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#$Date: 2016-03-22 12:37:16 +0200 (Tue, 22 Mar 2016) $
#$Revision: 178956 $
#$URL: svn://www.crystallography.net/cod/cif/4/11/85/4118563.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4118563
loop_
_publ_author_name
'Saskia Stegmaier'
'Markus Waibel'
'Alexander Henze'
'Laura-Alice Jantke'
'Antti J. Karttunen'
'Thomas F. Fässler'
_publ_contact_author_address
;Department Chemie
Technische Universität München
Lichtenbergstr. 4
85747 Garching
Germany
;
_publ_contact_author_email       thomas.faessler@lrz.tu-muenchen.de
_publ_contact_author_fax         '+49 89 28913186'
_publ_contact_author_name        'Prof. Dr. Thomas F. Fässler'
_publ_contact_author_phone       '+49 89 28913134'
_publ_section_title
;
 Soluble Zintl Phases A14ZnGe16 (A= K, Rb) Featuring
 [(η3-Ge4)Zn(η2-Ge4)]6- and [Ge4]4- Clusters and the Isolation of
 [(MesCu)2(η3,η3-Ge4)]4-: The Missing Link in the Solution Chemistry of
 Tetrahedral Group 14 Element Zintl Clusters
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              14450
_journal_page_last               14460
_journal_paper_doi               10.1021/ja304251t
_journal_volume                  134
_journal_year                    2012
_chemical_formula_sum            'Ge16 K14 Zn'
_chemical_formula_weight         1774.21
_space_group_IT_number           31
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      31
_symmetry_space_group_name_Hall  'P 2ac -2'
_symmetry_space_group_name_H-M   'P m n 21'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'manual editing of SHELXL-97 cif-file'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   20.1357(5)
_cell_length_b                   6.9934(2)
_cell_length_c                   14.0398(5)
_cell_measurement_temperature    150
_cell_volume                     1977.04(10)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT A'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0189
_diffrn_reflns_av_sigmaI/netI    0.0239
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            13760
_diffrn_reflns_theta_full        28.28
_diffrn_reflns_theta_max         28.28
_diffrn_reflns_theta_min         1.77
_diffrn_source                   'rotating anode'
_diffrn_source_type              'BRUKER NONIUS FR591'
_exptl_absorpt_coefficient_mu    14.025
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'Bruker 2007, APEX2, SADABS and SAINT, Bruker AXSInc., Madison, Wisconsin (USA)'
_exptl_crystal_colour            'lustrous black'
_exptl_crystal_density_diffrn    2.980
_exptl_crystal_description       block-shaped
_exptl_crystal_F_000             1616
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.06
_refine_diff_density_max         0.517
_refine_diff_density_min         -0.789
_refine_diff_density_rms         0.077
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.161(4)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.970
_refine_ls_matrix_type           full
_refine_ls_number_parameters     152
_refine_ls_number_reflns         4992
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      0.970
_refine_ls_R_factor_all          0.0168
_refine_ls_R_factor_gt           0.0138
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0030P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0186
_refine_ls_wR_factor_ref         0.0189
_reflns_number_gt                4710
_reflns_number_total             4992
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja304251t_si_002.cif
_cod_data_source_block           K14ZnGe16
_cod_database_code               4118563
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y, z+1/2'
'-x, y, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ge1 Ge 0.0000 0.06219(4) 0.67898(2) 0.01300(7) Uani 1 2 d S
Ge2 Ge 0.0000 0.25786(4) 0.53157(2) 0.01340(7) Uani 1 2 d S
Ge3 Ge 0.434191(10) 0.07163(3) 0.040518(18) 0.01555(5) Uani 1 1 d .
Zn1 Zn 0.0000 0.03020(5) 0.38708(3) 0.01322(7) Uani 1 2 d S
Ge4 Ge 0.0000 0.23095(4) 0.22741(2) 0.01425(7) Uani 1 2 d S
Ge5 Ge 0.0000 0.83921(4) 0.22717(2) 0.01413(7) Uani 1 2 d S
Ge6 Ge 0.064537(12) 0.03444(3) 0.105354(17) 0.02029(6) Uani 1 1 d .
Ge7 Ge 0.360584(10) 0.51599(3) 0.373150(19) 0.01463(5) Uani 1 1 d .
Ge8 Ge 0.255926(11) 0.35412(3) 0.439601(17) 0.01458(5) Uani 1 1 d .
Ge9 Ge 0.246988(11) 0.65134(3) 0.331154(17) 0.01646(5) Uani 1 1 d .
Ge10 Ge 0.283018(11) 0.33078(3) 0.262060(17) 0.01626(5) Uani 1 1 d .
K1 K 0.09052(2) 0.54184(6) 0.39192(4) 0.01843(11) Uani 1 1 d .
K2 K 0.14494(2) 0.57019(7) 0.13296(4) 0.02094(10) Uani 1 1 d .
K3 K 0.15504(2) 0.30679(7) 0.63614(4) 0.02918(13) Uani 1 1 d .
K4 K 0.15678(2) 0.04764(6) 0.31313(4) 0.01707(10) Uani 1 1 d .
K5 K 0.24966(2) 0.14689(7) 0.04376(4) 0.02632(12) Uani 1 1 d .
K6 K 0.38387(2) 0.01483(6) 0.36701(4) 0.02046(11) Uani 1 1 d .
K7 K 0.0000 0.45496(13) 0.00000(6) 0.0402(2) Uani 1 2 d S
K8 K 0.0000 0.58750(9) 0.71603(6) 0.02576(17) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge2 Ge1 Ge3 64.113(11) . 3_455
Ge2 Ge1 Ge3 64.113(11) . 2
Ge3 Ge1 Ge3 63.115(12) 3_455 2
Ge2 Ge1 K8 132.377(19) . 1_545
Ge3 Ge1 K8 75.740(14) 3_455 1_545
Ge3 Ge1 K8 75.740(14) 2 1_545
Ge2 Ge1 K6 134.469(10) . 2
Ge3 Ge1 K6 148.801(14) 3_455 2
Ge3 Ge1 K6 99.745(11) 2 2
K8 Ge1 K6 74.710(13) 1_545 2
Ge2 Ge1 K6 134.469(10) . 3_455
Ge3 Ge1 K6 99.745(10) 3_455 3_455
Ge3 Ge1 K6 148.801(14) 2 3_455
K8 Ge1 K6 74.710(13) 1_545 3_455
K6 Ge1 K6 81.913(18) 2 3_455
Ge2 Ge1 K3 66.403(11) . .
Ge3 Ge1 K3 119.985(14) 3_455 .
Ge3 Ge1 K3 66.088(10) 2 .
K8 Ge1 K3 119.597(10) 1_545 .
K6 Ge1 K3 68.162(12) 2 .
K6 Ge1 K3 139.608(15) 3_455 .
Ge2 Ge1 K3 66.403(11) . 4
Ge3 Ge1 K3 66.088(10) 3_455 4
Ge3 Ge1 K3 119.985(14) 2 4
K8 Ge1 K3 119.597(10) 1_545 4
K6 Ge1 K3 139.608(15) 2 4
K6 Ge1 K3 68.162(12) 3_455 4
K3 Ge1 K3 119.70(2) . 4
Ge2 Ge1 K8 64.587(15) . .
Ge3 Ge1 K8 118.269(14) 3_455 .
Ge3 Ge1 K8 118.269(14) 2 .
K8 Ge1 K8 163.04(3) 1_545 .
K6 Ge1 K8 92.623(13) 2 .
K6 Ge1 K8 92.623(13) 3_455 .
K3 Ge1 K8 63.526(10) . .
K3 Ge1 K8 63.526(10) 4 .
Ge1 Ge2 Zn1 108.403(14) . .
Ge1 Ge2 Ge3 58.874(10) . 3_455
Zn1 Ge2 Ge3 60.167(10) . 3_455
Ge1 Ge2 Ge3 58.874(10) . 2
Zn1 Ge2 Ge3 60.167(10) . 2
Ge3 Ge2 Ge3 59.732(11) 3_455 2
Ge1 Ge2 K1 145.014(10) . 4
Zn1 Ge2 K1 84.554(13) . 4
Ge3 Ge2 K1 105.746(11) 3_455 4
Ge3 Ge2 K1 144.682(16) 2 4
Ge1 Ge2 K1 145.013(10) . .
Zn1 Ge2 K1 84.554(13) . .
Ge3 Ge2 K1 144.682(16) 3_455 .
Ge3 Ge2 K1 105.746(10) 2 .
K1 Ge2 K1 66.296(17) 4 .
Ge1 Ge2 K3 72.614(11) . .
Zn1 Ge2 K3 113.209(10) . .
