4) . .
O22 Eu2 O19' 76.5(4) . .
O20 Eu2 O19' 133.0(4) . .
O19" Eu2 O19' 25.4(6) . .
O3 Eu2 O19 70.8(8) 4_475 .
O14 Eu2 O19 73.1(8) . .
O10 Eu2 O19 64.1(9) 2_646 .
O7 Eu2 O19 148.9(8) . .
O21 Eu2 O19 131.4(8) . .
O22 Eu2 O19 74.9(8) . .
O20 Eu2 O19 126.3(8) . .
O19" Eu2 O19 14.8(8) . .
O19' Eu2 O19 10.7(9) . .
O2 C1 O1 121.0(5) . .
O2 C1 C2 121.5(6) . .
O1 C1 C2 117.5(6) . .
O2 C1 Eu1 61.7(3) . .
O1 C1 Eu1 59.5(3) . .
C2 C1 Eu1 175.0(5) . .
C3 C2 C7 119.2(6) . .
C3 C2 C1 117.3(6) . .
C7 C2 C1 123.5(6) . .
C2 C3 C4 121.5(7) . .
C2 C3 H3A 119.2 . .
C4 C3 H3A 119.2 . .
O5 C4 C5 120.0(6) . .
O5 C4 C3 120.1(7) . .
C5 C4 C3 119.8(7) . .
C6 C5 C4 118.8(6) . .
C6 C5 C8 116.6(6) . .
C4 C5 C8 124.5(6) . .
C5 C6 C7 121.7(7) . .
C5 C6 H6A 119.2 . .
C7 C6 H6A 119.2 . .
O6 C7 C2 118.2(6) . .
O6 C7 C6 122.8(7) . .
C2 C7 C6 119.0(7) . .
O3 C8 O4 122.8(6) . .
O3 C8 C5 118.4(7) . .
O4 C8 C5 118.8(7) . .
O6 C9 H9A 109.5 . .
O6 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
O6 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
O5 C10 H10A 109.5 . .
O5 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
O5 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
O7 C11 O8 125.2(7) . .
O7 C11 C12 120.0(6) . .
O8 C11 C12 114.8(6) . .
C13 C12 C17 117.9(7) . .
C13 C12 C11 117.2(6) . .
C17 C12 C11 124.9(7) . .
C14 C13 C12 122.7(6) . .
C14 C13 H13A 118.7 . .
C12 C13 H13A 118.7 . .
O11 C14 C13 122.0(6) . .
O11 C14 C15 118.4(7) . .
C13 C14 C15 119.6(8) . .
C14 C15 C16 117.4(8) . .
C14 C15 C18 125.5(9) . .
C16 C15 C18 117.2(7) . .
C17 C16 C15 123.4(6) . .
C17 C16 H16A 118.3 . .
C15 C16 H16A 118.3 . .
C16 C17 O12 117.7(7) . .
C16 C17 C12 119.1(8) . .
O12 C17 C12 123.3(8) . .
O10 C18 O9 123.3(9) . .
O10 C18 C15 119.9(7) . .
O9 C18 C15 116.8(10) . .
O11 C19 H19A 109.5 . .
O11 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
O11 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
O12 C20 H20A 109.5 . .
O12 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
O12 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
O15 C21 H21A 109.5 . .
O15 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
O15 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
O15 C22 C24 121.7(6) . 3_577
O15 C22 C23 119.7(6) . .
C24 C22 C23 118.6(6) 3_577 .
C24 C23 C22 118.5(6) . .
C24 C23 C25 117.2(6) . .
C22 C23 C25 124.3(6) . .
C23 C24 C22 122.9(6) . 3_577
O14 C25 O13 123.7(6) . .
O14 C25 C23 118.9(6) . .
O13 C25 C23 117.4(6) . .
O17 C26 O16 120.8(5) . .
O17 C26 C27 120.9(5) . .
O16 C26 C27 118.3(5) . .
O17 C26 Eu1 60.8(3) . .
O16 C26 Eu1 60.3(3) . .
C27 C26 Eu1 172.1(4) . .
C28 C27 C29 119.0(5) . .
C28 C27 C26 116.6(5) . .
C29 C27 C26 124.4(5) . .
C27 C28 C29 122.2(6) . 3_676
O18 C29 C28 121.5(6) . 3_676
O18 C29 C27 119.6(5) . .
C28 C29 C27 118.8(6) 3_676 .
O18 C30 H30A 109.5 . .
O18 C30 H30B 109.5 . .
H30A C30 H30B 109.5 . .
O18 C30 H30C 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
N1 C31 H31A 109.5 . .
N1 C31 H31B 109.5 . .
H31A C31 H31B 109.5 . .
N1 C31 H31C 109.5 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
N1 C32 H32A 109.5 . .