Ge3 Ge2 K3 120.926(13) 3_455 .
Ge3 Ge2 K3 67.485(11) 2 .
K1 Ge2 K3 133.054(14) 4 .
K1 Ge2 K3 72.416(13) . .
Ge1 Ge2 K3 72.614(11) . 4
Zn1 Ge2 K3 113.210(10) . 4
Ge3 Ge2 K3 67.485(11) 3_455 4
Ge3 Ge2 K3 120.926(13) 2 4
K1 Ge2 K3 72.417(13) 4 4
K1 Ge2 K3 133.055(14) . 4
K3 Ge2 K3 128.45(2) . 4
Ge1 Ge2 K8 75.146(17) . .
Zn1 Ge2 K8 176.451(18) . .
Ge3 Ge2 K8 122.718(15) 3_455 .
Ge3 Ge2 K8 122.717(15) 2 .
K1 Ge2 K8 92.478(14) 4 .
K1 Ge2 K8 92.478(15) . .
K3 Ge2 K8 67.545(11) . .
K3 Ge2 K8 67.545(11) 4 .
Ge1 Ge3 Zn1 105.389(10) 2_554 2_554
Ge1 Ge3 Ge3 58.443(6) 2_554 4_655
Zn1 Ge3 Ge3 59.713(6) 2_554 4_655
Ge1 Ge3 Ge2 57.014(11) 2_554 2_554
Zn1 Ge3 Ge2 58.365(11) 2_554 2_554
Ge3 Ge3 Ge2 60.135(6) 4_655 2_554
Ge1 Ge3 K1 146.017(13) 2_554 2_564
Zn1 Ge3 K1 77.838(12) 2_554 2_564
Ge3 Ge3 K1 98.289(8) 4_655 2_564
Ge2 Ge3 K1 136.186(14) 2_554 2_564
Ge1 Ge3 K3 72.057(11) 2_554 2_554
Zn1 Ge3 K3 111.822(14) 2_554 2_554
Ge3 Ge3 K3 121.193(9) 4_655 2_554
Ge2 Ge3 K3 67.392(11) 2_554 2_554
K1 Ge3 K3 139.195(13) 2_564 2_554
Ge1 Ge3 K8 62.375(13) 2_554 2_564
Zn1 Ge3 K8 122.930(11) 2_554 2_564
Ge3 Ge3 K8 68.869(5) 4_655 2_564
Ge2 Ge3 K8 114.437(12) 2_554 2_564
K1 Ge3 K8 87.091(14) 2_564 2_564
K3 Ge3 K8 114.962(16) 2_554 2_564
Ge1 Ge3 K5 124.101(12) 2_554 .
Zn1 Ge3 K5 123.179(13) 2_554 .
Ge3 Ge3 K5 171.908(8) 4_655 .
Ge2 Ge3 K5 127.952(10) 2_554 .
K1 Ge3 K5 75.803(12) 2_564 .
K3 Ge3 K5 65.766(12) 2_554 .
K8 Ge3 K5 104.942(10) 2_564 .
Ge1 Ge3 K4 145.265(12) 2_554 2_554
Zn1 Ge3 K4 59.424(10) 2_554 2_554
Ge3 Ge3 K4 119.036(8) 4_655 2_554
Ge2 Ge3 K4 90.595(11) 2_554 2_554
K1 Ge3 K4 65.904(11) 2_564 2_554
K3 Ge3 K4 84.686(12) 2_554 2_554
K8 Ge3 K4 152.303(14) 2_564 2_554
K5 Ge3 K4 63.943(12) . 2_554
Ge2 Zn1 Ge5 172.625(17) . 1_545
Ge2 Zn1 Ge3 61.469(11) . 2
Ge5 Zn1 Ge3 124.473(12) 1_545 2
Ge2 Zn1 Ge3 61.469(11) . 3_455
Ge5 Zn1 Ge3 124.473(13) 1_545 3_455
Ge3 Zn1 Ge3 60.575(12) 2 3_455
Ge2 Zn1 Ge4 109.818(15) . .
Ge5 Zn1 Ge4 62.808(13) 1_545 .
Ge3 Zn1 Ge4 147.004(8) 2 .
Ge3 Zn1 Ge4 147.004(8) 3_455 .
Ge2 Zn1 K4 102.882(10) . 4
Ge5 Zn1 K4 75.549(11) 1_545 4
Ge3 Zn1 K4 138.131(14) 2 4
Ge3 Zn1 K4 77.709(10) 3_455 4
Ge4 Zn1 K4 73.498(10) . 4
Ge2 Zn1 K4 102.883(10) . .
Ge5 Zn1 K4 75.549(11) 1_545 .
Ge3 Zn1 K4 77.709(10) 2 .
Ge3 Zn1 K4 138.131(14) 3_455 .
Ge4 Zn1 K4 73.497(10) . .
K4 Zn1 K4 143.36(2) 4 .
Ge2 Zn1 K1 122.059(14) . 4_545
Ge5 Zn1 K1 64.155(11) 1_545 4_545
Ge3 Zn1 K1 89.080(12) 2 4_545
Ge3 Zn1 K1 60.602(10) 3_455 4_545
Ge4 Zn1 K1 118.885(14) . 4_545
K4 Zn1 K1 65.855(11) 4 4_545
K4 Zn1 K1 118.993(13) . 4_545
Ge2 Zn1 K1 122.059(14) . 1_545
Ge5 Zn1 K1 64.155(11) 1_545 1_545
Ge3 Zn1 K1 60.602(10) 2 1_545
Ge3 Zn1 K1 89.080(12) 3_455 1_545
Ge4 Zn1 K1 118.885(14) . 1_545
K4 Zn1 K1 118.993(13) 4 1_545
K4 Zn1 K1 65.855(11) . 1_545
K1 Zn1 K1 56.164(14) 4_545 1_545
Ge2 Zn1 K1 55.712(11) . 4
Ge5 Zn1 K1 118.039(13) 1_545 4
Ge3 Zn1 K1 117.161(14) 2 4
Ge3 Zn1 K1 89.927(11) 3_455 4
Ge4 Zn1 K1 62.707(11) . 4
K4 Zn1 K1 62.728(10) 4 4
K4 Zn1 K1 113.792(13) . 4
K1 Zn1 K1 124.887(12) 4_545 4
K1 Zn1 K1 177.743(16) 1_545 4
Ge2 Zn1 K1 55.713(11) . .
Ge5 Zn1 K1 118.038(13) 1_545 .
Ge3 Zn1 K1 89.927(11) 2 .
Ge3 Zn1 K1 117.162(14) 3_455 .
Ge4 Zn1 K1 62.706(11) . .
K4 Zn1 K1 113.793(13) 4 .
K4 Zn1 K1 62.727(10) . .
K1 Zn1 K1 177.744(16) 4_545 .
K1 Zn1 K1 124.887(12) 1_545 .
K1 Zn1 K1 53.979(13) 4 .
Ge6 Ge4 Ge6 61.216(13) . 4
Ge6 Ge4 Zn1 106.453(13) . .
Ge6 Ge4 Zn1 106.454(13) 4 .
Ge6 Ge4 Ge5 57.366(10) . 1_545
Ge6 Ge4 Ge5 57.367(10) 4 1_545
Zn1 Ge4 Ge5 58.010(12) . 1_545
Ge6 Ge4 K7 68.558(16) . .
Ge6 Ge4 K7 68.557(16) 4 .
Zn1 Ge4 K7 174.08(2) . .
Ge5 Ge4 K7 116.07(2) 1_545 .
Ge6 Ge4 K4 118.517(13) . 4
Ge6 Ge4 K4 65.657(10) 4 4
Zn1 Ge4 K4 61.926(9) . 4
Ge5 Ge4 K4 69.244(9) 1_545 4
K7 Ge4 K4 117.085(10) . 4
Ge6 Ge4 K4 65.656(10) . .
Ge6 Ge4 K4 118.516(13) 4 .
Zn1 Ge4 K4 61.927(9) . .
Ge5 Ge4 K4 69.244(9) 1_545 .
K7 Ge4 K4 117.085(10) . .
K4 Ge4 K4 121.761(17) 4 .
Ge6 Ge4 K1 176.014(15) . 4
Ge6 Ge4 K1 119.357(9) 4 4
Zn1 Ge4 K1 77.311(12) . 4
Ge5 Ge4 K1 126.515(13) 1_545 4
K7 Ge4 K1 107.760(17) . 4
K4 Ge4 K1 64.234(11) 4 4
K4 Ge4 K1 115.835(14) . 4
Ge6 Ge4 K1 119.356(9) . .
Ge6 Ge4 K1 176.013(15) 4 .
Zn1 Ge4 K1 77.312(12) . .
Ge5 Ge4 K1 126.515(12) 1_545 .
K7 Ge4 K1 107.759(17) . .
K4 Ge4 K1 115.835(14) 4 .
K4 Ge4 K1 64.234(11) . .
K1 Ge4 K1 59.763(15) 4 .
Ge6 Ge4 K2 118.015(14) . 4
Ge6 Ge4 K2 74.007(10) 4 4
Zn1 Ge4 K2 126.695(10) . 4
Ge5 Ge4 K2 126.478(9) 1_545 4
K7 Ge4 K2 55.906(11) . 4
K4 Ge4 K2 71.489(10) 4 4
K4 Ge4 K2 163.970(12) . 4
K1 Ge4 K2 59.456(11) 4 4
K1 Ge4 K2 102.766(12) . 4
Ge6 Ge4 K2 74.007(10) . .
Ge6 Ge4 K2 118.015(14) 4 .
Zn1 Ge4 K2 126.694(10) . .
Ge5 Ge4 K2 126.477(9) 1_545 .
K7 Ge4 K2 55.906(11) . .
K4 Ge4 K2 163.971(12) 4 .
K4 Ge4 K2 71.487(10) . .
K1 Ge4 K2 102.767(12) 4 .
K1 Ge4 K2 59.455(11) . .
K2 Ge4 K2 94.077(15) 4 .
Ge6 Ge5 Ge6 61.402(13) 4_565 1_565
Ge6 Ge5 Zn1 107.653(13) 4_565 1_565
Ge6 Ge5 Zn1 107.653(13) 1_565 1_565
Ge6 Ge5 Ge4 57.613(10) 4_565 1_565
Ge6 Ge5 Ge4 57.613(10) 1_565 1_565
Zn1 Ge5 Ge4 59.182(12) 1_565 1_565
Ge6 Ge5 K1 177.086(15) 4_565 .
Ge6 Ge5 K1 118.846(9) 1_565 .
Zn1 Ge5 K1 75.142(12) 1_565 .
Ge4 Ge5 K1 125.177(12) 1_565 .
Ge6 Ge5 K1 118.847(9) 4_565 4
Ge6 Ge5 K1 177.086(15) 1_565 4
Zn1 Ge5 K1 75.141(12) 1_565 4
Ge4 Ge5 K1 125.177(12) 1_565 4
K1 Ge5 K1 60.738(15) . 4
Ge6 Ge5 K4 116.475(13) 4_565 1_565
Ge6 Ge5 K4 64.533(10) 1_565 1_565
Zn1 Ge5 K4 61.034(9) 1_565 1_565
Ge4 Ge5 K4 66.645(9) 1_565 1_565
K1 Ge5 K4 65.446(11) . 1_565
K1 Ge5 K4 116.852(14) 4 1_565
Ge6 Ge5 K4 64.533(10) 4_565 4_565
Ge6 Ge5 K4 116.475(13) 1_565 4_565
Zn1 Ge5 K4 61.034(9) 1_565 4_565
Ge4 Ge5 K4 66.645(9) 1_565 4_565
K1 Ge5 K4 116.853(14) . 4_565
K1 Ge5 K4 65.447(11) 4 4_565
K4 Ge5 K4 118.116(17) 1_565 4_565
Ge6 Ge5 K2 68.369(10) 4_565 4
Ge6 Ge5 K2 115.683(14) 1_565 4
Zn1 Ge5 K2 124.390(10) 1_565 4
Ge4 Ge5 K2 120.448(10) 1_565 4
K1 Ge5 K2 109.476(13) . 4
K1 Ge5 K2 62.563(12) 4 4
K4 Ge5 K2 172.270(13) 1_565 4
K4 Ge5 K2 69.121(11) 4_565 4
Ge6 Ge5 K2 115.683(14) 4_565 .
Ge6 Ge5 K2 68.369(10) 1_565 .
Zn1 Ge5 K2 124.390(10) 1_565 .
Ge4 Ge5 K2 120.448(10) 1_565 .
K1 Ge5 K2 62.562(12) . .
K1 Ge5 K2 109.475(13) 4 .
K4 Ge5 K2 69.120(10) 1_565 .
K4 Ge5 K2 172.270(13) 4_565 .
K2 Ge5 K2 103.521(17) 4 .
Ge5 Ge6 Ge4 65.020(11) 1_545 .
Ge5 Ge6 Ge6 59.299(6) 1_545 4
Ge4 Ge6 Ge6 59.393(7) . 4
Ge5 Ge6 K4 73.846(11) 1_545 .
Ge4 Ge6 K4 72.111(11) . .
Ge6 Ge6 K4 122.472(9) 4 .
Ge5 Ge6 K6 137.464(14) 1_545 2_554
Ge4 Ge6 K6 147.255(13) . 2_554
Ge6 Ge6 K6 107.162(8) 4 2_554
K4 Ge6 K6 130.213(13) . 2_554
Ge5 Ge6 K7 122.624(12) 1_545 .
Ge4 Ge6 K7 69.279(17) . .
Ge6 Ge6 K7 68.457(6) 4 .
K4 Ge6 K7 121.828(18) . .
K6 Ge6 K7 78.022(17) 2_554 .
Ge5 Ge6 K2 71.205(11) 1_545 1_545
Ge4 Ge6 K2 129.328(13) . 1_545
Ge6 Ge6 K2 116.341(8) 4 1_545
K4 Ge6 K2 72.299(12) . 1_545
K6 Ge6 K2 83.278(12) 2_554 1_545
K7 Ge6 K2 161.220(19) . 1_545
Ge5 Ge6 K5 138.066(12) 1_545 .
Ge4 Ge6 K5 121.739(12) . .
Ge6 Ge6 K5 162.589(9) 4 .
K4 Ge6 K5 70.671(12) . .
K6 Ge6 K5 61.819(12) 2_554 .
K7 Ge6 K5 95.196(11) . .
K2 Ge6 K5 77.249(11) 1_545 .
Ge9 Ge7 Ge10 59.900(9) . .
Ge9 Ge7 Ge8 60.689(8) . .
Ge10 Ge7 Ge8 59.831(9) . .
Ge9 Ge7 K7 149.181(17) . 2_565
Ge10 Ge7 K7 150.589(17) . 2_565
Ge8 Ge7 K7 121.624(18) . 2_565
Ge9 Ge7 K6 75.253(11) . 1_565
Ge10 Ge7 K6 124.595(12) . 1_565
Ge8 Ge7 K6 123.710(12) . 1_565
K7 Ge7 K6 80.818(19) 2_565 1_565
Ge9 Ge7 K6 118.821(11) . .
Ge10 Ge7 K6 64.186(11) . .
Ge8 Ge7 K6 71.386(10) . .
K7 Ge7 K6 87.809(18) 2_565 .
K6 Ge7 K6 164.474(16) 1_565 .
Ge9 Ge7 K3 64.854(11) . 2_564
Ge10 Ge7 K3 63.463(11) . 2_564
Ge8 Ge7 K3 114.837(11) . 2_564
K7 Ge7 K3 123.524(18) 2_565 2_564
K6 Ge7 K3 69.170(13) 1_565 2_564
K6 Ge7 K3 109.477(14) . 2_564
Ge9 Ge7 K8 128.775(15) . 2_564
Ge10 Ge7 K8 90.040(13) . 2_564
Ge8 Ge7 K8 139.899(14) . 2_564
K7 Ge7 K8 71.725(17) 2_565 2_564
K6 Ge7 K8 94.555(14) 1_565 2_564
K6 Ge7 K8 71.713(14) . 2_564
K3 Ge7 K8 64.648(14) 2_564 2_564
Ge9 Ge7 K2 105.195(11) . 2_565
Ge10 Ge7 K2 120.015(12) . 2_565
Ge8 Ge7 K2 62.946(10) . 2_565
K7 Ge7 K2 60.524(16) 2_565 2_565
K6 Ge7 K2 100.929(13) 1_565 2_565
K6 Ge7 K2 82.333(12) . 2_565
K3 Ge7 K2 167.046(13) 2_564 2_565
K8 Ge7 K2 126.012(14) 2_564 2_565
Ge10 Ge8 Ge7 59.921(9) . .
Ge10 Ge8 Ge9 59.439(9) . .
Ge7 Ge8 Ge9 59.217(8) . .
Ge10 Ge8 K2 131.371(13) . 2_565
Ge7 Ge8 K2 74.957(11) . 2_565
Ge9 Ge8 K2 112.648(12) . 2_565
Ge10 Ge8 K4 65.105(11) . .
Ge7 Ge8 K4 124.464(13) . .
Ge9 Ge8 K4 99.055(12) . .
K2 Ge8 K4 148.296(14) 2_565 .