N1 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
N1 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
O23 C33 N1 127.4(19) . .
O23 C33 H33A 116.3 . .
N1 C33 H33A 116.3 . .
C1 O1 Eu1 94.1(4) . .
C1 O2 Eu1 92.2(4) . .
C8 O3 Eu2 163.4(5) . 4_676
C8 O4 Eu1 146.1(5) . 4_576
C10 O5 C4 119.1(7) . .
C9 O6 C7 120.3(7) . .
C11 O7 Eu2 136.2(5) . .
C11 O8 Eu1 160.0(5) . .
C18 O9 Eu1 167.8(7) . 2_656
C18 O10 Eu2 140.3(6) . 2_656
C14 O11 C19 118.3(7) . .
C17 O12 C20 118.8(8) . .
C25 O13 Eu1 144.2(5) . 1_455
C25 O14 Eu2 143.9(4) . .
C22 O15 C21 117.4(6) . .
C26 O16 Eu1 93.5(3) . .
C26 O17 Eu1 93.2(3) . .
C29 O18 C30 118.2(5) . .
C33 N1 C32 121.6(16) . .
C33 N1 C31 122.1(16) . .
C32 N1 C31 116.3(13) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O9 2.268(5) 2_646
Eu1 O8 2.286(4) .
Eu1 O4 2.325(4) 4_575
Eu1 O13 2.338(4) 1_655
Eu1 O1 2.473(4) .
Eu1 O16 2.486(4) .
Eu1 O17 2.496(4) .
Eu1 O2 2.522(4) .
Eu1 C26 2.856(5) .
Eu1 C1 2.862(6) .
Eu2 O3 2.284(6) 4_475
Eu2 O14 2.331(5) .
Eu2 O10 2.366(7) 2_646
Eu2 O7 2.397(5) .
Eu2 O21 2.409(5) .
Eu2 O22 2.430(5) .
Eu2 O20 2.480(5) .
Eu2 O19" 2.575(12) .
Eu2 O19' 2.656(16) .
Eu2 O19 2.71(4) .
C1 O2 1.260(8) .
C1 O1 1.273(8) .
C1 C2 1.494(8) .
C2 C3 1.377(10) .
C2 C7 1.381(10) .
C3 C4 1.396(9) .
C3 H3A 0.9300 .
C4 O5 1.358(10) .
C4 C5 1.380(10) .
C5 C6 1.376(10) .
C5 C8 1.498(8) .
C6 C7 1.409(9) .
C6 H6A 0.9300 .
C7 O6 1.353(9) .
C8 O3 1.239(9) .
C8 O4 1.245(9) .
C9 O6 1.335(13) .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C10 O5 1.325(12) .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
C11 O7 1.238(8) .
C11 O8 1.256(8) .
C11 C12 1.508(10) .
C12 C13 1.391(11) .
C12 C17 1.410(9) .
C13 C14 1.390(11) .
C13 H13A 0.9300 .
C14 O11 1.357(11) .
C14 C15 1.400(10) .
C15 C16 1.400(13) .
C15 C18 1.505(11) .
C16 C17 1.377(12) .
C16 H16A 0.9300 .
C17 O12 1.387(11) .
C18 O10 1.201(13) .
C18 O9 1.224(10) .
C19 O11 1.432(10) .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C20 O12 1.430(14) .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C21 O15 1.415(8) .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C22 O15 1.368(8) .
C22 C24 1.390(9) 3_577
C22 C23 1.422(9) .
C23 C24 1.388(10) .
C23 C25 1.499(9) .
C24 C22 1.390(9) 3_577
C25 O14 1.236(9) .
C25 O13 1.262(8) .
C26 O17 1.256(7) .
C26 O16 1.259(7) .
C26 C27 1.518(7) .
C27 C28 1.389(9) .
C27 C29 1.402(9) .
C28 C29 1.396(8) 3_676
C29 O18 1.361(8) .
C29 C28 1.396(8) 3_676
C30 O18 1.437(10) .
C30 H30A 0.9600 .
C30 H30B 0.9600 .
C30 H30C 0.9600 .
C31 N1 1.49(2) .
C31 H31A 0.9600 .
C31 H31B 0.9600 .
C31 H31C 0.9600 .
C32 N1 1.39(2) .
C32 H32A 0.9600 .
C32 H32B 0.9600 .
C32 H32C 0.9600 .
C33 O23 1.15(2) .
C33 N1 1.266(18) .
C33 H33A 0.9300 .
O3 Eu2 2.284(5) 4_676
O4 Eu1 2.325(4) 4_576
O9 Eu1 2.268(5) 2_656
O10 Eu2 2.366(7) 2_656
O13 Eu1 2.338(4) 1_455