Ge10 Ge8 K3 154.317(13) . .
Ge7 Ge8 K3 144.883(13) . .
Ge9 Ge8 K3 120.583(13) . .
K2 Ge8 K3 73.878(13) 2_565 .
K4 Ge8 K3 90.653(13) . .
Ge10 Ge8 K1 92.230(12) . .
Ge7 Ge8 K1 121.659(12) . .
Ge9 Ge8 K1 62.473(10) . .
K2 Ge8 K1 128.723(13) 2_565 .
K4 Ge8 K1 66.249(11) . .
K3 Ge8 K1 69.044(13) . .
Ge10 Ge8 K6 62.316(11) . .
Ge7 Ge8 K6 66.772(10) . .
Ge9 Ge8 K6 114.079(11) . .
K2 Ge8 K6 84.836(13) 2_565 .
K4 Ge8 K6 81.938(12) . .
K3 Ge8 K6 125.323(14) . .
K1 Ge8 K6 145.992(13) . .
Ge10 Ge8 K5 116.221(12) . 2_565
Ge7 Ge8 K5 76.015(11) . 2_565
Ge9 Ge8 K5 58.922(11) . 2_565
K2 Ge8 K5 64.332(12) 2_565 2_565
K4 Ge8 K5 139.449(13) . 2_565
K3 Ge8 K5 76.198(13) . 2_565
K1 Ge8 K5 73.237(11) . 2_565
K6 Ge8 K5 136.769(12) . 2_565
Ge10 Ge8 K5 108.831(12) . 2
Ge7 Ge8 K5 124.810(12) . 2
Ge9 Ge8 K5 165.294(12) . 2
K2 Ge8 K5 81.607(12) 2_565 2
K4 Ge8 K5 66.741(12) . 2
K3 Ge8 K5 65.495(13) . 2
K1 Ge8 K5 112.098(12) . 2
K6 Ge8 K5 61.864(11) . 2
K5 Ge8 K5 134.486(17) 2_565 2
Ge7 Ge9 Ge10 60.333(9) . .
Ge7 Ge9 Ge8 60.094(8) . .
Ge10 Ge9 Ge8 59.773(9) . .
Ge7 Ge9 K5 86.049(12) . 2_565
Ge10 Ge9 K5 135.577(13) . 2_565
Ge8 Ge9 K5 79.023(11) . 2_565
Ge7 Ge9 K4 144.998(12) . 1_565
Ge10 Ge9 K4 149.353(14) . 1_565
Ge8 Ge9 K4 138.945(12) . 1_565
K5 Ge9 K4 73.958(13) 2_565 1_565
Ge7 Ge9 K1 134.489(13) . .
Ge10 Ge9 K1 99.409(12) . .
Ge8 Ge9 K1 74.436(11) . .
K5 Ge9 K1 83.502(13) 2_565 .
K4 Ge9 K1 72.315(12) 1_565 .
Ge7 Ge9 K3 72.298(12) . 2_564
Ge10 Ge9 K3 66.579(12) . 2_564
Ge8 Ge9 K3 120.362(12) . 2_564
K5 Ge9 K3 132.981(14) 2_565 2_564
K4 Ge9 K3 100.645(14) 1_565 2_564
K1 Ge9 K3 140.598(15) . 2_564
Ge7 Ge9 K2 130.589(13) . .
Ge10 Ge9 K2 73.875(11) . .
Ge8 Ge9 K2 112.242(12) . .
K5 Ge9 K2 143.006(13) 2_565 .
K4 Ge9 K2 75.770(12) 1_565 .
K1 Ge9 K2 67.302(13) . .
K3 Ge9 K2 73.368(13) 2_564 .
Ge7 Ge9 K6 64.168(10) . 1_565
Ge10 Ge9 K6 115.747(11) . 1_565
Ge8 Ge9 K6 114.302(11) . 1_565
K5 Ge9 K6 65.021(12) 2_565 1_565
K4 Ge9 K6 81.255(11) 1_565 1_565
K1 Ge9 K6 143.538(13) . 1_565
K3 Ge9 K6 67.985(12) 2_564 1_565
K2 Ge9 K6 129.903(13) . 1_565
Ge9 Ge10 Ge8 60.787(9) . .
Ge9 Ge10 Ge7 59.768(8) . .
Ge8 Ge10 Ge7 60.248(9) . .
Ge9 Ge10 K4 103.049(12) . .
Ge8 Ge10 K4 70.259(11) . .
Ge7 Ge10 K4 129.877(13) . .
Ge9 Ge10 K3 68.862(12) . 2_564
Ge8 Ge10 K3 123.262(13) . 2_564
Ge7 Ge10 K3 73.140(12) . 2_564
K4 Ge10 K3 149.283(14) . 2_564
Ge9 Ge10 K6 125.917(13) . .
Ge8 Ge10 K6 75.056(12) . .
Ge7 Ge10 K6 72.254(11) . .
K4 Ge10 K6 88.598(12) . .
K3 Ge10 K6 120.607(13) 2_564 .
Ge9 Ge10 K5 128.414(13) . .
Ge8 Ge10 K5 149.665(13) . .
Ge7 Ge10 K5 149.732(13) . .
K4 Ge10 K5 79.414(13) . .
K3 Ge10 K5 83.288(14) 2_564 .
K6 Ge10 K5 105.547(14) . .
Ge9 Ge10 K2 64.940(11) . .
Ge8 Ge10 K2 106.679(12) . .
Ge7 Ge10 K2 121.713(11) . .
K4 Ge10 K2 78.471(12) . .
K3 Ge10 K2 71.260(12) 2_564 .
K6 Ge10 K2 165.210(13) . .
K5 Ge10 K2 65.288(12) . .
Ge2 K1 Ge9 143.093(16) . .
Ge2 K1 Ge3 91.848(14) . 2_565
Ge9 K1 Ge3 96.338(12) . 2_565
Ge2 K1 Ge5 116.401(13) . .
Ge9 K1 Ge5 100.376(13) . .
Ge3 K1 Ge5 82.132(12) 2_565 .
Ge2 K1 Ge8 100.204(13) . .
Ge9 K1 Ge8 43.091(7) . .
Ge3 K1 Ge8 107.641(14) 2_565 .
Ge5 K1 Ge8 142.019(15) . .
Ge2 K1 K1 56.851(9) . 4
Ge9 K1 K1 160.007(9) . 4
Ge3 K1 K1 81.710(8) 2_565 4
Ge5 K1 K1 59.631(8) . 4
Ge8 K1 K1 156.133(8) . 4
Ge2 K1 Ge4 75.219(11) . .
Ge9 K1 Ge4 116.314(14) . .
Ge3 K1 Ge4 140.844(14) 2_565 .
Ge5 K1 Ge4 71.692(11) . .
Ge8 K1 Ge4 110.945(12) . .
K1 K1 Ge4 60.118(8) 4 .
Ge2 K1 K2 138.686(16) . .
Ge9 K1 K2 58.263(11) . .
Ge3 K1 K2 125.366(15) 2_565 .
Ge5 K1 K2 60.144(11) . .
Ge8 K1 K2 86.044(12) . .
K1 K1 K2 106.750(10) 4 .
Ge4 K1 K2 64.590(12) . .
Ge2 K1 K4 79.885(12) . .
Ge9 K1 K4 78.878(12) . .
Ge3 K1 K4 157.365(17) 2_565 .
Ge5 K1 K4 120.437(16) . .
Ge8 K1 K4 54.184(10) . .
K1 K1 K4 110.187(9) 4 .
Ge4 K1 K4 57.321(10) . .
K2 K1 K4 70.951(13) . .
Ge2 K1 Zn1 106.168(13) . 1_565
Ge9 K1 Zn1 103.676(12) . 1_565
Ge3 K1 Zn1 41.559(8) 2_565 1_565
Ge5 K1 Zn1 40.703(9) . 1_565
Ge8 K1 Zn1 138.734(13) . 1_565
K1 K1 Zn1 61.918(7) 4 1_565
Ge4 K1 Zn1 106.178(13) . 1_565
K2 K1 Zn1 94.181(14) . 1_565
K4 K1 Zn1 161.075(17) . 1_565
Ge2 K1 K4 152.303(17) . 1_565
Ge9 K1 K4 53.498(10) . 1_565
Ge3 K1 K4 60.996(11) 2_565 1_565
Ge5 K1 K4 58.201(10) . 1_565
Ge8 K1 K4 93.759(12) . 1_565
K1 K1 K4 109.798(9) 4 1_565
Ge4 K1 K4 121.679(16) . 1_565
K2 K1 K4 65.612(12) . 1_565
K4 K1 K4 127.268(17) . 1_565
Zn1 K1 K4 50.386(9) 1_565 1_565
Ge2 K1 Zn1 39.733(9) . .
Ge9 K1 Zn1 128.732(13) . .
Ge3 K1 Zn1 129.994(14) 2_565 .
Ge5 K1 Zn1 105.882(12) . .
Ge8 K1 Zn1 95.567(11) . .
K1 K1 Zn1 63.010(7) 4 .
Ge4 K1 Zn1 39.982(8) . .
K2 K1 Zn1 99.270(14) . .
K4 K1 Zn1 49.862(9) . .
Zn1 K1 Zn1 124.886(12) 1_565 .
K4 K1 Zn1 161.629(17) 1_565 .
Ge8 K2 Ge9 105.285(13) 2_564 .
Ge8 K2 K7 95.603(18) 2_564 .
Ge9 K2 K7 159.11(2) . .
Ge8 K2 Ge6 92.122(13) 2_564 1_565
Ge9 K2 Ge6 101.559(13) . 1_565
K7 K2 Ge6 77.395(18) . 1_565
Ge8 K2 Ge7 42.095(8) 2_564 2_564
Ge9 K2 Ge7 145.776(14) . 2_564
K7 K2 Ge7 54.611(14) . 2_564
Ge6 K2 Ge7 91.540(13) 1_565 2_564
Ge8 K2 Ge5 131.636(16) 2_564 .
Ge9 K2 Ge5 95.501(14) . .
K7 K2 Ge5 69.945(17) . .
Ge6 K2 Ge5 40.426(8) 1_565 .
Ge7 K2 Ge5 114.202(14) 2_564 .
Ge8 K2 Ge10 91.161(11) 2_564 .
Ge9 K2 Ge10 41.186(7) . .
K7 K2 Ge10 140.13(2) . .
Ge6 K2 Ge10 141.670(15) 1_565 .
Ge7 K2 Ge10 115.464(13) 2_564 .
Ge5 K2 Ge10 129.936(17) . .
Ge8 K2 K1 159.675(17) 2_564 .
Ge9 K2 K1 54.434(11) . .
K7 K2 K1 104.687(18) . .
Ge6 K2 K1 91.153(13) 1_565 .
Ge7 K2 K1 157.787(15) 2_564 .
Ge5 K2 K1 57.294(11) . .
Ge10 K2 K1 74.089(13) . .
Ge8 K2 K5 62.563(12) 2_564 .
Ge9 K2 K5 93.540(13) . .
K7 K2 K5 96.01(2) . .
Ge6 K2 K5 153.382(18) 1_565 .
Ge7 K2 K5 64.516(12) 2_564 .
Ge5 K2 K5 159.504(16) . .
Ge10 K2 K5 53.256(11) . .
K1 K2 K5 115.430(16) . .
Ge8 K2 Ge4 141.740(16) 2_564 .
Ge9 K2 Ge4 105.151(14) . .
K7 K2 Ge4 55.893(14) . .
Ge6 K2 Ge4 103.885(12) 1_565 .
Ge7 K2 Ge4 102.063(12) 2_564 .
Ge5 K2 Ge4 66.924(9) . .
Ge10 K2 Ge4 96.736(12) . .
K1 K2 Ge4 55.956(10) . .
K5 K2 Ge4 92.959(13) . .
Ge8 K2 K3 53.413(11) 2_564 2_564
Ge9 K2 K3 52.000(11) . 2_564
K7 K2 K3 148.80(2) . 2_564
Ge6 K2 K3 104.429(14) 1_565 2_564
Ge7 K2 K3 94.250(13) 2_564 2_564
Ge5 K2 K3 131.181(15) . 2_564
Ge10 K2 K3 50.014(10) . 2_564
K1 K2 K3 106.400(16) . 2_564
K5 K2 K3 68.162(13) . 2_564
Ge4 K2 K3 146.750(15) . 2_564
Ge8 K2 K4 108.851(14) 2_564 1_565
Ge9 K2 K4 50.154(10) . 1_565
K7 K2 K4 122.91(2) . 1_565
Ge6 K2 K4 51.766(10) 1_565 1_565
Ge7 K2 K4 136.546(15) 2_564 1_565
Ge5 K2 K4 55.045(10) . 1_565
Ge10 K2 K4 91.259(13) . 1_565
K1 K2 K4 58.762(12) . 1_565
K5 K2 K4 141.084(15) . 1_565
Ge4 K2 K4 108.332(14) . 1_565
K3 K2 K4 76.802(13) 2_564 1_565
Ge10 K3 Ge9 44.559(9) 2_565 2_565
Ge10 K3 Ge8 97.541(13) 2_565 .
Ge9 K3 Ge8 107.211(13) 2_565 .
Ge10 K3 Ge2 129.552(17) 2_565 .
Ge9 K3 Ge2 151.081(18) 2_565 .
Ge8 K3 Ge2 101.621(16) . .
Ge10 K3 Ge3 168.347(18) 2_565 2
Ge9 K3 Ge3 132.875(18) 2_565 2
Ge8 K3 Ge3 93.943(15) . 2
Ge2 K3 Ge3 45.123(8) . 2
Ge10 K3 Ge7 43.397(8) 2_565 2_565
Ge9 K3 Ge7 42.847(9) 2_565 2_565
Ge8 K3 Ge7 140.073(15) . 2_565
Ge2 K3 Ge7 110.499(14) . 2_565
Ge3 K3 Ge7 125.508(15) 2 2_565
Ge10 K3 Ge1 126.559(17) 2_565 .
Ge9 K3 Ge1 114.200(17) 2_565 .
Ge8 K3 Ge1 133.582(17) . .
Ge2 K3 Ge1 40.983(9) . .
Ge3 K3 Ge1 41.855(8) 2 .
Ge7 K3 Ge1 86.155(13) 2_565 .
Ge10 K3 K8 76.196(14) 2_565 .
Ge9 K3 K8 101.097(18) 2_565 .
Ge8 K3 K8 131.47(2) . .
Ge2 K3 K8 56.234(13) . .
Ge3 K3 K8 94.686(14) 2 .
Ge7 K3 K8 58.658(14) 2_565 .
Ge1 K3 K8 59.503(12) . .
Ge10 K3 K5 127.345(16) 2_565 2
Ge9 K3 K5 92.990(15) 2_565 2
Ge8 K3 K5 61.623(12) . 2
Ge2 K3 K5 102.731(15) . 2
Ge3 K3 K5 60.598(11) 2 2
Ge7 K3 K5 129.205(18) 2_565 2
Ge1 K3 K5 95.436(14) . 2
K8 K3 K5 154.565(17) . 2
Ge10 K3 K1 105.222(15) 2_565 .
Ge9 K3 K1 147.421(16) 2_565 .
Ge8 K3 K1 57.823(12) . .
Ge2 K3 K1 52.257(11) . .
Ge3 K3 K1 79.303(13) 2 .
Ge7 K3 K1 128.740(16) 2_565 .
Ge1 K3 K1 93.235(14) . .
K8 K3 K1 77.181(16) . .
K5 K3 K1 101.924(16) 2 .
Ge10 K3 K6 94.055(15) 2_565 2
Ge9 K3 K6 60.687(12) 2_565 2
Ge8 K3 K6 144.551(18) . 2
Ge2 K3 K6 96.355(13) . 2
Ge3 K3 K6 77.550(13) 2 2
Ge7 K3 K6 54.902(11) 2_565 2
Ge1 K3 K6 55.416(11) . 2
K8 K3 K6 83.833(16) . 2
K5 K3 K6 84.810(15) 2 2
K1 K3 K6 148.585(15) . 2
Ge10 K3 K2 58.727(11) 2_565 2_565
Ge9 K3 K2 54.632(11) 2_565 2_565
Ge8 K3 K2 52.711(10) . 2_565
Ge2 K3 K2 153.717(19) . 2_565
Ge3 K3 K2 131.422(16) 2 2_565
Ge7 K3 K2 91.362(13) 2_565 2_565
Ge1 K3 K2 161.150(18) . 2_565
K8 K3 K2 133.532(18) . 2_565
K5 K3 K2 71.784(13) 2 2_565
K1 K3 K2 102.794(15) . 2_565
K6 K3 K2 108.420(16) 2 2_565
Ge10 K4 Ge9 95.503(12) . 1_545
Ge10 K4 Zn1 145.169(16) . .
Ge9 K4 Zn1 117.679(14) 1_545 .
Ge10 K4 Ge8 44.636(8) . .
Ge9 K4 Ge8 99.429(13) 1_545 .
Zn1 K4 Ge8 114.483(16) . .
Ge10 K4 Ge6 104.256(14) . .
Ge9 K4 Ge6 109.595(14) 1_545 .
Zn1 K4 Ge6 75.677(12) . .
Ge8 K4 Ge6 140.061(15) . .
Ge10 K4 Ge4 112.802(14) . .
Ge9 K4 Ge4 143.006(16) 1_545 .
Zn1 K4 Ge4 44.576(9) . .
Ge8 K4 Ge4 117.377(14) . .
Ge6 K4 Ge4 42.233(8) . .
Ge10 K4 Ge5 145.772(17) . 1_545
Ge9 K4 Ge5 99.408(13) 1_545 1_545
Zn1 K4 Ge5 43.417(9) . 1_545
Ge8 K4 Ge5 156.593(16) . 1_545
Ge6 K4 Ge5 41.622(8) . 1_545
Ge4 K4 Ge5 44.110(8) . 1_545
Ge10 K4 Ge3 133.637(16) . 2
Ge9 K4 Ge3 90.949(12) 1_545 2
Zn1 K4 Ge3 42.865(9) . 2
Ge8 K4 Ge3 89.008(13) . 2
Ge6 K4 Ge3 116.541(13) . 2
Ge4 K4 Ge3 86.340(11) . 2
Ge5 K4 Ge3 76.912(11) 1_545 2
Ge10 K4 K1 77.975(12) . .
Ge9 K4 K1 155.827(18) 1_545 .
Zn1 K4 K1 67.411(11) . .
Ge8 K4 K1 59.567(11) . .
Ge6 K4 K1 94.578(13) . .
Ge4 K4 K1 58.445(11) . .
Ge5 K4 K1 98.734(13) 1_545 .
Ge3 K4 K1 77.766(12) 2 .
Ge10 K4 K1 149.374(15) . 1_545
Ge9 K4 K1 54.187(10) 1_545 1_545
Zn1 K4 K1 63.759(11) . 1_545
Ge8 K4 K1 127.864(16) . 1_545
Ge6 K4 K1 91.775(13) . 1_545
Ge4 K4 K1 96.674(13) . 1_545
Ge5 K4 K1 56.352(10) 1_545 1_545
Ge3 K4 K1 53.100(10) 2 1_545
K1 K4 K1 127.266(17) . 1_545
Ge10 K4 K5 90.987(13) . 2
Ge9 K4 K5 52.781(11) 1_545 2
Zn1 K4 K5 100.520(16) . 2
Ge8 K4 K5 61.114(11) . 2
Ge6 K4 K5 158.395(16) . 2
Ge4 K4 K5 143.578(17) . 2
Ge5 K4 K5 122.455(15) 1_545 2
Ge3 K4 K5 57.774(11) 2 2
K1 K4 K5 103.641(16) . 2
K1 K4 K5 68.004(12) 1_545 2
Ge10 K4 K2 112.965(15) . 1_545
Ge9 K4 K2 54.076(10) 1_545 1_545
Zn1 K4 K2 96.032(13) . 1_545
Ge8 K4 K2 147.524(15) . 1_545
Ge6 K4 K2 55.935(10) . 1_545
Ge4 K4 K2 91.826(13) . 1_545
Ge5 K4 K2 55.834(10) 1_545 1_545
Ge3 K4 K2 107.850(13) 2 1_545
K1 K4 K2 149.796(16) . 1_545
K1 K4 K2 55.626(12) 1_545 1_545
K5 K4 K2 104.184(14) 2 1_545
Ge9 K5 Ge10 130.607(16) 2_564 .
Ge9 K5 Ge3 91.643(13) 2_564 .
Ge10 K5 Ge3 82.416(12) . .
Ge9 K5 Ge8 42.056(8) 2_564 2_564
Ge10 K5 Ge8 90.312(12) . 2_564
Ge3 K5 Ge8 98.859(12) . 2_564
Ge9 K5 Ge8 92.680(14) 2_564 2_554
Ge10 K5 Ge8 134.723(16) . 2_554
Ge3 K5 Ge8 83.989(11) . 2_554
Ge8 K5 Ge8 134.488(17) 2_564 2_554
Ge9 K5 K6 63.566(13) 2_564 2_554
Ge10 K5 K6 146.802(17) . 2_554
Ge3 K5 K6 130.224(17) . 2_554
Ge8 K5 K6 90.061(14) 2_564 2_554
Ge8 K5 K6 57.133(10) 2_554 2_554
Ge9 K5 K2 88.663(14) 2_564 .
Ge10 K5 K2 61.456(12) . .
Ge3 K5 K2 130.919(15) . .
Ge8 K5 K2 53.105(11) 2_564 .
Ge8 K5 K2 145.038(16) 2_554 .
K6 K5 K2 93.064(14) 2_554 .
Ge9 K5 Ge6 107.797(14) 2_564 .
Ge10 K5 Ge6 93.745(14) . .
Ge3 K5 Ge6 156.801(16) . .
Ge8 K5 Ge6 104.050(13) 2_564 .
Ge8 K5 Ge6 82.604(11) 2_554 .
K6 K5 Ge6 54.134(11) 2_554 .
K2 K5 Ge6 63.867(11) . .
Ge9 K5 K3 129.311(17) 2_564 2_554
Ge10 K5 K3 84.900(15) . 2_554
Ge3 K5 K3 53.636(10) . 2_554
Ge8 K5 K3 152.455(16) 2_564 2_554
Ge8 K5 K3 52.882(11) 2_554 2_554
K6 K5 K3 108.565(15) 2_554 2_554
K2 K5 K3 141.477(19) . 2_554
Ge6 K5 K3 103.324(14) . 2_554
Ge9 K5 K4 53.262(11) 2_564 2_554
Ge10 K5 K4 140.362(16) . 2_554
Ge3 K5 K4 58.282(11) . 2_554
Ge8 K5 K4 90.851(14) 2_564 2_554
Ge8 K5 K4 52.146(10) 2_554 2_554
K6 K5 K4 72.819(14) 2_554 2_554
K2 K5 K4 141.889(18) . 2_554
Ge6 K5 K4 124.207(15) . 2_554
K3 K5 K4 76.208(14) 2_554 2_554
Ge9 K5 K4 151.379(16) 2_564 .
Ge10 K5 K4 49.366(10) . .
Ge3 K5 K4 114.898(15) . .
Ge8 K5 K4 118.580(14) 2_564 .
Ge8 K5 K4 100.244(13) 2_554 .
K6 K5 K4 102.601(15) 2_554 .
K2 K5 K4 66.231(13) . .
Ge6 K5 K4 49.773(9) . .
K3 K5 K4 77.908(14) 2_554 .
K4 K5 K4 150.450(13) 2_554 .
Ge9 K5 K1 48.735(10) 2_564 2_564
Ge10 K5 K1 96.006(13) . 2_564
Ge3 K5 K1 49.012(9) . 2_564
Ge8 K5 K1 51.896(9) 2_564 2_564
Ge8 K5 K1 106.822(14) 2_554 2_564
K6 K5 K1 110.069(17) 2_554 2_564
K2 K5 K1 100.182(14) . 2_564
Ge6 K5 K1 153.932(16) . 2_564
K3 K5 K1 101.583(13) 2_554 2_564
K4 K5 K1 55.499(11) 2_554 2_564
K4 K5 K1 145.370(16) . 2_564
Ge10 K6 Ge6 131.514(15) . 2
Ge10 K6 Ge7 125.784(15) . 1_545
Ge6 K6 Ge7 85.357(12) 2 1_545
Ge10 K6 Ge7 43.560(8) . .
Ge6 K6 Ge7 96.483(13) 2 .
Ge7 K6 Ge7 164.472(16) 1_545 .
Ge10 K6 Ge1 99.892(15) . 2_554
Ge6 K6 Ge1 119.677(14) 2 2_554
Ge7 K6 Ge1 87.468(12) 1_545 2_554
Ge7 K6 Ge1 104.746(13) . 2_554
Ge10 K6 Ge8 42.628(8) . .
Ge6 K6 Ge8 90.372(13) 2 .
Ge7 K6 Ge8 122.929(14) 1_545 .
Ge7 K6 Ge8 41.842(7) . .
Ge1 K6 Ge8 140.165(15) 2_554 .
Ge10 K6 Ge9 86.728(12) . 1_545
Ge6 K6 Ge9 106.003(13) 2 1_545
Ge7 K6 Ge9 40.578(7) 1_545 1_545
Ge7 K6 Ge9 124.924(13) . 1_545
Ge1 K6 Ge9 106.118(14) 2_554 1_545
Ge8 K6 Ge9 87.692(11) . 1_545
Ge10 K6 K5 93.116(14) . 2
Ge6 K6 K5 64.047(12) 2 2
Ge7 K6 K5 66.298(11) 1_545 2
Ge7 K6 K5 100.590(14) . 2
Ge1 K6 K5 153.520(16) 2_554 2
Ge8 K6 K5 61.003(11) . 2
Ge9 K6 K5 51.414(10) 1_545 2
Ge10 K6 K3 84.038(14) . 2_554
Ge6 K6 K3 140.232(15) 2 2_554
Ge7 K6 K3 55.927(11) 1_545 2_554
Ge7 K6 K3 123.225(16) . 2_554
Ge1 K6 K3 56.423(11) 2_554 2_554
Ge8 K6 K3 116.831(15) . 2_554
Ge9 K6 K3 51.327(10) 1_545 2_554
K5 K6 K3 102.727(14) 2 2_554
Ge10 K6 K8 71.254(11) . 2_564
Ge6 K6 K8 112.309(15) 2 2_564
Ge7 K6 K8 137.851(16) 1_545 2_564
Ge7 K6 K8 55.312(11) . 2_564
Ge1 K6 K8 50.400(12) 2_554 2_564
Ge8 K6 K8 95.932(12) . 2_564
Ge9 K6 K8 141.460(18) 1_545 2_564
K5 K6 K8 155.788(17) 2 2_564
K3 K6 K8 94.123(17) 2_554 2_564
Ge10 K6 K7 173.423(16) . 2
Ge6 K6 K7 51.172(13) 2 2
Ge7 K6 K7 47.724(10) 1_545 2
Ge7 K6 K7 142.378(17) . 2
Ge1 K6 K7 81.627(13) 2_554 2
Ge8 K6 K7 137.319(18) . 2
Ge9 K6 K7 86.704(12) 1_545 2
K5 K6 K7 83.039(14) 2 2
K3 K6 K7 91.585(15) 2_554 2
K8 K6 K7 114.078(13) 2_564 2
Ge10 K6 K4 45.328(9) . .
Ge6 K6 K4 116.777(14) 2 .
Ge7 K6 K4 85.512(11) 1_545 .
Ge7 K6 K4 79.884(10) . .
Ge1 K6 K4 122.191(15) 2_554 .
Ge8 K6 K4 46.957(9) . .
Ge9 K6 K4 45.060(8) 1_545 .
K5 K6 K4 55.141(11) 2 .
K3 K6 K4 72.806(12) 2_554 .
K8 K6 K4 115.655(13) 2_564 .
K7 K6 K4 128.576(13) 2 .
Ge7 K7 Ge7 114.88(3) 3_464 2_564
Ge7 K7 Ge6 87.976(13) 3_464 4
Ge7 K7 Ge6 125.71(2) 2_564 4
Ge7 K7 Ge6 125.71(2) 3_464 .
Ge7 K7 Ge6 87.977(13) 2_564 .
Ge6 K7 Ge6 43.085(12) 4 .
Ge7 K7 Ge4 120.458(13) 3_464 .
Ge7 K7 Ge4 120.458(13) 2_564 .
Ge6 K7 Ge4 42.164(10) 4 .
Ge6 K7 Ge4 42.163(10) . .
Ge7 K7 K2 64.865(10) 3_464 4
Ge7 K7 K2 163.41(3) 2_564 4
Ge6 K7 K2 70.589(13) 4 4
Ge6 K7 K2 105.68(2) . 4
Ge4 K7 K2 68.201(16) . 4
Ge7 K7 K2 163.41(3) 3_464 .
Ge7 K7 K2 64.865(10) 2_564 .
Ge6 K7 K2 105.68(2) 4 .
Ge6 K7 K2 70.589(13) . .
Ge4 K7 K2 68.201(16) . .
K2 K7 K2 110.27(3) 4 .
Ge7 K7 K8 57.681(13) 3_464 1_554
Ge7 K7 K8 57.681(13) 2_564 1_554
Ge6 K7 K8 126.53(3) 4 1_554
Ge6 K7 K8 126.53(3) . 1_554
Ge4 K7 K8 166.95(3) . 1_554
K2 K7 K8 117.379(16) 4 1_554
K2 K7 K8 117.379(16) . 1_554
Ge7 K7 K6 51.460(13) 3_464 3_454
Ge7 K7 K6 105.30(2) 2_564 3_454
Ge6 K7 K6 50.806(14) 4 3_454
Ge6 K7 K6 75.788(19) . 3_454
Ge4 K7 K6 92.955(19) . 3_454
K2 K7 K6 87.493(13) 4 3_454
K2 K7 K6 145.06(2) . 3_454
K8 K7 K6 76.005(18) 1_554 3_454
Ge7 K7 K6 105.30(2) 3_464 2_554
Ge7 K7 K6 51.460(13) 2_564 2_554
Ge6 K7 K6 75.787(18) 4 2_554
Ge6 K7 K6 50.806(14) . 2_554
Ge4 K7 K6 92.955(19) . 2_554
K2 K7 K6 145.06(2) 4 2_554
K2 K7 K6 87.493(13) . 2_554
K8 K7 K6 76.005(18) 1_554 2_554
K6 K7 K6 63.499(18) 3_454 2_554
Ge7 K7 K6 99.011(19) 3_464 2_564
Ge7 K7 K6 47.882(11) 2_564 2_564
Ge6 K7 K6 172.151(12) 4 2_564
Ge6 K7 K6 129.067(7) . 2_564
Ge4 K7 K6 134.00(2) . 2_564
K2 K7 K6 115.60(2) 4 2_564
K2 K7 K6 68.079(14) . 2_564
K8 K7 K6 56.088(13) 1_554 2_564
K6 K7 K6 131.98(2) 3_454 2_564
K6 K7 K6 98.767(14) 2_554 2_564
Ge7 K7 K6 47.882(11) 3_464 3_464
Ge7 K7 K6 99.011(19) 2_564 3_464
Ge6 K7 K6 129.067(7) 4 3_464
Ge6 K7 K6 172.151(12) . 3_464
Ge4 K7 K6 134.00(2) . 3_464
K2 K7 K6 68.079(14) 4 3_464
K2 K7 K6 115.60(2) . 3_464
K8 K7 K6 56.088(13) 1_554 3_464
K6 K7 K6 98.767(14) 3_454 3_464
K6 K7 K6 131.98(2) 2_554 3_464
K6 K7 K6 58.782(15) 2_564 3_464
Ge1 K8 Ge2 122.77(2) 1_565 .
Ge1 K8 Ge7 106.858(14) 1_565 2_565
Ge2 K8 Ge7 108.675(14) . 2_565
Ge1 K8 Ge7 106.858(14) 1_565 3_465
Ge2 K8 Ge7 108.675(14) . 3_465
Ge7 K8 Ge7 100.82(2) 2_565 3_465
Ge1 K8 Ge3 41.884(10) 1_565 3_465
Ge2 K8 Ge3 86.012(18) . 3_465
Ge7 K8 Ge3 144.352(16) 2_565 3_465
Ge7 K8 Ge3 104.890(8) 3_465 3_465
Ge1 K8 Ge3 41.884(10) 1_565 2_565
Ge2 K8 Ge3 86.012(18) . 2_565
Ge7 K8 Ge3 104.890(8) 2_565 2_565
Ge7 K8 Ge3 144.352(16) 3_465 2_565
Ge3 K8 Ge3 42.263(11) 3_465 2_565
Ge1 K8 Ge1 163.03(3) 1_565 .
Ge2 K8 Ge1 40.266(10) . .
Ge7 K8 Ge1 83.581(13) 2_565 .
Ge7 K8 Ge1 83.581(13) 3_465 .
Ge3 K8 Ge1 123.24(2) 3_465 .
Ge3 K8 Ge1 123.24(2) 2_565 .
Ge1 K8 K3 117.265(15) 1_565 4
Ge2 K8 K3 56.222(12) . 4
Ge7 K8 K3 134.36(2) 2_565 4
Ge7 K8 K3 56.695(10) 3_465 4
Ge3 K8 K3 80.981(13) 3_465 4
Ge3 K8 K3 115.29(2) 2_565 4
Ge1 K8 K3 56.971(11) . 4
Ge1 K8 K3 117.265(15) 1_565 .
Ge2 K8 K3 56.221(12) . .
Ge7 K8 K3 56.695(10) 2_565 .
Ge7 K8 K3 134.36(2) 3_465 .
Ge3 K8 K3 115.29(2) 3_465 .
Ge3 K8 K3 80.980(13) 2_565 .
Ge1 K8 K3 56.971(11) . .
K3 K8 K3 108.17(2) 4 .
Ge1 K8 K7 111.99(2) 1_565 1_556
Ge2 K8 K7 125.24(2) . 1_556
Ge7 K8 K7 50.596(10) 2_565 1_556
Ge7 K8 K7 50.596(10) 3_465 1_556
Ge3 K8 K7 143.116(19) 3_465 1_556
Ge3 K8 K7 143.12(2) 2_565 1_556
Ge1 K8 K7 84.97(2) . 1_556
K3 K8 K7 99.677(17) 4 1_556
K3 K8 K7 99.678(17) . 1_556
Ge1 K8 K6 54.891(12) 1_565 2_565
Ge2 K8 K6 144.681(11) . 2_565
Ge7 K8 K6 52.974(10) 2_565 2_565
Ge7 K8 K6 104.75(2) 3_465 2_565
Ge3 K8 K6 96.284(16) 3_465 2_565
Ge3 K8 K6 73.061(12) 2_565 2_565
Ge1 K8 K6 136.488(15) . 2_565
K3 K8 K6 158.996(18) 4 2_565
K3 K8 K6 91.897(10) . 2_565
K7 K8 K6 70.057(18) 1_556 2_565
Ge1 K8 K6 54.891(11) 1_565 3_465
Ge2 K8 K6 144.681(11) . 3_465
Ge7 K8 K6 104.75(2) 2_565 3_465
Ge7 K8 K6 52.974(10) 3_465 3_465
Ge3 K8 K6 73.061(12) 3_465 3_465
Ge3 K8 K6 96.284(16) 2_565 3_465
Ge1 K8 K6 136.488(15) . 3_465
K3 K8 K6 91.897(10) 4 3_465
K3 K8 K6 158.996(18) . 3_465
K7 K8 K6 70.057(18) 1_556 3_465
K6 K8 K6 67.545(17) 2_565 3_465
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ge1 Ge2 2.4811(5) .
Ge1 Ge3 2.5320(4) 3_455
Ge1 Ge3 2.5320(4) 2
Ge1 K8 3.3602(8) 1_545
Ge1 K6 3.5675(5) 2
Ge1 K6 3.5675(5) 3_455
Ge1 K3 3.6102(5) .
Ge1 K3 3.6102(5) 4
Ge1 K8 3.7103(7) .
Ge2 Zn1 2.5788(5) .
Ge2 Ge3 2.6611(3) 3_455
Ge2 Ge3 2.6611(3) 2
Ge2 K1 3.3332(5) 4
Ge2 K1 3.3333(5) .
Ge2 K3 3.4667(5) .
Ge2 K3 3.4667(5) 4
Ge2 K8 3.4672(8) .
Ge3 Ge1 2.5320(4) 2_554
Ge3 Zn1 2.6275(4) 2_554
Ge3 Ge3 2.6503(4) 4_655
Ge3 Ge2 2.6611(3) 2_554
Ge3 K1 3.4507(5) 2_564
Ge3 K3 3.4691(5) 2_554
Ge3 K8 3.6757(7) 2_564
Ge3 K5 3.7531(5) .
Ge3 K4 3.7739(6) 2_554
Zn1 Ge5 2.6123(5) 1_545
Zn1 Ge3 2.6275(4) 2
Zn1 Ge3 2.6275(4) 3_455
Zn1 Ge4 2.6451(5) .
Zn1 K4 3.3254(5) 4
Zn1 K4 3.3254(5) .
Zn1 K1 3.8718(5) 4_545
Zn1 K1 3.8718(5) 1_545
Zn1 K1 4.0161(5) 4
Zn1 K1 4.0161(5) .
Ge4 Ge6 2.5522(4) .
Ge4 Ge6 2.5522(4) 4
Ge4 Ge5 2.7396(4) 1_545
Ge4 K7 3.5563(9) .
Ge4 K4 3.6135(5) 4
Ge4 K4 3.6136(5) .
Ge4 K1 3.6583(5) 4
Ge4 K1 3.6583(5) .
Ge4 K2 3.9879(5) 4
Ge4 K2 3.9880(5) .
Ge5 Ge6 2.5452(4) 4_565
Ge5 Ge6 2.5452(4) 1_565
Ge5 Zn1 2.6123(5) 1_565
Ge5 Ge4 2.7397(4) 1_565
Ge5 K1 3.6051(6) .
Ge5 K1 3.6051(6) 4
Ge5 K4 3.6806(5) 1_565
Ge5 K4 3.6806(5) 4_565
Ge5 K2 3.7156(5) 4
Ge5 K2 3.7157(5) .
Ge6 Ge5 2.5452(4) 1_545
Ge6 Ge6 2.5990(5) 4
Ge6 K4 3.4595(6) .
Ge6 K6 3.5208(6) 2_554
Ge6 K7 3.5391(8) .
Ge6 K2 3.6485(5) 1_545
Ge6 K5 3.9065(5) .
Ge7 Ge9 2.5447(3) .
Ge7 Ge10 2.5592(3) .
Ge7 Ge8 2.5676(3) .
Ge7 K7 3.3307(5) 2_565
Ge7 K6 3.5210(5) 1_565
Ge7 K6 3.5371(5) .
Ge7 K3 3.5648(6) 2_564
Ge7 K8 3.6429(6) 2_564
Ge7 K2 3.6988(6) 2_565
Ge8 Ge10 2.5569(3) .
Ge8 Ge9 2.5828(3) .
Ge8 K2 3.4110(6) 2_565
Ge8 K4 3.4253(5) .
Ge8 K3 3.4425(6) .
Ge8 K1 3.6420(5) .
Ge8 K6 3.6477(5) .
Ge8 K5 3.7853(5) 2_565
Ge8 K5 3.7985(5) 2
Ge9 Ge10 2.5481(3) .
Ge9 K5 3.3024(6) 2_565
Ge9 K4 3.3234(5) 1_565
Ge9 K1 3.3527(5) .
Ge9 K3 3.3873(6) 2_564
Ge9 K2 3.5053(6) .
Ge9 K6 3.7831(5) 1_565
Ge10 K4 3.3010(5) .
Ge10 K3 3.3324(5) 2_564
Ge10 K6 3.3432(5) .
Ge10 K5 3.3909(6) .
Ge10 K2 3.7173(5) .
K1 Ge3 3.4507(5) 2_565
K1 K1 3.6452(9) 4
K1 K2 3.8024(7) .
K1 K4 3.8663(6) .
K1 Zn1 3.8718(5) 1_565
K1 K4 3.9390(6) 1_565
K2 Ge8 3.4109(6) 2_564
K2 K7 3.5569(7) .
K2 Ge6 3.6486(5) 1_565
K2 Ge7 3.6988(6) 2_564
K2 K5 3.8441(7) .
K2 K3 4.1187(6) 2_564
K2 K4 4.1958(7) 1_565
K3 Ge10 3.3324(5) 2_565
K3 Ge9 3.3873(6) 2_565
K3 Ge3 3.4690(5) 2
K3 Ge7 3.5648(6) 2_565
K3 K8 3.8545(7) .
K3 K5 3.9283(7) 2
K3 K6 4.0223(8) 2
K3 K2 4.1188(6) 2_565
K4 Ge9 3.3233(5) 1_545
K4 Ge5 3.6806(5) 1_545
K4 Ge3 3.7739(6) 2
K4 K1 3.9391(6) 1_545
K4 K5 3.9856(7) 2
K4 K2 4.1958(7) 1_545
K5 Ge9 3.3024(6) 2_564
K5 Ge8 3.7853(5) 2_564
K5 Ge8 3.7984(5) 2_554
K5 K6 3.8296(7) 2_554
K5 K3 3.9283(7) 2_554
K5 K4 3.9856(7) 2_554
K5 K1 4.4318(7) 2_564
K6 Ge6 3.5207(6) 2
K6 Ge7 3.5210(5) 1_545
K6 Ge1 3.5675(5) 2_554
K6 Ge9 3.7832(5) 1_545
K6 K5 3.8297(7) 2
K6 K3 4.0223(8) 2_554
K6 K8 4.2066(7) 2_564
K6 K7 4.4439(10) 2
K7 Ge7 3.3308(5) 3_464
K7 Ge7 3.3308(5) 2_564
K7 Ge6 3.5390(8) 4
K7 K2 3.5568(7) 4
K7 K8 4.0933(12) 1_554
K7 K6 4.4440(10) 3_454
K7 K6 4.4440(10) 2_554
K7 K6 4.7649(9) 2_564
K7 K6 4.7649(9) 3_464
K8 Ge1 3.3602(8) 1_565
K8 Ge7 3.6429(6) 2_565
K8 Ge7 3.6429(6) 3_465
K8 Ge3 3.6757(7) 3_465
K8 Ge3 3.6757(7) 2_565
K8 K3 3.8545(7) 4
K8 K7 4.0932(12) 1_556
K8 K6 4.2066(7) 2_565
K8 K6 4.2066(7) 3_465
